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Safety Data Sheet

BETON

Safety Data Sheet dated 8/7/2016, version 2

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier
Mixture identification
Trade name: BETON
1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended use:
Sealer for floors.
Professional use (SU22)
PC31 – Polish and wax mixtures

Uses advised against:


Different uses than recommended. Do not use in combination with other products.
1.3. Details of the supplier of the safety data sheet
Manufacturer:

SUTTER INDUSTRIES s.p.a. - Società con Unico Socio


15060 Borghetto Borbera (AL) Italia
Tel. +39 0143 631.1
Competent person responsible for the safety data sheet:
regulatory.affairs@sutter.it
1.4. Emergency telephone number
+39 0143 631.1 mon-fri 9.00/17.00

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture
EC regulation criteria 1272/2008 (CLP)
The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP).
Adverse physicochemical, human health and environmental effects:
No other hazards
2.2. Label elements
Hazard pictograms:
None
Hazard statements:
None
Precautionary statements:
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
Special Provisions:
EUH210 Only for professional use. Safety data sheet available on request.
Contents
METHYLCHLOROISOTHIAZOLINONE, METHYLISOTHIAZOLINONE: May produce an
allergic reaction.

Special provisions according to Annex XVII of REACH and subsequent amendments:


None
2.3. Other hazards
vPvB Substances: None - PBT Substances: None
Other Hazards:
No other hazards

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SECTION 3: Composition/information on ingredients


3.1. Substances
Not applicable, the product is a mixture
3.2. Mixtures
Hazardous components within the meaning of the CLP regulation and related classification:
>= 5% - < 7% 2-(2-BUTOXYETHOXY)ETHANOL
REACH No.: 01-2119475104-44, Index number: 603-096-00-8, CAS: 112-34-5, EC:
203-961-6
3.3/2 Eye Irrit. 2 H319

SECTION 4: First aid measures


4.1. Description of first aid measures
In case of skin contact:
Wash with plenty of water and soap.
In case of eyes contact:
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
In case of Ingestion:
Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION
IMMEDIATELY.
In case of Inhalation:
Remove casualty to fresh air and keep warm and at rest.
4.2. Most important symptoms and effects, both acute and delayed
Until the revision date of this document, no adverse effects and symptoms to exposure of the
product are known, including chemical reactivity and instability.
Until revison date of this document, are unknown chronic effects from the mixture contact with
skin, eyes, inhalation, ingestion.
4.3. Indication of any immediate medical attention and special treatment needed
Treatment:
Until the revision date of this document, no adverse effects and symptoms to exposure of the
product are known, including chemical reactivity and instability.

SECTION 5: Firefighting measures


5.1. Extinguishing media
Suitable extinguishing media:
Water.
Carbon dioxide (CO2).
Extinguishing media which must not be used for safety reasons:
None in particular.
5.2. Special hazards arising from the substance or mixture
The product does not contain ingredients classified as explosive according to Regulation
1272/2008/EC (CLP).
Do not inhale explosion and combustion gases.
Burning produces heavy smoke.
5.3. Advice for firefighters
Use suitable breathing apparatus .
Collect contaminated fire extinguishing water separately. This must not be discharged into
drains.
Move undamaged containers from immediate hazard area if it can be done safely.
The mixture does not contain ingredients classified as explosive according to EC Regulation
1272/2008 (CLP).

SECTION 6: Accidental release measures

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6.1. Personal precautions, protective equipment and emergency procedures


Wear personal protection equipment.
Remove all sources of ignition.
Remove persons to safety.
See protective measures under point 7 and 8.
6.2. Environmental precautions
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
Retain contaminated washing water and dispose it.
In case of gas escape or of entry into waterways, soil or drains, inform the responsible
authorities.
Suitable material for taking up: absorbing material, organic, sand
6.3. Methods and material for containment and cleaning up
Wash with plenty of water. To converge the product in containment tanks.
6.4. Reference to other sections
See also section 8 and 13

