Wellington Catalogue

CERTIFICATE
OF REGISTRATION
This is to certify that
Wellington Laboratories Inc.

345 Southgate Drive, Guelph, Ontario N1G 3M5 Canada
operates a
Quality Management System

which complies with the requirements of
ISO 9001 :2015

for the following scope of certification
The Registration covers the Quality Management System as it applies to the design and
provision of reference standards and chemicals for use in environmental analysis and
toxicological research.
Certificate No.: CERT-0106807 Original Certification Date: December 30, 2004

File No.: 1039334 Certification Effective Date: November 4, 2020
Issue Date: November 3, 2020 Certificate Expiry Date: November 3, 2023
Heather Mahon
Global Head of Technical Services
SAi Global Assurance
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TRUSTED FOR QUALITY SINCE 1980
Wellington Laboratories Inc. (Wellington) celebrated its 40th anniversary in 2020. Without your continued support,
we couldn't have achieved this milestone and we want to thank you for your loyalty. We hope that you will continue
to trust us to provide you with high quality products, outstanding service, and efficient technical support for years to
come.
As you look through this catalogue, you will notice substantial overlap with our previous printing. We have retained
products that have demonstrated consistent sales, remained relevant for scientific research, and/or have been
mandated by regulations in various jurisdictions. If you are unable to find items that you ordered in the past, please
contact us or your local distributor (see page 10). Inventory of these withdrawn products might still be available and
we will do our best to accommodate your request.
Some of the new products in this catalogue include:

• Additional Alkyl-, Aryl- and Alkyl/Aryl Phosphates
• More Per- and Polyfluoroalkyl Substances (PFAS)
• Native and Mass-Labelled Organochlorine Pesticides (OCPs)
• New Native and Mass-Labelled Chlorinated Naphthalenes (PCNs)
We announce new products between catalogue printings so please visit our website (www.well-labs.com) to
subscribe to our newsletter, The Wellington Reporter, to receive new product announcements by e-mail.
Our Qyality Management System ( QMS) continues to be registered to ISO 9001 providing us with the structure and
procedures required to prepare accurate and precise products. Wellington is also accredited to ISO 17034 for
reference material production and to ISO/IEC 17025 for our testing activities. Current certificates for all
registrations and accreditations are available upon request.
Wellington employs a dynamic group of people who are all highly qualified and come from diverse, yet
complimentary backgrounds. Each one of them remain passionate about the science behind our products.
We trust that our products, service, and overall dedication will give you...an Added Measure of Confidence
President Analytical Support Reference Standards Division

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As Wellington marked our 40th anniversary, we reflected on the path that we've taken and looked forward to the
opportunities, risks, and road ahead. As part of our journey, we are training a new generation of chemists who are
dedicated to learning from those that have been with us from the beginning. The cover artwork recognises the
intersection of past knowledge with new ideas and skill at Wellington.
Wellington is proud to distribute our products globally, but loves to call the city of Guelph home. Pictures featured
in this catalogue showcase local scenery from Guelph, Ontario and the surrounding area.
TABLE OF CONTENTS
Introduction "Trusted for Quality Since 1980" 1
Table of Contents 2
"Support Solutions' s
General Information 6
Ordering, Terms, Warranty & Use 8
Distributors 10
PCDD/PCDF ANALYTICAL METHOD SOLUTIONS

EPA Method 1613 Standard Solutions ...............
............... 14
Alternative Method 16130 Standard Solutions
CS3WT
EPA Method 8280 Standard Solutions
...............
...............
16
17
18
EPA Method 8290 Standard Solutions ... ... ... ... ... 20
... ... ... ... ...
EPA Method 23 Standard Solutions
European Method EN-1948 Standard Solutions ...............
...............
22
24
HRGC/HRMS TCDD/TCDF Analysis Solutions
Capillary Column Performance Test Mixtures
Mass-Labelled Capillary Column Performance Test Mixtures
...............
...............
26
27
30
INDIVIDUAL PCDD & PCDF CONGENERS: NATIVE AND MASS-LABELLED
Native Polychlorinated Dibenzo-p-dioxins (PCDDs) 32
Native Polychlorinated Dibenzofurans (PCDFs) 33
Mass-Labelled Polychlorinated Dibenzo-p-dioxins 35
Mass-Labelled Polychlorinated Dibenzofurans 38
PCDDs and PCDFs: JIS METHODS & SPECIALTY SOLUTION/MIXTURES
DF-CVS-Al0 44
DF-CVS-Bl0 46
DF-CVS-ClO 48
DFP-CVS-BlO so
NK-CVS-J 52
DF-LCS-A 53
DF-LCS-B 54
DF-LCS-C 55
Mass-Labelled PCDDs & PCDFs: Solution/Mixtures 56
Mass-Labelled PCDDs/PCDFs/PCBs: Solution/Mixtures 61
Mass-Labelled PCDDs & PCBs: Solution/Mixtures 63
Native PCDDs & PCDFs: Solution/Mixtures 64
PCDDs & PCDFs: Solution/Mixtures 66
PCBs: ANALYTICAL METHOD SOLUTIONS
WP-CVS Standard Solutions 70
EPA Method 1668C Standard Solutions 72
EPA Method 1668 Standard Solutions 74
Environment Canada Method l/RM/31 Standard Solutions 76
P48-W-CVS 78
P48-M-CVS 79
WM48-CVS 80
P48-W-PAR 81
P48-M-PAR 81
Support Solutions for EN 1948-4:2010 82
PCBs: MASS-LABELLED CONGENERS
Mass-Labelled Polychlorinated Biphenyls 84
2
TABLEOF CONTENTS
PCBs:SPECIALTYSOLUTION/MIXTURES
PCB-CVS-H ... ... ... ... ... 90
PCB-CVS-AlO ... ... ... ... ... 92
PCB-CVS-BIO ... ... ... ... ... 94
Mass-Labelled PCBs: Solution/Mixtures ... ... ... ... ... 96
Native PCBs: Solution/Mixtures ... ... ... ... ... 98
BP-CP81 ... ... ... ... ... 98
BP-WD ... ... ...... ... 99
BP-MO ... ... ... ... ... 99
BP-MS ... ... ... ... ... 100
PCBs: Solution/Mixtures ... ... ... ... ... 101
Mass-Labelled PCDDs/PCDFs/PCBs: Solution/Mixtures ... ... ... ... ... 102
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BFR-CVS ...............104
BDE-CVS-F ............... 106
BDE-CVS-G ............... 108
Native Polybrominated Diphenyl Ethers (PBDEs) ...............110
PBDE Window Defining Solution/Mixture ...............112
Native PBDEs: Solution/Mixtures ...............112
Mass-Labelled Polybrominated Diphenyl Ethers (PBDEs) ...............114
Mass-Labelled PBDEs: Solution/Mixtures ............... 116
Polybrominated Diphenyl Ether Technical Mixtures ............... 117
Native Methoxy-Bromodiphenyl Ethers (MeO-BDEs) ...............118
Methoxy-Bromodiphenyl Ethers: Solution/Mixture ...............119
Mass-Labelled Methoxy-Bromodiphenyl Ethers ...............119
Mass-Labelled Hydroxy-Bromodiphenyl Ethers ...............119
Native Polybrominated Biphenyls (PBBs) ............... 120
Native PBBs: Solution/Mixture & Technical Mixtures ............... 121
Mass-Labelled Polybrominated Biphenyls ...............121
Mass-Labelled PBBs: Solution/Mixture ...............122
HALOGENATEDFLAMERETARDANTS& RELATEDCOMPOUNDS
Native Hexabromocyclododecanes (HBCDDs) ............... 126
Native HBCDD Enantiomers ............... 126
Mass-Labelled Hexabromocyclododecanes ...............127
Native Pentabromocyclododecene (PBCD) ...............127
Tetrabromobisphenol-A (TBBPA): Native and Mass-Labelled ...............127
Decabromodiphenylethane (DBDPE): Native and Mass-Labelled ...............128
1,2-Bis(2,4,6-tribromophenoxy)ethane (BTBPE): Native and Mass-Labelled ............... 128
Hexabromobenzene (HBBZ): Native and Mass-Labelled ............... 128
Pentabromobenzene (PBBZ): Native and Mass-Labelled ...............129
Native Pentabromoethylbenzene (PBEB) ...............129
Native Pentabromotoluene (PBT) ...............129
Native Tetrabromo-p-xylene (pTBX) ...............129
Native 1,2,S,6-Tetrabromocyclooctane (TBCO) ............... 129
Native Tetrabromoethylcyclohexane (TBECH) ............... 130
Native Octabromotrimethylphenylindane ( OBIND) ...............130
Bis(2-ethylhexyl) tetrabromophthalate (BEHTBP): Native and Mass-Labelled ...............131
2-Ethylhexyl 2,3,4,S-tetrabromobenzoate (EHTBB): Native and Mass-Labelled ...............131
Native Hexachlorocyclopentenyl-dibromocyclooctane (HCDBCO) ...............131
Native Tetrabromo-o-chlorotoluene (TBCT) ............... 131
Native Pentabromobenzyl acrylate (PBBA) ............... 132
Native 2,4,6-Tribromophenyl ethers (ATE, DPTE, & BATE) ...............132
Dechlorane Plus®(DP): Native and Mass-Labelled ...............132
Dechlorinated Dechlorane Plus® ...............132
Native Dechlorane Plus®Mono Adducts ...............133
Native Experimental Flame Retardants ............... 133
Native Tris ( 2,3-dibromopropyl) isocyanurate ( T23BPI C) ............... 134
2,3,4,S-Tetrabromobenzoic acid: Native and Mass-Labelled (TBBA) ...............134
Native Methyl-2,3,4,S-Tetrabromobenzoate (MeTBBA) ...............134
3
TABLEOF CONTENTS
Tetrabromophthalic anhydride: Native and Mass-Labelled (TBPAn) 134
Native Organophosphorus Compounds 135
Mass-Labelled Organophosphorus Com!'ounds 139
Brominated Dibenzo-p-dioxins (PBDDsJ: Native and Mass-Labelled 140
Native Brominated Dibenzofurans (PBDFs) 141
Bromo/Chloro Dibenzo-p-dioxins: Native and Mass-Labelled 141
Bromo/Chloro Dibenzofurans: Native and Mass-Labelled 142
PER-& POLYFLUOROALKYL
SUBSTANCES
{PFAS)
PFC-CVS-C 144
Native Linear Perfluoroalkanesulfonates: Individual Solutions & Mixture .............. . 146
Native Perfluoroethylcyclohexanesulfonate (PFECHS) .............. . 146
Native Chloro-Perfluoroalkanesulfonate .............. . 147
Native Branched Perfluoroalkanesulfonates .............. . 147
Mass-Labelled Perfluoroalkanesulfonates .............. . 147
Native Linear PerfluoroalkylcarboxylicAcids: Individual Solutions & Mixture .............. . 148
Native Branched PerfluoroalkylcarboxylicAcids .............. . 148
Mass-Labelled Perfluoroalkylcarboxylic Acids .............. . 149
Mixed Native PFAS: Solution/Mixtures .............. . 151
Mixed Mass-Labelled PFAS: Solution/Mixture .............. . 153
Mixed Native and Mass-Labelled PFAS: Solution/Mixture .............. . 154
EPA Method 537.1 Solutions/Mixtures .............. . 156
ISO 21675:2019 Solutions/Mixtures .............. . 158
EPA Method 533 Solutions/Mixtures .............. . 160
PFOS/PFOA Isomers .............. . 161
Perfluoroalkanesulfonamides (FASA): Native and Mass-Labelled .............. . 162
Native Perfluoroalkanesulfonamidoethanols (N-MeFASE and N-EtFASE) .............. . 162
Mass-Labelled Perfluoroalkanesulfonamidoethanols .............. . 163
Perfluorooctanesulfonamidoacetic Acids (FOSAA): Native and Mass-Labelled .............. . 163
Native Fluorotelomer Alcohols (X:2FTOH) .............. . 163
Mass-Labelled Fluorotelomer Alcohols .............. . 164
Native Fluorotelomer Carboxylic Acids (FTCA): Individual Solutions .............. . 164
Native Fluorotelomer Carboxylic Acids (FTCA): Solution/Mixture .............. . 164
Mass-Labelled Fluorotelomer Carboxylic Acids: Individual Solutions & Mixture .............. . 165
Native Fluorotelomer Unsaturated Carboxylic Acids (FTUCA) .............. . 166
Mass-Labelled Fluorotelomer Unsaturated Carboxylic Acids .............. . 166
Native Chloroperfluoroalkyl Ether Sulfonates ( Cl-PFESA) .............. . 166
Native Per- and Polyfluoroalkyl Ether Carboxylic Acids (PFECA) .............. . 166
Native Perfluoroalkyl Ether Sulfonates (PFESA) .............. . 167
Hexafluoropropylene Oxide Dimer Acid (HFPO-DA): Native and Mass-Labelled .............. . 167
Native and Mass-Labelled Fluorotelomer Sulfonates (X:2FTS) .............. . 167
Native PerfluoroalkylphosphonicAcids (PFAPA) .............. . 168
Native Sodium Perfluoroalkyl Phosphinates (X:XPFPi) .............. . 168
Polyfluorinated Phosphate Esters (PAP & diPAP): Native and Mass-Labelled .............. . 168
Native Polyfluorinated Phosphate Esters (SAmPAP) .............. . 169
Native Telomer Acrylates (X:2FTAcr) .............. . 170
Native Telomer Acetates (X:2FTOAc) .............. . 170
Native Cationic/Zwitterionic PFAS .............. . 171
ORGANOCHLORINE
PESTICIDES{OCPs)
Individual Native Organochlorine Pesticides 174
Native Organochlorine Pesticides Solutions/Mixtures 175
Individual Mass-Labelled Organochlorine Pesticides 176
Mass-Labelled Organochlorine Pesticides Solutions/Mixtures 177
ENVIRONMENTALREFERENCE
MATERIALS{ERMs)
WMF-02: Reference Fish Tissue for Organic Contaminant Analysis 180
WMF-03: Reference Fish Tissue for Organic Contaminant Analysis 182
WMF-EX: Reference Fish Tissue Extract for Organic Contaminant Analysis 184
WMS-01: Reference Lake Sediment for Organic Contaminant Analysis 186
CARP-2: Reference Fish Tissue for Organic Contaminant Analysis 187
4
TABLEOF CONTENTS
ADDITIONAL PRODUCTS
PAH-CVS-B ............... 190
Method 429: HRGC/LRMS Calibration Solutions for PAHs ............... 192
EPA & EU PAH Solution/Mixtures ...............194
Chlorinated Biphenylols (HO-PCBs): Native and Mass-Labelled ...............196
Mass-Labelled Chlorinated Biphenxiols: Solution/Mixture ...............197
Native Methoxy-Chlorobiphenyls (MeO-PCBs) ...............198
Native Methoxy-Chlorobiphenyls: Solution/Mixtures ............... 199
Mass-Labelled Methoxy-Chlorobiphenyls ............... 200
Mass-Labelled Methoxy-Chlorobiphenyls: Solution/Mixture ...............201
Chlorinated Biphenylenes (PCBPs): Native and Mass-Labelled ...............201
Triclocarban (TCC): Native and Mass-Labelled ............... 202
Triclosan and Methyl Triclosan: Native and Mass-Labelled ...............202
Chlorinated Derivatives ofTriclosan and Methyl Triclosan ...............203
Native Chloroxanthene ...............203
Tris( 4-chlorophenyl)methane: Native and Mass-Labelled ...............203
Tris( 4-chlorophenyl)methanol: Native and Mass-Labelled ............... 203
PCN-CVS-A ............... 204
Native Polychlorinated Naphthalenes: Solution/Mixtures ...............206
Native Polychlorinated Naphthalenes (PCNs) ...............208
Mass-Labelled Polychlorinated Naphthalenes ...............210
Native Polychlorinated Diphenyl Ethers (PCDEs) ...............212
Mass-Labelled Polychlorinated Diphenyl Ethers ............... 212
Native Chlorobenzenes: Solution/Mixture ............... 213
Mass-Labelled Chlorobenzenes: Individual Solutions and Mixture ...............213
Native and Mass-Labelled Chlorophenols: Solution/Mixtures ...............214
Mass-Labelled Chlorophenols: Individual Solutions ...............215
Melamine & Cyanuric Acid: Native and Mass-Labelled ...............215
Bisphenol A: Native and Mass-Labelled ............... 216
Native Bisphenol Analogues ............... 216
Tetrachlorodibenzothiophenes: Native and Mass-Labelled ...............217
Native Chlorinated, Brominated, and Bromo/Chloro Carbazoles ...............217
Native Halogenated Carbazoles: Solution/Mixture ...............218
Mass-Labelled Chlorinated Carbazoles ...............218
APPENDIX
Guidelines for the Use and Handling ofWellington Products .............. . 222
General Structure and Numbering System of Selected Aromatic Hydrocarbons .............. . 224
Number of Possible Isomers for Selected Halogenated Aromatic Compounds .............. . 225
Molecular Weights for Selected Chlorinated and BrominatedAromatic Compounds .............. . 225
Exact Mass & Relative Ion Abundance of Selected Chlorinated Aromatic .............. . 226
Hydrocarbons
Molecular Ion Clusters for Chlorinated Aromatic Hydrocarbons 228
Molecular Ion Clusters for Brominated Aromatic Hydrocarbons 229
Exact Mass & Relative Ion Abundance of Selected Brominated Aromatic 230
Hydrocarbons
Systematic Numbering of Chlorinated Dibenzo-p-dioxins 231
Systematic Numbering of Chlorinated Dibenzofurans 233
Systematic Numbering of Chlorinated Biphenyls 238
Systematic Numbering of Chlorinated Naphthalenes 244
Reference Methods 247
SUPPORT SOLUTIONS
Throughout this catalogue, among the products listed are sets of Calibration and Y'erification Solutions
designed for use with a variety of GC/MS applications. These solution sets are denoted by the
incorporation of the code CVS into their catalogue numbers, for example EPA-1613CVS or DFP-CVS-BlO.
These calibration solutions are designed to be used with their corresponding "support solutions".
These are the solution/mixtures of native or mass-labelled compounds required for sample processing and
method validation as determined by the appropriate method.
5
GENERAL INFORMATION
WELLINGTON
LABORATORIES
INC.
Wellington Laboratories Inc. (Wellington) has been a reliable and respected supplier of reference
standards for over 40 years. Moreover, the company has developed a global reputation and a loyal
clientele.
This has been achieved due to:

• The superior quality of our products, which includes the accompanying documentation.
• Our consistent and timely service to all our clients.
• The technical support, pre- and post-delivery, that we gladly provide.
• Our overall dedication to customer service and continual improvement.
Considering that the products we provide are necessary to ensure the accuracy of environmental, trace
contaminant analyses, and for toxicological research, the qualifications and performance of our staff is
critical.
Wellington has put together a highly qualified team of synthetic chemists, analytical chemists, product
development chemists and administrative personnel. They are all dedicated to preparing high quality
products, supporting them with science, and delivering them to our clients.
THISCATALOGUE/NEWPRODUCTS
As in our original catalogue, Wellington continues to offer an extensive collection of native and mass-
labelled chlorinated dibenzo-p-dio:xins (PCDDs), dibenzofurans (PCDFs) and biphenyls (PCBs).
This includes ready-to-use calibration solutions and support solutions for:
• PCDD/PCDF methods, such as EPA Method 1613B,JIS Methods K 0311 and K 0312,
and European Standard Method 1948-4.
• PCB methods, such as EPA Method 1668C and Environment Canada Method
1/RM/31.
As new products or groups of products were developed and offered, additional sections were added to
our catalogue, including those presenting:
• Polybrominated Diphenyl Ethers (PBDEs) and Polybrominated Biphenyls (PBBs).
• Other Halogenated Flame Retardants ( e.g. HBCDDs) and related compounds
(e.g. organo phosphates).
• Per- and Polyfluoroalkyl substances (PFAS) .
• Environmental Reference Materials (ERMs) .
• Additional products including polyaromatic hydrocarbons (P AHs ), polychlorinated
naphthalenes (PCNs), and other reference standards.
In this new catalogue we have added many new native and mass-labelled PFAS, expanded our offerings of
PCNs, and introduced a separate section for organochlorine pesticides ( OCPs), including newly
prepared native and mass-labelled OCPs.
Please refer to the Table of Contents to review our updated product line and continue to visit our website
for new product announcements.
6
GENERAL INFORMATION
SYNTHESIS
The chemical standards offered by Wellington are prepared using unambiguous synthetic routes and
purified using a battery of methods. All products are purified to a minimum of 98% chemical purity and
the isotopic purity of 13C-labelled products is required to be >99%. The structure of all of our compounds
is unequivocally confirmed using a variety of techniques including, as appropriate, NMR ( 400 or 600
MHz), HRGC with LRMS and/or HRMS, UPLC-MS/MS, and SFC/UV/MS/MS.
ACCURACY/TRACEABILITY
All of the solutions listed in this catalogue are prepared in our laboratories using:
• Microbalances calibrated regularly by an external, ISO /IEC 17025 accredited laboratory
• External weights traceable to an ISO /IEC 17025 accredited laboratory to verify
microbalance calibration
• Volumetric glassware of Class A tolerance calibrated and traceable to an
ISO /IEC 17025 accredited laboratory
• Distilled-in-glass or HPLC grade solvents
• Replicate solutions to ensure accuracy and confirm homogeneity
When possible, these solutions are compared to standard reference materials or certified standards from
another source. The expanded maximum percent relative uncertainty of solution concentrations is ± 5%,
unless stated otherwise in this catalogue.
VALIDATION/CERTIFICATION
Wellington was the first supplier of PCDDs, PCDFs and WHO PCBs to validate their solution/mixtures
using "truly blind" interlaboratory studies. Since 1991, solutions of our PCDD, PCDF and PCB standards
have been submitted to more than 30 international round-robins, resulting in over 2000 independent sets
of HRGC/HRMS data.
In addition, over the past several years, Wellington has also submitted standards for 18 interlaboratory
studies on PBDEs and 23 studies involving PFAS.
Summaries of all of these interlaboratory studies are available on request. However, in all the studies,
averages of the data received for all compounds were well within ± 10% of the design values.
ANALYSIS/DOCUMENTATION
Each of our products comes with a detailed Certificate of Analysis ( CofA) which includes data which the
end user should be able to replicate using equivalent instrumentation and conditions. The CofA includes
HRGC/LRMS and/or HRGC/HRMS data depending upon the intended use of the product. Those
compounds that are not amenable to GC analysis come with LC/MS data.
Additionally, all of our mass-labelled products come with data that clearly shows their isotopic purity. All
calibration sets include RRF summaries showing the required linearity. Safety Data Sheets and handling
guidelines are available for all products.
OTHER PRODUCTS/CUSTOM REQUESTS
For products not listed in this catalogue, please visit our website for updates or contact us at
info@well-labs.com. Custom solution preparation and synthetic services are also available.
7
ORDERING, TERMS, WARRANTY & USE
ORDERING INFORMATION
To place an order, please contact the distributor that serves your country. Distributors are listed on
pages 10 and 11, as well as on our website.
For Canada, and for other countries where we do not have a distributor, please contact:

345 Southgate Drive
Guelph, Ontario CANADA NlG 3M5
Telephone: (519) 822-2436

Toll-free: (800) 578-6985
FAX: (519) 822-2849
E-mail: orders@well-labs.com
Website: www.well-labs.com
When ordering, please provide as much information as possible, including:
• Detailed shipping address and billing address

• Purchase order number, if known
• Catalogue number and description of product
• Quantity and unit size
TERMS & CONDITIONS OF SALE

Prices: A price list for the products listed in this catalogue is availablefrom your local distributor. Prices
are subject to change without notice.
Payment: Payment terms are net 30 days from date of invoice. Past due invoices will be subject to a 2%
monthly finance charge.
Note: We may also accept credit card payments.

