Chemistry An Atoms First Approach 2nd Edition Zumdahl Solutions Manual 1
Chemistry An Atoms First Approach 2nd Edition Zumdahl Solutions Manual 1
Chemistry An Atoms First Approach 2nd Edition Zumdahl Solutions Manual 1
CHAPTER 6
Questions
13. a. Polarity is a term applied to covalent compounds. Polar covalent compounds have an
unequal sharing of electrons in bonds that results in unequal charge distribution in the
overall molecule. Polar molecules have a partial negative end and a partial positive end.
These are not full charges as in ionic compounds but are charges much smaller in
magnitude. Water is a polar molecule and dissolves other polar solutes readily. The oxygen
end of water (the partial negative end of the polar water molecule) aligns with the partial
positive end of the polar solute, whereas the hydrogens of water (the partial positive end
of the polar water molecule) align with the partial negative end of the solute. These opposite
charge attractions stabilize polar solutes in water. This process is called hydration.
Nonpolar solutes do not have permanent partial negative and partial positive ends; nonpolar
solutes are not stabilized in water and do not dissolve.
b. KF is a soluble ionic compound, so it is a strong electrolyte. KF(aq) actually exists as
separate hydrated K+ ions and hydrated F ions in solution: C6H12O6 is a polar covalent
molecule that is a nonelectrolyte. C6H12O6 is hydrated as described in part a.
c. RbCl is a soluble ionic compound, so it exists as separate hydrated Rb+ ions and hydrated
Cl ions in solution. AgCl is an insoluble ionic compound, so the ions stay together in
solution and fall to the bottom of the container as a precipitate.
d. HNO3 is a strong acid and exists as separate hydrated H+ ions and hydrated NO3 ions in
solution. CO is a polar covalent molecule and is hydrated as explained in part a.
14. Water is a polar solvent because the H2O molecule exhibits a permanent dipole moment, that
is, H2O is a molecule which has a partial negative charged end and a partial positive charged
end. Water will dissolve other polar covalent compounds (other covalent compounds which
have permanent dipole moments), but nonpolar covalent compounds will be insoluble in water.
In the electrostatic potential diagrams, a permanent dipole moment exists in a molecule if the
molecule has one specific area with a partial negative end (a red end) and a different specific
region with a partial positive end (a blue end). If the blue and red colors are equally distributed
in the electrostatic potential diagrams, then no permanent dipole exists; the molecule is
classified as nonpolar and will be insoluble in water.
218
219CHAPTER 6 SOLUTION STOICHIOMETRY
CHAPTER 6 SOLUTION STOICHIOMETRY219
15. Water is a polar solvent and will dissolve other polar covalent solutes. F 2 is a nonpolar
compound and will not be soluble in water. For CF4 and SF2, let’s look at the Lewis structures
and draw in arrows to represent the bond dipoles in the polar bonds.
CF4, 4 + 4(7) = 32 e SF2, 6 + 2(7) = 20 e
F
S
C F F
F F
F
Both CF4 and SF2 have polar bonds, but only SF2 is polar. The individual bond dipoles cancel
each other in the tetrahedral CF4 molecule, so CF4 is nonpolar and will not be soluble in water.
However, the individual bond dipoles do not cancel each other out in the bent SF2 molecule,
and this molecule is polar. Of the three molecules, the polar SF 2 molecule will be the most
soluble in water.
16. 2.0 L × 3.0 mol/L = 6.0 mol HCl; the 2.0 L of solution contains 6.0 mol of the solute. HCl is
a strong acid; it exists in aqueous solution as separate hydrated H+ ions and hydrated Cl ions.
So the solution will contain 6.0 mol of H+(aq) and 6.0 mol of Cl (aq). For the acetic acid
solution, HC2H3O2 is a weak acid instead of a strong acid. Only some of the 6.0 moles of
HC2H3O2 molecules will dissociate into H+(aq) and C2H3O2(aq). The 2.0 L of 3.0 M HC2H3O2
solution will contain mostly hydrated HC2H3O2 molecules but will also contain some hydrated
H+ ions and hydrated C2H3O2 ions.
17. Only statement b is true. A concentrated solution can also contain a nonelectrolyte dissolved
in water, e.g., concentrated sugar water. Acids are either strong or weak electrolytes. Some
ionic compounds are not soluble in water, so they are not labeled as a specific type of
electrolyte.
18. One mole of NaOH dissolved in 1.00 L of solution will produce 1.00 M NaOH. First, weigh
out 40.00 g of NaOH (1.000 mol). Next, add some water to a 1-L volumetric flask (an
instrument that is precise to 1.000 L). Dissolve the NaOH in the flask, add some more water,
mix, add more water, mix, etc. until water has been added to 1.000-L mark of the volumetric
flask. The result is 1.000 L of a 1.000 M NaOH solution. Because we know the volume to four
significant figures as well as the mass, the molarity will be known to four significant figures.
This is good practice, if you need a three-significant-figure molarity, your measurements should
be taken to four significant figures.
When you need to dilute a more concentrated solution with water to prepare a solution, again
make all measurements to four significant figures to ensure three significant figures in the
molarity. Here, we need to cut the molarity in half from 2.00 M to 1.00 M. We would start with
220CHAPTER 6 SOLUTION STOICHIOMETRY
CHAPTER 6 SOLUTION STOICHIOMETRY220
1 mole of NaOH from the concentrated solution. This would be 500.0 mL of 2.00 M NaOH.
Add this to a 1-L volumetric flask with addition of more water and mixing until the 1.000-L
mark is reached. The resulting solution would be 1.00 M.
19. Use the solubility rules in Table 6-1. Some soluble bromides by Rule 2 would be NaBr, KBr,
and NH4Br (there are others). The insoluble bromides by Rule 3 would be AgBr, PbBr2, and
Hg2Br2. Similar reasoning is used for the other parts to this problem.
