Maisaroh 2022 IOP Conf. Ser. Earth Environ. Sci. 1116 012065
Maisaroh 2022 IOP Conf. Ser. Earth Environ. Sci. 1116 012065
Maisaroh 2022 IOP Conf. Ser. Earth Environ. Sci. 1116 012065
*Email: mais001@brin.go.id
Abstract. Keladi Tikus (Typhonium flagelliforme (Lodd) Blume) has many health benefits as an
anticancer, anti-inflammatory, and analgesic. Its leaf and tuber can be dried and used as
simplicia. This study was performed to discover the drying kinetics and modelling for Keladi
Tikus, especially its leaves and tuber parts. Factorial Randomized Complete Block Design
(RCBD) was implied as the experiment design in this study. Three temperature variables (40,
50, and 60oC) and a dehydrated oven were employed in the drying procedure. The rates of drying
of Keladi Tikus simplicia were observed, and the results are shown as the decreasing drying rate
curve, i.e. drying time gets faster with increasing drying temperature. Drying models are obtained
by plotting moisture ratio to drying time. The dried tuber can reach a water content below 10%
at all temperature drying variations. Meanwhile, drying leaves using temperatures below 50C
cannot reduce the water content to reach less than 10%. The mathematical models for the drying
process were generated and their accuracies were judged by implying the statistical parameters
Standard Error (SE) and determination coefficient (R2). The best model was chosen based on a
comparison of six models. Page's model is the best model for all drying temperatures of tuber,
while the Two-term's model is best for leaves drying. The results from this study provide suitable
mathematical models to predict the optimal temperature and drying time for Simplicia of Keladi
Tikus tuber and leaves.
1. Introduction
Keladi Tikus (Typhonium flagelliforme Lodd) belongs to the herbal group and has a shape similar to a
taro plant. It is a wild clump plant that grows on moist, shady loose soil and has considerable health
benefits as anti-cancer, anti-inflammatory, and analgesic. Keladi Tikus contains terpenoid, phenolic,
flavonoid, saponin, steroid or triterpenoid, stigmasterol and coumarin [1]. The tuber and leaf are the
most widely used parts of the plant.
Moisture content reduction is widely used to preserve food and agricultural products. By lessening
their water content, the food products can have a longer shelf-life and are safer to be stored. The thermal
technique is the most basic and commonly used to reduce water content in food products, which involves
using heat or high temperatures. Drying involves lessening chemical, biochemical and microbiological
spoilages in food and agricultural products. It can also cut down the costs of storage, packaging, and
transportation [2]. In addition, drying can also restrain the quality of herbs, aromatics, and medicinal
Content from this work may be used under the terms of the Creative Commons Attribution 3.0 licence. Any further distribution
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Published under licence by IOP Publishing Ltd 1
ICATES-2022 IOP Publishing
IOP Conf. Series: Earth and Environmental Science 1116 (2022) 012065 doi:10.1088/1755-1315/1116/1/012065
plants. The most prevalent drying method is convective drying, which most raw materials manufacturers
hugely apply since this method can be done with simple techniques.
Important parameters as indicators of success in drying were calculated to be analyzed to recommend
the use of a suitable model. Those parameters are moisture content, moisture ratio, diffusion effectivity,
activation energy, mass transfer coefficient, drying rate, and kinetic modelling. The dimensionless Biot
number (Bi) for mass transfer establishes a correlation between the convective mass transfer and the
diffusivity coefficients [3].
A study of the research referred to here is the drying of tubers and leaves of Keladi Tikus in a drying
oven under various conditions, including temperature, drying time, and drying rate had been carried out.
The study also learned some models of drying the tuber and leaves of Keladi Tikus suitable to determine
the drying behavior of varied materials and evaluate the drying system performance. Effective empirical
models are essential for process design, optimization, energy integration, and dryer control. Empirical
models of the food drying process are fundamental, but theoretical models have not been provided as
practically as possible to unify the calculations [4]. This study aimed to determine the drying rate
kinetics and modelling of Keladi Tikus with six empirical thin-layer models.