Shipping e!t Handling: All shipments will be arranged using a courier licensed to carry dangerous goods
in excepted quantities.
Returns: Please contact Wellington Laboratories Inc. or your local distributor for a return authorization
number. No credit or exchange will be approved after 30 days from shipment and without prior
authorization.
LIMITED WARRANTY
At the time of shipment, all products are warranted to be free of defects in material and workmanship
and to conform to the accompanying technical and purity specifications. Wellington Laboratories Inc.
makes no other warranty, expressed or implied, pertaining to the suitability of the product for any
specific application. In case of breach of this warranty, the entire liability of Wellington Laboratories
Inc. will be limited to the invoice price of the goods. In no case will Wellington Laboratories Inc. be
liable for any special, incidental or consequential damages resulting from the use of its products.
8
ORDERING, TERMS, WARRANTY & USE
INTENDED USE
The products prepared by Wellington Laboratories Inc. are for laboratory use only. They are not for
use in humans.
These chemicals should only be used by qualified personnel who are familiar with their potential
hazards and are trained in their handling. With all of our products, due care should be exercised to
prevent human contact and ingestion.
The absence of a toxicity warning on any of our products must not be interpreted as an indication that
there is no possible health hazard.
Safety Data Sheets ( SDSs) are supplied upon request.
PACKAGING
For the safety and convenience of our clients, the solutions provided by Wellington Laboratories Inc.
are packaged in clear or amber glass flame-sealed ampoules. Crystalline materials are packaged in glass
vials with teflon-lined screw caps.
The solution volumes stated in this catalogue are the minimum volumes which will be delivered and
should be considered as approximate. To retain the accuracy of the solutions, dilutions should be
made using volumetric glassware.
END USE ONLY/NOT FOR RESALE

The reference standards and materials supplied by Wellington Laboratories Inc. are for end use only by
the original purchaser and are not to be resold without written authorization from Wellington
Laboratories Inc.
9
DISTRIBUTORS
To determinewhichdistributorservesyour country,pleasevisit ourwebsite at
www.well-labs.comand followthe distributorlinkunderorderinfo.
DISTRIBUTOR HEADOFFICE CONTACTINFORMATION
WELLINGTON LABORATORIES JAPAN 1-22-12 Fujimidai

JAPAN INC. Nerima-ku, Tokyo,Japan 177-0034
Phone: +(81) 3-5934-4184
Fax: +(81) 3-5241-4222
Website: www.well-labs.co.jp
Email: info@well-labs.co.jp
KANTO CHEMICAL CO., INC. JAPAN East Muromachi Mitsui BLDG, 2-1,
Nihonbashi Muromachi 2-chome,
Chuo-ku, Tokyo,Japan 103-0022
Phone: +(81) 3-6214-1090
Fax: +(81) 3-3241-1047
Website: www.kanto.co.jp
Email: reag-info@gms.kanto.co.jp
WELLINGTON UNITED STATES 7208 West 80th Street, Suite 206

LABORATORIES LLC. OFAMERICA Overland Park, KS, USA 66204
Phone: (913) 722-4919
Toll Free: (877) 809-7039
Fax: (913) 722-4669
Website: www.well-labs.com
Email: wellington@swbell.net
GREYHOUND CHROMATOGRAPHY ENGLAND 6 Kelvin Park, Birkenhead,

& ALLIED CHEMICALS Merseyside, England CH411LT
Phone: ( +44)-0-151-649-4000
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14167 Berlin Germany
Phone: +49.(0)30.629.01.89.0
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10
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H your countryis not servedby an officialdistributor,please contact
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DISTRIBUTOR HEADOFFICE CONTACTINFORMATION
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11
PCDD/PCDF ANALYTICAL
METHOD SOLUTIONS
Complete sets of calibration and support solutions are offered for the following methods:
U.S. EPA Method 1613B

U.S. EPA Method 8280
U.S. EPA Method 8290
U.S. EPA Method 23
European Standard Method EN 1948-4
HRGC/HRMS TCDD and TCDF Analysis Solutions
Also included in this section are the following solution/mixtures of PCDDand PCDFcongeners.
These are used to test and confirm the resolution of the HRGCcolumn being used and to set
retention time windows for the PCDDand PCDFcongener groups:
CS3WT: EPA-1613CS3 calibration solution combined with PCDD/PCDFwindow

defining congeners and 2,3,7,8-TCDD resolution testing isomers.
SCWDS: PCDD/PCDFwindow defining congener mix.
STCDD: 2,3,7,8-TCDD resolution test mixture.
225TCDF: 2,3,7,8-TCDF resolution test mixture.
TDTFWD: Combined PCDD/PCDFwindow defining and resolution testing mixture
for 3 HRGC columns of varying polarity.
In this edition. we have added solution/mixtures of 13C-labelled. window-defining PCDDs

(MDSCWDS) and PCDFs(MFSCWDS). These can be added to samples prior to extraction, or to
extracts prior to analysis to confirm that the congener group HRGCwindows have not shifted
significantly during the analysis. Moreover, these solutions can also be used as injection or
sampling standards.
EPA METHOD 1613 STANDARD SOLUTIONS
Catalogue Number Product (nonane solution) Qty/Cone

EPA·1613CVS EPA Method 1613 1 kit
Calibration and Verification Solutions CS1-CS5 (5 ampoules)
EPA·1613CSL* CSL Extended Calibration/Low Level 500 µL
EPA-1613CS0.5* CS0.5 500 µL
EPA-1613CS1 CS1 500 µL
EPA·1613CS2 CS2 500 µL
EPA-1613CS3 CS3 Calibration Verification 1.0 ml
NOTE: 200 µL AMPOULES OF THE CALIBRATION SOLUTIONS ARE ALSO AVAILABLE. PLEASE CONTACT WELLINGTON
OR YOUR LOCAL DISTRIBUTOR FOR PRICING INFORMATION.
1613CSL 1613CS0.5 1613CS1 1613CS2 1613CS3 1613CS4 1613CS5

NATIVE PCDDs & PCDFs {ng/mL) {ng/mL) {ng/mL) {ng/mL) {ng/mL) {ng/mL) {ng/mL)
2,3,7,8-Tetrachlorodibenzo-p-dioxin 0.100 0.250 0.500 2.00 10.0 40.0 200
1,2,3,7,8-Pentachlorodibenzo-p-dioxin 0.500 1.25 2.50 10.0 50.0 200 1000
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 0.500 1.25 2.50 10.0 50.0 200 1000
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 0.500 1.25 2.50 10.0 50.0 200 1000
Octachlorodibenzo-p-dioxin 1.00 2.50 5.00 20.0 100 400 2000
2,3,7,8-Tetrachlorodibenzofuran 0.100 0.250 0.500 2.00 10.0 40.0 200

1,2,3,7,8-Pentachlorodibenzofuran 0.500 1.25 2.50 10.0 50.0 200 1000
1,2,3,4,7,8-Hexachlorodibenzofuran 0.500 1.25 2.50 10.0 50.0 200 1000
1,2,3,4,6,7,8-Heptachlorodibenzofuran 0.500 1.25 2.50 10.0 50.0 200 1000
Octachlorodibenzofuran 1.00 2.50 5.00 20.0 100 400 2000
MASS-LABELLED PCDDs & PCDFs

2,3,7,8-Tetrachloro("C 12)dibenzo-p-dioxin 100 100 100 100 100 100 100
1,2,3,7,8-Pentachloro("C,,)dibenzo-p-dioxin 100 100 100 100 100 100 100
1,2,3,4,7,8-Hexachloro("C,)dibenzo-p-dioxin 100 100 100 100 100 100 100
1,2,3,6,7,8-Hexachloro("C,)dibenzo-p-dioxin 100 100 100 100 100 100 100
1,2,3,4,6,7,8-Heptachloro("C 12)dibenzo-p-dioxin 100 100 100 100 100 100 100
Octachloro(''C,)dibenzo-p-dioxin 200 200 200 200 200 200 200
2,3,7,8-Tetrachloro("C,,)dibenzofuran 100 100 100 100 100 100 100

1,2,3,7,8-Pentachloro("C,,)dibenzofuran 100 100 100 100 100 100 100
2,3,4,7,8-Pentachloro(''C,,)dibenzofuran 100 100 100 100 100 100 100
1,2,3,4,7,8-Hexachloro("C,)dibenzofuran 100 100 100 100 100 100 100
1,2,3,4,6,7,8-Heptachloro("C,,)dibenzofuran 100 100 100 100 100 100 100
1,2,3,4,7,8,9-Heptachloro("C,)dibenzofuran 100 100 100 100 100 100 100
CLEANUP STANDARD
2,3,7,8-("Cl4)Tetrachlorodibenzo-p-dioxin 0.100 0.250 0.500 2.00 10.0 40.0 200
INTERNAL STANDARDS
1,2,3,4-Tetrachloro("C,,)dibenzo-p-dioxin 100 100 100 100 100 100 100
1,2,3,7,8,9-Hexachloro("C,,)dibenzo-p-dioxin 100 100 100 100 100 100 100
* EPA-1613CSL and EPA-1613CS0.5 are not included in the EPA-1613CVS kit and must be ordered separately.
14

EPA·1613LCS* Labelled Compound Stock Solution 1.2 ml
EPA-1613CSS* Cleanup Standard Spiking Solution 1.2 ml
EPA-1613I55 Internal Standard Spiking Solution 1.2 ml
EPA-1613PAR* Precision and Recovery Stock Solution 1.2 ml
EPA-1613STOCK EPA Method 1613 Native Stock Solution 1.2 ml
1613LCS 1613CSS 1613155 1613PAR 1613STOCK

NATIVE PCDDs & PCDFs {ng/mL) {ng/mL) {ng/mL) {ng/mL) {ng/mL)
2,3,7,8-Tetrachlorodibenzo-p-dioxin 40.0 400
1,2,3,7,8-Pentachlorodibenzo-p-dioxin 200 2000
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 200 2000
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 200 2000
Octachlorodibenzo-p-dioxin 400 4000
2,3,7,8-Tetrachlorodibenzofuran 40.0 400

1,2,3,7,8-Pentachlorodibenzofuran 200 2000
2,3,4,7,8-Pentachlorodibenzofuran 200 2000
1,2,3,4,7,8-Hexachlorodibenzofuran 200 2000
1,2,3,4,6,7,8-Heptachlorodibenzofuran 200 2000
1,2,3,4,7,8,9-Heptachlorodibenzofuran 200 2000
Octachlorodibenzofuran 400 4000

2,3,7,8-Tetrachloro("C,,)dibenzo-p-dioxin 100
1,2,3,7,8-Pentachloro("C,,)dibenzo-p-dioxin 100
1,2,3,4,7,8-Hexachloro("C,)dibenzo-p-dioxin 100
1,2,3,4,6,7,8-Heptachloro("C,,)dibenzo-p-dioxin 100
Octachloro(''C,)dibenzo-p-dioxin 200
2,3,7,8-Tetrachloro("C,,)dibenzofuran 100
1,2,3,7,8-Pentachloro("C,,)dibenzofuran 100
2,3,4,7,8-Pentachloro(''C,,)dibenzofuran 100
1,2,3,4,7,8-Hexachloro("C,)dibenzofuran 100
1,2,3,4,6,7,8-Heptachloro("C,,)dibenzofuran 100
1,2,3,4,7,8,9-Heptachloro("C,)dibenzofuran 100
CLEANUP STANDARD
2,3,7,8-("Cl4)Tetrachlorodibenzo-p-dioxin 40.0
INTERNAL STANDARDS
1,2,3,4-Tetrachloro("C,,)dibenzo-p-dioxin 200
1,2,3,7,8,9-Hexachloro("C,,)dibenzo-p-dioxin 200
* Working solutions are prepared by diluting EPA-1613LCS (in acetone), EPA-1613CSS(in nonane) and
EPA-1613PAR (in acetone) 1:50 (v/v)
15
ALTERNATIVE METHOD 16130 STANDARD SOLUTIONS

16130CV5 Alternative Method 16130 1 kit
16130C5L* CSL Extended Calibration/Low Level 500 µL
16130(505* CS0.5 500 µL
16130(51 CS1 500 µL
16130(52 CS2 500 µL
16130(53 CS3 Calibration Verification 1.0 ml
16130(54 CS4 500 µL
16130(55 CS5 500 µL
*FOR SUPPORTSOLUTIONS, see EPA-1613LCS, EPA-1613CSS, EPA-16131SS, EPA-1613PAR, and EPA-1613STOCK.
16130CSL 16130CS05 16130CS1 16130CS2 16130CS3 16130CS4 16130CS5

NATIVE PCDDs & PCDFs {ng/mL) {ng/mL) {ng/mL) {ng/mL) {ng/mL) {ng/mL) {ng/mL)
2,3,7,8-Tetrachlorodibenzo-p-dioxin 0.0100 0.0250 0.0500 0.200 1.00 4.00 20.0
1,2,3,7,8-Pentachlorodibenzo-p-dioxin 0.0500 0.125 0.250 1.00 5.00 20.0 100
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 0.0500 0.125 0.250 1.00 5.00 20.0 100
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 0.0500 0.125 0.250 1.00 5.00 20.0 100
Octachlorodibenzo-p-dioxin 0.100 0.250 0.500 2.00 10.0 40.0 200
2,3,7,8-Tetrachlorodibenzofuran 0.0100 0.0250 0.0500 0.200 1.00 4.00 20.0

1,2,3,7,8-Pentachlorodibenzofuran 0.0500 0.125 0.250 1.00 5.00 20.0 100
2,3,4,7,8-Pentachlorodibenzofuran 0.0500 0.125 0.250 1.00 5.00 20.0 100
1,2,3,4,7,8-Hexachlorodibenzofuran 0.0500 0.125 0.250 1.00 5.00 20.0 100
1,2,3,4,6,7,8-Heptachlorodibenzofuran 0.0500 0.125 0.250 1.00 5.00 20.0 100
1,2,3,4,7,8,9-Heptachlorodibenzofuran 0.0500 0.125 0.250 1.00 5.00 20.0 100
Octachlorodibenzofuran 0.100 0.250 0.500 2.00 10.0 40.0 200

2,3,7,8-Tetrachloro("C 12)dibenzo-p-dioxin 10.0 10.0 10.0 10.0 10.0 10.0 10.0
1,2,3,7,8-Pentachloro("C 12)dibenzo-p-dioxin 10.0 10.0 10.0 10.0 10.0 10.0 10.0
1,2,3,4,7,8-Hexachloro("C,)dibenzo-p-dioxin 10.0 10.0 10.0 10.0 10.0 10.0 10.0
1,2,3,4,6,7,8-Heptachloro("C 12)dibenzo-p-dioxin 10.0 10.0 10.0 10.0 10.0 10.0 10.0
Octachloro(''C,)dibenzo-p-dioxin 20.0 20.0 20.0 20.0 20.0 20.0 20.0
2,3,7,8-Tetrachloro("C 12)dibenzofuran 10.0 10.0 10.0 10.0 10.0 10.0 10.0

1,2,3,7,8-Pentachloro("C 12)dibenzofuran 10.0 10.0 10.0 10.0 10.0 10.0 10.0
2,3,4,7,8-Pentachloro("C 12)dibenzofuran 10.0 10.0 10.0 10.0 10.0 10.0 10.0
1,2,3,4,7,8-Hexachloro("C,)dibenzofuran 10.0 10.0 10.0 10.0 10.0 10.0 10.0
1,2,3,4,6,7,8-Heptachloro("C 12)dibenzofuran 10.0 10.0 10.0 10.0 10.0 10.0 10.0
1,2,3,4,7,8,9-Heptachloro("C,)dibenzofuran 10.0 10.0 10.0 10.0 10.0 10.0 10.0
CLEANUP STANDARD
2,3,7,8-("Cl4)Tetrachlorodibenzo-p-dioxin 0.0100 0.0250 0.0500 0.200 1.00 4.00 20.0
INTERNAL STANDARDS
1,2,3,4-Tetrachloro("C,,)dibenzo-p-dioxin 10.0 10.0 10.0 10.0 10.0 10.0 10.0
1,2,3,7,8,9-Hexachloro("C,,)dibenzo-p-dioxin 10.0 10.0 10.0 10.0 10.0 10.0 10.0
* 16130CSL and 16130CS05 are not included in the 16130CVS kit and must be ordered separately.
16
CS3WT
This solution allows the HRGC/HRMSoperator, with one injection, to:
• Set, or confirm, PCDDand PCDFcongener group windows
• Test, or confirm, 2,3,7,8-TCDD resolution
• Verify the calibration

CS3WT EPA Method 1613; Calibration and Verification 500 µL
Solution (CS3)combined with Window Defining
and 2,3,7,8-TCDDResolution Testing Congeners
QUANTITATIVE ANALYTES (ng/mL) SEMI-QUANTITATIVE ANALYTES (ng/mL)

NATIVE PCDDs & PCDFs WINDOW DEFINERS*
2,3,7,8-Tetrachlorodibenzo-p-d ioxi n 10.0 1,3,6,8-Tetrachlorodibenzo-p-d ioxi n 10.0
1,2,3,7,8-Pentachlorodibenzo-p-dioxin 50.0 1,2,8,9-Tetrachlorodibenzo-p-d ioxi n 10.0
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 50.0 1,2,4,7,9-Pentachlo rod i benzo-p-dioxi n 50.0
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin 50.0 1,2,3,8,9-Pentachlo rod i benzo-p-dioxi n 50.0
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin 50.0 1,2,4,6,7,9-Hexachlorodibenzo-p-dioxin 50.0
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin (WD) 50.0 1,2,3,4,6,7,9-Heptach lorodibenzo-p-d ioxi n 50.0
Octachlorodibenzo-p-dioxin 100
1,3,6,8-Tetrachlorodibenzofuran 10.0
2,3,7,8-Tetrachlorodibenzofuran 10.0 1,2,8,9-Tetrachlorodibenzofuran 10.0
1,2,3,7,8-Pentachlo rod i benzofu ran 50.0 1,3,4,6,8-Pentachlorodibenzofuran 50.0
2,3,4,7,8-Pentachlo rod i benzofu ran 50.0 1,2,3,8,9-Pentachlorodibenzofuran 50.0
1,2,3,4,7,8-Hexachlorodibenzofuran 50.0 1,2,3,4,6,8-Hexachlorodibenzofuran 50.0
1,2,3,6,7,8-Hexachlorodibenzofuran 50.0
1,2,3,7,8,9-Hexachlorodibenzofuran 50.0 2,3,7,8-TCDD RESOLUTION TESTING ISOMERS
2,3,4,6,7,8-Hexachlo rod i benzofura n 50.0 1,2,3,4-Tetrachlorodibenzo-p-dioxin 5.00
1,2,3,4,6,7,8-Heptach lorodibenzofu ran (WD) 50.0 1,2,3,7/1,2,3,8-Tetrachlorodibenzo-p-dioxin mix 5.00
1,2,3,4,7,8,9-Heptachlorodibenzofuran (WD) 50.0 1,2,3,9-Tetrachlorodibenzo-p-dioxin 10.0
Octachlorodibenzofuran 100

2,3,7,8-Tetrachloro("C,,)d i benzo-p-dioxi n 100
1,2,3,7,8-Pentachloro("C,,)dibenzo-p-dioxin 100
1,2,3,4,6,7,8-Heptachloro("C,,)dibenzo-p-dioxin 100
Octachloro("C,,)dibenzo-p-dioxin 200
2,3,7,8-Tetrachloro("C 12)d i benzofu ran 100

2,3,4,7,8-Pentachloro("C 12)d i benzofura n 100
1,2,3,4,7,8-Hexachloro("C,,)dibenzofuran 100
1,2,3,4,7,8,9-Heptachloro("C 12)dibenzofuran 100
CLEANUP STANDARD
2,3,7,8-("Cl4)Tetrachlo rod i benzo-p-dioxi n 10.0
INTERNAL STANDARDS
1,2,3,4-Tetrachloro("C,,)d i benzo-p-dioxi n 100
(WD) - Window Definer

* 1,2,3,4,6,7-Hexachlorodibenzo-p-dioxin (last eluting HxCDD) was not included as it co-elutes with 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin.
Use 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin and 1,2,3,4,6,7,9-Heptachlorodibenzo-p-dioxin to approximate the end of the HxCDD window.
* 1,2,3,4,8,9-Hexachlorodibenzofuran (last eluting HxCDF)was not included as it can interfere with 1,2,3,7,8,9-Hexachlorodibenzofuran. Use
1,2,3,4,6,7,8-Heptachlorodibenzofuran to approximate the end of the HxCDFwindow.
17

EPA-8280CVS EPA Method 8280 1 kit
Calibration and Verification Solutions CC1-CC5 (5 ampoules)
EPA-8280CC1 cc, 500 µL
EPA-8280CC2 CC2 500 µL
EPA-8280CC3 CC3 Calibration Verification 1.0 ml
8280CC1 8280CC2 8280CC3 8280CC4 8280CC5

NATIVE PCDDs & PCDFs (ng/µL) (ng/µL) (ng/µL) (ng/µL) (ng/µL)
2,3,7,8-Tetrach lorodibenzo-p-d ioxi n 0.100 0.250 0.500 1.00 2.00
1,2,3,7,8-Pentachlorodibenzo-p-dioxin 0.100 0.250 0.500 1.00 2.00
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 1.25
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin 0.250 0.625 1.25 2.50 5.00
1,2,3,4,6,7,8-Heptach lorodibenzo-p-d ioxi n 0.250 0.625 1.25 2.50 5.00
Octachlorodibenzo-p-dioxin 0.500 1.25 2.50 5.00 10.0
2,3,7,8-Tetrach lorodibenzofuran 0.100 0.250 0.500 1.00 2.00

1,2,3,7,8-Pentachlorodibenzofuran 0.100 0.250 0.500 1.00 2.00
2,3,4, 7,8-Pentach lo rod i benzofu ran 0.500
1,2,3,6,7,8-Hexachlorodibenzofuran 0.250 0.625 1.25 2.50 5.00
2,3,4,6, 7,8-Hexachlorodibenzofuran 1.25
1,2,3,4,6,7,8-Heptachlorodibenzofuran 0.250 0.625 1.25 2.50 5.00
1,2,3,4,7,8,9-Heptachlorodibenzofuran 1.25
Octachlorodibenzofuran 0.500 1.25 2.50 5.00 10.0
INTERNAL STANDARDS
2,3,7,8-Tetrach loro("C,,)d i benzo-p-dioxi n 0.500 0.500 0.500 0.500 0.500
1,2,3,6,7,8-Hexachloro("C,,)dibenzo-p-dioxin 0.500 0.500 0.500 0.500 0.500
Octachloro("C,,)dibenzo-p-dioxin 1.00 1.00 1.00 1.00 1.00
2,3,7,8-Tetrach loro("C,,)d i benzofu ran 0.500 0.500 0.500 0.500 0.500

1,2,3,4,6,7,8-Heptach loro("C,,)d i benzofuran 1.00 1.00 1.00 1.00 1.00
CLEANUP STANDARD
2,3,7,8-("Cl.)Tetrach lo rod i benzo-p-dioxi n 0.250
RECOVERY STANDARDS
1,2,3,7,8,9-Hexachloro("C,,)dibenzo-p-dioxin 0.500 0.500 0.500 0.500 0.500
18

EPA-828015 Internal Standard Solution 1.2 ml
EPA-828015B* Additional Internal Standard Solution 1.2 ml
EPA-8280CS Cleanup Standard Solution 1.2 ml
EPA-8280RS Recovery Standard Solution 1.2 ml
EPA-8280MSS Matrix Spiking Solution 1.2 ml
828015 828015B 8280CS 8280RS 8280MSS

NATIVE PCDDs & PCDFs (ng/1,1L) (ng/1,1L) (ng/1,1L) (ng/1,1L) (ng/1,1L)
2,3,7,8-Tetrachlorodibenzo-p-dioxin 2.50
1,2,3,7,8-Pentachlorodibenzo-p-dioxin 6.25
1,2,3,4, 7,8-Hexachlorodibenzo-p-dioxin
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 6.25
Octachlorodibenzo-p-dioxin 12.5
1,2,3,7,8-Pentachlorodibenzofuran 6.25
2,3,4,7,8-Pentachlorodibenzofuran
1,2,3,4,7,8-Hexachlorodibenzofuran
1,2,3,4, 7,8,9-Heptachlorodibenzofuran
Octachlorodibenzofuran 12.5
INTERNAL STANDARDS
2,3,7,8-Tetrachloro("C,,)dibenzo-p-dioxin 5.00
1,2,3,6,7,8-Hexachloro("C,,)dibenzo-p-dioxin 5.00
Octachloro("C,,)dibenzo-p-dioxin 10.0
2,3,7,8-Tetrachloro("C,,)dibenzofuran 5.00
1,2,3,4,6,7,8-Heptachloro("C,,)dibenzofuran 10.0
CLEANUP STANDARD
2,3,7,8-("Cl4)Tetrachlorodibenzo-p-dioxin 5.00
RECOVERY STANDARDS
1,2,3,4-Tetrachloro("C,,)dibenzo-p-dioxin 5.00
1,2,3,7,8,9-Hexachloro("C,,)dibenzo-p-dioxin 5.00
ADDITIONAL INTERNAL STANDARDS