Sulfates: Na2SO4, K2SO4, and (NH4)2SO4 (and others) would be soluble, and BaSO4, CaSO4,
and PbSO4 (or Hg2SO4) would be insoluble.
Hydroxides: NaOH, KOH, Ca(OH)2 (and others) would be soluble, and Al(OH)3, Fe(OH)3, and
Cu(OH)2 (and others) would be insoluble.
Phosphates: Na3PO4, K3PO4, (NH4)3PO4 (and others) would be soluble, and Ag3PO4, Ca3(PO4)2,
and FePO4 (and others) would be insoluble.
Lead: PbCl2, PbBr2, PbI2, Pb(OH)2, PbSO4, and PbS (and others) would be insoluble. Pb(NO3)2
would be a soluble Pb2+ salt.
The 1.0 mol of Pb2+ ions would react with the 2.0 mol of I ions to form 1.0 mol of the PbI2
precipitate. Even though the Pb2+ and I ions are removed, the spectator ions K+ and NO3 are
still present. The solution above the precipitate will conduct electricity because there are plenty
of charge carriers present in solution.
21. The Brønsted-Lowry definitions are best for our purposes. An acid is a proton donor, and a
base is a proton acceptor. A proton is an H+ ion. Neutral hydrogen has 1 electron and 1 proton,
so an H+ ion is just a proton. An acid-base reaction is the transfer of an H+ ion (a proton) from
an acid to a base.
22. The acid is a diprotic acid (H2A), meaning that it has two H+ ions in the formula to donate to a
base. The reaction is H2A(aq) + 2 NaOH(aq) 2 H2O(l) + Na2A(aq), where A2 is what is
left over from the acid formula when the two protons (H+ ions) are reacted. For the HCl
reaction, the base has the ability to accept two protons. The most common examples are
Ca(OH)2, Sr(OH)2, and Ba(OH)2. A possible reaction would be 2 HCl(aq) + Ca(OH)2(aq)
2 H2O(l) + CaCl2(aq).
23. a. The species reduced is the element that gains electrons. The reducing agent causes reduc-
tion to occur by itself being oxidized. The reducing agent generally refers to the
entire formula of the compound/ion that contains the element oxidized.
b. The species oxidized is the element that loses electrons. The oxidizing agent causes
oxidation to occur by itself being reduced. The oxidizing agent generally refers to the entire
formula of the compound/ion that contains the element reduced.
221CHAPTER 6 SOLUTION STOICHIOMETRY
CHAPTER 6 SOLUTION STOICHIOMETRY221
c. For simple binary ionic compounds, the actual charges on the ions are the same as the
oxidation states. For covalent compounds, nonzero oxidation states are imaginary charges
the elements would have if they were held together by ionic bonds (assuming the bond is
between two different nonmetals). Nonzero oxidation states for elements in covalent
compounds are not actual charges. Oxidation states for covalent compounds are a
bookkeeping method to keep track of electrons in a reaction.
24. Reference the Problem Solving Strategy in Section 6-10 of the text for the steps involved in
balancing redox reactions by oxidation states. The key to the oxidation states method is to
balance the electrons gained by the species reduced with the number of electrons lost from the
species oxidized. This is done by assigning oxidation states and, from the change in oxidation
states, determining the coefficients necessary to balance electrons gained with electrons lost.
After the loss and gain of electrons is balanced, the remainder of the equation is balanced by
inspection.
Exercises
Aqueous Solutions: Strong and Weak Electrolytes
- + 2+ -
Br Na Mg - Cl
Cl
+ - - 2+
Na Br Cl Mg
Your drawing should show equal Your drawing should show twice the
number of Na+ and Br- ions. number of Cl ions as Mg2+ ions.
+ - - -
Al3 NO3 NO3 SO 4
2-
NH 4
+
+ +
- - +
NO 3 NO3 Al3 NH 4 NH4 SO4 2
- - - - +
NO
NO 3 NO3 2
3 SO 4 NH 4
- - + +
3+ NO3 NH4 NH 4
NO 3 Al
For e-i, your drawings should show equal numbers of the cations and anions present because
each salt is a 1 : 1 salt. The ions present are listed in the following dissolution reactions.
Boil one cupful of rice as directed in ‘How to boil Rice’; add half a
cupful of Tomato sauce (see Sauces, p. 126), season with some butter,
salt, and pepper to taste, and one or two bay leaves. Toss, or mix lightly
with a fork, being careful not to mash the grains. Serve hot. This makes a
nice dish for winter.
Mince up half an onion, one clove of garlic, one carrot, half a head of
celery, and a bunch of parsley, and brown in pure olive oil. Then put six
or seven ounces of prawns into the sauce-pan, and season with salt and
pepper. Turn them often, and when all are red put in two or three
tablespoonfuls of Tomato sauce (or conserve), and add enough hot water
to cook fourteen or fifteen ounces of rice in afterwards. Do not boil too
much, as prawns cook fast. Take the prawns out, dry them, choose about
a third of the finest, shell and lay them aside. Pound the others in a
mortar (shells and all), rub them through a sieve, and mix again with the
water in which they were cooked. Meanwhile put some butter into a
sauce-pan, add the rice, stir well, and as soon as it has taken up the
butter, pour the water little by little on to it. When half-boiled add the
shelled prawns, and before serving sprinkle Parmesan cheese over the
whole.
Cut two ounces of bacon into small pieces, and put them into a sauce-
pan with chopped-up cabbage. Steam for half an hour and add a little
salt, pepper, and chopped parsley; then throw in a quarter of a pound of
rice and half a pint of veal broth. Cook for fifteen or eighteen minutes,
and serve with grated Parmesan cheese sprinkled over it.
Melt two ounces of good fresh butter in a sauce-pan over a sharp fire,
add one onion chopped fine, brown a deep golden colour, then add about
ten ounces of clean rice (Italian if possible) and two large truffles
chopped up. Stir without stopping for one and a half minutes, and add
one quart of boiling veal broth, stir and let it cook for fourteen minutes.
