http://www.islandoilsupply.com/shell/msds/057115.

txt

ALVANIA(R) R3 GREASE
71034 11/07/96
SHELL MATERIAL SAFETY DATA SHEET
BE SAFE. READ OUR PRODUCT SAFETY INFORMATION ... AND PASS IT ON.
PRODUCT LIABILITY LAW REQUIRES IT!
******************** MATERIAL SAFETY DATA SHEET 57115 - 00 ********************

ALVANIA(R) R3 GREASE SH MSDS: 57115 - 00 11/07/96

MANUFACTURER'S NAME AND ADDRESS

SHELL OIL COMPANY
PRODUCT SAFETY & COMPLIANCE
P.O. BOX 4320
HOUSTON, TX 77210

TELEPHONE NUMBERS:
24 HOUR EMERGENCY ASSISTANCE
SHELL: 713-473-9461 CHEMTREC: 800-424-9300

GENERAL MSDS ASSISTANCE

SHELL: 713-241-4819

_______________________________________________________________________________
SECTION I NAME
_______________________________________________________________________________
PRODUCT: ALVANIA(R) R3 GREASE
CHEM NAME: MIXTURE (SEE SECTION II-A) HEALTH HAZARD: 1
CHEM FAMILY: PETROLEUM HYDROCARON; LUBRICATING GREASE FIRE HAZARD: 1
SHELL CODE: 71034 REACTIVITY: 0
_______________________________________________________________________________
SECTION II-A PRODUCT/INGREDIENT
_______________________________________________________________________________
NO. COMPOSITION CAS NO. PERCENT
--- ----------- ------- -------

P ALVANIA R3 GREASE MIXTURE 100

1 HIGHLY REFINED MINERAL OIL MIXTURE 1-5
2 SODIUM NITRITE 7632-00-0 1
3 N-1-NAPHTHYLAMINE 90-30-2 4.0

NFPA HAZARD RATING: HEALTH 0 FIRE 1 REACTIVITY 0

_______________________________________________________________________________
SECTION II-B ACUTE TOXICITY DATA
_______________________________________________________________________________
NO. ACUTE ORAL LD50 ACUTE DERMAL LD50 ACUTE INHALATION LC50
--- --------------- ----------------- ---------------------

P >200 MG/KG* >2000 MG/KG NOT AVAILABLE

* BASED ON SIMILAR PRODUCTS.

_______________________________________________________________________________
SECTION III HEALTH INFORMATION
_______________________________________________________________________________

THE HEALTH EFFECTS NOTED BELOW ARE CONSISTENT WITH REQUIREMENTS UNDER THE OSHA

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HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200).

EYE CONTACT: MAY BE MILDLY IRRITATING TO THE EYES.

SKIN CONTACT: MAY CAUSE SKIN SENSITIZATION.

INHALATION: NO SPECIFIC INFORMATION IDENTIFIED.

INGESTION: MAY BE HARMFUL IF SWALLOWED. SODIUM NITRITE MAY AFFECT BLOOD

HEMOGLOBIN SUCH THAT THE OXYGEN CARRYING CAPACITY OF THE BLOOD IS
REDUCED. THIS MAY LEAD TO CYANOSIS, SHORTNESS OF BREATH,
PALPITATIONS AND IN EXTREME CIRCUMSTANCES UNCONSCIOUSNESS.

SIGNS AND SYMPTOMS: IRRITATION AS NOTED ABOVE. LOCAL NECROSIS IS EVIDENCED BY

DELAYED ONSET OF PAIN AND TISSUE DAMAGE A FEW HOURS
FOLLOWING INJECTION.

AGGRAVATED MEDICAL CONDITIONS:

PREEXISTING SKIN DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT.

OTHER HEALTH EFFECTS:

THIS PRODUCT AND ITS COMPONENTS ARE NOT CLASSIFIED AS CARCINOGENS BY
INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC), NATIONAL TOXOCOLOGY
PROGRAM (NTP) OR OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA).

_______________________________________________________________________________
SECTION IV OCCUPATIONAL EXPOSURE LIMITS
_______________________________________________________________________________

COMP OSHA ACGIH

NO. PEL/TWA PEL/CEILING TLV/TWA TLV/STEL OTHER
--- ------- ----------- ------- -------- -----

NO OSHA/PEL OR ACGIH/TLV HAS BEEN ESTABLISHED.

_______________________________________________________________________________
SECTION V EMERGENCY AND FIRST AID PROCEDURES
_______________________________________________________________________________

EYE CONTACT: FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET
MEDICAL ATTENTION.

