XDLIE005EN K FirstInfo

Measure
what is measurable
and make measurable
that which is not.
Galileo Galilei (1564-1642)
First Info
LDC and LPS
This document is for your internal, informative use only.

Do not pass to customers or third parties!
Version: February 2018

Document is subject to change
Latest version is saved online.
First Info
LDC and LPS
This document is for your internal, informative use only.

Do not pass to customers or third parties!
Version: February 2018

Document is subject to change
Latest version is saved online.
Important note to the distributor:
Confidentiality
This document and any and all annexes to it (together “this document”) are confidential and are
intended only for use by (1) employees of Anton Paar GmbH and its group companies (together
“Anton Paar”) and (2) Anton Paar distributors. This document is for your internal, informative use
only. Do not give or show this document to anyone who is not an employee of Anton Paar.
Disclaimer
This document may contain errors and omissions. If you discover any such errors or if you would
like to see more information in this document, please contact us at our address below. Anton Paar
assumes no liability for any errors or omissions in this document. This document does not alter
your contractual relationship with Anton Paar and you must not act or omit to act in reliance upon
the information contained in this document. Anton Paar assumes no liability for any losses or
damages in this regard.
Changes, copyright, trademarks etc.

This document and its contents may be changed or amended by Anton Paar at any time without
prior notice. All rights reserved (including translation). This document, or any part of it, may not be
reproduced, changed, copied, or distributed by means of electronic systems in any form (print,
photocopy, microfilm or any other process) without prior written permission by Anton Paar GmbH.
Trademarks, registered trademarks, trade names, etc. may be used in this document without
being marked as such. They are the property of their respective owner.
Further information
Published and printed by Anton Paar GmbH, Austria
Copyright © 2018 Anton Paar GmbH, Graz, Austria
Address of the instrument producer:

Anton Paar GmbH
Anton-Paar-Str. 20
A-8054 Graz / Austria – Europe
Tel: +43 (0) 316 257-0
Fax: +43 316 (0) 257-257
E-Mail: info@anton-paar.com
Web: www.anton-paar.com
Date: February 8, 2018
Document number: XDLIE005EN-K
ATTENTION
This document is strictly CONFIDENTIAL and is intended for INTERNAL USE only!
1. Conventions for the Symbols in the Document
The following conventions for the symbols are used in this document:
Required reading
This sign calls attention to a link to a document, video, etc. that you must read or
watch in order to complete the First Info. Please study the information provided. In
text, the required reading is marked with a grey line on the left and right side. In tables
the red font color is additionally used to mark the required reading rows. The content
of these sections is required to pass the test.
Did you know?

Here you will find some interesting stories behind the topics for your own interest.
Optional reading
This sign calls attention to a link to a document, video, etc. which might be of interest
to you. It is not obligatory to study the information provided.
NOTICE – Notice indicates a situation which, if not avoided, could result in damage to property.
TIP – Tip gives extra information about the situation at hand.
6/186 1. Conventions for the Symbols in the Document XDLIE005EN-K

2. About the First Info
When you are just getting started on a topic, you might sometimes be faced with an information
overload. This First Info you are holding in your hands is for you – available from your very first
work day. It is designed to ideally prepare you for subsequent training sessions. It is also meant
as a small reference that contains all the info you need before training – nothing more, nothing
less. A perfect starting point!
On Your Way to Becoming a Sales/Service Expert for Anton Paar Products:
First Info for Sales Qualification Training for Sales People Sales Experts Meeting
& Service People Qualification Training for Service People Service Experts Meeting
Learn the basic Become qualified in selling / servicing Anton Be invited by Anton Paar to
concepts of a Paar products by gaining deeper insight into the Experts Meetings to
product line. application knowledge, market/customer/ exchange knowledge,
competitor information, sales/service experience and new ideas in
strategies, technical/product knowledge. Above terms of product, application,
all, the trainings emphasize laboratory practice. market and sales/service
The autonomous learning process is supported developments on a high level.
by webinars, Anton Paar Knowledge Update A good opportunity to talk
and information on the Anton Paar Extranet. shop without distraction.
What the First Info Can Do for You

The First Info introduces you to a product line and serves as your basic reference book to look things
up. It is self-explanatory, full of interesting background stories and contains topics such as:
• measuring/operating principles and methods
• the instruments, their USPs and the most important applications
• the markets/customers/competitors/references
• contact persons & responsibilities at Anton Paar
The First Info addresses both Sales and Service persons at Anton Paar subsidiaries and
representations. It ensures that everyone enters the Qualification Trainings at the same level.
It’s the First Info – Not the Last Word

The First Info is the essential basis, but it cannot replace an actual Qualification Training with its
wealth of additional detailed information for successful customer contacts. The First Info does not
enable Service engineers to perform a service on Anton Paar instruments, and does not enable
Sales people to win projects against experienced competition.
• Before attending training you have to pass an online test on the contents of the First Info. To
help you prepare for this, the First Info contains study questions which you can use to check
your knowledge.
• Studying the First Info ensures that you get the most out of your training - the trainers at the
Qualification Trainings cannot consider participants who haven’t studied the First Info
Any feedback on the First Info is very welcome – help us to further improve it.
And now, enjoy getting on with your First Info package!
XDLIE005EN-K 2. About the First Info 7/186

3. Product Line – Instrumentation Overview
The product line Lab Density & Concentration (LDC) is the largest Anton Paar product
department in terms of turnover and also personnel. The following chapter gives an overview of
the different products of the product line LDC.
It all began with density measurement in 1967. From then on, apart from standard density and
concentration meters (employing sound velocity measurement), Anton Paar has developed new
instruments for alcohol and CO2 content measurement: CarboQC, measuring the CO2 content with
the volume expansion method, and the Alcolyzer with its patented near infrared (NIR) absorption
method (in cooperation with Joanneum Research). In 2008 the new DMA™ Generation M density
meters were introduced, setting new standards for user-friendliness and measuring accuracy.
These days the product line LDC includes lab instruments for
• Density measurement
• Sound velocity measurement
• Alcohol content measurement
• CO2 and O2 measurement
• Turbidity measurement
• Temperature measurement
Areas of usage include analysis and quality control, industrial applications, testing centers and
research and development.
Our product range covers portable density meters, highly precise laboratory benchtop equipment and
modular measuring systems. Our customers include nearly all major beverage producers, refineries,
Formula I racing teams and many more.
The following table shows an overview of all LDC instruments (products discontinued before 2013
are not considered):
Type of instrument Instruments
Density meters
Based on the oscillating U-tube technology Anton Paar
• DMA™ 35
density meters are used for quality and production
• DMA™ 500
control in an incredibly wide field of applications.
• DMA™ 4100/4500/5000 M
Density measurement is commonly also used for
• DMA™ 4200 M
concentration determination of binary solutions (e.g. a
mixture of water and ethanol).
Density and sound velocity meters
Simultaneous density and sound velocity measurement
leads to a higher accuracy in the concentration • DSA 5000 M
determination of binary mixtures and even enables • Soft Drink Analyzer M
concentration measurement of ternary solutions (e.g. a
mixture of water, sugar and alcohol).
8/186 3. Product Line – Instrumentation Overview XDLIE005EN-K

Type of instrument Instruments
Alcohol meters
• Snap 41
Alcohol is measured as a basis for tax calculation, to
• Snap 51
ensure the correct labeling of the bottle and of course
• Alex 500
for the reason of its influence on the taste on a
• Alcolyzer Wine M/ME
beverage. Whereas the Snap instrument family
• Alcolyzer Sake M/ME
determines the alcohol content in distilled spirits, Alex
• Alcolyzer Spirits M/ME
500 measures the alcohol and extract in craft beer and
• Alcolyzer Beer M/ME
wine, and the Alcolyzers are used to determine the
• Alcolyzer ME
alcohol content in beer, wine and spirits.
CO2 and O2 meters
The taste of a non-alcoholic or alcoholic beverage is • CarboQC / CarboQC At-line
strongly influenced by the content of CO2. The O2 • CboxQC™ / CboxQC™ At-line
content can lead to corrosion in the can (e.g. in soft • CarboQC ME / CarboQC ME with
drinks) or might even reduce the product life Option O2 (Plus)
dramatically (e.g. for beer). Anton Paar CO2 and O2 • OxyQC
meters determine the true content of dissolved CO2 or • OxyQC Wide Range
O2 in fluids.
Turbidity meters
Another important parameter for analyzing fluids is
turbidity. HazeQC ME measures the scattered light at • HazeQC ME
three angles (0°, 25°, 90°) and calculates the turbidity
value in EBC or NTU according to established norms.
Thermometers
Temperature is one of the most frequently measured • MKT 10
physical values. Anton Paar has engaged in this matter • MKT 50
for 25 years, since density measurement strongly
depends on highly accurate temperature measurement.
Filling systems • Xsample™ 320/520
With the sample filling and rinsing units for density and • Xsample™ 330
concentration meters, samples are automatically filled • Xsample™ 340
into the instrument. Sample filling units are available • Xsample™ 630
with or without a magazine and for pressurized filling. • Xsample™ 530
• PFD (Plus)/SFD
Measuring systems • Modulyzer
LDC measuring systems combine two or more of the • PBA-S/SI/SD/SID Generation M
above listed instruments and provide measurement of • PBA-B Generation M
several parameters simultaneously within one • PBA-W Generation M
measuring cycle. • Alcolyzer Analyzing System
Study the information provided for the single instruments precisely. The better you know the
instruments, the better you can advise your customer on what instrument suits his needs in the best
way.
XDLIE005EN-K 3. Product Line – Instrumentation Overview 9/186

4. Density Meters
Countless analytical methods prevail in today’s quality and production control: One of the easiest,
fastest and most significant is density measurement. It requires very little sample, does not
change the sample’s composition and consumes no chemicals. Density measurement
determines concentrations of binary mixtures with the utmost precision and allows you to always
offer first-rate product quality.
The following chapter introduces you to the world of Anton Paar density meters, from the small
portable density meter up to the most accurate density meter in the world.
From X-Rays to Density

Prof. Otto Kratky was an Austrian physicist best known for his
contribution to the small-angle X-ray scattering method. For his
research work, he needed to calculate the partial specific volume of
organic objects by measuring their density in the fifth digit, having only
very small sample amounts available. Hence, he needed an extremely
accurate density measuring instrument.
In 1965 Professor Kratky assigned two students to a research project

at the University of Graz, aiming at developing such a measuring
instrument that could deliver highly precise and accurate results. Only
two years later, in 1967, the first DMA™ 02 (Density Measuring
Apparatus) was presented at the Achema Exhibition in Frankfurt.
What does this have to do with Anton Paar?

Kratky's small-angle X-ray cameras were manufactured by Anton Paar and so it was only
understandable that also the DMAs were manufactured here. This way, Anton Paar became the
cradle of the oscillating U-Tube method and has further developed and improved the method ever
since.
Anton Paar is the world leader in density measurement with a share of around 70% of the global
market and over 100,000 sold instruments. Density measurement in the lab is used for all kinds of
fluids in the beverage industry, in the chemical and petroleum industry, in medicine, the
pharmaceutical industry, cosmetics and the food industry as well as at research institutes and
governmental agencies.
Did you know?

Ferrari pilot Michael Schumacher was once disqualified after using an “illegal” fuel in a
race. This was determined with an Anton Paar density meter. After that, Ferrari
immediately bought a density meter from Anton Paar.
Have a look at this interesting blog-article:

http://blog.anton-paar.com/the-very-basics-of-density-measurement/
10/186 4. Density Meters XDLIE005EN-K

4.1 Why Measure the Density?
The density of a sample is a proven method for quality control in numerous industries. For two-
component solutions (also called binary solutions) the density of the sample gives information about
the composition of the mixture, provided that the densities of the two components are known.
During quality control (in production quality control, intake- and pre-delivery control), the measured
density or concentration is compared to an expected reference value. When it comes to bottling
products the density of a product helps to determine the filling volume – often the basis for book
keeping.
4.2 Measuring Principle
All important facts you should know about density measurement are available online at the Anton
Paar Wiki website: https://wiki.anton-paar.com
The Anton Paar Wiki will inform you about:
• what is density and how it is measured,
• common density units,
• the history of density measurement,
• the physical basics and measurement methods in general,
• applications of density measurement, especially concentration determination
Required reading
Read the online articles on density basics, common applications of density
measurement and concentration determination by means of density measurement at
the Anton Paar Wiki: https://wiki.anton-paar.com/glossary/
4.3 U-tube measuring Cells
The basic principle of digital density meters is always the same: a u-shaped tube is filled with sample
and oscillates at its characteristic frequency. But there are some variations providing significant
advantages over each other.
The most obvious difference, which is the direction of the physical movement, is used to name the
different oscillators.
Fig. 4-1: x, y - and w - oscillator
XDLIE005EN-K 4. Density Meters 11/186

The dimensions of a so called x oscillator are compact which makes it easy to control the temperature
and allows the application in mobile instruments (DMA™ 500) because due to two parts oscillating
in opposite directions a countermass is not required. However, the impact of the sample´s viscosity
becomes most noticeable compared to the other U-tubes.
The y oscillator is used in high-end density meters (DMA™ Generation M) but requires a
countermass to eliminate the harmful effects of vibrations originating in the instrument´s
environment. Also the viscosity influence requires compensation as well as drifts due to temperature
stress (ThermoBalance™). Managing these complementary technologies and adding highly precise
temperature regulation creates the most accurate density meter on the market (DMA™ 5000 M).
Also in the w oscillator two parts of the sensor are moving in opposite directions eliminating the need
for a countermass which allows the application in handheld devices (DMA™ 35). Usually the
temperature is not regulated but only measured and compensated with these devices.
4.4 Important facts on measurement practice
Since 1967 Anton Paar GmbH has specialized in providing highly accurate and reliable density
meters for research and industry. The following guideline sums up our experience and insights into
measurement practice on water check, adjustment, sample preparation, sample filling, and cleaning.
Follow these guidelines and you will be well on your way to accurate and reproducible density results.
4.4.1 Water Check
If you carry out density checks at regular intervals you can ensure the high and stable accuracy of
your density and concentration measurements.
Workflow
• Fill ultra-pure (e.g. bi-distilled or deionized), freshly degassed water into the measuring cell.
• Start the measurement (“check”).
• Compare the determined density with the reference value:
ρWater = 0.998203 g/cm³ for T = 20 °C
The water check fails if the measured density value is not within a required tolerance range. The
tolerance range depends on the application and is usually more stringent in the pharmaceutical
industry than in the soft drink industry, for instance.
Example: A common tolerance limit for soft drinks is ± 1 x 10-4 g/cm³. This means the water check
is positive if the determined density is between 0.9981 g/cm³ and 0.9983 g/cm³.
If the water check fails, try the following

• Use fresh ultra-pure water.

• Repeat the water check.
If the water check still fails

• Clean the measuring cell thoroughly.
• Repeat the water check using fresh ultra-pure water.
If the water check still fails

• Perform an air/water adjustment.
DMA™ Generation M
The factory set tolerance for the check result for both air and water checks are depending on the
instrument type and can be looked up in the according instrument manual.
Using a DMA™ Generation M instrument you can set a reminder for your daily water check. Of
course the preset tolerances can be changed to your requirements. DMA™ Generation M performs
the water and air checks automatically at the measuring temperature of the active method. The
density of water and air at this specific measuring temperature is calculated and then compared with
the actually measured density value.
4.4.2 Adjustment
An adjustment changes the instrument constants. For the consistency and comparability of results
an adjustment should only be performed if the water check fails and if using fresh water and cleaning
the measuring cell does not help. Poor cleaning is the cause of the majority of measuring errors and
adjustment should be seen as a last resort.
Workflow
• Common adjustment media are dry air and ultra-pure (e.g. bi-distilled), freshly degassed water.
• Follow the automatic adjustment procedure on your instrument.
In the past it was recommended to perform an adjustment once a week, but this is no longer the case.
Adjust your instrument only if it is out of range.
Reasons why the side effects of cleaning need to be compensated by an adjustment:
Cause Effect Influence on density
Aggressive cleaning Volume of the measuring cell is Artificial density decrease

increased
Ineffective cleaning Volume of the measuring cell is Artificial density increase
decreased

DMA™ Generation M
Due to the ThermoBalance™ technology, one adjustment at 20 °C is sufficient to provide precise
measurements over the whole temperature range. A further benefit of ThermoBalance™ is that there
is no drift if you fill samples at different temperatures and measure immediately.
4.4.3 Sample Preparation
Choose your sample preparation according to the characteristics of your sample:
4.4.3.1 Your sample contains gases

There are different methods for the degassing of liquid samples. The best method for your application
depends on the kind of sample, the kind of gas, and the amount of gas that is dissolved in the sample.
Be aware of the fact that you may slightly change the composition of many samples during sample
preparation due to evaporation of volatile components.
Stirring:
• Stir your sample vigorously for 2 to 15 minutes (depending on the stirring equipment) until no
more bubbling occurs.
• You can also pour the sample through a paper filter after stirring to get an even more efficient
degassing effect.
Ultrasonic bath:
• Put your sample into an ultrasonic bath for approximately 5 to 10 minutes until the bubble
formation stops.
Boiling:
• Boil the liquid for several minutes to remove dissolved air.
• Fill a clean glass flask full with the boiled liquid and cover it.
• Wait until the liquid has cooled down to the approximate measuring temperature.
Warning: Do not boil flammable liquids because of a high risk of fire.
If your sample contains volatile compounds that are toxic, always handle the sample in an
appropriate environment, like a fume hood.
4.4.3.2 Your sample is aggressive

• Observe all safety regulations regarding the handling of the samples, cleaning, rinsing and
waste liquids (e.g. use of safety glasses, gloves, respiratory protection, etc.).
• Check the chemical resistance of all materials which come into contact with the sample before
starting the measurement.

4.4.3.3 Your sample is viscous
• Heat up your sample to get lower viscosities.
• For highly viscous samples use a heating attachment to prevent sample freezing in the
sample in- and outlet.
• If you use a sample filling system, check whether the viscosity corresponds to the given
specifications.
4.4.3.4 Your sample is volatile

• Close the sample vials with caps.
• Gently swirl the vials to bring condensed droplets back into the bulk liquid.
• For highly volatile samples use a sample filling unit which supports sample filling under
pressure.
DMA™ Generation M and CarboQC:

If you use a DMA™ M density meter in combination with a CarboQC carbonation meter and a PFD
filling device, then you do not need to degas your samples. The measured carbon dioxide content is
used to automatically correct the density value.
Before activating the PFD filling device, equilibrate the bottle or can by shaking it horizontally for
about 30 seconds.
4.4.4 Sample Filling
Warning: Before filling any sample into the density meter, make sure that all wetted parts are
resistant to it.
4.4.4.1 Automatic filling with sample filling units

Samples are ideally filled into the measuring cell with automatic sample changers. Sample filling units
operate in the same way every time. This kind of filling leads to repeatable results and is independent
of the operator.
Even critical samples, like highly viscous samples or samples with volatile components, are filled
smoothly. Some sample filling units additionally support automatic cleaning.
Workflow
• Fill your samples in the corresponding sample vials and prepare the magazine.
• If your sample unit supports automatic cleaning, make sure that sufficient amounts of cleaning
liquid are available and that the cleaning liquid suits your samples.
• Empty the waste container before starting a series of measurements.
• Check the instrument settings.
• Prepare the sample list for your instrument.
• Start the measurement.

Please refer to section 10. for a list of Sample Filling Units available.
4.4.4.2 Manual filling with syringe

Using a syringe is the traditional way of filling a sample into a density meter. It requires some training
to achieve repeatable results and to avoid bubbles in the measuring cell.
Workflow
• Press the plunger smoothly and slowly without stopping.
• Check whether the measuring cell is filled without bubbles.
• Check the instrument settings.
• Start the measurement.
For paste-like materials, always use a syringe. If the samples have a very high viscosity, you can fill
them into the syringe by pulling the plunger completely out of the syringe, filling it from the back using
a spoon and then inserting the plunger again.
DMA™ Generation M:
DMA™ Generation M provides useful features for improving the quality of sample filling:
• FillingCheck™ uses an actual measurement to monitor the filling quality. It detects filling
errors in the whole measuring cell using unique Anton Paar measuring technology.
• U-View™ displays a live stream of images of the oscillating U-tube sensor with the filled-in
sample. Potential sample filling problems can be reliably identified in real-time or at a later
review of the pictures automatically stored in the data memory. This is especially important for
verification of results when using automatic sampling systems.
Cleaning
Warning: Before filling any cleaning liquid into the density meter, make sure that all wetted parts are
resistant (check in the instruction manual).
How often?
Clean and dry the measuring cell at least after each working day or work shift.
Cleaning more frequently may be necessary when
• you perform adjustments,
• you measure a sample that is not miscible with the previous sample (e.g. water after a
petrochemical sample),
• you want to use a minimum sample amount for your measurement,
• you measure a sample that could chemically react with the previous sample.
The best way to clean your instrument is by using sample filling units which support automatic
cleaning. In this case make sure that the applied cleaning liquids suit your samples.

Workflow
• Clean the measuring cell using two cleaning liquids:
- Cleaning liquid 1 dissolves and removes sample residues in the measuring cell. It needs to
be a good solvent for all sample components.
- Cleaning liquid 2 removes cleaning liquid 1 and is easily evaporated by a stream of dry air
in order to accelerate drying of the cell. Cleaning liquid 2 needs to be a good solvent for
cleaning liquid 1.
• Dry the measuring cell by activating the internal air pump.
• Check whether the cleaning and drying was successful by measuring the density of air (=air
check).
• Compare the determined density with the reference value:
ρAir = 0.001199 g/cm³ | for T = 20 °C, p = 1013 mbar
List of typical samples and suggested cleaning liquids
Sample Suggested cleaning liquid 1 Suggested cleaning liquid 2
After-shave, perfume Alcohol -

Beer Water, enzymatic lab cleanera Alcohol
Beer wort Water, enzymatic lab cleanera Alcohol
Fuel Petroleum naphtha Acetone, Alcohol
Liquid soap & detergent Water Alcohol
Lubricating oil Petroleum naphtha Acetone, Alcohol
Milk, cream Water, enzymatic lab cleanera Alcohol
Motor oil Petroleum naphtha Acetone, Alcohol
Orange juice Water Alcohol
Schnapps Alcohol -
Soft drinks Water Alcohol
Salad dressing, Petroleum naphtha Alcohol
mayonnaise
Shampoo Water Alcohol
Suntan lotion Petroleum naphtha Alcohol
Wood protection / white Petroleum naphtha (water) Alcohol
spirit based (water-based)
a Using enzymatic lab cleaner is recommended for special cleaning. After using the lab cleaner you need to rinse the
measuring cell with water.

4.5 Portable Density Meter: DMA™ 35
The DMA™ 35 is a battery-operated portable density meter. Due to its

compact and robust design and light weight users can easily take it along
to the sampling location to perform quick quality checks on-site (e.g.
directly at a tank or production line), instead of taking the sample to the
lab to measure it there.
Density readings are performed with an accuracy of 0.001 g/cm3 within a
temperature range of 0 to 40 °C.
DMA™ 35 is mainly used in the food & beverage industry, as well as in
the chemical and petrochemical industries. More details on applications
will follow in chapter 4.3.6.
4.5.1 How to Use DMA™ 35

There are two different ways how to fill a sample into the measuring cell (see fig. 4-1):
• Filling using the built-in pump
• Filling using a syringe (mainly for highly viscous samples. Furthermore, less sample is
required.)
Fig. 4-1: For filling sample with a syringe, the instrument is put into its stable tabletop position.
Via the inspection window you can check whether the sample is filled without containing any gas
bubbles.

Did you know?
The influence of gas bubbles on the measured result is different, depending on where
exactly the bubble is located within the U-tube.
For this reason, winemakers who do not want to spend time on degassing their
fermenting wine sample before measuring it with DMA™ 35 put the instrument in its
tabletop position, so that all bubbles move into the direction of the sample outlet. This
slightly minimizes the influence of CO2 on the measured result.
However, to get the best accuracy and repeatability of results, it is recommended to
degas the sample.
The most common concentration units and product-specific parameters are preinstalled on the
instrument, so instead of density DMA™ 35 can also display values like e.g. °Brix, % alcohol, %
sulfuric acid, API values, etc.
The measured result is shown continuously on the display, but you can also store results and print
or export them to a PC later.
4.5.2 How Does DMA™ 35 Work?

The instrument measures the density of the filled-in sample based on the oscillating U-tube principle.
As the density of one and the same sample changes as soon as the temperature changes,
information about density is worth nothing without information about the related temperature.
Therefore, DMA™ 35 simultaneously measures the sample’s temperature.
The ambient temperature and the instrument’s housing temperature have an influence on the
measured sample temperature as the measuring cell of DMA™ 35 is not temperature controlled.
If the sample temperature differs from ambient temperature, it starts to adapt to the ambient
temperature as soon as the sample has been filled into the measuring cell.
As the density is highly temperature-dependent you’ll see also the density value shown on the screen
changes as long as the temperature has not stabilized. This can take a while if the sample
temperature strongly differs from measuring temperature.
Example: If the sample temperature is the same as the ambient temperature, the
measurement is finished within 10 seconds. However, if the sample temperature
differs from ambient temperature by 20 °C, the measurement can take about
5 minutes.
TIP – To speed up the measurement, store the instrument at a place with similar ambient conditions
to your measuring environment.
If your customer complains about the long measuring time due to temperature
differences he/she can choose a different measurement mode providing quicker, but
less accurate results.
For details see the DMA™ 35 instruction manual, chapter 9.1.
To obtain comparable results, independent of the measured temperature, the result can be
calculated at a reference temperature of your choice, e.g. 20 °C.

The Standard Operating Procedure (SOP) for DMA™ 35 is a graphical instruction for
installation and daily use of the instrument which aims to enable customers to self-
handedly put the instrument into operation and start measuring without the need to
study the instruction manual in detail. The booklet is shipped with each DMA™ 35 free
of charge, in addition to the instruction manual.
For a pdf-version of the document, have a look on the Extranet!
4.5.3 What Are the Customer Benefits?
Feature How/why does the customers benefit?

Intuitive user The user does not want to study bulky instruction manuals before
interface being able to use an instrument designed for quick checks. Therefore,
operation is easy, for both left- and right-handed users. A calibration
with deionized water can simply be performed by following the
predefined calibration routine.
Robust and leakproof Due to its portability DMA™ 35 is often used in very harsh
design environments. Very high or low temperatures, high humidity,
inadequate cleaning and rough handling are the daily business of
DMA™ 35. With its robust hard-glass front, protection class IP54, and
additional rubber protection for the measuring cell to withstand knocks
during routine operations, it is an instrument to rely on in any of those
situations. If the instrument nevertheless suffers from a cell rupture by
mischance, the cell can simply be replaced by a trained service
technician.
Storage of up to 1024 The user does not need to write down the results from the screen. The
results user can take the instrument with him/her and store measurements all
day long. The data can then be printed or transferred to a PC via the
Bluetooth interface.
Storage of measuring A method includes certain measurement settings (measuring unit,
methods temperature coefficient, offset and limits, if needed). Via changing the
measuring method, users can switch between the different measuring
units required for analysis of their specific sample.
Quick sample RFID (Radio Frequency Identification) helps to clearly identify a
identification via RFID sample within seconds and helps to speed up the measuring process,
especially when a customer has many sampling points (e.g. tanks,
barrels, ...).
An RFID tag (a small storage device), programmed with a sample ID
and/or method is attached to the sample container. Before the user
performs a measurement DMA™ 35 reads the respective tag and the
sample ID and method are changed automatically. The sample name
is stored together with the result, ensuring full traceability of data.
Wireless printouts The user can take the printer along, if needed. Printouts and data
and exports to a PC exports can be done without the need of a cable. The user does not
via Bluetooth need to write down the results from the screen. Exported results can
be archived or processed further (e.g. statistics, diagrams) on the PC.

Feature How/why does the customers benefit?
Stable tabletop When measuring viscous samples, the instrument turns into a mini-
position for syringe benchtop instrument by putting it into the stable tabletop position. The
filling pump is locked to reduce the dead-space within the system and
prevent any carryovers of sample or cleaning liquid. This guarantees
best possible accuracy and repeatability of results. The screen rotates
automatically so the user can conveniently read the result.
Ex certification DMA™ 35 Ex and Ex Petrol have been
certified according to the EX regulation of
the European Parliament. This means the
instruments are suitable for use within
hazardous areas. They went through special
tests to ensure they cannot cause any fire or
explosion when explosive gases or vapors
are present within the measuring
environment. This is extremely important for
customers handling petroleum samples or
highly flammable chemicals.
It’s the customers liability to use Ex certified
devices in hazardous Ex areas.
As long as there are no Ex-certified

versions available for DMA 35 Version 4,
please refer to DMA 35 Version 3 Ex and
Ex Petrol! Information about availablility
of the new instruments will be sent out
via Knowledge Update.

4.5.4 What Is So Special About DMA™ 35?
DMA™ 35 Version 4:
• The robust design (protection class IP54, hard-glass front, special rubber protection housing,
replaceable cell)
• The automatic sample identification via RFID
• The stable tabletop position for convenient filling of viscous/expensive samples via syringe
• The intuitive user interface for easy operation
DMA™ 35 Version 3 Ex and Ex Petrol:

• The Ex-certification for use in hazardous atmospheres
• The special petol resistant housing of DMA™ 35 Ex Petrol
Did you know?

The RFID technology is already very common for container tracking in logistics, goods
tracking in supermarkets or personnel cards in companies.
4.5.5 What Product Version to Choose?

To make sure you can advise your customer with the one product version which best fits the
application, the following short overview helps you to keep an eye on the differences.
DMA™ 35 Version 4 Standard:
• for general industrial and laboratory applications (e.g. food & beverages, pharmaceutical
industry, chemical samples, etc.)
• not suitable for / resistant to petroleum samples
DMA™ 35 Version 3 Ex (respectively DMA™ 35 Version 4 Ex, as soon as available):

• chemical industry, explosive/flammable samples or measuring environment
• not suitable for / resistant to petroleum samples
DMA™ 35 Version 3 Ex Petrol (respectively DMA™ 35 Version 4 Ex Petrol, as soon as

available):
• petroleum industry, explosive/flammable samples or measuring environment
• not resistant to acids
TIP – For detailed information regarding resistance of the product to the customer’s sample consult
a list of chemical resistances (available e.g. on the Internet)

4.5.6 DMA™ 35 - Market Information
4.5.6.1 Applications
The more flexible an instrument is, the more varied the customers are. DMA™ 35 is found in large
concerns as well as in one-man businesses and is used for an incredibly wide field of applications.
When talking to customers in different kind of industries, always be aware of their different needs and
financial situation.
The chart shows the fields of application in which DMA™ 35 is mainly used. Find below a short
explanation, as well as some references for each industry mentioned.
DMA™ 35 industries
Description References
Food & Beverages (31%) • Europe: Brauunion Österreich,
Radeberger Gruppe
Producers of alcoholic and non–alcoholic • Mexico:Bacardi y Compañía
beverages like breweries, wineries, distilleries, • USA:Anheuser-Busch, Bin-to-Bottle,
producers of soft drinks, juice, dairy products, Coca-Cola, Pepsi-Cola
etc.
Chemicals (23%) • Europe:Agfa, BASF, BAYER, Brenntag,
Carl Zeiss
Manufacturers of chemical products and
others, where chemicals play a role during the
manufacturing process.
Petrochemistry & Plastics (14%) • Europe: BP AG, Esso, Total, OMV
• USA:Western Refining Company
Petroleum refineries measuring crude oil, • USA and Europe: ExxonMobil, Shell
lubricants and fuels as well as
suppliers/wholesale traders/purchasers of
petroleum products: fuel stations, producing
companies, fuel terminals, military etc.

Description References
Public Administration and Education (12%) • Asia:Hangzhou Institute of Quality
Inspection and Testing Technology
Administrative offices, civil service, calibration • Europe:UK Ministry of Defence
authorities, public authorities and educational • USA: Harvard University, U.S. Army
institutions like schools and universities.
Did you know?

In pharmaceutical companies each instrument that is going to be used in research or
production needs to get internally qualified. This means it has to run through an
extensive qualification procedure, verifying if the instrument meets the required
specifications and functionality. For DMA™ 35, a comprehensive Pharma Qualification
and Validation Package (PQP-S) is available, enabling a customer to get the
qualification done in one day, instead of 6 weeks. A more detailed description of this
documentation can be found on the Extranet!
The three main industries are the food and beverage industry, chemical industry and petrochemical
industry. Therefore, one application for each of those three industries is explained in more detail.
Food & Beverage Industry: Example Wine
Winemakers check the sugar content within the grape juice (must) directly
at the wine tank or barrel within the wine cellar. The higher the sugar
content in the must, the higher the alcohol content of the resulting wine.
Performing daily density checks enables winemakers to make sure that
the fermentation does not stop unexpectedly or lets them step in if the
fermentation is too fast.
DMA™ 35 displays the result in the preferred unit (°Brix, °KMW, Oechsle,
Baumé, etc.). The optional longer filling tube simplifies sampling out of tanks, especially when the
tank is not fully filled.
Chemical Industry / Public Utilities: Example Battery Acid
The % w/w concentration of H2SO4 measured with the DMA™ 35
gives information about the charging status of the battery. (18.5%
w/w means the battery is 80% charged, 36% w/w means the
battery is fully charged.)
Especially for energy suppliers or organizations with emergency
power systems it is essential to check the acid concentration on a
regular basis.
Petroleum Industry: Example Petrol
The density of petroleum products is one of the major measuring units for determining the quality and
type of product. The DMA™ 35 is used in refineries for quality and mixing control (e.g. a mix of diesel
and biodiesel) and by wholesalers and fuel stations or the military for intake control.
The DMA™ 35 displays API SG, API Density and API Gravity for the product groups A (crude oil), B
(fuels) and D (lubricants) at different reference temperatures.
The optional longer filling tube simplifies sampling out of tanks, especially when the tank is not fully
filled.

4.5.6.2 Cross Selling
DMA™ 35 is a product you should always have with you when you go to a customer’s site to be ready
to show it to any customer, anytime. Especially when customers think about buying a whole Anton
Paar system, DMA™ 35 could be interesting for them – for doing quick checks additionally to their
complex lab analysis.
A partner DMA™ 35 is often seen with is Alcolyzer Wine M/ME. Wine customers use the Alcolyzer
Wine M/ME within the lab for a very accurate analysis and the DMA™ 35 directly at the barrel or tank
to perform a quick fermentation check.
4.5.6.3 Competition
There are only few comparable portable instruments on the market. They mainly differ from DMA™
35 in measuring principle, accuracy and user interface:
Name Picture Accuracy Temp.