Add six chopped-up mushrooms, and, a little at a time, one more quart of
broth, stirring constantly over a sharp fire for ten minutes more. Put in
half a teaspoonful of salt, a little pepper, one and a half ounces of grated
Parmesan cheese, and a teaspoonful of saffron soaked in two
tablespoonfuls of hot broth, and strained. Cook three or four minutes
longer, stirring all the time, then pour into a deep dish, and serve hot with
some grated Parmesan cheese separate. It is an improvement to put a
tablespoonful of marrow into the centre just before serving.
Cut up an onion and cook it with one and a half ounces of beef
marrow, and the same quantity of good butter; when browned put in one
pound of rice and add three-quarters of a glass of good white wine and
broth enough to cook the rice. Before taking off the fire add one and a
half ounces of butter and some grated Parmesan cheese, and serve with
more grated cheese separately.
Boil some small and tender artichokes and leave them to cool. Just
before serving drop into the middle of each, one drop of onion juice, lay
them on lettuce leaves, and pour sauce Mayonnaise (see Sauces, p. 123)
over them.
Beetroot Salad.
Slice two or three cold, boiled beetroots and place them in a salad-
bowl. Pour half a pint of sauce Tartara (see Sauces, p. 126) over them
and serve up with a garnish of parsley leaves.
Broccoli Salad.
Boil one or two heads of broccoli in salted water, then strain them and
dry with a cloth. Make a sauce of pure olive oil, white wine vinegar, very
little salt and pepper, one tablespoonful of capers, and two or three
anchovies chopped up with some parsley. Pour over the broccoli when
cold and serve.
Cabbage Salad.
Cut the heart of a white cabbage and half a head of celery into shreds.
Boil half a teacup of vinegar with one tablespoonful of butter, add one
tablespoonful of sugar, salt and pepper to taste, and put in the cabbage,
but do not let it boil. Meanwhile beat up two eggs, mix them in one
cupful of hot milk, and boil to a custard. Then put the cabbage into a
salad-bowl, pour the custard over it, and mix well. Place in the ice-box
until wanted.
Wash and dry well two lettuces and a bunch of water-cresses, cut two
large cold, boiled beetroots into strips, add twelve radishes, six hard-
boiled eggs chopped up, and one sliced cucumber. Arrange the lettuce
leaves round a salad-bowl, mix all the rest with half a pint of sauce
Mayonnaise (see Sauces, p. 123) and serve.
Cauliflower Salad.
Boil a large cauliflower, then put it in cold water; when quite cold,
break it into pieces, and put these to dry on a napkin before placing in the
salad-bowl. Add two shalots and some parsley chopped up, salt and
pepper to taste, and pour half a pint of sauce Mayonnaise (see Sauces, p.
123) over it before serving.
Celery Salad.
Cut the white stalks into small pieces and add half a pint of sauce
Mayonnaise (see Sauces, p. 123) to every pound of celery. Sprinkle with
salt and pepper, mix well with the sauce, and serve the dish trimmed with
the green leaves of the celery.
Peel and slice two cucumbers, dry them on a napkin, then peel and
slice two large tomatoes. Cover the bottom of the salad-bowl with lettuce
leaves, and then alternate layers of the cucumbers and tomatoes, pour
sauce ‘alla Francese’ (see Sauces, p. 123) over and serve.
Wash the curly inside leaves of two heads of endive, dry them well,
put them into a salad-bowl, pour three tablespoonfuls of good olive oil
over them, and add a finely chopped shalot. Mix one tablespoonful of
honey (or sugar), one of vinegar, and salt and pepper to taste, in a cup,
and pour over the salad just before serving.
Boil one pound of French beans until tender, drain, and put them in
cold water. Dry them on a napkin, and cut them lengthwise into four
pieces. Pour sauce ‘alla Francese’ (see Sauces, p. 123) over them just
before serving.
Cut one carrot and one turnip into slices and cook them in boiling
soup. When cold mix them with two large cold, boiled potatoes, and one
beetroot cut into strips. Add a very little chopped leeks, or onion, pour
some sauce ‘Lombarda’ (see Sauces, p. 123) over the salad, and garnish
with water-cress.
Lettuce Salad.
Use only the tender leaves, and let them stand in cold water until
wanted. Wipe them quite dry, then break with the fingers into the
following sauce: Two or three yolks of hard-boiled eggs beaten up with
one tablespoonful of pure olive oil, salt and pepper to taste, two more
tablespoonfuls of oil added gradually, and one of white wine vinegar, and
one teaspoonful of mustard. Mix well and garnish the salad-bowl with
nasturtium (Tropæolum) flowers.
Put the tender leaves of lettuce into cold water till wanted; then wipe
them dry and stand them in circles in the salad-bowl. Sprinkle them with
half a teaspoonful of chopped taragon, the same of chervil, of parsley
and of chives, and pour the following sauce over them: mix in a cup one
tablespoonful of pure olive oil, one saltspoonful of salt, and half a
saltspoonful of pepper, stir well; add two more tablespoonfuls of oil, and
one of vinegar (if liked add two drops of onion juice). The salad must not
be mixed till wanted, and can be garnished with small radishes or
nasturtium flowers.
Slice up a head of lettuce and chop up two boiled eggs in large pieces,
add half a pound of cold veal (or fish), cut into strips one inch long, and
mix in a salad-bowl. Then beat up the yolks of two raw eggs, add a very
little salt, and mix in gradually four tablespoonfuls of pure olive oil, and
one of white wine vinegar; a few drops of taragon vinegar is an
improvement.
Cut into small pieces one cold boiled beetroot and half an onion, add
some cold boiled French beans, two ounces of cold boiled asparagus
heads, two tablespoonfuls of cold cooked peas, one cold boiled carrot,
and one head of celery. Mix them well together, pour sauce Mayonnaise
(see Sauces, p. 123) over them, add the juice of a lemon, and serve.
