MCQ Coordination Compound

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Name.………………………………………………… Class…………… Date…………….. Marks……………………
Chapter: Coordination Compound
Q.1 A coordination complex’s core atom/ion is also known as ________
(a) Bronsted-Lowry acid (b) Lewis base (c) Lewis acid (d) Bronsted-Lowry base
Q.2 Determine the proper name for K2[PdCl4].
(a) Potassium tetrachlorinepalladium(II) (b) Potassium tetrachloridopalladate(II)Potassium

(c) Potassium tetrachloridopalladium(II) (d) tetrachlorinepalladate(II)
Q.3 The core atom of which of the following biologically significant coordination molecules is magnesium?
(a) Vitamin B12 (b) Haemoglobin (c) Chlorophyll (d) Carboxypeptidase-A
Q.4 IUPAC name of [Pt(NH3)3 Br (NO2) Cl] Cl is

(a) triamminechlorodibromidoplatinum (IV) chloride (b) triamminechloridobromidonitrochloride- platinum (IV) chloride
(c) triamminebromidochloridonitroplatinum (IV) chloride (d) triamminenitrochlorobromoplatinum (IV) chloride
Q.5 Primary and secondary valency of Pt in [Pt(en)2Cl2] are

(a) 4, 4 (b) 4, 6 (c) 6, 4 (d) 2, 6
Q.6 The complex ions [Co(NH3)5(NO2)]2+ and [Co(NH3)5 (ONO)]2+ are called
(a) Ionization isomers (b) Linkage isomers (c) Co-ordination isomers (d) Geometrical isomers
Q.7 Which of the following has square planar structure?

(a) [NiCl4]2- (b) [Ni(CO)4] (c) [Ni(CN)4]2- (d) None of these
Q.8 Mohr’s salt is

(a) Fe2(SO4)3.(NH4)2SO4 . 6H2O (b) FeSO4.(NH4)2SO4.6H2O (c) MgSO4 . 7H2O (d) FeSO4 . 7H2O
Q.9 EDTA is used for the estimation of

(b) Cl– and Br– ions
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(a) Na+ and K+ ions (c) Cu2+ and Cs+ ions (d) Ca2+ and Mg2+ ions
Q.10 The solution of the complex [Cu(NH3)4] SO4 in water will

(a) give the tests of Cu2+ ion (b) give the tests of NH3
2-
(c) give the tests of SO4 ions (d) not give the tests of any of the above
Q.11 How many donor atoms can EDTA4- ligand bind through?
(a) 2 (b) 4 (c) 6 (d) 8
Q.12 The SCN– ion is a unidentate ligand.

(a) True (b) False
Q.13 What is the coordination number of chromium in K3[Cr(C2O4)3]?

(a) 1 (b) 2 (c) 3 (d) 6
Q.14 Which of the following will not give test for Cl– with AgNO3(aq) at 25°C?
(a) COCl3.5NH3 (b) COCl3.6NH3 (c) COCl3.3NH3 (d) COCl3.4NH3
Q.15 Which of these statements about [Co(CN)6]3- is true?

(a) It has 4 unpaired electron, high spin (b) No unpaired electron, high spin
(c) No unpaired electron, low spin (d) 4 unpaired electron, low spin
Q.16 Facial and meridional isomerism will be shown by

(a) [Co(NH3)3Cl3] (b) [Co(NH3)4Cl2]Cl (c) [Co(en)3]Cl3 (d) [Co(NH3)5Cl]Cl2
Q.17 Which one has highest molar conductivity?

(a) [Pt(NH3)2 Cl2] (b) [CO(NH3)4 Cl2] Cl (c) K4[Fe(CN)6] (d) [Cr(H2O)6] Cl3
Q.18 Which one will show optical isomerism?

(a) [Co(NH3)3Cl3] (b) cis-[Co(en)2 Cl2] Cl (c) trans-[Co(en)2 Cl2] Cl (d) [Co(NH3)4 Cl2] Cl
Q.19 The pair having the same magnetic moment is (At No. Cr = 24, Mn = 25, Fe = 26, Co = 27)
(а) [Cr(H2O)6]2+ and [CoCl4]2- (b) [Cr(H2O)6]2+ and [Fe (H2O)6]2+
2+ 2+
(c) [Mn(H2O)6] and[Cr(H2O)6] (d) [COCl4]2- and [Fe(H2O)6]2+
Q. 20 Among the ligands NH3, en, CN and CO, the correct order of field strength is
(a) NH3 < en < CN– < CO (b) CN– < NH3 < CO < en
(c) en < CN–< NH3 < CO (d) CO < NH3 < en < CN–
Q.21 Which of the following is the most stable complex species? [NCERT Exemplar]
(a) [Fe(CO)5] (b) [Fe(CN)6]3- (c) [Fe(C2O4)3]3- (d) [Fe(H2O)6]3+
Q.22 Indicate the complex ion which shows geometrical isomerism.