1,2,3,7,8-Pentachloro("C,,)dibenzo-p-dioxin 5.00
1,2,3,4,6,7,8-Heptachloro("C,,)dibenzo-p-dioxin 10.0
1,2,3,7,8-Pentachloro("C,,)dibenzofuran 5.00
1,2,3,4,7,8-Hexachloro("C,,)dibenzofuran 5.00
Octachloro(''C,,)dibenzofuran 10.0
* Not required by US EPA Method 8280
19

EPA-8290HRCC1
·5 EPA Method 8290 High Resolution 1 kit
Calibration Solutions HRCC1-HRCC5 (5 ampoules)
EPA·8290HRCC0.25* HRCC0.25 Supplemental Calibration Solution 500 µL
EPA-8290HRCC0.5* HRCC0.5 Supplemental Calibration Solution 500 µL
EPA-8290HRCC1 HRCC1 500 µL
EPA·8290HRCC2 HRCC2 500 µL
EPA-8290HRCC3 HRCC3 Calibration Verification 1.0 ml
8290- 8290- 8290- 8290- 8290- 8290- 8290-

HRCC0.25 HRCC0.5 HRCC1 HRCC2 HRCC3 HRCC4 HRCCS
NATIVE PCDDs & PCDFs (ng/mL) (ng/mL) (ng/mL) (ng/mL) (ng/mL) (ng/mL) (ng/mL)
2,3,7,8-Tetrachlorodibenzo-p-0ioxin 0.250 0.500 1.00 2.50 10.0 50.0 200
1,2,3,7,8-Pentachlorodibenzo-p-dioxin 0.625 1.25 2.50 6.25 25.0 125 500
Octachlorodibenzo-p-0ioxin 1.25 2.50 5.00 12.5 50.0 250 1000

Octachlorodibenzofuran 1.25 2.50 5.00 12.5 50.0 250 1000
INTERNAL STANDARDS
1,2,3,7,8-Pentachloro("C,,)dibenzo-p-dioxin 50.0 50.0 50.0 50.0 50.0 50.0 50.0
1,2,3,6,7,8-Hexachloro("C,Jdibenzo-p-dioxin 125 125 125 125 125 125 125
1,2,3,4,6,7,8-Heptachloro("C,,)dibenzo-p-dioxin 125 125 125 125 125 125 125
Octachloro(''C, 2)dibenzo-p-0ioxin 250 250 250 250 250 250 250
2,3,7,8-Tetrachloro("C,,)dibenzofuran 50.0 50.0 50.0 50.0 50.0 50.0 50.0

1,2,3,7,8-Pentachloro("C,,)dibenzofuran 50.0 50.0 50.0 50.0 50.0 50.0 50.0
1,2,3,4,7,8-Hexachloro("C,Jdibenzofuran 125 125 125 125 125 125 125
1,2,3,4,6,7,8-Heptachloro("C,,)dibenzofuran 125 125 125 125 125 125 125
RECOVERY STANDARDS
1,2,3,7,8,9-Hexachloro("C,Jdibenzo-p-dioxin 125 125 125 125 125 125 125
* EPA-8290HRCC0.25 and EPA-8290HRCC0.5 are not included in the EPA-8290HRCC1-5 kit and must be ordered
separately.
20

EPA-8290S
FS Sample Fortification Solution 1.2 ml
EPA-8290RSS Recovery Standard Solution 1.2 ml
EPA·8290MSS Matrix Spiking Solution 1.2 ml
EPA-8290S
TN Native Stock PCDDsand PCDFs 1.2 ml
8290SFS 8290RSS 8290MSS 8290STN

NATIVE PCDDs & PCDFs (ng/mL) (ng/mL) (ng/mL) {1,1g/ml)
2,3,7,8-Tetrachlorodibenzo-p-dioxin 100 1.00
1,2,3,7,8-Pentachlorodibenzo-p-dioxin 250 2.50
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 250 2.50
1,2,3,4,6,
7,8-Heptachlorodibenzo-p-dioxin 250 2.50
Octachlorodibenzo-p-dioxin 500 5.00
2,3,7,8-Tetrachlorodibenzofuran 100 1.00

1,2,3,7,8-Pentachlorodibenzofuran 250 2.50
2,3,4,7,8-Pentachlorodibenzofuran 250 2.50
1,2,3,4,7,8-Hexachlorodibenzofuran 250 2.50
1,2,3,4,6,
7,8-Heptachlorodibenzofuran 250 2.50
1,2,3,4,7,8,9-Heptachlorodibenzofuran 250 2.50
Octachlorodibenzofuran 500 5.00
INTERNAL STANDARDS
2,3,7,8-Tetrachloro("C,Jdibenzo-p-dioxin 100
12)dibenzo-p-dioxin
1,2,3,7,8-Pentachloro("C 100
1,2,3,6,7,8-Hexachloro("C,Jdibenzo-p-dioxin 250
1,2,3,4,6,
7,8-Heptachloro("C,,)dibenzo-p-dioxin 250
Octachloro(''C,,)dibenzo-p-dioxin 500
2,3,7,8-Tetrachloro("C,Jdibenzofuran 100
1,2,3,4,7,8-Hexachloro("C,Jdibenzofuran 250
1,2,3,4,6,
7,8-Heptachloro("C,,)dibenzofuran 250
RECOVERY STANDARDS
1,2,3,4-Tetrachloro("C,Jdibenzo-p-dioxin 500
1,2,3,7,8,9-Hexachloro("C,Jdibenzo-p-dioxin 500
21

EPA·23CS1·5 EPA Method 23 1 kit
HRGC/HRMSCalibration Solutions CS1-CS5 (5 ampoules)
EPA-23CS1 cs, 500 µL
EPA-23CS3 CS3 Calibration Verification 1.0 ml
23CS1 23CS2 23CS3 23CS4 23CS5

NATIVE PCDDs & PCDFs {ng/mL) (ng/mL) {ng/mL) {ng/mL) {ng/mL)
2,3,7,8-Tetrach lorodibenzo-p-d ioxi n 0.500 1.00 5.00 50.0 100
1,2,3,7,8-Pentachlorodibenzo-p-dioxin 2.50 5.00 25.0 250 500
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 2.50 5.00 25.0 250 500
1,2,3,4,6,7,8-Heptach lorodibenzo-p-d ioxi n 2.50 5.00 25.0 250 500
Octachlorodibenzo-p-dioxin 5.00 10.0 50.0 500 1000
2,3,7,8-Tetrach lorodibenzofuran 0.500 1.00 5.00 50.0 100

1,2,3,7,8-Pentachlorodibenzofuran 2.50 5.00 25.0 250 500
2,3,4, 7,8-Pentach lo rod i benzofu ran 2.50 5.00 25.0 250 500
1,2,3,4,7,8-Hexachlorodibenzofuran 2.50 5.00 25.0 250 500
2,3,4,6, 7,8-Hexachlorodibenzofuran 2.50 5.00 25.0 250 500
1,2,3,4,6,7,8-Heptachlorodibenzofuran 2.50 5.00 25.0 250 500
1,2,3,4,7,8,9-Heptachlorodibenzofuran 2.50 5.00 25.0 250 500
Octachlorodibenzofuran 5.00 10.0 50.0 500 1000
INTERNAL STANDARDS
2,3,7,8-Tetrach loro("C,,)d i benzo-p-dioxi n 100 100 100 100 100
1,2,3,7,8-Pentach loro("C,,)d i benzo-p-d ioxin 100 100 100 100 100
1,2,3,6,7,8-Hexachloro("C,,)dibenzo-p-dioxin 100 100 100 100 100
1,2,3,4,6,7,8-Heptachloro("C,,)dibenzo-p-dioxin 100 100 100 100 100
Octachloro("C,,)dibenzo-p-dioxin 200 200 200 200 200
2,3,7,8-Tetrach loro("C,,)d i benzofu ran 100 100 100 100 100

1,2,3,7,8-Pentachloro("C,,)dibenzofuran 100 100 100 100 100
1,2,3,6,7,8-Hexachloro("C,,)dibenzofuran 100 100 100 100 100
1,2,3,4,6,7,8-Heptach loro("C,,)d i benzofuran 100 100 100 100 100
SURROGATE STANDARDS
2,3,7,8-("Cl.)Tetrach lo rod i benzo-p-dioxi n 0.500 1.00 5.00 50.0 100
1,2,3,4,7,8-Hexachloro("C,,)dibenzo-p-dioxin 2.50 5.00 25.0 250 500
2,3,4, 7,8-Pentach loro("C,,)d i benzofura n 2.50 5.00 25.0 250 500

1,2,3,4,7,8-Hexachloro("C, 2)dibenzofuran 2.50 5.00 25.0 250 500
1,2,3,4,7,8,9-Heptach loro("C, 2)d i benzofuran 2.50 5.00 25.0 250 500
ALTERNATIVE STANDARD
1,2,3,7,8,9-Hexachloro("C,,)dibenzofuran 2.50 5.00 25.0 250 500
RECOVERY STANDARDS
1,2,3,4-Tetrach loro("C,,)d i benzo-p-dioxi n 100 100 100 100 100
1,2,3,7,8,9-Hexachloro("C,,)dibenzo-p-dioxin 100 100 100 100 100
22

EPA-231S Internal Standard Solution 1.2 ml
EPA-231S
S Internal Standard Stock Solution 1.2 ml
EPA-23S5 Surrogate Standard Solution 1.2 ml
EPA-23S
SS Surrogate Standard Stock Solution 1.2 ml
EPA-23RS Recovery Standard Solution 1.2 ml
EPA-23AS Alternative Standard Solution 1.2 ml
231S 231SS 23SS 23SSS 23RS 23AS

INTERNAL STANDARDS (ng/ml) (Jig/ml) (ng/ml) (Jig/ml) (ng/ml) (ng/ml)
2,3,7,8-Tetrachloro("C,,)dibenzo-p-dioxin 100 1.00
1,2,3,7,8-Pentachloro("C,,)dibenzo-p-dioxin 100 1.00
1,2,3,6,7,8-Hexachloro("C,)dibenzo-p-dioxin 100 1.00
1,2,3,4,6,7,8-Heptachloro("C,)dibenzo-p-dioxin 100 1.00
Octachloro( 1'C12)dibenzo-p-dioxin 200 2.00
2,3,7,8-Tetrachloro("C,,)dibenzofuran 100 1.00

1,2,3,7,8-Pentachloro("C,,)dibenzofuran 100 1.00
1,2,3,6,7,8-Hexachloro("C,)dibenzofuran 100 1.00
1,2,3,4,6,7,8-Heptachloro("C,,)dibenzofuran 100 1.00
SURROGATE STANDARDS
2,3,7,8-("Cl4)Tetrachlorodibenzo-p-dioxin 100 1.00
1,2,3,4,7,8-Hexachloro("C,)dibenzo-p-dioxin 100 1.00
2,3,4,7,8-Pentachloro( 1'C12)dibenzofuran 100 1.00

1,2,3,4,7,8-Hexachloro("C,)dibenzofuran 100 1.00
1,2,3,4,7,8,9-Heptachloro("C,)dibenzofuran 100 1.00
ALTERNATIVE STANDARD
RECOVERY STANDARDS
1,2,3,4-Tetrachloro("C12)dibenzo-p-dioxin 500
23
EUROPEAN METHOD EN-1948 STANDARD SOLUTIONS

EN•1948CVS European Method EN-1948 1 kit
EN-1948CSL* CSL Extended Calibration/Low Level 500 µL
EN-1948CS1 CS1 500 µL
EN-1948CS2 CS2 500 µL
EN•1948CS3 CS3 500 µL
EN-1948CS4 CS4 500 µL
EN-1948CS5 CS5 500 µL
EN•1948CS6 CS6 500 µL
1948CSL 1948CS1 1948CS2 1948CS3 1948CS4 1948CS5 1948CS6

NATIVE PCDDs & PCDFs (pg/µL) (pg/µL) (pg/µL) (pg/µL) (pg/µL) (pg/µL) (pg/µL)
2,3,7,8-Tetrachlorodibenzo-p-0ioxin 0.0400 0.200 0.800 4.00 16.0 80.0 320
1,2,3,7,8-Pentachlorodibenzo-p-0ioxin 0.0800 0.400 1.60 8.00 32.0 160 640
Octachlorodibenzo-p-0ioxin 0.160 0.800 3.20 16.0 64.0 320 1280

Octachlorodibenzofuran 0.160 0.800 3.20 16.0 64.0 320 1280
SAMPLING STANDARDS
1,2,3,4,7,8,9-Heptachloro("C,,)dibenzofuran 32.0 32.0 32.0 32.0 32.0 32.0 32.0
EXTRACTION STANDARDS
1,2,3,7,8-Pentachloro("C,,)dibenzo-p-dioxin 16.0 16.0 16.0 16.0 16.0 16.0 16.0
1,2,3,4,6,7,8-Heptachloro("C 12)dibenzo-p-dioxin 32.0 32.0 32.0 32.0 32.0 32.0 32.0
Octachloro(''C, 2)dibenzo-p-0ioxin 32.0 32.0 32.0 32.0 32.0 32.0 32.0
2,3,7,8-Tetrachloro("C,,)dibenzofuran 16.0 16.0 16.0 16.0 16.0 16.0 16.0

1,2,3,4,6,7,8-Heptachloro("C12)dibenzofuran 32.0 32.0 32.0 32.0 32.0 32.0 32.0
Octachloro(''C,,)dibenzofuran 32.0 32.0 32.0 32.0 32.0 32.0 32.0
SYRINGE STANDARDS
1,2,3,4-Tetrachloro("C,,)dibenzo-p-Oioxin 16.0 16.0 16.0 16.0 16.0 16.0 16.0
* EN-1948CSL is not included in the EN-1948CVS kit and must be ordered separately.
24
EUROPEAN METHOD EN-1948 STANDARD SOLUTIONS

EN•1948ES Extraction Standard Solution 1.2 ml
EN-194815 Syringe Standard Solution 1.2 ml
EN-194855 Sampling Standard Solution 1.2 ml
EN•1948STK PCDD/PCDFSolution/Mixture 1.2 ml
1948ES 194815 194855 1948STK

NATIVE PCDDs & PCDFs (pg/1,1L} (pg/1,1L} (pg/1,1L} (1,1g/ml}
2,3,7,8-Tetrachlorodibenzo-p-dioxin 0.500
1,2,3,7,8-Pentachlorodibenzo-p-dioxin 1.00
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 2.00
Octachlorodibenzo-p-dioxin 2.00
Octachlorodibenzofuran 2.00
SAMPLING STANDARDS
1,2,3,7,8-Pentachloro("C 12)dibenzofuran 200
1,2,3,4,7,8,9-Heptachloro("C 12)dibenzofuran 400
2,3,7,8-Tetrachloro("C,)dibenzo-p-dioxin 200
1,2,3,7,8-Pentachloro("C 12)dibenzo-p-dioxin 200
1,2,3,4,6,7,8-Heptachloro("C12)dibenzo-p-dioxin 400
Octachloro(''C,)dibenzo-p-dioxin 400
2,3,7,8-Tetrachloro("C,,)dibenzofuran 200
2,3,4,7,8-Pentachloro("C 12)dibenzofuran 200
Octachloro(''C,)dibenzofuran 400
SYRINGE STANDARDS
1,2,3,4-Tetrachloro("C,)dibenzo-p-dioxin 800
25
HRGC/HRMS TCDD/TCDF ANALYSIS SOLUTIONS

EPA·513CVS EPA Method 513 1 kit
513-CS0.25* CS0.25 Custom Calibration Solution 500 µL
513-CS1 500 µL
513-CS2 500 µL
513·CS3 500 µL
513-CS4 500 µL
513-CSS 500 µL
513·CS6 500 µL
513-CS0.25 513-CS1 513-CS2 513-CS3 513-CS4 513-CSS 513-CS6

NATIVE TCDD & TCDF (ng/mL) (ng/mL) (ng/mL) (ng/mL) (ng/mL) (ng/mL) (ng/mL)
2,3,7,8-Tetrachlorodibenzo-p-dioxin 0.250 0.100 0.500 2.00 10.0 40.0 200
MASS-LABELLED TCDD & TCDF

2,3,7,8-Tetrachloro("C,,)dibenzofuran 100 100 100 100 100 100 100
INTERNAL STANDARDS
1,2,3,4-Tetrachloro("C 12)dibenzofuran 100 100 100 100 100 100 100
CLEANUP STANDARDS
2,3,7,8-(''CI.)Tetrachlorodi benzo-p-d ioxin 0.250 0.100 0.500 2.00 10.0 40.0 200
1,3,6,8-Tetrachloro("C 12)dibenzofuran 100 100 100 100 100 100 100
EPA·513LCSS EPA Method 513 Labelled TCDD/TCDFSpiking Solution 1.2 ml
2,3,7,8-Tetrachloro("C 12)dibenzo-p-dioxin 100 ng/ml

2,3,7,8-Tetrachloro("C 12)dibenzofuran 100 ng/ml
EPA·513ISS EPA Method 513 Internal Standard Spiking Solution 1.2 ml
1,2,3,4-Tetrachloro("C 12)dibenzo-p-dioxin 200 ng/ml

1,2,3,4-Tetrachloro("C,,)dibenzofuran 200 ng/ml
EPA·513CSSA EPA Method 513 Cleanup Standard Spiking Solution 1.2 ml
2,3,7,8-("CI4)Tetrachlorodi benzo-p-d ioxin 40.0 ng/ml
EPA·513CSSB EPA Method 513 Alternative Cleanup Standard Spiking Solution 1.2 ml
1,3,6,8-Tetrachloro("C,,)dibenzo-p-dioxin 100 ng/ml

1,3,6,8-Tetrachloro("C,,)di benzofura n 100 ng/ml
EPA·513PAR EPA Method 513 Precision and Recovery Solution 1.2 ml
2,3,7,8-Tetrachlorodibenzo-p-dioxin 40.0 ng/ml

2,3,7,8-Tetrachlorodibenzofuran 40.0 ng/ml
* 513-CS0.25 is not included in the EPA-513CVSkit and must be ordered separately.
26
CAPILLARYCOLUMN PERFORMANCETEST MIXTURES
Catalogue Number Product {nonane solution) Qty/Cone

SCWDS Window Defining Mixture 1.2 ml
for DB-5, BPS,HP-2, Rtx-5, SPB-5,
or Equivalent Capillary Columns
1,3,6,8-Tetrachlorodibenzo-p-dioxin 1.00 µg/ml

1,2,8,9-Tetrachlo rod i benzo-p-dioxi n 1.00 µg/ml
1,2,4,7,9-Pentachlorodibenzo-p-dioxin 1.00 µg/ml
1,2,3,8,9-Pentachlorodibenzo-p-dioxin 1.00 µg/ml
1,2,4,6,7,9-Hexachlorodibenzo-p-dioxin 1.00 µg/ml
1,2,3,4,6,7-Hexachlorodibenzo-p-dioxin 1.00 µg/ml
1,2,3,4,6,7,9-Heptachlorodibenzo-p-dioxin 1.00 µg/ml
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 1.00 µg/ml
Octachlorodibenzo-p-dioxin 1.00 µg/ml
1,3,6,8-Tetrachlorodibenzofuran 1.00 µg/ml

1,3,4,6,8-Pentachlorodibenzofuran 1.00 µg/ml
1,2,3,8,9-Pentachlorodibenzofuran 1.00 µg/ml
1,2,3,4,6,8-Hexachlorodibenzofuran 1.00 µg/ml
1,2,3,4,8,9-Hexachlorodibenzofuran 1.00 µg/ml
1,2,3,4,6,7,8-Heptachlorodibenzofuran 1.00 µg/ml
1,2,3,4,7,8,9-Heptachlorodibenzofuran 1.00 µg/ml
Octachlorodibenzofuran 1.00 µg/ml
STCDD 2,3,7,8-TCDD Isomer Specificity Test Mixture 1.2 ml

for DB-5, BPS,HP-2, Rtx-5, SPB-5,

1,2,3,7 and 1,2,3,8-Tetrachlorodibenzo-p-dioxin mix 0.500 µg/ml
1,2,3,4-Tetrachloro("C,,)dibenzo-p-dioxin 0.500 µg/ml

2,3,7,8-Tetrachloro("C,,)d i benzo-p-d ioxin 0.500 µg/ml
225TCDF 2,3,7,8-TCDFIsomer Specificity Test Mixture 1.2 ml

for DB-225, BP225, HP-225, Rtx-225, SPB-225,

2,3,7,8-Tetrachloro("C,,)dibenzofuran 0.500 µg/ml
27

STDWD Combined Window Defining/TCDD Resolution 1.2 ml
Testing Mixture for DB-5, BPS, HP-2, Rtx-5,
SPB-5,or Equivalent Capillary Columns
WINDOW DEFINERS
1,3,6,8-Tetrachlorodibenzo-p-dioxin 100 ng/ml
1,2,8,9-Tetrach lo rod i benzo-p-dioxi n 100 ng/ml
1,2,4,7,9-Pentachlorodibenzo-p-dioxin 100 ng/ml
1,2,3,8,9-Pentachlorodibenzo-p-dioxin 100 ng/ml
1,2,4,6,7,9-Hexachlorodibenzo-p-dioxin 100 ng/ml
1,2,3,4,6,7-Hexachlorodibenzo-p-dioxin 100 ng/ml
1,2,3,4,6,7,9-Heptachlorodibenzo-p-dioxin 100 ng/ml
1,2,3,4,6,7,8-Heptach lo rod i benzo-p-dioxin 100 ng/ml
Octachlorodibenzo-p-dioxin 100 ng/ml
1,3,6,8-Tetrachlorodibenzofuran 100 ng/ml

1,2,8,9-Tetrachlorodibenzofuran 100 ng/ml
1,3,4,6,8-Pentachlorodibenzofuran 100 ng/ml
1,2,3,8,9-Pentachlorodibenzofuran 100 ng/ml
1,2,3,4,8,9-Hexachlorodibenzofuran 100 ng/ml
1,2,3,4,6,8-Hexachlorodibenzofuran 100 ng/ml
1,2,3,4,6,7,8-Heptachlorodibenzofuran 100 ng/ml
1,2,3,4,7,8,9-Heptachlorodibenzofuran 100 ng/ml
Octachlorodibenzofuran 100 ng/ml
2,3,7,8-TCDD RESOLUTION TESTING ISOMERS

1,2,3,4-Tetrachlorodibenzo-p-dioxin 50.0 ng/ml
1,2,3,7 and 1,2,3,8-Tetrachlorodibenzo-p-dioxin mix 50.0 ng/ml
2,3,7,8-Tetrachloro("C,,)dibenzo-p-dioxin 50.0 ng/ml
OTHERS
1,2,3,7,8,9-Hexachloro("C,,)dibenzo-p-dioxin 50.0 ng/ml
NativeTCODs
22.00 24.00 25.00 26.00 28.00
10
'*C,t·2,3,7,8-TCDO
22.00 23.00 24.00 25.00 26.00 27.00 28.00
GC/MS DATA: TCDDson a 60m DB-5 Column.
28

TDTFWD Combined Window Defining and Resolution 1.2 ml
Testing Mixture for 3 Capillary Columns
Concentrations for each compound are listed in brackets (ng/mL :t 20%) 8
WINDOW DEFINING STANDARDS
FIRST LAST FIRST LAST

1368-TCDD (50.0) 1289-TCDD (50.0) 1368-TCDD (50.0) 1289-TCDD (50.0)
12479-PeCDD (50.0) 12389-PeCDD (50.0) 12479-PeCDD (50.0) 12389-PeCDD (50.0)
124679-HxCDD (50.0) 123467-HxCDD (50.0) 124679-HxCDD (50.0) 123467-HxCDD (50.0)
1234679-HpCDD (50.0) 1234678-HpCDD (50.0) 1234679-HpCDD (50.0) 1234678-HpCDD (50.0)
OCDD (50.0) OCDD (50.0)
1368-TCDF (100) 1289-TCDF (110) 1368-TCDF (100) 1289-TCDF (110)

13468-PeCDF (50.0) 12389-PeCDF (50.0) 13468-PeCDF (50.0) 23467-PeCDF (50.0)
123468-HxCDF (50.0) 123489-HxCDF (50.0) 123468-HxCDF (50.0) 234678-HxCDF (50.0)
1234678-HpCDF (50.0) 1234789-HpCDF (50.0) 1234678-HpCDF (50.0) 1234789-HpCDF (50.0)
OCDF (50.0) OCDF (50.0)
RESOLUTION TESTING MIXTURES
2378-TCDD 1234-TCDD (25.0) 1478-TCDD (25.0) 1478-TCDD (25.0)

1237- and 1238-TCDD (25.0)e 2378-TCDD (50.0) 2378-TCDD (50.0)
2378-TCDD (50.0) 1237- and 1238-TCDD (2s.ot 1237- and 1238-TCDD (2s.ot
1239-TCDD (50.0) 1234-TCDD (25.0) 1234-TCDD (25.0)
2378-TCDF 2347-TCDF,2348-TCDF, 1269-TCDF (50.0) 2347-TCDF (50.0)

and 2378-TCDF 2378-TCDF (100) 2378-TCDF (100)
(not resolved) 2348-TCDF (50.0) 1239-TCDF (65.0)
(200t
OTHER PCDDs AND PCDFs INCLUDED
12378-PeCDD (50.0) 123478-HxCDD (50.0) 123478-HxCDF (50.0) "C,,-1234-TCDD (25.0)

12378-PeCDF (50.0) 123678-HxCDD (50.0) 123678-HxCDF (50.0) "C,,-2378-TCDD (25.0)
23478-PeCDF (50.0) 123789-HxCDD (50.0) 123789-HxCDF (50.0) "C,,-2378-TCDF (25.0)
"C,,-123789-HxCDD (50.0)
a Maximum percent relative combined uncertainty of weights and volumes

b 5/2 - DB-5, BPS, HP-2, Rtx-5, SPB-5or equivalent capillary column
c 2331 - SP-2331, Rtx-2330 or equivalent capillary column
d 225 - DB-225, BP225, HP-225, Rtx-225, SPB-225or equivalent capillary column
e Total concentration of isomers
29
MASS-LABELLEDCAPILLARYCOLUMN PERFORMANCETEST MIXTURES
The two mixtures detailed below, MDSCWDSand MFSCWDS,contain 13C-labelled PCDDand
13C-labelled PCDFcongeners, respectively. These solutions were designed to be run on a DB-5 (or
equivalent} capillary column to confirm the congener group windows for tetra-, penta-, hexa- and
heptachloro- PCDDsand PCDFs. It is intended that these mixtures, or dilutions thereof, be added
to the samples prior to extraction, at some stage during cleanup, or just prior to instrumental
analysis. The final, cleaned-up, sample extracts would thus contain all the PCDDand PCDFwindow
defining 13C-labelled congeners when used in concert with our calibration set support solutions.
This would allow the analyst to immediately confirm that the congener group windows had not
shifted and that all the PCDDsand PCDFshad been detected where present.
Please note that some 2,3,7,8-substituted PCDDsor PCDFsare also window defining congeners and
are already present in 13C-labelled PCDDand PCDFsolution/mixes added as sampling
(e.g. EPA-23SS},extraction (e.g. EPA-1613LCS},cleanup, or internal standards (e.g. EPA-1613IS$}.
Therefore, they are not included in these window defining mixtures.