Chop up six lettuce leaves, and three stalks of celery; cut the remains
of a cold boiled fowl into small pieces and mix with one tablespoonful of
white wine vinegar and salt and pepper to taste, in a salad-bowl. Pour a
cupful of sauce Mayonnaise (see Sauces, p. 123) over; and garnish with
quarters of hard-boiled eggs, one tablespoonful of capers, twelve stoned
olives, and some small tender lettuce leaves.
Boil six potatoes; peel, slice them fine, mix with one or two small
onions cut into quarters, and half a tumbler of red wine; add salt and
pepper to taste, four or five tablespoonfuls of oil, and half a
tablespoonful of white wine vinegar, one tablespoonful of chervil
chopped fine, and some thin slices of anchovies, or, if preferred, smoked
herring. Stir well, but before serving take out the onions.
Boil some fine potatoes, peel and slice them. Slice some truffles
(boiled in white wine) very thin and put them in alternate layers with
potatoes into a salad-bowl. Season with four or five tablespoonfuls of
good olive oil, one dessert-spoonful of white wine vinegar, and salt and
pepper to taste. Garnish with slices of anchovies, stoned olives, and (if
liked) a few young chives.
Boil six fine potatoes, slice them and place them to cool. Slice three
hard-boiled eggs, and mince four ounces of pickled tunny-fish fine. Place
alternate layers of minced tunny, and sliced potato and egg, in the salad-
bowl, sprinkle the last layer with chopped chervil, and season the dish
with pure olive oil, white wine vinegar, pepper and a very little salt,
mixed separately and poured over before serving.
Cut up two boiled carrots, one small turnip, half a bunch of asparagus
(the green part) one small beetroot, and some cold chicken or partridge,
into dice, take some cold boiled young French beans, and green peas,
one tablespoonful of capers, some stoned olives, slices of anchovies, and
some prawns. Make a sauce of pure olive oil (a good deal), a little
vinegar, pepper, half a pinch cayenne, some mustard, a spoonful of
caviare, and one finely chopped shalot.
Peel and slice two large Spanish onions and two cucumbers. Put them
into iced water for twenty minutes, then drain, and dry them well on a
cloth. Arrange the slices of onion and cucumber alternately on a dish,
pour sauce ‘alla Francese’ (see Sauces, p. 123), over them and serve.
N.B.—Cucumbers should if possible always be kept on ice, and never
be put into salted water.
Take two large cucumbers, and one head of celery, peel and slice; add
a bunch of red radishes. Add six cold, boiled young artichokes cut into
quarters. Sprinkle with finely chopped chervil, mix, and pour sauce ‘alla
Francese’ (see Sauces, p. 123) over just before serving.
Scald[18] and peel ripe tomatoes and put them in ice. Cut them into
thin slices and put on a flat dish. In the centre of each slice put one
teaspoonful of sauce Mayonnaise (see Sauces, p. 123), and garnish with
sprigs of parsley. Or the tomato can be cut in two, laid on a young lettuce
leaf, and sauce Mayonnaise poured over them.
[18] Put the tomatoes in a wire basket and plunge them into boiling water
for one minute. If left too long in the water they get soft.
Scald and peel twelve or eighteen small yellow tomatoes. Pile them on
a dish like plums, garnish with young lettuce leaves, and pour the
following sauce over them: mix well in a cup one tablespoonful of pure
olive oil, one saltspoonful of salt, and half a saltspoonful of pepper, add,
stirring all the time, two tablespoonfuls of oil, and one of vinegar, and, if
the flavour is liked, add two drops of onion juice.
Peel round red tomatoes of equal size, and scoop out a bit of the fruit
from the stem end. Keep them on ice till wanted, then fill them high with
sauce Mayonnaise (see Sauces, p. 123) and celery cut into shreds of half
an inch long. Place each on a young lettuce leaf on which a little sauce
Mayonnaise has been put, and arrange on a flat dish. (Chopped hard-
boiled eggs and lettuce may be used instead of celery.)
Scald and peel six fine tomatoes and put them in ice, cut them into
very thin slices in a salad-bowl so as to keep the juice. Season with salt
and pepper to taste, two tablespoonfuls of oil, one of vinegar, and, if
liked, one small teaspoonful of chives. Mix well and serve as cold as
possible.
Take round tomatoes (not too big), fill them as in No. 3, but do not let
the stuffing stand out beyond the fruit. Then put small moulds, or cups,
on ice, and pour in one-eighth of an inch of clear aspic jelly; when set,
place a tomato (the filled side uppermost) into each mould, and pour
more jelly round it and over it. Ice well, turn out the tomatoes on a dish
garnished with sliced lettuce or watercress, and serve with sauce
Mayonnaise (see Sauces, p. 123) separate.
Tomato Jelly Salad.
Boil five or six tomatoes until they are soft with one teaspoonful of
salt, one of sugar, half a teaspoonful of thyme, a saltspoonful of pepper,
one slice of onion, one bay leaf, and three cloves. Then add enough
calves’ feet jelly (or isinglass) to set the tomato juice, strain, and pour
into a mould on ice. If the jelly is in the shape of a ring fill the centre
with curled celery, mix with sauce Mayonnaise (see Sauces, p. 123), and
garnish with lettuce cut into shreds; if solid put the celery and sauce
Mayonnaise round the jelly.
Scald and peel twelve small round tomatoes, cut off the stem end, take
out the seeds, and put them on ice. Meanwhile chop up fine the inside of
a head of celery, mix with some sauce ‘Francese’ (see Sauces, p. 123),
and fill the tomatoes with it. Place each tomato on a fresh lettuce leaf,
and pour a seasoning of oil, vinegar, salt and pepper over all.
Watercress Salad.
Wash three or four bunches of watercress and drain them, slice four or
five cold boiled potatoes very thin and mix with the following sauce:
four tablespoonfuls of oil, half a tablespoonful of vinegar, salt and black
pepper to taste, one shalot minced up fine, half a pinch of cayenne, and
half a tablespoonful of sugar.