Additional information
Range
0.001 These two instruments are the main

DA- 0 to 40 °C competitiors of DMA™ 35. Both instruments
g/cm3
130N are very similar and provide the same basic
functionality as DMA™ 35 (e.g. same
accuracy, same preinstalled concentration
units). They provide less features than
DMA™ 35 and the user interface is not as
0.001 simply structured.
5 to 35 °C
g/cm3 No Ex certification
Densito
30XP
The VDM version additionally provides

viscosity correction
0.001 or Bluetooth interface
(V)DM- 0.0005 or Requires large sample amount
0 to 50 °C
300 0.0002 With this instrument Lemis tries to also enter
g/cm3 new markets like pharmacy, chemistry or
cosmetics.
No Ex certification
viscosity correction
Concentrates on beverages and
0.0003 or
(V)DM- petrochemistry
0.0005 -40 to 85 °C
Bluetooth interface
250.3 g/cm3
Requires large sample amount
Higher accuracy and pricing
Ex certified

Our competitor Lemis also offers two types of dip-in density meters. They are designed to measure
the density directly within large reservoirs. The sensor is submerged into the sample and a spot
density measurement is performed. However they are not really competing to DMA™ 35 as they are
much more expensive.
Name Picture Accuracy Temp.

Additional information
Range

viscosity correction.
(V)DM- 0.0003 or
With these instruments Lemis focuses more
250.1 / 0.0005 -40 to 85 °C
on the petroleum and beverage industry.
250.2 g/cm3
Bluetooth interface
Ex certified
,
Actually, the most important competition of DMA 35 is the glass hydrometer. Learn
more about our benefits as compared to the glass hydrometer, as well as some more
details about our digital competition and market information by reading the Sales
Guide, available in the Extranet.
4.5.7 Check Your Knowledge

1. Name three USPs of DMA™ 35.
____________________________________________________________________________
____________________________________________________________________________
____________________________________________________________________________
2. Complete the text by filling the gaps
The DMA™ 35 is a _______________-operated ______________ density meter. The

measuring cell of DMA™ 35 is not _____________________. The _____________temperature
as well as the instruments housing temperature have an influence on the measured temperature.
As the_____________ is highly temperature-dependent, the instrument will wait for temperature
stabilization before the density value is stored. To obtain comparable results, independent of the
measured temperature, the result can be calculated at a _______________ temperature of your
choice, e.g. 20 °C. The measured result is shown continuously on the display, but you can also
_____________ results and print or export them to a PC later.

3. DMA™ 35 Version 4 Standard is equipped with an RFID interface by default. What are the
customer benefits of an RFID interface? Mark the correct answers.
a RFID is used for wireless data transfer to a PC or printer.
b RFID allows for quick sample identification.
c RFID enables connection of an external keyboard.
d RFID enables automatic bubble detection in the measuring cell.
4.6 Benchtop Density Meter DMA™ 500
The DMA™ 500 combines the accuracy and functionality of a

benchtop density meter with the usability and flexibility of a
portable instrument. The accuracy of determined density results
is 0.001 g/cm3. In addition to DMA™ 35, it provides temperature
control of the sample, resulting in a better repeatability of results.
The optionally integrated rechargeable battery serves as a UPS
(uninterruptible power supply) in case of large voltage fluctuations
or short power outages. An optional – and more powerful – battery
pack enables you to use the instrument off the line outside the lab
(but still indoors! – DMA™ 500 is designed for indoor operation
only.)
4.6.1 How to Use DMA™ 500

The sample can be filled into the measuring cell by either using a syringe or the optionally
integrated peristaltic pump. For samples with low viscosities (comparable to water) filling with the
peristaltic pump is recommended as this facilitates the precise and bubble-free filling of sample and
gives perfect repeatability of results (see fig. 4-2). Samples with higher viscosities should be carefully
filled with a syringe.
Fig. 4-2: DMA™ 500 with integrated peristaltic pump

Measured values are shown conti- You can create up to 20 customized
nuously on the display and can be measuring methods on your instru-
stored within the instrument’s me- ment, defining the unit which should be
mory (including the live image of used, as well as the measuring tempe-
the measuring cell) and transfer- rature. (You could e.g. create a method
red to a USB flash drive, printer named “soft drink” measuring °Brix at
or PC later on. 20 °C).
The most common The measuring

concentration units temperature can be
and calculations (like set to a value bet-
e.g. specific gravity, ween 15 °C and 40
sugar tables, acid/ °C. The sample is
base tables, API cooled or heated to
functions, alcohol the set temperature.
tables …) are
preinstalled on the
instrument. Up to two
measuring units can
be shown on the main Via the live image of the measuring cell (U-
screen. View™), the user can once more make sure
there are no gas bubbles within the cell which
The instrument warns you may influence the measured result. The
automatically in case of any filling viscosity influence on the measured density is
errors (FillingCheck™). automatically compensated by the instrument.
4.6.2 What Is So Special About DMA™ 500?

A nice feature is not worth a lot, if the customer does not see any benefit for his daily operation.
Therefore it is even more important that we talk to him in the "language of benefits" instead of
bombarding him with technical details. You can consider the following table as being a translator –
from technical details to benefits. Further, it includes some hints on what the competition offers at the
same time.
All stated features are unique selling propositions, meaning that no other comparable product on
the market provides the same functionality.

Feature How/why does the customer What does competition
benefit? offer?
One-fold U-tube design Easy filling and removal of samples – Two-fold U-tube design
especially viscous ones. making filling and cleaning
more difficult.
Intuitive user interface & DMA™ 500 is designed so that users Results as well as menu
large color display can immediately start measuring after entries are shown on a
switching the instrument on. The self- small 2-line display.
explanatory menu structure enables
the user to perform standard
operations without the need to consult
the instruction manual.
Besides the keys you can also operate
the DMA™ 500 by an external
keyboard or bar code reader,
connected to the USB interface.
The large display gives a good
overview about the measurement and
enables an easy and convenient
measuring procedure.
Storage of 1000 results No need to write off results from the Results are directly printed
screen. or transferred to a PC via
Measured results are stored together the RS232 interface.
with the sample ID and the image of One competitive
the measuring cell, ensuring full instrument (BHDM) is able
traceability. to store 80 results only.
Integrated rechargeable DMA™ 500 is the first benchtop Operation only when
battery density meter providing optional off- connected to the mains.
the-line operation – for the purpose of
compensating electrical power
outages, flexibility regarding the
position of the instrument within the
lab, or temporary operation outside
the lab (but still indoors!).
Viscosity correction DMA™ 500 provides additional safety Not available
for measuring highly viscous samples:
The instrument’s viscosity correction
compensates potential viscosity-
related errors.

Feature How/why does the customer What does competition
benefit? offer?
U-View™ The measuring cell can be visually Inspection window only
inspected using a real-time camera
(U-View™).
Storage of the image with the result
ensures traceability.
The FillingCheck™ feature Not available
automatically detects gas bubbles in
the measuring cell by an advanced
analysis of its oscillation pattern and
FillingCheck™ generates a warning message.
Sample identification Giving names to measured samples Not available
and storing the name together with the
result ensures traceability and a clear
correlation of the result to a certain
measured sample (e.g. a tank,
location or user). For instant
identification a bar code reader can be
connected.
Wireless printing via Printouts can be done without the Data can be printed and
Bluetooth need for cables via the integrated transferred via the RS232
Bluetooth interface. The Bluetooth interface.
technology allows a certain flexibility
regarding positioning of the small
printer within the lab due to the wide
communication range
Many predefined No need for consultation of density- Only two units (density
concentration units concentration tables. DMA™ 500 and SG) are available by
comes with the most important default. Other calculations
concentration units (like e.g. sugar have to be transferred to
tables, acid / base tables, API the instrument.
functions, alcohol tables …)
preinstalled and offers the option for
additional custom-specific units.
Data transfer to a USB You can export your measured data in Data can be printed and
flash drive or PC the format of your choice (csv, txt, transferred via the RS232
html) to a USB flash drive or - via the interface.
Bluetooth interface or a cable - to a
PC. Also other kind of data - like
firmware updates, custom functions or
instrument backups - can conveniently
be transferred to or from an external
device.

4.6.3 Target Groups and Applications
The DMA™ 500 was introduced in the first quarter of 2011. It is very popular in the chemical and
cosmetics industries as well as in the food and petroleum industry (see the following chart). Don't get
irritated by the high percentage of "Other" industries: due to its low price and compact design, DMA™
500 is sold successfully via resellers and it is often difficult to assign those to a certain industry.
References:
Cosmetics: Johnson & Johnson

(USA), Chanel Beauté (France),
Colgate Palmolive (India), Procter &
Gamble (UK)
Chemicals: BASF, Brenntag

(Germany), Clariant (France),
ChemTreat (USA), Mifa AG
(Switzerland)
Food, F&F: Milenia (Brazil), Canada

Malting (Canada), Sanomed, Silesia
(Germany), Kerry Ingredients (UK),
AFF Aromatics Pvt. (India)
Petroleum: Baker Hughes (USA),

Česká Rafinérská (Czech Republic),
Tetra Technologies (UK), TAU AG
(Switzerland)
Pharma: Baxter (Austria), Bayer

(USA), Ratiopharm (Germany),
GlaxoSmithKline (UK, USA)
Thanks to its compact design and integrated rechargeable battery the instrument opens the door for
us to new applications!
In the lab:
Customers using DMA™ 500 in the lab will benefit from its ease-of-use and compact design:
• DMA™ 38 or DMA™ 48 users might want to replace their old instrument with a new 3-digit
instrument
• customers who currently own a portable density meter might want to have a benchtop
instrument for their small lab
• newcomers in the digital density meter business might want an easy to handle instrument to
start with
• customers who are confronted with regular power outages will benefit from the optional off-
the-line operation ensuring that they can continue their work during power outages.

On the road: DMA™ 500 can be placed in a mobile lab - a car or container equipped
with analytical instruments – common e.g. for military or research
applications. The users will benefit from the compact format and the
optional off-the-line operation as well as the possibility to charge the
instrument via the cigarette lighter.
Near the sample: Customers who want to organize their production and quality inspection
processes more efficiently will like to place the instrument near the
sampling location so that employees do not have to carry samples back
and forth to the lab any more. This saves time – and therefore money!
To summarize, the target groups for DMA™ 500 sales are:
Have a look at the Sales Guide, leading you the way to successful DMA™ 500
sales!
The DMA™ 500 Sales Guide is a 20 page guideline to successful DMA™ 500 sales
and is available on the Extranet (Density Meters & Concentration Meters\DMA™
500\Sales Information\English\DMA™ 500 Sales Guide). It prepares you for a first
discussion with your customer about the instrument’s features and its applications,
provides you with arguments against the competition and offers helpful hints on how to
identify potential DMA™ 500 customers and how to get their attention.
4.6.4 Competition
DMA™ 500 is the youngster among the instruments in its accuracy and price range. The two most
important competitors to be remembered are Mettler Toledo and KEM, although their instruments
compete more with DMA™ 38, the predecessor of DMA™ 500. As the features listed in section 4.6.2
are unique compared to competitors’ products, they are not listed in the comparison table.

Name Picture Accuracy Additional information
Inspection window of measuring cell instead
of live image.
0.001 g/cm3 No viscosity correction
DA-100M
Optional peristaltic pump
DA-100
Shijiazhuang ZYMD-1B and

Measurements at 20 °C only
Baiheng ZYMD- BHDM-YM10:
Inspection window of measuring cell instead
1, BHDM-YM10 0.001 g/cm3
of live image.
and BHDM- ZYMD-1A:
No viscosity correction
YM08 0.0005 g/cm3
Competitor only active in China
BHDM-YM08:
Integrated peristaltic pump
0.0008 g/cm3
OEM product from KEM
Same specs & functionality as KEM DA-100
plus USB interface and storage of 10
results.
0.001 g/cm3
Disadvantages, additionally to KEM DA-
DA155 100:
11.6 kg weight, larger dimensions, only 15-
25 °C temperature range

1. Which functions and features support the user in the correct filling of the sample? Tick the correct
answer(s):
□ The automatic viscosity correction
□ The optionally integrated peristaltic pump
□ The optional keyboard operation
□ The FillingCheck™ feature
□ The U-View™ feature
□ The possibility to store 20 methods
2. DMA™ 500 carries an integrated rechargeable battery. What for?

The optionally integrated rechargeable battery serves as a UPS (u______________
p____________ s_______________) in case of large voltage fluctuations or short
__________________. So customers can continue their work and don’t lose any data or time. The
instrument can be placed in a ______________ lab too – a car or container equipped with analytical
instruments. DMA™ 500 can even be charged via the c_____________ l_____________.

4.7 Benchtop Density Meter DMA™ Generation M
DMA™ Generation M density meters are instruments to determine

the true density of liquids and gases in the lab and provide density
readings with an accuracy of 0.0001 g/cm3 up to 0.000005 g/cm³
within a temperature range of 0 to 100 °C.
Anton Paar’s DMA™ Generation M density meters combine
•the groundbreaking oscillating U-tube principle,
•the integrated reference oscillator,
•highly accurate platinum thermometers and
•a full-range viscosity correction
to provide exceptional measurement performance of density and related values in the laboratory.
The features add an outstanding level of user confidence and comfort and – besides measuring
accuracy – they are combined in three different instruments: DMA™ 4100 M, DMA™ 4500 M and
DMA™ 5000 M.
Front view of DMA™ Generation M
Fig. 4-3: View of the front and right side of the DMA™ M
1 Power on LED 4 Sample inlet and outlet

2 Color PCAP touch screen 5 Air pump outlet
3 Xsample™ slot cover plate

Rear view of DMA™ Generation M
1 2
15
4
5
14
6
7
13 12 11 10 9 8
Fig. 4-4: Rear view
1 DRY AIR BLOCK connectors 9 Fuse holder

2 USB interface 10 Power inlet
3 VGA interface 11 UL test mark
4 RS-232 interface (COM) 12 Type plate with serial number
5 Ethernet interface 13 Product number ("P/N")
6 CAN interfacea 14 Fan
7 "DRY AIR IN AIR PUMP" connector 15 Carrying ledge
8 Power switch
a for the connection of further measuring modules

View of the Left Side
1 2 3
Fig. 4-5: View of the left side
1 Blind covers for inlet and outlet of the optional cooling kit
2 USB interfaces
3 Protection cover for the USB interfaces
The M in ‘DMA™ Generation M’ reminds you of the powerful modular concept that offers a variety
of possibilities for different measuring systems; via the CAN interface, several ME measuring
modules (modular extensions such as CarboQC ME, Alcolyzer Beer ME etc.) are connected to and
controlled by the master instrument such as DMA™ 4100 M, DMA™ 4500 M or DMA™ 5000 M.
4.7.1 How to Use DMA™ Generation M

The operation is easy and convenient for both highly skilled and new users. The sample is simply
filled into the instrument’s filling adapter at the right-hand side. For the highly precise DMA™ 5000 M
and DSA 5000 M, a special syringe holder is recommended and delivered by default. This way, the
weight of the syringe is decoupled from the filling adapter to prevent negative influences on the
measured density see fig. 4-6. After measuring the sample and cleaning, the integrated air pump –
with its connector directly below the sample in-/outlet – is used to dry the cell before the next sample
is measured.
There are three different ways of filling a sample into the measuring cell:
• Filling using a sample handling unit or sample changer, if the necessary amount of sample is
not a knock-out criterion: please refer to section 10..
• Filling using special filling equipment (aerosol adapter) for demanding industries: see
accessories, section 4.7.3.
• Filling using a syringe (requires less sample) (see fig. 4-6 ). A syringe clamp for 5 mL plastic
syringes enables easier filling of highly viscous samples (see fig. 4-7).

Fig. 4-6: Filling via syringe
Fig. 4-7: Syringe clamp
You can create up to 400 customized measuring methods

on your instrument, defining the units, temperature and
Start the screen layout to be used for measuring. Up to 15 measu-
measurement with the ring units can be shown on the main screen. The most
push of a button. common concentration units and calculations (like e.g. su-
Measured values are gar tables, acid/base tables, API functions, alcohol
shown continuously tables …) are preinstalled on the instrument. Before mea-
on the display and can suring, select the desired method.
be stored within the
instrument’s memory
Fill 1 mL of sample into
(including the live
the oscillating U-tube
image of the
sensor. The instrument
measuring cell). Errors
warns you automatically
related to sample
in case of any filling er-
viscosity are
rors.
continuously
corrected. The results
can also be
transferred to a PC,
LIMS or data storage
device.
Enter a sample name or number via touch

Via the live image of the screen, a connected keyboard or bar code
measuring cell the user can once reader. You can pre-configure the sample list
more make sure there are no gas before carrying out measurement series,
bubbles within the cell, which may particularly when using an automatic sample
influence the measured result. changer

Did you know?
If you need to know anything about the DMA™ Generation M that you´re not so sure
about and you don´t have a real device available to crosscheck, you should visit the
online version of the Extranet. Go to ‘Software/Firmware > Density Meter > LDC Lab
Density & Concentration > Software and Firmware’ to download the latest Simulator.
You can then simulate the whole menu structure and user interface of DMA™
Generation M on your computer.
As the density is highly temperature-dependent you’ll see also the density value shown on the screen
changes as long as the temperature has not stabilized. This can take a while if the sample
temperature greatly differs from measuring temperature.
If your customer complains about the long measuring time due to temperature
differences he/she can choose a different measurement mode providing quicker, but
less accurate results. For details see the DMA™ Generation M instruction manual:
‘Precision class’.
Feature How/why does the customer benefit?

PCAP touchscreen The systems’ large 10.4” touchscreen employs projected capacitive
technology (PCT/PCAP) for a state-of-the-art user experience. The
chemically hardened glass surface is robust and sensitive at the same
time which makes the DMA™ a unique density meter.
Learn more about the advantages of PCAP-technology in this blog-article:

http://blog.anton-paar.com/how-modern-user-interaction-design-
revolutionizes-the-lab
FillingCheck™ Be sure of correctly filled samples. FillingCheck™ is an
intelligent system based on an advanced analysis of the
U-tube’s oscillation pattern. It will alert you if the
oscillating U-tube sensor is incompletely filled (filling
errors) or the sample contains gas bubbles or particles directly at the main
screen or via documentation of the incident in data exports, printouts or
the data memory.
U-View™ Be sure of verified results, even while you
are away. Use the real-time camera with
zoom function to monitor the filled in
sample.
That real-time checking of the U-tube filling process is called U-View™: it
also allows for storage of images of the entire filled-in sample and you can
safely walk away and verify the measurements later, particularly when
using automatic sampling systems.

ThermoBalance™ Be sure to go with the best. The reference oscillator
ThermoBalance™ eliminates the need for multi-
temperature adjustments (only one single air/water
adjustment at 20 °C is necessary) and allows you to
quickly perform accurate measurements at very different
temperatures.
It compensates for drifts due to temperature stress, also
when filling samples at temperatures very different from the measuring
temperature, and provides stable readings over extended periods of time.
Automatic air For an adjustment only air and water as well as their reference densities
adjustments (at 20 °C) need to be known. This reference value is constant for water
but varies for air (depending on sea level and weather).
Rest assured that the local air pressure for air adjustments is correctly
accounted for thanks to the integrated air pressure sensor.
Accurate Two integrated Pt100 platinum thermometers and Peltier

temperature elements provide an extremely precise temperature control of
the sample. The selectable temperature range reaches from 0
to 100 °C.
Viscosity Viscosity-related errors are automatically corrected over

correction the full viscosity range by measuring the damping effect
of the viscous sample followed by a mathematical
correction of the density value.
No need for viscous standards, no need for customers to
know about the viscosities of their samples!
Plug and Play A major source of measuring errors

Sample Changer when using density meters are gas
bubbles in the measuring cell. A variety
of Plug and Play sample changers
facilitate the precise and bubble-free
filling of sample with optional cleaning
routines afterwards, which strongly
contributes to an accurate and
repeatable measuring result.
User-friendliness The easy-to-use 10.4” PCAP-touch-screen
allows you to perform your tasks quickly and
efficiently. Save time by using the Quick
Access Area (symbols on the screen) to
access your most frequently needed menu
functions.
Multiple parameters are displayed
simultaneously on the large and easy-to-read
colored touch screen, providing unparalleled
ease-of-use.

Modular concept Special additions are available when ordering or any time later, such as
an alcohol meter, refractometer or CO2 meter.
The operator uses the DMA™ Generation M for the complete operation
(starting / stopping a measurement, collecting / displaying / storing the
data, editing the measuring methods of the whole measuring system,
etc.). This way, various measured parameters are controlled and
displayed via a single user interface only.
Intuitive user The touch screen user interface supports easy and intuitive operation in
interface routine applications as well as in sophisticated scientific research work:
Thanks to three predefined user levels and custom defined user levels,
the instrument does not confuse unskilled lab staff with sophisticated
features, if they only want to perform density measurements and nothing
else.
Complete QM Complete transparency and traceability of sample filling and
compliance measurement process due to FillingCheck™ and U-View™
and the powerful audit trail function – a traceable data
handling system providing tamper-proof data export
(checksum) help you to comply with your quality management
regulations. (cGLP/GMP and 21 CFR part 11, Pharmacopoeia…)
All adjustments, measurement results, reports as well as instrument
settings are protected and passwords are verified based on user account
settings and security level. Measurement results and check reports can
be electronically signed. You can export measuring and adjustment data
including date and time, serial number, user name, sample identification
and other vital information.
Compact and Despite the modularity, the design of DMA™ Generation M is compact
robust and robust at the same time. A sealed housing and coated aluminum
design materials provide resistance to sample spills.
Besides the touch screen you can also operate the DMA™ Generation M
under harsh industrial conditions using an external keyboard, mouse, bar
code reader or even contactless gesture control, connected to the USB
interface. You can even connect a large PC monitor or touch screen to
read the results or operate the instrument from afar.
For highly aggressive environmental conditions (e.g. acid fumes) various
protective measures such as interface caps or connectors to introduce dry
air are available to protect the instrument.
Using measuring For the most common applications, 10 measuring methods are
methods predefined. Just select the method fitting your application or create your
own methods.
A method includes certain measurement settings (measuring unit,
measuring temperature, etc.). Defining methods is useful for customers
determining different measuring parameters at different measuring
temperatures or measuring many different liquids.

Convenient data Store your measured data in the instrument and use the
handling of up to various interfaces for data export via USB flash drive, printer
1000 results or Ethernet services (bidirectional data handling when
connected to a LIMS). Reports are provided in popular
formats such as PDF, TXT and XLS. Also other kinds of data
- like firmware updates, custom functions or instrument
backups - can conveniently be transferred to or from an
external device.
4.7.3 Optional Accessories for DMA™ Generation M

As different industries call for different demands, a variety of accessories is available to simplify daily
business as much as possible. Find the most important ones below:
• Different sample changers and sample handling units offer different levels of automation
(please refer to section 10.).
• A keyboard, mouse, bar code reader or contactless gesture control can be used to
operate the instrument.
• For demanding environments – such as petrochemical testing laboratories – protection
covers for the various interfaces and the external keyboard are available.
• To perform measurements at temperatures lower than 20 °C (36 °F) below ambient
temperature, a cooling kit is pre-installed in DMA™ M CK density meters to remove heat from
the peltier elements (generated when cooling the cell) by means of an external thermostat or
tap water.
• As the integrated air pump blows air from the instrument’s environment through the measuring
cell to dry it, a special drying cartridge is available for humid areas. If humid air is used to dry
the U-tube, this might result in failed checks of the air density after cleaning and drying.
• Using the RS-232, Ethernet or USB interfaces different printers can be connected to the
instrument to print out results and such. Find the list of tested printers on the
DMA™ Generation M product webpage (see "Common documents" in the "Download" tab
and click "Product Information > Recommended printers")
• The Aerosol Adapter (see fig. 4-8) is a special filling device which fills volatile liquids bubble-
free under (can) pressure out of all commercial aerosol/spray cans into the DMA™ M density
meters.
• The Heating Attachment (see fig. 4-8) for DMA™ M heats the PTFE filling adapters allowing
samples that are normally solid or very viscous (chocolate, wax, mineral/crude oils, light tars)
at room temperature to be injected easily at elevated temperatures between 40 °C (104 °F)
and 90 °C (194 °F).
Fig. 4-8: Aerosol Adapter (left) and Heating Attachment (right)

4.7.4 What Product Version to Choose
To make sure you can advise your customer with the one product version which best fits the
application, the following table shows the differences between the three product versions –
DMA™ 4100 M, DMA™ 4500 M and DMA™ 5000 M – with regards to performance, functionality
and the resulting target group.
TIP – Print out the following table and have it available in your pocket so you can serve your customer
with the right solution any time. In this way you do not need to learn the differences by heart in detail!
DMA™ 4100 M DMA™ 4500 M DMA™ 5000 M

Accuracy 0.0001 g/cm3 0.00005 g/cm3 0.000005 g/cm3
Measuring
0 to 100 °C
temperature
Ultrafast
Ultrafast Fast
Precision class
Standard Standard
Precise
Adjustment at high
viscosity
10 predefined measuring methods
storage of 1000 measured results
several preinstalled concentration units
Features FillingCheck™ & U-View™

ThermoBalance™
temperature scan
full range viscosity correction
Testing labs, Authorities
and standards
organizations
Food Industry
Education, Research
Target group
Beverages, Chemical Industry, Cosmetics, Personal Care, Electronics,
Environmental, Petroleum Industry, Pharmacy, Medicine/Biotechnology
If you have a customer who asks for a density meter providing highly accurate results but also flexible
data handling and you are not sure whether to offer a DMA™ 4100 M or a DMA™ 5000 M, see the
following recommendations:
Offer the customer a DMA™ 5000 M instead of a DMA™ 4100 M if:
• the customer is only interested in the highest accuracy but isn’t too price sensitive.
• he/she wants to measure in high viscosity areas, and also wants to adjust the instrument in
these areas.

4.7.4.1 Special Product Version: DMA™ 4500 M Chemicals
DMA™ 4500 M Chemicals is the robust concentration meter which provides the same great user
experience, high accuracy and convenient data handling as the renowned DMA™ Generation M
density meter series along with special features for chemicals.
To quickly and efficiently determine the concentration of chemicals for incoming checks and quality
control, DMA™ 4500 M Chemicals has 140+ conversion tables at its command to precisely analyze
alcohols, acids, bases, salts, sugars and more.
To keep it at the same time as simple as possible, the following features have been removed:
- API calculations for petrochemical industries
- security features for pharmaceutical industries
- modularity (only sample changers but no measuring modules can be connected)
Learn more about modern concentration measurement in this blog
http://blog.anton-paar.com/easy-quick-and-precise-concentration-determination-made-easy.
4.7.5 What Is So Special About DMA™ Generation M?

Above you have read about the features of DMA™ Generation M. But which of these features are
unique compared to competitors’ instruments with comparable accuracy? Find the answer below:
1. PCAP touchscreen technology for unmatched robustness
2. FillingCheck™ giving a warning in case of a filling error
3. U-View™, showing the live image of the measuring cell
4. ThermoBalance™: only one adjustment at 20 °C for the whole measuring range thanks to the
reference oscillator
5. The simple adjustment procedure. Competitors’ instruments need product-specific calibrations,
which makes life much more complicated.
6. Modularity: countless customized measuring systems can be configured thanks to the modular
concept. With Anton Paar measuring modules connected to DMA™ Generation M density
meters (see section 11.), such systems are especially compact, efficient and easy to operate.
For details consult the list in section 4.7.2.
Win tenders with help of the DMA™ Generation M Lock-out specifications

document!
The DMA™ Generation M “Lock-out specifications” summarizes the most important
sales arguments of the products and differentiation factors from competitors.
Mentioning those arguments in your bid will definitely increase your chances to win the
tender and will “lock-out” competitors. The document can be found on the Extranet.
Did you know?

If you need more hard facts than summarized in the above mentioned Lock-out
specifications document, please have a look at the ROI calculator on the Extranet
(sales information). This tool helps you to quickly highlight the changes when switching
from traditional methods to a digital density meter and provides quantified savings of
money.

Did you know?
Refer to the “Tender Guide” for a list of real-life demands for benchtop density meters.
For each specific situation, you´ll find the proper feature of DMA™ Generation M that
helps to handle the challenges. Also, you´ll see what competition can or can not offer.
Use this document for your personal argumentations but also when co-creating a
tender.
If you are not sure whether a customized system configuration was technically
approved and released, the Configurator tool will provide the required information on
hundreds of released configurations. Find the tool on the Extranet (sales information).
4.7.6 DMA™ M – Market Information
Consider that only two materials (borosilicate glass: measuring cell, PTFE: filling adapters) have to
be resistant to the measured samples and please check prior to measurement for their chemical
resistance which is (in case of acids) highly temperature-dependent. If chemical resistance of the
wetted parts is guaranteed, any homogeneous samples (no air bubbles or particles inside) can be
measured in either gaseous or liquid phase. The DMA™ Generation M is mainly used in the following
industries:
Beverages Anton Paar’s longstanding experience as a measuring specialist for

the beverage industry (soft drinks, beer, spirits, etc.) and the highly
precise results DMA™ delivers in next to no time have established it as
the benchmark for this field.
Pharma & Cosmetics DMA™ meets the strict regulations in the pharmaceutical and cosmetic
industries: Quality control of raw materials and final products,
determination of specific gravity and density of medicinal formulations
as well as filling volume determination.
Did you know?

To help customers in the pharmaceutical industry, Anton Paar GmbH offers the
Pharma Qualification and Validation Package (PQP) containing all relevant documents
for instrument qualification and validation in pharmaceutical companies. This package
complies with the relevant pharmaceutical regulations: GMP, GAMP 5, 21 CFR Part 11,
USP <1058> and uses a risk-based approach.

Petroleum: A thorough, fast viscosity correction and a measuring range up to
100 °C make DMA™ the perfect density meter for highly viscous
samples such as bitumen, heavy fuel oil, or crude oil: Quality control of
raw materials and final products, quality control of additives, blending
checks, etc.
Flavors & Fragrances: DMA™ only requires a minimal amount of expensive sample in order
to deliver highly precise results: Quality control of raw materials and
final products, specification checks, filling volume determination. The
modular concept and fully automatic data processing (LIMS) are well
received by this industry.
Chemicals: The chemical industry relies on DMA™’s renowned robustness. The
use of DMA™ has considerably reduced the workload: quality control
of raw materials and final products, concentration determination of
acids and bases, solids content determination of dispersions, reaction
process control.
Did you know?

The various possibilities for successful applications of digital density meters in chemical
industries are summarized in comprehensive chemical guides available from the
Extranet (sales information).
For specific chemicals, these documents provide insights into production processes,
producer-/ and consumer-groups, global production volumes etc.
Chemicals guides are available for H2SO4, NaOH, NH3 and there are more to come.
Research and The great accuracy, the small sample volume required and the
Development: temperature scan by means of the reference oscillator guarantee easy,
time-saving work: determination of partial specific volume,
determination of density gradient for ultracentrifuging,
density/temperature profile, determination of molarity and normality.
Calibration Offices, DMA™ 5000 M is the high-precision reference instrument with the
Testing Agencies: least sample consumption: determination of alcohol content for fiscal
reasons, filling volume determination, stability monitoring of density
standards.
Biofuels Bioethanol producers use DMA™ M because its accuracy assures
considerable savings, the biodiesel industry chooses the instrument for
its robustness and fast viscosity correction: Quality control of raw
materials and final products, production control, blending checks.
Food: Various sectors from food industries use the DMA™ M for quality
control or product characterization. Often measured at elevated
temperatures the optional heating attachment ensures that samples
such as chocolate or palm oil remain liquid in the whole measuring
system (including sample in-/outlet at the filling adapters).

Did you know?
Are you planning to approach any of the above mentioned industries or applications
with some focused activity? Open the document type ‘External Marketing Material’ and
watch out for draft newsletters for end customers. Simply translate them and enter your
contact data to efficiently generate leads.
The charts show, in which fields of application the DMA™ Generation M and its predecessors DMA™
4100/4500/5000 "classic" (discontinued) are mainly used. Find below some references for each
industry mentioned.
312 Beverage 8%
311 Food 5%
324x Petro & Coal 21%

3251 Basic Chem. 9%
3254 Pharma 8%
3256 Soap, Cleaning etc. 6%
3259 Other Chem. Prod.
& Prep. Manuf. 6%
References DMA™ 4100 M:
Refined Petroleum Products: BP, Total, Shell, Chevron, Saybolt, Bharat,

Reliance
Inorganic Chemicals: BASF, Henkel, DOW, Akzo Nobel, Agfa, DuPont,
Solvay, Duracell
Calibration Services; Customs & Excise: SGS, ITS Caleb Brett (Intertek)
Research: Universities (California, Beijing, Shanghai, Leeds)
Pharmaceuticals: Bayer, Fresenius Kabi, Roche, Novartis, Baxter
Cosmetics: Unilever, Weleda
Flavors & Fragrances: Takasago, Firmenich

324x Petro & Coal
31212 Breweries 13%
14%
31211 Soft Drink 11%
3251 Basic Chem. 9%
311xx Food 4%
3254 Pharma 7%
31214 Distilleries 1%
31213 Wineries 1%
Refined Petroleum Products: Saybolt, Statoil, Indian Oil Corporation Ltd., Exxon,
Shell, BP, Chevron, Total, Schlumberger,
ConocoPhillips, Core Lab
Chemicals: BASF, Akzo Nobel, Brenntag, DOW, DuPont, Fuji,
Procter & Gamble
Research: Universities (Delhi, Osaka, Beijing, Delaware,
Washington)
Pharmaceuticals: Octapharma, Baxter, Glaxo SmithKline, Pfizer, Abbott,
Merz, Roche
Cosmetics: Henkel, Wella
Flavors & Fragrances: Firmenich, IFF, Symrise, Takasago
Tobacco Manufacturing: China Tobacco Ltd., Philip Morris
Soft Drinks: Coca Cola, Nestlé, PepsiCo
Spirits: Diageo
Beer: Heineken, Kirin, Coors, Asia Pacific Brewery, Inbev,
China Resources Snow Breweries, Tsingtao

31212 Brewe-
3251 Basic Chem. 5% ries 23%
324x Petro & Coal 4% 31214 Distilleries 23%
3254 Pharma 3% 31213 Wineries 6%
311xx Food 5%
Spirits Absolut, Chivas, Jack Daniel´s, Cott, Jim Beam, Diageo

Soft drinks: Coca Cola, Pepsi Cola
Beer: Heineken, Kirin, Budweiser, Inbev
Wine: Baker Wine & Grape Analysis
Liqueurs: Bacardi-Martini, Diageo Baileys
Research & Teaching: Universities (Gent, Iowa, Stuttgart)
Chemicals: Intel, BASF
Calibration Services; National Institute for the Control of Pharmaceutical and
Customs & Excise: Biological Products, China National Institute of
Metrology P.R.China, Trinidad & Tobago Bureau of
Standards, Department of the Treasury Alcohol and
Tobacco Tax and Trade Bureau
Refined Petroleum Products: Shell, Total, Vinci Technologies, ConocoPhillips, Exxon
Pharmaceuticals: Sandoz, Fresenius, Pfizer
Below, a selection of three important industries - each with various possibilities for the application of
our density meters - is explained in more detail.