SKIN CONTACT: REMOVE CONTAMINATED CLOTHING AND WIPE EXCESS OFF. WASH WITH SOAP
AND WATER OR A WATERLESS HAND CLEANER FOLLOWED BY SOAP AND WATER.
DO NOT REUSE CLOTHING UNTIL THOROUGHLY CLEANED. IF IRRITATION
PERSISTS, GET MEDICAL ATTENTION. IF MATERIAL IS INJECTED UNDER
THE SKIN, GET MEDICAL ATTENTION PROMPTLY TO PREVENT SERIOUS
DAMAGE; DO NOT WAIT FOR SYMPTOMS TO DEVELOP.

INHALATION: REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS

DIFFICULT. GET MEDICAL ATTENTION.

INGESTION: DO NOT INDUCE VOMITING. IN GENERAL, NO TREATMENT IS NECESSARY

UNLESS LARGE QUANTITIES OF PRODUCT ARE INGESTED. HOWEVER, GET
MEDICAL ADVICE.*

NOTE TO PHYSICIAN: *NOTE TO THE PHYSICIAN: IN GENERAL, EMESIS INDUCTION IS

UNNECESSARY IN HIGH VISCOSITY, LOW VOLATILITY PRODUCTS,
I.E., MOST OILS AND GREASES.

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_______________________________________________________________________________
SECTION VI SUPPLEMENTAL HEALTH INFORMATION
_______________________________________________________________________________

NONE IDENTIFIED.

_______________________________________________________________________________
SECTION VII PHYSICAL DATA
_______________________________________________________________________________

BOILING POINT (DEG F): SPECFIC GRAVITY (H2O = 1): VAPOR PRESSURE (MM HG):
NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE

MELTING POINT (DEG F): SOLUBILITY IN WATER: VAPOR DENSITY (AIR = 1):
300 (DROP POINT) INSOLUBLE NOT AVAILABLE

EVAPORATION RATE (NORMAL BUTYL ACETATE = 1):NOT AVAILABLE

APPEARANCE AND ODOR:BEIGE, SEMI-SOLID GREASE. SLIGHT HYDROCARBON ODOR.

PHYS/CHEM PROPERTIES:

_______________________________________________________________________________
SECTION VIII FIRE AND EXPLOSION HAZARDS
_______________________________________________________________________________

FLASH POINT AND METHOD: >392 DEG F. COC (BASE OIL)

FLAMMABLE LIMITS/PERCENT VOLUME IN AIR: LOWER: N/AV HIGHER: N/AV

EXTINGUISHING MEDIA:
USE WATER FOG, DRY CHEMICAL OR CO2. DO NOT USE A DIRECT STREAM OF WATER.
PRODUCT WILL FLOAT AND CAN BE REIGNITED ON SURFACE OF WATER.

SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS:

DO NOT ENTER CONFINED FIRE SPACE WITHOUT PROPER PROTECTIVE EQUIPMENT
INCLUDING A NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS. COOL FIRE
EXPOSED CONTAINERS SURROUNDING EQUIPMENT AND STRUCTURES WITH WATER.

UNUSUAL FIRE AND EXPLOSION HAZARDS:

_______________________________________________________________________________
SECTION IX REACTIVITY
_______________________________________________________________________________

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STABLITY: STABLE HAZARDOUS POLYMERIZATION WILL NOT OCCUR

CONDITIONS AND MATERIALS TO AVOID:

AVOID HEAT, OPEN FLAME AND CONTACT WITH STRONG OXIDIZING AGENTS.

HAZARDOUS DECOMPOSITION PRODUCTS:

THERMAL DECOMPOSITION PRODUCTS ARE HIGHLY DEPENDENT ON THE COMBUSTION
CONDITIONS. A COMPLEX MIXTURE OF AIRBORNE SOLID, LIQUID PARTICULATES AND
GASES WILL EVOLVE WHEN THIS MATERIAL UNDERGOES PYROLYSIS OR COMBUSTION.
CARBON MONOXIDE, SULFUR OXIDES AND UNIDENTIFIED ORGANIC COMPOUNDS MAY BE
FORMED UPON COMBUSTION.

_______________________________________________________________________________
SECTION X EMPLOYEE PROTECTION
_______________________________________________________________________________

RESPIRATORY PROTECTION:
NOT ORDINARILY REQUIRED.

PROTECTIVE CLOTHING
USE OIL RESISTANT GLOVES AND OTHER CLOTHING AS NEEDED TO MINIMIZE SKIN
CONTACT.

ADDITIONAL PROTECTIVE MEASURES:

_______________________________________________________________________________
SECTION XI ENVIRONMENTAL PROTECTION
_______________________________________________________________________________

SPILL OR LEAK PROCEDURES:

SCOOP UP EXCESS GREASE. CLEAN AREA WITH APPROPRIATE CLEANER.

_______________________________________________________________________________
SECTION XII SPECIAL PRECAUTIONS
_______________________________________________________________________________

STORE IN A COOL, DRY PLACE WITH ADEQUATE VENTILATION. KEEP AWAY FROM OPEN
FLAMES AND HIGH TEMPERATURES.