SAUCES
Roux for Sauces.
Bearnese Sauce.
Take five yolks of eggs, one ounce of butter, a pinch of salt, and one of
pepper. Stir, and as soon as the eggs begin to consolidate take the sauce-
pan off the fire and add one ounce of butter. Then put the sauce-pan on
the fire again and stir in one ounce more butter; repeat this twice, then
add one tablespoonful of chopped tarragon, and one teaspoonful of
tarragon vinegar. This sauce must be stiff and have the consistency of
Mayonnaise.
Put two ounces of butter and two tablespoonfuls of flour into a sauce-
pan and stir for five minutes. Pour one and a half pints of boiling milk in
gradually, beating well with a whisk. Add a bouquet, half a teaspoonful
of grated nutmeg, twelve peppercorns, a pinch of salt, and three ounces
of chopped mushrooms. Cook for a quarter of an hour, and rub through a
fine sieve.
Cut a thick slice of veal or part of a knuckle into small cubes and put
them into a sauce-pan with two ounces of butter, two medium-sized
onions and two carrots sliced. Cook for ten minutes, taking care it should
not brown, then put in five ounces of flour and stir for five minutes over
the fire. Pour in three quarts of strong white stock and one of good
cream. Add three and a half ounces of minced mushrooms, one bouquet,
one saltspoonful of salt, and half a saltspoonful of pepper. Let it boil, and
then stand the sauce-pan to simmer on the hob for one and a half hours,
skimming often. Strain through a sieve into a large sauce-pan to jelly,
add two wineglassfuls of cream and reduce till the sauce clings to the
spoon. Then strain again. Stir occasionally while it is cooling, or a skin
will form on the top of the sauce, in which case it must be strained again.
Slice three onions and one carrot, and put them into a sauce-pan with
two whole onions and seven ounces of butter. Cook for five minutes,
then add seven ounces of flour, stir, and add three quarts of milk. Put in a
bunch of parsley and half an ounce of salt. Reduce for a quarter of an
hour stirring all the time, then strain through a sieve. Cover the sauce
with a thin layer of melted butter, and it will keep some days. When
wanted boil and stir in three and a half ounces of butter for every quart of
sauce.
Mince an anchovy and dissolve it in oil and butter over a slow fire,
add four ounces of capers, three tablespoonfuls of vinegar, and some
chopped parsley. This sauce can be served hot or cold.
Mince up one small onion with two ounces of capers and three-
quarters of an ounce of anchovies. Brown them in a sauce-pan with a
little butter, then add one cupful of broth or good gravy, a little vinegar,
and a pinch of sweet herbs. Boil up twice and serve with any boiled
meat.
Take four ounces of butter, one tablespoonful of flour, pepper and salt
to taste, and mix well over the fire in a sauce-pan. Do not let it boil, and
just before serving add two ounces of capers and one teaspoonful of
white wine vinegar.
Take pure olive oil, four ounces of capers and the juice of a lemon.
Mix them well together and serve.
Put two ounces of flour into one quart of water, with one and a half
ounces of butter, and a little salt and pepper. Cook for twenty minutes,
stirring well, then strain into a covered bowl and put into a Bain-marie.
Just before serving boil again, take off the fire, add twelve ounces of
butter cut into pieces, and the juice of one fine lemon. The heat of the
sauce must melt the butter as it must not be put on the fire again. If the
sauce is too thick mix in half a wineglassful of hot water.
Francese Sauce.
Stir six yolks of eggs, seventeen ounces of butter, salt and pepper to
taste, well together. When they begin to consolidate mix in one
wineglassful of purée of tomatoes passed through a fine sieve, one ounce
of chicken jelly, one tablespoonful of chopped parsley, and one
teaspoonful of capsicum vinegar.
Lombarda Sauce.
Put two tumblers of white roux and one of chicken jelly into a sauce-
pan, reduce, and add three yolks of eggs mixed with two ounces of butter
and the juice of half a lemon. Before it boils take the sauce-pan off the
fire and add one tumbler of thick Tomato sauce (see Sauces, p. 126) (or
conserve), strain, and just before serving add one tablespoonful of sweet
herbs minced fine.
Mayonnaise Sauce.
Put one yolk of egg (quite free from any white), half a teaspoonful of
salt, and a pinch of cayenne, into a bowl standing in ice. Stir constantly,
and add one cupful of pure olive oil, drop by drop. The goodness of the
sauce depends upon adding the oil slowly. When it begins to get thick,
alternate a few drops of tarragon vinegar with the oil till you have put in
one and a half teaspoonfuls of vinegar (lemon juice may be used
instead). In summer it is a good plan to mix the yolk of a hard-boiled egg
with the raw one; the sauce is made more quickly and is less likely to
curdle.
Olandese Sauce.
Melt half a pound of butter, add a little flour, salt, pepper, and grated
nutmeg. Stir until thick, then add one pint of cream, a little chopped
parsley, and heat for five minutes.
Put four quarts of good stock into a sauce-pan with two pounds of
knuckle of veal and the body of a fowl. Boil well, skimming off the
grease, add one teaspoonful of salt, two onions (one of them stuck with
cloves), one bouquet, and a pinch of grated nutmeg. Simmer on the hob
until the veal is quite cooked, then strain. Add three tablespoonfuls of
white roux and stir over the fire until it boils. Skim, and put it into a
Bain-marie to reduce. Just before serving boil it again and add one ounce
of butter and three tablespoonfuls of milk of sweet almonds.
Put the body of a fowl into a sauce-pan, cover it with water, and cook
quickly. Take it out as soon as it boils, drain, and wash it well. Then put
the fowl into a clean sauce-pan, with one quart of veal broth, one dessert-
spoonful of salt, and a bouquet. Cook for forty-five minutes, then pour
the broth through a strainer into another sauce-pan with two
tablespoonfuls of white roux, and stir well.