MD5CWDS PCDD Window Defining Mixture 1.2 ml
for DB-S, BPS, HP-2, Rtx-S, SPB-S,
Concentrations for each compound are listed in brackets (ng/ml :t 200/o)a
FIRST LAST
1,3,6,8-Tetrachloro("C,,)dibenzo-p-dioxin (1000) 1,2,8,9-Tetrachloro("C,,)dibenzo-p-dioxin (1000)

1,2,4,7,9-Pentachloro("C,,)dibenzo-p-d ioxi n (1000) 1,2,3,8,9-Pentachloro("C,,)dibenzo-p-dioxin (1000)
1,2,4,6,7,9-Hexachloro("C,,)dibenzo-p-d ioxin (1000) *
1,2,3,4,6,7,9-Heptachloro("C 12)dibenzo-p-dioxin (1000) **
* 1,2,3,4,6,7-Hexachloro("C,,)dibenzo-p-dioxin (last eluting HxCDD) is not included in this solution as it co-elutes with
1,2,3,7,8,9-Hexachloro("C,,)dibenzo-p-dioxin which is present in compatible support solutions.
** 1,2,3,4,6,7,8-Heptachloro("C,,)dibenzo-p-dioxin (last eluting HpCDD) is not included in this solution as it is present in compatible
support solutions.
MF5CWDS PCDFWindow Defining Mixture 1.2 ml

for DB-S, BPS, HP-2, Rtx-S, SPB-S,
Concentrations for each compound are listed in brackets (ng/mL :t 200/o)a
FIRST LAST
1,3,6,8-Tetrachloro("C,,)dibenzofuran (1000) 1,2,8,9-Tetrachloro("C,,)dibenzofuran (1000)
1,3,4,6,8-Pentachloro("C12)dibenzofuran (1000) 1,2,3,8,9-Pentachloro("C,,)dibenzofuran (1000)
1,2,3,4,6,8-Hexachloro("C,,)dibenzofuran (1000) ***
**** ****
*** 1,2,3,4,8,9-Hexachloro("C,,)dibenzofuran (last eluting HxCDF)is not included in this solution as it co-elutes with
1,2,3,7,8,9-Hexachloro("C,,)dibenzofuran which is present in compatible support solutions.
**** 1,2,3,4,6,7,8-Heptachloro("C12)dibenzofuran (first eluting HpCDF)and 1,2,3,4,7,8,9-Heptachloro("C,,)dibenzofuran (last eluting
HpCDF)are not included in this solution as they are present in compatible support solutions.
a Maximum percent relative combined uncertainty of weights and volumes
30
INDIVIDUAL PCDD & PCDF CONGENERS:
NATIVE AND MASS-LABELLED
Wellington offers a large selection of individual polychlorinated dibenzo-p-dioxins (PCDDs)and

polychlorinated dibenzofurans (PCDFs). We now also offer the largest selection of
mass-labelled PCDD and PCDFcongeners.
The following product groups are presented in this section:
Native Polychlorinated Dibenzo-p-dioxins (PCDDs)
Native Polychlorinated Dibenzofurans (PCDFs)
Mass-labelled PCDDs
Mass-labelled PCDFs
These compounds have all been prepared using single product, unambiguous synthetic routes
and rigorously purified using various techniques. Prior to release, their structures, chemical and
isotopic purities are confirmed using several instrumental methods and this data is summarized
in the Certificates of Analysis (CofAs).
In addition, the concentrations of the 2,3,7,8-substituted PCDDsand PCDFshave been
continually certified since 1991 through a large number of interlaboratory studies and are thus
traceable to these studies.
Since our last catalogue, we have added 3 new mass-labelled PCDDsand 2 new mass-labelled
PCDFs,namely:
MDD-27 2, 7-Dichloro( 13 C12)dibenzo-p-dioxin
MDD-28 2,8-Dichloro( 13 C12)dibenzo-p-dioxin
MDD-1289 1,2,8, 9-Tetrachloro( 13C12)dibenzo-p-dioxin
MDF-12389 1,2,3,8, 9-Pentachloro( 13 C12)dibenzofuran
MDF-123489 1,2,3,4,8,9-Hexachloro( 13 C12)dibenzofuran
NATIVE POLYCHLORINATED DIBENZO-p-DIOXINS (PCDDs)
Catalogue Number Product (toluene or nonane solution) Qty/Cone

DD·O·S Dibenzo-p-dioxin 1.2 ml 50.0 µg/ml
DD-1•5 1-Chlorodibenzo-p-dioxin 1.2 ml 50.0 µg/ml
DD-2-5 2-Ch lorodibenzo-p-dioxi n 1.2 ml 50.0 µg/ml
DD-23·5 2, 3-D ich lo rod i be nzo-p-d i oxi n 1.2 ml 50.0 µg/ml
DD-27-5 2, 7-Dichlorodibenzo-p-dioxin 1.2 ml 50.0 µg/ml
DD-28-5 2, 8-D ich lo rod i be nzo-p-d i oxi n 1.2 ml 50.0 µg/ml
DD-123-5 1,2,3-Trich lorodibenzo-p-dioxin 1.2 ml 50.0 µg/ml
DD-124-5 1,2,4-Trich lorodibenzo-p-dioxin 1.2 ml 50.0 µg/ml
DD-237•5 2,3, 7-Trichlorodibenzo-p-dioxin 1.2 ml 50.0 µg/ml
DD-1234-5 1,2,3,4-Tetrach lorodibenzo-p-dioxin 1.2 ml 50.0 µg/ml
DD-1247/8-5 1,2,4, 7/1,2,4,8-Tetrachlorodibenzo-p-dioxin mix 1.2 ml 50.0 µg/ml
DD-1278•5 1,2, 7,8-Tetrach lorodibenzo-p-dioxin 1.2 ml 50.0 µg/ml
DD-1289-5 1,2,8, 9-Tetrach lorodibenzo-p-dioxin 1.2 ml 50.0 µg/ml
DD-1368-5 1,3,6,8-Tetrach lorodibenzo-p-dioxin 1.2 ml 50.0 µg/ml
DD-1379-5 1,3, 7, 9-Tetrach lorodibenzo-p-dioxin 1.2 ml 50.0 µg/ml
DD-1478-5 1,4, 7,8-Tetrach lorodibenzo-p-dioxin 1.2 ml 50.0 µg/ml
DD-12378-5 1,2,3, 7,8-Pentachlorodibenzo-p-dioxin 1.2 ml 50.0 µg/ml
DD-12478-5 1,2,4, 7,8-Pentachlorodibenzo-p-dioxin 1.2 ml 50.0 µg/ml
DD-123467•5 1,2,3,4,6, 7-Hexach lorodibenzo-p-dioxin 1.2 ml 50.0 µg/ml
DD-123468-5 1,2,3,4,6,8-Hexach lorodibenzo-p-dioxin 1.2 ml 50.0 µg/ml
DD-123478-5 1,2,3,4, 7,8-Hexach lorodibenzo-p-dioxin 1.2 ml 50.0 µg/ml
DD-123678•5 1,2,3,6, 7,8-Hexach lorodibenzo-p-dioxin 1.2 ml 50.0 µg/ml
DD-123789-5 1,2,3, 7,8, 9-Hexach lorodibenzo-p-dioxin 1.2 ml 50.0 µg/ml
DD-124679-5 1,2,4,6, 7, 9-Hexach lorodibenzo-p-dioxin 1.2 ml 50.0 µg/ml
DD-1234678•5 1,2,3,4,6, 7,8-Heptach lorodibenzo-p-dioxin 1.2 ml 50.0 µg/ml
DD-12346789-S Octachlorod i benzo-p-d ioxi n 1.2 ml 50.0 µg/ml
9
8 2
7 3
6 4
32
NATIVE POLYCHLORINATEDDIBENZOFURANS(PCDFs)
Catalogue Number Product (toluene or nonane solution} Qty/Cone

DF·O·S Dibenzofuran 1.2 ml 50.0 µg/ml
DF-2-5 2-Ch lorodibenzofu ran 1.2 ml 50.0 µg/ml
DF-4-5 4-Ch lorodibenzofu ran 1.2 ml 50.0 µg/ml
DF-23·5 2,3-Dich lorodibenzofu ran 1.2 ml 50.0 µg/ml
DF-24-5 2,4-Dich lorodibenzofu ran 1.2 ml 50.0 µg/ml
DF-27-5 2, 7-Dichlorodibenzofuran 1.2 ml 50.0 µg/ml
DF-136·5 1,3,6-Trich lorodibenzofuran 1.2 ml 50.0 µg/ml
DF-138-5 1,3,8-Trich lorodibenzofuran 1.2 ml 50.0 µg/ml
DF-147•5 1,4, 7-Trichlorodibenzofuran 1.2 ml 50.0 µg/ml
DF-149-5 1,4, 9-Trich lorodibenzofuran 1.2 ml 50.0 µg/ml
DF-236·5 2,3,6-Trich lorodibenzofuran 1.2 ml 50.0 µg/ml
DF-247•5 2,4, 7-Trichlorodibenzofuran 1.2 ml 50.0 µg/ml
DF-267-5 2,6, 7-Trichlorodibenzofuran 1.2 ml 50.0 µg/ml
DF-1236·5 1,2,3,6-Tetrach lorodibenzofuran 1.2 ml 50.0 µg/ml
DF-1238-5 1,2,3,8-Tetrach lorodibenzofuran 1.2 ml 50.0 µg/ml
DF-1239-5 1,2,3, 9-Tetrach lorodibenzofuran 1.2 ml 50.0 µg/ml
DF-1246·5 1,2,4,6-Tetrach lorodibenzofuran 1.2 ml 50.0 µg/ml
DF-1247-5 1,2,4, 7-Tetrachlorodibenzofuran 1.2 ml 50.0 µg/ml
DF-1248-5 1,2,4,8-Tetrach lorodibenzofuran 1.2 ml 50.0 µg/ml
DF-1267•5 1,2,6, 7-Tetrachlorodibenzofuran 1.2 ml 50.0 µg/ml
DF-1278-5 1,2, 7,8-Tetrach lorodibenzofuran 1.2 ml 50.0 µg/ml
DF-1279-5 1,2, 7, 9-Tetrach lorodibenzofuran 1.2 ml 50.0 µg/ml
DF-1347•5 1,3,4, 7-Tetrachlorodibenzofuran 1.2 ml 50.0 µg/ml
9
8 2
7 3
6 4
33
NATIVE POLYCHLORINATED DIBENZOFURANS (PCDFs)
Catalogue Number Product (toluene or nonane solution) Qty/Cone
DF-1348-S 1,3,4,8-Tetrachlorodibenzofuran 1.2 ml 50.0 µg/ml
DF·1367•S 1,3,6,7-Tetrachlorodibenzofuran 1.2 ml 50.0 µg/ml
DF-2346-S 2,3,4,6-Tetrach I orodibenzofuran 1.2 ml 50.0 µg/ml
DF·2348·S 2,3,4,8-Tetrach I orodibenzofuran 1.2 ml 50.0 µg/ml
DF-12347-S 1,2,3,4,7-Pentachlorodibenzofuran 1.2 ml 50.0 µg/ml
DF-13678-S 1,3,6,7,8-Pentachlorodibenzofuran (97% pure) 1.2 ml 48.5 µg/ml
9
8 2
7 3
6 4
34
NATIVE POLYCHLORINATEDDIBENZOFURANS(PCDFs)
Catalogue Number Product (toluene or nonane solution} Qty/Cone

DF-123467-S 1,2,3,4,6, 7-Hexachlorodibenzofuran 1.2 ml 50.0 µg/ml
DF-123468-S 1,2,3,4,6,8-Hexach lorodi benzofura n 1.2 ml 50.0 µg/ml
DF-123478-S 1,2,3,4, 7,8-Hexachlorodibenzofuran 1.2 ml 50.0 µg/ml
DF-123489-S 1,2,3,4,8, 9-Hexach lorodi benzofura n 1.2 ml 50.0 µg/ml
DF-123678-S 1,2,3,6, 7,8-Hexach lorodi benzofura n 1.2 ml 50.0 µg/ml
DF-123789-S 1,2,3, 7,8,9-Hexachlorodibenzofuran 1.2 ml 50.0 µg/ml
DF-234678-S 2,3,4,6, 7,8-Hexach lorodi benzofura n 1.2 ml 50.0 µg/ml
DF-1234678-S 1,2,3,4,6, 7,8-Heptachlorodibenzofuran 1.2 ml 50.0 µg/ml
DF-1234689-S 1,2,3,4,6,8,9-Heptach lorodi benzofura n 1.2 ml 50.0 µg/ml
DF-1234789-S 1,2,3,4, 7,8, 9-Heptach lorodi benzofura n 1.2 ml 50.0 µg/ml
DF-12346789-S Octachlorod ibenzofuran 1.2 ml 50.0 µg/ml
37 (1-MASS-LABELLED DI BENZO-p-DIOXIN
Catalogue Number Product

2,3,7,8-("CI4)Tetrachlo rod ibenzo-p-dioxi n
MCDD-2378 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene
(isotopic purity 94 to 95%)
MASS-LABELLEDPOLYCHLORINATEDDIBENZO-p-DIOXINS
("C,,)Dibenzo-p-dioxin
MDD-0
1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene
~Cl 2-Chloro("C,,)dibenzo-p-dioxin
~
MDD-2
~Cl 2,3-Dichloro("C,,)dibenzo-p-dioxin
MDD-23
~I 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene
2,7-Dichloro("C,,)dibenzo-p-dioxin
MDD-27
2,8-Dichloro("C,,)dibenzo-p-dioxin
MDD-28
* Unless stated otherwise, isotopic purities of these compounds are 99% or greater.
35
MASS-LABELLEDPOLYCHLORINATEDDIBENZO-p-DIOXINS
2,3,7-Trichloro("C,,)dibenzo-p-d ioxi n
MDD-237
Cl
1,2,3,4-Tetrachloro("C,,)d i benzo-p-dioxi n
MDD-1234
Cl
Cl 1,2,7,8-Tetrachloro("C,,)d i benzo-p-dioxi n
MDD-1278
C
Cl Cl 1,2,8,9-Tetrachloro("C,,)d i benzo-p-dioxi n
MDD-1289
Cl
MDD-1368
Cl 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene
Cl
1,3,7,8-Tetrachloro("C,,)d i benzo-p-dioxi n
MDD-1378
MDD-2378
Cl
Cl 1,2,3,7,8-Pentachloro("C,,)di benzo-p-d ioxin
MDD-12378
Cl Cl
Cl Cl 1,2,3,8,9-Pentach loro("C,,)di benzo-p-d ioxin
MDD-12389
Cl
Cl Cl 1,2,4,7,8-Pentachloro("C 12)di benzo-p-d ioxin
MDD-12478
36
MASS-LABELLED POLYCHLORINATED DIBENZO-p-DIOXINS

Cl Cl
Cl 1,2,4, 7,9-Pentachloro("C,,)dibenzo-p-dioxin
MDD-12479
Cl
Cl 1,2,3,4,6, 7-Hexachloro("C,,)dibenzo-p-dioxin
MDD-123467
Cl Cl 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene
Cl Cl
Cl
Cl 1,2,3,4,6,8-Hexachloro("C12)dibenzo-p-dioxin
MDD-123468
Cl 1,2,3,4,7,8-Hexachloro("C,,)dibenzo-p-dioxin
MDD-123478
MDD-123678
Cl
MDD-123789
Cl Cl
1,2,4,6, 7,9-Hexachloro("C,,)dibenzo-p-dioxin
MDD-124679
Cl 1,2,3,4,6,7,8-Heptachloro("C,,)dibenzo-p-dioxin
MDD-1234678
Cl Cl
Cl Cl
1,2,3,4,6, 7,9-Heptachloro("C,,)dibenzo-p-dioxin
MDD-1234679
Cl Cl
Cl Cl
Cl Octachloro("C,,)dibenzo-p-dioxin
MDD-12346789
37
MASS-LABELLED POLYCHLORINATED DIBENZOFURANS
("C,,)Dibenzofuran
MDF-0
1.2 ml; 50.0 µg/ml (±2.5 µg/ml}; in toluene
2-Chloro("C,,)dibenzofuran
MDF-2
Cl 2,3-Dichloro("C,,}dibenzofuran
MDF-23
c1 1.2 ml; 50.0 µg/ml (±2.5 µg/ml}; in toluene
Cl 2,3,8-Trichloro("C,,}dibenzofuran
MDF-238
Cl 1.2 ml; 50.0 µg/ml (±2.5 µg/ml}; in toluene
Cl
Cl 1,2,3,4-Tetrachloro("C,,)dibenzofuran
MDF-1234
Cl
Cl
MDF-1278
Cl
Cl
)SQsr Cl 1,2, 7,8-Tetrachloro("C,,}dibenzofuran
Cl
1,3,6,8-Tetrachloro("C,,}dibenzofuran
MDF-1368
c1 1.2 ml; 50.0 µg/ml (±2.5 µg/ml}; in toluene
Cl
Cl~CI 2,3, 7,8-Tetrachloro("C,,)dibenzofuran

MDF-2378
Cl~I 1.2 ml; 50.0 µg/ml (±2.5 µg/ml}; in toluene
Cl
1,2,3.4,6-Pentachloro("C,,)dibenzofuran
MDF-12346
38
MASS-LABELLEDPOLYCHLORINATEDDIBENZOFURANS
Cl Cl
1,2,3,7,8-Pentach loro("C,,)d i benzofuran
MDF-12378
Cl Cl
Cl 1,2,3,8,9-Pentach loro("C 12)d i benzofuran
MDF-12389
Cl
Cl 1,3,4,6,8-Pentachloro("C 12)d i benzofuran
MDF-13468
Cl Cl
Cl Cl
2,3,4,7,8-Pentach loro("C 12)d i benzofuran
MDF-23478
Cl Cl
Cl
Cl 1,2,3,4,6,8-Hexachloro("C,,)dibenzofuran
MDF-123468
Cl Cl
Cl 1,2,3,4,6,9-Hexachloro("C 12)dibenzofuran
MDF-123469
Cl
Cl Cl 1,2,3,4,7,8-Hexachloro("C,,)dibenzofuran
MDF-123478
Cl
Cl Cl
Cl Cl 1,2,3,4,8,9-Hexachloro("C 12)dibenzofuran
MDF-123489
Cl
Cl Cl 1,2,3,6,7,8-Hexachloro("C 12)dibenzofuran
MDF-123678
39
MASS-LABELLEDPOLYCHLORINATEDDIBENZOFURANS
Cl Cl 1,2,3,7,8,9-Hexachloro("C,,)dibenzofuran
MDF-123789
Cl Cl
Cl
2,3,4,6,7,8-Hexachloro("C 12)dibenzofuran
MDF-234678
Cl
Cl
Cl 1,2,3,4,6,7,8-Heptachloro("C,,)dibenzofuran
MDF-1234678
Cl Cl 1,2,3,4,6,8,9-Heptach loro("C,,)d i benzofuran

MDF-1234689
Cl Cl
Cl 1,2,3,4,7,8,9-Heptachloro("C,,)dibenzofuran
MDF-1234789
Octachloro("C, 2)dibenzofuran
MDF-12346789
MDF-1234789
-------------------------------
-·-
HRGC/lRMSdata of 1,2,3,4,7,8,9-Heptachloro("C,,)dibenzofuran (30m DB-5 column).
40
NOTES AND NEW PRODUCTS
In order to keep up-to-date on new releases from Wellington Laboratories Inc.,

please visit our website at www.we/I-labs.com.
New Products are announced in the Wellington Reporter.
41
PCDDS & PCDF S:
JAPANESE INDUSTRIAL STANDARD METHODS
JIS K 0311 AND JIS K 0312 &
ADDITIONAL PCDD/PCDF SPECIALTYSOLUTION/MIXTURES
Due to requests from clients several years ago, Wellington designed and prepared multi-point
calibration sets containing native and mass-labelled polychlorinated dibenzo-p-dioxins (PCDDs)
and polychlorinated dibenzofurans (PCDFs). These remain popular, and thus are still offered, as
they include up to 13 individual calibration solutions. This allows the user some flexibility in
selecting the calibration range that is most appropriate for their instrumentation and the
matrices being analyzed.
Moreover, these calibration sets, and their support solutions, incorporate additional mass-labelled
PCDDsand PCDFswhich can be used as part of more involved sampling and sample processing
procedure.
~;«al ....
All of these calibration sets and support solutions are suitable for use with the Japanese
. Industrial Standards JIS K 0311 and JIS K 0312. Provided that all performance criteria are
'-I".!'!~~ achieved, they can also be used with regulatory methods from other countries.
DF-CVS-A10

DF-CVS•A10-Set1 CS1/CS3/CS5/CS7/CS9 1 kit (5 ampoules)
DF-CVS-A10-Set2 CS2/CS4/CS6/CS8/CS10 1 kit (5 ampoules)
DF•CVS•A10•Set3 CS3/CS5/CS7/CS9/CS11 1 kit (5 ampoules)
DF·A10-CSL CSL Extended Calibration/Low Level 200 µL
DF·A10-CS1 CS1 200 µL
DF·A10·CS2 CS2 200 µL
DF-A10- DF-A10- DF-A10- DF-A10- DF-A10-