Petrochemistry: from crude oil to finished gasoline
The raw material, crude oil, and its refinery products are complex
mixtures of various hydrocarbons that are usually characterized
via their physical properties. Density is one of the analytically
useful characteristics.
The software of the DMA™ M includes the API functions as a
standard feature. The API functions automatically convert the
density values of petroleum samples measured at any
temperature to density, API gravity or specific gravity at 15 °C,
20 °C, 29.5 °C or 60 °F for the product groups A, B and D. The API
results can immediately be displayed, printed and stored.
Beverage industry: soft drinks

Soft drinks are traditionally produced by mixing syrup with water
and carbon dioxide. Syrup is an aqueous sugar solution of 60 to
70% w/w. In addition, various amounts of additives, natural or
artificial aroma, color etc. may be added. Finished products usually
contain 9 to 11% w/w of sugar. The determination of the
concentration of sugar in these soft drinks is of crucial importance
for the production and processing of syrup and finished products.
Fortunately, the density of sugar solutions corresponds precisely
with the concentration. The density measured by the instrument
can automatically be converted into concentration-related values
and units using programmable tables and/or formulae. A standard setup widely used in the soft drink
industry gives the display of °Brix (according to NBS tables 113/114), specific gravity and other
customer-specific values (e.g. conversion of true density to apparent density).
Beverage industry: Alcohol measurement

In the alcoholic beverage industry, in tax and customs
laboratories and in the pharmaceutical industry, the alcohol
content of alcoholic beverages is an important parameter for
quality control and correct product declaration conforming to tax
regulations.
An officially recognized method to determine the alcohol
concentration is to measure the density and subsequently convert
it into alcohol concentration using official alcohol tables.
Pycnometers, hydrometers and digital density meters are
accepted instruments.
4.7.6.2 Cross Selling Potential

Always keep in mind that there are always several opportunities for optional accessories to adapt the
DMA™ to the customer´s needs and measurement processes in the best way:
• Any device of the Xsample™ family might be used for different levels of automation (see
section 10.).
• Heating Attachment, Aerosol Adapter and Cooling Kit depending on the sample to be
measured.
• Drying cartridge for humid environments and/or low measuring temperatures.

The main potential for further sales addresses different measuring units:
• Please refer to the corresponding chapters for modular extensions (ME) determining
parameters like CO2, O2, pH, nD, alcohol, turbidity, viscosity or optical rotation.
• Furthermore, a variety of related products may be of interest for a potential customer, e.g.
SVM™ viscometers or online density measurement in process applications.
Did you know?

The synergies of Anton Paar instruments create a strong market position for Anton
Paar. In addition to DMA™ Generation M density meters, there are other Anton Paar
instruments also important for the petroleum industry such as the SVM™ series - a
whole portfolio of unique viscometers equipped with precise U-tube technology up to
the 4th digit.
To ensure that customers are offered the most appropriate solutions for measuring density one
needs to deal with the following questions regarding customers´ needs.
In case a solution for measurement of both density and viscosity is requested, Anton Paar competes
against competition for viscometers and density meters. An indication that both DMA™ and SVM™
are required is given, when the following questions are answered with 'yes':
• a reproducibility of better than 0.0001 g/cm³ is needed
• density and viscosity are not measured in the same lab
• density and viscosity are determined in parallel but at different temperatures
• U-View™ is used for traceability reasons
In all other cases, the unique SVM™ shall be the right choice and brings us far beyond the
competition.
If a comparable scenario is identified in chemical industries, the powerful combination of DMA™ +
Lovis M/ME module will be the right solution.
4.7.6.3 Competition
There are only few main competitors which have been on the market for a long time (Mettler Toledo,
KEM), but throughout the last decade – starting from approx. 2005 – several others appeared. As
DMA™ Generation M covers three instruments with different specifications for the accuracy, so does
the competition. Therefore the competitive situation is shown separately for each version.
As the features listed in section 4.7.5 are unique compared to competitors’ products, they are not
listed in the comparison table. For further information, please refer to Anton Paar Extranet (sales
information).

Company / Instrument & Meas. Range Features & general information
Picture Accuracy
DA-640: 0 to 93 °C • Measuring time: shorter than in
0.0001 g/cm3 previous generation; much longer
(folder)
with viscosity correction (approx. 3
0 to 96 °C to 7 minutes)
DA-645: 0.00005
g/cm3 (EN-web) • Eco-friendliness: less power
consumption (sleep mode)
DA-650: 0 to 90 °C
• Temperature scan functionality
0.00002 g/cm3 (JP-web)
• Measuring performance: better
0 to 3 g/cm³ than for other competitors
DM 40 / DX 40:
0.0001 g/cm3
DM 45 / DX 45:
0.00005 g/cm3 0 to 91 °C • Several additional parameters
available: conductivity, color, pH,
DM 50 / DX 50: 0 to 3 g/cm³
air pressure sensor, fingerprint
0.00004 g/cm3 reader, etc.
• Inspection window of measuring

cell and video-assisted view of
measuring cell (with 10 x
magnification); no automatic
DDM 2909: bubble detection
15 to 30 °C
0.0002-0.0003 • Ethernet: remote technical support
g/cm³ 0 to 3 g/cm³ possible
• Reference oscillator: separated
from measuring cell; thus multi-
temperature adjustments are still
required
DDM 2910: • Video-assisted view of measuring
0.0001 g/cm³ cell (with 10 x magnification); no
automatic bubble detection
DDM 2911:
0.00005 g/cm³ 0 to 95 °C • Ethernet: remote technical support
0 to 3 g/cm³ possible
DDM 2911 plus: • Reference oscillator: integrated into
0.00001 g/cm³ the measuring cell but supported
by weak temperature measurement

Company / Instrument & Meas. Range Features & general information
Picture Accuracy
DS 7800: 0.0001
10 to 40 °C • Measuring time: 5 min
g/cm3
EDM 4000+:
0.0001 g/cm3 • 3“ color touchscreen integrated;
5 to 95 °C external control unit with bigger
EDM 5000: 0 to 3 g/cm3 touchscreen
0.00005 g/cm3 • Newcomer in density business
• Measuring principle: U-tube

(vertically)
VIDA ML/40/80: • Automatic detection of gas
0 to 100 °C
0.0001-0.00005 bubbles, but neither inspection
0 to 3 g/cm3
g/cm3 window nor camera due to metal
U-tube
• Newcomer in density business

1. Name three USPs of DMA™ Generation M
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
2. Complete the text by filling the gaps.

Generation M density meters embody decades of experience. They build on the robust design and
renowned features of past DMA™ generations: the integrated _______________ oscillator (also
called ______________™), built-in high-precision platinum ____________________, and full-range
_______________ correction. Generation M features all of this – and more.
Your density meter automatically detects filling errors or _______________ in the sample, alerts you
and documents the incident.
Check the sample filling process on screen or recall stored _______________ of the entire filled-in
sample any time later. The stored images allow you to later verify correct sample filling and
measurements, particularly when using _______________. So you can safely walk away and let the
instrument do the work.

3. Name four main competitors for DMA™ Generation M.
________________________________
________________________________
________________________________
________________________________
4. Explain the measuring procedure of DMA™ Generation M.

______________________________________________________________________________
______________________________________________________________________________
______________________________________________________________________________
4.8 Benchtop Density Meter DMA™ 4200 M
The density measuring instrument DMA™ 4200 M is your solution for petroleum samples. It designed
to measure the density of liquids and gases under high pressures and high temperatures.
These special measuring conditions are needed for density measurement of highly viscous or volatile
samples or samples with a high melting point like all petroleum samples e.g. crude oil, intermediate
products, asphalt, liquid petroleum gas and high-viscosity liquids.
The measuring principle of DMA™ 4200 M is the well known oscillating U-tube principle, but for these
extreme conditions the U-tube is made of Hastelloy C-276.
DMA™ 4200 M can be used in the temperature range from -10 °C to +200 °C (+14 °F to +392 °F)
and operated within a pressure range of 0 to 500 bar (0 to 7,250 psi). It is ready to work since it is
delivered with factory adjustments for typical applications.
Designed to measure under high Numerous interfaces: 4xUSB,

temperatures and pressures 1xRS-232, 1x Ethernet
U-tube made of Hastelloy that

is extremely robust
Connection for water bath Big touchscreen: 10.4” PCAP

DMA™ 4200 M is not only designed for measurements at high temperatures, but also at
temperatures below 0 °C. If the measurement is performed at low temperatures, a water bath can
easily be connected.
The DMA™ 4200 M further provides a viscosity correction that compensates potential viscosity-
related errors.
The very big 10.4” touchscreen is projected capacitive (PCAP) and easy to operate even when
wearing gloves. The slightest contact with your finger activates the touchscreen. The big screen
shows up to 12 results in easy-to-read font size.
Measuring performance
Density 0-3 g/cm3

Density accuracy 0.0001 g/cm3
Temperature range -10 to +200 °C (14 °F to 392 °F)
Temperatur accuracy 0.03 K
Pressure range 0 to 500 bar (0 psi to 7,250 psi)
Sample volume > 2 mL
U-tube resistance H2S, HCl, HF, NaOH
Did you know?

At a glance: From gaseous to liquid and up to solid at room temperature
Crude oil, live crude oil, bitumen, asphalt, pitch, tar, liquefied petroleum gas (LPG),
heavy intermediates from production process, up-stream and down-stream samples –
all can be measured with the DMA™ 4200 M.
4.8.1 How to Use DMA™ 4200 M?

You can fill viscous samples by sucking or pressing them into the DMA™ 4200 M measuring cell
using a syringe (see fig. 4-9). These kinds of operation are very easy and convenient.
Fig. 4-9: Filling samples by sucking (left) or pressing (right)

TIP – For filling samples that are highly viscous or solid at room temperature and have to be heated
to enable filling, we recommend using the optional syringe heating attachment.
After a measurement the measurement cell can be cleaned with an appropriate solvent and dried
with the integrated air pump.
Did you know?

At a glance: From off-shore laboratories to QC labs
Whether at off-shore laboratories, QC labs for incoming crude oil checks or process
labs for QC of heavy process samples as well as in R&D labs – DMA™ 4200 M can be
installed everywhere!
4.8.2 What Is So Special About DMA™ 4200 M?
Expanded limits = Extended performance
DMA™ 4200 M extends the measurement limits for density measurement in

petroleum applications, as not only the temperature can be set from -10 °C up
to +200 °C, but also pressures up to 500 bar can be applied.
Samples can be filled with viscosities up to 35,000 mPa.s
Measurements at elevated temperatures in combination with accessories even
allows you to measure samples which are solid at room temperature. The
density values are automatically calculated for the required reporting
temperature
Strong
A U-tube made of Hastelloy C-276 is not only a high performance material

withstanding high temperatures and pressures, but it also has a much higher
chemical resistance to chloride and sour gas than stainless steel. No damage
or corrosion of the measuring cell has to be feared!
Versatile
DMA™ 4200 M can be used for a multitude of tasks at multiple locations

throughout the petroleum-refining process. Application areas include offshore
laboratories, refineries and research and development establishments.
The DMA™ 4200 M is a must-have tool for laboratories at petroleum refineries
as it improves, accelerates and simplifies density measurements for incoming
crude oil, for intermediate samples to give quick feedback to the refining
process and for QC of samples like asphalt, bitumen and LPG.
Savings: Reduction in time, cleaning solvents and waste
Forget tedious, manual and time-intensive measurements with pycnometers or

hydrometers. Filling of even viscous samples is simplified and only 2 mL of
sample is needed. After measurement, instead of laborious, solvent-intensive
cleaning routines with pycnometers and hydrometers, you just quickly clean the
DMA™ 4200 M sample cell with only a small amount of solvent.
All calculations are done for you, there is no need to look up API tables and
work out the temperature compensation. This enhances lab productivity while
minimizing human error and environmental influences.

4.8.3 Optional Accessories for DMA™ 4200 M
business as much as possible:
Gesture Control
The gesture control is an accessory for the DMA™ 4200 M to operate the instrument without touching
it. It is designed for usage with dirty or sticky hands e.g. in a bitumen/asphalt lab. The measurement
can be started and stopped, the air pump can be turned on and the methods can be selected by
swiping. The accessory is connected via USB interface.
Syringe Heating Attachment
The syringe heating attachment is an accessory for the DMA™ 4200 M.

It heats the sample inlet and outlet up to 190 °C and prevents clogging of
the sample in the inlet and outlet. The Syringe Heating Attachment is
ideally for heavy samples in the petroleum industry like bitumen/asphalt,
pitch, tar, bottom vacuum. The sample is melted in an oven and injected
into the DMA™ 4200 M with a heat-resistant syringe. This accessory is
the must-have-tool for every DMA™ 4200 M customer measuring heavy
petroleum samples .
LPG Adapter
The LPG Adapter is a special device for filling liquefied petroleum gas
(propane, butane and mixtures of these) into the DMA™ 4200 M density
measuring cell.
It acts as a link between gas container and the DMA™ 4200 M density
measuring cell. Once mounted to DMA™ 4200 M, it offers a complete and
“ready-to-go” solution for filling LPG into the density measuring cell.
Difficult and strenuous preparations are no longer necessary!
The gas container is connected to the sample inlet of the LPG Adapter.
By opening two valves, fill LPG into the LPG Adapter and from there into
the pre-tempered measuring cell.
Did you know?

… that the LPG Adapter is designed and manufactured in accordance with the Sound
Engineering Practice SEP Remark?

ASTM compliance kit
The ASTM compliance kit is an additional accessory, which makes the DMA™ 4200 M ASTM D4052
and D5002 compliant. With this kit and the software version > 2.70 you can activate the
FillingCheck™. After the measurement, the internal air pump is activated for 30 seconds and it is
determined if air bubbles are present in the sample automatically activated.
Read the application flash "Yes of course! DMA™ 4200 M is ASTM compliant!"
4.8.4 What Does Competition Offer?

DMA™ 4200 M is the only oscillating U-tube density meter on the market for density measurement
at elevated pressures and temperature. Nevertheless competitive instruments are available from
ISL-PAC and traditional instruments such as pycnometers and hydrometers.
ISL-PAC Anton Paar

VIDA 40 DMA™ 4200 M
Material measuring cell Stainless Steel Hastelloy C-276
Measurement range density 0-3 g/cm3 0-3 g/cm3
Temperature range 0 to 100 °C -10 to +200 °C
Pressure range 0 to 10 bar 0 to 500 bar
Viscosity range up to 15.000 cSt (at 20 °C) up to 35.000 cSt (at 20 °C)
Temperature accuracy 0.03 °C 0.03 °C
Density accuracy 0.0001 g/cm3 0.0001 g/cm3
Density repeatability 0.00005 g/cm3 0.00005 g/cm3
Viscosity correction No Yes
Price (ILP) -20% to AP- ILP AP- ILP
Autosampler Yes Yes, Xsample™ 340 (up to
100 °C)

Fast measurement: Compared to traditional methods like pycnometer the

DMA™ 4200 M is 10 times faster. The customer saves
a lot of time, chemicals and efforts in measuring the
bitumen/asphalt with DMA™ 4200 M.
Intuitive user interface & large
touch display: No studying of manuals, quickly start a measurement
after switching on the instrument. The menu is self-
explanatory and you can even operate the instruments
via external keyboard and mouse.
Data memory & transfer: No need to write the results into a note book. The
measured results are stored together with the sample ID
and other information such as user name, date, time
etc. and are therefore full traceable. Data can be
exported via USB flash drive, printer or Ethernet
services and reports are provided in popular formats
such as PDF, TXT and XLS. Viscosity correction:
additional safety due to an automatic compensation of
viscosity related errors.
Predefined quantities: The DMA™ 4200 M automatically converts the
measured values into the most important quantities
such as API functions or SG. Next to preinstalled tables
custom-specific functions can be entered.
Accurate temperature: Due to the Peltier elements the temperature control of
the DMA™ 4200 M is extremely precise.
4.8.6 Market Information

Target Groups
The target group and application is the petroleum industry, including
• Refineries
• QC labs for incoming crude oil check
• Final product QC labs for heavy samples
• Process labs for QC of process samples
• Heavy labs“
• Petroleum R&D labs
• Testing labs
• Off-shore laboratories
Upstream Research laboratories at universities, Petroleum Companies
Applications
Generally speaking the DMA™ 4200 M can measure all samples. It is due to its Hastelloy C-276 U-
tube and its possibility to measure density up to 200 °C and 500 bar especially designed for heavy
samples.
But what are heavy samples?

The group of heavy samples includes:
• Heavy crude oil
• Asphalt/bitumen, pitch, tar
• Vacuum gas oil (VGO)
• Vacuum residual oil (VRO)
• Heavy fuel oil (HFO)
• Medium fuel oil (MFO)
• Furnace fuel oil (FFO)
• Navy special fuel oil (NSFO)
• Residual fuel oil
• Fuel oil: No.5, No.6
Other “petroleum” samples are Liquified Petroleum Gas (LPG), fuel, diesel, RFG, wax, grease
Other samples, relevant for DMA™ 4200 M, aside the listed petroleum samples are chemicals:
strong acids, strong bases, e.g. NaOH, HCl, HF, H2S, LiF6 etc.
References
• Bitumen/asphalt labs: Imperial Oil (ExxonMobil), Shell Global Solutions, Nynas
• Testing labs: Intertek Caleb Brett, Inspectorate, SGS
• Chemicals: BASF, Solvay Advanced Silica
4.8.7 DMA™ 4100 M, 4200 M, 4500 M or 5000 M – What product to choose?
DMA™ 4200 M DMA™ 4100/4500/5000 M

U-tube material Hastelloy C-276 Borosilicate glass
ASTM compliance: D4052, YES (with software > 2.70) YES
D5002 and ASTM compliance kit
Accuracy 0.0001 g/cm3 Better than 0.0001 -
0.000005 g/cm3 depending
on model
Sample type Heavy, solid at room Light end, fuels, crude oil,
temperature, asphalt/ diesel, RFG, lube, grease
bitumen, crude oil, LPG, wax
NaOH conc., HCl conc., HF
Measuring time 10-12 minutes (with viscosity 5 minutes (with and without
correction) viscosity correction)
8-10 minutes (without)
Pour point of the sample YES NO
above 100 °C
Cleaning issues Nothing to worry about Cleaning might be difficult
with heavy samples

Fear of breaking the U-tube Nothing to worry about. Fear from the customer side
by measuring heavy Hastelloy is nearly exists, but no breakage issues
samples unbreakable are known
Sample changer Yes, Xsample™ 340 (up to YES
100 °C)

1. What DMA™ 4200 M accessory could be sold if the customer would like to measure waxes,
bitumen or tar?
the s _ _ _ _ _ _ h _ _ _ _ _ _ _ t _ _ _ _ _ _ _ _
2. List the main advantages of the Syringe Heating Attachment / DMA™ 4200 M Plus that can be
used in a tender?
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
3. Link the DMA™ 4200 M to the according characteristics

• U-tube made of stainless steel
• U-tube made of borosilicate glass
• U-tube made of Hastelloy
• Viscosity correction
• Upgrade with automatic sample changer
• Measuring range up to 200 bar and 100 °C
• Measuring range up to 500 bar and 200 °C
• Inspection window and U-View™ functionality
• Accessories: LPG adapter
• Special version with syringe heating attachment
(DMA™ 4200 M Plus)

5. Density and Sound Velocity Meters
As density measurement alone does not always provide enough information on your sample´s
characteristics, sound velocity can be used as an additional parameter.
The following chapter introduces you to the world of Anton Paar density and sound velocity
meters: DSA 5000 M and Soft Drink Analyzer M – both provide the advantages of the most
accurate density meter in the world.
Learn more about the physical property sound velocity in this blog-article:
http://blog.anton-paar.com/from-cannons-and-organ-pipes-to-modern-measurement-technology/
5.1 Why Measure Sound Velocity
The combined density and sound velocity measurement provides two important general benefits
when it comes to analysis of liquids:
• Double safety for two component solutions:
Since all possible combinations of measured density and sound velocity for pure two-component
solutions have to be on distinctive curves, product identification becomes much safer by applying this
method. All samples whose density and sound velocity measurements fall outside of the
density/sound velocity plot for the sample are contaminated. A certain tolerance area within the
density vs. sound velocity plot can be defined. Samples showing density and sound velocity values
within this area are accepted, all others are rejected.
• Concentration determination of ternary solutions:
A ternary solution consists of
• a component A with a concentration A,
• a component B with a concentration B,
• and a solvent, typically water.
Whereas information about the solvent is given, concentration A and B are unknown. For an equation
with two unknown parameters, information about density alone is not enough. Therefore sound
velocity is measured simultaneously.
An example: if a component A with high density and a component B with low density are added to
water, the total density might remain the same, but the additional and simultaneous measurement of
the sound velocity will clarify the matter.
Fig. 5-1: Measuring ternary solutions based on density and sound velocity
XDLIE005EN-K 5. Density and Sound Velocity Meters 61/186

5.2 What Are Density and Sound Velocity Meters?
Anton Paar´s density and sound velocity meters are the only laboratory instruments that determine
the two physically independent properties density and sound velocity simultaneously within one
measuring cycle. The two-in-one instruments are equipped with a density cell and a sound velocity
cell thus combining the proven Anton Paar oscillating U-tube method with a highly accurate
measurement of sound velocity.
Both cells are temperature-controlled by a built-in Peltier thermostat. Density and sound velocity,
and their derived values are used as input for various concentration calculation models that are
integrated in these instruments.
DSA 5000 M Soft Drink Analyzer M

Depending on the The Soft Drink
concentration range of Analyzer M is the
the sulfuric acid/oleum, only instrument on
results are calculated the market
either based on the combining density
sound velocity or and sound
density of the sample. velocity
Therefore, DSA 5000 M measurements to
measures both deliver precise
parameters in one cycle results for fresh
and applies the method and inverted sugar concentration.
with the highest accuracy to calculate the A true picture of the state of sugar inversion is
results. provided within a few minutes
Further, the composition of three-component-
solutions can be determined using the two
measured parameters
5.3 How Is Sound Velocity Measured?
The sample is introduced into the sound velocity measuring cell that is bordered by an ultrasonic
transmitter on the one side and by a receiver on the other side (see fig. 5-2).
The transmitter sends sound waves of a known period
through the sample. The velocity of sound can be
calculated by determining the period of received sound
waves and by considering the distance between the
transmitter and receiver. Due to the high temperature
dependency of the density and velocity of sound values, the
measuring cells have to be temperature-controlled
precisely.
Fig. 5-2: Measuring cells in DSA 5000 M and Soft Drink Analyzer M
62/186 5. Density and Sound Velocity Meters XDLIE005EN-K

Did you know?
Due to the installation of both measuring cells in one single Peltier-controlled block,
these instruments guarantee the highest possible accuracies, as the sample´s
condition is equally the same and constant all over the sample´s volume.
5.4 DSA 5000 M
The integration of both density and sound velocity

measurement in one instrument opens a new dimension in
analysis and quality control of fluids. The most common
applications of that instrument are:
• Analysis of three-component solutions
• Purity checks on two-component solutions
• Product identification
• General fluid research
This instrument enhances laboratory quality control of liquids
in two distinct ways. First, it can accurately analyze the percent concentrations of each
component in a three-component solution. Secondly, it significantly reduces the margin of error
in checking the purity and the concentration of two-component solutions.
5.4.1 How to use DSA 5000 M

There are two different ways for filling a sample into the measuring cell:
• For measuring non-corrosive samples – if the necessary amount of sample is not a knock-out
criterion – DSA 5000 M can be operated with semi-automatic and fully automatic Xsample™
sampling units, such as the Xsample™ 320 or 340 sample handling unit or the Xsample™
520 or 530 sample changer (please refer to section 10.). Xsample™ 320 and Xsample™ 520
can also be upgraded with chemical resistant hoses and needle.
• Filling using a syringe (see fig. 5-3), requires less sample.
Fig. 5-3: Filling sample into DSA 5000 M with a syringe

NOTICE – To make sure that air bubbles leave the measuring cells when filling the sample, always
connect the syringe to the lower adapter (sound velocity cell) and connect the waste hose to the
upper adapter.
Filling adapters
1 ...Injection adapter DSA (sample inlet)
2 ...Injection adapter Luer (sample outlet)
3 ...Connection between sound velocity measuring cell and density measuring cell
Did you know?

…how a leak tightness test of the filling adapters is performed?
• Close the outlet adapter or the connected waste hose tightly with a finger and fill air
through the inlet adapter using a 5 mL plastic syringe.
• Release the plunger of the syringe.
If the connections are leak tight, the plunger of the syringe will be slowly pushed back
by the pressure in the measuring cell(s).
The operation of DSA 5000 M is exactly the same as described for DMA™ Generation M density
meters in section 4.7.1. The few exceptions are as follows:
• only 5 measuring methods are predefined
• API functions are not available
• the pressure is limited to 8 bar

Most of the features from DMA™ Generation M are also available with DSA 5000 M (see
section 4.7.2 for details):
• 10.4" PCAP touchscreen
• FillingCheck™, U-View™ and ThermoBalance™
• Accurate temperature control and viscosity correction
• Automatic air adjustments

• User-friendliness
• Modular concept
• Complete QM compliance
• Compact and robust design
• Usage of measuring methods
• Convenient data handling of up to 1000 results
5.4.3 Optional Accessories

DSA 5000 M can be combined with either Xsample™ 320, Xsample™ 520, Xsample™ 340 or
Xsample™ 530 offering different levels of automation (please refer to section 10.).
DSA 5000 M provides the same interfaces as DMA™ Generation M, hence providing the same
possibilities for keyboard, mouse, bar code reader, gesture control, external touch screen, data
projector and printers as well as drying cartridge and cooling kit. Also the same protecting covers are
available (please refer to section 4.7.3).
5.4.4 What Is So Special About DSA 5000 M

Most of the specifications from DMA™ 5000 M (section 4.7.4) are also available for DSA 5000 M:
Precision class, high viscosity adjustment, features, etc.
DSA 5000 M
Application-dependent, typically 0.01 to 0.1% of the determined
Accuracy
concentration
Density: 0.000001 g/cm³
Repeatability, s.d.
Sound velocity: 0.1 m/s
Density: 0 to 3 g/cm³
Measuring range Sound velocity: 1000 to 2000 m/s
Temperature: 0 to 100 °C (32 to 212 °F)
Target group Chemical industries, universities, pharmaceutical industries
For details, please refer to section 4.7.5.
5.4.5 DSA 5000 M – Market Information
Consider that due to the sound velocity measuring cell, there are – compared to DMA™ Generation
M – two more material in contact with the sample (borosilicate glass: measuring cell, PTFE: filling
adapters + stainless steel DIN 1.4539/UNS N08904: sound velocity cell + solder HTL 5 CR: sound
velocity cell). Please check prior measurement for their chemical resistance which is (in case of
acids) highly temperature-dependent. If chemical resistance of the wetted parts is guaranteed, any
homogeneous samples (no air bubbles or particles) can be measured in its liquid phase.

In section 5.1 you already got an idea of why people measure density and sound velocity
simultaneously. See below some examples for applications in which a DSA 5000 M could be
interesting.
• Double safety for two-component solutions:
An interesting application of combined density and sound velocity measurements is in the field of
product identification. Since all possible combinations of measured density and sound velocity for
pure two-component solutions have to be on distinctive curves, product identification becomes much
safer by applying this method.
• Identify three-component solutions:
This second application is especially important in the production of basic chemicals. Many basic
chemicals are produced through the conversion of one raw material to a final product, where not all
of the raw material is actually converted. As typical examples, methanol converts to formaldehyde
and sodium chloride converts to sodium hydroxide.
Further example applications include the production of phosphoric acid, plastics, fertilizers, water
glass and several other 3-component solutions. R&D applications include investigations into phase
transitions (e.g. lipids, polysaccarides, proteins, insulin, etc.)
• Sulfuric Acid and Oleum
100% sulfuric acid (H2SO4) is a colorless and odorless oily liquid which is highly hygroscopic.
Dissolving sulfur trioxide (SO3) in 100% sulfuric acid results in a fuming solution called oleum.
Sulfuric acid and oleum cause very strong reactions: They destroy all kinds of tissue and fabric on
contact. Diluting with water must be performed with caution as the extremely exothermal
reaction generates a large amount of heat.
Did you know?

When handling sulfuric acid, oleum or other strong acids always remember the
sentence you maybe already have heard in your chemistry classes in school:
"Always do things as you oughta, add the acid to the water!"
DSA 5000 M determines the concentration of sulfuric acid and oleum across the whole concentration
range. The benefits speak for themselves: sample does not need to be diluted before
measurement and the result is ready after only two minutes.
Depending on the concentration range of the sulfuric acid/oleum, precise results are provided by
measuring either the sound velocity or density of the sample. Therefore, DSA 5000 M measures
both the sound velocity and density in one cycle and applies the method with the highest accuracy
to calculate the results.
Sulfuric acid is widely used in the organic chemical industry, such as the plastics industry and
petrochemistry, in the production of phosphoric acid and fertilizers, and also in other industries, e.g.
with metallic mordants or accumulators.

Fig. 5-4: Density and sound velocity curve of sulfuric acid and oleum
Due to the fact that the density curve of sulfuric acid is very unstable in certain concentration ranges,
sound velocity is used instead to determine the concentration. fig. 5-4 shows what measuring
principle is used in what concentration range of sulfuric acid and oleum.
Between 90 and 100% the density curve becomes very flat, making it impossible to determine the
correct concentration based on density. At the same time the sound velocity curve is very steep in
this range. Therefore, sound velocity is used for concentration determination. The same applies for
the range of 47 to 65% oleum. See the table below for details.
Temperature Density Sound velocity

20 °C 0 – 87% H2SO4 87 – 100% H2SO4
0 – 27% free SO3
40 °C 0 – 90% H2SO4 90 – 100% H2SO4
0 – 47% free SO3 47 – 65% free SO3
Several companies from chemical industries have used the DSA 5000 M successfully for years,
when …
• producing H2SO4: DOW, BASF, PVS Chemicals, Degussa
• developing new substances or researching their behaviors: universities, Akzo Nobel, DuPont
• conducting general chemical applications: Hewlett Packard, Seiko Epson, Toshiba

Always keep in mind that there are always several opportunities for optional accessories to adapt the
DSA 5000 M to the customer´s needs and measurement processes in the best way.
• Either Xsample™ 320, Xsample™ 520, Xsample™ 530 or Xsample™ 340 might be used for
measurements of non-corrosive samples.
• To perform measurements at temperatures lower than 20 °C (36 °F) below ambient temperature,
the cooling kit can be ordered pre-installed ex works to remove heat from the pelitier elements by
means of an external thermostat or tap water.

• The main potential for further sales addresses different measuring units:
- Please refer to the corresponding chapters for modular extension modules (ME)
determining parameters like pH, viscosity or nD.
- Furthermore, a variety of related products may be of interest for a potential customer, e.g.
online density and sound velocity sensors for process applications.
- Drying cartridge for humid environments and / or low measuring temperatures
5.4.5.3 Competition
There is not any comparable instrument available on the market.

1. Why isn’t density alone used for concentration determination of sulfuric acid over the whole
concentration range?
a. The sound velocity values are more stable than density over the whole concentration range
b. The density curve is very flat in certain concentration ranges
c. In some concentration ranges the sound velocity changes more than density
d. Sulfuric acid has no density value.
2. Can all the sample changers from Anton Paar be used with DSA 5000 M? If no, which one would
you use?
□ Yes □ Xsample™ 320
□ No □ Xsample™ 520
□ Xsample™ 330
□ Xsample™ 630
□ Xsample™ 530
□ Xsample™ 340
3. Name the two possible cross selling possibilities for chemical industries and projects at
universities.
______________________________________________________________________________
______________________________________________________________________________
4. What two measuring principles are used by DSA 5000 M?

______________________________________________________________________________
______________________________________________________________________________

5.5 Soft Drink Analyzer M
Anton Paar's method for determining sugar inversion based

on density and sound velocity measurement suits all types of
liquids. Whether measuring a highly concentrated syrup or the
finished soft drink product, Soft Drink Analyzer M provides
precise information about the true sugar content before,
during and after the inevitable inversion process.
The Soft Drink Analyzer M determines the fresh, actual and
fully inverted sugar content of soft drinks, syrups and
HFCS (high fructose corn syrup) samples within a few
minutes. No ageing of the sample and no forced inversion
are required. Instead, a true picture of the state of sugar
inversion is provided by measuring both the density and
sound velocity of the partially inverted sample.
The sample to be measured is usually filled automatically by combining the Soft Drink Analyzer M
with the sample changer Xsample™ 520 or with a high-pressure filling device (the PFD Piercing and
Filling Device) and a CO2 measuring module (the CarboQC ME) to the measuring system PBA-SI
(see section 11.2.2.3).
5.5.1 How to Use Soft Drink Analyzer M

Sample Preparation
Degassing to remove dissolved CO2 is the only sample preparation required, but only necessary if
Soft Drink Analyzer M is used as a stand-alone or in combination with an Xsample™ 520 sample
changer. In combination with a PBA-SI (Packaged Beverage Analyzer for Soft Drinks with Inversion),
the influence of CO2 on the various measurements is automatically corrected.
There are different methods for the degassing of liquid samples. The preferable method for your
application depends on the kind of sample and the amount of gas that is dissolved in the sample.
Always take care that you treat all samples in the same way in order to get reproducible measuring
results.
Degassing of samples can be achieved by boiling or stirring the sample or when using an
ultrasonic bath.
Sample Filling
There are three different ways for filling a sample into the measuring cell:
• Semiautomatic and fully automatic Xsample™ sampling units, such as the Xsample™ 320
sample handling unit or the Xsample™ 520 sample changer (see section 10.4.1 and
section 4.6.3)

• Filling using a syringe, see fig. 5-5.
Fig. 5-5: Filling via syringe
• Directly from the sample package using a PFD (PBA-SI/-SID Gen. M System)
Operation
The operation of Soft Drink Analyzer M is exactly the same as described for DMA™ Generation M
density meters in section 4.7.1. The few exceptions are mentioned accordingly:
• API functions and Acid/Base tables are not available
• The measuring temperature is 20 °C only
.
Fig. 5-6: Main scren example Soft Drink Analyzer M
5.5.2 How Does Soft Drink Analyzer M Work?

Using two physical properties of sucrose solutions, density and sound velocity, Anton Paar has
developed a sugar inversion algorithm to automatically calculate current, fresh and inverted sugar
concentration for soft drinks and syrups of any concentration in the range of 0 to 80 ° Brix.
Soft Drink Analyzer M simultaneously measures the density and sound velocity (1) values of the
sample. The result ('current') lies between the density and sound velocity values of solutions with 0 %
inversion (sucrose) and 100% inversion (invert sugar).