Wash and mince two anchovies with the yolks of two hard-boiled
eggs. Mince separately some parsley, tarragon, one shallot (or a small
onion). Put them into a bowl with one tablespoonful of white wine
vinegar, one and a half of olive oil, one of French mustard, and a little
pepper and salt. Beat up well with a wooden spoon till quite smooth.
Take four pounds of tomatoes, cut them in two and put them into a
two-quart sauce-pan with two wineglassfuls of water, two saltspoonfuls
of salt, one of pepper, and a bouquet. Cover the sauce-pan and boil for
forty minutes, stirring often to prevent burning; then strain. Make a roux
in another sauce-pan with one ounce of butter, and three-quarters of an
ounce of flour. Cook for three minutes, mixing well. Take the roux off
the fire and pour the tomatoes into it a little at a time, stirring to keep it
smooth. Add two wineglassfuls of stock, put on the fire, and cook for
twenty minutes, stirring all the time.
Vellutata Sauce.
Put one pound of knuckle of veal and any scraps you have of fowl into
a well-buttered sauce-pan with two or three slices of ham, two carrots,
one onion, and one tumbler of veal broth. When the broth is reduced add
twelve mushrooms, two or three shallots, salt and pepper to taste, a
bouquet, and enough veal broth to cover the meat. Boil, skim off the fat,
and let it simmer for one and a half hours. It will keep some days if well
corked in a cold place. Before using mix white roux with it.
Sorrel Purée.
Nip the stalks off a peck of sorrel, wash well, drain, and chop up fine
with one head of well-washed lettuce and a small bunch of chervil. Put
all into a sauce-pan and stir over a hot fire for three minutes, then place
in the oven until well dissolved. Add one and a half ounces of fresh
butter, stir until it bubbles, add half a pint of good stock or beef gravy,
and cook for five minutes.
Take sorrel as above, but instead of stock or gravy, add two yolks of
eggs and half a cupful of cream.
Sorrel Stewed.
Wash clean the necessary quantity of sorrel, boil until tender, then rub
through a sieve into a stew-pan. Add one or two tablespoonfuls of
Béchamel sauce (see Sauces, p. 119), a little salt and sugar, and two or
three ounces of fresh butter. Stew for a few minutes and serve.
SOUPS.
Artichoke Soup.
Boil three large artichokes for forty minutes, then dry and cut them in
pieces and rub through a sieve. Put one quart of milk in an earthen pot,
boil, add the artichokes, two ounces of butter, and three tablespoonfuls of
flour. Stir until the milk thickens, add pepper and salt to taste, and boil
for ten minutes, adding chicken forcemeat balls just before serving. (For
the forcemeat balls take four tablespoonfuls of minced raw fowl, some
grated bread, the white of an egg beaten up, and a little salt and pepper.
Place the balls in boiling water as you make them, and boil for ten
minutes. Take them out with the strainer and put them into the soup.)
Cut the bottom out of several artichokes, blanch them, remove the
chokes and boil with a little salt, flour, and lemon juice. Then mash them
and mix with one (or more, according to the number of people) cupful of
Béchamel sauce (see Sauces, p. 119); rub through a sieve, add enough
good stock to make a thick soup, and serve with small croûtons (fried
bread).
Asparagus Soup.
Boil a bunch of asparagus in salted water for half an hour, then cut off
their heads and put them into a soup-tureen. Meanwhile boil one quart of
milk, mix three tablespoonfuls of flour and one of butter together, and
add to the milk; stir until it thickens. Rub the rest of the asparagus
through a sieve and add to the milk. Take it off the fire, season with salt
and pepper, and pour it into the tureen on to the asparagus heads.
Carrot Soup.
Put eight or ten finely sliced carrots, one onion, two heads of celery
sliced, five ounces of fresh white haricot beans, four ounces of butter,
and salt and pepper to taste, in a sauce-pan. Cook over a slow fire for one
hour, and stir from time to time. Then add about one and a half quarts of
good stock, boil for one and a half hours, and rub through a sieve. Thin
the purée with three quarts of stock, add half an ounce of sugar, boil for
half an hour, and serve with croûtons (fried bread).
Chestnut Soup.
Peel some roast chestnuts, warm them in butter, moisten them with
stock and white wine, and simmer over a slow fire until soft. Then pound
them in a mortar, rub through a sieve, and mix with a thin purée of game.
Heat in a Bain-marie, and serve with small croûtons (fried bread).
Soak one pint of lentils in cold water all night. Strain and wash them
again, then put them in an earthen pot with two quarts of broth and
simmer for one and a half hours. Fry one sliced onion, a little chopped
parsley and thyme, and one bay leaf in two ounces of butter. Add these to
the lentils and simmer for another half-hour. Rub through a sieve and
boil, season with salt and pepper. Serve with croûtons (fried bread).
Put about half a pint of well-cleaned, dry lentils into boiling water in
an earthen pot. Be careful to remove those which float to the surface.
Leave the rest to cook until they are quite soft, then take them out and
strain them. Meanwhile mix two or three anchovies, a bunch of parsley
and some sage, and mix with some good oil in a sauce-pan. When well
browned put in the lentils. Stir well, add more oil, and cook over a slow
fire, stirring from time to time. When ready, mix in some strained stock,
and serve with croûtons (fried bread).
Lettuce Soup.
Put the mealy part of four potatoes into boiling consommé, the
blanched leaves of two heads of celery, one lettuce chopped up, one pint
of green peas, and two large tablespoonfuls of flour well stirred in cold
broth. Boil for one and a half hours, and serve with croûtons (fried
bread).
Potato Soup ‘alla Provinciale.’
Boil and rub two pounds of potatoes through a sieve, put them in a
sauce-pan with four ounces of good butter, a little salt, and half a tumbler
of cream (or milk). Simmer until it is thick like Polentina (see p. 135),
then add six yolks of eggs to consolidate it to a paste. Cut into small
dice, throw them into boiling soup, and cook for five minutes. Just
before serving sprinkle a little grated Parmesan cheese into the soup.