CSL cs, CS2 CS3 CS4
NATIVE PCDDs & PCDFs (ng/mL) (ng/mL) (ng/mL) (ng/mL) (ng/mL)
1,3,7,9-Tetrachlorodibenzo-p-dioxin 0.0500 0.100 0.200 0.500 1.00
1,2,8,9-Tetrachlorodibenzo-p-dioxin 0.0500 0.100 0.200 0.500 1.00
1,2,3,7,8-Pentachlorodibenzo-p-dioxin 0.0500 0.100 0.200 0.500 1.00
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 0.0500 0.100 0.200 0.500 1.00
Octachlorodibenzo-p-dioxin 0.100 0.200 0.400 1.00 2.00
1,3,6,8-Tetrachlorodibenzofuran 0.0500 0.100 0.200 0.500 1.00

2,3,7,8-Tetrach lorodibenzofuran 0.0500 0.100 0.200 0.500 1.00
1,2,3,7,8-Pentachlorodibenzofuran 0.0500 0.100 0.200 0.500 1.00
2,3,4, 7,8-Pentach lo rod i benzofu ran 0.0500 0.100 0.200 0.500 1.00
2,3,4,6, 7,8-Hexachlorodibenzofuran 0.0500 0.100 0.200 0.500 1.00
1,2,3,4,6, 7,8-Heptach lorodibenzofu ran 0.0500 0.100 0.200 0.500 1.00
1,2,3,4,7,8,9-Heptachlorodibenzofuran 0.0500 0.100 0.200 0.500 1.00
Octachlorodibenzofuran 0.100 0.200 0.400 1.00 2.00
EXTRACTION SPIKE:
1,2,3,7,8-Pentach loro("C,,)d i benzo-p-d ioxin 10.0 10.0 10.0 10.0 10.0
1,2,3,4,7,8-Hexachloro("C, 2)dibenzo-p-dioxin 10.0 10.0 10.0 10.0 10.0
1,2,3,6,7,8-Hexach loro("C,,)dibenzo-p-d ioxi n 10.0 10.0 10.0 10.0 10.0
1,2,3,7,8,9-Hexachloro("C ,)dibenzo-p-dioxin 10.0 10.0 10.0 10.0 10.0
1,2,3,4,6,7,8-Heptach loro("C,,)d i benzo-p-dioxin 10.0 10.0 10.0 10.0 10.0
Octachloro("C,,)dibenzo-p-dioxin 20.0 20.0 20.0 20.0 20.0

1,2,3,7,8-Pentachloro("C,,)dibenzofuran 10.0 10.0 10.0 10.0 10.0
2,3,4, 7,8-Pentach loro("C,,)d i benzofura n 10.0 10.0 10.0 10.0 10.0
1,2,3,4,7,8-Hexachloro("C,,)dibenzofuran 10.0 10.0 10.0 10.0 10.0
1,2,3,6,7,8-Hexachloro("C,,)dibenzofuran 10.0 10.0 10.0 10.0 10.0
1,2,3,7,8,9-Hexachloro("C, 2)dibenzofuran 10.0 10.0 10.0 10.0 10.0
2,3,4,6, 7,8-Hexachloro("C ,)dibenzofuran 10.0 10.0 10.0 10.0 10.0
1,2,3,4,6,7,8-Heptachloro("C,,)dibenzofuran 10.0 10.0 10.0 10.0 10.0
1,2,3,4,7,8,9-Heptachloro("C,,)dibenzofuran 10.0 10.0 10.0 10.0 10.0
Octachloro("C,,)dibenzofuran 20.0 20.0 20.0 20.0 20.0
SYRINGE SPIKE:
MASS-LABELLED PCDFs
1,2,3,4,6-Pentach loro("C,,)d i benzofura n 10.0 10.0 10.0 10.0 10.0
1,2,3,4,6,9-Hexachloro("C ,)dibenzofuran 10.0 10.0 10.0 10.0 10.0
1,2,3,4,6,8, 9-Heptach loro("C,,)d i benzofuran 10.0 10.0 10.0 10.0 10.0
SAMPLING SPIKE:
44
DF-CVS-A10
Catalogue Number Product (nonane solution} Qty/Cone

DF·A10·CS7 CS7 200 µL
DF·A10-CS8 css 200 µL
DF·A10·CS10 CS10 200 µL
DF·A10-CS11 CS11 200 µL
DF·A10-CSH CSH Extended Calibration/High Level 200 µL
*FOR SUPPORT SOLUTIONS, see DF-ST-A, DF-LCS-A, DF-IS-B, and DF-IS-I (and their dilutions).
DF-A10- DF-A10- DF-A10- DF-A10- DF-A10- DF-A10- DF-A10- DF-A10-

css CS6 CS7 css CS9 CS10 CS11 CSH
(ng/ml) (ng/ml) (ng/ml) (ng/ml) (ng/ml) (ng/ml) (ng/ml) (ng/ml)
2.00 5.00 10.0 20.0 50.0 100 200 1000
2.00 5.00 10.0 20.0 50.0 100 200 1000
2.00 5.00 10.0 20.0 50.0 100 200 1000
2.00 5.00 10.0 20.0 50.0 100 200 1000
2.00 5.00 10.0 20.0 50.0 100 200 1000
2.00 5.00 10.0 20.0 50.0 100 200 1000
2.00 5.00 10.0 20.0 50.0 100 200 1000
2.00 5.00 10.0 20.0 50.0 100 200 1000
2.00 5.00 10.0 20.0 50.0 100 200 1000
4.00 10.0 20.0 40.0 100 200 400 2000
2.00 5.00 10.0 20.0 50.0 100 200 1000

2.00 5.00 10.0 20.0 50.0 100 200 1000
2.00 5.00 10.0 20.0 50.0 100 200 1000
2.00 5.00 10.0 20.0 50.0 100 200 1000
2.00 5.00 10.0 20.0 50.0 100 200 1000
2.00 5.00 10.0 20.0 50.0 100 200 1000
2.00 5.00 10.0 20.0 50.0 100 200 1000
2.00 5.00 10.0 20.0 50.0 100 200 1000
2.00 5.00 10.0 20.0 50.0 100 200 1000
2.00 5.00 10.0 20.0 50.0 100 200 1000
2.00 5.00 10.0 20.0 50.0 100 200 1000
2.00 5.00 10.0 20.0 50.0 100 200 1000
4.00 10.0 20.0 40.0 100 200 400 2000
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0

10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0

10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0

10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0

10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
45
DF-CVS-810

DF-CVS•B10-Set1 CS1/CS3/CS5/CS7/CS9 1 kit (5 ampoules)
DF-CVS-B10-Set2 CS2/CS4/CS6/CS8/CS10 1 kit (5 ampoules)
DF•CVS•B10•Set3 CS3/CS5/CS7/CS9/CS11 1 kit (5 ampoules)
DF·B10-CS1 CS1 200 µL

DF·B10·CS2 CS2 200 µL
DF-B10- DF-B10- DF-B10- DF-B10-

CS1 CS2 CS3 CS4
NATIVE PCDDs & PCDFs {ng/mL) {ng/mL) {ng/mL) {ng/mL)
1,3,6,8-Tetrachlorodibenzo-p-dioxin 0.100 0.200 0.500 1.00
2,3,7,8-Tetrach lorodibenzo-p-d ioxi n 0.100 0.200 0.500 1.00
1,2,3,7,8-Pentachlorodibenzo-p-dioxin 0.100 0.200 0.500 1.00
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 0.200 0.400 1.00 2.00
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 0.200 0.400 1.00 2.00
Octachlorodibenzo-p-dioxin 0.500 1.00 2.50 5.00
1,3,6,8-Tetrach lorodibenzofuran 0.100 0.200 0.500 1.00

1,2,7,8-Tetrachlorodibenzofuran 0.100 0.200 0.500 1.00
1,2,3,7,8-Pentachlorodibenzofuran 0.100 0.200 0.500 1.00
2,3,4,7,8-Pentach lo rod i benzofu ran 0.100 0.200 0.500 1.00
1,2,3,4,7,8-Hexachlorodibenzofuran 0.200 0.400 1.00 2.00
2,3,4,6, 7,8-Hexachlorodibenzofuran 0.200 0.400 1.00 2.00
1,2,3,4,6,7,8-Heptach lorodibenzofu ran 0.200 0.400 1.00 2.00
1,2,3,4,7,8,9-Heptachlorodibenzofuran 0.200 0.400 1.00 2.00
Octachlorodibenzofuran 0.500 1.00 2.50 5.00
EXTRACTION SPIKE:
1,3,6,8-Tetrach loro("C,,)d i benzo-p-dioxi n 10.0 10.0 10.0 10.0
1,2,3,7,8-Pentachloro("C,,)dibenzo-p-dioxin 10.0 10.0 10.0 10.0
1,2,3,4,7,8-Hexach loro("C,,)dibenzo-p-d ioxi n 10.0 10.0 10.0 10.0
1,2,3,6,7,8-Hexachloro("C,,)dibenzo-p-dioxin 10.0 10.0 10.0 10.0
1,2,3,7,8,9-Hexachloro("C ,)dibenzo-p-dioxin 10.0 10.0 10.0 10.0
1,2,3,4,6,7,8-Heptach loro("C,,)d i benzo-p-dioxin 10.0 10.0 10.0 10.0
Octachloro("C,,)dibenzo-p-dioxin 20.0 20.0 20.0 20.0
1,3,6,8-Tetrachloro("C,,)dibenzofuran 10.0 10.0 10.0 10.0

2,3,7,8-Tetrach loro("C,,)d i benzofu ran 10.0 10.0 10.0 10.0
1,2,3,7,8-Pentachloro("C,,)dibenzofuran 10.0 10.0 10.0 10.0
2,3,4,7,8-Pentach loro("C,,)d i benzofura n 10.0 10.0 10.0 10.0
1,2,3,4,7,8-Hexachloro("C,,)dibenzofuran 10.0 10.0 10.0 10.0
2,3,4,6, 7,8-Hexachloro("C,,)dibenzofuran 10.0 10.0 10.0 10.0
1,2,3,4,6,7,8-Heptach loro("C,,)d i benzofuran 10.0 10.0 10.0 10.0
1,2,3,4,7,8,9-Heptachloro("C,,)dibenzofuran 10.0 10.0 10.0 10.0
Octachloro("C,,)dibenzofuran 20.0 20.0 20.0 20.0
SYRINGE SPIKE:
MASS-LABELLED PCDFs
1,2,3,4,6-Pentach loro("C,,)d i benzofura n 10.0 10.0 10.0 10.0
1,2,3,4,6,9-Hexachloro("C ,)dibenzofuran 10.0 10.0 10.0 10.0
1,2,3,4,6,8,9-Heptach loro("C,,)d i benzofuran 10.0 10.0 10.0 10.0
SAMPLING SPIKE:
46
DF-CVS-B10

DF·B10-CSS CS5 200 µL
DF·B10·CS7 CS7 200 µL
DF·B10-CS8 css 200 µL
DF·B10·CS10 CS10 200 µL
DF·B10-CS11 CS11 200 µL
*FOR SUPPORT SOLUTIONS, see DF-ST-B, DF-LCS-A, DF-IS-B, and DF-IS-I (and their dilutions).
DF-B10- DF-B10- DF-B10- DF-B10- DF-B10- DF-B10- DF-B10-

css CS6 CS7 CSB CS9 CS10 CS11
(ng/ml) (ng/ml) (ng/ml) (ng/ml) (ng/ml) (ng/ml) (ng/ml)
2.00 5.00 10.0 20.0 50.0 100 200
2.00 5.00 10.0 20.0 50.0 100 200
2.00 5.00 10.0 20.0 50.0 100 200
2.00 5.00 10.0 20.0 50.0 100 200
2.00 5.00 10.0 20.0 50.0 100 200
4.00 10.0 20.0 40.0 100 200 400
4.00 10.0 20.0 40.0 100 200 400
4.00 10.0 20.0 40.0 100 200 400
4.00 10.0 20.0 40.0 100 200 400
10.0 25.0 50.0 100 250 500 1000
2.00 5.00 10.0 20.0 50.0 100 200

2.00 5.00 10.0 20.0 50.0 100 200
2.00 5.00 10.0 20.0 50.0 100 200
2.00 5.00 10.0 20.0 50.0 100 200
2.00 5.00 10.0 20.0 50.0 100 200
2.00 5.00 10.0 20.0 50.0 100 200
4.00 10.0 20.0 40.0 100 200 400
4.00 10.0 20.0 40.0 100 200 400
4.00 10.0 20.0 40.0 100 200 400
4.00 10.0 20.0 40.0 100 200 400
4.00 10.0 20.0 40.0 100 200 400
4.00 10.0 20.0 40.0 100 200 400
10.0 25.0 50.0 100 250 500 1000
10.0 10.0 10.0 10.0 10.0 10.0 10.0

10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0
20.0 20.0 20.0 20.0 20.0 20.0 20.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0

10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0
20.0 20.0 20.0 20.0 20.0 20.0 20.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0

10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0

10.0 10.0 10.0 10.0 10.0 10.0 10.0
47
DF-CVS-C10

DF-CVS•C10 PCDD & PCDF Calibration Solutions 1 kit (7 ampoules)
CS1 / CS2/ CS3/ CS4/ CS5/CS6/CS7
DF-C10-CS1 CS1 200 µL

DF-C10-CS2 CS2 200 µL
DF·C10·CS3 CS3 200 µL
DF-C10-CS1 DF-C10-CS2 DF-C10-CS3

NATIVE PCDDs & PCDFs (ng/ml) (ng/ml) (ng/ml)
1,3,6,8-Tetrachlorodibenzo-p-dioxin 0.100 0.500 2.00
1,2,3,7,8-Pentachlorodibenzo-p-dioxin 0.100 0.500 2.00
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 0.200 1.00 4.00
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 0.200 1.00 4.00
Octachlorodibenzo-p-dioxin 0.500 2.50 10.0
1,3,6,8-Tetrachlorodibenzofuran 0.100 0.500 2.00

1,2,3,7,8-Pentachlorodibenzofuran 0.100 0.500 2.00
1,2,3,4,7,8-Hexachlorodibenzofuran 0.200 1.00 4.00
1,2,3,4,6,7,8-Heptachlorodibenzofuran 0.200 1.00 4.00
Octachlorodibenzofuran 0.500 2.50 10.0
EXTRACTION SPIKE: MASS-LABELLED PCDDs & PCDFs

1,3,6,8-Tetrachloro("C,,)dibenzo-p-dioxin 10.0 10.0 10.0
1,2,3,7,8-Pentachloro("C,,)dibenzo-p-dioxin 10.0 10.0 10.0
1,2,3,4,7,8-Hexachloro("C,)dibenzo-p-dioxin 10.0 10.0 10.0
1,2,3,4,6,7,8-Heptachloro("C,,)dibenzo-p-dioxin 10.0 10.0 10.0
Octachloro("C,,)dibenzo-p-dioxin 20.0 20.0 20.0
2,3,7,8-Tetrachloro("C,,)dibenzofuran 10.0 10.0 10.0

1,2,3,7,8-Pentachloro("C,,)dibenzofuran 10.0 10.0 10.0
1,2,3,4,7,8-Hexachloro("C,)dibenzofuran 10.0 10.0 10.0
1,2,3,4,6,7,8-Heptachloro("C,,)dibenzofuran 10.0 10.0 10.0
1,2,3,4,7,8,9-Heptachloro("C,,)dibenzofuran 10.0 10.0 10.0
Octachloro("C,,)dibenzofuran 20.0 20.0 20.0
SYRINGE SPIKE: MASS-LABELLED PCDDs

1,2,4,7,8-Pentachloro("C,,)dibenzo-p-dioxin 10.0 10.0 10.0
1,2,3,4,6,8-Hexachloro(''C,,)dibenzo-p-dioxin 10.0 10.0 10.0
1,2,3,4,6,7,9-Heptachloro("C,,)dibenzo-p-dioxin 10.0 10.0 10.0
SAMPLING SPIKE
48
DF-CVS-C10

DF·C10-CS4 CS4 200 µL
DF-C10-CSS css 200 µL
DF·C10·CS6 CS6 200 µL
DF·C10-CS7 CS7 200 µL
*FOR SUPPORT SOLUTIONS, see DF-ST-C, DF-LCS-B, DF-IS-J, and DF-SS-A (and their dilutions).
DF-C10-CS4 DF-C10-CSS DF-C10-CS6 DF-C10-CS7

NATIVE PCDDs & PCDFs (ng/mL) (ng/mL) (ng/mL) (ng/mL)
1,3,6,8-Tetrachlorodibenzo-p-dioxin 10.0 50.0 200 500
1,2,3,7,8-Pentachlorodibenzo-p-dioxin 10.0 50.0 200 500
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 20.0 100 400 1000
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 20.0 100 400 1000
Octachlorodibenzo-p-dioxin 50.0 250 1000 2500
1,3,6,8-Tetrachlorodibenzofuran 10.0 50.0 200 500

1,2,3,7,8-Pentachlorodibenzofuran 10.0 50.0 200 500
2,3,4,7,8-Pentachlorodibenzofuran 10.0 50.0 200 500
1,2,3,4,7,8-Hexachlorodibenzofuran 20.0 100 400 1000
1,2,3,4,6,7,8-Heptachlorodibenzofuran 20.0 100 400 1000
Octachlorodibenzofuran 50.0 250 1000 2500
EXTRACTION SPIKE: MASS-LABELLED PCDDs & PCDFs

1,3,6,8-Tetrachloro("C,,)dibenzo-p-dioxin 10.0 10.0 10.0 10.0
1,2,3,4,7,8-Hexachloro("C,)dibenzo-p-dioxin 10.0 10.0 10.0 10.0
1,2,3,4,6,7,8-Heptachloro("C,,)dibenzo-p-dioxin 10.0 10.0 10.0 10.0
Octachloro( 1'C 12)dibenzo-p-dioxin 20.0 20.0 20.0 20.0

1,2,3,4,7,8-Hexachloro("C,)dibenzofuran 10.0 10.0 10.0 10.0
Octachloro(''C,,)dibenzofuran 20.0 20.0 20.0 20.0
SYRINGE SPIKE: MASS-LABELLED PCDDs

1,2,3,4,6,8-Hexachloro(1'C 12)dibenzo-p-dioxin 10.0 10.0 10.0 10.0
1,2,3,4,6,7,9-Heptachloro("C,,)dibenzo-p-dioxin 10.0 10.0 10.0 10.0
SAMPLING SPIKE
49
DFP-CVS-B10

DFP-CVS-810 PCDD/PCDF/PCB Calibration Solutions 1 kit (7 ampoules)
CS1/ CS2/CS3/CS4/CS5/CS6/CS7
DFP·B10-CS1 CS1 200 µL

DFP·B10·CS3 CS3 200 µL
DFP-B10-CS1 DFP-B10-CS2 DFP-B10-CS3

NATIVE PCDDs & PCDFs (ng/ml) (ng/ml) (ng/ml)
1,3,6,8-Tetrach lorodibenzo-p-dioxi n 0.100 0.500 2.00
1,2,8,9-Tetrach lorodibenzo-p-dioxi n 0.100 0.500 2.00
2,3, 7,8-Tetrach lorodibenzo-p-dioxi n 0.100 0.500 2.00
1,2,3,7,8-Pentachlorodibenzo-p-d ioxin 0.100 0.500 2.00
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxi n 0.200 1.00 4.00
1,2,3,4,6,7,8-Heptach lorodibenzo-p-dioxin 0.200 1.00 4.00
1,3,6,8-Tetrach lorodibenzofuran 0.100 0.500 2.00
2, 3,7,8-Tetrach lorodibenzofuran 0.100 0.500 2.00
2,3,4, 7,8-Pentachlorodibenzofuran 0.100 0.500 2.00
1,2,3,4,6,7,8-Heptach lorodibenzofuran 0.200 1.00 4.00
1,2,3,4,7,8, 9-Heptach lorodibenzofuran 0.200 1.00 4.00
NATIVE PCBs /UPAC
3,3',4,4'-Tetrachlorobiphenyl 77 0.200 1.00 4.00
3,4,4', 5-Tetrach lorobi phenyl 81 0.200 1.00 4.00
2,3,3',4,4'-Pentachlorobiphenyl 105 0.200 1.00 4.00
2,3,4,4',5-Pentachlorobiphenyl 114 0.200 1.00 4.00
2,3',4,4',5-Pentachlorobiphenyl 118 0.200 1.00 4.00
2',3,4,4',5-Pentachlorobiphenyl 123 0.200 1.00 4.00
2,3,3',4,4',5-Hexachlorobiphenyl 156 0.200 1.00 4.00
2,3,3',4,4',5'-Hexachlorobiphenyl 157 0.200 1.00 4.00
2,3',4,4',5,5'-Hexachlorobiphenyl 167 0.200 1.00 4.00
2,2',3,3',4,4',5-Heptachlorobiphenyl 170 0.200 1.00 4.00
2,2',3,4,4',5,5'-Heptachlorobiphenyl 180 0.200 1.00 4.00
2,3,3',4,4',5,5'-Heptachlorobiphenyl 189 0.200 1.00 4.00
EXTRACTION SPIKE: "C PCDDs/PCDFs/PCBs
1,2,3,7,8-Pentachloro("C,,)dibenzo-p-dioxi n 10.0 10.0 10.0
1,2,3,4,7,8-Hexachloro("C,,)dibenzo-p-dioxin 10.0 10.0 10.0
1,2,3,4,6,7,8-Heptach loro("C,,)di benzo-p-dioxi n 10.0 10.0 10.0
Octachloro("C,,)dibenzo-p-dioxin 20.0 20.0 20.0
2,3, 7,8-Tetrach loro("C,,)d ibenzofuran 10.0 10.0 10.0
2, 3,4,7,8-Pentachloro("C,,)dibenzofuran 10.0 10.0 10.0
1,2,3,4,7,8-Hexachloro("C,,)dibenzofuran 10.0 10.0 10.0
2,3,4,6, 7,8-Hexachloro(''C,,)dibenzofuran 10.0 10.0 10.0
1,2,3,4,6,7,8-Heptach loro("C,,)di benzofuran 10.0 10.0 10.0
1,2,3,4,7,8, 9-Heptach loro("C,,)di benzofuran 10.0 10.0 10.0
Octachloro("C,,)dibenzofuran 20.0 20.0 20.0
3,3',4,4'-Tetrachloro("C,,)biphenyl 77L 10.0 10.0 10.0
3,4,4',5-Tetrachloro("C,,)biphenyl BIL 10.0 10.0 10.0
2,3,3',4,4'-Pentachloro("C,,)biphenyl 105L 10.0 10.0 10.0
2,3,4,4',5-Pentachloro("C,,)biphenyl 114L 10.0 10.0 10.0
2,3',4,4',5-Pentachloro("C,,)biphenyl 118L 10.0 10.0 10.0
2' ,3,4,4' ,5-Pentach loro("C,,)bi phenyl 123L 10.0 10.0 10.0
3,3' ,4,4' ,5-Pentach loro("C,,)bi phenyl 126L 10.0 10.0 10.0
2,3,3',4,4',5-Hexachloro("C,,)biphenyl 156L 10.0 10.0 10.0
2,3,3',4,4',5'-Hexachloro(''C,,)biphenyl 157L 10.0 10.0 10.0
2,3',4,4',5,5'-Hexachloro("C,,)biphenyl 167L 10.0 10.0 10.0
2,2' ,3,3 ',4,4', 5-Heptachloro("C,,)biphenyl 170L 10.0 10.0 10.0
2,2' ,3,4,4', 5,5' -Heptachloro("C,,)biphenyl 180L 10.0 10.0 10.0
2,3,3',4,4',5,5'-Heptachloro("C,,)biphenyl 189L 10.0 10.0 10.0
SYRINGE SPIKE: "C PCDDs & PCBs
1,3,7,8-Tetrach loro("C,,)dibenzo-p-dioxin 10.0 10.0 10.0
1,2,4,7,8-Pentachloro("C,,)dibenzo-p-dioxi n 10.0 10.0 10.0
1,2,3,4,6,8-Hexachloro(''C,,)dibenzo-p-dioxin 10.0 10.0 10.0
1,2,3,4,6,7,9-Heptach loro("C,,)di benzo-p-dioxi n 10.0 10.0 10.0
2,3',4',5-Tetrachloro("C,,)biphenyl 70L 10.0 10.0 10.0
2,2',3,4,4',5'-Hexachloro("C,,)biphenyl 138L 10.0 10.0 10.0
2,2',3,3',5,5',6-Heptachloro("C,,)biphenyl 178L 10.0 10.0 10.0
SAMPLING SPIKE
1,2,3,4-Tetrach loro("C,,)dibenzo-p-dioxin 10.0 10.0 10.0
so
DFP-CVS-B10