Using these two measured values and the known course of inversion over time in the sound velocity
and density chart, fresh and inverted sugar concentration (2) are calculated automatically, see
fig. 5-7.
Fig. 5-7: Measuring Brix actual, fresh and inverted with Soft Drink Analyzer M
During storage, sucrose solutions undergo a slow conversion into a 1:1 mixture of glucose and
fructose. This process, called "sugar inversion", is enhanced through
• the presence of acids (contained in cola and most other beverages) and
• elevated temperatures.
It affects concentrate as well as finished products. The 1:1 mixture of glucose and fructose is called
"invert sugar". The density of the liquid increases during this process and therefore no longer gives
precise information about the sucrose content of the original liquid.
To guarantee constant product quality, the recipe for a specific product must be adhered to very
strictly. The recipe is either based on sucrose concentration in the fresh product or on sugar
concentration in the inverted product. For soft drink producers it is therefore important to know
the °Brix of samples during production to calculate the correct concentrate/water mixing ratio.

Most of the features from DMA™ Generation M (see section 4.7.2) are also available with Soft Drink
Analyzer M.
For the Soft Drink Analyzer M the modular concept is limited to combination with the HazeQC ME,
DietQC™ ME, Xsample™ 320, Xsample™ 520, PFD (Plus), CarboQC ME (+ O2) and pH ME.
5.5.4 Optional Accessories

Xsample™ 320 and Xsample™ 520 offer different levels of automation (see section 10.).
business as much as possible.
The same interfaces are used in Soft Drink Analyzer M as with DMA™ Generation M, hence
providing the same possibilities for keyboard, mouse, barcode reader, external touch screen, data
projector and printers as well as the drying cartridge. Also the same protecting covers and foils are
available (please refer to section 4.7.3)

5.5.5 What Is So Special About Soft Drink Analyzer M?
Most of the features from DMA™ Generation M are also available with the Soft Drink Analyzer M (see
section 4.7.2 for details on the stated features):
• FillingCheck™ and U-View™
• Automatic air adjustments
• Accurate temperature and viscosity correction
• User-friendliness
• Modular concept (the modular concept is limited to Xsample™ 320, Xsample™ 520,
PFD (Plus), CarboQC ME (+ O2), pH ME, the HazeQC ME and DietQC™ ME.
• Complete QM compliance
• Compact and robust design
• Usage of up to 400 measuring methods
• Convenient data handling of up to 1000 results
Due to the beverage industry´s demands, the measuring temperature is 20 °C and cannot be
changed within a supported range.
Soft Drink Analyzer M

Repeatability, s.d. Density: 0.000001 g/cm³
Current sugar concentration: 0.01 °Brix
Fresh/inverted sugar concentration: 0.02 °Brix
Degree of inversion: 1%
Measuring range Density: 0 to 3 g/cm³
Current/fresh/inverted sugar concentration: 0 to 80 °Brix
Temperature: 20 °C (68 °F)
Target group Soft drink bottlers using sucrose or sucrose/HFCS mixtures as
starting material
Invert sugar manufacturers and users
5.5.6 Soft Drink Analyzer M – Market Information
• Soft drinks and syrups based on sucrose or sucrose/HFCS mixtures:
Most soft drinks are produced from concentrate, water and carbon dioxide. An important quality
control parameter during production is the density of the concentrate and the finished beverage,
mainly reflecting the sucrose concentration (Brix content).
• Measure additional parameters
The PBA-SI/SID Generation M (Packaged Beverage Analyzer for Soft Drinks with Inversion) is an
analysis system for the determination of CO2-corrected sugar concentration values (see
section 11.2.2.3).
You can use Soft Drink Analyzer M:
- for manual or (semi)-automatic filling of soft drink, syrup or HFCS samples
- for combination to a PBA-SI/SID Generation M system

Always keep in mind that even if the customer is only interested in density and sound velocity
measurements, there are several opportunities for optional accessories: Either Xsample™ 320 or
Xsample™ 520 might be used for measurements of non-corrosive samples.
The main potential for further sales addresses different measuring units:
• Please refer to the corresponding chapters for modular extensions (ME) determining parameters
like CO2, O2, Diet or pH.
• Furthermore, a variety of related products may be of interest for a potential customer, e.g. online
density and sound velocity sensors for process applications.
5.5.6.3 Competition
With the Soft Drink Analyzer M you have to compete against the traditional manual forced inversion
method only.

1. At what temperature are measurements with Soft Drink Analyzer M performed?
______ °C
2. Explain the process of sugar inversion and how Soft Drink Analyzer M is able to measure it.
The process of sugar inversion describes changes of _______________________ in the original soft
drink which splits up into _________________ and ____________________. Using two measuring
parameters – _________________ and _________________ – it is possible to determine the stage
of that process as well as the original and the fully _______________ sugar content.

6. Alcohol Meters
Anton Paar has the optimal solution for lab analytics in all alcohol producing organizations – be it
a brewery, a winery or distillery; be it a craft producer or industrial producer. Due to the different
sample constituents, different measuring technologies apply for analysis of different alcoholic
beverages. Furthermore, depending on the size and available budget of our potential customer,
different solutions in different price and functionality classes are available. Learn more in the
following chapter.
6.1 Alcohol in Beverages
An alcoholic beverage is a drink containing ethanol (commonly called alcohol). Alcoholic

beverages are divided into three general classes: beers, wines, and spirits. They are legally
consumed in most countries, and over 100 countries have laws regulating their production, sale and
consumption 1 .
Simple, fast and accurate determination of the alcohol content of alcoholic beverages is very
important for their making, blending, trading and labeling.
The knowledge of the alcohol content is necessary to ensure that the beverage conforms to the label
declaration of alcohol content and to establish the basis for the payment of tax.
Did you know?

Beer is the world's oldest and most widely consumed alcoholic beverage and the third
most popular drink overall after water and tea. It is produced by the brewing and
fermentation of starches which are mainly derived from cereal grains — most
commonly malted barley although wheat, maize (corn), and rice are also used.
Wine is produced from grapes. Wine involves a longer (complete) fermentation
process and a long aging process (months or years) that results in an alcohol content
of 9 % to 16 % vol. Sparkling wine can be made by adding a small amount of sugar
before bottling, which causes a secondary fermentation to occur in the bottle.
Unsweetened, distilled, alcoholic beverages that have an alcohol content of at least
20 %v/v are called spirits. Spirits are produced by the distillation of a fermented base
product. Distilling concentrates the alcohol and eliminates some of the aromatic
compounds.
6.2 Snap Portable Alcohol Meters for Distilled Spirits
Our series of Portable Alcohol Meters for distilled spirits, the ‘Snap’ instrument family, allow the
measurement of the alcohol content of distilled spirits directly on site and out of the sample
container. Both instruments, Snap 41 and Snap 51, cover the measuring range from 0 %v/v to
100 %v/v alcohol, which means, that you can measure all samples in the distillery with one and the
same instrument: pure distilled spirits directly after distillation, samples during blending with water,
and ready-to-drink spirits. The Snap alcohol meters therefore replace all glass hydrometers in the
craft distillery.
1 Source: http://en.wikipedia.org/wiki/Alcoholic_beverage - cite_note-icap-0
74/186 6. Alcohol Meters XDLIE005EN-K

Both instruments show the measured result in %v/v (compensated to 15 °C) or °Proof (compensated
to 60 °F), so there is no need for any further calculations or manual compensation of the measured
result with help of a temperature correction table (as compared to a hydrometer). The user just reads
off the result from the big screen.
Fig. 6-1: Snap 41 (left picture) and Snap 51 (right picture) Portable Alcohol Meters
6.2.1 Measuring Principle

Snap 41 and Snap 51 are actually both density meters, working according to the oscillating U-tube
principle, but are branded as alcohol meters and solely sold for the application of alcohol
concentration measurement in the distillery. The oscillating U-tube of Snap 41 is made of borosilicate
glass, whereas the measuring cell of Snap 51 is made of Inconel, hidden within the long metal tube.
6.2.2 How to Use Snap 41 and Snap 51

Both, Snap 41 and Snap 51 use a built-in pump to suck the sample into the measuring cell.
When measuring with a Snap 41, the measured result can now be read directly from the screen. The
Snap 41 does not provide any possibility to store, print, or export results.
When measuring with Snap 51, the metal tube stays immersed into the sample to at least one third
(see lower marker on the metal tube of the instrument and see instruction manual for details). As the
oscillator is located in this area, this procedure provides the best possible temperature equilibrium
within the measuring cell and therefore the best possible accuracy of the result. If samples at low
concentrations and at low temperatures are to be measured, make sure to immerse the instrument
to the second marking to guarantee the accuracy of measured results. Snap 51 provides storage,
printout and export of data, as well as an RFID interface to automatically identify samples within
seconds. With Snap 51 users can also print data or export them to a PC via Bluetooth®.
TIP – To ensure the accuracy of the result as stated within specifications, always start a
measurement on the instrument (via the Quick Access menu in Snap 41 or the store key on Snap 51,
respectively via gesture control) to ensure that the stability criterion is activated.
XDLIE005EN-K 6. Alcohol Meters 75/186

6.2.3 What are the Differences between Snap 41 and Snap 51?
Specification/Feature Snap 41 Snap 51

Accuracy alcohol 0.2 %v/v 0.1 %v/v
Temperature range 5 to 30 °C 0 to 40 °C
(ambient temp +/- 5 °C)
Measuring cell material Glass Inconel
Measuring units Only alcohol Additionally sugar, density,
(%v/v and °Proof) custom functions
Storage of results No Yes, 1024
Export/print of results No Yes, both via Bluetooth®
RFID interface No sample identification at all Yes
International list price 60% of Snap 51 See price list

Snap 41 and Snap 51 are unique on the market, as there are no other
portable alcohol meters available offering a comparable accuracy at a
comparable price. However, we are competing against traditional
measuring methods, like the glass hydrometer. Therefore, the following
table shows our selling arguments against the glass hydrometer. Those
actually have only one advantage over the Snap instrument series,
which is the purchasing price. What the operation of a glass
hydrometer is like is also stated in the table and gives you the relevant
background information to our selling arguments.
Keywords Customer benefit Snap 41 & 51 What is it like with a glass

hydrometer?
On-site use The measurement is performed Sample (approx. 200 to 300 mL)
directly out of the sample container needs to be poured into a
using 2 mL of sample. measuring cylinder. The
hydrometer is inserted and needs
to stabilize before the result is read
from the scale.
Quick The measurement – including filling Pouring the sample into a cylinder
measurement and cleaning – is done in less than + waiting for stabilization of
a minute. hydrometer + consulting the
temperature correction table +
pouring sample back + cleaning =
10 minutes

Keywords Customer benefit Snap 41 & 51 What is it like with a glass
hydrometer?
One instrument for The Snap instrument family A hydrometer in this accuracy
distilled spirits of measures distilled spirits of all range has a measuring range of
all strengths strengths – from pure to ready-to- only 5 to 10 %v/v. Therefore, to
drink spirits (0 to 100 %v/v). cover the whole relevant measuring
Further, with Snap 51 the sugar range, more hydrometers (typically
concentration in fruit juices and 3-5) need to be used in a distillery.
must can be measured. Also for measuring °Brix,
customers would require an
additional hydrometer.
Automatic The alcohol content at a reference The temperature has to be
temperature temperature (20 °C, 15 °C or 60 °F) determined separately. A
compensation is automatically calculated and temperature correction table is
displayed consulted to get the measured
Explicit and The measuring method is well alcohol value compensated to the
trustworthy proven and reliable, as the market respective reference temperature.
results: No user leader Anton Paar has 50 years of This bears the risk of reading &
influence in experience in density meters based calculation errors by the user.
reading results on the oscillating U-tube principle.
Robust design Snap 41 │ Snap 51 are both splash Glass hydrometers break easily
proof and have low maintenance and are therefore typically replaced
costs. Snap 51 has a metal regularly.
oscillator, whereas Snap 41 has a
special rubber protection for its
glass measuring cell included in
scope of supply. Additional
protection like carrying straps and a
rubber housing for the operating
panel is available. Both instruments
are operated via capacitive keys
and the display of Snap 51 is even
protected by a hard-glass front.
Clearly defined The user can easily follow the There are no general ‘rules’ on how
working routines: predefined calibration routine, done to operate a glass hydrometer (e.g.
no chance for with deionized water. Results are whether to read the scale when
errors clearly shown on the big screen. looking at it from the bottom or
Measurements can even simply be straight) and therefore different
started via a gesture while using users might get different results.
the other hand to note down results
or hold steady when measuring
difficult to reach samples.
Traceability Sample identification via RFID and The result is read from the scale
storage and export or printouts of and corrected and written down
results via Bluetooth® ensure manually. No identification of
perfect documentation and samples, no storage of results.
traceability of results
(Snap 51 only!).

To summarize all those arguments: The investment for a Snap 41 or Snap 51 pays off very quickly
(good Return on Investment).
6.2.5 Snap – Market Information
6.2.5.1 Applications / Customers

The target groups of Snap 51 are
• Microdistilleries with the demand for a high measuring accuracy, who use the instrument as a
replacement of their glass hydrometers
• Industrial spirits producers or pharmaceutical companies who already have a highly
sophisticated measuring solution available in their lab and require an additional portable
instrument for quick checks on site.
• Producers of cleaning liquids that can be considered as ethanol-water solutions
• Customs offices, treasury department - under reserve, as they usually require type approval,
which Snap 51 does not provide.
The main target groups of the Snap 41 are hobby distillers and very small microdistilleries with a very
limited budget, who use the instrument as a replacement for their set of glass hydrometers.
6.2.5.2 Competition
The main competitor of Snap 41 and Snap 51 is the glass hydrometer. See section 6.2.2 for details
on glass hydrometers and information on how to sell against them.
Portable density meters

Portable density meters like the Mettler Densito 30PX or the KEM DA-130N (see section 4.5.6.3 for
details) have an accuracy of only 0.5 %v/v alcohol (or 0.001 g/cm3) which is usually too inaccurate
for the demands of spirits manufacturers.
3-digit benchtop density meters
3-digit benchtop instruments like Mettler Toledo DA-100M and KEM DA-100 (see section 4.6.4 for
details), are on the one hand too inaccurate for alcohol measurements (3-digits density correspond
to 0.5 %v/v). At the same time they are considered to be too expensive for the main target group of
small and mid-sized distilleries.
4-digit (and better) benchtop density meters
This group of density meters is of course suitable for the target group from the accuracy point of view,
but are completely out of range concerning the price and not affordable – at least not for the main
target group of small and mid-sized distilleries. Many industrial spirits producers might also already
have a sophisticated benchtop density meter in the lab. For those, the Snap 51 is the perfect
supplement for quick on-site checks. Instruments in this accuracy range are the Rudolph DDM291x
series, KEM DA6xx series or Mettler DMxx series (see section 4.7.6.3 for details).

1. Snap family: Find the correct ending for each sentence.
A The measuring cell of Snap 41 □ is made of Inconel.
B The measuring cell of Snap 51 □ sample IDs via RFID.
the alcohol content in distilled

C With Snap 41, you □ spirits of all strengths can be
measured.
D With Snap 51, customers □ is made of borosilicate glass.
E Snap 51 can identify □ can also measure

content in juice.
the sugar
F With both, Snap 41 and Snap 51 □ cannot store, export or print results.
6.3 Alex 500 Alcohol and Extract Meter
Alex 500 is a compact Alcohol and Extract meter for

small to mid-sized breweries, wineries, cider and
sake producers. The accuracy of the determined
results is 0.2 %v/v for alcohol and 0.001 g/cm3 for
density results.
Alex 500 enables our customers to monitor their
entire production from the raw product (beer wort,
apple or grape juice) to the bottle and provides them
with independence from external organizations, now
capable to perform their analyses on their own and
under their own roof. Furthermore, a regular check
with the alcohol and extract meter provides them the
security that the correct values are printed on the
bottle.
6.3.1 Measuring Principle

Alex 500 uses a combination of two different measuring principles: density and NIR (Near Infrared)
for determination of the alcohol and extract in beer and wine.
A Near Infrared (NIR) light source emits light at three different wavelengths whereas the detector
measures how much light is absorbed by the sample. Due to the three different wavelengths, three
different absorption parameters at three different wavelengths are determined.

Simultaneously, the density of the sample is determined based on the oscillating U-tube principle.
Based on the four raw data values (3 absorption values plus density) a statistical model is used to
determine the alcohol and extract content of the sample.
Each measuring method on the instrument uses its own
statistical model for calculation of the measured results.
For the beer methods, around 80 different beer types have
been analyzed and used as a basis for the statistical
model, for the red wine method an according number of
red wines, etc. Due to the sample-specific methods, it
is not possible to measure any other alcoholic
beverages than stated in the product description (e.g.
measurement of alcopops, kombucha, spirits, etc. is not
possible with Alex 500).
6.3.2 How to Use Alex 500

Alex 500 provides two different operation modes:
• In the fermentation monitor mode brewers can check the
extract content in wort and winemakers and cider producers the
sugar content in their juice. After the fermentation started, a daily
fermentation control is performed to check whether the
fermentation proceeds as expected. Alex 500 displays the
fermentation curve for each tank, assigned to the tank via a
sample ID which is selected before the measurement. In the
fermentation monitor mode only the density is used to calculate
the apparent extract / apparent sugar content of the sample.
• Towards the end of fermentation Alex 500 is switched to the

standard mode,
• to determine the alcohol, real/apparent extract, degree of
fermentation, calories and more specific parameters in beer.
The measuring range for beer is 0.5 %v/v to 15 %v/v.
• to determine the alcohol and total extract content in wine. The
measuring range for wine is 8 %v/v to 20 %v/v.
• to determine the alcohol and total extract content in cider. The
measuring range for cider is 2 %v/v to 10 %v/v.
• to determine the alcohol and extract content in Sake. The measuring range for sake is 5 %v/v
to 20 %v/v.


Two measuring modes: Alex 500 provides our customers certainty from the raw
Fermentation monitor mode & product (wort/ juice) to the bottle, meaning that one instrument
standard mode can be used to monitor the quality during the whole
production process. In the fermentation monitor mode the
extract or sugar content is determined, followed by a precise
fermentation control. As soon as the fermentation is almost
done, Alex 500 determines alcohol and extract within the
wine, beer, cider or sake to ensure correct labeling and
payment of taxes.
Peristaltic pump by default The instrument provides automatic filling via a peristaltic
pump by default, to standardize the filling procedure and
eliminate the potential error caused by wrong sample
handling and filling. Filling via the peristaltic pump provides
the maximum user-support, as well as accuracy and
repeatability of results.
Adjustment with water only Deionized water is enough to check whether Alex 500 still
measures according to specifications or needs a
readjustment. Furthermore a readjustment is done with
deionized water only. Comparable instruments on the market
(available for beer only) need a sample specific adjustment for
each beer type being measured.
Storage of data, wireless Handwritten notes are a thing of the past. Alex 500 stores all
printouts & easy export of measured data in the internal memory and makes them
data to a PC available for export to a PC or wireless printouts on a
Bluetooth printer. This saves time and enables a perfectly
traceable quality control during the entire production.
6.3.4 Alex 500 – Market Information
6.3.4.1 Target Groups

The main target groups of Alex 500 are:
• Craft brewers: Craft breweries are small breweries producing very creative beer styles. Craft
brewers create their own new recipes, give old traditional recipes a new modern touch, or
experiment with fruit or flavor additions. The quality and amount of raw material used (e.g. hops)
is usually far higher than compared to an industrial brewery. The Anton Paar internal definition in
terms of size is a maximum production amount of 50,000 hl/year.
• Small to mid-sized wineries & winemaking cooperatives: The definition of a typical ‘small to
mid-sized’ winery is far more difficult than it is for the brewery. There are many small producers,
focusing on premium wine, which could achieve the same financial situation as a bigger winery
producing a wine with average quality. Many small vineyard owners involve a winemaking
cooperative in wine production, meaning that the grapes are delivered to the cooperative, where
all the production, quality control, bottling and marketing is organized. Therefore not only the
winery itself, but also winemaking cooperatives are a main target group of Alex 500.

• Craft cider producers: Many craft breweries also produce their own cider and can use one and
the same instrument for both applications. Cider is very popular, especially in Skandnavian
countries, Germany or Australia. Craft ciders are often cloudy, so make sure to recommend the
proper sample preparation.
• Sake producers: Sake is a Japanese rice wine, that is made from fermenting rice. In Japan,
officially accepted measuring methods during Sake production are clearly defined (distillation +
4-digit density measurement or Alcolyzer Sake M). Therefore, Alex 500 is positioned as
instrument for quick checks along the production process and not for official measurements on
sake.
• Industrial breweries and big wineries: Customers producing on a large scale usually have
already a lab in place where sophisticated lab instruments are used for quality control.
Nevertheless, some of them are interested to use Alex 500 as a supplement to their existing
sophisticated measuring solutions, e.g. for quick checks in their storage facilities.
6.3.4.2 Competition
Company Instrument Measuring Additional information / weak

principle points
• More hydrometers are required to
cover the whole relevant
measuring range for wort / grape
Hydrometer juice
• No determination of alcohol and
extract (only calculation /
Various measurement of apparent
Gravimetric
manufacturers extract/sugar possible)
• No automatic documentation of
data
• No temperature compensation or
temperature control
• High potential for errors and user
influence on the result
ALCOQUICK • Density measurement optional
4000 • Claim 0,1 %v/v ? not proven!
• Available as lab version or
portable version
Unisensor • More focussing on wine
Near Infrared
http://www.unisen (according to brochure) but claim
Transmittance
sor.de/ to measure also beer & spirits
(measuring range 5 to 18 %v/v)
• Narrow temperature range (15 to
25 °C)
• Higher price as Alex 500

Competitor in the beer segment only:
Company Instrument Measuring Additional information / weak

principle points
• Product-specific calibrations with
reference beers are necessary!
• Only suitable for breweries with
constant beer assortment (no
Thermo-
flexibility regarding measurement
Funke analytical
of newly created beer styles due
Gerber measurement
to necessary reference
www.funke- methods
calibration.)
gerber.de combined with
• Export/printing only possible via
mathematical
RS232/parallel interface
algorithms
FermentoFlash • No storage of data
• No fermentation control
• Price: approx. one third of Alex
500
• wet chemical sample preparation
(costy consumables to be
purchased for daily analysis)
• no fermentation monitor mode
available (no continuous
fermentation monitoring)
• does not provide standard quality
Spectroscopic
parameters for beer (Original
analysis after
Extract, Real Extract,...)
wet-chemical
• each analysis just provides 1
sample
parameter
preparation
• potential influence of user
+ capability of
CDR interaction
measuring many
• time consuming analysis and
BeerLab Touch different
sample preparation (takes more
parameters, like
than twice the time compared to
e.g. bitterness,
Alex 500)
total acids, pH,
• 4 times more analysis steps
color, etc.
required
• See the competition information

on CDR BeerLab (XDLIE039EN-
A) available on the Extranet, for
more details.

1. Alex 500: True or false?
True False
Alex 500 can measure alcohol-free beers.
□ □
Alex 500 helps brewers and winemakers with their fermentation control, by
drawing fermentation charts. □ □
Alex 500 is adjusted with deionized water.
□ □
Alex 500 can measure the alcohol and extract content in all different types of
alcoholic beverages (e.g. spirits, alcopops). □ □
2. What measuring technologies and parameters is Alex 500 based on? Tick the correct answers!
□ Sound velocity
□ Near Infrared
□ Microwave
□ Density
□ Optical rotation
□ Refractive index
6.4 Alcolyzer M/ME
Our Alcolyzers determine the alcohol content of alcoholic beverages based on the near infrared
absorption method. Different instrument versions, considering the special ingredients of the samples
to be measured – be it beer, wine or spirits – are tailored to the needs of the respective customer
segment. Read more in the following chapter.
6.4.1 What Is an Alcolyzer

The Alcolyzer is a laboratory device to determine the alcohol content of beverages.
It uses a patented method (US 6,690,015; AT 406711) based on Near Infrared Spectroscopy to
determine the alcohol content in a highly alcohol-specific range. For this reason, the other
constituents of the beverage do not influence the result. This means the determination of various
products can all be done with one 2-point adjustment!

6.4.2 Alcolyzer Measuring Principle
Do the eLearning course "Basics of Optical Analysis"!

Please find the eLearning course on the Extranet.
Fig. 6-2: Measuring principle of Anton Paar Alcolyzers
A near infrared light beam is sent through a cuvette filled with the sample (see fig. 6-2). Depending
on the alcohol content of the sample, a certain amount of the light intensity is absorbed. The more
alcohol there is in the sample, the higher the absorption.
A highly alcohol-specific range of the NIR spectrum was identified between 1170 and 1200 nm. The
evaluation method uses the significant alcohol peak in this area and two spectral points very
close to it for defining the baseline. The alcohol results based on this type of evaluation are virtually
free of influences from other known sample constituents. This allows adjustments to be done
simply with water for the zero point and one binary ethanol-water mixture.
The Alcolyzers utilize an optical set-up without any moving parts. The instrument consists of a Near
Infrared Light Emitting Diode, a condenser lens, a sample cell, a collimator lens to focus the parallel
beam and a grating spectrometer with a detector array. The absorption information read by the
detector array is used to determine the alcohol content of the sample.
Optional color measurement: The color value is determined by the measurement of light
absorption and is mainly dedicated to the measurement of beer color. The absorption is measured
at a wavelength of 430nm which complies with established standards in the beer industry such as
the EBC, MEBAK and ASBC.

As there are very different types or alcohol-containing beverages on the market, Anton Paar offers
different versions of Alcolyzer, depending on the application:
Alcolyzer Type Description Application

Alcolyzer Wine M/ME Alcolyzer Wine M determines the
alcohol content of wine in the
concentration range of 0 – 20 %v/v.
Alcolyzer Wine ME is a measuring wine, cider, sake,

module (looks like the Alcolyzer Beer wine based
ME, see below) which needs to be alcopops
combined with a master instrument
(DMA™ 4100 M, DMA™ 4500 M or
DMA™ 5000 M)
Alcolyzer Spirits M/ME Alcolyzer Spirits M determines the

alcohol content of spirits in the
concentration range of 35 – 65 %v/v.
Additionally, Alcolyzer Spirits M can be
equipped with color measurement. Various kinds of
Alcolyzer Spirits ME is a measuring spirits like
module (looks like the Alcolyzer Beer whiskey, vodka,
ME, see below) which needs to be rum, tequila, etc.
combined with a master instrument
(DMA™ 4500 M or DMA™ 5000 M)

Alcolyzer Type Description Application
Alcolyzer Beer M/ME Alcolyzer Beer M determines the
alcohol content of beer in the
concentration range of 0 - 12 %v/v.
Alcolyzer Beer ME is a module, which
needs to be combined with a “master
instrument” - either a DMA™ 4500 M
or a DMA™ 5000 M. The complete
operation as well as the data
acquisition is done on the master Beer including
instrument. low- and non-
Due to the combination of two alcoholic beer,
measuring parameters (alcohol cider, molasses,
content - measured by the Alcolyzer wash (an
Beer ME, and density - measured by intermediate
the DMA™ 4500 M or DMA™ 5000 product in
M), it is possible to calculate further whiskey
important parameters like original production),
extract, real extract, calories etc. alcopops
The instruments can be equipped with
an optional color measurement
device. This is an absorbance
measurement at 430 nm
(photometer). The sensor is integrated
in the Alcolyzer Beer M/ME measuring
cell. Common units for beer color are
EBC or ASBC.
Alcolyzer ME The Alcolyzer ME is a combination of
The all-in-one solution the Alcolyzer Spirits ME, Beer ME, Wine: wine, cider,
Wine ME and Sake ME. That enables sake, wine based
the alcohol measurement of all these alcopops
drinks with only one alcohol module, Spirits: Various
just by selecting the right method. kinds of spirits
like whiskey,
In the mandatory combination with a vodka, rum,
DMA™ 4500/5000 M the system is tequila, etc.
perfect for Beer: Beer, cider,
- Contract bottlers
molasses, wash
- Test and tax labs
- Developers of new beverages
(an intermediate
product in
Measuring range whiskey
Beer: 0 %v/v to 12 %v/v production),
alcopops
Wine: 0 %v/v to 20 %v/v
Spirits: 35 %v/v to 65 %v/v

6.4.3 Combinations with Other Anton Paar Instruments
6.4.3.1 Combinations with Density Meters

Alcolyzer Wine M:
You can combine Alcolyzer Wine M with a DMA™ Generation M Benchtop instrument.
The combination of alcohol measurement (Alcolyzer Wine M) and density measurement
(DMA™ Generation M) allows the calculation of further important parameters like total extract, etc.
Alcolyzer ME, Alcolyzer Beer ME, Alcolyzer Spirits ME and Alcolyzer Wine ME:
This instruments are modules which always require the combination with a master instrument.
Possible combinations with density meters:
Alcolyzer Alcolyzer Alcolyzer Alcolyzer Alcolizer Alcolyzer Alcolyzer

Beer M Spirits M Wine M Beer ME Spirits Wine ME ME
ME
DMA™
X X
4100 M
DMA™
X X X X X X X
4500/5000 M
Alcolyzer Analyzing System for Liqueurs

Adding an MCP 100 polarimeter to the existing Alcolyzer
Analyzing System for Spirits enables you to directly
analyze liqueurs containing high levels of sugar. The
optical rotation is measured to correct the impact of sugar
on the alcohol analysis and to estimate the saccharose
and invert sugar contents of the sample.
6.4.3.2 Combinations with Sample Filling Units and Sample Changers

The simplest way to fill a sample into the measuring cell of the Alcolyzer is by syringe.
However, for more comfortable and safe filling, you can use either the Xsample™ 320 sample filling
unit, or, for a higher and automated sample throughput, the Xsample™ 520 sample changer. For a
more detailed description of the sample changers, see section 10.

6.4.3.3 PBA-B Generation - Packaged Beverage Analyzer for Beer
Packaged beverage analyzers are designed to provide quick results of

packaged beverages. The aim is to minimize potential product loss using a fast,
reliable and operator- uninfluenced method of analyses. All parameters
determined in PBA-B Generation M are automatically corrected for the impact of
dissolved CO2 and therefore correlate with the test results provided by a
common Beer Analyzing System.
The basic configuration of a PBA-B Generation M consists of:

• PFD piercing and filling device
• DMA™ 4500 M or DMA™ 5000 M density meter
• Alcolyzer Beer ME or Alcolyzer ME alcohol meter
• CarboQC ME beverage carbonation meter
This configuration enables the direct analyses of all relevant quality parameter with the following
benefits:
• Analyses directly from the package without the need for sample preparation
• Simultaneous analyses of up to 7 parameters in one go
• Analyses are finished up to 6 times faster than conventional methods
Optional measuring modules:
PFD Plus piercing and filling device equipped with a longer filling tube and additional
safety equipment
Option Color 430nm ME Optional Color measurement for Alcolyzer Beer
ME and Alcolyzer ME
HazeQC ME turbidity meter Optional turbidity measuring module
pH ME measuring module Optional pH measuring module
Option O2 Plus for CarboQC ME Optional module for oxygen analyses
Alcolyzer Beer ME Heavy Duty Designed for the use in harsh ambient conditions
(details below)
PBA-B Generation M and the Beer Analyzing System are designed for use under laboratory
conditions where temperature and relative humidity are actively monitored, controlled and kept in the
range, required by the instruments.
In comparison to that Alcolyzer Beer ME Heavy Duty is equipped with dry-air-purging which enables
an installation of a PBA-B Generation M directly in production areas where temperature up to 35°C
and relative humidity up to 90% may be present.

Thanks to that, the sample can be brought to the point of analyses more quickly which additionally
reduces the time of analyses.
6.5 How to Use the Alcolyzers
Sample preparation other than degassing the samples and filtering very turbid samples is not
necessary. Special care must be taken at each step to prevent any evaporation of alcohol.
The second step is to fill the sample with one of the possibilities mentioned in section 6.4.3.2.
After filling is completed, the measurement takes place. This will take approx. 2-3 minutes.
The result is printed out automatically if a printer is connected. The result can also be stored in the
internal memory or transferred to a PC for further processing.
After the measurement, either fill the next sample or thoroughly clean with deionized water.
Did you know?

… that the Alcolyzers are equipped with preset methods for different kinds of beverage
and also allow you to custom-tailor methods to optimally match your customer’s
requirements?
6.6 What Are the Customer Benefits?
Feature
Product-independent The complete adjustment procedure for the Alcolyzers is
adjustment simply performed with two adjustment points (water and a
water-ethanol solution). This adjustment is valid for almost all
sample types.
Virtually no influence of other Due to the selectivity, other substances do not interfere with
ingredients the alcohol measurement.
Direct ethanol measurement No time-consuming distillation necessary.
in the sample
Modular concept Extension with other instruments / modules possible.
6.7 What Is So Special About the Alcolyzers?
Above you have read about the features of Alcolyzer systems. But which of these features are unique
on the market?
• The simple adjustment procedure! Competitive instruments need time-consuming product-
specific calibrations, which makes life much more complicated.

6.8 Alcolyzers – Market Information
6.8.1 Competition
Competition Alcolyzer Wine M / ME
Company Instrument Measuring Additional information / weak points

principle
• Time-consuming calibration/adjustment
• Quality of alcohol result depends on
FTIR (Fourier sample composition, region and
Foss Transform vintage. Necessary to perform different
www.foss.dk Infrared or special calibration curves
Spectroscopy) • High accuracy only if the sample was
part of the calibration
WineScan FT120 • Alcopops cannot be measured
FTIR
• Big competition as this instrument
(standard
Foss offers additionally the determination of
module) and
www.foss.dk sugars, acids, color and pH – which
(optional) VIS
cannot be done with Alcolyzer Wine
OenoFoss (color module)
Competition Alcolyzer Beer M / ME

principle
• If samples are analyzed directly in a
colored bottle, the calibration must be
made for this colored bottle.
• Samples in reused bottles cannot be
measured because it is not possible to
calibrate bottles with scratched
Foss Near Infrared surfaces
www.foss.dk Transmittance • Customer has to adjust the calibration
with typical laboratory samples
Infratec 1256 • Calibrations are only available for beer,
Beverage non-alcoholic beer and alcopops/ready-
Analyzer to-drink mixes.
• Not available at Foss anymore but still
available in a few shops

Competition Alcolyzer Spirits M / ME

principle
• If samples are analyzed directly in a
colored bottle, the calibration must be
made for this colored bottle.
• Samples in reused bottles cannot be
measured because it is not possible to
Foss Near Infrared
calibrate bottles with scratched
www.foss.dk Transmittance
surfaces.
Infratec 1256 • Customer has to adjust the calibration
Beverage with typical laboratory samples
Analyzer • Not available at Foss anymore but still
available in a few shops
Competition Alcolyzer ME
No real known competition. There are plenty of competitors out there, but also their devices are hard
to adjust or they are not that accurate in comparison to the Alcolyzer ME. As an example, see
‘Alcoquick 4000’ from Unisensor in section 6.3.4.2.
6.8.2 Cross Selling Potential

• To simplify the filling procedure, offer a sample filling unit Xsample™ 320 or a sample changer
Xsample™ 520.
• A combination of Alcolyzer Beer ME, DMA™ 4500/5000 M, CarboQC ME and PFD leads to a
PBA-B system, a Packed Beverage Analyzer for Beer (see section 11.2.2.5)
6.9 Check Your Knowledge
1. List the different types of Alcolyzers and their main application.

