AS LEVEL Section A

FACT FILES
Technology & Design
For first teaching from September 2011
For first award in Summer 2012

Plastic
 1.4 Plastic

Learning Outcomes

Students should be able to: Thermoplastic articles are formed at relatively high
• Understand the difference between thermoplastic and temperatures and are cooled to set in a desired shape.
thermomsetting plastics; They can be reheated and reshaped many times without
changing their structure and properties.
• Demonstrate knowledge and understanding of the
Common examples of thermoplastics are:
properties, working characteristics and uses for the
• Polythene (bottles, pipes, packaging etc.)
following polymers – polythene, polystyrene, PVC,
acrylic, nylon, ABS, melamine-formaldehyde and epoxy • Nylon (fabrics, gear wheels, bearings etc.)
resins. • PVC (cable insulation, guttering, window frames etc.)
• Polystyrene (flower pots, model kits, packaging etc.)
• Acrylic
• ABS (kitchen ware, safety helmets, car components etc.)
Course Content

There are 2 main types of plastics:

1. Thermoplastics
2. Thermosetting plastics

Thermoplastics
These plastics can be re-heated and therefore shaped in
various ways. They become mouldable after reheating as
they do not undergo significant chemical or molecular
change. Reheating and shaping can be repeated. The bond
between the molecules is weak and become weaker when
reheated, allowing reshaping. Thermoplastics tend to be
composed of ‘long chain monomers’. These types of plastics
can be recycled.

These plastics can be easily moulded and are economically

viable for industrial use due to the fact that that can be
re-used. However, with the exception of PTFE, the weakness
of Thermoplastics is that when heat is applied to them they
are less useful. At temperatures of over 100°C they tend
to lose their rigidity and soften due to the bond between
the molecules being weak and becoming weaker when
reheated, allowing reshaping.
Unit 1.4 Plastic

1
 Material Forms Properties Uses
(LDPE) Powder, granules, Low density: Tough, good chemical Kitchen ware, buckets, food
Polythene sheet resistance, flexible, soft, electrical insulator, bags, bottles.
(HDPE) available in a range of colours.
Powder, film, sheet Food containers, lamp
High density: stiff, harder than LDPE, high shades, yoghurt cartons.
softening point, waxy texture, can be
sterilised.

Polyamide (Nylon) Powder, granules, Hard, clear, very durable, tough, resilient to Gears, bearings, washers,
rod, tube, sheet. wear, low coefficient of friction and self- bristles, textiles, clothing,
lubricating, resistant to high temperature, stocking etc.
machines well, difficult to join.
Polyvinyl chloride (PVC) Rigid - Powder, Weather resistant, stiff, hard, tough, Pipes, guttering, bottles,
pastes. lightweight, range of colours, needs to be shoe soles, window frames,
stabilised for outdoor use. hosepipes.
Flexible – powders, Soft, flexible, good electrical insulator.
pastes, liquid, sheet

Polystyrene (PS) (HIPS) Powders, granules, Conventional: Light, hard, stiff, colourless, Model kits, packaging,
sheet, expanded transparent, brittle, low impact strength, disposable plates/cups.
foam, beads, slabs. hygienic with food, water resistant Refrigerator linings, toys.
Sound and heat insulation,
Toughened: increased impact strength, packaging.
pigmented.

Expanded/foam: buoyant, lightweight,

crumbles, good sound and heat insulator.

Polymethyl Sheet, rod, tube. Stiff, hard, durable, similar impact resistance Illuminated signs, windows,
methacrylate (Acrylic) as glass, scratches easily, fibre optic qualities, rear car lights, reflectors,
hygienic with food, good electrical insulator, sanitary ware, light units.
colours, polishes and machines well.
Acrylonitrile Powder, granules High impact strength, tough, scratch Safety helmets, car
butadienestyrene resistant, lightweight, durable, high quality components, kitchen ware,
(ABS) surface finish, resistant to chemicals. durable cases for electronic
products, toys.
Unit 1.4 Plastic

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 Examples of products manufactured Material Forms Properties Uses
using thermoplastics: Melamine Laminates, Hard, resists Tableware,
formaldehyde granules, scratches buttons,
powders. and marking, laminated
strong, brittle, work surfaces,
odourless, stain electrical
resistant, resists insulation,

iStockphoto/Thinkstock
some chemicals, cookers,
Hemera/Thinkstock

wide range refrigerators.

of colours,
tasteless.
Epoxy resin Liquids, High strength Surface
pastes. when coatings,
Polythene Nylon reinforced, bonding agent,
high adhesive encapsulation,
qualities (low laminating, PCB.
shrinkage),
good chemical
and wear
iStockphoto/Thinkstock resistance, heat
Hemera/Thinkstock

resistant to
250°C.

PVC Polystyrene Examples of products manufactured

using thermosetting plastics:
Comstock/Thinkstock

Photodisc/Thinkstock

Stockbyte/Thinkstock
Acrylic ABS

Epoxy resin
Thermosetting plastics
Once ‘set’ these plastics cannot be reheated to soften, shape
and mould. The molecules of these plastics are cross linked
in three dimensions and this is why they cannot be reshaped
or recycled. The bond between the molecules is very strong
iStockphoto/Thinkstock

These plastics can withstand heat much better than

Thermoplastics without losing their rigidity and they are
good insulators.

Common examples of thermosetting plastics include:

• Melamine formaldehyde Melamine formaldehyde
• Epoxy resin
Unit 1.4 Plastic

3
 Revision questions

1. Briefly explain the difference between thermoplastic

and thermosetting plastics.

2. For each application listed below, select a suitable

plastic from acrylic, nylon and polystyrene, and give one
main reason for your choice.
a. Shop signs.
b. Beads for wall insulation.
c. Gearwheels.
d. Packaging.

3. Give one main reason why:

a. Acrylic is used for illuminated signs.
b. Nylon is used for gear wheels.
c. Polyvinyl chloride (PVC) is used for drain pipes and
guttering.
d. Polythene is used for detergent bottles.

4. ABS and polystyrene are used in a range of products.

a. Give two main characteristics of ABS which make it
suitable for certain parts of children’s toys.
b. Give two main characteristics of polystyrene which
it suitable for cups in vending machines or yoghurts
pots.
Unit 1.4 Plastic