DFP·B10-CSS css 200 µL
DFP·B10·CS6 CS6 200 µL
*FOR PCDD/PCDF/PCB SUPPORT SOLUTIONS, see DFP-LCS•B, DFP-IS-B10, and DFP-SS-A10 (and their dilutions).
*FOR PCDD/PCDF SUPPORT SOLUTIONS, see DF-ST•C. DF-LCS•B, DF-15-J, and DF-SS·A (and their dilutions).
*FOR PCB SUPPORT SOLUTIONS, see pages 96 and 98.
DFP-B10-CS4 DFP-B10-CSS DFP-B10-CS6 DFP-B10-CS7

NATIVE PCDDs & PCDFs (ng/mL) (ng/mL) (ng/mL) (ng/mL)
1,3,6,8-Tetrachlorod ibenzo-p-dioxin 10.0 50.0 200 500
1,2,3,7,8-Pentachlorodi benzo-p-dioxi n 10.0 50.0 200 500
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxi n 20.0 100 400 1000
Octachlorodibenzo-p-dioxin 50.0 250 1000 2500
1,3,6,8-Tetrachlorod ibenzofuran 10.0 50.0 200 500
1,2,3,7,8-Pentachlorodi benzofuran 10.0 50.0 200 500
2,3,4,7,8-Pentachlorodi benzofuran 10.0 50.0 200 500
Octachlorodibenzofuran 50.0 250 1000 2500
NATIVE PCSs IUPAC
3,3',4,4'-Tetrachlorobiphenyl 77 20.0 100 400 1000
3,4,4', 5-Tetrachlorobiphenyl 81 20.0 100 400 1000
2,3,3',4,4'-Pentachlorobiphenyl 105 20.0 100 400 1000
2,3,4,4',5-Pentachlorobiphenyl 114 20.0 100 400 1000
2,3 ',4,4', 5-Pentachlorobi phenyl 118 20.0 100 400 1000
2',3,4,4',5-Pentachlorobiphenyl 123 20.0 100 400 1000
3,3',4,4',5-Pentachlorobiphenyl 126 20.0 100 400 1000
2,3,3 ',4,4', 5-Hexachlorobiphenyl 156 20.0 100 400 1000
2,3,3 ',4,4', 5'-Hexachlorobiphenyl 157 20.0 100 400 1000
2,3',4,4',5,5'-Hexachlorobiphenyl 167 20.0 100 400 1000
2,2',3,3',4.4',5-Heptachlorobiphenyl 170 20.0 100 400 1000
2,2',3,4,4',5,5'-Heptachlorobiphenyl 180 20.0 100 400 1000
2,3,3',4,4',5,5'-Heptachlorobiphenyl 189 20.0 100 400 1000
EXTRACTION SPIKE: "C PCDDs/PCDFs/PCBs
1,3,6,8-Tetrachloro("C,)dibenzo-p-dioxin 10.0 10.0 10.0 10.0
2,3,7,8-Tetrachloro("C,,)dibenzo-p-d ioxin 10.0 10.0 10.0 10.0
1,2,3,7,8-Pentach loro("C,,)d ibenzo-p-dioxin 10.0 10.0 10.0 10.0
1,2,3,4,6,7,8-Heptachloro("C,)dibenzo-p-dioxin 10.0 10.0 10.0 10.0
Octachloro("C,,)dibenzo-p-dioxin 20.0 20.0 20.0 20.0
1,2,3,7,8-Pentach loro("C,,)d ibenzofuran 10.0 10.0 10.0 10.0
2,3,4,7,8-Pentach loro("C,,)d ibenzofuran 10.0 10.0 10.0 10.0
1,2,3,4,7,8,9-Heptachloro("C,)dibenzofuran 10.0 10.0 10.0 10.0
Octachloro("C,,)dibenzofuran 20.0 20.0 20.0 20.0
3,3',4,4'-Tetrachloro("C,,)biphenyl 77L 10.0 10.0 10.0 10.0
3,4,4', 5-Tetrachloro("C,,)biphenyl BIL 10.0 10.0 10.0 10.0
2,3,3',4,4'-Pentachloro("C,,)biphenyl 105L 10.0 10.0 10.0 10.0
2,3,4,4',5-Pentachloro("C,)biphenyl 114L 10.0 10.0 10.0 10.0
2,3',4,4',5-Pentachloro("C,)biphenyl 118L 10.0 10.0 10.0 10.0
2',3,4,4',5-Pentachloro("C,,)biphenyl 123L 10.0 10.0 10.0 10.0
3,3',4,4',5-Pentachloro("C,,)biphenyl 126L 10.0 10.0 10.0 10.0
2,3,3',4,4',5-Hexachloro("C,,)biphenyl 156L 10.0 10.0 10.0 10.0
2,3,3',4,4',5'-Hexachloro("C,,)biphenyl 157L 10.0 10.0 10.0 10.0
2,3 ',4,4', 5,5'-Hexachloro("C,,)bi phenyl 167L 10.0 10.0 10.0 10.0
3,3',4,4',5,5'-Hexachloro("C,)biphenyl 169L 10.0 10.0 10.0 10.0
2,2',3,3',4,4',5-Heptachloro("C,,)biphenyl 170L 10.0 10.0 10.0 10.0
2,2',3,4,4',5,5'-Heptachloro("C,,)biphenyl 180L 10.0 10.0 10.0 10.0
2,3,3',4,4',5,5'-Heptachloro("C,,)biphenyl 189L 10.0 10.0 10.0 10.0
SYRINGE SPIKE: "C PCDDs & PCBs
1,2,3,4,6,7,9-Heptachloro("C,)dibenzo-p-dioxin 10.0 10.0 10.0 10.0
2,3',4',5-Tetrachloro("C,,)biphenyl 70L 10.0 10.0 10.0 10.0
2,2',3,4,4',5'-Hexachloro("C,,)biphenyl 138L 10.0 10.0 10.0 10.0
SAMPLING SPIKE
51
NK-CVS-J

NK-CVS-J PCDD & PCDF Calibration Solutions 1 kit
CS1-J/CS2-J/CS3-J/CS4-J/CS5-J/CS6-J (6 ampoules)
NK•CS1·J CS1-J 200 µL
NK-CS2·J CS2-J 200 µL
NK-CS3-J CS3-J 200 µL
NK•CS4·J CS4-J 200 µL
NK-CSS·J CS5-J 200 µL
NK-CS6-J CS6-J 200 µL
*FOR SUPPORT SOLUTIONS, see NK-LCS-T, NK-IS-J4, and NK-IS-JS.
NK-CS1-J NK-CS2-J NK-CS3-J NK-CS4-J NK-CSS-J NK-CS6-J

NATIVE PCDDs & PCDFs (ng/mL) (ng/mL) (ng/mL) (ng/mL) (ng/mL) (ng/mL)
1,3,6,8-Tetrachlorodibenzo-p-dioxin 0.100 0.400 2.00 10.0 50.0 100
1,3,7,9-Tetrachlorodibenzo-p-dioxin 0.100 0.400 2.00 10.0 50.0 100
2,3, 7,8-Tetrach lorodibenzo-p-d ioxi n 0.100 0.400 2.00 10.0 50.0 100
1,2,3, 7,8-Pentachlorodibenzo-p-dioxin 0.100 0.400 2.00 10.0 50.0 100
1,2,3,4, 7,8-Hexachlorodibenzo-p-dioxin 0.200 0.800 4.00 20.0 100 200
1,2,3,6, 7,8-Hexachlorodibenzo-p-dioxin 0.200 0.800 4.00 20.0 100 200
1,2,3, 7,8,9-Hexachlorodibenzo-p-dioxin 0.200 0.800 4.00 20.0 100 200
1,2,3,4,6, 7,8-Heptach lorodibenzo-p-d ioxi n 0.200 0.800 4.00 20.0 100 200
Octachlorodibenzo-p-dioxin 0.500 2.00 10.0 50.0 250 500
1,2,7,8-Tetrachlorodibenzofuran 0.100 0.400 2.00 10.0 50.0 100

2,3, 7,8-Tetrachlorodibenzofuran 0.100 0.400 2.00 10.0 50.0 100
1,2,3, 7,8-Pentachlorodibenzofuran 0.100 0.400 2.00 10.0 50.0 100
2,3,4, 7,8-Pentach lo rod i benzofu ran 0.100 0.400 2.00 10.0 50.0 100
1,2,3,4, 7,8-Hexachlorodibenzofuran 0.200 0.800 4.00 20.0 100 200
1,2,3, 7,8,9-Hexachlorodibenzofuran 0.200 0.800 4.00 20.0 100 200
1,2,3,4,6,7,8-Heptachlorodibenzofuran 0.200 0.800 4.00 20.0 100 200
1,2,3,4, 7,8,9-Heptachlorodibenzofuran 0.200 0.800 4.00 20.0 100 200
Octachlorodibenzofuran 0.500 2.00 10.0 50.0 250 500

2,3,7,8-Tetrachloro("C,)dibenzo-p-dioxin 20.0 20.0 20.0 20.0 20.0 20.0
1,2,3,7,8-Pentachloro("C,)dibenzo-p-dioxin 20.0 20.0 20.0 20.0 20.0 20.0
1,2,3,4,7,8-Hexachloro("C,,)dibenzo-p-dioxin 20.0 20.0 20.0 20.0 20.0 20.0
1,2,3,6,7,8-Hexachloro("C,)dibenzo-p-dioxin 20.0 20.0 20.0 20.0 20.0 20.0
1,2,3,4,6,7,8-Heptachloro("C,)dibenzo-p-dioxin 20.0 20.0 20.0 20.0 20.0 20.0
Octachloro("C,)dibenzo-p-dioxin 40.0 40.0 40.0 40.0 40.0 40.0
2,3,7,8-Tetrachloro("C,)dibenzofuran 20.0 20.0 20.0 20.0 20.0 20.0

2,3,4,7,8-Pentachloro("C,,)dibenzofuran 20.0 20.0 20.0 20.0 20.0 20.0
1,2,3,4,7,8-Hexachloro("C,)dibenzofuran 20.0 20.0 20.0 20.0 20.0 20.0
1,2,3,6,7,8-Hexachloro("C,,)dibenzofuran 20.0 20.0 20.0 20.0 20.0 20.0
1,2,3,4,6,7,8-Heptachloro("C,)dibenzofuran 20.0 20.0 20.0 20.0 20.0 20.0
1,2,3,4,7,8,9-Heptachloro("C,)dibenzofuran 20.0 20.0 20.0 20.0 20.0 20.0
Octachloro("C,)dibenzofuran 40.0 40.0 40.0 40.0 40.0 40.0
INTERNAL STANDARDS
1,2,3,4-Tetrachloro("C,,)dibenzo-p-dioxin 20.0 20.0 20.0 20.0 20.0 20.0
1,2,3,7,8,9-Hexachloro("C,,)dibenzo-p-<lioxin 20.0 20.0 20.0 20.0 20.0 20.0
1,2,3,7,8-Pentachloro("C,,)dibenzofuran 20.0 20.0 20.0 20.0 20.0 20.0

52
DF-LCS-A
Support solutions for DF-CVS-A10 and DF-CVS-B10.

DF·LCS·A Mass-Labelled PCDD/PCDFSolution/Mixture 1.2 ml
DF-LCS-A200 Mass-Labelled PCDD/PCDFSolution/Mixture 1.2 ml
DF·LCS-A40 Mass-Labelled PCDD/PCDFSolution/Mixture 1.2 ml
DF-LCS-A DF-LCS-A200 DF-LCS-A40

MASS-LABELLED PCDDs (ng/mL) (ng/mL) (ng/mL)
1,3,6,8-Tetrach loro("C,,)d i benzo-p-dioxi n 1000 200 40.0

1,2,3,7,8-Pentachloro("C,,)dibenzo-p-dioxin 1000 200 40.0
1,2,3,4,7,8-Hexachloro("C,,)dibenzo-p-d ioxi n 1000 200 40.0
1,2,3,6,7,8-Hexachloro("C,,)dibenzo-p-dioxin 1000 200 40.0
1,2,3,4,6,7,8-Heptach loro("C,,)d i benzo-p-dioxin 1000 200 40.0
Octachloro("C,,)dibenzo-p-dioxin 2000 400 80.0
MASS-LABELLED PCDFs
1,3,6,8-Tetrachloro("C,,)dibenzofuran 1000 200 40.0

2,3,7,8-Tetrach loro("C,,)d i benzofu ran 1000 200 40.0
1,2,3,7,8-Pentachloro("C,,)dibenzofuran 1000 200 40.0
2,3,4, 7,8-Pentach loro("C,,)d i benzofura n 1000 200 40.0
1,2,3,4,7,8-Hexachloro("C,,)dibenzofuran 1000 200 40.0
2,3,4,6, 7,8-Hexachloro("C,,)dibenzofuran 1000 200 40.0
1,2,3,4,6,7,8-Heptach loro("C,,)d i benzofuran 1000 200 40.0
Octachloro("C,,)dibenzofuran 2000 400 80.0
53
DF-LCS-B
Support solutions for DF-CVS-A10, DF-CVS-B10, DF-CVS-C10, and DFP-CVS-B10.

DF-LCS-B Mass-Labelled PCDD/PCDFSolution/Mixture 1.2 ml
DF-LCS-B200 Mass-Labelled PCDD/PCDFSolution/Mixture 1.2 ml
DF-LCS-B40 Mass-Labelled PCDD/PCDFSolution/Mixture 1.2 ml
DF-LCS-B DF-LCS-B200 DF-LCS-B40

MASS-LABELLED PCDDs {ng/mL) {ng/mL) {ng/mL)
1,3,6,8-Tetrachloro("C,,)dibenzo-p-dioxin 1000 200 40.0

1,2,3,7,8-Pentachloro("C,,)dibenzo-p-dioxin 1000 200 40.0
1,2,3,4,7,8-Hexach loro("C,,)dibenzo-p-d ioxi n 1000 200 40.0
1,2,3,4,6,7,8-Heptach loro("C,,)d i benzo-p-dioxin 1000 200 40.0
MASS-LABELLED PCDFs
2,3,7,8-Tetrach loro("C,,)d i benzofu ran 1000 200 40.0

2,3,4,7,8-Pentach loro("C,,)d i benzofura n 1000 200 40.0
1,2,3,4,7,8-Hexach loro("C,,)dibenzofuran 1000 200 40.0
2,3,4,6, 7,8-Hexach loro("C,,)dibenzofuran 1000 200 40.0
1,2,3,4,7,8,9-Heptachloro("C,,)dibenzofuran 1000 200 40.0
54
DF-LCS-C
Support solutions for DF-CVS-A10, DF-CVS-B10, DF-CVS-C10, and DFP-CVS-B10.

DF-LCS-C Mass-Labelled PCDD/PCDFSolution/Mixture 1.2 ml
DF-LCS·C200 Mass-Labelled PCDD/PCDFSolution/Mixture 1.2 ml
DF-LCS-C40 Mass-Labelled PCDD/PCDFSolution/Mixture 1.2 ml
DF-LCS-C DF-LCS-C200 DF-LCS-C40

MASS-LABELLED PCDDs {ng/mL) {ng/mL) (ng/mL)

1,2,3,7,8-Pentachloro("C )dibenzo-p-dioxin
12 1000 200 40.0
1,2,3,6,7,8-Hexachloro("C,,)dibenzo-p-d ioxi n 1000 200 40.0
1,2,3,4,6,7,8-Heptach loro("C 12)d i benzo-p-dioxin 1000 200 40.0
MASS-LABELLED PCDFs
2,3,7,8-Tetrach loro("C 12)d i benzofu ran 1000 200 40.0

2,3,4,7,8-Pentach loro("C 12)d i benzofura n 1000 200 40.0
2,3,4,6, 7,8-Hexachloro("C,,)dibenzofuran 1000 200 40.0
1,2,3,4,7,8,9-Heptachloro("C )dibenzofuran
12 1000 200 40.0
55
MASS-LABELLED PCDDs & PCDFs: SOLUTION/MIXTURES
NOTE CONCENTRATIONS: DS-1000 and FS-1000= µg/ml

NK-LCS-Oand NK-LCS-T= ng/ml

DS-1000 Mass-Labelled PCDD Solution/Mixture 1.2 ml
FS-1000 Mass-Labelled PCDFSolution/Mixture 1.2 ml
NK-LCS-O Mass-Labelled PCDD/PCDFSolution/Mixture 1.2 ml
NK-LCS·T Mass-Labelled PCDD/PCDFSolution/Mixture 1.2 ml
DS-1000 FS-1000 NK-LCS-O NK-LCS-T

MASS-LABELLED PCDDs {l.1g/mL) (1,1g/mL) (ng/mL) {ng/mL)
2,3,7,8-Tetrach loro("C,,)d i benzo-p-dioxi n 1.00 100 40.0

1,2,3,7,8-Pentachloro("C )dibenzo-p-dioxin
12 1.00 100 40.0
1,2,3,4,7,8-Hexachloro("C,,)dibenzo-p-dioxin 1.00 100 40.0
1,2,3,6,7,8-Hexach loro("C,,)dibenzo-p-d ioxi n 1.00 100 40.0
1,2,3,4,6,7,8-Heptach loro("C 12)d i benzo-p-dioxin 1.00 100 40.0
Octachloro("C,,)dibenzo-p-dioxin 2.00 200 80.0
MASS-LABELLED PCDFs
2,3,7,8-Tetrach loro("C 12)d i benzofu ran 1.00 100 40.0

1,2,3,7,8-Pentachloro("C )dibenzofuran
12 1.00 100
2,3,4,7,8-Pentach loro("C 12)d i benzofura n 1.00 100 40.0
1,2,3,4,7,8-Hexachloro("C, 2)dibenzofuran 1.00 100 40.0
1,2,3,6,7,8-Hexachloro("C,,)dibenzofuran 1.00 100 40.0
1,2,3,7,8,9-Hexach loro("C,,)dibenzofuran 1.00 100
2,3,4,6,7,8-Hexach loro("C, 2)dibenzofuran 1.00 100 40.0
1,2,3,4,6,7,8-Heptachloro("C )dibenzofuran
12 1.00 100 40.0
1,2,3,4,7,8,9-Heptach loro("C,,)d i benzofuran 1.00 100 40.0
Octachloro("C, 2)dibenzofuran 200 80.0
56
MASS-LABELLED PCDDs & PCDFs:SOLUTION/MIXTURES
Support solutions for DF-CVS-A10 and DF-CVS-810.

DF·IS·A Mass-Labelled PCDD Internal Standard Solution 1.2 ml
DF-IS-A200 Mass-Labelled PCDD Internal Standard Solution 1.2 ml
DF-IS-A40 Mass-Labelled PCDD Internal Standard Solution 1.2 ml
DF-IS-A DF-IS-A200 DF-IS-A40

MASS-LABELLED PCDD (µg/mL) (ng/mL) (ng/mL)
1,2,3,4-Tetrachloro("C,,)dibenzo-p-dioxin 1.00 200 40.0
DF-15-B Mass-Labelled PCDD/PCDFInternal Standard Solution 1.2 ml

DF·IS·B200 Mass-Labelled PCDD/PCDFInternal Standard Solution 1.2 ml
DF-15-B40 Mass-Labelled PCDD/PCDFInternal Standard Solution 1.2 ml
DF-IS-B DF-IS-B200 DF-IS-B40

MASS-LABELLED PCDD/PCDF (1.19/mL) (ng/mL) (ng/mL)

1,2,3,4-Tetrachloro("C,,)dibenzofuran 1.00 200 40.0
DF-15-C Mass-Labelled PCDD/PCDFInternal Standard Solution 1.2 ml

DF·IS·C200 Mass-Labelled PCDD/PCDFInternal Standard Solution 1.2 ml
DF-IS-C40 Mass-Labelled PCDD/PCDFInternal Standard Solution 1.2 ml
DF-IS-C DF-IS-C200 DF-IS-C40

MASS-LABELLED PCDD/PCDF (1.19/mL) (ng/mL) (ng/mL)

57
Support solutions for DF-CVS-A10 and DF-CVS-B10.

DF·IS·D Mass-Labelled PCDD/PCDFInternal Standard Solution 1.2 ml
DF·IS·D200 Mass-Labelled PCDD/PCDFInternal Standard Solution 1.2 ml
DF·IS·D40 Mass-Labelled PCDD/PCDFInternal Standard Solution 1.2 ml
DF-IS-D DF-IS-D200 DF-IS-D40

MASS-LABELLED PCDD/PCDF (Jig/ml) (ng/mL) (ng/mL)
1,3,6,8-Tetrach loro("C,,)d i benzo-p-dioxi n 1.00 200 40.0

DF-15-E Mass-Labelled PCDFInternal Standard Solution 1.2 ml
DF-IS-E200 Mass-Labelled PCDFInternal Standard Solution 1.2 ml
DF·IS·E40 Mass-Labelled PCDFInternal Standard Solution 1.2 ml
DF-IS-E DF-IS-E200 DF-IS-E40

MASS-LABELLED PCDFs (Jig/ml) (ng/mL) (ng/mL)
1,3,6,8-Tetrach loro("C,,)d i benzofu ran 1.00 200 40.0

1,2,3,4,6,8,9-Heptach loro("C,,)d i benzofuran 1.00 200 40.0
DF-15-F Mass-Labelled PCDFInternal Standard Solution 1.2 ml
DF-IS-F200 Mass-Labelled PCDFInternal Standard Solution 1.2 ml
DF·IS·F40 Mass-Labelled PCDFInternal Standard Solution 1.2 ml
DF-IS-F DF-IS-F200 DF-IS-F40

MASS-LABELLED PCDFs (Jig/ml) (ng/mL) (ng/mL)
1,2,7,8-Tetrach loro("C,,)d i benzofu ran 1.00 200 40.0

1,2,3,4,6,8,9-Heptachloro("C,,)dibenzofuran 1.00 200 40.0
58
MASS-LABELLED PCDDs & PCDFs:SOLUTION/MIXTURES
Support solutions for DF-CVS-A10 and DF-CVS-810.

DF·IS·G Mass-Labelled PCDFInternal Standard Solution 1.2 ml
DF-IS-G200 Mass-Labelled PCDFInternal Standard Solution 1.2 ml

DF-IS-G40 Mass-Labelled PCDFInternal Standard Solution 1.2 ml
DF-IS-G DF-IS-G200 DF-IS-G40

MASS-LABELLED PCDFs (µg/mL) (ng/mL) (ng/mL)
1,2,3,4,6-Pentachloro("C,,)dibenzofuran 1.00 200 40.0

DF-15-H Mass-Labelled PCDFInternal Standard Solution 1.2 ml

DF-IS-H200 Mass-Labelled PCDFInternal Standard Solution 1.2 ml
DF·IS·H40 Mass-Labelled PCDFInternal Standard Solution 1.2 ml
DF-IS-H DF-IS-H200 DF-IS-H40

1,2,3,4,6,9-Hexachloro("C,,)dibenzofuran 1.00 200 40.0

DF-15-1 Mass-Labelled PCDFInternal Standard Solution 1.2 ml

DF-IS-1 DF-IS-1200 DF-IS-140


1,2,3,4,6-Pentachloro("C,,)dibenzofuran 1.00 200 40.0
1,2,3,4,6,9-Hexachloro("C,,)dibenzofu ran 1.00 200 40.0
1,2,3,4,6,8,9-Heptach loro("C,,)di benzofura n 1.00 200 40.0
59
Support solutions for DFP-CVS-B10 and DF-CVS-C10.