SECTION 7: Handling and storage


7.1. Precautions for safe handling
Avoid contact with skin and eyes, inhalation of vapours and mists.
Do not eat or drink while working.
See also section 8 for recommended protective equipment.
7.2. Conditions for safe storage, including any incompatibilities
Store away from sunlight.
Store in a cool and well ventilated place.
Do not store in open or unlabeled containers.
Keep away from food, drink and feed.
Incompatible materials:
None in particular. See also section 10.
Instructions as regards storage premises:
Adequately ventilated premises.
7.3. Specific end use(s)
None in particular, see paragraph 1.2

SECTION 8: Exposure controls/personal protection


8.1. Control parameters
Until the revision date of this document, no experimental data are available for the mixture.
Below, listed occupational exposure limits, if available, for the components listed in paragraph 3.2.
2-(2-BUTOXYETHOXY)ETHANOL - CAS: 112-34-5
EU - LTE(8h): 67.5 mg/m3, 10 ppm - STE(15min): 101.2 mg/m3, 15 ppm
ACGIH - LTE(8h): 10 ppm
DNEL Exposure Limit Values
Until the revision date of this document, no experimental data are available for the mixture.
Below, listed the DNEL exposure limits, if available, for the components listed in paragraph 3.2.
2-(2-BUTOXYETHOXY)ETHANOL - CAS: 112-34-5
Worker Industry: 67.5 mg/m3 - Consumer: 34 mg/m3 - Exposure: Human Inhalation -
Frequency: Long Term (repeated)
Worker Industry: 20 mg/kg - Consumer: 10 mg/kg - Exposure: Human Dermal -
Frequency: Long Term, systemic effects
Worker Industry: 101.2 mg/m3 - Consumer: 50.6 mg/m3 - Exposure: Human Inhalation
- Frequency: Short Term, local effects
Consumer: 1.25 mg/kg - Exposure: Human Oral - Frequency: Long Term, systemic
effects
PNEC Exposure Limit Values
Until the revision date of this document, no experimental data are available for the mixture.

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BETON

Below, listed the PNEC exposure limits, if available, for the components listed in paragraph 3.2.
2-(2-BUTOXYETHOXY)ETHANOL - CAS: 112-34-5
Target: Marine water - Value: 0.1 mg/l
Target: Marine water sediments - Value: 0.4 mg/kg
Target: Microorganisms in sewage treatments - Value: 200 mg/l
Target: Soil (agricultural) - Value: 0.4 mg/kg
Target: Freshwater sediments - Value: 4 mg/kg

8.2. Exposure controls


Eye protection:
Not needed for normal use. Anyway, operate according good working practices.
Protection for skin:
No special precaution must be adopted for normal use.
Protection for hands:
Not needed for normal use.
Respiratory protection:
Not needed for normal use.
Thermal Hazards:
The product is not flammable or explosive - see paragraph 2.1. The product contains no
explosive components.
Until the revision date of this document, no adverse effects and symptoms to exposure of the
product are known, including chemical reactivity and instability.
Environmental exposure controls:
The product is not dangerous for the environment - see section 2.1.
Until the revision date of this document, no adverse effects and symptoms to exposure of the
product are known, including chemical reactivity and instability.
Appropriate engineering controls:
No further technical checks suitable for your product under normal conditions.
See also section 1.2, section 7 and Exposure Scenario - Annex I of this document.

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties

Properties Value Method: Notes:


Appearance and colour: Opaque Visual --
liquid, creamy
white
Odour: Technical Olfactory --
Odour threshold: Evident Olfactory --
pH: 7,7 +/- 0,5 Instrumental --
control
Melting point / freezing Not Relevant -- Parameter not relevant for the
point: type of product
Initial boiling point and >= 100 °C -- Estimated value on chemical /
boiling range: physical properties of
components
Flash point: > 65 ° C -- Estimated value on chemical /
physical properties of
components
Evaporation rate: Not Relevant -- Parameter not relevant for the
type of product
Solid/gas flammability: Not Relevant -- Parameter not relevant for the
type of product
Upper/lower flammability Not Relevant -- Parameter not relevant for the