MINIMIZE SKIN CONTACT. WASH WITH SOAP AND WATER BEFORE EATING, DRINKING,
SMOKING OR USING TOILET FACILITIES. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. PROPERLY DISPOSE OF CONTAMINATED LEATHER ARTICLES, INCLUDING SHOES,
THAT CANNOT BE DECONTAMINATED.

_______________________________________________________________________________
SECTION XIII TRANSPORTATION REQUIREMENTS
_______________________________________________________________________________

DEPARTMENT OF TRANSPORTATION CLASSIFICATION:

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NOT HAZARDOUS BY D.0.T. REGULATIONS

DOT PROPER SHIPPING NAME:

OTHER REQUIREMENTS:

_______________________________________________________________________________
SECTION XIV OTHER REGULATORY CONTROLS
_______________________________________________________________________________

THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE EPA/TSCA INVENTORY OF CHEMICAL
SUBSTANCES.

PROTECTION OF STRATOSPHERIC OZONE (PURSUANT TO SECTION 611 OF THE CLEAN AIR ACT
AMENDMENTS OF 1990): PER 40 CFR PART 82, THIS PRODUCT DOES NOT CONTAIN NOR
WAS IT DIRECTLY MANUFACTURED WITH ANY CLASS I OR CLASS II OZONE DEPLETING
SUBSTANCES.

IN ACCORDANCE WITH SARA TITLE III, SECTION 313, THE ATTACHED ENVIRONMENTAL DATA
SHEET (EDS) SHOULD ALWAYS BE COPIED AND SENT WITH THE MSDS.

_______________________________________________________________________________
SECTION XV STATE REGULATORY INFORMATION
_______________________________________________________________________________

THE FOLLOWING CHEMICALS ARE SPECIFICALLY LISTED BY INDIVIDUAL STATES; OTHER PROD
UCT SPECIFIC HEALTH AND SAFETY DATA IN OTHER SECTIONS OF THE MSDS MAY ALSO BE AP
PLICABLE FOR STATE REQUIREMENTS. FOR DETAILS ON YOUR REGULATORY REQUIREMENTS YO
U SHOULD CONTACT THE APPROPRIATE AGENCY IN YOUR STATE.

STATE LISTED COMPONENT CAS NO PERCENT STATE CODE

_______________________________________________________________________________

SODIUM NITRATE 7632-00-0 1 CA, CT, IL, LA,

MA NJ, PA

CA = CALIFORNIA HAZ. SUBST. LIST; CA65C, CA65R, CA65C/R = CALIFORNIA SAFE

DRINKING WATER AND TOXICS ENFORCEMENT ACT OF 1986 OR PROPOSITION 65 LIST; CT =
CONNECTICUT TOX. SUBST. LIST; FL = FLORIDA SUBST. LIST; IL = ILLINOIS TOX.
SUBST. LIST; LA = LOUISIANA HAZ. SUBST. LIST; MA = MASSACHUSETTS SUBST. LIST;
ME = MAINE HAZ SUBST. LIST; MN = MINNESOTA HAZ. SUBST. LIST; NJ = NEW JERSEY
HAZ. SUBST. LIST; PA = PENNSYLVANIA HAZ. SUBST. LIST; RI = RHODE ISLAND HAZ.
SUBST. LIST.

_______________________________________________________________________________
SECTION XVI SPECIAL NOTES
_______________________________________________________________________________

NEW PRODUCT. ORIGINAL MSDS ISSUED.

_______________________________________________________________________________

THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE TO US AND IS

BELIEVED TO BE CORRECT. HOWEVER, SHELL MAKES NO WARRANTY, EXPRESSED OR IMPLIED
REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE
THEREOF. SHELL ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE
PRODUCT DESCRIBED HEREIN.

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BE SAFE. READ OUR PRODUCT SHELL OIL COMPANY

SAFETY INFORMATION...AND PRODUCT SAFETY AND COMPLIANCE
PASS IT ON. (PRODUCT P. O. BOX 4320
LIABILITY LAW REQUIRES IT) HOUSTON, TX 77210

_______________________________________________________________________________

* * * * * * * E N V I R O N M E N T A L D A T A S H E E T * * * * * * *
PRODUCT NAME: ALVANIA(R) R3 GREASE SH EDS: 57115 - 00 11/07/96
PRODUCT CODE: 71034