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ICATES-2022 IOP Publishing
IOP Conf. Series: Earth and Environmental Science 1116 (2022) 012065 doi:10.1088/1755-1315/1116/1/012065
In which, WC is sample water content (g water/g dry matter), Wf is the weight of the fresh sample (g),
while Wd is the sample dry weight (g).
𝑀𝑡+𝑑𝑡 − 𝑀𝑒
𝐷𝑟𝑦𝑖𝑛𝑔 𝑟𝑎𝑡𝑒 = (3)
𝑑𝑡
Where,
M0 : moisture content of fresh sample (db.)
Mt : moisture content at t (db.)
Me : equilibrium moisture content (db.)
Mt+dt : moisture content at t + dt (db.)
MR : moisture ratio
t : drying (hour)
𝑀− 𝑀𝑒 8 1 𝑛2 𝜋2 𝐷𝑒𝑓𝑓 .𝑡
𝑀𝑅 = = 2
∑∞
𝑛=1 2 𝑒𝑥𝑝 (− ) (4)
𝑀𝑜 − 𝑀𝑒 𝑛 𝑛 4𝑟 2
8 𝜋2 𝐷𝑒𝑓𝑓
ln(𝑀𝑅) = ln ( 2 ) − ( 𝑡) (5)
𝜋 4𝑟 2
𝐷𝑒𝑓𝑓 (𝜋2 )
𝑆𝑙𝑜𝑝𝑒 = (6)
4𝑟 2
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IOP Conf. Series: Earth and Environmental Science 1116 (2022) 012065 doi:10.1088/1755-1315/1116/1/012065
The following equation can be used to express the relationship of the Arrhenius type between the
effectivity of diffusivity and the reciprocity of absolute temperature:
𝐸𝑎
𝐷𝑒𝑓𝑓 = 𝐷0 . 𝑒𝑥𝑝 (− ) (7)
𝑅𝑇
𝐸𝑎
ln (𝐷𝑒𝑓𝑓 ) = ln (𝐷0 ). (− ) (8)
𝑅𝑇
Where D0 (m2/s) is Arrhenius’ pre-exponential factor, Ea (kJ/ mol) is the activation energy, T (K), while
R is 8.314 kJ/mol.K. The linear line's slope in figure 5 can be used to determine the activation energy.
Dincer number (Di) yields a correlation between the drying airflow velocity and the coefficient of
the drying of the product [7]. Its calculation can be done using Eq. (10).
𝜐
𝐷𝑖 = 𝑘 ′ .𝐿 (10)
In where, n is the drying airflow velocity (0.5 m/s), L is thickness ± 3 × 10-3 m for tubers and ± 2.5
×10-4 m for leaves; k’ drying constant that calculated from chosen semi-empirical model with the best
value based on R2. Furthermore, the convective mass transfer coefficient can be calculated by Eq. (12).
ℎ𝑚 𝐿
𝐵𝑖 = (11)
𝐷𝑒𝑓𝑓
𝐵𝑖 × 𝐷𝑒𝑓𝑓
So, ℎ𝑚 = (12)
𝐿
Page MR = y = e-k(x^n)
Henderson and Pabis MR = y = ae(-kx)
Lewis MR = y = e(-kx)
Logarithmic MR = y = ae(-kx) + c
Two-term MR = y = ae(-k1x) + be(-k2x)
Midilli MR = y = ae(-kx) + bx
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ICATES-2022 IOP Publishing
IOP Conf. Series: Earth and Environmental Science 1116 (2022) 012065 doi:10.1088/1755-1315/1116/1/012065
The empirical constants a, b, c, k' and n were determined using regression analysis and CurveExpert
Professional 2.6.5 (trial mode). Statistical parameters can be used to describe the variability in a set of
data. This variability can be used to identify patterns and trends in the data. The coefficient of
determination (R2), reduced chi-square (X2), and root mean square error (RMSE) were used to assess
the goodness of fit of the models and to choose the model that best represents the drying kinetics. Based
on the results of these parameters, the model with the highest R 2 value and the smallest X2 and RMSE
values has been selected and declared as the best model. These statistical parameters can be determined
by using the following equations:
∑𝑁 𝑁
𝑖=1(𝑀𝑅𝑖 −𝑀𝑅𝑝𝑟𝑒,𝑖 ).∑𝑖=1(𝑀𝑅𝑖 −𝑀𝑅𝑒𝑥𝑝,𝑖 )
𝑅2 = 2 2
(13)
√(∑𝑁 𝑁
𝑖 (𝑀𝑅𝑖 −𝑀𝑅𝑝𝑟𝑒,𝑖 ) ).(∑𝑖 (𝑀𝑅𝑖 −𝑀𝑅𝑒𝑥𝑝,𝑖 ) )
2
∑𝑁
𝑖 (𝑀𝑅𝑒𝑥𝑝,𝑖 −𝑀𝑅𝑝𝑟𝑒,𝑖 )
𝑋2 = (14)
𝑁−𝑧
1
1 2 2
𝑅𝑆𝑀𝐸 = [𝑁 ∑𝑁
𝑖=1(𝑀𝑅𝑒𝑥𝑝,𝑖 − 𝑀𝑅𝑝𝑟𝑒,𝑖 ) ] (15)
In the equations above, N is the number of observations, MRexp is the experimental moisture ratio,
MRpre is the predicted moisture ratio, and Z is the number of constants. The experimental moisture
content values were obtained and used to calculate the moisture ratio, which fitted into the
aforementioned models next.