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______________________________________________________________________________
______________________________________________________________________________
2. Explain the customer benefits of Anton Paar alcohol meters.
______________________________________________________________________________
______________________________________________________________________________
3. Explain the measuring principle of Anton Paar alcohol meters.
______________________________________________________________________________

7. CO2 and O2 Meters
The concentration of dissolved gases such as carbon dioxide or oxygen during filling or in the
final product is of interest for many beverage manufacturers. In the following chapter you will
learn the basics about measurement of dissolved gases in beverages using the Anton Paar CO2
and O2 meters.
7.1 CO2 and O2 Determination
In the production of alcoholic and non-alcoholic beverages, it is essential to check and control the
CO2 and O2 content of the product during the production process and after bottling.
7.1.1 Why Determine Carbon Dioxide?

The CO2 content strongly influences the taste of beverages and is a considerable cost factor in
beverage production. For this reason, as well as for product safety, the precise measurement of the
CO2 content ensures consistent taste and cost-efficient dosing.
Did you know?

… that carbon dioxide was one of the first gases to be described as a substance
different to air? Already in the seventeenth century, it could be observed that when
charcoal was burnt in a closed vessel, the mass of the resulting ash was much lower
than the mass of the original charcoal. Where did the disappeared mass go?
Charcoal, when burnt in the atmosphere, forms CO2 – which is a gas. Thus, if you burn
charcoal, the remaining ash is lighter because parts of the charcoal have become
volatile.
The theory: three physical laws apply
XDLIE005EN-K 7. CO2 and O2 Meters 93/186

7.1.1.1 How Does Anton Paar’s CO2 Measurement Work?
A measuring method that avoids the shortcomings of conventional methods of CO2 measurement
has been developed by Anton Paar. This method is called the Multiple Volume Expansion method.
This measuring method, incorporated into Anton Paar’s CO2 meters (CarboQC, CarboQC At-line,
CboxQC™, CboxQC™ At-line, CarboQC ME), is not influenced by other dissolved gases such as air
or nitrogen, and therefore makes it possible to determine the true amount of dissolved CO2,
unaffected by the presence of other dissolved gases!
Did you know?

… that the Multiple Volume Expansion method is patented by Anton Paar (AT 409673,
GB 237 3584, US 6,874,351)?
The measurement is based on temperature and pressure measurements and is performed in three
steps:
Step 1: Step 2: Step 3:
The measuring chamber is The volume of the measuring The measuring chamber
completely filled with sample chamber is expanded. volume is further expanded,
and sealed. Equilibrium is generated and equilibrium is generated and
pressure and temperature are pressure and temperature are
measured. measured again. The two
pressures and temperatures
are used for CO2
determination and dissolved
air compensation.
7.1.1.2 Why Does Anton Paar’s CO2 Measurement Work?

The patented Multiple Volume Expansion method makes use of the fact that the solubility of air in
beverages is much lower than that of CO2. Therefore, when expanding the volume of the measuring
chamber, the partial pressure of air decreases much more than that of CO2.
Measuring the equilibrium pressures and temperatures at two different volume expansions of the
measuring chamber allows a CO2 result to be detected where the effect of other dissolved gases,
such as air or nitrogen, is completely compensated.
The graph (see fig. 7-1) explains how two volume expansions eliminate this influence.
94/186 7. CO2 and O2 Meters XDLIE005EN-K

If CO2 as well as some air is dissolved in the beverage, the second measurement gives a lower
reading than the first measurement which can be seen from the red curve. The difference between
the first and second measurement is used to quantify the amount of dissolved air and mathematically
calculate and compensate for the amount of dissolved air.
The result is the true CO2 concentration in the beverage.
Fig. 7-1: Two volume expansions eliminate the influence of dissolved air
Required reading
It is essential and therefore compulsory to carefully study the eLearning course “Basics
of CO2 measurement”.
Please find the eLearning course on the Extranet.
7.1.2 Why Determine Oxygen?

Oxygen reacts with some beverage components. A high level of dissolved O2 in beverages has a
negative impact on the taste and shelf life of the beverage. This is why glass bottles and aluminum
cans are the prime containers in the beer industry. PET bottles are not frequently used as they allow
oxygen migration through the container walls. The continuous monitoring of the oxygen content
ensures product safety and consistent beverage quality.
Did you know?

… that oxygen is the most abundant chemical element, by mass, in our biosphere, air,
sea and land. Oxygen gas is the second most common component of the Earth's
atmosphere and oxygen is the third most abundant chemical element in the universe,
after hydrogen and helium.

7.1.2.1 How Does the O2 Measurement Work?
Anton Paar’s O2 meters (OxyQC, OxyQC Wide Range, CboxQC™, CboxQC™ At-line, CarboQC ME
+ Option O2 (Plus)) contain an optochemical oxygen sensor. Inside the sensor, a light-emitting diode
illuminates the light-sensitive layer.
This layer absorbs the light and gets transferred to a higher energy level. The light-sensitive layer is
in direct contact with the sample. If dissolved oxygen is present, the energy – or parts of it - gets
transferred to the oxygen. If no oxygen is present, the entire absorbed light gets emitted again.
In short, knowing the “amount” of excitation light, the quantity of emitted light is a measure of the
amount of oxygen in the sample.
Fig. 7-2: Measuring principle of dissolved oxygen
For all oxygen sensors, do not use any cleaning agents that contain chlorine or hypochlorite. Even
the chlorine concentration in tap water could be high enough to damage the oxygen sensitive layer
of the sensor.
7.2 Get to Know the Product Portfolio of CO2 and O2 Measurement
Whether directly at the production line, in the laboratory or as part of a larger beverage analyzing
system, Anton Paar provides the best instrument for every application. The measurement
instruments will be divided into three application fields (see fig. 7-3):
• Measuring modules for system application: Measuring module for CO2/O2 measurement only in
combination with Anton Paar’s density meter DMA™/Soft Drink Analyzer M
• Measuring instruments for the most precise measurement in the laboratory: Stand-alone
measuring instruments for CO2/O2 measurement in the lab with PFD Piercing and Filling Device

• Measuring instruments for robust use at-line in the production process: Stand-alone measuring
instruments for CO2/O2 measurement from process lines, tanks, kegs or casks
Fig. 7-3: Anton Paar’s product portfolio of CO2 and O2 measurement
Did you know?

… that there are two new innovations at a glance: firstly, a new combined CO2 and O2
meter – CboxQC™ – is introduced onto the market; secondly, the portfolio is extended
with a new robust product line – CarboQC At-line and CboxQC™ At-line – for special
use in at-line applications.

Main Differences between Lab and At-line Products
CarboQC | CboxQC™ CarboQC At-line | CboxQC™ At-line |

OxyQC | OxyQC Wide Range
• Lower measurement performance than lab
• Most precise measurement performance
version (e.g. different built-in pressure
(e.g. integrated absolute pressure sensor)
sensor)
CO2 repeatability: 0.01 g/L (0.005 vol.)
CO2 repeatability: 0.04 g/L (0.02 vol.)
• Compatible with Anton Paar’s analyzing
systems (PBA-B/W/S/SI/SD/SID • Not compatible with Anton Paar’s analyzing
Generation M – available from SW release systems
2.40)a
• Higher flow rate due to 6 mm hose
• 4 mm hose connections between in-/outlet
connections between in-/outlet valve and
valve and PFD
measuring point (tank, production line,…)
• Filter set for measurement with PFD Piercing
and Filling Device available
• Equipped with rubber protection for harsh
environments by default
a In order to perform adjustments, the CarboQC | CboxQC™ must be disconneted from the PBA system. For full functionality
in regard of adjustments, it is recommended to use the CarboQC ME within PBA systems
7.3 CboxQC™ and CboxQC™ At-line
What is CboxQC™?
CboxQC™ and CboxQC™ At-line are combined CO2 and O2 meters to determine the true amount
of dissolved CO2 and O2 in beverages for use
• in the lab in combination with the PFD Piercing and Filling Device
• and at-line.
What is so special about CboxQC™ and CboxQC™ At-line?
CboxQC™ with its patented Multiple Volume Expansion method is the
only instrument on the market that is capable of telling apart CO2 from
other dissolved gases such as air. For that reason, CboxQC™ gives
information on the true CO2 content that is dissolved in a beverage.
CboxQC™ and CboxQC™ At-line measure CO2 and O2 within 90
seconds using a sample volume of up to 150mL.
These instruments are an affordable solution for calculating the Total
Package Oxygen (TPO) via Anton Paar’s free software AP-SoftPrint or
by connecting to a DMA™ Generation M system (CboxQC™ only).

7.4 CarboQC and CarboQC At-line
What is CarboQC?
CarboQC and CarboQC At-line are CO2 meters to determine the true amount of dissolved CO2 in
beverages for use
• in the lab in combination with the PFD Piercing and Filling Device
• and at-line.
What is so special about CarboQC and CarboQC At-line?
CarboQC with its patented Multiple Volume Expansion method is
the only instrument on the market that is capable of telling apart
CO2 from other dissolved gases such as air. For that reason,
CarboQC gives information on the true CO2 content that is
dissolved in a beverage.
7.5 OxyQC and OxyQC Wide Range
What is OxyQC | OxyQC Wide Range?

OxyQC and OxyQC Wide Range are O2 meters to determine
the true amount of dissolved O2 in beverages for use
• in the lab in combination with the PFD Piercing and Filling
Device
• and at-line.
What is so special about OxyQC and OxyQC Wide Range?

The new series of oxygen meter uses a new optochemical sensor for fast and highly accurate
determination of dissolved oxygen.
The instrument measures O2 within 55 seconds using a sample volume of up to 150mL.
These instruments are an affordable solution for calculating the Total Package Oxygen (TPO) via
Anton Paar’s free software AP-SoftPrint.
7.6 What Does the CboxQC™ and CarboQC Look Like?
The CO2 meter CarboQC as well as the combined CO2 and O2 meter CboxQC™ can be used as a
stand-alone instrument in the lab in combination with a PFD Piercing and Filling Device (Plus), but
also in combination with other measuring systems.

Equipped with a transparent measuring chamber, CboxQC™ and CarboQC allow visual observation
of the filling process. The bright color LD display is easy to read and the user interface with the new
menu structure is clearly arranged. The display of measurement results allows survey of the CO2 and
O2 content (for CboxQC™ only), Air Index (N2 Index, O2 Index, Air Index), Temperature and
Package Pressure.
Top view lab instruments Rear view lab instruments
4 5
3 3
4 2
9
2
5
1 6 1
7
8
1 <Rinse> key 1 Type plate with serial number

2 Softkeys 2 RFID/Bluetooth sticker (optional)
3 Color LC display 3 Sample inlet
4 Window to the measuring chamber 4 Sample outlet
5 Arrow keys 5 Protecting covers
6 <Start/Stop> key 6 USB interface
7 Power key 7 RS-232 interface (CAN capable)
8 Power inlet
9 Cover for the battery

7.7 How to Use CarboQC and CboxQC™ in the Laboratory
How to fill samples into the measuring chamber

For measurements of samples out of bottles or cans CarboQC and
CboxQC™ can be connected to the PFD Piercing and Filling Device
(Plus).(see fig. 7-4). The PFD pierces the bottle closure or the base
of the can and forces the beverage into the measuring chamber
using compressed gas (for CboxQC™ with O2: compressed nitrogen
>99.999%). The integrated safety shield protects the operator in the
unlikely event of a pressurized beverage container bursting.
Pressing one button fills the measuring chamber with sample and
starts the measurement.
Fig. 7-4: CboxQC™ and PFD
How to perform a measurement with CarboQC and CboxQC™
Required reading
It is essential to watch the movies “CO2 and O2 Measurement - Laboratory” about the
measuring principle of CarboQC and CboxQC™. You will find it in the Media Gallery of
the Anton Paar website and on youtube.
Sources: http://www.anton-paar.com/static/MediaGallery/index.html
Youtube: “Anton Paar CboxQC™ Laboratory”
https://www.youtube.com/watch?v=d3UPUUhreZA
To equilibrate the sample, shake the container 15 times horizontally for CO2 measurement |
shake the package vigorously for at least 3 minutes for combined CO2 and O2 measurement,
(this is best performed by a laboratory shaker) then insert it into the PFD Piercing and
Filling Device (Plus). Select the corresponding method and sample ID according to the sample to be
measured, and press the start button to start the measurement.
Replacement of the sample is carried out automatically. The magnetic stirrer which is built into the
measuring chamber allows bubble-free filling of the chamber with new sample. It will take about 55
seconds for CO2 measurement and 90 seconds for the combined measurement of CO2 and O2 to be
completed. The result is automatically stored in the internal memory (maximum 500 data sets).
After the measurement, either rinse and fill with fresh sample or thoroughly clean with deionized
water.
Did you know?

… that Anton Paar’s CO2 meters are equipped with seven standard methods for
different kinds of beverage, one CO2 standard method and also allows you to custom-
tailor methods to optimally match your customer’s requirements?
How does the sample get into the measuring chamber of CarboQC and CboxQC™?
Once pressure has been applied, a hole is pierced into the closure of the bottle or the base of a can,
respectively. This allows you to introduce the sample tube. Pressing the start button will open inlet
and outlet valves and allow the sample to enter the measuring chamber. The valves close
automatically when filling is completed, and then the measurement starts all by itself.

Fig. 7-5: Filling principle of CarboQC/CboxQC™/OxyQC
How does the test sequence of CarboQC and CboxQC™ take place?
Fig. 7-6: Test sequence of CarboQC/CboxQC™
7.8 What do CboxQC™ At-line | CarboQC At-line | OxyQC | OxyQC Wide

Range look like?
The CboxQC™ At-line, CarboQC At-line, OxyQC and OxyQC Wide Range are well protected for
harsh environments. The robust rubber protection provides the assurance that these instruments are
built to operate for years under rough conditions. Based on the leakproof housing and new design
the protection class IP67 can be guaranteed.
Using the CO2 and O2 Data Logger function enables the operator to define the interval for continuous
measurements from the line or tank. Whether using the RFID interface or Bluetooth option, with the
new product series valuable time can be saved due to fast and wireless technologies.

Top view At-line instruments
4
5
3
6 1 Rubber protection
2 <Rinse> key
3 Softkeys
2 7 4 Color LC display
5 Window to the measuring chamber
6 Arrow keys
8 7 <Start/Stop> key
8 Power key
1
Rear view At-line instruments
4
5
2
9
1 Type plate with serial number

2 RFID/Bluetooth sticker (optional)
3 Sample inlet
4 Sample outlet
5 Protecting covers
6 USB interface
1 7 RS-232 interface
8 Power inlet
9 Cover for the battery
7
8

7.9 How to Use CboxQC™ At-line|CarboQC At-line|OxyQC
How to fill samples into the measuring chamber

For measurements from tanks or from the production line, the instrument is connected to the tank or
production line by a hose and filled by the given system pressure (up to max. 10 bar/145 psi), see
fig. 7-7.
Fig. 7-7: Filling principle of CarboQC At-line/CboxQC™ At-line/OxyQC
Did you know?

… the difference between at-line, inline and online? Have a look at the sketch:
If sample is transferred from a line or tank into a measuring chamber and discarded after the
measurement, it is called an at-line measurement. If the probe is inserted into a tank or line and takes
data continuously, it is called inline measurement. If a bypass leads to the measurement site and
then the sample is led back to the line, it is called online measurement.
How does the test sequence of CarboQC At-line and CboxQC™ At-line take place?
See the test sequence presented in fig. 7-6.
TIP – At-line Instruments can also be used in combination with the PFD Piercing and Filling Device
(Plus).

How to perform a measurement with CarboQC At-line and CboxQC™ At-line
Required reading
It is essential to watch the movies “CO2 and O2 Measurement – At-line” about the
measuring principle of CarboQC and CboxQC™. You will find it in the Media Gallery of
the Anton Paar website and on youtube.
Sources: http://www.anton-paar.com/static/MediaGallery/index.html
Youtube: “Anton Paar CboxQC™ At-line”
https://www.youtube.com/watch?v=BXXLEkAbwV8
7.10 CarboQC ME and Option O2 (Plus)
What is CarboQC ME?

CarboQC ME is a measuring module that can be used in the Anton Paar measuring systems PBA-
S, PBA-SI, PBA-SD, PBA-SID, PBA-B or PBA-W Generation M to determine the CO2 content of
sugar-based soft drinks, soft drinks with low sugar concentration, diet drinks, beer, strong beer,
sparkling wine and mineral water.
See section 11.2 for detailed information about the PBA-S, PBA-SI, PBA-SD, PBA-SID, PBA-B and
PBA-W Generation M.
What is CarboQC ME and Option O2 (Plus)?
CarboQC ME with Option O2 (Plus) determines the dissolved CO2 and oxygen contents and can be
used in the Anton Paar measuring systems PBA-S, PBA-SI, PBA-SD, PBA-SID, PBA-B or PBA-W
Generation M to measure sugar-based soft drinks, soft drinks with low sugar concentration, diet
drinks (only the CO2 and O2 content), beer, strong beer and mineral water.

7.10.1 What Does CarboQC ME with / without Option O2 (Plus) Look Like?
Top view of CarboQC ME
1
7
1 Housing for pressure and 6 LED indicators

temperature sensors 7 Cable connecting pressure and
2 Sample outlet temperature sensors to the
3 Sample inlet electronic board
4 Measuring chamber
5 Piston drive housing
Top view of CarboQC ME with Option O2

7 8 9 10 11
12
2
1 Piston drive housing 7 Connection to the CarboQC ME sample outlet

2 Cable connecting the oxygen sensor to 8 Connection to the CarboQC ME sample inlet
CarboQC ME 9 Flow valve to adjust the sample flow
3 Housing for the oxygen sensor 10 Measuring chamber of the CarboQC ME
4 Sample inlet 11 Cable connecting pressure and temperature
5 Sample outlet sensors of CarboQC ME to the electronic board
6 Cable connecting the temperature 12 LED indicators
sensor of the Option O2 to CarboQC ME

Top view of CarboQC ME with Option O2 Plus mounted on modular stand with PFD Plus
3 4 5 6 7 8
11 10 9
1 Temperature sensor cable (connector hidden behind 7 Temperature sensor cable of Option O2 Plus
Option O2 Plus) 8 LED indicators
2 Sample inlet and outlet of Option O2 Plus 9 Coupling of the O2 sensor cable
3 O2 sensor cable connector 10 Temperature sensor cable
4 Sample inlet and outlet of CarboQC ME 11 Modular stand for Option O2 Plus
5 Flow valve to adjust the sample flow
6 Cable connecting pressure and temperature sensors
of CarboQC ME to the electronic board
How do CarboQC ME and CarboQC ME with Option O2 (Plus) work?

CarboQC ME uses the patented Multiple Volume Expansion method to eliminate the influence of
dissolved air on the determined carbon dioxide content. The analysis is based on highly accurate
absolute pressure and temperature measurements.
The analysis of dissolved oxygen with the optical oxygen sensor of Option O2 (Plus) is based on the
phenomenon of oxygen absorbing energy from the excited dye called "luminescence quenching".
For further information please refer to section 7.1.2.1 How Does the O2 Measurement Work?

7.10.2 How to Use CarboQC ME and CarboQC ME with Option O2 (Plus)
CarboQC ME is designed to work in combination with a master instrument and cannot be used
as a stand-alone. The Option O2 (Plus) is an optional add-on module for the CarboQC ME and only
works in combination with CarboQC ME. CarboQC ME with/without Option O2 (Plus) is easily
connected to the master instrument of the measuring system with a CAN interface cable and is
controlled and supplied with power by the master instrument.
As sample or calibration/adjustment media is filled by PFD (Plus) or SFD, a compressed gas supply
is required for the operation.
To perform a measurement, select the appropriate method on the master instrument of the
measuring system and press the <Start> button. Within approx. 2 minutes the CO2 (or CO2 and O2)
concentration is shown on the display of the master instrument and transferred to the data memory.
The measuring result can be printed out immediately or later from the data memory of the master
instrument.
How to perform a measurement with CarboQC ME in a PBA system
Required reading
It is essential to watch the movies “CO2 and O2 Measurement – Systems” about the
measuring principle of CarboQC ME and the SOP video. You will find them in the Media
Gallery of the Anton Paar website.
Source: http://www.anton-paar.com/static/MediaGallery/index.html
Specifications for Option O2 (Plus)
Measuring ranges Repeatability, s.d.

CO2 0 - 6 vol. (0 - 12 g/L) at 30°C (86°F)
0.005 vol. (0.01 g/L)
0 - 10 vol. (0 - 20 g/L) < 15°C (59°F)
O2 0 - 4 ppm 2 ppb
(in the range < 200 ppb)
Sample volume
140 mL – 160 mLa
for CO2 & O2
Typical
approx. 2 minutes
measuring time
a Sample volume strongly depends on the installed modules in a PBA system

Information at a glance
Option O2 Plus for Beer Option O2 for Soft Drinks & Wine
Optimized for low O2 content in Beer (< Ideal for Soft Drink / Wine Industry
100ppb)
Installed on the filling device Installed on the CarboQC ME
→ first measuring module → last measuring module
Retrofit is possible at all times (starting with Retrofit is possible at all time
V2.90 and higher)
Modular Stand for PFD required No modular stand required
Operating with OS01 O2 sensor only Operating with OS01 (and Visibev DO 120) O2
sensor

7.11 Market Information
7.11.1 CarboQC and CboxQC™

Optional reading
Have a look at the Sales Guide, leading you the way to successful CarboQC and
CboxQC™ sales!
The Sales Guide Instruments for Measurement of Dissolved CO2 and O2 in Beverages
is a guideline to successful sales and is available on the Extranet. It prepares you for a
first discussion with your customer about the instruments’ features and applications,
provides you with arguments against the competition and offers helpful hints on how to
identify new potential customers.
Applications for CarboQC, CboxQC™, CarboQC At-line and CboxQC™ At-line? Beverages! In the
laboratory in combination with a suitable filling device as well as at-line!
Application Tips and Comments

Beer, Many breweries use CarboQC/CboxQC™ for analysis in the bottled product
mixed beer, and CarboQC At-line/CboxQC™ At-line during production control. Also beers
cider with a lot of nitrogen, for example Guinness, can be analyzed accurately without
any problem!
Soft drinks, Anton Paar’s CO2 meter has become very popular with soft drink producers.
mineral water Some even had their own CarboQC method developed to ideally match their
needs!
Water In general, tap water does not contain dissolved CO2 and is therefore suited to
check the zero point of CarboQC and CboxQC™. If you use tap water, always
rinse with distilled water afterwards to remove any limestone residuals that may
be in the tap water.
Wine, Wine and sparkling wine are well-proven applications. Filling can be done with a
sparkling PFD Piercing and Filling Device for cans and bottles closed with caps, or with
wine an SFD sparkling wine filling device for bottles closed with a cork.
Other It is quite possible that CarboQC can be useful for other applications that are
not investigated and launched yet. Have you come across other application
inquiries? If so, let us know!
Did you know?

… that a PET bottle manufacturer purchased a CarboQC? Now you are wondering
what he uses it for? Quite simple: to monitor the CO2 losses of carbonated products
over time and make his product, which is the PET bottle, the most suitable one for
beverage producers.

7.11.1.2 Competition
The determination of carbon dioxide as well as combined determination of carbon dioxide and
oxygen is of great interest among producers and bottlers of beverages. Thus, a number of instrument
manufacturers offer instrumentation for CO2 determination, but also instruments for combined
determination of CO2, O2 and TPO. Several manufacturers and some of their instruments are listed
below.
Optional reading
Have a look at the presentation of D35IV002EN-D Competitive Information CarboQC,
CboxQC™, OxyQC, OxyQC Wide Range for Lab and At-line which deals with the
competitive situation of CO2 and O2 measurement in detail.
The presentation is available on the Extranet.
Competitive situation of CO2 | O2 | TPO measurement
7.11.1.3 Cross-Selling Potential

• You can retrofit all PBA Generation M systems (from Software-Release 2.40) with
CarboQC|CboxQC™
• You can retrofit a PBA-S classic system (a Packaged Beverage Analyzer for Soft Drinks
consisting of a DMA™ 4100/4500/5000 classic density meter1, a CarboQC and PFD).
• You can retrofit a PBA-SI classic system (a Packaged Beverage Analyzer for Soft Drinks with
Inversion consisting of a Soft Drink Analyzer 2P classic density and sound velocity meter2, a
CarboQC and PFD).
1 already discontinued

• You can retrofit a PBA-B classic system, a Packaged Beverage Analyzer for Beer (a PBA-S with
an additional Alcolyzer Plus Beer1 connected). This instrument gives the additional information of
the alcohol content of beer samples.
7.11.1.4 References
If your customer asks for references or publications, the following list might contain the right literature
reference for your customer’s interest! You can find them on the Anton Paar Extranet.
• G. Murer, Measuring dissolved gases in packaged beverages, Brauwelt International, 2005/II,
pp. 100 107.
• G. Murer, The Nitrogen challenge, Beverage World, February 2006, p. 38.
• G. Murer, J. Gautsch, Selective CO2 measurement for beverages with the new multiple
volume expansion method, Brauwelt International, 2004/3, p.176-178.
• G. Murer, J. Gautsch, Selektive CO2-Messung für Getränke mit dem Mehrfach-Volumen-
Expansionsverfahren, Brauwelt Nr. 39/40 (2003), pp. 1225-1230.
• K. Biebernik, CO2-Bestimmung ohne Fremdeinfluss: Sekt & Co. analytisch unter Druck, GTM
5 (2008), pp. 4-5.
7.11.2 OxyQC
Applications for OxyQC? Beverages!
Application Tips and Comments

Beer, mixed beer, Expected oxygen content in bottled/canned products is low. Therefore,
cider select the output unit “ppb”.
Make sure that no leaks allow introduction of oxygen during filling!
Soft drinks Expected oxygen contents may be a few ppb to several ppm
Water, sparkling Expected oxygen contents may be a few ppb to several ppm.
wine
Other It is quite possible that OxyQC can be useful for other applications that
are not investigated and launched yet. Have you come across other
application inquiries? If so, let us know!
Did you know?

… that there is a growing demand for measuring O2 in juices and soft drinks due to the
trend towards natural flavorings and addition of vitamins.
Additional advice
Check the Anton Paar Extranet for application reports, application flashes and tender guides. It is
always available, 24 hours a day! Maybe you can find the solution for your application problem!

7.11.2.2 Competition
The determination of dissolved oxygen is becoming increasingly important. Thus, a number of
instrument manufacturers offer instrumentation for dissolved oxygen determination. Several
manufacturers and some of their instruments are listed below. Please note that this table is
incomplete! For more comprehensive information and the latest developments on competitor’s
portfolios, refer to the respective homepages.
Manufacturer and website Instrument denotation (excerpt)

Dr. Thiedig DIGOX 5/ electrochemical (without
www.thiedig.de membrane)
Haffmans c-DGM (CO2/O2 Gehaltemeter)/ optical
www.haffmans.nl measuring principle
Mettler-Toledo InTap 4000e/ InTap4004e/ electrochemical
www.mt.com Inpro 6870i optical sensor
Hach-Lange Orbisphere 6110
www.hach-lange.com Orbisphere 3650/3655
Package Analyzer 3625/ electrochemical
7.11.2.3 Cross-Selling Potential

The OxyQC can be used as a "stand-alone" instrument either at-line in the production process or in
the lab to measure dissolved oxygen in combined with a PFD Piercing and Filling Device (Plus).
This combination allows sample transfer directly from the container into the OxyQC without changing
the dissolved oxygen content during sample transfer.
1. What makes CarboQC and CboxQC™ so unique?

______________________________________________________________________________
______________________________________________________________________________
2. Why is it essential to ensure equilibrium of the CO2 distribution in a package?

______________________________________________________________________________
______________________________________________________________________________
3. How do you create equilibrium of the CO2 distribution / O2 distribution in a package?

______________________________________________________________________________
______________________________________________________________________________
4. Why do CarboQC and CboxQC™ provide several methods?

______________________________________________________________________________

5. What needs to be measured in order to determine the true CO2 content?
______________________________________________________________________________
______________________________________________________________________________
6. Name three differences between the lab (CarboQC, CboxQC™) and at-line (CarboQC At-line,
CboxQC™ At-line) product lines.
______________________________________________________________________________
______________________________________________________________________________
7. Name four possible reasons for deviations between CO2 results out of the Multiple Volume
Expansion method and results obtained with a competitor‘s instrument.
______________________________________________________________________________
______________________________________________________________________________
8. True or False?
True False
CO2 and air have different solubilities in the beverage
Snifting does not affect the dissolved CO2 content
9. Tick the right answer, one or more correct answers possible: How many gas laws are executed
by CarboQC and CboxQC™?
□ 1
□ 3
□ 5
10.Can CarboQC ME only be used in the laboratory?

______________________________________________________________________________
11.What measuring principle is applied by Option O2?

______________________________________________________________________________

1. Tick the right answer, one or more correct answers possible: Option O2 (Plus) needs to be
connected to the following measuring module:
□ CarboQC ME
□ CarboQC
□ DMA™ Generation M
2. Why is it essential to ensure equilibrium of the O2 distribution in a package?

______________________________________________________________________________
3. True or False?
True False
CO2 and air have different solubilities in the beverage
OxyQC is an instrument to determine the amount of dissolved CO2 in
beverages.
CboxQC™ At-line and CarboQC At-line are compatible with Anton Paar’s
analyzing systems.
CarboQC At-line and CboxQC™ At-line are able to regulate the flow rate
via an integrated ball valve
CboxQC™ and OxyQC works with an electrochemical sensor.
CboxQC™ and OxyQC works with an optochemical sensor

8. Filling Systems for Dissolved Gas Analyses
Measurement of dissolved gases with CarboQC, CboxQC™, OxyQC, OxyQC Wide Range,
CarboQC ME and CarboQC ME with Option O2 (Plus) require filling under pressure. Depending
on the kind of container we have different filling systems available for filling samples under
pressure. Learn more about our filling systems for dissolved gas analysis in the following chapter.
8.1 What Are Filling Systems Needed For?
Filling systems in general are devices to transfer sample into the measuring cell of an analytical
instrument. In the special case of dissolved gas analysis, the sample transfer must not affect the
dissolved gas concentration of the sample during transfer. Here, sample has to be transferred
directly from the closed beverage container to the analytical instrument without the need to
open the package. This can be accomplished with a PFD piercing and filling device (Plus) and a
sparkling wine filling device (SFD).
8.2 What Filling Systems for Dissolved Gas Analyses Are Available?
The PFD (Plus) and SFD are designed to transfer beverage samples directly from a closed container
to the measuring chamber of an analytical instrument, for example a CboxQC™. With these filling
devices any change of dissolved gas composition during sample transfer is omitted. Hence it is
necessary to have a bubble-free filling, otherwise the measurement could result in too low or too high
CO2/O2 readings.
8.3 What Is Required for PFD (Plus) and SFD Operation?
Prerequisites
Sample transfer takes place after piercing the closure of the beverage container or the can. After
having inserted the sample tube, sample can be transferred to the measuring chamber of the
analytical instrument with pressurized gas. No electricity is required! The PFD (Plus) is used with
pressurized gas of max. 6 ± 0.5 bar (87 ± 7 psi) relative pressure. The SFD is operated with pressures
up to 7.5 bar relative ±0.5 bar (109 psi ±7 psi) to transfer the sample into an analytical instrument.
Which gas for which measurement?
For carbon dioxide measurement, air or nitrogen are the most commonly used transfer gases. For
oxygen measurement, nitrogen is the most commonly used transfer gases. For combined oxygen
and carbon dioxide measurements, nitrogen gas is best used.
Which gas purity is required?
Necessary quality of air if used as compressed gas supply:
• max. 6 ± 0.5 bar (87 ± 7 psi) relative pressure
• Class 5 from ISO 8573-1
• max. particle size: 40 μm
• max. pressure dew point: +7 °C (44.6 °F)
• max. oil content: 25 mg/m3
116/186 8. Filling Systems for Dissolved Gas Analyses XDLIE005EN-K

Necessary quality of nitrogen if used as compressed gas supply:
• max. 6 ± 0.5 bar (87 ± 7 psi) relative pressure
• N2 ≥ 99.999% (Class 5)
8.4 PFD Piercing and Filling Device (Plus)
What is a PFD (Plus)?

The PFD (Plus) is used for filling samples directly from closed beverage packages
such as PET bottles, glass bottles or cans into measuring instruments, for example
a CarboQC, CboxQC™, OxyQC or OxyQC Wide Range. The PFD (Plus) pierces
the bottle closure or the base of the can and transfers the beverage directly from
the package by means of compressed gas. Air or, if CboxQC™, OxyQC or OxyQC
Wide Range is connected, nitrogen is used as the compressed gas for sample
transfer into the measuring chamber.
Why use a PFD (Plus)?
The PFD (Plus) pierces the bottle closure or the base of the can and forces the
beverage out of the package using compressed gas. Air or nitrogen is mostly used
as compressed gas supply. Therefore, the amount of dissolved gas in the sample is not affected
during transfer into the measuring chamber of CarboQC, CboxQC™, OxyQC or OxyQC Wide Range.
What does a PFD (Plus) look like?
With its dimensions of 190 x 270 x 670 mm (7.5 x 10.6 x 26.4 inches) L x W x H and a maximum
height with piercing head in highest position of 1020 mm (40.2 inches) the PFD only requires little
bench space.
Front view of a PFD (Plus) Piercing and Filling Device
10
9
1
8
7
2 5
4
3
1 Fixation clamp for safety shield 6 Piercing head

2 Handle 7 Warning sign and mandatory signs
3 Base plate 8 Safety shield
4 Activating lever 9 Sample tube
5 PET bottle adapter 10 Fixation screw of the sample tube
XDLIE005EN-K 8. Filling Systems for Dissolved Gas Analyses 117/186

Rear view of a PFD (Plus) Piercing and Filling Device
11
10
1
8
2
7
9
9
3
3 6
4 4 6
5
5
PFD Filling Device PFD Filling Device Plus
1 Fixation screw for piercing head 8 Gas spring

2 Warning sign relates to the possibility of 9 Knurled nut
a container bursting 10 Splinter shield
3 Holding channel for the sample hose 11 Gap for the chain leading the
4 Type plate compressed gas hoses
5 Exhaust
6 Inlet for the compressed gas supply
7 Fixation nut of the safety shield
Special Safety Features

The operator is protected by a safety shield. A safety pin on the bottom of the safety shield ensures
that the system cannot be pressurized as long as the safety shield is not in the protective position.

