Class Xi Chemistry Ut I 2019 20 1

KENDRIYA VIDYALAYA SITAPUR (I-SHIFT )
FIRST PERIODIC TEST-2019-20

SUBJECT-CHEMISTRY
CLASS-XI
TIME : 90 min Max.Marks : 50
All questions are compulsory.

Q1.Choose the option which is correct :- [1 x5]
6
{a} How many significant figures are there in 4.00x10 ?
(i) 2 (ii) 3 (iii) 6 (iv) 9
(b) What is the S.I. unit of density ?
(i) kg/m3 (ii)g/cm3 (iii) kg/litre (iv) all of these
(c) The energy associated with the first orbit in the hydrogen atom is - 2.18 x 10 -18 J/atom. What is
the energy associated with the fifth orbit in J/atom :-
(i) - 2.18 x 10 -18 / 25 (ii) - 2.18 x 10 -18 /5 (iii) - 2.18 x 10 -18 (iv) none of these
(d) How many atoms in 4 u of H2 :- (i) 4 (ii) 4 moles (iii) 2 moles (iv) none of these
88
(e) The number of neutrons in 38 Sr are :-
(i) 40 (ii) 50 (iii) 88 (iv) 38
Q 2 . Answer the following :- [1 x5]
(a) What is the mass of electron in kg ?(b) What is the charge on 1 mole of proton?
(c) Express 2808 into scientific notation .
(d) Convert 1 mg into kg and ng.
(e) Write de Broglie’s equation.
Q 3.Calculate energy of photon of radiation whose frequency is 5 x 10 14 hertz. (h =6.626 x 10-34 Js) [2]
Q 4.Write short note on photo electric effect . [2]
Q 5. Define:- [i] atomic mass unit [ii] mole. [2]
Q 6. The energy of electron in hydrogen atom has negative value. What does it mean ? [2]
Q 7. Calculate the amount of carbon dioxide formed when two moles of carbon are burnt in Oxygen . [2]
C + O2 CO 2
Q 8.Calculate the percentage composition of oxygen in CuSO4 .5H2O . [3]

[At wt :- Cu =63.5 ,S =32,O = 16 ,H=1 ]
Q.9. How many grams of NaCl should be dissolved to make 100 ml of 0.15 M NaCl ? [3]
Q 10. State Gay Lussac’s law of gaseous volume .Explain with suitable example . [3]
Q 11. Q 4.Calculate number of atoms in each of the following :- (atomic wt of He = 4)
(i) 52 moles of He (ii) 52 u of He (iii) 52 gm of He [3]
Q 12. Complete the following table ;- [3]
Name of the Atomic no. Mass No. No. of electron No. of proton No. of neutron
particle (Z) (A) (e) (p) (n)
Aluminium ion 27 10
Sodium ion 10 12
Q 13. 80 gm H2 reacted with 80 gm of O2 to form water . Find out the mass of water formed . Which one
is the limiting reagent . Which reactant will remain unreacted and what wouid be its mass? [5]
Q.14. A compound contains 4.07% Hydrogen, 24.47%Carbon & 71.65 % Chlorine. Its molar mass is
98.96 gm. What is its empirical formula and molecular formula? [5]
Q 15.Write the postulates of Bohr’s model of atom and its limitations. [5]
KENDRIYA VIDYALAYA SITAPUR (I-SHIFT )
FIRST PERIODIC TEST-2019-20
SUBJECT-CHEMISTRY
CLASS-XII
TIME : 90 min Max.Marks : 50
All questions are compulsory.

Q1.Choose the option which is correct :- [1 x5]
(A).What will be the van’t hoff factor for a solution of K4[FeCN6] if its dissociation is 50% :-
(a) 5 (b)3 (c) 4 (d) none of the above
(B). Sea water can be converted into fresh water by :-
(a) Osmosis (b) Sedimentation (c) Diffusion (d) Reverse Osmosis
(C). Which of the following catalyst is used in Haber’s process –:
(a) Fe (b) Na (c) Mo (d) K2SO4
(D). Graph of [R] vs time is a straight line . The order of the reaction is -:
(a) 3 (b) 2 (c) 0 (d) 1
(E). The quantity of charge required to obtain one mole of aluminium from Al 2O3 is-:
(a) 1F (b) 3F (c) 6 F (d) 2 F
Q 2 . Answer the following :- [1 x5]
(A) Name two compounds used as adsorbent for controlling humidity.
(B) Mention one shape selective catalyst used to convert alcohol directly into gasoline.
(C) Name the battery which is generally used in inverters .
(D) Is it safe to stir 1M AgNO3 solution with a copper spoon? Given E0 Ag+/Ag=0.80V .
(E) What are the electrolysis products of solution of dilute sulphuric acid using Pt electrodes?
Q 3. For a reaction , the energy of activation is zero. What is the value of rate constant at 300K,
if k = 1.6 x 10 6 s-1 at 280 K ? [R = 8.314 J K-1] [2]
Q 4.. What is pseudo first order reaction . Give example. [2]
Q 5.Write any two differences between ideal & non-ideal solution [2]
Q 6.Consider the reaction 2A + B _______> Products [2]
When concentration of B alone was doubled, half life time does not change. When conc. of A
alone is doubled, the rate increases by two times. What is the order of the reaction?
Q 7. Explain promoter and poison with example . [2]
Q 8. What is fuel cell, write reaction involved in H2-O2 fuel cell. [3]
Q 9. State Henery’s law and mention its two important applications. [3]
Q 10. Write the difference between order and molecularity of reaction. [3]
Q 11. Explain the following :- [3]
(a) Aquatic species are more comfortable in cold waters than in warm waters.
(b) To avoid bends scuba divers use air diluted with helium.
(c) Cold drinks bottles are sealed under high pressure of CO2.
Q 12. Give reasons :- [3]
(i) Generally high temperature is favourable for chemisorption.
(ii)Physisorption decrease with increase of temperature .
(iii) A finely devided substance is more effective as an adsorbent .
Q 13.(a)Identify the reaction order from each of following units of rate constants. [5]
(i) L mol-1sec-1 (ii) mol L-1sec-1
(b) The following data were obtained during the first order thermal decomposition of SO 2CI2 at
a constant volume :- SO2 CI2 SO2 + CI2
Experiment Time (second) Total pressure (atm)

1. 0 0.4
2. 100 0.7
Calculate the rate constant. (Given: log 4=0.6021, log 2= 0.3010)
Q14(a).Calculate e.m.f of the cell at 298K :- Cr /Cr3+ (0.1M) II Fe2+ (0.01M) / Fe [5]
0 0
[ Given: E Cr3+/Cr = -0.75V, : E Fe2+ / Fe = -0.45V ]
(b) A current of 0.5 ampere is flowing through a wire for 2 hours .Then how many electrons would
flow through the wire .
Q 15.a) Define the following terms [5]
i) Mole fraction
ii) Molal depression constant (Kf)
b) 15 g of an unknown molecular material is dissolved in 450 g of water. The resulting solution freezes
at -0.34◦C. What is the molar mass of the material. ( Kf for water = 1.86 K kg mol-1)
.

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KENDRIYA VIDYALAYA SITAPUR (I-SHIFT )

FIRST PERIODIC TEST-2019-20

All questions are compulsory.

Q 8.Calculate the percentage composition of oxygen in CuSO4 .5H2O . [3]

All questions are compulsory.

Experiment Time (second) Total pressure (atm)

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