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Assignment Haloalkanes and Haloarenes

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ASSIGNMENT 1

HALOALKANES and HALOARENES

CLASS XII

1.Write IUPAC names of the following compounds:

a) CH3CH(Cl)CH(Br)CH3
b) (CH3)3CCH=C(Cl)C6H4I-p
c) (CCl3)3CCl
d) CH3C(P-ClC6H4)2CH(Br)CH3

2. Write structures of the following compounds and identify them as 1 o ,2o ,3o ,geminal or
vicinal dihalides. :

3-Bromopentane , Neopentyl chloride , 2,2 Dichlorobutane , 2,3-Dichlorobutane

3. How will you prepare the following from an alcohol?

a) Ethyl Iodide
b) Fluoroethane

4. How would you convert the following:

a) Chlorobenzene to 2-Chlorotoluene
b) Prop-1-ene to 1-fluoropropane
c) Toluene to Benzyl alcohol
d) Benzene to Biphenyl
e) Benzyl alcohol to Phenyl ethanenitrile
f) But-1-ene to But-2-ene

5. Write the main products when :

a) n-Butyl chloride is treated with alcoholic KOH.


b) 2,4,6-trinitrochlorobenzene is subjected to hydrolysis.
c) Methyl chloride is treated with AgCN.
d) Chloroethane is treated with silver nitrite.
e) 1-Methylcyclohexene is treated with HI.

6. Give reasons:

a) Haloarenes are insoluble in water but soluble in benzene.


b) The p-isomers of Dichlorobenzene has higher melting point than o- and m-isomers.
c) Alkyl halides though polar are immiscible with water.
d) The dipole moment of chlorobenzene is lower than that of cyclohexyl chloride.

7. A Hydrocarbon C5H12 gives only one chlorination product. Identify the compound.

8. Arrange set of compounds in order of increasing boiling points:

a) Bromomethane , Bromoform , Chloromethane ,Dibromomethane


b) 1-Chloropropane , Isopropyl chloride , 1- Chlorobutane

9. Waht are ambident nucleophiles? Give example.

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