DF·IS·J Mass-Labelled PCDD Internal Standard Solution 1.2 ml
DF·IS·J100 Mass-Labelled PCDD Internal Standard Solution 1.2 ml
DF·IS·J20 Mass-Labelled PCDD Internal Standard Solution 1.2 ml
DF-15-J DF-IS-J100 DF-IS-J20

MASS-LABELLED PCDDs (ng/mL) (ng/mL) (ng/mL)
1,3,7,8-Tetrachloro("C,,)dibenzo-p-dioxin 1000 100 20.0

1,2,4,7,8-Pentach loro("C,,)d i benzo-p-d ioxin 1000 100 20.0
1,2,3,4,6,7,9-Heptach loro("C 12)d i benzo-p-dioxin 1000 100 20.0
DF-SS-A Mass-Labelled PCDDSampling Spike Solution 1.2 ml

DF-SS-A100 Mass-Labelled PCDDSampling Spike Solution 1.2 ml
DF-SS-A20 Mass-Labelled PCDDSampling Spike Solution 1.2 ml
DF-SS-A DF-SS-A100 DF-SS-A20

MASS-LABELLED PCDD {ng/mL) {ng/mL) {ng/mL)
1,2,3,4-Tetrachloro("C,,)d i benzo-p-dioxi n 1000 100 20.0

MDF-1278•1 1.2 ml
1,2,7,8-Tetrachloro("C,,)dibenzofuran 1.00 µg/ml
MDF-12346-1 1.2 ml
1,2,3,4,6-Pentachloro("C,,)d i benzofura n 1.00 µg/ml
MDF-123469-1 1.2 ml
1,2,3,4,6,9-Hexachloro("C 12)dibenzofuran 1.00 µg/ml
MDF-1234689·1 1.2 ml
1,2,3,4,6,8,9-Heptachloro("C,,)dibenzofuran 1.00 µg/ml
NK-IS-J4 Internal Standard Solution 1.2 ml
1,2,3,4-Tetrachloro("C,,)d i benzo-p-dioxi n 40.0 ng/ml

NK•IS·JS Internal Standard Solution 1.2 ml
1,2,3,7,8-Pentachloro("C,,)dibenzofuran 40.0 ng/ml

1,2,3,7,8,9-Hexachloro("C,,)dibenzofuran 40.0 ng/ml
60
MASS-LABELLEDPCDDs/PCDFs/PCBs:
SOLUTION/MIXTURES
Support solutions for DFP-CVS-B10, DF-CVS-C10, and PCB-CVS-B10 {see page 94).

DFP·LCS-B Mass-Labelled PCDDs/PCDFs/PCBs
Solution/Mixture 1.2 ml
DFP·LCS-B100 Mass-Labelled PCDDs/PCDFs/PCBs
DFP·LCS-B20 Mass-Labelled PCDDs/PCDFs/PCBs
DFP-LCS-B DFP-LCS-B100 DFP-LCS-B20

MASS-LABELLED PCDDs & PCDFs (ng/mL) (ng/mL) (ng/mL)
1,3,6,8-Tetrach loro{"C,,)d i benzo-p-dioxi n 1000 100 20.0

2,3, 7,8-Tetrach loro{"C,,)d i benzo-p-dioxi n 1000 100 20.0
1,2,3,7,8-Pentachloro{"C,,)dibenzo-p-dioxin 1000 100 20.0
1,2,3,4,7,8-Hexachloro{"C,,)dibenzo-p-dioxin 1000 100 20.0
1,2,3,6,7,8-Hexachloro{"C,,)dibenzo-p-dioxin 1000 100 20.0
1,2,3,7,8,9-Hexachloro{"C,,)dibenzo-p-dioxi n 1000 100 20.0
1,2,3,4,6,7,8-Heptach loro{"C,,)di benzo-p-d ioxin 1000 100 20.0
Octa ch loro{"C,,)d i benzo-p-dioxi n 2000 200 40.0
2,3, 7,8-Tetrachloro{"C,,)dibenzofuran 1000 100 20.0

1,2,3,7,8-Pentachloro{"C,,)dibenzofuran 1000 100 20.0
2,3,4, 7,8-Pentach loro{"C,,)dibenzofura n 1000 100 20.0
1,2,3,4,7,8-Hexachloro{"C,,)dibenzofuran 1000 100 20.0
1,2,3,7,8,9-Hexachloro{"C,,)dibenzofu ran 1000 100 20.0
1,2,3,4,6,7,8-Heptach loro{"C,,)di benzofura n 1000 100 20.0
1,2,3,4,7,8,9-Heptachloro{"C,,)dibenzofuran 1000 100 20.0
Octa ch loro{"C,,)d i benzofu ran 2000 200 40.0
MASS-LABELLED PCBs IUPAC
3,3' ,4,4' -Tetrach loro{"C, 2)biphenyl 77L 1000 100 20.0

3,4,4',5-Tetrachloro{"C, 2)biphenyl 81L 1000 100 20.0
2,3,3',4,4'-Pentachloro{"C,,)biphenyl 105L 1000 100 20.0
2,3,4,4', 5-Pentach loro{"C,,)bi phenyl 114L 1000 100 20.0
2,3',4,4',5-Pentachloro{"C,,)biphenyl 118L 1000 100 20.0
2',3,4,4',5-Pentachloro{"C,,)biphenyl 123L 1000 100 20.0
3,3',4,4',5-Pentachloro{"C,,)biphenyl 126L 1000 100 20.0
2,3,3 ',4,4', 5-Hexach loro{"C,,)bi phenyl 156L 1000 100 20.0
2,3,3',4,4',5'-Hexachloro{"C,,)biphenyl 157L 1000 100 20.0
2,3',4,4',5,5'-Hexachloro{"C,,)biphenyl 167L 1000 100 20.0
3,3',4,4',5,5'-Hexachloro{"C,,)biphenyl 169L 1000 100 20.0
2,2',3,3',4,4',5-Heptachloro{"C,,)biphenyl 170L 1000 100 20.0
2,2',3,4,4',5,5'-Heptachloro{"C,,)biphenyl 180L 1000 100 20.0
2,3,3',4,4',5,5'-Heptachloro{"C,,)biphenyl 189L 1000 100 20.0
61
SOLUTION/MIXTURES
Support solutions for DF-CVS-A10, DF-CVS-B10, and PCB-CVS-A10 (page 92).

DFP-LCS-A Mass-Labelled PCDD/PCDF/PCB
MASS-LABELLED PCDDs
2,3,7,8-Tetrach loro("C,,)d i benzo-p-dioxi n 10.0 ng/ml

1,2,3,7,8-Pentachloro("C,,)dibenzo-p-dioxin 10.0 ng/ml
1,2,3,6,7,8-Hexach loro("C,,)dibenzo-p-d ioxi n 10.0 ng/ml
1,2,3,7,8,9-Hexachloro("C ,)dibenzo-p-dioxin 10.0 ng/ml
1,2,3,4,6,7,8-Heptachloro("C 12)dibenzo-p-dioxin 10.0 ng/ml
Octachloro("C,,)dibenzo-p-dioxin 20.0 ng/ml
MASS-LABELLED PCDFs
2,3,7,8-Tetrach loro("C 12)d i benzofu ran 10.0 ng/ml

1,2,3,7,8-Pentachloro("C,,)dibenzofuran 10.0 ng/ml
2,3,4,7,8-Pentach loro("C,,)d i benzofura n 10.0 ng/ml
2,3,4,6,7,8-Hexachloro("C ,)dibenzofuran 10.0 ng/ml
1,2,3,4,6,7,8-Heptach loro("C,,)d i benzofuran 10.0 ng/ml
1,2,3,4,7,8,9-Heptachloro("C 12)dibenzofuran 10.0 ng/ml
Octachloro("C,,)dibenzofuran 20.0 ng/ml
3,3' ,4,4' -Tetrach loro("C, 1)biphenyl llL 10.0 ng/ml

3,4,4',5-Tetrachloro("C 21biphenyl 81L 10.0 ng/ml
2,3,3',4,4'-Pentachloro("C, 1)biphenyl 105L 10.0 ng/ml
2,3,4,4', 5-Pentach loro("C 121biphenyl 114L 10.0 ng/ml
2,3' ,4,4', 5-Pentachloro("C,,)bi phenyl 118L 10.0 ng/ml
2',3,4,4',5-Pentachloro("C,,)biphenyl 123L 10.0 ng/ml
3,3',4,4',5-Pentachloro("C,,)biphenyl 126L 10.0 ng/ml
2,3,3',4,4', 5-Hexachloro("C,,)bi phenyl 156L 10.0 ng/ml
2,3,3',4,4',5'-Hexachloro("C,,)biphenyl 157L 10.0 ng/ml
2,3',4,4',5,5'-Hexachloro("C,,)biphenyl 167L 10.0 ng/ml
3,3',4,4',5,5'-Hexachloro("C ,)biphenyl 169L 10.0 ng/ml
2,2' ,3,3' ,4,4', 5-Heptach loro("C,,)biphenyl 170L 10.0 ng/ml
2,2',3,4,4',5,5'-Heptachloro("C,,)biphenyl 180L 10.0 ng/ml
2,3,3',4,4', 5,5'-Heptach loro("C,,)biphenyl 189L 10.0 ng/ml
DFP-15-A Mass-Labelled PCDF/PCBSyringe Spike Solution 1.2 ml
IUPAC
1,2,3,4,6,9-Hexachloro("C ,)dibenzofuran 10.0 ng/ml
1,2,3,4,6,8,9-Heptach loro("C 12)d i benzofuran 10.0 ng/ml
2,3' ,4', 5-Tetrach loro("C,,)bipnenyl lOL 10.0 ng/ml
DFP-55-A Mass-Labelled PCDD/PCBSampling Spike Solution 1.2 ml
IUPAC
1,2,3,4-Tetrachloro("C 12)d i benzo-p-dioxi n 50.0 ng/ml
3,3' ,4,5' -Tetrach loro("C,,)biphenyl 79L 50.0 ng/ml
62
MASS-LABELLED PCDDs & PCBs:SOLUTION/MIXTURES
Support solutions for DFP-CVS-B10, DF-CVS-C10, and PCB-CVS-B10 (page 94).

DFP·IS·B10 Mass-Labelled PCDD/PCBInternal Standard Solution 1.2 ml
MASS-LABELLED PCDDs
1,2,4,7,8-Pentachloro("C,,)dibenzo-p-dioxin 10.0 ng/ml
1,2,3,4.6,8-Hexachloro("C,,)dibenzo-p-dioxin 10.0 ng/ml
1,2,3,4,6,7,9-Heptach loro("C,,)di benzo-p-d ioxin 10.0 ng/ml

2,3',4',S-Tetrachloro("C,,)biphenyl 70L 10.0 ng/ml
2,3,3',5,5-Pentachloro("C,,)biphenyl 111L 10.0 ng/ml
2,2',3,4,4',S'-Hexachloro("C,,)biphenyl 13BL 10.0 ng/ml
2,2',3,3',S,5',6-Heptachloro("C,,)biphenyl 17BL 10.0 ng/ml
DFP-SS-A10 Mass-Labelled PCDD/PCBSampling Spike Solution 1.2 ml
MASS-LABELLED PCDD & PCB IUPAC

3,3',4,5'-Tetrachloro("C,,)biphenyl 79L 10.0 ng/ml
63
NATIVE PCDDs & PCDFs:SOLUTION/MIXTURES
* Support solutions for DF-CVS-A10 and DF-CVS-B10.

** Support solution for DF-CVS-C10 and DFP-CVS-B10.

DF·ST·A* Native PCDD/PCDFSolution/Mixture 1.2 ml
DF·ST·B* Native PCDD/PCDFSolution/Mixture 1.2 ml
DF·ST·C** Native PCDD/PCDFSolution/Mixture 1.2 ml
DF-ST-A* DF-ST-B* DF-ST-C**

NATIVE PCDDs (1-1g/ml) (1-1g/ml) (1-1g/ml)

1,3,6,8-Tetrach lorodibenzo-p-d ioxi n 1.00 1.00 1.00
1,3,7,9-Tetrachlorodibenzo-p-dioxin 1.00 1.00
2,3,7,8-Tetrach lorodibenzo-p-d ioxi n 1.00 1.00 1.00
1,2,3,7,8-Pentachlorodibenzo-p-dioxin 1.00 1.00 1.00
1,2,3,4,6,7,8-Heptach lorodibenzo-p-d ioxi n 1.00 2.00 2.00
NATIVE PCDFs
1,2,7,8-Tetrachlorodibenzofuran 1.00 1.00

2,3,4,7,8-Pentach lo rod i benzofu ran 1.00 1.00 1.00
2,3,4,6, 7,8-Hexachlorod i benzofura n 1.00 2.00 2.00
64
NATIVE PCDDs & PCDFs:SOLUTION/MIXTURES

NK-ST·A Native PCDD/PCDFSolution/Mixture 1.2 ml
NK-ST-A4 Native PCDD/PCDFSolution/Mixture 1.2 ml
NK•ST·B2 Native PCDD/PCDFSolution/Mixture 1.2 ml
NK-ST·B4 Native PCDD/PCDFSolution/Mixture 1.2 ml
NK-ST-A NK-ST-A4 NK-ST-B2 NK-ST-B4

NATIVE PCDDs (1,19/ml) (ng/mL) (ng/mL) (1,19/ml)
2,3, 7,8-Tetrachlorodibenzo-p-dioxin 2.00 2.00 100 1.00

1,2,3,7,8-Pentachlorodibenzo-p-dioxin 2.00 2.00 100 1.00
1,2,3,4,7,8-Hexachlorodibenzo-p-d ioxin 2.00 2.00 200 2.00
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin 2.00 2.00 200 2.00
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin 2.00 2.00 200 2.00
1,2,3,4,6,7,8-Heptach lo rod i benzo-p-dioxi n 2.00 2.00 200 2.00
Octachlorodibenzo-p-dioxin 4.00 4.00 400 5.00
NATIVE PCDFs
2,3, 7,8-Tetrachlorodibenzofuran 2.00 2.00 100 1.00

1,2,3,7,8-Pentachlorodibenzofuran 2.00 2.00 100 1.00
2,3,4, 7,8-Pentachlorodibenzofuran 2.00 2.00 100 1.00
1,2,3,4,7,8-Hexachlorodibenzofuran 2.00 2.00 200 2.00
2,3,4,6, 7,8-Hexachlorodibenzofura n 2.00 2.00 200 2.00
1,2,3,4,6,7,8-Heptachlorodibenzofuran 2.00 2.00 200 2.00
1,2,3,4,7,8,9-Heptachlorodibenzofuran 2.00 2.00 200 2.00
Octachlorodibenzofuran 4.00 4.00 400 5.00
65
PCDDs & PCDFs:SOLUTION/MIXTURES
Catalogue Number Product (nonane/toluene solution) Qty/Cone

DDF-MDT Native PCDD/PCDFSolution/Mixture 1.2 ml
MDDF-MDT Mass-Labelled PCDD/PCDFSolution/Mixture 1.2 ml
DDF-MDT
NATIVE PCDDs & PCDFs (1,1g/mL)
Dibenzo-p-dioxin 1.00
2-Chlorodibenzo-p-dioxin 1.00
2,3-Dichlorodibenzo-p-dioxin 1.00
2,3,7-Trichlo rod i benzo-p-dioxi n 1.00
Dibenzofuran 1.00
2-Chlorodibenzofuran 1.00
2,3-Dichlorodibenzofuran 1.00
2,3,8-Trichlorodibenzofuran 1.00
MDDF-MDT
MASS-LABELLEDPCDDs & PCDFs (1,1g/mL)
("C 12)Dibenzo-p-dioxin 1.00
2-Chloro("C,,)dibenzo-p-dioxin 1.00
2,3-Dichloro("C,,)dibenzo-p-dioxin 1.00
2,3,7-Trichloro("C 12)dibenzo-p-d ioxi n 1.00
("C,,)Dibenzofuran 1.00
2-Chloro("C,,)dibenzofuran 1.00
2,3-Dich loro("C 12)d i benzofura n 1.00
2,3,8-Trichloro("C,,)dibenzofuran 1.00
66

67
PCBS:
ANALYTICAL METHOD SOLUTIONS
Wellington offers several calibration kits, along with support solutions, for the analysis of
individual PCBcongeners.
WP-CVS
This set of solutions is to be used for the analysis of the 12 'dioxin-like' PCBcongeners by
HRGQHRMS.
EPA Method 1668C

This series of calibration solutions, and corresponding support solutions, were prepared to be used
according to U.S. EPA Method 1668, Revision C.
EPA Method 1668

This calibration kit, and support solutions, were designed and prepared to be used with the Draft
version (March, 1997) of U.S. EPA Method 1668 which is still popular with some laboratories.
Environment Canada Method 1/RM/31 is a HRGQLRMSmethod for PCBanalysis and these

solutions were prepared to be used with this method.
P48-W-CVS and P48-M-CVS

European Standard Method EN 1948-4 is to be used for the analysis of the 12 'dioxin-like' PCB
congeners and the 6 'marker' PCBcongeners in stationary source emissions. These two calibration
kits, and their support solutions, were prepared for this method.
This calibration set is a combination of P48-W-CVSand P48-M-CVS.

WP-CVS STANDARD SOLUTIONS

WP-CVS Dioxin-Like PCBs 1 kit
WP-CS1 CS1 500 µL
WP-CS2 CS2 500 µL
WP-CS3 CS3 500 µL
WP-CS4 CS4 500 µL
WP-CS5 CS5 500 µL
WP-CS6 CSG 500 µL
WP-CS7 CS7 500 µL
WP-CS1 WP-CS2 WP-CS3 WP-CS4 WP-CSS WP-CS6 WP-CS7

NATIVE PCBs IUPAC {ng/mL) (ng/mL) {ng/mL) {ng/mL) (ng/mL) (ng/mL) (ng/mL)
3,3',4,4'-Tetrachlorobiphenyl 77 0.100 0.500 2.00 10.0 40.0 200 800

3,4,4',5-Tetrachlorobiphenyl 81 0.100 0.500 2.00 10.0 40.0 200 800
2,3,3',4,4'-Pentachlorobiphenyl 105 0.100 0.500 2.00 10.0 40.0 200 800
2,3,4,4',5-Pentachlorobiphenyl 114 0.100 0.500 2.00 10.0 40.0 200 800
2,3',4,4',5-Pentachlorobiphenyl 118 0.100 0.500 2.00 10.0 40.0 200 800
2 ',3,4,4', 5-Pentachlorobi phenyl 123 0.100 0.500 2.00 10.0 40.0 200 800
3,3',4,4',5-Pentachlorobiphenyl 126 0.100 0.500 2.00 10.0 40.0 200 800
2,3,3',4,4',5-Hexachlorobiphenyl 156 0.100 0.500 2.00 10.0 40.0 200 800
2,3,3',4,4',5'-Hexachlorobiphenyl 157 0.100 0.500 2.00 10.0 40.0 200 800
2,3',4,4',5,5'-Hexachlorobiphenyl 167 0.100 0.500 2.00 10.0 40.0 200 800
3,3',4,4',5,5'-Hexachlorobiphenyl 169 0.100 0.500 2.00 10.0 40.0 200 800
2,3,3',4,4',5,5'-Heptachlorobiphenyl 189 0.100 0.500 2.00 10.0 40.0 200 800
MASS-LABELLED PCBs
3,3' ,4,4' -Tetrach loro("C,,)biphenyl 77L 50.0 50.0 50.0 50.0 50.0 50.0 50.0
3,4,4', 5-Tetrachloro("C,,)bi phenyl 81L 50.0 50.0 50.0 50.0 50.0 50.0 50.0
2,3,3',4,4'-Pentachloro("C,,)biphenyl 105L 50.0 50.0 50.0 50.0 50.0 50.0 50.0
2,3,4,4', 5-Pentach loro("C,,)bi phenyl 114L 50.0 50.0 50.0 50.0 50.0 50.0 50.0
2,3' ,4,4', 5-Pentachloro("C,,)bi phenyl 118L 50.0 50.0 50.0 50.0 50.0 50.0 50.0
2 ',3,4,4', 5-Pentachloro("C,,)bi phenyl 123L 50.0 50.0 50.0 50.0 50.0 50.0 50.0
3,3' ,4,4', 5-Pentachloro("C,,)bi phenyl 126L 50.0 50.0 50.0 50.0 50.0 50.0 50.0
2,3,3',4,4',5-Hexachloro("C,,)biphenyl 156L 50.0 50.0 50.0 50.0 50.0 50.0 50.0
2,3,3',4,4',5'-Hexachloro("C,,)biphenyl 157L 50.0 50.0 50.0 50.0 50.0 50.0 50.0
2,3',4,4',5,5'-Hexachloro("C,,)biphenyl 167L 50.0 50.0 50.0 50.0 50.0 50.0 50.0
3,3',4,4',5,5'-Hexachloro("C,,)biphenyl 169L 50.0 50.0 50.0 50.0 50.0 50.0 50.0
2,3,3',4,4',5,5'-Heptachloro("C,,)biphenyl 189L 50.0 50.0 50.0 50.0 50.0 50.0 50.0
INTERNAL STANDARDS
2,3' ,4', 5-Tetrach loro("C,,)biphenyl 70L 50.0 50.0 50.0 50.0 50.0 50.0 50.0
2,3,3',5,5'-Pentachloro("C,,)biphenyl 111L 50.0 50.0 50.0 50.0 50.0 50.0 50.0
2,2',3,4,4',5'-Hexachloro("C,,)biphenyl 138L 50.0 50.0 50.0 50.0 50.0 50.0 50.0
2,2',3,3',4,4',5-Heptachloro("C,,)biphenyl 170L 50.0 50.0 50.0 50.0 50.0 50.0 50.0
70
WP-CVS STANDARD SOLUTIONS

WP-LCS Surrogate Spiking Solution 1.2 ml
WP-ISS Internal Standard Solution 1.2 ml
WP-STK Native PCBSolution 1.2 ml
WP-LCS WP-ISS WP-STK

NATIVE PCBs IUPAC (ng/mL) (ng/mL) (ng/mL)
3,3',4,4'-Tetrachlorobiphenyl 77 2000
3,4,4',5-Tetrachlorobiphenyl 81 2000
2,3,3',4,4'-Pentachlorobiphenyl 105 2000
2,3,4,4', 5-Pentach lorobiphenyl 114 2000
2,3',4,4',5-Pentachlorobiphenyl 118 2000
2 ',3,4,4', 5-Pentachlorobi phenyl 123 2000
2,3,3',4,4',5-Hexachlorobiphenyl 156 2000
2,3,3',4,4',5'-Hexachlorobiphenyl 157 2000
2,3',4,4',5,5'-Hexachlorobiphenyl 167 2000
2,3,3',4,4',5,5'-Heptachlorobiphenyl 189 2000
MASS-LABELLED PCBs
3,3' ,4,4' -Tetrach loro("C,,)biphenyl 77L 1000

3,4,4', 5-Tetrachloro("C,,)bi phenyl 81L 1000
2,3,3',4,4'-Pentachloro("C,,)biphenyl 105L 1000
2,3,4,4', 5-Pentach loro("C,,)bi phenyl 114L 1000
2,3' ,4,4', 5-Pentachloro("C,,)bi phenyl 118L 1000
2 ',3,4,4', 5-Pentachloro("C,,)bi phenyl 123L 1000
3,3',4,4',5-Pentachloro("C,,)biphenyl 126L 1000
2,3,3',4,4', 5-Hexachloro("C,,)bi phenyl 156L 1000
2,3,3',4,4',5'-Hexachloro("C,,)biphenyl 157L 1000
2,3',4,4',5,5'-Hexachloro("C,,)biphenyl 167L 1000
2,3,3',4,4',5,5'-Heptachloro("C,,)biphenyl 189L 1000
INTERNAL STANDARDS
2,3' A' ,5-Tetrach loro("C,,)biphenyl 70L 1000

2,2',3,4,4',5'-Hexachloro("C,,)biphenyl 138L 1000
2,2' ,3,3' ,4,4', 5-Heptach loro("C,,)biphenyl 170L 1000
71
EPA METHOD 1668C STANDARD SOLUTIONS

68C-CVS EPA Method 1668C 1 kit
Calibration and Verification Solutions CS0.2-CS5 (6 ampoules)
68C-CS0.2 CS0.2 High Sensitivity 200 µL
68C·CS1 CS1 200 µL
68C-CS2 CS2 200 µL
68C·CS3 CS3 Calibration Verification 500 µL
68C-CS4 CS4 200 µL
68C·CS5 CS5 200 µL
NOTE: The above product codes were updated to reflect the change of EPA Method 1668B to 1668C in April of 2010.
68C-CS0.2 68C-CS1 68C-CS2 68C-CS3 68C-C54 68C-CS5