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or explosive limits: type of product


Vapour pressure: Not Relevant -- Parameter not relevant for the
type of product
Vapour density: Not Relevant -- Parameter not relevant for the
type of product
Relative density: 1.018 g/ml Instrumental --
control
Solubility in water: Total -- internal tests
Solubility in oil: None -- internal tests
Partition coefficient < 1000 -- Value estimated based on the
(n-octanol/water): solubility of the mixture.
Auto-ignition temperature: Not Relevant -- Parameter not relevant for the
type of product
Decomposition Not Relevant -- Parameter not relevant for the
temperature: type of product
Viscosity: < 10 cP -- Estimated indicative value. Not
viscous mixture.
Explosive properties: Not Relevant -- Parameter not relevant for
product composition.
Oxidizing properties: Not Relevant -- Parameter not relevant for
product composition.

9.2. Other information

Properties Value Method: Notes:


Miscibility: Not Relevant -- Parameter not relevant for the
type of product
Fat Solubility: Not Relevant -- Parameter not relevant for the
type of product
Conductivity: Not Relevant -- Parameter not relevant for the
type of product
Substance Groups Not Relevant -- Parameter not relevant for the
relevant properties type of product

SECTION 10: Stability and reactivity


10.1. Reactivity
Until the revision date of this document, no adverse effects and symptoms to exposure of the
product are known, including chemical reactivity and instability.
10.2. Chemical stability
Until the revision date of this document, no adverse effects and symptoms to exposure of the
product are known, including chemical reactivity and instability.

10.3. Possibility of hazardous reactions


Until the revision date of this document, no adverse effects and symptoms to exposure of the
product are known, including chemical reactivity and instability.
See also scetion 7.2.
10.4. Conditions to avoid
Different uses than recommended. Do not use in combination with other products. See also
1.2 and 7.2

10.5. Incompatible materials


Until the revision date of this document, no adverse effects and symptoms to exposure of the
product are known, including chemical reactivity and instability. see also 1.2 and 7.2.

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10.6. Hazardous decomposition products


Until the revision date of this document, no adverse effects and symptoms to exposure of the
product are known, including chemical reactivity and instability.

SECTION 11: Toxicological information


11.1. Information on toxicological effects
Toxicological information of the mixture:
Until the revision date of this document, are not available experimental toxicological data on the
mixture.
For the classification of the mixture see section 2.1.
Not applicable
Toxicological information of the main substances found in the mixture:
Below are reported, if available, the toxicological information of the components listed in paragraph
3.2.
2-(2-BUTOXYETHOXY)ETHANOL - CAS: 112-34-5
a) acute toxicity:
Test: LD50 - Route: Oral - Species: Mouse = 2410 mg/kg
Test: LD50 - Route: Skin - Species: Rabbit = 2764 mg/kg
Test: LC50 - Route: Inhalation - Species: Rat > 29 ppm - Duration: 2h
b) skin corrosion/irritation:
Test: Skin Irritant No - Source: OECD 404
c) serious eye damage/irritation:
Test: Eye Irritant Yes - Source: OECD 405
d) respiratory or skin sensitisation:
Test: Skin or Resp. Sensitization Negative
e) germ cell mutagenicity:
Test: Mutagenesis Negative
f) carcinogenicity:
Test: Carcinogenicity Negative
g) reproductive toxicity:
Test: Reproductive Toxicity Negative

If not differently specified, the information required in Regulation (EU)2015/830 listed below must be
considered as Not Applicable:
a) acute toxicity;
b) skin corrosion/irritation;
c) serious eye damage/irritation;
d) respiratory or skin sensitisation;
e) germ cell mutagenicity;
f) carcinogenicity;
g) reproductive toxicity;
h) STOT-single exposure;
i) STOT-repeated exposure;
j) aspiration hazard.