Cut two or three slices of white pumpkin into small dice. Put them into
a sauce-pan with four ounces of butter, and cook till they take a golden
colour. Mince up one onion, some parsley, sweet basil, celery, thyme,
and (for those who like it) one clove of garlic. Mix well, and add two
cloves, one quart of water, and some butter, or pure olive oil, or both.
Boil for one hour, serve very hot with croûtons (fried bread).
Take a slice (about one and a half pounds) of a large yellow pumpkin,
peel it and remove the seeds. Cut into small dice and put them into a
sauce-pan with one ounce of butter, a pinch of salt, one ounce of sugar,
and half a tumblerful of water. Boil for two hours, then drain, and put
back into the sauce-pan with one and a half tumblers of well-boiled milk.
As soon as it boils pour into the tureen and add croûtons (fried bread).
Chop up a few onions, warm them in butter, but take care they do not
brown. Stir in three tablespoonfuls of purée of white haricot beans, add a
pinch of grated nutmeg, and rub through a sieve. If the purée is too thick
add a little stock. Serve with croûtons (fried bread) in the soup.
Palestine Soup.
Scrape and slice six or eight large Jerusalem artichokes and put them
into cold water. Then place them in boiling water, boil for one hour, and
rub through a cullender. Mix them with two ounces of butter and three
tablespoonfuls of flour, and pour them into one quart of boiling milk,
stirring continually until thick. Season with salt and pepper, and serve
with croûtons (fried bread).
Pea Soup.
Shell four pounds of fresh green peas, put them in an earthen pot,
cover them with cold water, and boil for twenty minutes. Take out one
cupful of peas. Rub the rest through a sieve, and mix in an earthen pot
with one quart of milk, four ounces of butter, and two tablespoonfuls of
flour. Stir until the soup is thick, add a pinch of salt and of grated
nutmeg, and the whole peas, and serve very hot.
Put two large tablespoonfuls of fine yellow Indian-corn meal into one
quart of boiling milk. Stir continually for twenty minutes to prevent
burning, then add one teaspoonful of salt (or more to taste), and four to
six ounces of fresh butter. Serve with croûtons (fried bread).
Sorrel Soup.
Wash and dry two bunches of sorrel. Chop it fine, and cook with two
ounces of butter until it becomes a pulp. Stir in one spoonful of flour, salt
and pepper to taste, and a cupful of water. When it boils add two or more
yolks of eggs and a cupful of cream. Serve with croûtons (fried bread).
Boil two pounds of spinach, mince fine, and put it in a sauce-pan with
four ounces of melted butter. Stir well, add salt to taste, then take off the
fire and mix in two eggs, a little grated cheese, and a pinch of grated
nutmeg. Pour this purée into boiling broth, take it off the fire after a few
minutes, and cover with a salamander; this will coagulate the eggs and
turn the purée into a soft green paste. Serve very hot with croûtons (fried
bread).
Stew eight or ten tomatoes thoroughly, then rub them through a sieve,
and put them in a pot with one tablespoonful of soda. When the foaming
is over add two tablespoonfuls of butter (a little at a time), one
teaspoonful of salt, half a teaspoonful of pepper, and a pinch of cayenne.
Meanwhile heat one quart of milk in a Bain-marie for about ten minutes,
and add to the tomatoes (beating well together) just before serving.
Turnip Soup.
Parboil ten or twelve turnips cut into fine strips. Strain, cook them
over a slow fire in a stew-pan with a minced onion browned in three
ounces of butter, add some broth (or fish soup for maigre). Serve with
croûtons (fried bread), and one ounce grated Parmesan cheese.
Cut two potatoes and one onion in pieces. Fry the onion in two ounces
of butter till browned, then pour it over the potatoes in an earthen pot,
add two tablespoonfuls of rice, one sliced carrot, and one quart of water.
Boil for one hour, then pass through a sieve and put back in the pot.
Moisten two ounces of fine Indian-corn meal with a little cold milk, add
to the vegetables and then pour in half a pint of milk. Stir until it boils,
season with pepper and salt, and serve with croûtons (fried bread).
Wash, blanch, and chop up fine two pounds of spinach. Put it into an
earthen pot with fresh butter, and salt and pepper to taste. Add two or
three tablespoonfuls of flour and half a pint of milk, mixing continually.
Serve hot with croûtons (fried bread), as a garnish.
Wash half a peck of spinach in several waters to get the grit out, and
put it into a covered earthen pan on a brisk fire. Stir now and then to
prevent its burning, and after fifteen minutes put in one tablespoonful of
salt. Cook five minutes more, then drain, and when dry chop it up very
fine. Mix one and a half tablespoonfuls of fresh butter, and one of flour,
in an earthen pot, and when half-cooked add the spinach and a little salt
and pepper. Cook for five minutes, pour in half a cupful of good cream,
and cook five minutes more, stirring constantly to prevent burning. Serve
with croûtons (fried bread), or hard boiled eggs sliced.
Spinach Croquettes.
Take two pounds of boiled spinach, strain, and chop it up fine. Put it
into an earthen pan with four ounces of butter, some sweet marjoram
chopped up, allspice, sugar, and grated lemon peel. Mix well over the
fire, then put in one tumbler of milk, and when it boils add two beaten-up
eggs. When thick and cooled roll up into croquets, meanwhile make the
following batter: two handfuls of flour, one tablespoonful of good olive
oil, half a glass of white wine, and a little salt, well mixed together. Roll
the croquets in this and fry. Serve hot.
Clean and wash eight bunches of spinach, cook them in salted boiling
water, and then put them into cold. Dry well, chop up very fine, put them
into a sauce-pan and mix well with four ounces of butter, eight ounces of
fresh curds (out of which all the water has been pressed), two
tablespoonfuls of grated Parmesan cheese, and three yolks of eggs. When
cold make small balls or rolls of the spinach, flour them well, and throw
them into boiling water. As they rise to the surface take them out with a
strainer, pour melted butter over them, sprinkle with grated Parmesan
cheese, and serve at once.