8.5 SFD Sparkling Wine Filling Device
What is an SFD?
The SFD is a filling device for the sampling of sparkling wine or wine directly from a bottle that is
closed with a cork. It transfers the sample straight from the bottle into an analytical instrument. No
electricity is required for operation as sample gets transferred by means of pressurized gas.
It is possible to take sparkling wine samples without any change of dissolved gas composition and
without any loss of CO2.
Why use an SFD?
If e.g. the true CO2 content in sparkling wine needs to be determined, it is essential not to lose any
CO2 during transfer from the bottle to the measuring cell of the analytical instrument. With an SFD,
no CO2 is lost during sample transfer! In combination with a suitable measuring system, for example
the CarboQC beverage carbonation meter by Anton Paar, the determination of dissolved carbon
dioxide and the amount of other gases in the sample can be performed quickly and reliably. The
package pressure, based on the determined content of all dissolved gases, is also calculated.
What does an SFD look like?
The dimensions of SFD (L x W x H) are: 320 x 370 x 550 mm (12.6 x 14.6 x 21.7 inches) and, with
the sample tube in the highest possible position 320 x 370 x 690 mm (12.6 x 14.6 x 27.2 inches). The
SFD weighs 12.3 kg (27.1 lbs).
Front view of an SFD

1
4 1 Sample outlet
2 Sample tube
3 Turning handle
5 4 Drilling device
5 Piercing head
6 6 Protective housing
7 7 Door with polymeric viewing window
8 Door knob
9 Centering plates
10 Adjustable front legs
8
10

Interior view of an SFD
Piercing head
with gasket
Pressure to
bottle
Pressure to
waste
How does an SFD work?

Connect the SFD to a suitable pressurized gas supply, insert the bottle, pull down the gasket to
achieve a seal to the upper surface of the cork, close the safety door and drill a hole through the cork
with the drilling device, then insert the sample tube and perform the measurement!
And most important: special safety features
The SFD provides full protection to the operator due to a safety housing. A safety bolt connected to
the door handle ensures that the bottle can only be pressurized with the door properly closed and the
lock in position.
8.6 Which Filling Device for Which Application?
8.6.1 Applications of the PFD (Plus)

• Glass bottles
• PET bottles
• Cans
that withstand the specified maximum applied pressure.
Maximum allowed volume of packages to be measured:
• Can: 0.5 L
• Glass bottle: 1 L
• PET bottle: 3 L

PFD Plus:
Additional splinter shield for protection at the back enables to fill the full
amount of sample out of glass and PET bottles
8.6.2 Applications of the SFD

• Bottles closed with corks that withstand the specified maximum applied
pressure.
• Specified bottle volume: from 0.2 liter bottles up to 1.5 liter bottles
Who needs SFD?

Anyone who wants to determine the CO2 or O2 content in beverages without the gain or loss of CO2
or O2 during sample transfer when filling directly from a package that is closed with a cork.
Applications: beverages, mostly wine and sparkling wine.
Does an SFD work for all kinds of corks?
The SFD works for the majority of commercially available corks. However, with some corks,
especially with polymer corks that consist of two parts, it is not possible to achieve a good seal.
Therefore, always try out the SFD with the customer’s corks beforehand!
Optional reading
Have a look at the Extranet where you can find additional “Handling Information” for
SFD Sparkling Wine Fillings Systems.
8.7 PFD (Plus) and SFD – Market Information
8.7.1 Finding Customers

Beverage manufacturers, bottlers or similar institutions who want to determine the CO2 or O2 content
in beverages without the gain or loss of CO2 or O2 during sample transfer when filling directly from a
closed package.
Applications: beverages!

8.7.2 Competition
In general, instrument manufacturers of dissolved gas analysis also offer instrumentation for
sampling. Several manufacturers and some of their instruments are listed below.
Please note that this table is incomplete! For more comprehensive information and latest
developments on competitor’s portfolios, refer to the respective websites.
Steinfurth Lg-automatic aps Haffmans (Pentair Haffmans)
STEINFURTH SAMPLING DEVICE HAFFMANS ISD

PROBEENTNAHMESYSTEM INPACK SAMPLING DEVICE
www.steinfurth.de www.lg-automatic.com www.haffmans.nl

A PFD (Plus) and/or an SFD are designed to be used with measuring instruments.
End users of a PFD (Plus) and/or an SFD in combination with one instrument might have the need
to expand their measuring system.
PFD (Plus) and/or an SFD with Possible extension

DMA™ classic, Soft Drink Analyzer 2P CarboQC
PBA systems classic CarboQC
PBA Gen. M systems CarboQC, CboxQC™
1. What gas can be used for operating a PFD (Plus)?

______________________________________________________________________________
2. True or False?
True False
SFD works for all sorts of plastic corks thus making it obsolete to check
whether SFD works for the customer’s closures.
SFD can be operated with pressurized gas or electricity.

3. Tick the right answer, one or more correct answers possible.
A PFD (Plus) can be accommodated with pressurized gas from
□ in-house supply
□ gas cylinder
□ compressor

9. Turbidity Measuring Module HazeQC ME
9.1 Turbidity in Liquids
Turbidity or Haze is defined in the DIN EN 27027 standard as follows:

"Turbidity is the decrease in the transparency of a liquid caused by the presence of
undissolved substances."
So, turbidity is not a simple physical quantity like density, temperature or weight.
It is based on the effect of light scattering by particles, whose size
is in the same order of magnitude as the incident light.
Light scattering means: If a light beam passes near a small
particle, its direction is slightly changed (the light beam is “bent”).
Therefore, the optical picture we get through a turbid sample seems
to be blurry, the sharp edges disappear.
So a simple turbidity measurement would be to put a scale with different sized letters behind the
sample cuvette and check which is the smallest letter that can be read.
Did you know?

… that turbidity has nothing to do with the color of a liquid?
E.g. A yellow apple juice can be clear or cloudy (turbid).
To make it clearer: Imagine you try to read a newspaper behind a glass of apple juice:
In both cases the letters will look yellow, but in the case of clear apple juice you will be
able to read it. In the case of a turbid apple juice, the letters will be too blurry and diffuse
to be read!
Fig. 9-1: Two apple juices: Same color – different turbidity!
9.2 Turbidity in Beer
In beer, there are mainly two types of particles that create turbidity: yeast cells and protein colloids.
So in beer, we can differentiate between “yeast turbidity” and “colloidal turbidity”.
Yeast cells are about 5 - 10 µm in diameter and thus much bigger than protein colloids (< 1µm).
Later, in the chapter “Influence of particle size”, you will see why it makes sense to mention this fact!
124/186 9. Turbidity Measuring Module HazeQC ME XDLIE005EN-K

Did you know?
… that the scientific name for brewing (and baking!) yeast, Saccharomyces
cerevisiae, includes already the latin word for beer, “cerevisia”?
9.3 Get to Know the HazeQC ME
The HazeQC ME is a measuring module for Anton Paar systems to

determine the turbidity of liquids. It measures light at three angles: 0°
transmission, 25° and 90° scattered light.
The wavelength of the incident light is 650 nm (red light).
It complies with the MEBAK (Mitteleuropäische Brautechnische
Analysenkommission) and the EBC (European Brewery Convention)
standards.
The measuring cell is temperature-controlled with a Peltier element.
9.4 How Does HazeQC ME Work?
A red light beam (650 nm) enters the sample cuvette. Three detectors measure an intensity signal at
three angles: 0°, 25° and 90° of the incident light beam.
Out of these signals, various turbidity values are calculated.
Fig. 9-2: Measuring principle of HazeQC ME
The measuring cell is temperature-controlled and the measuring temperature can be set in a range
of –5 to +40 °C.
9.4.1 Ratio Method

As the absorbance (color) of a sample also effects the 90° and 25° detector signals, the absorbance
at 0° also has to be measured and taken into account.
By this measure, the absorbance can be compensated and the result is really a turbidity and not a
mixture of turbidity and color!
Thus, the results are always ratios of the scattered light and the transmission (0°). This principle is
called the “ratio method”.
XDLIE005EN-K 9. Turbidity Measuring Module HazeQC ME 125/186

Four parameters are currently provided by the HazeQC ME module:
• Turbidity, Anton Paar (this is a function of S0, S25 and S90, the most universal parameter,
linear also for a mix of differently sized particles)
• Turbidity S25 (this is a function of the ratio S25/S0, is more sensitive for bigger particles like
yeast cells)
• Turbidity S90 (this is a function of S90/S0, is more sensitive for smaller particles like protein
colloids)
• Absorbance S0 (this is directly the absorbance, the signal of the 0° sensor. Equals a
photometer at 650 nm)
Also see section 9.5 for further details on which parameter to use when.
9.4.2 Influence of Particle Size

The scattering effect of light is stronger if the particle size is similar to the wavelength of the light.
As very small particles (in the range of 650 nm in diameter) will result in a strong scattering, the 90°
sensor will detect more intensity.
Bigger particles (like yeast cells with 10 µm diameter) will not “bend” the light beam as strongly and
therefore the forward-scattering detector signal at 25° will increase.
Small particles: 90° scattering increases
Big particles: 25° scattering increases
Fig. 9-3: The influence of particle size
Turbidity process sensors commonly employ only a 90° measurement as they are used just to detect
a rough filter break-through.
Laboratory devices normally provide at least a 90°/0° ratio, if not a 25°/90° ratio too.
NOTICE – Be careful when comparing different turbidity instruments: The geometry (angles), the
wavelength and finally the calculation (ratio or not) have to be the same if results shell be compared
directlty!
9.5 Comparing Turbidity Meters
If we are talking about turbidity, we always have to provide some more information about which value
we are talking about. The three most important attributes that always have to be mentioned along
with a turbidity result are:

1. Geometry (measuring angles 0°, 25° and 90°)
2. Wavelength (red light, 650 nm)
3. Mathematics (ratio method)
If one of these attributes differs, the turbidity reading can be equal for some samples, but also for
some other samples you can get very big deviations!
Also make sure, you are comparing the correct output parameters of the HazeQC ME with the
customer’s reference values. An overview for the most common industries is given here:
Industry HazeQC ME Common Unit Competitor’s instruments and their

Output Quantity units
Beer Haze S0/S90 and EBC, ASBC Haffmans VosRota: 25°, 90° EBC
Haze S0/S25 Sigrist LabScat: 25°, 90° EBC
Wine, Spirits, Haze Value NTU Hach 2100N/AN: Turbidity NTU
Pharma, Other
industries like
Chemistry
9.6 What Are the Customer Benefits?

One additional parameter in The HazeQC ME is an additional module for turbidity analysis
one measuring cycle used in the Beer-, Spirits-, Wine- and Pharma industry. So you
get one more important parameter extra, without the need to
do a separate measurement on another instrument. This
saves sample and time!
Easy and quick adjustment The HazeQC ME comes factory adjusted.
If the system is cleaned regularly, no readjustment of the
HazeQC ME is needed.
If necessary a zero-point adjustment with bi-distilled water can
be performed. For experts there is also the possibility for an
adjustment with a known turbidity standard (Formazine), but
this is critical as Formazine has a very limited shelf-life!
Very little sample volume Especially if the sample is expensive like in the whiskey
(approx. 3 mL) industry, this saves money. Competitive instruments need
some hundreds of mL for one measurement
Temperature control over a Turbidity heavily depends on temperature. With the
wide range:–5 to +40°C temperature-controlled measuring cell highly repeatable
results can be achieved.
Automation By adding an Xsample™ sample changer to the system,
turbidity measurement can be automated, which is a feature
other turbidity meter producers do not provide. This makes us
the only provider with an off-the-shelf sampler solution for
turbidity on the market.

9.7 HazeQC ME – Market Information
9.7.1 Who Needs the HazeQC ME and What For?

Industry/Sample Application
Quality control of final product
Quality control during production, samples out of the line
Breweries/Beers
Control of the online turbidity measurement
Shelf-life estimation (force test)
Quality control of final product
Distilleries/Whiskeys
Quality control during production
Purity checks of pharmaceutical liquids and raw materials
Pharma
QC checks of final products (e.g. antibiotic infusions)
Various applications like water control,
Chemistry, Food …
concentration checks ...
Did you know?

Anton Paar GmbH offers the Pharma Qualification and Validation Package (PQP) also
for the combination of DMA™ M, HazeQC ME and Xsample™ 520! So, Anton Paar is
the only one on the market, providing a combined system including turbidity
measurement, with PQP.
9.7.1.1 Application in Beer and Whiskeys: Filter Control

For production line filter control in both, beer and whiskeys, laboratory turbidity meters are common.
Regularly a sample is taken out of the line and its turbidity is checked. If the reading exceeds a
special limit, the production line filters are controlled and if necessary replaced.
A common check interval in the beer and whiskey industries is one sample each 30 minutes from
each line. Common limits for turbidity in clear beers (e.g. lagers) and for whiskeys are 1 EBC for the
final product. Yeast beers and naturally cloudy beers can give values up to 100 EBC in the final
product.
9.7.1.2 Application in Beer: the "Force Test"

For estimating the shelf-life of beer, various stability tests based on turbidity measurement were
developed.
The idea is to cycle the beer temperature over a period of time and observe the turbidity regularly. If
the beers gets turbid fast, the shelf-life will be short and vice versa.
A common test is to measure one day at 0°, one day at 60° and so on for one week. Another shorter
one is to store the beer three hours at 0 °C and measure the turbidity then at 0 °C directly.
These tests are called "force tests". There is not a real standard yet, each brewery has its own rules
about time and temperature!

Another similar test, which is quicker, is the "chapon" test. Here, ethanol is added to the –5 °C cold
beer sample and the sample is measured after 40 minutes.
For further information see the EBC handbook:
• Haze in Beer: Section 9 Beer, Method 9.29
• Prediction of Shelf-Life of Beer: Section 9 Beer, Method 9.30
• Sensitive Proteins in Beer by Nephelometry, Method 9.40
• Alcohol Chill Haze in Beer (Chapon Test): Section 9 Beer, Method 9.41
9.7.2 Competition
Company Instrument Additional information/weak points

Haffmans Vos Rota 90/25
Measure through closed bottle. Bottle turns around,

average value is taken.
Sigrist LabScat - Scratches on the bottle influence reading.
- Calibration for each bottle type has to be done.
- External water flow needed for temperature control.
- Temperature control is not very accurate
Hach Lange 2100AN - Measuring in a cuvette

- Temperature control not possible
- Various modes (Ratio, Non-Ratio)
- Possibility for light filter (for Beer 650 nm!!)
- Uses 30 mL sample cells

Cross Selling HazeQC ME to Breweries
Possible combinations:DMA™ Generation M, PBA-B, Alcolyzer Beer Analyzing System (both
classic1 or Generation M), Retrofitting an Alcolyzer Plus Spirits1 or Alcolyzer Plus Beer1.
There are some situations in which it might make sense to offer a HazeQC ME module:
• If quoting a new PBA-B or Alcolyzer Beer Analyzing System (both Generation M)
• If you have customers who have an Alcolyzer Plus Beer1 or Alcolyzer Plus Spirits1. Maybe they
want to upgrade with a turbidity module!
• If you are selling a DMA™ Generation M to breweries, distilleries or also chemical or
pharmaceutical industry.

Cross Selling HazeQC to Pharma
A customer interested in a DMA™ M, can upgrade his instrument with a HazeQC ME. Anton Paar is
the only one on the market, who provides a solution for density, turbidity and automation out of one
hand!

Turbidity is the same as
□ Color
□ Absorption
□ Haze
□ Refractive Index

Reasons for turbidity in beer are
□ Yeast cells
□ Color
□ High ethanol content
□ Proteins and their colloids
□ Low pH value
3. List at least two main applications for the HazeQC ME.

______________________________________________________________________________
______________________________________________________________________________
______________________________________________________________________________
4. List one main benefit of the HazeQC ME (USP).

______________________________________________________________________________

5. Tick the right answer, one or more correct answers possible: Why are the measuring angles of
the HazeQC ME 0°, 25° and 90°?
□ Because light is mainly scattered to these angles
□ Because this way three sensors fit into the measuring cell
□ Because this is proposed by the EBC and MEBAK
6. List two of the three main points that have to be taken into account when comparing different
turbidity meters
______________________________________________________________________________
______________________________________________________________________________

10. Sample Filling Units and Sample Changers
Anton Paar offers various sample filling units and sample changers to fill the sample automatically
into the measuring cell of the master instruments as DMA™ Generation M or Soft Drink Analyzer
M and their connected modules. Depending on the level of automation different sampling units are
available. Most of them belong to the “Xsample™ Family”. Meet the whole family in the following
chapter!
10.1 Why Automation?
Automation grants constant measurement results and prevents operating errors as wrong filling. In
this way it saves the operator time during his routine work in the laboratory. Especially the systems
with a magazine can be loaded with samples and they do the work like filling the master instrument
and its modules, measuring and cleaning fully automatically. Meanwhile the operator is able to do
other important analyses in the laboratory.
For automatic filling of samples we have two mainly different ways, whereas one (the pressurized
filling systems for dissolved gas analyses) you partially already got to know in section 8.
Filling system families

Modular Plug & Play sample filling units and Stand-alone sample filling units
sample changers: The Stand-alone sample filling units are placed
The Plug & Play sample filling units and sample nearby the master instrument and can be
changers perfectly fit into the housing of the connected via CAN cable (if necessary). The
master instrument (DMA™ Generation M, DSA Xsample™ 340 as well as pressurized filling
5000 M, Soft Drink Analyzer M and Alcolyzer systems PFD (for bottles and cans), SFD (for
M). They are detected automatically by the wines and sparkling wines) are stand-alone
master instrument, as soon as connected and units. The handling of the samples (putting the
controlled via the user interface of the sample or package into and out from the filling
respective master instrument, too. The modular device) has to be done manually.
design makes it very easy to install them and to
retrofit in existing instruments.
DMA M master instrument
Xsample™
Fig. 10-1: Installing Xsample™ Fig. 10-2: Xsample™ 340 Filling and Rinsing Unit
132/186 10. Sample Filling Units and Sample Changers XDLIE005EN-K

Depending on the customer’s demands according to automation grade, application (volatile samples,
viscous samples, very highly viscous samples, aggressive samples…) and daily sample throughput,
a certain sampling unit has to be offered to your customer. In the next chapters you find charts, which
give you a guideline for recommendation of a certain sampling unit in reference to the customer’s
applications.
10.2 What Sample Filling Units and Sample Changers are Available?
Modular Devices Plug & Play Pressurized Filling

Single sample Magazine Single sample Single sample
Xsample™ 320 Xsample™ 520 PFD/PFD Plus SFD
Single Sample Multi Sample Changer Filling Device Filling Device
Changer
Xsample™ 330
Single Sample
Changer
Xsample™ 340 Xsample™ 530
Single Sample Multi Sample Changer
Changer
Xsample™ 630
Heated Sample
Changer
Filling Units with the same color have the same filling technology, but a different automation grade:
Peristaltic Pump, the sample is replaced by the next
Peristaltic pump with cleaning
Overpressure in the vial
Overpressure in the vial and decreasing sample viscosity by preheating up to 95 °C
6 bar overpressure in package to avoid degassing of dissolved gases
Pressure on syringe
XDLIE005EN-K 10. Sample Filling Units and Sample Changers 133/186

10.3 How to Determine the Demands of Your Customer
10.4 Modular Sample Filling Units
Did you know?

Easy installation and retrofitting of existing master instruments is possible with all
Sample Filling Units. Simple Plug and Play operation is needed to use the new
sampling device with the Generation M master instruments.
10.4.1 Xsample™ 320 Sample Filling Unit

Overview
Type Filling principle Max. sample Automatic Typical Master

viscosity cleaning applications instrument
Soft drink, DMA™ M,
Peristaltic pump,
syrup, beer, DSA M, Soft
Single the sample is
3,000 mPa.s no non- Drink Analyzer
sample replaced by the
aggressive M,
next
samplesa Alcolyzer M
a aggressive samples in combination with Xsample™ 320 High-resistance

User-independent filling and therefore reduction of handling
errors can be achieved with this sample changer for single
samples. Operators are able to focus on more important tasks
while filling and measurement are performed automatically. The
simple and robust design using a peristaltic pump makes
Xsample™ 320 virtually maintenance-free. The flexible filling
speed enables optimized sample treatment for perfect measuring
results.
Feature/Benefit How/why does the customer benefit?

Virtually Only hoses have to be replaced, which can be done by the customer, no
maintenance-free time-consuming servicing required
“Gas-free” filling of Filling errors due to manual filling are avoided.
samples
Flexible Pump To optimize the filling behavior and the filling time. This can improve the
speed sample throughput.
Less space needed The Plug and Play design saves valuable space on the bench.
10.4.2 Xsample™ 330 Sample Filling Unit

Overview
Type Filling principle Max. Automatic Typical Master

sample cleaning applications instrument
viscosity
DMA™ M
Petrochemic
Yes, up to 2 DSA M,
Single al samples,
Peristaltic pump 3000 mPa.s cleaning Soft Drink
sample aggressive
agents Analyzer M,
samples
Alcolyzer M

Enhancing the benefits of user-independent filling via a peristaltic
pump by adding automatic cleaning makes Xsample™ 330
perfectly suitable for measuring low-viscosity samples with widely
different properties in direct succession. Once measured, the
sample is drained or recovered and the system is automatically
cleaned with up to two rinsing agents. To perfectly prepare the
measurement cell(s) for the next sample a drying step is
performed as well.

Sample recovery With this feature the customer can save money especially when very
after measurement expensive samples like perfumes have to be analyzed with different
possible instruments
Automatic cleaning The automatic cleaning function avoids carryover effects and prevents
residues in the measuring cell(s). The operator does not come in contact
with solvents.
Multiple filling out of To build a mean value of up to 5 measurements out of the same sample
one vial vial.
Less space needed The Plug and Play design saves valuable space on the bench.
Simple handling The whole procedure of filling and cleaning a measuring system is
reduced to filling a sample vial and pressing the <START> button. No
difficult handling with syringes and cleaning agents. The operator can do
other important things during a measurement cycle.
10.4.3 Xsample™ 520 Sample Changer

Overaggressive samples in combination with resistant hoses retrofit kitiew

Soft drink,
Sample Peristaltic pump, DMA™ M, DSA
syrup, beer,
changer the sample is M, Soft Drink
3,000 mPa.s no non-
(24/48/96 replaced by the Analyzer M,
aggressive
vials) next Alcolyzer M
samplesa
a aggressive samples in combination with resistant hoses retrofit kit

The Xsample™ 520 sample changer automatically fills samples from up
to 96 sample vials into the Generation M master instruments via a
peristaltic pump. In a single cycle the instrument independently performs
several filling and measuring procedures in combination with Generation
M instruments. Optional bar code reader for automatic sample scanning
(up to 48 samples) available (Laser Class II).

Virtually Only hoses have to be replaced, which can be done by the customer, no
maintenance-free time-consuming servicing required
“Gas-free” filling of Filling errors due to manual filling are avoided.
samples
Flexible Pump To optimize the filling behavior and the filling time. This can improve the
speed sample throughput.
one vial vial.
Flexible assignment This increases the system flexibility because a certain measuring method
of methods to can be assigned to a certain magazine position. A measuring method
magazine positions contains e.g. measuring temperature or Xsample™ cleaning parameters.
Priority If all magazine positions are loaded and a very urgent measurement is
measurement during required, this feature allows the operator to add this prior sample to the
a measurement actual running measuring cycle and measure it as the next one.
cycle
Optional bar code For automatic sample scanning
reader Bar code types: Code 39, Code 128, Code 93, Codabar, EAN, EAN 128,
UPC, 2/5 Interleaved, Pharmacode
10.4.4 Xsample™ 630 Heated Sample Changer

Overview Xsample™ 630 Heated Sample Changer

Overpressure in
Petrochemical
the vial and
Yes, up to 3 samples e.g.
Sample decreasing 15,000 mPa.s
cleaning very highly DMA™ M
changer sample viscosity at 95 °C
agents viscous oils,
by preheating up
flavors
to 95 °C

Fig. 10-3: Xsample™ 630
Improved heating leads to shorter heating periods, time savings, and increased performance.
Temperatures up to 95°C can be achieved in the system. Even challanging samples can be
measured according to strict ASTM standards. The robust design ensures reliable and virtually
maintenance-free operation. A removable magazine with dedicated non-heated positions saves time
by facilitating sample handling and even makes a second measuring system obsolete

Automatic cleaning The automatic cleaning function avoids carryover effects and prevents
residues in the measuring cell(s). The operator does not come in contact
with solvents.
one vial vial.
cycle
1 displacement of To save time, it is possible to perform multiple measurements without a
the sample without cleaning procedure in-between. The content of the measuring cell is only
cleaning in-between replaced by a new one.
Filling and drying Especially for highly viscous samples, 2.0 bar external compressed air
with external can be used optionally for filling and drying, this saves time
compressed air
Auto air check To check automatically, if the measuring cell is clean before a sample is
before filling filled and measured.

Accurate Electrically controlled, no external water bath required
temperature control Accurate temperature control according to the requirements of the
(heated) application and strict standards.
Convenient No handling of hot syringes! For the user this means easy sample
operation (heated) handling because the magazine, needle, sensors and hoses are
electrically preheated to the set temperature.
Detailed information about cleaning can be found in the cleaning recommendations in

the Appendix of the instruction manual.
10.4.5 Xsample™ 530 Sample Changer

Overview Xsample™ 530 Sample Changer

Petrochemical
samples e.g.
Yes, up to 3 viscous oils,
Sample Overpressure in
36,000 mPa.s cleaning aggressive DMA™ M
changer the vial
agents samples, volatile
samples e.g.
vodka
The Xsample™ 530 sample changer for all DMA™ Generation M

instruments and Lovis M/ME viscometers handles a wide range of
liquid viscosities. The system’s adaptive filling power is controlled
so that all samples from plain water to highly viscous oils (of up to
36,000 mPas) are filled in a minimum of time.
Its fully automatic filling, rinsing and drying ensures perfect results
without any sample cross-contamination. The 71-position
magazine for unattended operation can be exchanged with one
hand to ensure easy handling and filling. With up to three cleaning
liquids, Xsample™ 530 is ready to measure a great diversity of
samples in one run.

Removable The magazine can be exchanged easily by one hand and carried to
Magazine wherever it is needed.
Different filling Automated or manual selection from 3 different filling pressure sources
modes (piston pump, internal air pump or external compressed air (2 bar)) to get
the sample into the measuring cell
Automatic cleaning 3 different rinsing agents can be used in any order to ensure the best
cleaning results. Each cleaning step can be modified on its own and
different cleaning modes ensure perfect results without any sample cross-
contamination.
Flexible cleaning Various pre-programmed cleaning modes are supplied and due to an
modes expert mode flexible adjustment to users’ individual needs can be set.
Optional bar code Bar code reader for up to 71 positions ensures easy sample designation
reader and traceability
cycle
Overfilling sample For some applications the sample filling behavior can be improved by
volume overfilling. You can specify additional sample volume to be filled.
Displacement of the To save time, it is possible to perform multiple measurements without a
sample without cleaning procedure in-between. The content of the measuring cell is only
Filling and drying Especially for highly viscous samples, 2 bar external compressed air can
with external be used optionally for filling and drying, this saves time.
compressed air

10.5 Stand-alone Sample Filling Units
10.5.1 Xsample™ 340 (with cleaning)

Overview Xsample™ 340 Sample Changer

Petrochemical
samples
Yes, up to 2
Single aggressive
syringe 36,000 mPa.s cleaning DMA™ M
sample samples,
agents
volatile
samples
Xsample™ 340 is a single unit for different types of syringes that

automatically fills all DMA™ Generation M instruments and Lovis
M/ME viscometers using your favorite syringes. Perfect filling and
excellent precision is facilitated by the system’s adjustable filling
speed. Many years of trouble-free operation are guaranteed due to the
robust and streamlined design. Xsample™ 340 (with cleaning) is
automatically prepared with up to two rinsing agents, ensuring perfect
measuring conditions regardless of the operator and sample.
The sampler is able to handle samples with viscosities up to 36,000
mPa.s while a force sensor ensures safe operation under any
condition.

Different syringe Whether you already use 2, 5 or 10ml syringes you can use your favorite
sizes size by a simple exchange of an adapter.
Adjustable filling Perfect filling and excellent precision is facilitated by the system’s
adjustable filling speed.
Intelligent operation Viscosities up to 36,000 mPa.s can be handled while a force sensor
ensures safe operation under any condition.
Automatic cleaning 2 different rinsing agents can be used in any order to ensure the best
cleaning results. Each cleaning step can be modified on its own to ensure
perfect results without any sample cross-contamination.
High cleaning If “Toggle” is activated small air-liquid sections (air-gaps) will be generated
performance in the hose during the rinsing procedure to ensure high cleaning
performance.
Displacement of the To save time, it is possible to perform multiple measurements without a
sample without cleaning procedure in-between. The content of the measuring cell is only

Draining and drying Especially for highly viscous samples, 2 bar external compressed air can
with external be used optionally for draining and drying, this saves time.
compressed air
10.5.2 PFD (Plus) / SFD

These ones you already know from section 8.! Nevertheless, let’s see how they fit the portfolio of
Anton Paar filling devices.
Overview

Single 6 bar aqueous no PFD(Plus): Soft Refer to
sample overpressure in drink, beer, mineral chapter 8
package water
SFD: (sparkling)
wine

No CO2 losses as piercing Filling under pressure prevents CO2 from degassing out of the
is performed under sample. Therefore, no degassing of the sample is required, the
pressure operator saves time.
Different bottle adapters/ The PFD Plus with an additional spiter shield for protection at the
filling devices for different back enables to fill the full amount of sample out of glass and PET
package sizes and types bottles.
Safe handling due to In the unlikely event of bursting a package, the operator is
safety shield/housing protected.
No sample preparation Filling under pressure prevents CO2 from degassing out of the
required - high sample sample. Therefore, no degassing of the sample is required; this
throughput saves time and provides a high sample throughput.
Easy handling No time-consuming degassing required because of filling with 6 bar
overpressure

10.6 Competition
Xsample™ 320
Competitors Product Picture Additional competitor information

Type: single sample
Krüss DS7070 Filling principle: Peristaltic pump

Peristaltic Pump • For aggressive samples
www..kruess.com • Adjustable pump speed
Type: single sample

Filling principle: Peristaltic pump
Max. sample viscosity: 1.000 mPa.s
Mettler FillPal™
The FillPal is available in 2 versions:
https://www.mt.com/at/
de/home.html • FillPal “Food” for water based samples such
as beer, milk and soft drinks.
• FillPal “Chem” is suitable for aggressive
samples including most acids, bases and
organic solvents.
Xsample™ 330

Type: single sample
Filling principle: Piston pump
Number of rinsing liquids: 2
Rudolph ECS Max. sample viscosity: 3.000 mPa.s
(Easy Clean Auto
Automatic cleaning: yes
Sampler)
Sample recovery: yes
The Easy Clean Auto Sampler is very similar to
Xsample™ 52, but specified for higher viscous
samples.
Xsample™ 530/630
The Kyoto U-551 is similar to Mettler SC-1

Kyoto-KEM U-551
concerning features and technology (see
www.kyoto-kem.com
following page)

Type: single sample
Filling principle: suction/overpressure
Disadvantages:
Mettler SC-1 • Requires much more space on the bench -
www.mt.com higher power consumption
• Moving parts with dismounted safety cover
• Filling samples with viscosities up to 30,000
mPa.s (5.000 mPa.s less than Xsample™
352)
• Does not support operation with external
compressed air → longer drying time
Advantages:
• Active cleaning of the outside of filling needle
with rinsing agent
Type: single sample
Filling principle: overpressure
(30.000 mPa.s with the heating option)
VIDA 40/50 (H)
Disadvantages:
• high power consumption of 400 W
• heating option is limited to 70 °C
Advantages:
• space saving sample changer concept

Xsample™ 530

Type: sample changer
Filling principle: suction/overpressure
Disadvantages:
Mettler SC-30
• Requires much more space on the bench
www.mt.com
• Higher power consumption
• Moving parts with dismounted safety cover
• Filling samples with viscosities up to
30,000 mPa.s
• Does not support operation with external
compressed air → longer drying time
Advantages:
• Active cleaning of the outside of filling needle
with rinsing agent
Kyoto-KEM CHD-502
The Kyoto CHD-502 is similar to Mettler SC-30
www.kyoto-kem.com
concerning features and technology.
Type: X/Y sample changer

Filling principle: suction or overpressure
Rudolph CETAC Disadvantages:

ASX-1400 • requires much more space on the bench
www.cetac.com • Installation requires a specialist
• moving needle not protected
• long filling time of high viscous samples due
to long sample hoses
Advantages:
• active cleaning of the outside of filling needle
with rinsing agent
• 3 rinsing liquids

Filling principle: overpressure
(30.000 mPa.s with the heating option)
VIDA 40/50 SC(H)

Disadvantages:
• high power consumption of 400 W
• heating option (for sample changers too) is
limited to 70 °C
• sample changer needs to be factory-pre-
installed: no upgrade-possibility at the
customer´s
Advantages:
• space saving sample changer concept
Filling principle: overpressure/suction
Rudolph
AutoFlex R837 Disadvantages:
• No Plug&Play Design
Advantages:
• Automatic low solvent and waste full level
detection
• Active needle cleaning
• Flexible test tube size

1. Assign each sample filling unit to its main group, type and filling principle (mark with a cross).
Unit Main Group Type Filling principle
Modular Stand- Single Sample Peristaltic Over- Over- Syringe Over-
Plug and alone sample changer pump pressure pressure pressure
Play in the vial and pre in
heating package
Xsample™
320
Xsample™
330
Xsample™
520
Xsample™
340
Xsample™
630
Xsample™
530
PFD/SFD
2. Find the right Xsample™ for your customers’ needs.