MANUFACTURER'S NAME AND ADDRESS

SHELL OIL COMPANY
P.O. BOX 4320
HOUSTON, TX 77210

TELEPHONE NUMBERS:
24 HOUR EMERGENCY ASSISTANCE
SHELL: 713-473-9461 CHEMTREC: 800-424-9300

FOR ADDITIONAL INFORMATION ON THIS ENVIRONMENTAL DATA PLEASE

CALL 713-241-2252

_______________________________________________________________________________
SECTION I PRODUCT COMPOSITION
_______________________________________________________________________________
NO. COMPOSITION CAS PERCENT
===============================================================================

P ALVANIA R3 GREASE MIXTURE 100

1 HIGHLY REFINED MINERAL OIL MIXTURE 1-5
2 SODIUM NITRATE 7632-00-0 1
3 N-1-NAPHTHYLAMINE 90-30-2 4.0

_______________________________________________________________________________
SECTION II SARA TITLE III INFORMATION
_______________________________________________________________________________
NO. EHS RQ EHS TPQ SEC-313 313 CATEGORY 311/312 CATEGORY
(*1) (*2) (*3) (*4) (*5)
===============================================================================

P H-1

2 YES

_______________________________________________________________________________
*1 = REPORTABLE QUANTITY OF EXTREMELY HAZARDOUS SUBSTANCE, SEC 302
*2 = THRESHOLD PLANNING QUANTITY, EXTREMELY HAZARDOUS SUBSTANCE, SEC 302
*3 = TOXIC CHEMICAL, SEC 313
*4 = CATEGORY AS REQUIRED BY SEC 313 (40 CFR 372.65 C), MUST BE USED ON TOXIC
RELEASE INVENTORY FORM
*5 = CATEGORY (FOR AGGREGATE REPORTING REQUIREMENTS UNDER SARA 311, 312)
HEALTH: H-1 = IMMEDIATE (ACUTE) HEALTH HAZARD
H-2 = DELAYED (CHRONIC) HEALTH HAZARD
PHYSICAL: P-3 = FIRE HAZARD
P-4 = SUDDEN RELEASE OF PRESSURE HAZARD
P-5 = REACTIVE HAZARD

_______________________________________________________________________________
SECTION III ENVIRONMENTAL RELEASE INFORMATION
_______________________________________________________________________________

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THIS PRODUCT IS COVERED BY EPA'S COMPREHENSIVE ENVIRONMENTAL RESPONSE,

COMPENSATION AND LIABILITY ACT (CERCLA) PETROLEUM EXCLUSION. THEREFORE,
RELEASES TO AIR, LAND, OR WATER ARE NOT REPORTABLE UNDER CERCLA
("SUPERFUND"). HOWEVER, UNDER SECTION 311 OF EPA'S CLEAN WATER ACT (CWA),
THIS PRODUCT IS CONSIDERED AN OIL. AS SUCH, SPILLS INTO OR LEADING TO
SURFACE WATERS THAT CAUSE A SHEEN MUST BE REPORTED TO THE NATIONAL RESPONSE
CENTER, 800-424-8802.

_______________________________________________________________________________
SECTION IV RCRA INFORMATION
_______________________________________________________________________________
IF THIS PRODUCT BECOMES A WASTE, IT WOULD NOT BE A HAZARDOUS WASTE BY RCRA
CRITERIA (40 CFR 261). PLACE IN AN APPROPRIATE DISPOSAL FACILITY IN
COMPLIANCE WITH LOCAL REGULATIONS.

_______________________________________________________________________________

THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE TO US AND IS

BELIEVED TO BE CORRECT. HOWEVER, SHELL MAKES NO WARRANTY, EXPRESSED OR IMPLIED
REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE
THEREOF. SHELL ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE
PRODUCT DESCRIBED HEREIN.

_______________________________________________________________________________
SHELL OIL COMPANY
P.O. BOX 4320
HOUSTON, TX 77210

FOR ADDITIONAL INFORMATION ON THIS ENVIRONMENTAL DATA PLEASE CALL

(713) 241-2252

FOR EMERGENCY ASSISTANCE PLEASE CALL

SHELL: (713) 473-9461
CHEMTREC: (800) 424-9300

********************************************************************************
THIS MSDS HAS BEEN PROVIDED IN AN ELECTRONIC FORMAT FOR USE IN THE CHEMTREC
EMERGENCY RESPONSE PROGRAM AND/OR OTHER APPROVED PROGRAMS. THIS FORMAT MAY
CONTAIN BLANKS WHERE INFORMATION WAS NOT AVAILABLE OR NOT APPLICABLE AND
THEREFORE MAY NOT BE FULLY COMPLIANT WITH THE OSHA HAZARD COMMUNICATION
STANDARD. IF YOU PURCHASE OR USE THIS SHELL PRODUCT AND HAVE NOT RECEIVED
A MSDS FROM SHELL PLEASE CONTACT US AND WE WILL PROVIDE ONE. THIS WILL ENSURE
THAT YOU RECEIVE UPDATES OF THIS INFORMATION.
********************************************************************************

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