Spinach Fried.
Put two or three bunches of spinach into an earthen pot with a finely
chopped up shallot, and two ounces of butter, and mix well. When
cooked, take off the fire, chop up very fine, add one egg, one ounce of
grated cheese, a pinch of allspice, and roll up into balls or croquets;
sprinkle with flour, and fry over a quick fire. Serve very hot garnished
with fried parsley. (N.B.—Any vegetable, cardoon, cauliflower, etc.,
which is left over, can be fried in this way.)
Boil a bunch of spinach and rub it through a sieve. Beat up two eggs,
season them with salt and pepper, and mix enough spinach with them to
make them green. Put a little oil into the frying-pan, and when well
heated pour a little of the egg in, turning the pan about so that the
pancake should be as thin as a piece of paper, and dry. Toss if necessary.
Take it out, repeat with the rest of the egg, then take the pancakes, place
them one on the top of the other, and cut them into pieces the width of a
finger and about two inches long. Fry them in butter and grate a little
Parmesan cheese over them. They make an effective garnish.
Spinach Soufflé.
Tomatoes Broiled.
Slice large ripe tomatoes (without peeling them), broil or toast them
until slightly browned. Place them on a hot dish and pour boiling melted
butter, mixed with a very little good wine vinegar, salt, pepper, and
mustard, over them.
Cut five or six tomatoes in half (do not peel them), put them in an
earthen pan with bits of butter, and sprinkle with salt and pepper. Bake
for about one hour, or until the tomatoes are soft. Meanwhile prepare
squares of buttered toast, place a half tomato on each square of toast,
pour sauce ‘alla Panna’ (see Sauces, p. 125) round them, and serve.
Scald, peel, and mash up eight or ten tomatoes, add one teaspoonful of
salt, and one saltspoonful of pepper. Put a layer of bread-crumbs into a
shallow baking-dish, lay the tomatoes on them, and sprinkle with one
tablespoonful of sugar, and a few drops of onion juice. Then cover the
tomatoes with a large cupful of bread crumbs moistened with one
tablespoonful of melted butter. Bake half an hour in a hot oven, and
serve in the baking-dish.
Scald and peel six or eight tomatoes, slice off their tops, and scoop out
a little of the inside. Drop a little oil into each tomato and a small pinch
of salt and pepper, replace their tops, sprinkle them with grated bread,
salt and pepper, place each on a slice of bread in a tinned dish, add a
little pure olive oil, and bake for twenty minutes.
Scald and peel six or eight tomatoes, take out their seeds, and place
them in a tinned dish. Meanwhile mix one tablespoonful of flour, one of
fresh butter, four or five fresh mushrooms, some parsley chopped up
with one shallot, a little salt and pepper, and some thick purée (or
conserve) of tomatoes in a sauce-pan, and stir well. Fill each tomato with
this, sprinkle them with grated bread, put four or five tablespoonfuls of
pure olive oil in the tin dish, and bake for ten minutes, then brown with a
salamander.
Tomatoes ‘Fritti.’
Cut six fine ripe tomatoes in half and put them in a shallow pan with
the peel downwards. Add four ounces of butter, sprinkle with pepper and
salt, and put them in the oven for ten minutes, then fry them slowly on
the fire (do not turn them). When cooked place them carefully on a hot
dish, put the pan on the fire again, and brown the butter, adding two
tablespoonfuls of flour, mix well, then add one pint of milk, and stir until
it boils. Season with salt and pepper, pour it over the tomatoes and serve
hot.
Cut four or five tomatoes in half without peeling them. Put them on
the gridiron, dust them with salt and pepper, and cook over a moderate
fire. Then place them on a hot dish and pour a white sauce over them.
Serve with croûtons (fried bread).
Tomatoes Iced.
Scald and peel small round tomatoes, ice them, and serve them whole
with sauce ‘Francese’ (see Sauces, p. 123) separate.
Wash half a pint of rice in several waters. Take two pounds of boiled
and strained tomatoes (or tomato conserve), season with a little salt and
allspice. Put alternate layers of tomato and of rice in a pie-dish, and
finish off with a layer of tomato covered with grated bread-crumbs
moistened with melted butter. Bake in a moderate oven for a good half-
hour, and serve in the pie-dish.
Peel and cut in slices six or more (according to the size of your dish)
ripe tomatoes, and lay them in a baking-dish with alternate layers of
bread-crumbs and bits of good butter. Season each layer of tomatoes with
sugar, pepper, and salt. The upper layer must be bread-crumbs moistened
with melted butter. Bake in a moderate oven for half an hour, and serve
in the baking-dish.
Tomato Pudding.
Tomato Purée.
Scald and peel about eighteen ounces of ripe tomatoes, and take out
the stem end. Cut them up and put them in an earthen pan with a little
salt, pepper, a bouquet, and one sliced onion. Stir over a moderate fire,
parboil, and then rub through a sieve. Make a roux with one ounce of
good butter and one tablespoonful of flour, cook for five minutes, then
pour the tomatoes into the roux, add two ounces of meat jelly, and reduce
for five minutes. Strain through a cullender and put into a Bain-marie
until wanted.
Tomatoes ‘Ripieni.’
Choose twelve large and smooth tomatoes, cut off the stem end and
take out the seeds. Put four ounces of grated bread, one quarter of an
onion minced, a little salt, and two ounces of butter into a frying-pan;
mix well and then fill the tomatoes with it. Put them in an earthen pan
and cook for half an hour over a hot fire, serve very hot.
Take the pulp of six tomatoes and put it in a sauce-pan with two
ounces of butter. Cook thoroughly, then strain through a sieve, add one
large cupful of consommé, and cook till reduced one quarter. Meanwhile