SECTION 12: Ecological information


12.1. Toxicity
Adopt good working practices, so that the product is not released into the environment.
The environmental hazard of the product are reported in Section 2.1 if applicable.
Until the revision date of this document, are not available experimental data on the mixture.
Below are reported, if available, the eco-toxicological information of the components listed in
paragraph 3.2.
2-(2-BUTOXYETHOXY)ETHANOL - CAS: 112-34-5
a) Aquatic acute toxicity:

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Endpoint: LC50 - Species: Fish = 1300 mg/l - Duration h: 96 - Notes: Lepomis


macrochirus
Endpoint: EC50 - Species: Daphnia > 100 mg/l - Duration h: 48 - Notes: Daphnia
magna
Endpoint: EC50 - Species: Algae > 100 mg/l - Duration h: 72 - Notes: Scenedesmus
subspicatus
12.2. Persistence and degradability
Until the revision date of this document, are not available experimental data on the mixture.
Below are reported, if available, the eco-toxicological information of the components listed in
paragraph 3.2.
2-(2-BUTOXYETHOXY)ETHANOL - CAS: 112-34-5
Biodegradability: Readily biodegradable -OECD 301C - Duration: 28 days - %: 80-90
The surfactant(s) contained in this preparation complies with the biodegradability criteria laid down
in Regulation (EC) No 648/2004 on detergents. All supporting data are kept available to the
competent authorities of the Member States and will be provided to those authorities if they so
request or at the request of a detergent manufacturer.

12.3. Bioaccumulative potential


Until the revision date of this document, are not available experimental data on the mixture.
Below are reported, if available, the eco-toxicological information of the components listed in
paragraph 3.2.
2-(2-BUTOXYETHOXY)ETHANOL - CAS: 112-34-5
Bioaccumulation: Not bioaccumulative - Test: Kow - Partition coefficient 0.56 -
12.4. Mobility in soil
Until the revision date of this document, are not available experimental data on the mixture.
Below are reported, if available, the eco-toxicological information of the components listed in
paragraph 3.2.
Not applicable
12.5. Results of PBT and vPvB assessment
vPvB Substances: None - PBT Substances: None
12.6. Other adverse effects
Until the revision date of this document, unknown adverse effects and symptoms towards the
environment.

SECTION 13: Disposal considerations


13.1. Waste treatment methods
Recover if possible. In so doing, comply with the local and national regulations currently in
force. Do not discharge into the ground or into drains.
See also section 6.

SECTION 14: Transport information

14.1. UN number
Not classified as dangerous in the meaning of transport regulations.
14.2. UN proper shipping name
Not applicable
14.3. Transport hazard class(es)
Not applicable
14.4. Packing group
Not applicable
14.5. Environmental hazards
ADR-Enviromental Pollutant: No
IMDG-Marine pollutant: No
14.6. Special precautions for user

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BETON

Not applicable
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable

SECTION 15: Regulatory information


15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Dir. 98/24/EC (Risks related to chemical agents at work)
Dir. 2000/39/EC (Occupational exposure limit values)
Regulation (EC) n. 1907/2006 (REACH)
Regulation (EC) n. 1272/2008 (CLP)
Regulation (EC) n. 790/2009 (ATP 1 CLP) and (EU) n. 758/2013
Regulation (EU) 2015/830
Regulation (EU) n. 286/2011 (ATP 2 CLP)
Regulation (EU) n. 618/2012 (ATP 3 CLP)
Regulation (EU) n. 487/2013 (ATP 4 CLP)
Regulation (EU) n. 944/2013 (ATP 5 CLP)
Regulation (EU) n. 605/2014 (ATP 6 CLP)
Restrictions related to the product or the substances contained according to Annex XVII Regulation
(EC) 1907/2006 (REACH) and subsequent modifications:
None
Where applicable, refer to the following regulatory provisions :
Regulation (EC) nr 648/2004 (detergents).
1999/13/EC (VOC directive)

Provisions related to directive EU 2012/18 (Seveso III):


Seveso III category according to Annex 1, part 1
None

15.2. Chemical safety assessment


No, for instructions on safe mangling you see Sections 7 and 8 and the exposure scenario - Annex I
of this document.