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ICATES-2022 IOP Publishing
IOP Conf. Series: Earth and Environmental Science 1116 (2022) 012065 doi:10.1088/1755-1315/1116/1/012065
Figure 1. Moisture content vs drying time (% dry basis) of Keladi Tikus in various drying temperatures
As shown in figure 3, that the drying process was halted when the sample weight did not show any
further change, which marks a constant state or equilibrium. Under a drying temperature of 60 0C, the
moisture content of Keladi Tikus leaves decreased from 90 – 92% to less than 10 % (wet basis) after
10.44 hours of drying. However, drying temperatures of 40 0C and 500C were shown to be inefficient to
reduce the moisture content of Keladi Tikus leaves since a moisture content point below 10% (wet basis)
was not obtainable, even after 20 hours of drying.
Meanwhile. as shown in figure 4, faster drying can be achieved by increasing the drying temperature.
This mechanism can be illustrated as follows: when heat transfer increases, the evaporation of water in
the leaves will also increase. Nevertheless, the drying rate of the sample decreases by time. As
anticipated, the higher temperature drying (600C), means the higher the heat transfer will become,
resulting in a lesser time to reach a certain level of humidity ratio. It is proven that higher temperatures
allow the water in the product to achieve evaporation temperature faster, which increases the diffusion
phenomenon, i.e. moisture migration in the product from the centre to the surface.
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ICATES-2022 IOP Publishing
IOP Conf. Series: Earth and Environmental Science 1116 (2022) 012065 doi:10.1088/1755-1315/1116/1/012065
Figure 2. The drying rate (g water /g dry matter /hours) of Keladi Tikuus tubers under various drying
temperatures
Figure 3. The effect of drying time on moisture content (% dry basis) of leaves of Keladi Tikus under
various drying temperatures.
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ICATES-2022 IOP Publishing
IOP Conf. Series: Earth and Environmental Science 1116 (2022) 012065 doi:10.1088/1755-1315/1116/1/012065
-...
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QI
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0 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 2 1
Time (hr)
Figure 4. The drying rate (g water/g dry matter/hour) of Keladi Tikus leaves under various drying
temperatures
During the initial stage or the first 120 minutes of drying operation, the drying rate was higher and
faster than in the following minutes due to the high availability of free water in the sample. However,
figures 2 and 4 show that, as time progressed, both the moisture content and drying rate will gradually
decrease to a point where the drying rate is no longer perceived because water is not available any more
on the surface of the material and the drying rate is constrained by the diffusion of moisture from the
innermost part of the solid to the surface.