For very highly viscous samples
A PFD/SFD
Xsample™ 340/530 and

B Low viscous, corrosive samples
Xsample™ 630 are recommended.
Highly viscous samples with multiple samples
C Xsample™ 520
per day
Dissolved gas analyses in Beverage
D Xsample™ 530
industry with few samples
Non corrosive samples with multiple
E Xsample™ 330
samples per day
3. Name at least one competitor in the field of the following sample filling units.
Xsample™ 530 _____________________________________________________
Xsample™ 320/330 _____________________________________________________
Xsample™ 340 _____________________________________________________

11. Modular Measuring Systems
By combining several of the instruments you already got to know you can create measuring
systems that are capable of measuring numerous measuring parameters simultaneously. This
saves the lab personnel a lot of time and gives them one printout – containing all relevant data on
one and the same sample. The following chapter gives an overview of LDC systems.
The advantages of combined systems are:

• Maximized efficiency in the laboratory by saving work time.
• The measured data is collected on one printout and one data file.
• A number of measuring instruments can be combined to a LIMS (Laboratory Information
Management System).
• A system saves space on the lab bench.
11.1 What Does a System Look Like?
Depending on the instruments that need to be combined, Anton Paar supplies two different system
solutions:
• the Plug and Play solution and
• the PC-based solution.
The Plug and Play solution
A Plug and Play system always consists of a master instrument and one or more measuring modules
and/or filling modules connected to the master instrument. The whole system is operated via the user
interface of the master instrument, which also controls the system and handles the whole data
processing and printouts.
The advantage?
It is extremely easy to install and operate. As soon as a module is connected to the master
instrument, it is automatically recognized and additional settings and methods are automatically
available on the master instrument.
Plug and Play systems described in further detail within this document are e.g.
• measuring systems for the beer, wine and soft drink industry (Alcolyzer Beer Analyzing System,
PBA-B, PBA-W, PBA-S, PBA-SI, PBA-SD and PBA-SID Generation M)
• Modulyzer Prime Class – Combined System for Density / Refractive Index / pH / Turbidity,
Alcohol, Viscosity or Optical Rotation.
148/186 11. Modular Measuring Systems XDLIE005EN-K

Fig. 11-1: Modulyzer Prime Class
The PC-based solution

The Modulyzer Unlimited Class from Anton Paar can be controlled via the software tiamo™ (from
Metrohm) additionaly a colorimeter and/or a polarimeter (MCP 200/300/500) can be included in the
system. The system is open to non–Anton-Paar instruments, which enables the user to add a system
component that is currently not provided by Anton Paar (e.g. a colorimeter).
11.2 Measuring Systems for Beer, Wine and Soft Drinks
For beverage applications, standard configurations of Anton Paar instruments are available as
systems which can be expanded by some optional modules.
Below, the basic composition of each system is described and the possible additional modules are
mentioned.
Required reading
It is essential that you have carefully read the previous chapters about the instruments,
which - put together - form our systems!
First, we have a non-pressurized system, the Alcolyzer Beer Analyzing System.

Then, we have pressurized systems which measure directly out of the bottle or can. They are called
PBA (Packaged Beverage Analyzers).
There is the PBA-S and PBA-SI for Soft Drinks, a PBA-SD and PBA-SID for Regular and Diet
Soft Drinks, a PBA-W for Wine and the PBA-B for Beer (includes additionally an Alcolyzer Beer
ME).
XDLIE005EN-K 11. Modular Measuring Systems 149/186

11.2.1 Alcolyzer Beer Analyzing System (Non-Pressurized)
The Alcolyzer Beer Analyzing System consists of a DMA™ 4500 M or DMA™ 5000 M, an Alcolyzer
Beer ME and an Xsample™ 520 sample changer.
Fig. 11-2: Alcolyzer Beer Analyzing System
11.2.1.1 How Does the Alcolyzer Beer Analyzing System Measure?

The sample changers use a carousel with vials filled with the sample. The sample will be sucked out
of the vials and filled into the measuring system by means of a peristaltic pump.
The system works at atmospheric pressure, so if your samples contain CO2, degassing is necessary.
Dissolved CO2 in the sample would otherwise form bubbles and falsify the measurement. Therefore,
the sample has to be degassed before measurement.
Did you know?

… how to degas a sample easily? Fill your sample into a container with a cap, shake
it, open the cap and listen carefully! Repeat this until you cannot hear any gas escaping
the container anymore! Then, degassing is done!
For a detailed description see the Alcolyzer Beer ME/Alcolyzer Beer Analyzing System
instruction manual, chapter “Sample Preparation”. There, the degassing process is
described according to the MEBAK regulations.
One of the big advantages of our systems: Fill the sample once and get results for up to 7
parameters!
For details on alcohol and density measurement, check out the corresponding chapters for Alcolyzer
and DMA™ Generation M!
11.2.1.2 What Does the Alcolyzer Beer Analyzing System Measure?

By measuring alcohol content and density, a lot of important beer parameters can be calculated.
Some of them are: apparent extract, real extract, original extract, apparent degree of fermentation,
real degree of fermentation, calories, extract gravity, specific gravity of the alcohol …

For a full list of relevant beer parameters, see the Alcolyzer Beer Analyzing System
manual, Appendix “List of Output Quantities”.
For the formulas of the calculation see the Alcolyzer Beer Analyzing System manual,
Appendix “Calculations”.
Do you know?
…how to adjust your Alcolyzer Beer Analyzing System? The Alcolyzer measures the
alcohol content using Near Infrared Spectroscopy (NIR). An adjustment is done by
measuring water (zero point) and a sample with known alcohol concentration (slope
adjustment).
If you are measuring a binary solution of ethanol and water, only density is enough to
calculate an exact alcohol content. So for a slope adjustment, just fill an ethanol and
water solution and start the adjustment procedure. The Alcolyzer takes the alcohol
value for the adjustment from the density meter automatically.
11.2.2 Packaged Beverage Analyzers: PBA (Pressurized)

These pressurized systems consist basically of a master instrument (DMA™ M or SDA M), a
CarboQC ME and a PFD / PFD Plus or SFD Piercing and Filling Device.
In this basic configuration the system is called PBA-S: Packaged Beverage Analyzer for Soft Drinks
If you use a Soft Drink Analyzer M instead of the DMA™ M, you have a PBA-SI: Packaged Beverage
Analyzer for Soft Drinks with Inversion
If you add a DietQC™ ME measuring module to your PBA-S or PBA-SI, you have a PBA-SD:
Packaged Beverage Analyzer for Regular and Diet Soft Drinks or a PBA-SID: Packaged Beverage
Analyzer for Regular Soft Drinks with Inversion and Diet Soft Drinks.
If you add an Alcolyzer Beer ME module to the PBA-S, you have a PBA-B: Packaged Beverage
Analyzer for Beer
If an Alcolyzer Wine will be used instead of the Alcolyzer Beer ME, you just created a PBA-W:
Packaged Beverage Analyzer for Wine.

11.2.2.1 How Does a Packaged Beverage Analyzer Measure?
All pressurized systems have to include the CarboQC ME, as the CO2 exact content of the beverage
is required to apply corrections to measured parameter such as density or pH but it is also acting as
a valve in order to maintain the operating pressure in the system.
In these systems, sample is filled out of the package by employing overpressure of 6 bars. In this
way, no degassing is needed as all the CO2 stays in solution and does not form bubbles during the
measurement.
Did you know?

… that dissolved gases like CO2 increase the density of a liquid sample?
The big advantage of a PBA system is that the sample is measured under pressure, so
no CO2 is lost and no sample preparation is needed. The measured CO2 value then is
used to do correction calculations for the density and thus, all dependent parameters
in one measuring cycle.
So the DMA™ measures a density, and together with the CO2 result, you get a
CO2-corrected density result without degassing!
11.2.2.2 PBA-S
The PBA-S consists of a DMA™ M density meter, a CarboQC ME
dissolved carbon dioxide meter, and the PFD Piercing and Filling
Device in its basic configuration.
For soft drink bottlers, the CO2 content is important because it strongly
influences the flavor of a drink and it is a considerable cost factor.
The sugar content is a very important parameter as sugar is a costly
ingredient in a soft drink. The most common unit is °Brix which is
mass % of sucrose in the solution.
Other units are degree Plato (°P) and Baumé.
11.2.2.3 PBA-SI
The PBA-SI consists of a Soft Drink Analyzer M, a CarboQC ME dissolved carbon dioxide meter, and
the PFD Piercing and Filling Device in its basic configuration.
Same as on the PBA-S but on top the PBA-SI allows controlling the sugar inversion process. With
the additional integrated sound velocity cell of the Soft Drink Analyzer M the instrument provides also
detailed information on the sugar content before sugar inversion started (Concentration Sugar
Fresh), respectively the sugar content when being fully inverted (Concentration Sugar Inverted) and
the Degree of Inversion.
11.2.2.4 PBA-SD / PBA-SID

What is PBA-SD/SID and what is it used for?
A PBA-SD/SID Generation M, a Packaged Beverage Analyzer for Regular and Diet Soft Drinks with
or without sugar inversion, is a combination of a DMA™ M Density Meter/Soft Drink Analyzer M, a
CarboQC ME, a DietQC™ ME Measuring Module and a Piercing and Filling Device such as

PFD (Plus) for the analysis of soft drinks with and without sugar (see fig. 11-3). PBA-SD/SID M gives
information on the dissolved CO2 concentration and the density or concentration in e.g vol. or, in
dietary, non-sugared soft drinks, the dissolved CO2 concentration and the Diet concentration.
For the determination of soft drinks containing sugar, the use of a Soft Drink Analyzer M instead of a
DMA™ M might be the ideal option: the Soft Drink Analyzer M not only allows the precise
determination of density and therefrom the actual content of sugar (°Brix), but also concentration
sugar fresh (°Brix) and concentration sugar when fully inverted. The system is then called PBA-SID:
Packaged Beverage Analyzer for Regular Soft Drinks with Inversion and Diet Soft Drinks.
“Diet” is commonly expressed in "% Target" which expresses the agreement of the composition of
the diet drink with the target. If the beverage corresponds to the standard then it reads 100% Target.
If the beverage is process water, the instrument will show 0% Target. Some laboratories express the
Diet concentration in mL NaOH or g/L Total Acids (titratable acidity).
DietQC™ ME
Measuring
Module
PFD Piercing
CarboQC ME and Filling
Beverage Device
Carbonation
Module
DMA™ 5000 M
Density Meter
Fig. 11-3: PBA-SD Packaged Beverage Analyzer for Regular and Diet Soft Drinks
Optionally, an Option O2 oxygen measuring module and a pH measuring module can be connected.
The following table summarizes the characteristic instrument specifications. For more details, refer
to the PBA-SD/SID manual and to the manuals of the respective instruments and modules.
PBA-SD/SID M Specifications
Beverage type Repeatability Instrument

standard deviation
Regular soft drinks 0.01 °Brix DMA™ 5000 M/SDA M
Diet soft drinks (colored samples) 0.2% a DietQC™ ME
Diet soft drinks (uncolored or turbid 0.4% a DMA™ 5000 M/SDA M
samples)
Diet soft drinks (uncolored UV) 0.4% a DietQC™ ME with option for
uncolored drinks
CO2 0.01 g/L (0.005 vol.) CarboQC ME
CO2
Sample volume (all products) min. 150 mL
a for typical diet soft drink compositions

Did you know?
… that several studies were undertaken to shed light on the effects of soft drink
consumption on health. The literature cites that obesity and type 2 diabetes in the
United States increased alongside the rise in the consumption of soft drinks that
contain sugar.
How does a PBA-SD/SID work?

For the concentration determination of a diet soft drink, either DMA™ 5000 M / SDA M or
DietQC™ ME is used.
The vast majority of diet soft drink samples are colored. In case of a colored sample, DietQCT™ ME
does the analysis. DietQC™ ME is a colorimeter that determines the light absorption in the spectral
range of visible light (430 nm). Based on the DietQC™ ME measurement, the diet concentration of
cola beverages and other colored diet drinks is determined in only around 3 minutes. A temperature
controlled measuring cell ensures fast and reproducible results. See fig. 11-4, it illustrates what
happens inside the DietQC™ ME measuring cell.
Fig. 11-4: Schematics of the DietQC TM ME measuring cell
If the sample is turbid or colorless, the analysis is performed by density measurement with
the DMA™ 5000 M density meter or Soft Drink Analyzer M. Typical diet soft drinks only show small
density differences in the range of 0.001 g/cm³ when compared to process water. Extensive tests
showed that this small density increase can be accurately determined by a DMA™ 5000 M density
meter or Soft Drink Analyzer M. However, the analysis may take around 2 minutes longer.
It is also possible to order a DietQC™ ME with option for uncolored drinks to reduce the
measuring time as well as the influence coming from the quality fluctuations of the process
water. In this instrument, the light absorption of the sample is measured at two wavelengths: At 430
nm as in the normal DietQC™ ME version, and additionally in the UV range at 280 nm. The UV
measurement can be used to measure uncolored diet drinks. The most common type is diet lemon
or lime drinks like Sprite Zero™ from the Coca-Cola Company or diet versions of 7up from Pepsi.

System configuration based on customers samples
Diet Product Standard Configurations Diet Analysis done by
Colored diet beverages: DMA™ 4100 M / DietQC™ ME
brown (like cola), yellow or red DMA™ 4500 M (Diet-colored → 430nm)
and non-turbid + DietQC™ ME
+ CarboQC ME
+ PFD
Turbid diet beverages: DMA™ 5000 M / SDA M DMA™ 5000 M or SDA M
turbid, but only few large or + DietQC™ ME (Diet-Uncolored → density)
sedimenting particles are + CarboQC ME
visible + PFD
Colorless diet beverages: DMA™ 4100 M / DietQC™ ME with option for
uncolored and non-turbid (e. DMA™ 4500 M uncolored drinks(Diet-
g. many diet lemon drinks) + DietQC™ ME with option Uncolored UV → 280nm)
for uncolored drinks
+ CarboQC ME
+ PFD
Other diet beverages: DMA™ 5000 M / DMA™ 5000 M /
pink, green, … or blue colored SDA M SDA M or DietQC™ ME
+ DietQC™ ME with option with/without option for
for uncolored drinks uncolored drinks
+ CarboQC ME Strongly depending on the
+ PFD sample!
There is not really a strict definition of “Diet” as the beverages are composed of various constituents
such as caffeine, artificial sweeteners, colorants, acids (phosphoric acid, citric acid, …),
preservatives, flavors – just to name a few of them. All diet beverages have one feature in common:
they do not contain any sugar!
Common laboratory reference methods are based on the determination of a so-called lead
substance. The following table lists the most frequently used ones and the reference determination
methods.
Common laboratory reference methods for leading substances
Beverage Leading substance Laboratory Reference

Method
Diet Cola Phosphate Photometric method or ion
chromatography
Diet Cola Caffeine HPLC
Most Diet Beverages Total Acids Titration
All these reference methods need chemicals, instrumentation and a lot of time and the quality of the
results is highly dependent on the skills of the operator. All these methods also need degassing of
the sample which leads to additional time consumption.

A PBA-SD/SID cannot fully replace these reference methods because the reference methods are
needed to adjust the PBA-SD/SID.
How to perform a measurement with PBA-SD/SID
A daily zero adjustment is carried out using process water. This zero adjustment eliminates the
influence of density fluctuations in the process water due to its salinity.
The adjustment of a PBA-SD/SID system is performed with the respective laboratory reference
method. This allows precise concentration adjustment for each type of diet drink. A new measuring
method for each diet drink type is automatically created and saved by the master instrument. During
the adjustment, the user defines if the soft drink…
• …is colored (measurement via DietQC™ ME)
• …uncolored (measurement via DietQC™ ME with Option for Uncolored Drinks)
• …uncolored or turbid (measurement via DMA™ 5000 M or Soft Drink Analyzer M).
PBA-S(I)D systems allow the determination of diet soft drinks as well as soft drinks containing sugar.
The ° Brix content of soft drinks that contain sugar and turbid or colorless diet soft drinks are
measured by the high-precision DMA 5000 M or Soft Drink Analyzer M with CO2 correction. Colored
diet soft drinks are determined by a temperature-controlled high-precision color measurement. This
optical method (430 nm respectively 280 nm) does not show any cross-sensitivity to process water
salinity.
Competition and market information
The biggest and best known competitor is Maselli. Maselli Misure (http://www.masellimisure.com) is
an Italian company distributing the so-called DR 10 Easy Diet™
(http://www.maselli.com/en/product/dr10-lab-differential-refractometer).
DR 10 Easy Diet™ is a refractometer that compares the properties of the respective beverage
sample to the properties of the process water used. A typical laboratory instrument, it is equipped
with a large touch screen. The DR 10 Easy Diet™ is limited to the analysis of Diet products. It is not
able to do sugar analysis in regular products such as the PBA-SD/SID. Another competitor is ACM
(www.acm.co.at).
Cross selling potential and selling arguments

PBA-SD/SID customers may also be interested in the simultaneous determination of oxygen or the
pH value. It is also possible to upgrade existing PBA-SD/SID M systems with an Option O2 and a
pH ME.
Further, all PBA-SD/SID customers also need process equipment for soft drink production like Cobrix
and other products of the process instrumentation department. A few suggestions about prospective
sales are listed in the table beyond.
Customer already has Customer might be interested in

DMA™ 5000 M pH ME, CarboQC ME, DietQC™ ME or
DietQC™ ME with the option for uncolored
drinks
DMA™ 5000 classica CarboQC/CboxQC™ (lab version)
PBA-S(I)D Option O2, pH ME, Option UV for uncolored
drinks
a already discontinued

There are many good reasons for purchasing a PBA-S(I)D!
• user-friendly and easy to operate
• does not require sample preparation such as degassing
• no chemicals needed
• already existing PBA-S(I) Generation M and PBA-S classic systems can easily be upgraded
• modular setup allows for step-by-step extension, full flexibility for possible future requirements
• several parameters out of the same beverage container saves time
• PBA-SD/SID is able to provide information about the sugar concentrator in regular products as
well
11.2.2.5 PBA-B
The PBA-B (fig. 11-5) consists of a DMA™ M density meter, a CarboQC ME dissolved carbon dioxide
meter, an Alcolyzer Beer ME alcohol meter and a Piercing and Filling Device such as PFD/ PFD Plus.
Fig. 11-5: PBA-B
What does it measure?

Additional to the classical beer parameters like density, alcohol content, real, apparent and original
extract and degree of fermentation, etc. (which also can be determined with the Alcolyzer Beer
Analyzing System), the PBA-B gives:
• CO2 concentration, air content, current pressure and package pressure.
• The most common units for CO2 are: g/l and % vol.
• A typical beer or soft drink has about 5 g/l CO2.
For details, see the Appendices “Output Quantities” in the corresponding module
manuals!

Did you know?
… that some bottlers handle both beers and soft drinks. The PBA-B also can be used
as a PBA-S and gives you the relevant parameters for soft drinks like °Brix!
Sales Arguments:
• No sample preparation is required due to which PBA-B finishes the analysis up to 6 times faster
than conventional analysis methods.
• Increased accuracy of measurements as no sample preparation is required (human error is

eliminated)
• Fast results granted for online measurement systems
• Short production downtime due to fast analysis
Did you know?

… that we do have an “ROI-calculator” (Return On Investment) available, which allows
you to present the customer the savings he can achieve when using a PBA-B
Generation M?
11.2.2.6 PBA-W
The PBA-W (fig. 11-6) consists of a DMA™ M density meter, a CarboQC ME dissolved carbon
dioxide meter, an Alcolyzer Wine ME alcohol meter and a Piercing and Filling Device such as PFD/
PFD Plus or SFD.

Fig. 11-6: PBA-W
What does it measure?

Additional to the commonly analyzed parameters, like density, alcohol content and total extract
(which also can be determined with the Alcolyzer Wine Analyzing System), the PBA-W gives CO2
concentration, air content, current pressure and package pressure.
The most common units for CO2 are: g/l and % vol. A typical sparkling wine can show a CO2
concentration of 7 g/l and more.
For details, see the Appendices “Output Quantities” in the corresponding module
manuals!
Sales Arguments:
• No sample preparation is required due to which PBA-W finishes the analysis more than 5 times
faster than conventional analysis methods
• Increased accuracy of measurements as no sample preparation is required (human error is

eliminated)
• Short production downtime due to fast analysis

• All parameters are determined simultaneously
• Easy operation – Place the sample in the filling device, apply pressure and press “START”.
Did you know?

… that we do have an “ROI-calculator” (Return On Investment) available, which allows
you to present the customer the savings he can achieve when using a PBA-W
Generation M?
11.2.3 Optional Modules

• pH Option for Generation M masters
Basically, the pH option can be installed and also retrofitted in all Generation M master instruments
like DMA™ M, Alcolyzer M, DSA 5000 M and Soft Drink Analyzer M.
The pH option consists of an electronic board, the measuring cell (electrode holder), and a pH
electrode. If a pH option is retrofitted, the electronic board has to be mounted into the master
instrument (e.g. DMA™ M).
Of course, the pH option can also be part of our measuring systems, e.g. the Alcolyzer Beer
Analyzing System.
Be aware that if you install the pH option in a PBA system, you have to order the pressure-proof
version of the pH electrode!
• Color Option for Alcolyzer Beer M / ME and Alcolyzer Spirits M / ME (see section 4.8.1)
These instruments can be delivered or also later upgraded with a color option.
TIP – In Generation M, pH and color options are independent! You can install either pH or color
option or both!
• Option O2 for the CarboQC ME (see section 7.10)
The PBA systems can be upgraded by an option for dissolved oxygen too. In Generation M, this is a
little add-on on the CarboQC ME, the Option O2.
NOTICE – Be aware that we are talking about extremely low concentrations of oxygen. A common
value in beer is 20 ppb, which equals only 0.002%! So for demonstrating this parameter, always use
only cans and glass bottles out of the SAME BATCH!
Plastic bottles for example are not 100% tight for oxygen, so the value will differ a lot from bottle to
bottle!
• HazeQC ME, Turbidity Module (see section 9.)
For a clear sight in cloudy media! HazeQC ME, Anton Paar’s turbidity module, is especially
interesting for beer and whiskey applications. It is fully MEBAK and EBC compliant and puts the final
touches to your PBA system!

1. PBA Generation M systems: Is that correct?
□ Measurement is done pressure-less
□ Measurement is done at 5 bar pressure
□ Cans, glass bottles and PET bottles can be measured
□ No degassing necessary because bubbles do not influence the PBA
□ No degassing necessary because measurement is done under pressure
2. Which parameters can be measured with a PBA-B Generation M?

Check if correct:
□ Titratable acids
□ Density
□ CO2 content
□ Bitterness
□ Alcohol content
□ Extract
□ Diacetyl

3. Which options can be added to a PBA-B Generation M?
□ Titratable acids
□ Oxygen
□ SO2
□ Bitterness
□ pH
□ Turbidity
□ Beer color
□ FAN
4. What is the typical sample preparation for beer before it is filled into the Alcolyzer Beer Analyzing
System?
______________________________________________________________________________
5. A PBA-SI is a PBA-S that additionally can measure the degree of inversion of the sugar (°Brix
fresh, °Brix inverted). Therefore, one more parameter has to be measured. Which one?
Check if correct:
□ Color
□ Sound velocity
□ pH
□ Sweetness
□ Optical rotation
□ Viscosity

6. PBA-SD/SID: Tick the right answer(s).
Measuring diet beverages with a PBA-SD/SID saves time! Tick the correct answer: The measuring
time per colored sample is
□ 2 minutes per sample
7. PBA-SD/SID: Tick the right answer!

Right Wrong
PBA-SD/SID can be used for soft drinks with and without sugar
Colorless Diet samples are measured with the DMA™ 4100 M density
meter
The sample has to be degassed prior to measurement
Only colored samples can be measured with PBA-SD/SID
8. PBA-SD/SID: Fill the gaps (one word per line)!

PBA-SD consists of a DMA™ M density meter, a DietQC™ ___ , a CarboQC ME and a Piercing and
Filling Device such as ________________ or ____________. PBA-SD can be upgraded with an
____________ O2 and a ____ ME. If the fresh and inverted Brix also need to be determined, the
___________ ___________ M has to be replaced by a _______ ______ _____________ M/P.

12. MKT 10 and MKT 50 – Millikelvin Thermometers
Now let’s come to a topic that is already a part of our everyday life. Even on weekends, when we
take time of from our hard working life, we maybe think about doing an outdoor trip and ask
ourselves: By the way, what’s the temperature outside?
Temperature measurement – at the highest precision – is also needed by our customers. Get
more insight in the following chapter.
The MKT 10 and MKT 50 are Millikelvin thermometers. The abbreviation MKT is deduced from
MilliKelvin Thermometer. The number 10 indicates the accuracy and shows that it is less accurate
than the MKT 50. MKT 10 and MKT 50 are the two Anton Paar Millikelvin thermometers. Two
instruments with that high accuracy underline the importance of accurate temperature measurement
for accurate density determination.
12.1 How Does MKT 10 Look Like?
Pt 100 temperature sensor

(in the protection sleeve)
2.8" Display
Function keys
Temperature sensor cable
<On/Off> key
Thread for the optional
protection tube
12.2 How Does MKT 50 Look Like?
LDC Display
Sensor Input 1
Sensor Input 2
Sensor
Cable
Pt 100
Keypad
164/186 12. MKT 10 and MKT 50 – Millikelvin Thermometers XDLIE005EN-K

12.3 Why Measure Temperature that Accurately?
Almost all chemical and physical processes are influenced by temperature.

Therefore, a reliable measurement of temperature is so important. To guarantee that a temperature
sensor gives correct readings, it has to be calibrated regularly.
The calibration interval depends on the type, use and expected accuracy of the sensor.
Example 0.1 °C comparison calibration:
In a big, modern brewery, there are up to 1000 temperature sensors installed. Some of them need to
be calibrated only if they are replaced. Others, more critical ones, have to be calibrated regularly
twice a year.
MKT 50 has two channels to measure the reference sensor and device under test simultaneously.
The sensor under test and a reference sensor are placed in a temperature-stable system. After
reaching thermo-dynamic equilibrium the two temperatures are compared.
A common uncertainty that is expected here is 0.1 °C.
As you know, for a legitimate calibration, the reference instrument should be 3 times to 10 times
more accurate than the instrument to be calibrated.
The basic uncertainty of the MKT 50 is 0.001 °C, though the standard sensors provided by Anton
Paar are calibrated to 0.01 °C accuracy.
So the system accuracy (MKT 50 + sensor) depends mostly on the sensor and is 0.01 °C (10 mK).
Therefore the MKT 50 is perfectly suitable for calibration applications of 0.1 °C accuracy!
Optional reading
For more details about comparison calibration, see the Application Report and
Application Flash "Calibration of Temperature Sensors Using an MKT 50".
12.4 How Do MKT 10 and MKT 50 Work?
Basically the MKT 50 measures electrical resistance in the range 0 to 440 Ohms and the MKT 10 in
the range of 80 to 175 Ohm. As all electrical conductors change their resistance with temperature,
the resistance value can be used as an indicator for the temperature.
As the resistance of a material depends on its mechanical dimensions and purity of the material itself,
platinum is commonly used because it is chemically quite inert (which means there is no chemical
reaction which may change the sensor’s behavior).
A Pt100 sensor changes its resistance by about 0.4 Ohm per °C (per K).
Did you know?

… that the most common platinum sensor has 100 Ohms resistance at 0 °C and is
therefore called Pt100.
Other common sensors are Pt1000 and Pt25.

The problem is that the correlation between temperature and resistance is not completely linear.
Therefore, for high-accuracy applications, for every single sensor calibration coefficient has to be
determined.
XDLIE005EN-K 12. MKT 10 and MKT 50 – Millikelvin Thermometers 165/186

12.5 Calibration Standards: DIN EN 60751 and ITS-90
There are two common standards, that are used to calculate a temperature from a resistance value:
• EN DIN 60751 former IEC 751 (Calender-Van-Dusen Equation)
• ITS-90: International Temperature Scale 1990
The most important unique parameter of a sensor is its resistance at 0°, the R0 value. This is needed
for both EN DIN 60751 (IEC 751) and ITS-90.
12.5.1 DIN EN 60751 (former IEC 751)

The DIN EN 60751 just needs three further coefficients: A, B, C
The constant C is only needed if temperatures below 0 °C are measured above 0 °C it has no
influence!
For the range between -200 °C to 0 °C the equation is
R(t) = R0[1 + A * t + B * t2 + (t − 100)C * t3]
For the range between 0 °C to 661 °C the equation is
R(t) = R0(1 + A * t + B * t2)
Did you know?
The DIN EN 60751 (former IEC 751) is the most common calibration standard and all
sensors provided by Anton Paar come with the three or four coefficients needed: R0,
A, B, C.
12.5.2 ITS-90
The ITS-90 employs up to 7 coefficients depending on the temperature range. This standard is
mostly used by high-end calibration services.
For more details on these calibration standards, see the Appendix “Temperature Calculation
Methods” in the MKT 50 Manual.
12.6 How to Use MKT 50
12.6.1 How to Set a Sensor Calibration

If you want to setup a MKT 50 with a new sensor, first you have to enter the calibration coefficients
of this sensor into the instrument. The coefficients are stated in the calibration certificate of the Pt100
sensor.
Just enter the menu, create a new sensor calibration (mostly IEC 751), and type in the
coefficients as stated on the certificate. You can store up to 30 different calibration sets for 30
sensors in the MKT 50. Now, you have to select which sensor is really connected to the MKT 50 and
which calibration set shall be used for that.
12.6.2 How to Select the Previously Created Calibration for Your Sensor
Using the menu function "Select Sensor", you now can define which calibration data shall be used
for channel 1 and for channel 2 (MKT 50 Menu: Select sensor #1, Select Sensor #2). For more details
on how to perform these two procedures, refer to the MKT 50 manual.

NOTICE – A temperature measurement can only be accurate if the correct corresponding calibration
parameters are used for the connected sensor.
12.7 MKT 10 & MKT 50 - Market Information
12.7.1 Competitive Overview
Manufacturer Instruments
P 705 - Universalthermometer
1523 Reference Thermometer

CTH 6200
Almemo 1030-2
Table 12-1: Competitive overview of portable Millikelvin thermometers
CTR2000
CTR 5000
CTR 6000
Superthermometer 1594 A,
1595 A
Reference Thermometers
1523, 1524

T995
T4200
MilliK
Table 12-2: Overview of all competitors in comparison to MKT 50 by Anton Paar

If you are discussing with a customer about one of the following devices, always bear in mind that
there might be a possibility to sell a MKT 10 or 50 too!
Customer’s purpose Potentially interested persons

DMA™, SVM™, Lovis and MCP temperature Service technicians, end-customers
calibration
Process sensor calibrations End-customers (QC managers of labs & lines)
If you are visiting a customer, always ask how
they currently do their temperature sensor
calibrations!
12.7.3 Customers and Applications for the MKT 10 and MKT 50

Applications for temperature measurements?
• National calibration services (National Metrology Institutes like NIST, DKD, NMIJ, UKAS…)
• Industrial calibration services
• All industries, especially beverage manufacturers with high quality standards
• Temperature sensor and bath producers (e.g. Siemens, Epcos, Julabo, Lauda, Vishay…)

Actually, at all the big industries you are visiting, you can ask how they do their temperature sensor
calibrations. A big brewery for example employs around one thousand temperature sensors in their
production. They all have to be calibrated regularly, or at least they do if they fail and need to be
replaced.
12.7.3.1 Target Market Differentiation

MKT 10: ”little brother” for mobile use
• Secondary Calibration Service/labs
• Industry: onsite measurements, inspection of temperature probes
MKT 50: for high-end use
• National Metrology Institutes
• Secondary Calibration Service
• Industry : for reference calibration of probes
Application User Tips and Comments Instruments

Comparison Calibration Most common application in nearly all MKT 50
Calibration services industries: “Check if your sensors are in
Industrial spec!”
(external or
internal QC
services)
Fixed Point High-end Somebody has to define which temperature MKT 50
Calibration calibration is correct. Therefore, so-called “Fixed Point
services Cells” are used (for details see the “Did you
(e.g. NMI) know” box below). There the temperature is
stable and defined. E.g. the fixed-point cell
of water provides a temperature of
0.01000 °C.
Fixed point calibration is quite complex and
costly and therefore normally only done in
high-end calibration laboratories like
National Metrology Institutes (NMI).
Calibration of Measurement Density of a liquid is highly dependent on MKT 10 &
other instrument temperature. And density is not the only MKT 50
instruments manufacturers one! Almost all physical and chemical
Service parameters can only be measured if the
technicians temperature is well-known.
Therefore, a lot of instruments also have
internal temperature sensors.
E.g. the DMA™ temperature sensors should
be checked by a calibration once a year
(part of our service contracts). A special
sensor for the MKT 50 is provided for this
purpose.

Application User Tips and Comments Instruments
Research and Research Temperature is always an issue! MKT 10 &
Development institutes MKT 50
Did you know?