(a) [Cr(H2O)4Cl2]+ (b) [Pt(NH3)3 Cl] (c) [Co(NH3)6]3+ (d) [Co(CN)5(NC)]3-
Q.23 The compounds [Co(SO4)(NH3)5]Br and [CO(SO4)(NH3)5]Cl represent

(a) linkage isomerism (b) ionisation isomerism (c) coordination isomerism (d) no isomerism
Q.24 Which of the following shall form an octahedral complex?

(a) d4 (low spin) (b) d8 (high spin) (c) d6 (low spin) (d) All of these

Q.25 The name of complex [Fe(CN)6]3- is
(a) Tricyanido ferrate (III) ion (b) Hexacyanido ferrate (III) ion
(c) Hexacyanido iron (III) (d) Hexacyanido ferrate (II) ion
Q.26 Atomic number of Mn, Fe and Co are 25, 26 and 27 respectively. Which of the following inner orbital
octahedral complex ions are diamagnetic?
(a) [CO(NH3)6]3+ (b) [Mn(CN)]3- (c) [Fe(CN)6]4- (d) [Fe(CN)6]3-
Q.27 If ∆o > P for d4, electronic configuration in terms of CFT is _________ .
Q.28 Write IUPAC name of K3[Fe(C2O4)3].............................................................................................................

Q.29The formula of potassium dicyanobis (oxalato) nickelate (II) is
(a) K4[Ni(CN)(Ox)2] (b) K3[Ni2 (CN)2 (Ox)2] (c) K4[Ni(CN)2(Ox)2] (d) K2[Ni(CN)2(Ox)2]
Q.30 K3[Al(C2O4)3] is called

(a) Potassium alumino oxalate (b) Potassium aluminium (III) trioxalate
(c) Potassium trioxalato aluminate (III) (d) Potassium tris (oxalato) aluminium.
Answer Key:
1. C 2. B 3. C 4. C 5. D 6. B 7.C 8.B 9.D 10.C 11.C 12. A 13. D 14.C 15. C

16.A 17. C 18.B 19. B 20. A 21. C 22.A 23. B 24. B 25.B 26.A 27. T2g4 eg0
28…………… 29.C 30.C

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THE GURU Institute,9785414777

Name.………………………………………………… Class…………… Date…………….. Marks……………………

Chapter: Coordination Compound

Q.1 A coordination complex’s core atom/ion is also known as ________

Q.2 Determine the proper name for K2[PdCl4].

(a) Potassium tetrachlorinepalladium(II) (b) Potassium tetrachloridopalladate(II)Potassium

(a) Vitamin B12 (b) Haemoglobin (c) Chlorophyll (d) Carboxypeptidase-A

Q.4 IUPAC name of [Pt(NH3)3 Br (NO2) Cl] Cl is

Q.5 Primary and secondary valency of Pt in [Pt(en)2Cl2] are

Q.7 Which of the following has square planar structure?

Q.8 Mohr’s salt is

Q.9 EDTA is used for the estimation of

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Q.10 The solution of the complex [Cu(NH3)4] SO4 in water will

Q.12 The SCN– ion is a unidentate ligand.

Q.13 What is the coordination number of chromium in K3[Cr(C2O4)3]?

Q.15 Which of these statements about [Co(CN)6]3- is true?

Q.16 Facial and meridional isomerism will be shown by

Q.17 Which one has highest molar conductivity?

Q.18 Which one will show optical isomerism?

Q.22 Indicate the complex ion which shows geometrical isomerism.

Q.23 The compounds [Co(SO4)(NH3)5]Br and [CO(SO4)(NH3)5]Cl represent

Q.24 Which of the following shall form an octahedral complex?

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Q.27 If ∆o > P for d4, electronic configuration in terms of CFT is _________ .

Q.28 Write IUPAC name of K3[Fe(C2O4)3].............................................................................................................

Q.30 K3[Al(C2O4)3] is called

1. C 2. B 3. C 4. C 5. D 6. B 7.C 8.B 9.D 10.C 11.C 12. A 13. D 14.C 15. C

28…………… 29.C 30.C

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