Table 2. The effective diffusivity (Deff), the activation energy (Ea), and mass transfer (hm)
parameters for Keladi Tikus dried
Plaut pai1 T ("C) Deffx 10-9 (m 1/s) Ea (kJ/mol) k' Bi bm xl0- 5 (mis)
Leaves 40 4.050 0.154 0.560 1.719
50 4 .050 0.279 0.701 2.15 1
60 8.099 29.74 0.467 0.850 5.216
Tubers 40 0.365 0.23 1 1.966 0.029
50 0.365 0.406 2.429 0.035
60 0.729 0.47 1 2 .570 0.075
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ICATES-2022 IOP Publishing
IOP Conf. Series: Earth and Environmental Science 1116 (2022) 012065 doi:10.1088/1755-1315/1116/1/012065
1.0
60 °C
0.8
50 °C
0.6 40 °C
MR
0.4
0.2
0.0
0 2 4 6 8 10 12 14 16 18 20
Time (h)
Figure 5. The experimental moisture ratio of Keladi Tikus tubers against drying time under various
drying temperatures
1.0
60 °C
50 °C
40 °C
0.5
MR
0.0
0 2 4 6 8 10 12 14 16 18 20 22
Time (h)
Figure 6. The experimental moisture ratio of Keladi Tikus leaves against drying time under various
drying temperatures
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ICATES-2022 IOP Publishing
IOP Conf. Series: Earth and Environmental Science 1116 (2022) 012065 doi:10.1088/1755-1315/1116/1/012065
(a) (d)
(b) (e)
(c) (f)
Figure 7. The plot of Ln (MR) against time for determination of effectual diffusivity (Deff) under
various drying temperatures for tuber (a), (b), (c), and for leaves (d), (e), (f)
Activation energy is the minimum energy required to initiate the diffusion of water from a material
[10]. The value of the activation energy of Keladi Tikus in this study was 29.74 kJ/mol. This value is
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ICATES-2022 IOP Publishing
IOP Conf. Series: Earth and Environmental Science 1116 (2022) 012065 doi:10.1088/1755-1315/1116/1/012065
still within the range of activation energy values for agricultural products, namely 12 – 110 kJ/mol [11].
Based on table 2, higher temperature results in higher Bi number with leaves and tubers values ranging
from 0.56 to 0.85 and 1.96 to 2.57, respectively. This trend shows similarity to a study by [12] on
vacuum-dried apples with an increase in temperature from 50 0C to 700C and a study by [3] on Moringa
olivera leaves that dried in a vacuum tray dryer at 40 – 60 0C. The mass-exchange coefficient (hm) for
leaves and tubers ranges from 1.719 × 10-5 to 5.216 × 10-5 m/s and 0.029 × 10-5 to 0.075 × 10-5,
respectively. This indicates a higher drying temperature will generate a higher moisture transfer rate.
Heat causes an increase in activity energy and its availability increases due to higher temperatures in
the drying process causing a higher mass exchange rate [5]. The drying operation of the Rodent Tuber
with a Bi value ranging from 0.56 to 2.57 can be classified as a process that must be controlled internally
and externally where the Bi value is between 0.1 < Bi < 100 [13].
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Table 3. Keladi Tikus drying models, model constants and the results of statistical
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50 Leaf Page k: 0.294223; n: 0.991276 0,99913 0,00006 0,00764
Henderson and Pabis k: 0.286832; a: 0.987513 0,99925 0,00005 0,00709
Lewis k: 0.290485 0,99911 0,00006 0,00772
Logarithmic k: 0.279474; a: 0.990043; c: -0.007343 0,99952 0,00004 0,00571
1116 (2022) 012065
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1116 (2022) 012065
IOP Publishing
doi:10.1088/1755-1315/1116/1/012065
ICATES-2022 IOP Publishing
IOP Conf. Series: Earth and Environmental Science 1116 (2022) 012065 doi:10.1088/1755-1315/1116/1/012065
4. Conclusions
Table 3 shows that for the drying of Keladi Tikus leaves, the Two-term model is the most suitable model
to predict the MR value for drying at 50 and 60 0C, while the Logarithmic model is the fittest model for
drying at 40 0C. Therewith, for the drying of tuber, the Page model is the most appropriate model to
predict the MR value compared to the other six equation models. Table 3 shows that for drying the
Keladi Tikus leaves, the Two-term model is the most suitable model to predict the MR value for drying
at 50 and 60 oC, and the Logarithmic model is the most suitable model at 40 oC. As for tuber drying, the
Page model is the most appropriate model to predict the MR value compared to the other six equation
models.
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