… that in “Fixed Point Cells” all three states of aggregation (solid, liquid and gaseous)
exist simultaneously? These are closed vessels with different highly pure materials
inside. By freezing the content and melting it slowly, a temperature plateau is created
as long as there is a mix of liquid and solid phase and sometimes even gas phase in
the cell simultaneously.
Optional reading
There are some application reports (Comparison Calibration, Calibration of
DMA™/SVM™) available in the Anton Paar Extranet! Check them out for further details
on how to use the MKT 50 in common applications. Furthermore you will learn when a
MKT 10 and when a MKT 50 shall be sold.
12.8 References
PTB Berlin, Dr. Rudtsch, National Metrology Institute Germany

DKD Calibration Service ZMK, Wolfen, DKD Calibration Service Merz Messfühlertechnik,
Deisenhofen, Munich, Germany
ÖKD Calibration Service IsoCal Graz, Austria
UKAS, Isotech UK; NIST, Isotech USA
SMU Institute of Metrology Slovakia; National Institute of Metrology, China
Epcos Deutschlandsberg, Temperature Sensor Producer for Automotives, Austria
H&D Fitzgerald, UK; Testo, Germany
1. The MKT 50 measures temperature using which kind of sensors:

Check if correct:
□ Thermocouples
□ Platinum resistance thermometers (Pt100)
□ Mercury in-glass thermometers
□ Semiconductor sensors

2. The physical quantity that is measured by the MKT to calculate the temperature is:
Check if correct
□ Resistance
□ Pressure
□ Gravity
□ Frequency
□ Voltage
3. If I connect a new calibrated sensor to the MKT 50, I have to:

Check if correct:
□ Define sensor dimensions (length, diameter) in the MKT 50
□ Define the sensor calibration coefficients
□ Re-calibrate the sensor together with the MKT 50
4. List at least 2 target groups (customers) for the MKT 10 & 50

MKT 10 _______________________________________________________________________
MKT 10 _______________________________________________________________________
MKT 50 _______________________________________________________________________
MKT 50 _______________________________________________________________________

13. Would You Like to Know More?
If you need further and more concise information on instruments of the product line Lab Density &
Concentration, please refer to the following references.
• Instruction manuals of the instruments
• Application reports and application flashes
• Recommended configurations and example quotations
These are available on
• the Anton Paar website (www.anton-paar.com)
• the Anton Paar Extranet (powerpoints, manuals, videos, …)
If you have an unusual customer request, check these sources as well as relevant textbooks – if
available - for information. If the information provided does not enable you to answer the customer's
question properly you may ask our customer support team for help (see section 14.).
XDLIE005EN-K 13. Would You Like to Know More? 173/186

14. Product Line – Contact & Responsibilities
The following chapter gives you an overview of how the product line Lab Density & Concentration
is organized and where to find your contact persons in specific product-related matters
Head of Product Line

LDC
Product Customer Product Production

Product
Management Support Engineering Planning &
Competence
Beverage Mario Gotthard Werner Assembly
Michaela Heinz Tieber
Truschnegg Franz Absenger
Schölnberger
Product
Specialists Service/ Distribution
Repair
Technical
Documentation
Application
Development
In those departments you’ll find your contact persons for product related questions.
TIP – Have a look at the contact persons listed in Anton Paar Extranet to find the correct contact
person for your product related question! Open Anton Paar Extranet and click "Contacts >
Productlines > Laboratory Density and Concentration Measurement (LDC)".
174/186 14. Product Line – Contact & Responsibilities XDLIE005EN-K

15. Check Your Knowledge – Solutions
Section 4. Density Meters
Section 4.5 Portable Density Meter: DMA™ 35

1. Name three USPs of DMA™ 35.
• The intuitive user interface
• The Ex certification of DMA™ 35 Ex and Ex Petrol
• The sample identification via RFID
• The wireless data transfer to printer and PC via IrDA
• The special petrol-resistant housing of DMA™ 35 Ex Petrol
2. Complete the text by filling the gaps
battery / portable / temperature controlled / ambient / density /reference / store
3. DMA™ 35 Version 4 Standard is equipped with an RFID interface by default. What are the
customer benefits of an RFID interface? Mark the correct answers.
b) RFID allows for quick sample identification.
Section 4.6 Benchtop Density Meter DMA™ 500

1. Which functions and features support the user in the correct filling of the sample? Tick the correct
answer(s):
The optionally integrated peristaltic pump / The FillingCheck™ feature / The U-View™ feature
2. DMA™ 500 carries an integrated rechargeable battery. What for?
uninterruptible power supply / power outages / mobile / cigarette lighter
Section 4.7 Benchtop Density Meter DMA™ Generation M

1. Name three USPs of DMA™ Generation M
• FillingCheck™ giving a warning in case of a filling error.
• U-View™, the live image of the measuring cell
• ThermoBalance™: only one adjustment at 20 °C for the whole measuring range thanks to the
reference oscillator
• The simple adjustment procedure. Competitive instruments need product-specific calibrations,
which makes life much more complicated.
2. Complete the text by filling the gaps.
reference / ThermoBalance / thermometers / viscosity / gas-bubbles / images /automatic
sampling systems
3. Name four main competitors for DMA™ Generation M.
• KEM: DA-640/645/650
• Mettler Toledo: DM 40/45/50
• Rudolph Research Analytical: DDM 2909/2910/2911/2911 plus
• PAC: VIDA 40/80
4. Explain the measuring procedure of DMA™ Generation M.
• Based on the oscillating U-tube method the density is calculated based on adjustment
coefficients (characteristics of the U-tube) and the period of oscillation.
• Select the desired measuring method
• Enter a sample name or number
XDLIE005EN-K 15. Check Your Knowledge – Solutions 175/186

• Fill 1 mL of sample into the oscillating U-tube sensor.
• Start the measurement with the push of a button.
• Read the results directly from the display, the printout or a connected PC monitor. The results
can also be transferred to a PC, LIMS or data storage device.
Section 4.8 Benchtop Density Meter DMA™ 4200 M

1. What DMA™ 4200 M accessory could be sold if the customer would like to measure waxes,
bitumen or tar?
the syringe heating attachment
2. List the main advantages of the Heating Attachment / DMA™ 4200 M Plus that can be used in a
tender.
Temperature range, pressure range, strong and highly resistant U-tube made of Hastelloy, large
touch screen, viscosity correction, data memory & export functionalities, robust housing, LPG
adapter, accessory to fill bitumen/asphalt
3. Link the DMA™ 4200 M to the according characteristics
U-tube made of Hastelloy, Viscosity correction, Measuring range up to 500 bar and 200 °C,
Accessories: LPG adapter & heating block
Section 5. Density and Sound Velocity Meters
Section 5.4 DSA 5000 M

1. Why isn’t density alone used for concentration determination of sulfuric acid over the whole
concentration range?
B, C
2. Can all the sample changers from Anton Paar be used with DSA 5000 M? If no, which one would
you use?
No, Xsample™ 320, 520, 530 and 340
3. Name the two possible cross selling possibilities for the chemical industries and projects at
universities.
Measuring modules for determination of pH (pH ME) and nD (Abbemat) offer excellent cross
selling possibilities for these applications.
4. What two measuring principles are used by DSA 5000 M?
Based on the oscillating U-tube method the density is calculated based on adjustment
coefficients (characteristics of the U-tube) and the period of oscillation.
The velocity of sound can be calculated by determining the period of received sound waves and
by considering the distance between the transmitter and receiver.
Section 5.5 Soft Drink Analyzer M

1. At what temperature are measurements with Soft Drink Analyzer M performed?
20 °C
2. Explain the process of sugar inversion and how Soft Drink Analyzer M is able to measure it.
sucrose / glucose / fructose / density / sound velocity / inverted
176/186 15. Check Your Knowledge – Solutions XDLIE005EN-K

Section 6. Alcohol Meters
Section 6.2 Snap Portable Alcohol Meters for Distilled Spirits

1. Find the correct ending for each sentence.
A The measuring cell of Snap 40 B is made of Inconel.
B The measuring cell of Snap 51 E sample IDs via RFID.
the alcohol content in distilled
C With Snap 40, you F spirits of all strengths can be
measured.
D With Snap 51, customers A is made of borosilicate glass.
can also measure the sugar
E Snap 51 can identify D
content in juice.
F With both, Snap 40 and Snap 51 C cannot store, export or print results.
Section 6.3 Alex 500 Alcohol and Extract Meter

1. True or false?
True False
Alex 500 can measure alcohol-free beers. X
Alex 500 helps brewers and winemakers with their fermentation control, by
X
drawing fermentation charts.
Alex 500 is adjusted with deionized water. X
Alex 500 can measure the alcohol and extract content in all different types of
X
alcoholic beverages (e.g. spirits, alcopops).
2. What measuring technologies and parameters is Alex 500 based on? Tick the correct answers!
Near Infrared, Density
Section 6.4 Alcolyzer M/ME

1. List the different types of Alcolyzers and their main application.
Alcolyzer Beer ME applications: All types of beer, cider
Alcolyzer Wine M/ME applications: All types of wine, cider, sake
Alcolyzer Spirits M/ME applications: Whiskey, vodka, cognac, rum, tequila and similar spirits
2. Explain the customer benefits of Anton Paar alcohol meters.
• Simple adjustment with only 2 liquids
• No product-specific calibration necessary
• Easy handling
• Optional color measurement (exception: Alcolyzer Wine)
3. Explain the measuring principle of Anton Paar alcohol meters.
The alcohol content of beverages is determined by measuring the absorption of light in a specific
NIR (Near Infrared) range. The more alcohol in the sample, the higher the absorption. The
influence of other ingredients is so small that extremely accurate alcohol results are obtained.

Section 7. CO2 and O2 Meters
1. What makes CarboQC so unique?
Anton Paar’s CO2 meters with its Multiple Volume Expansion method are instruments to
determine the true amount of dissolved CO2 in beverages unaffected by the presence of other
dissolved gases.
CboxQC™ and CboxQC™ At-line are the only instruments on the market that are capable of
measuring CO2 and O2 within 90 seconds using a sample volume of only up to 150 mL.
These instruments provide an affordable solution of calculating the Total Package Oxygen (TPO)
via Anton Paar’s free software AP-SoftPrint or by connecting to a DMA™ Generation M system.
2. Why is it essential to ensure equilibrium of the CO2 distribution in a package?
CO2 in a beverage container is distributed between liquid and headspace.
3. How to create equilibrium of the CO2 distribution/ O2 distribution in a package?
CO2 distribution: equilibrium can be established by shaking the container horizontally 15 times
O2 distribution: equilibrium can be established by shaking the container horizontally for 3 minutes
because of the poor solubility of oxygen in beverages. Shaking is best done with a laboratory
shaker.
4. Why do CarboQC and CboxQC™ provide several methods?
The solubility of CO2 depends on the beverage. Selecting the corresponding method activates
the correct factor for the beverage to be measured.
5. What needs to be measured in order to determine the true CO2 content?
Two different pressure and temperature measurements, obtained at the two volume expansions
6. Name three differences between the lab (CarboQC, CboxQC™) and at-line (CarboQC At-line,
CboxQC™ At-line) product lines.
Lab instruments do have the most precise measurement performance (resolution of 0.001 g/L)
with CO2 repeatability of 0.01 g/L (0.005 vol.)
Only lab instruments are compatible with Anton Paar’s analyzing systems (PBA-B/S/SI/SD
Generation M – available from SW release 2.40)
Only in at-line instruments the flow rate can be regulated via an integrated ball valve and 6 mm
hoses
The at-line instruments are equipped with robust rubber protection for harsh environments
7. Name four possible reasons for deviations between CO2 results out of the Multiple Volume
Expansion method and results obtained with a competitor‘s instrument.
Temperature, dissolved air, failure of establishing equilibrium, snifting, package size
8. True or False?
True False
CO2 and air have different solubilities in the beverage X
Snifting does not affect the dissolved CO2 content X
9. Tick the right answer, one or more correct answers possible: How many gas laws are executed
by CarboQC and CboxQC™?
3
10.Can CarboQC ME only be used in the laboratory?
Yes, CarboQC ME can only be used in the lab in combination with a master instrument.
11.What measuring principle is employed by Option O2?

Option O2 works with an optochemical sensor
12.Tick the right answer, one or more correct answers possible
Option O2 needs to be connected to CarboQC ME
13.Why is it essential to ensure equilibrium of the O2 distribution in a package?
O2 in a beverage container is distributed between liquid and headspace
14.True or False?
True False
CO2 and air have different solubilities in the beverage X
OxyQC is an instrument to determine the amount of dissolved CO2 in X
beverages.
CboxQC™ At-line and CarboQC At-line are compatible with Anton Paar’s X
analyzing systems.
CarboQC At-line and CboxQC™ At-line are able to regulate the flow rate X
via an integrated ball valve
CboxQC™ and OxyQC works with an electrochemical sensor. X
CboxQC™ and OxyQC works with an optochemical sensor X
Section 8. Filling Systems for Dissolved Gas Analyses

1. What gas can be used for operating a PFD Piercing and Filling Device?
PFD is best used with pressurized air or nitrogen, but NOT with CO2!
2. True or False?
True False
SFD works for all sorts of plastic corks thus making it obsolete to check X
whether SFD works for the customer’s closures.
SFD can be operated with pressurized gas or electricity. X
3. Tick the right answer, one or more correct answers possible

A PFD filling system can be accommodated with pressurized gas from in-house supply / gas
cylinder / compressor
Section 9. Turbidity Measuring Module HazeQC ME

Turbidity is the same as Haze
Reasons for turbidity in beer are yeast cells / proteins and their colloids
3. List at least two main applications for the HazeQC
• Beer: quality control of final product
• Beer: Filter checks during production
• Beer: shelf-life estimation (force test)
• Whiskey: filter control
• Chemistry/Pharma: Concentration measurements and/or purity

4. List one main benefits of the HazeQC ME (USP)
• One additional parameter in one measuring cycle
• Peltier-thermostatted: Wide temperature range –5 to +40°C
5. Tick the right answer, one or more correct answers possible Why are the measuring angles of the
HazeQC ME 0°, 25° and 90° ?
Because this is proposed by the EBC and MEBAK
6. List the two of the three main points that have to be taken into account when comparing different
turbidity meters
• Geometry (HazeQC ME Measuring angles 0°, 25° and 90°)
• Wavelength (Red Light, 650 nm)
• Mathematics (Ratio Method)
Section 10. Sample Filling Units and Sample Changers

1. Assign each sample filling unit to its main group, type and filling principle (mark with cross).
Unit Main Group Type Filling principle

Modular Stand- Single Sample Peristaltic Over- Over- Syringe Over-
Plug and alone sample changer pump pressure pressure pressure
Play in the vial and pre in
heating package
Xsample™ x x x
320
Xsample™ x x x
330
Xsample™ x x x
520
Xsample™ x x x
340
Xsample™ x x x
630
Xsample™ x x x
530
PFD/SFD x x x

2. Find the right Xsample™ for your customers’ needs
For very highly viscous samples
A D PFD/SFD
Xsample™ 340/530 and

B Low viscous, corrosive samples A
Xsample™ 630 are recommended.
Highly viscous samples with multiple samples
C E Xsample™ 520
per day
Dissolved gas analyses in Beverage
D C Xsample™ 530
industry with few samples
Non corrosive samples with multiple
E B Xsample™ 330
samples per day
3. Name one competitor in the field of the following sample filling units.
Xsample™ 530: Mettler SC-30 / Kyoto-KEM CHD-502 / Rudolph CETAC ASX-1400
Xsample™ 320/330: Rudolph ECS / Mettler FillPal™
Xsample™ 340: Mettler SC-1 / Kyoto-KEM DCU-551
Section 11. Modular Measuring Systems
Measuring Systems for Beer, Wine and Soft Drinks

1. PBA systems: Check if correct:
Measurement is done at 6 bar pressure
Cans, glass bottles and PET bottles can be measured
No degassing necessary because measurement is done under pressure
2. Which parameters can be measured with a PBA-B?
Check if correct:
Density / CO2 content / alcohol content / extract
3. Which options can be added to a PBA-B?
Check if correct:
Oxygen / pH / turbidity / beer color
4. What is the typical sample preparation for beer before it is filled into the Alcolyzer Beer Analyzing
System?
Degassing the samples and filtering very turbid samples
5. A PBA-SI is a PBA-S that additionally can measure the degree of Inversion of the sugar (°Brix
fresh, °Brix inverted). Therefore, one more parameter has to be measured. Which?
Sound velocity
6. Measuring diet beverages with a PBA-SD saves time! Tick the correct answer: The measuring
time per colored sample is 3 minutes per sample

7. PBA-SD/SID: Tick the right answer!
Right Wrong
PBA-SD/SID can be used for soft drinks with and without sugar X
Colorless Diet samples are measured with the DMA™ 4100 M density X
meter
The sample has to be degassed prior to measurement X
Only colored samples can be measured with PBA-SD/SID X
8. PBA-SD/SID: Fill the gaps (one word per line)!

ME / PFD / PFD Plus / Option / pH / DMA™ Generation / Soft Drink Analyzer
Section 12. MKT 10 and MKT 50 – Millikelvin Thermometers

1. The MKT 50 measures temperature using which kind of sensors?
Platinum resistance thermometers (Pt100)
2. The physical quantity that is measured by the MKT to calculate the temperature is:
Resistance
3. If I connect a new calibrated sensor to the MKT 50, I have to:
Define the sensor calibration coefficients
4. List at least 2 target groups (customers) for the MKT 10 & 50
MKT 10
• Secondary Calibration Service / labs
• Industry: onsite measurements, inspection of temperature probes
MKT 50
• National Metrology Institutes
• Secondary Calibration Service
• Industry: for reference calibration of probes

16. Glossary
The glossary summarizes explanations for the most common expressions used in the world of lab
instruments for density, concentration and temperature measurement.
API density
API density gives information about the density of a petroleum product at a reference temperature of
15 °C, 20 °C or 60 °F
API gravity
API stands for the American Petroleum Association which once defined the unit “API Gravity”. It gives
information about how heavy or light a petroleum liquid is compared to water. If its API gravity is
greater than 10, it is lighter and floats on water; if less than 10, it is heavier and sinks. It is calculated
at a reference temperature of 15 °C, 20 °C or 60 °F.
API SG
API SG gives information about the specific gravity of a petroleum product at a reference temperature
of 15 °C, 20 °C or 60 °F.
ASBC
ASBC is the abbreviation of the organisation "American Society of Brewing Chemists". ASBC is a
common unit for beer color.
CO2
CO2 is the chemical formula for carbon dioxide. Carbon dioxide is a colorless, odorless and tasteless
gas that is readily soluble in liquids. It is very popular in the beverage industry because it lends a
refreshing touch to beverages.
Degree Balling [°Balling]

is the old unit for the saccharose or extract content within a sample by weight and is very similar to
°Brix and °Plato. Nevertheless, it’s still used in some regions of the world.
Degree Baumé [°Baumé]

is an old hydrometer scale for measuring the density of liquids. There are two different calculation
methods, one for liquids heavier than water, the other for liquids lighter than water.
Degree Brix [°Brix]

Degree Brix specifies the saccharose or extract content within a sample by weight.
XDLIE005EN-K 16. Glossary 183/186

Degree Plato [°Plato]
is used in the brewing industry and gives information about the (percent by weight) concentration of
extract (dissolved solids, must sugars) in beer wort or beer.
Degree Proof [°Proof]

The unit °Proof specifies the alcohol content of a sample and is very common in the spirits industry.
Degree Proof is the percent by volume alcohol, multiplied by two and calculated at a reference
temperature of 60 °F.
EBC
In the European area, EBC is the unit for the color of beer and wort. The unit, defined by the European
Brewery Convention describes the amount of light, absorbed by a beer with a certain extract
concentration. The European Brewery Convention (EBC) is an organisation of technical experts for
European brewers and maltsters, which defines a large number of beer and malt related analysis
methods.
HPLC
High Pressure Liquid Chromatography, a chromatographic technique that can separate a mixture of
compounds. It is used in biochemistry and analytical chemistry to identify, quantify and purify the
individual components of the mixture.
LED
stands for “light emitting diode”. It is a device emitting light of a very small wavelength range thus
allowing the selective excitation of certain components in a mixture.
LIMS
A LIMS is a software based Laboratory Information Management System that offers a set of key
features that support a modern laboratory's operations. When connected to a LIMS, instrument's
operation is controlled via the LIMS and the instrument's result files are imported to the LIMS for data
extraction.
MEBAK
The Mitteleuropäische Brautechnische Analysenkommission e.V. (MEBAK) is represented by the
governmental and private brewing technical institutes of Germany, Austria, the Czech Republic and
Switzerland as well as the corresponding national brewing industry. The association works on
standardization of basic principles and proceedings for the analysis of raw materials, semi-finished
goods, by-products and finished products, additives and technical supplies, containers and
packaging means, primarily in the field of malthouse and brewery and has published a collection of
brewing technical analysis methods.
Percent by weight [% w/w, % m/m]

Percent by weight specifies how many grams of the component are contained in 100 grams of the
solution. Temperature can be left aside, as the temperature does not have any influence on weight
or mass.
184/186 16. Glossary XDLIE005EN-K

Percent by volume [% v/v]
Percent by volume is a temperature-dependent unit. It gives information about the volume of a
component in mL per 100 mL of the solution.
XDLIE005EN-K 16. Glossary 185/186

186/186 16. Glossary XDLIE005EN-K
Contents
1. Conventions for the Symbols in the Document..............................................................................6
2. About the First Info.........................................................................................................................7
3. Product Line – Instrumentation Overview ......................................................................................8
4. Density Meters .............................................................................................................................10
4.1 Why Measure the Density? ...................................................................................................11
4.2 Measuring Principle...............................................................................................................11
4.3 U-tube measuring Cells.........................................................................................................11
4.4 Important facts on measurement practice .............................................................................12
4.4.1 Water Check ................................................................................................................................ 12
4.4.2 Adjustment ................................................................................................................................... 13
4.4.3 Sample Preparation ..................................................................................................................... 14
4.4.3.1 Your sample contains gases................................................................................................ 14
4.4.3.2 Your sample is aggressive................................................................................................... 14
4.4.3.3 Your sample is viscous ........................................................................................................ 15
4.4.3.4 Your sample is volatile......................................................................................................... 15
4.4.4 Sample Filling .............................................................................................................................. 15
4.4.4.1 Automatic filling with sample filling units.............................................................................. 15
4.4.4.2 Manual filling with syringe.................................................................................................... 16
4.5 Portable Density Meter: DMA™ 35 .......................................................................................18
4.5.1 How to Use DMA™ 35................................................................................................................. 18
4.5.2 How Does DMA™ 35 Work? ....................................................................................................... 19
4.5.3 What Are the Customer Benefits? ............................................................................................... 20
4.5.4 What Is So Special About DMA™ 35?......................................................................................... 22
4.5.5 What Product Version to Choose?............................................................................................... 22
4.5.6 DMA™ 35 - Market Information ................................................................................................... 23
4.5.6.1 Applications ......................................................................................................................... 23
4.5.6.2 Cross Selling........................................................................................................................ 25
4.5.6.3 Competition.......................................................................................................................... 25
4.5.7 Check Your Knowledge ............................................................................................................... 26
4.6 Benchtop Density Meter DMA™ 500 ....................................................................................27
4.6.1 How to Use DMA™ 500............................................................................................................... 27
4.6.2 What Is So Special About DMA™ 500?....................................................................................... 28
4.6.3 Target Groups and Applications .................................................................................................. 31
4.6.4 Competition.................................................................................................................................. 32
4.7 Benchtop Density Meter DMA™ Generation M.....................................................................34
4.7.1 How to Use DMA™ Generation M ............................................................................................... 36
4.7.3 Optional Accessories for DMA™ Generation M........................................................................... 41
4.7.4 What Product Version to Choose................................................................................................. 42
4.7.4.1 Special Product Version: DMA™ 4500 M Chemicals .......................................................... 43
4.7.5 What Is So Special About DMA™ Generation M?....................................................................... 43
4.7.6 DMA™ M – Market Information ................................................................................................... 44
XDLIE005EN-K Contents 1
4.7.6.1 Applications ......................................................................................................................... 44
4.7.6.2 Cross Selling Potential......................................................................................................... 49
4.7.6.3 Competition.......................................................................................................................... 50
4.8 Benchtop Density Meter DMA™ 4200 M ..............................................................................53
4.8.1 How to Use DMA™ 4200 M?....................................................................................................... 54
4.8.2 What Is So Special About DMA™ 4200 M?................................................................................. 55
4.8.3 Optional Accessories for DMA™ 4200 M .................................................................................... 56
4.8.4 What Does Competition Offer? .................................................................................................... 57
4.8.6 Market Information ....................................................................................................................... 58
4.8.7 DMA™ 4100 M, 4200 M, 4500 M or 5000 M – What product to choose? ................................... 59
5. Density and Sound Velocity Meters .............................................................................................61
5.1 Why Measure Sound Velocity ...............................................................................................61
5.2 What Are Density and Sound Velocity Meters? ....................................................................62
5.3 How Is Sound Velocity Measured? .......................................................................................62
5.4 DSA 5000 M ..........................................................................................................................63
5.4.1 How to use DSA 5000 M.............................................................................................................. 63
5.4.3 Optional Accessories ................................................................................................................... 65
5.4.4 What Is So Special About DSA 5000 M....................................................................................... 65
5.4.5 DSA 5000 M – Market Information............................................................................................... 65
5.4.5.1 Applications ......................................................................................................................... 65
5.4.5.3 Competition.......................................................................................................................... 68
5.5 Soft Drink Analyzer M............................................................................................................69
5.5.1 How to Use Soft Drink Analyzer M............................................................................................... 69
5.5.2 How Does Soft Drink Analyzer M Work? ..................................................................................... 70
5.5.4 Optional Accessories ................................................................................................................... 71
5.5.5 What Is So Special About Soft Drink Analyzer M? ...................................................................... 72
5.5.6 Soft Drink Analyzer M – Market Information ................................................................................ 72
5.5.6.1 Applications ......................................................................................................................... 72
5.5.6.3 Competition.......................................................................................................................... 73
6. Alcohol Meters .............................................................................................................................74
6.1 Alcohol in Beverages.............................................................................................................74
6.2 Snap Portable Alcohol Meters for Distilled Spirits .................................................................74
6.2.1 Measuring Principle ..................................................................................................................... 75
6.2.2 How to Use Snap 41 and Snap 51............................................................................................... 75
6.2.3 What are the Differences between Snap 41 and Snap 51?......................................................... 76
6.2.5 Snap – Market Information........................................................................................................... 78
2 Contents XDLIE005EN-K
6.2.5.1 Applications / Customers ..................................................................................................... 78
6.2.5.2 Competition.......................................................................................................................... 78
6.3 Alex 500 Alcohol and Extract Meter ......................................................................................79
6.3.1 Measuring Principle ..................................................................................................................... 79
6.3.2 How to Use Alex 500 ................................................................................................................... 80
6.3.4 Alex 500 – Market Information ..................................................................................................... 81
6.3.4.1 Target Groups...................................................................................................................... 81
6.3.4.2 Competition.......................................................................................................................... 82
6.4 Alcolyzer M/ME .....................................................................................................................84
6.4.1 What Is an Alcolyzer .................................................................................................................... 84
6.4.2 Alcolyzer Measuring Principle...................................................................................................... 85
6.4.3 Combinations with Other Anton Paar Instruments....................................................................... 88
6.4.3.1 Combinations with Density Meters ...................................................................................... 88
6.4.3.2 Combinations with Sample Filling Units and Sample Changers .......................................... 88
6.4.3.3 PBA-B Generation - Packaged Beverage Analyzer for Beer............................................... 89
6.5 How to Use the Alcolyzers ....................................................................................................90
6.6 What Are the Customer Benefits?.........................................................................................90
6.7 What Is So Special About the Alcolyzers? ............................................................................90
6.8 Alcolyzers – Market Information ............................................................................................91
6.8.1 Competition.................................................................................................................................. 91
6.8.2 Cross Selling Potential................................................................................................................. 92
6.9 Check Your Knowledge.........................................................................................................92
7. CO2 and O2 Meters......................................................................................................................93
7.1 CO2 and O2 Determination....................................................................................................93
7.1.1 Why Determine Carbon Dioxide? ................................................................................................ 93
7.1.1.1 How Does Anton Paar’s CO2 Measurement Work? ............................................................ 94
7.1.1.2 Why Does Anton Paar’s CO2 Measurement Work? ............................................................ 94
7.1.2 Why Determine Oxygen?............................................................................................................. 95
7.1.2.1 How Does the O2 Measurement Work? .............................................................................. 96
7.2 Get to Know the Product Portfolio of CO2 and O2 Measurement..........................................96
7.3 CboxQC™ and CboxQC™ At-line ........................................................................................98
7.4 CarboQC and CarboQC At-line.............................................................................................99
7.5 OxyQC and OxyQC Wide Range ..........................................................................................99
7.6 What Does the CboxQC™ and CarboQC Look Like?...........................................................99
7.7 How to Use CarboQC and CboxQC™ in the Laboratory ....................................................101
7.8 What do CboxQC™ At-line | CarboQC At-line | OxyQC | OxyQC Wide Range look like?..102
7.9 How to Use CboxQC™ At-line|CarboQC At-line|OxyQC ....................................................104
7.10 CarboQC ME and Option O2 (Plus) ..................................................................................105
7.10.1 What Does CarboQC ME with / without Option O2 (Plus) Look Like? .................................... 106
7.10.2 How to Use CarboQC ME and CarboQC ME with Option O2 (Plus)........................................ 108
7.11 Market Information ............................................................................................................110
7.11.1 CarboQC and CboxQC™ ........................................................................................................ 110
7.11.1.1 Applications ..................................................................................................................... 110
7.11.1.2 Competition...................................................................................................................... 111
7.11.1.3 Cross-Selling Potential .................................................................................................... 111
7.11.1.4 References ...................................................................................................................... 112
7.11.2 OxyQC ..................................................................................................................................... 112
7.11.2.1 Applications ..................................................................................................................... 112
7.11.2.2 Competition...................................................................................................................... 113
7.11.2.3 Cross-Selling Potential .................................................................................................... 113
7.12 Check Your Knowledge.....................................................................................................113
8. Filling Systems for Dissolved Gas Analyses..............................................................................116
8.1 What Are Filling Systems Needed For? ..............................................................................116
8.2 What Filling Systems for Dissolved Gas Analyses Are Available?......................................116
8.3 What Is Required for PFD (Plus) and SFD Operation?.......................................................116
8.4 PFD Piercing and Filling Device (Plus) ...............................................................................117
8.5 SFD Sparkling Wine Filling Device......................................................................................119
8.6 Which Filling Device for Which Application? .......................................................................120
8.6.1 Applications of the PFD (Plus) ................................................................................................... 120
8.6.2 Applications of the SFD ............................................................................................................. 121
8.7 PFD (Plus) and SFD – Market Information..........................................................................121
8.7.1 Finding Customers..................................................................................................................... 121
8.7.2 Competition................................................................................................................................ 122
8.7.3 Cross Selling Potential............................................................................................................... 122
8.8 Check Your Knowledge.......................................................................................................122
9. Turbidity Measuring Module HazeQC ME .................................................................................124
9.1 Turbidity in Liquids ..............................................................................................................124
9.2 Turbidity in Beer ..................................................................................................................124
9.3 Get to Know the HazeQC ME .............................................................................................125
9.4 How Does HazeQC ME Work? ...........................................................................................125
9.4.1 Ratio Method.............................................................................................................................. 125
9.4.2 Influence of Particle Size ........................................................................................................... 126
9.5 Comparing Turbidity Meters ................................................................................................126
9.6 What Are the Customer Benefits?.......................................................................................127
9.7 HazeQC ME – Market Information ......................................................................................128
9.7.1 Who Needs the HazeQC ME and What For? ............................................................................ 128
9.7.1.1 Application in Beer and Whiskeys: Filter Control............................................................... 128
9.7.1.2 Application in Beer: the "Force Test" ................................................................................. 128
9.7.2 Competition................................................................................................................................ 129
9.7.3 Cross Selling Potential............................................................................................................... 129
9.8 Check Your Knowledge.......................................................................................................130
10. Sample Filling Units and Sample Changers ............................................................................132
10.1 Why Automation? ..............................................................................................................132
10.2 What Sample Filling Units and Sample Changers are Available?.....................................133
10.3 How to Determine the Demands of Your Customer ..........................................................134
10.4 Modular Sample Filling Units.............................................................................................134
10.4.1 Xsample™ 320 Sample Filling Unit ......................................................................................... 134
10.4.2 Xsample™ 330 Sample Filling Unit ......................................................................................... 135
10.4.3 Xsample™ 520 Sample Changer ............................................................................................ 136
10.4.4 Xsample™ 630 Heated Sample Changer................................................................................ 137
10.4.5 Xsample™ 530 Sample Changer ............................................................................................ 139
10.5 Stand-alone Sample Filling Units ......................................................................................141
10.5.1 Xsample™ 340 (with cleaning) ................................................................................................ 141
10.5.2 PFD (Plus) / SFD ..................................................................................................................... 142
10.6 Competition .......................................................................................................................143
11. Modular Measuring Systems ...................................................................................................148
11.1 What Does a System Look Like? ......................................................................................148
11.2 Measuring Systems for Beer, Wine and Soft Drinks .........................................................149
11.2.1 Alcolyzer Beer Analyzing System (Non-Pressurized) .............................................................. 150
11.2.1.1 How Does the Alcolyzer Beer Analyzing System Measure? ........................................... 150
11.2.1.2 What Does the Alcolyzer Beer Analyzing System Measure? .......................................... 150
11.2.2 Packaged Beverage Analyzers: PBA (Pressurized) ................................................................ 151
11.2.2.1 How Does a Packaged Beverage Analyzer Measure?.................................................... 152
11.2.2.2 PBA-S .............................................................................................................................. 152
11.2.2.3 PBA-SI ............................................................................................................................. 152
11.2.2.4 PBA-SD / PBA-SID .......................................................................................................... 152
11.2.2.5 PBA-B .............................................................................................................................. 157
11.2.2.6 PBA-W ............................................................................................................................. 158
11.2.3 Optional Modules ..................................................................................................................... 160
11.2.4 Check Your Knowledge ........................................................................................................... 161
12. MKT 10 and MKT 50 – Millikelvin Thermometers ....................................................................164
12.1 How Does MKT 10 Look Like?..........................................................................................164
12.2 How Does MKT 50 Look Like?..........................................................................................164
12.3 Why Measure Temperature that Accurately?....................................................................165
12.4 How Do MKT 10 and MKT 50 Work? ................................................................................165
12.5 Calibration Standards: DIN EN 60751 and ITS-90............................................................166
12.5.1 DIN EN 60751 (former IEC 751) .............................................................................................. 166
12.5.2 ITS-90 ...................................................................................................................................... 166
12.6 How to Use MKT 50 ..........................................................................................................166
12.6.1 How to Set a Sensor Calibration.............................................................................................. 166
12.6.2 How to Select the Previously Created Calibration for Your Sensor ......................................... 166
12.7 MKT 10 & MKT 50 - Market Information............................................................................167
12.7.1 Competitive Overview .............................................................................................................. 167
12.7.2 Cross Selling Potential............................................................................................................. 169
12.7.3 Customers and Applications for the MKT 10 and MKT 50....................................................... 169
12.7.3.1 Target Market Differentiation ........................................................................................... 170
12.7.3.2 Applications ..................................................................................................................... 170
12.8 References ........................................................................................................................171
13. Would You Like to Know More?...............................................................................................173
14. Product Line – Contact & Responsibilities ...............................................................................174
15. Check Your Knowledge – Solutions.........................................................................................175
16. Glossary...................................................................................................................................183

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LDC and LPS

This document is for your internal, informative use only.

Version: February 2018

LDC and LPS

This document is for your internal, informative use only.

Version: February 2018

Changes, copyright, trademarks etc.

Address of the instrument producer:

Did you know?

6/186 1. Conventions for the Symbols in the Document XDLIE005EN-K

On Your Way to Becoming a Sales/Service Expert for Anton Paar Products:

What the First Info Can Do for You

It’s the First Info – Not the Last Word

And now, enjoy getting on with your First Info package!

XDLIE005EN-K 2. About the First Info 7/186

Type of instrument Instruments

8/186 3. Product Line – Instrumentation Overview XDLIE005EN-K

XDLIE005EN-K 3. Product Line – Instrumentation Overview 9/186

From X-Rays to Density

In 1965 Professor Kratky assigned two students to a research project

What does this have to do with Anton Paar?

Did you know?

Have a look at this interesting blog-article:

10/186 4. Density Meters XDLIE005EN-K

4.2 Measuring Principle

4.3 U-tube measuring Cells

Fig. 4-1: x, y - and w - oscillator

XDLIE005EN-K 4. Density Meters 11/186

4.4 Important facts on measurement practice

4.4.1 Water Check

If the water check fails, try the following

12/186 4. Density Meters XDLIE005EN-K

If the water check still fails

If the water check still fails

Reasons why the side effects of cleaning need to be compensated by an adjustment:

Cause Effect Influence on density

Aggressive cleaning Volume of the measuring cell is Artificial density decrease

XDLIE005EN-K 4. Density Meters 13/186

4.4.3 Sample Preparation

Choose your sample preparation according to the characteristics of your sample:

4.4.3.1 Your sample contains gases

4.4.3.2 Your sample is aggressive

14/186 4. Density Meters XDLIE005EN-K

4.4.3.4 Your sample is volatile

DMA™ Generation M and CarboQC:

4.4.4 Sample Filling

4.4.4.1 Automatic filling with sample filling units

XDLIE005EN-K 4. Density Meters 15/186

4.4.4.2 Manual filling with syringe

16/186 4. Density Meters XDLIE005EN-K

List of typical samples and suggested cleaning liquids

Sample Suggested cleaning liquid 1 Suggested cleaning liquid 2

After-shave, perfume Alcohol -

XDLIE005EN-K 4. Density Meters 17/186

The DMA™ 35 is a battery-operated portable density meter. Due to its

4.5.1 How to Use DMA™ 35

18/186 4. Density Meters XDLIE005EN-K

4.5.2 How Does DMA™ 35 Work?

The DMA™ 35 is a _-operated density meter. The