CHEMISTRY CLASSES 9868366053, 9968253763

Time: 2 hour SOLUTIONS Max. Marks: 50

(1)
1. What is the limiting value of the van’t Hoff factor for Na 2SO4 . 10H2O?
2. What type of deviation is shown by ethanol-acetone mixture and why? (1)
3. State Raoult’s law for a solution containing both volatile components. (1)
4. What do you infer about the molecular state of the solute if the van’t Hoff factor is less
than 1? (1)
-1
5. 100 g of liquid A (molar mass 140 g mol ) was dissolved in 1000 g of liquid B (molar
mass 180 g mol-1). The vapour pressure of pure liquid B was found to be 500 torr.
Calculate the vapour pressure of pure liquid A and its vapour Pressure in the solution if (2)
the total vapour pressure of the solution is 475 torr.
6. Account for the following:
(i) 0.1 m NaCl solution has a higher boiling point than 0.1 m glucose solution.
(2)
(ii) Ethylene glycol is added to car radiator as an antifreeze.
7.
(i) Name one semi-permeable membrane used in osmosis.
(ii) Arrange the following solutions in order of increasing van’t Hoff factor:
0.1 m NaCl, 0.01 m NaCl, 0.001 m NaCl (2)
8. What types of non-idealities are exhibited by the following system:
(i) Acetone + chloroform (ii) ethanol + water? (2)
9. Calculate the mass of NaCl that must be added to one kilogram of water so that the
freezing point of water is depressed by 3 K. Given: K f for water = 1.86 oC kg mol-1.
(2)
(Atomic mass: Na = 23, Cl =35.5)
10. Give reason:
(i) Oxygen diluted with helium gas is used as a breathing gas by deep sea divers.
(ii) Blood cells placed in pure water swell and finally burst. (2)
11. Calculate the molality of 1 L solution of H2SO4 (d = 1.20 g/cm3) which is 23% w/v (mass
by volume). (3)
12. 1.00 g of a non-electrolyte sulphur is dissolved in 50.0 g of benzene and lowers the
freezing point of benzene by 0.40 K. The freezing pont depression constant of benzene
is 5.12 K kg mol-1. Find the molecular mass and molecular formula of sulphur. (3)
13. (i) Define molal elevation constant.
(ii) Show with well-labelled diagram, the variation between the vapour pressure and
the freezing point for a pure solvent and the solution containing non-volatile
(3)
solute.
14. 2 g of benzoic acid (C6H5COOH) is dissolved in 30 g benzene shows a depression in
freezing point equal to 1.62 K. Molal depression constant for benzene is 4.9 K kg mol -1.
 CHEMISTRY CLASSES 9868366053, 9968253763

What is the percentage association of acid if it forms a double molecule (called dimer) in
solution?
(3)
(Atomic Mass: H = 1, C = 12, O = 16)
15. Define osmotic pressure.
Explain how molecular mass of a solute can be determined using osmotic pressure.
Why is osmotic pressure preferred over other colligative properties? (3)
16. An antifreeze solution is prepared from 222.6 g of ethylene glycol (C 2H6O2) and 200 g
water.
(i) Calculate the molality of the solution.
(ii) Find freezing point of the solution. (3)
(Kf for water = 1.86 K kg mol-1)
17. Why and when do we observe abnormal molecular masses? Explain giving suitable
(3)
examples.
18. An aqueous solution of glucose (C6H12O6) boils at a temperature 0.01 oC higher than that
of pure water. The molal elevation constant for water is 0.52 K kg mol -1. What is the
number of glucose molecules in the solution containing 100 g of water? (3)
19.
(i) What are azeotropes?
(ii) State Henry’s Law.
(iii) Which of the following changes with change in temperature and why?
Molarity or molality
(iv) The partial pressure of ethane over a saturated solution containing 6.56 X 10 -2 g
of ethane is 1 bar. If the solution contains 5.00 X 10-2 g of ethane, then what
shall be the partial pressure of the gas? (1+1+1+2=5)
20.
(i) What is reverse osmosis?
(ii) CaCl2 is used to clear snow from roads in hill station. Give reason.
(iii) A bottle of sulphuric acid is labeled as 13% w/w.
(a) What is the mole fraction of each component?
(b) What is the molality of the solution?
(c) Find the molarity of the solution if the density of the solution is 1.10 g/ml.
(molecular mass of sulphuric acid = 98) ( 1 + 1 + 3 = 5)