SECTION 16: Other information

Full text of phrases referred to in Section 3:


H319 Causes serious eye irritation.
Paragraphs modified from the previous revision:

SECTION 1: Identification of the substance/mixture and of the company/undertaking


SECTION 2: Hazards identification
SECTION 3: Composition/information on ingredients
SECTION 4: First aid measures
SECTION 5: Firefighting measures
SECTION 6: Accidental release measures
SECTION 7: Handling and storage
SECTION 8: Exposure controls/personal protection
SECTION 9: Physical and chemical properties
SECTION 10: Stability and reactivity
SECTION 11: Toxicological information
SECTION 12: Ecological information
SECTION 14: Transport information
SECTION 15: Regulatory information

The classification of the product is based on conventional calculation method.

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This document was prepared by a competent person who has received appropriate training.
Main bibliographic sources:
ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre,
Commission of the European Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van
Nostrand Reinold
The information contained herein is based on our state of knowledge at the above-specified date. It
refers solely to the product indicated and constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to
the specific use intended.
This MSDS cancels and replaces any preceding release.

ADR: European Agreement concerning the International Carriage of


Dangerous Goods by Road.
CAS: Chemical Abstracts Service (division of the American Chemical
Society).
CLP: Classification, Labeling, Packaging.
DNEL: Derived No Effect Level.
EINECS: European Inventory of Existing Commercial Chemical Substances.
GefStoffVO: Ordinance on Hazardous Substances, Germany.
GHS: Globally Harmonized System of Classification and Labeling of
Chemicals.
IATA: International Air Transport Association.
IATA-DGR: Dangerous Goods Regulation by the "International Air Transport
Association" (IATA).
ICAO: International Civil Aviation Organization.
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization"
(ICAO).
IMDG: International Maritime Code for Dangerous Goods.
INCI: International Nomenclature of Cosmetic Ingredients.
KSt: Explosion coefficient.
LC50: Lethal concentration, for 0/10/20/50/100 percent of test population.
LD50: Lethal dose, for 0/10/20/50/100 percent of test population.
LTE: Long-term exposure.
PNEC: Predicted No Effect Concentration.
RID: Regulation Concerning the International Transport of Dangerous Goods
by Rail.
STE: Short-term exposure.
STEL: Short Term Exposure limit.
STOT: Specific Target Organ Toxicity.
TLV: Threshold Limiting Value.
TWATLV: Threshold Limit Value for the Time Weighted Average 8 hour day.
(ACGIH Standard).
WGK: German Water Hazard Class.

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ANNEX I
PROFESSIONAL PRODUCT – WAX AND POLISH

Title of exposure scenario


Polish product: Manual process
Use description

Sector Use SU22 – Professional use


Product Category PC31 – Polish and wax mixtures
Description of activities/process considered on exposure scenario.
Use following the use instruction as specified on the label.
Leave on.
Rinse, if necessary.
Frequency and duration
Use phase monthly average use, depending on the surfaces to treat.
Relevant limit values of ingredients, if available, are stated in section 8 of the SDS.
Physical appearence and concentration
Liquid. Ready to use.
In section 2 of the SDS of product and on the label the classification of mixture is provided.
Mixture classification is based on ingredients classification and on chemical/physical properties stated in section 9 of the SDS of
product.
Use conditions
Room temperature
Good general ventilation at workplace is sufficient.
Protection
See section 8 of the SDS of product to more information on PPE. Training of worker to use and maintenance of PPE is supposed.
Don’t eat or drink, don’t smoke. Avoid contact with damaged skin.
No open flame. Do not use in combination with other products
Wash hand after use.
In case of accidental release: dilute with water and dry.
See section 6 of the SDS in case of accidental release
Follow use instruction as specified on the label or on technical sheet. Use good occupational hygiene practices as specified in section
7 on the SDS.
Environmental measures
See section 6 of the SDS in case of accidental release
See section 12 of the SDS for ecotoxicological information of mixture and dangerous ingredients.
See section 13 of the SDS for disposal considerations.

Note:

SDS: Safety Data Sheet

PPE: Personal Protection Equipment

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