NATIVE TOXICS/LOC STANDARDS IUPAC (ng/mL) (ng/mL) (ng/mL) (ng/mL) (ng/mL) (ng/mL)
2-Chlorobiphenyl 1 0.200 1.00 5.00 50.0 400 2000
4-Chlorobiphenyl 3 0.200 1.00 5.00 50.0 400 2000
2,2'-Dichlorobiphenyl 4 0.200 1.00 5.00 50.0 400 2000
4,4'-Dichlorobiphenyl 15 0.200 1.00 5.00 50.0 400 2000
2,2',6-Trichlorobiphenyl 19 0.200 1.00 5.00 50.0 400 2000
3,4,4' -Trichlorobiphenyl 37 0.200 1.00 5.00 50.0 400 2000
2,2',6,6'-Tetrachlorobiphenyl 54 0.200 1.00 5.00 50.0 400 2000
3,4,4',5-Tetrachlorobiphenyl 81 0.200 1.00 5.00 50.0 400 2000
2,2',4,6,6'-Pentachlorobiphenyl 104 0.200 1.00 5.00 50.0 400 2000
2,3,3',4,4'-Pentachlorobiphenyl 105 0.200 1.00 5.00 50.0 400 2000
2,3,4,4',5-Pentachlorobiphenyl 114 0.200 1.00 5.00 50.0 400 2000
2,3',4,4',5-Pentachlorobiphenyl 118 0.200 1.00 5.00 50.0 400 2000
2',3,4,4',5-Pentachlorobiphenyl 123 0.200 1.00 5.00 50.0 400 2000
2,2',4,4',6,6'-Hexachlorobiphenyl 155 0.200 1.00 5.00 50.0 400 2000
2,3,3',4,4',5-Hexachlorobiphenyl 156 0.200 1.00 5.00 50.0 400 2000
2,3,3',4,4',5'-Hexachlorobiphenyl 157 0.200 1.00 5.00 50.0 400 2000
2,2',3,4',5,6,6'-Heptachlorobiphenyl 188 0.200 1.00 5.00 50.0 400 2000
2,3,3',4,4',5,5'-Heptachlorobiphenyl 189 0.200 1.00 5.00 50.0 400 2000
2,2',3,3',5,5',6,6'-Octachlorobiphenyl 202 0.200 1.00 5.00 50.0 400 2000
2,3,3',4,4',5,5',6-Octachlorobiphenyl 205 0.200 1.00 5.00 50.0 400 2000
2,2',3,3',4,4',5,5',6-Nonachlorobiphenyl 206 0.200 1.00 5.00 50.0 400 2000
2,2',3,3',4,5,5',6,6'-Nonachlorobiphenyl 208 0.200 1.00 5.00 50.0 400 2000
Decachlorobiphenyl 209 0.200 1.00 5.00 50.0 400 2000
MASS-LABELLED TOXICS/LOCI
WINDOW-DEFINING STANDARDS
2-Chloro("C,,)biphenyl 1L 100 100 100 100 100 100
4-Chloro("C,,)biphenyl 3L 100 100 100 100 100 100
2,2'-Dichloro("C,,)biphenyl 4L 100 100 100 100 100 100
4,4'-Dichloro("C,,)biphenyl 15L 100 100 100 100 100 100
2,2',6-Trichloro("C,,)biphenyl 19L 100 100 100 100 100 100
3,4,4'-Trichloro("C,,)biphenyl 37L 100 100 100 100 100 100
2,2',6,6'-Tetrachloro("C,,)biphenyl 54L 100 100 100 100 100 100
3,3',4,4'-Tetrachloro("C,,)biphenyl lll 100 100 100 100 100 100
3,4,4',5-Tetrachloro("C,,)biphenyl 81L 100 100 100 100 100 100
2,2',4,6,6'-Pentachloro("C,,)biphenyl 104L 100 100 100 100 100 100
2,3,3',4,4'-Pentachloro("C,,)biphenyl 105L 100 100 100 100 100 100
2,3,4,4',5-Pentachloro("C.,)biphenyl 114L 100 100 100 100 100 100
2,3',4,4',5-Pentachloro("C,,)biphenyl 118L 100 100 100 100 100 100
2',3,4,4',5-Pentachloro("C,,)biphenyl 123L 100 100 100 100 100 100
3,3',4,4',5-Pentachloro("C,,)biphenyl 126L 100 100 100 100 100 100
2,2•.~,4•,~,6'-Hexachloro\;'C,j)~iphenyl 155L 100 100 100 100 100 100
2,3,3 ,4,4 ,5-Hexachloro( C12 bi phenyl 156L 100 100 100 100 100 100
2,3,3',4,4',5'-Hexachloro("C,,)biphenyl 157L 100 100 100 100 100 100
2,3',4,4',5,5'-Hexachloro("C,,)biphenyl 167L 100 100 100 100 100 100
2,2',3,4',5,6,6'-Heptachloro("C,,)biphenyl 188L 100 100 100 100 100 100
2,3,3',4,4',5,5'-Heptachloro("C,,)biphenyl 189L 100 100 100 100 100 100
2,2',3,3',5,5',6,6'-Octachloro("C,,)biphenyl 202L 100 100 100 100 100 100
2,3,3',4,4',5,5',6-Octachloro("C,,)biphenyl 205L 100 100 100 100 100 100
2,2',3,3',4,4',5,5',6-Nonachloro("C,,)biphenyl 206L 100 100 100 100 100 100
2,2',3,3',4,5,5',6,6'-Nonachloro("C,,)biphenyl 208L 100 100 100 100 100 100
Decachloro("C,,)biphenyl 209L 100 100 100 100 100 100
MASS-LABELLED CLEANUP STANDARDS
2,4,4'-Trichloro("C,,)biphenyl 28L 100 100 100 100 100 100
2,3,3',5,5'-Pentachloro("C,,)biphenyl 111L 100 100 100 100 100 100
2,2',3,3',5,5',6-Heptachloro("C,,)biphenyl 178L 100 100 100 100 100 100
MASS-LABELLED INJECTION/
INTERNAL STANDARDS
2,5-Dichloro("C,,)biphenyl 9L 100 100 100 100 100 100
2,2',5,5'-Tetrachloro("C,,)biphenyl 52L 100 100 100 100 100 100
2,2',3,4,4',5'-Hexachloro("C, )biphenyl 138L 100 100 100 100 100 100
2,2',3,3',4,4',5,5'-0ctachloro("C,,)biphenyl 194L 100 100 100 100 100 100
72
EPA METHOD 1668C STANDARD SOLUTIONS

68C-LCS Mass-Labelled Toxics/LOC/Window Defining Stock Solution 1.2 ml
68C·CS Mass-Labelled Cleanup Stock Solution 1.2 ml
68C-IS Mass-Labelled Injection/Internal Standard Stock Solution 1.2 ml
68C·PAR Native Toxics/LOCStock Solution 1.2 ml
NOTE: The above product codes were updated to reflect the change of EPA Method 1668B to 1668C in April of 2010.
68C-LCS 68C-CS 68C-IS &BC-PAR

NATIVE TOXICS/LOC STANDARDS IUPAC (ng/mL) (ng/mL) (ng/mL) (ng/mL)
2-Chlorobiphenyl 1 2000
4-Chlorobiphenyl 3 2000
2,2'-Dichlorobiphenyl 4 2000
4,4'-Dichlorobiphenyl 15 2000
2,2',6-Trichlorobiphenyl 19 2000
3,4,4'-Trichlorobiphenyl 37 2000
3,4,4',5-Tetrachlorobiphenyl 81 2000
2,2',4,6,6'-Pentachlorobiphenyl 104 2000
2,3,4,4',5-Pentachlorobiphenyl 114 2000
2',3,4,4',5-Pentachlorobiphenyl 123 2000
2,2',3,4',5,6,6'-Heptachlorobiphenyl 188 2000
2,2',3,3',5,5',6,6'-Octachlorobiphenyl 202 2000
2,3,3',4,4',5,5',6-Octachlorobiphenyl 205 2000
2,2',3,3',4,4',5,5',6-Nonachlorobiphenyl 206 2000
2,2',3,3',4,5,5',6,6'-Nonachlorobiphenyl 208 2000
Decachlorobiphenyl 209 2000
MASS-LABELLED TOXICS/LOCI
WINDOW-DEFINING STANDARDS
2-Chloro("C,,)biphenyl 1L 1000
2,2'-Dichloro("C,,)biphenyl 4L 1000
4,4'-Dichloro("C,,)biphenyl ISL 1000
2,2',6-Trichloro("C,,)biphenyl 19L 1000
3,4,4'-Trichloro("C,,)biphenyl 37L 1000
2,2',6,6'-Tetrachloro("C,,)biphenyl 54L 1000
3,4,4',5-Tetrachloro("C,,)biphenyl 81L 1000
2,2',4,6,6'-Pentachloro("C,,)biphenyl 104L 1000
2,3,4,4',5-Pentachloro("C.,)biphenyl 114L 1000
2',3,4,4',5-Pentachloro("C,,)biphenyl 123L 1000
2,2•.~,4•,~,6'-Hexachloro\;'C,j)~iphenyl 155L 1000
2,3,3 ,4,4 ,5-Hexachloro( C12 bi phenyl 156L 1000
2,2',3,4',5,6,6'-Heptachloro("C,,)biphenyl 188L 1000
2,2',3,3',5,5',6,6'-Octachloro("C,,)biphenyl 202L 1000
2,3,3',4,4',5,5',6-Octachloro("C,,)biphenyl 205L 1000
2,2',3,3',4,4',5,5',6-Nonachloro("C,,)biphenyl 206L 1000
2,2',3,3',4,5,5',6,6'-Nonachloro("C,,)biphenyl 208L 1000
Decachloro("C,,)biphenyl 209L 1000
MASS-LABELLED CLEANUP STANDARDS
2,2',3,3',5,5',6-Heptachloro("C,,)biphenyl 178L 1000
MASS-LABELLED INJECTION/
INTERNAL STANDARDS
2,5-Dichloro("C,,)biphenyl 9L 5000
2,2',3,4,4',5'-Hexachloro("C, )biphenyl 138L 5000
2,2',3,3',4,4',5,5'-0ctachloro("C,,)biphenyl 194L 5000
73

EPA-1668CV5 EPA Method 1668 1 kit
EPA-1668C51 CS1 200 µL
EPA-1668C52 CS2 200 µL
EPA-1668C53 CS3 Calibration Verification 500 µL
EPA-1668C54 CS4 200 µL
EPA-1668C55 CS5 200 µL
1668C51 1668CS2 1668C53 1668CS4 1668C55

NATIVE PCBs IUPAC (ng/mL) (ng/mL) (ng/mL) (ng/mL) (ng/mL)
3,3',4,4'-Tetrachlorobiphenyl 77 0.500 2.00 10.0 40.0 200

2,3,3',4,4'-Pentachlorobiphenyl 105 2.50 10.0 50.0 200 1000
2,3,4,4', 5-Pentachlorobi phenyl 114 2.50 10.0 50.0 200 1000
2,3',4,4',5-Pentachlorobiphenyl 118 2.50 10.0 50.0 200 1000
2',3,4,4',5-Pentachlorobiphenyl 123 2.50 10.0 50.0 200 1000
3,3',4,4',5-Pentachlorobiphenyl 126 2.50 10.0 50.0 200 1000
2,3,3',4,4',5-Hexachlorobiphenyl 156 5.00 20.0 100 400 2000
2,3,3',4,4',5'-Hexachlorobiphenyl 157 5.00 20.0 100 400 2000
2,3',4,4',5,5'-Hexachlorobiphenyl 167 5.00 20.0 100 400 2000
2,2',3,3',4,4',5-Heptachlorobiphenyl 170 5.00 20.0 100 400 2000
2,2',3,4,4',5,5'-Heptachlorobiphenyl 180 5.00 20.0 100 400 2000
2,3,3',4,4',5,5'-Heptachlorobiphenyl 189 5.00 20.0 100 400 2000
MASS-LABELLED PCBs
3,3',4,4'-Tetrachloro("C,,)biphenyl 77L 100 100 100 100 100

2,3,3',4,4'-Pentachloro("C,,)biphenyl 105L 100 100 100 100 100
2,3',4,4',5-Pentachloro("C,,)biphenyl 118L 100 100 100 100 100
3,3 ',4,4', 5-Pentachloro("C,,) bi phenyl 126L 100 100 100 100 100
2,3,3',4,4',5-Hexachloro("C 12)biphenyl 156L 100 100 100 100 100
2,3,3',4,4',5'-Hexachloro("C 12)biphenyl 157L 100 100 100 100 100
2,3',4,4',5,5'-Hexachloro("C 12)biphenyl 167L 100 100 100 100 100
3,3',4,4',5,5'-Hexachloro("C,,)biphenyl 169L 100 100 100 100 100
2,2',3,4,4',5,5'-Heptachloro("C,,)biphenyl 180L 100 100 100 100 100
2,3,3',4,4',5,5'-Heptachloro("C,,)biphenyl 189L 100 100 100 100 100
Decachloro("C 12)biphenyl 209L 200 200 200 200 200
CLEANUP STANDARDS
3,4,4', 5-Tetrach loro("C 12) bi phenyl 81L 0.500 2.00 10.0 40.0 200
2,3,3', 5,5' -Penta chloro("C 12) bi phenyl 111L 2.50 10.0 50.0 200 1000
INTERNAL STANDARDS
2,2 ', 5,5'-Tetra ch loro("C,,) bi phenyl 52L 100 100 100 100 100
2,2',4,5,5'-Pentachloro("C 12)biphenyl 101L 100 100 100 100 100
2,2',3,4,4',5'-Hexachloro("C,,)biphenyl 138L 100 100 100 100 100
2,2',3,3',5,5',6-Heptachloro("C 12)biphenyl 178L 100 100 100 100 100
74

EPA·1668LCS Labelled Compound Stock Solution 1.2 ml
EPA-1668CS Cleanup Standard Solution 1.2 ml
EPA-1668I5 Internal Standard Stock Solution 1.2 ml
EPA-1668PAR Precision and Recovery Solution 1.2 ml
1668LCS 1668CS 1668IS 1668PAR

NATIVE PCBs IUPAC (ng/mL) (ng/mL) (ng/mL) (ng/mL)
3,3',4,4'-Tetrachlorobiphenyl 77 20.0
2,3,4,4', 5-Pentachlorobiphenyl 114 1000
2,3' ,4,4', 5-Pentachlorobi phenyl 118 1000
2 ',3,4,4', 5-Pentachlorobi phenyl 123 1000
3,3' ,4,4', 5-Pentachlorobi phenyl 126 100
2,2',3,3',4,4',5-Heptachlorobiphenyl 170 200
2,2',3,4,4',5,5'-Heptachlorobiphenyl 180 1000
MASS-LABELLED PCBs

2,3,3',4,4',5-Hexachloro("C,,)biphenyl 156L 1000
2,2',3,4,4',5,5'-Heptachloro("C,,)biphenyl 180L 1000
CLEANUP STANDARDS

INTERNAL STANDARDS
2,2',5, 5' -Tetrach loro("C,,)biphenyl 52L 1000

2,2' ,4,5,5'-Pentachloro("C,,)bi phenyl 101L 1000
2,2',3,3',5,5',6-Heptachloro("C,,)biphenyl 178L 1000
75
ENVIRONMENT CANADA METHOD 1/RM/31 STANDARD SOLUTIONS
Catalogue Number Product (isooctane solution) Qty/Cone

EC9605-CVS PCBCalibration Solutions for GC/MS 1 kit
ECPCS1 CS1 500 µL
ECPCS2 CS2 500 µL
ECPCS3 CS3 500 µL
ECPCS4 CS4 500 µL
ECPCSS CS5 500 µL
ECPCS1 ECPCS2 ECPCS3 ECPCS4 ECPCSS

NATIVE PCBs* IUPAC {ng/mL) {ng/mL) {ng/mL) {ng/mL) {ng/mL)
2,2',5-Trichlorobiphenyl 18 20.0 50.0 200 800 2000

2,4,4' -Trichlorobi phenyl 28 20.0 50.0 200 800 2000
2',3,4-Trichlorobiphenyl 33 20.0 50.0 200 800 2000
2,2',5,5'-Tetrachlorobiphenyl 52 20.0 50.0 200 800 2000
2,2',3,5'-Tetrachlorobiphenyl 44 20.0 50.0 200 800 2000
2,3',4',5-Tetrachlorobiphenyl 70 20.0 50.0 200 800 2000
2,2',4,5,5'-Pentachlorobiphenyl 101 20.0 50.0 200 800 2000
2,3',4,4',5-Pentachlorobiphenyl 118 20.0 50.0 200 800 2000
2,3,3',4,4'-Pentachlorobiphenyl 105 20.0 50.0 200 800 2000
2,2',3,4,4',5'-Hexachlorobiphenyl 138 20.0 50.0 200 800 2000
2,2',3,4,4',5,5'-Heptachlorobiphenyl 180 20.0 50.0 200 800 2000
2,2',3,3',4,5,5',6'-Octachlorobiphenyl 199 20.0 50.0 200 800 2000
2,2',3,3',4,4',5,6-Octachlorobiphenyl 195 20.0 50.0 200 800 2000
2,2',3,3',4,4',5,5'-Octachlorobiphenyl 194 20.0 50.0 200 800 2000
2,2',3,3',4,4',5,5',6-Nonachlorobiphenyl 206 20.0 50.0 200 800 2000
Decachlorobiphenyl 209 20.0 50.0 200 800 2000
MASS-LABELLED PCBs *
2,4,4' -Trichloro("C 12)bi phenyl 28L 400 400 400 400 400
2,2', 5,5' -Tetrach loro("C 12)biphenyl 52L 400 400 400 400 400
2,3' ,4,4', 5-Pentachloro("C,,)bi phenyl 118L 400 400 400 400 400
2,2',4,4',5,5'-Hexachloro("C,,)biphenyl 153L 400 400 400 400 400
2,2',3,4,4',5,5'-Heptachloro("C,,)biphenyl 180L 400 400 400 400 400
2,2',3,3',5,5',6,6'-Octachloro("C,,)biphenyl 202L 400 400 400 400 400
2,2',3,3',4,4',5,5',6-Nonachloro("C,,)biphenyl 206L 400 400 400 400 400
Decachloro("C 12)biphenyl 209L 400 400 400 400 400
MASS-LABELLED RECOVERY STANDARDS*
2,2',4,5,5'-Pentachloro("C,,)biphenyl 101L 400 400 400 400 400

2,2',3,3',4,4',5,5'-Octachloro("C,,)biphenyl 194L 400 400 400 400 400
* In order of elution on a 60 m DB-5 column.
76
ENVIRONMENT CANADA METHOD 1/RM/31 STANDARD SOLUTIONS

EC9605-RS Recovery Standard Solution 1.2 ml
EC9605-SS Surrogate Solution 1.2 ml
EC9605-PAR Precision and Recovery Solution 1.2 ml
EC9605-RS EC9605-SS EC9605-PAR

NATIVE PCBs IUPAC (~g/mL) (~g/mL) (ng/mL)
2,2' ,5-Trichlorobiphenyl 18 100

2,4,4' -Trichlorobi phenyl 28 100
2' ,3,4-Trichlorobiphenyl 33 100
2,2',S,5'-Tetrachlorobiphenyl 52 100
2,3',4',S-Tetrachlorobiphenyl 70 100
2,2'.4.5,S'-Pentachlorobiphenyl 101 100
2,3',4,4',S-Pentachlorobiphenyl 118 100
2,3,3'.4.4'-Pentachlorobiphenyl 105 100
2,2',4,4',S,5'-Hexachlorobiphenyl 153 100
2,2',3,4,4',S'-Hexachlorobiphenyl 138 100
2,2',3,3'.4.4'-Hexachlorobiphenyl 128 100
2,2',3,4',S,5',6-Heptachlorobiphenyl 187 100
2,2',3,4,4',S,5'-Heptachlorobiphenyl 180 100
2,2',3,3',4,4',S-Heptachlorobiphenyl 170 100
2,2',3,3',4,S,5',6'-Octachlorobiphenyl 199 100
2,2',3,3',4,4',S,6-Octachlorobiphenyl 195 100
2,2',3,3',4,4',S,5'-Octachlorobiphenyl 194 100
2,2',3,3',4,4',S,5',6-Nonachlorobiphenyl 206 100
Decachlorobiphenyl 209 100
MASS-LABELLED PCBs
2,4,4' -Trichloro("C,,)bi phenyl 28L 2.00

2,2',S,5'-Tetrachloro("C,,)biphenyl 52L 2.00
2,3' ,4,4', 5-Pentachloro("C,,)bi phenyl 118L 2.00
2,2',4,4',S,5'-Hexachloro("C,,)biphenyl 153L 2.00
2,2',3,4,4',S,5'-Heptachloro("C,,)biphenyl 180L 2.00
2,2',3,3',S,5',6,6'-Octachloro("C, 2)biphenyl 202L 2.00
2,2',3,3',4,4',S,5',6-Nonachloro("C, 2)biphenyl 206L 2.00
Decachloro("C,,)biphenyl 209L 2.00
MASS-LABELLED RECOVERY STANDARDS
2,2' ,4,5,5'-Pentachloro("C, 2)bi phenyl 101L 2.00

2,2',3,3',4,4',S,5'-Octachloro("C, 2)biphenyl 194L 2.00
77
P48-W-CVS

P48-W-CVS P48-W-CVS;EN 1948-4:2010 1 kit
HRGC/HRMSCalibration Solutions for the Dioxin-like PCBsCS1-CS6 (6 ampoules)
P48•W-CS1 CS1 500 µL
P48-W-CS2 CS2 500 µL
P48·W·CS3 CS3 500 µL
P48•W-CS4 CS4 500 µL
P48-W-CS5 CS5 500 µL
P48·W·CS6 CS6 500 µL
P48•W• P48•W• P48•W• P48•W• P48•W• P48•W•

CS1 CS2 CS3 CS4 css CS6
NATIVE DIOXIN-LIKE PCBs IUPAC (pg/1,1L) (pg/1,1L) (pg/1,1L) (pg/1,1L) (pg/1,1L) (pg/1,1L)

3,4,4',5-Tetrachlorobiphenyl 81 0.100 1.00 10.0 50.0 200 800
2,3,3',4,4'-Pentachlorobiphenyl 105 0.100 1.00 10.0 50.0 200 800
2,3,4,4', 5-Pentach lorobiphenyl 114 0.100 1.00 10.0 50.0 200 800
2,3',4,4',5-Pentachlorobiphenyl 118 0.600 6.00 60.0 300 1200 4800
2',3,4,4',5-Pentachlorobiphenyl 123 0.100 1.00 10.0 50.0 200 800
2,3,3',4,4',5-Hexachlorobiphenyl 156 0.100 1.00 10.0 50.0 200 800
2,3,3',4,4',5'-Hexachlorobiphenyl 157 0.100 1.00 10.0 50.0 200 800
2,3,3',4,4',5,5'-Heptachlorobiphenyl 189 0.100 1.00 10.0 50.0 200 800
WHO PCB EXTRACTION STANDARDS
3,3',4,4'-Tetrachloro("C,,)biphenyl 77L 10.0 10.0 10.0 10.0 10.0 10.0

3,4,4',5-Tetrachloro("C,,)biphenyl 81L 10.0 10.0 10.0 10.0 10.0 10.0
2,3,3',4,4'-Pentachloro("C,,)biphenyl 105L 10.0 10.0 10.0 10.0 10.0 10.0
2,3,4,4', 5-Pentach loro("C,,)bi phenyl 114L 10.0 10.0 10.0 10.0 10.0 10.0
2,3',4,4',5-Pentachloro("C,,)biphenyl 118L 10.0 10.0 10.0 10.0 10.0 10.0
2',3,4,4',5-Pentachloro("C,,)biphenyl 123L 10.0 10.0 10.0 10.0 10.0 10.0
3,3' ,4,4', 5-Pentachloro("C 12)bi phenyl 126L 10.0 10.0 10.0 10.0 10.0 10.0
2,3,3',4,4',5-Hexachloro("C,,)biphenyl 156L 10.0 10.0 10.0 10.0 10.0 10.0
2,3,3',4,4',5'-Hexachloro("C,,)biphenyl 157L 10.0 10.0 10.0 10.0 10.0 10.0
2,3',4,4',5,5'-Hexachloro("C 12)biphenyl 167L 10.0 10.0 10.0 10.0 10.0 10.0
3,3',4,4',5,5'-Hexachloro("C,,)biphenyl 169L 10.0 10.0 10.0 10.0 10.0 10.0
2,3,3 ',4,4', 5,5'-Heptach loro("C,,)biphenyl 189L 10.0 10.0 10.0 10.0 10.0 10.0
SAMPLING STANDARDS
2,3,4,4'-Tetrachloro("C,,)biphenyl 60L 10.0 10.0 10.0 10.0 10.0 10.0

3,3',4,5,5'-Pentachloro("C,,)biphenyl 127L 10.0 10.0 10.0 10.0 10.0 10.0
2,3,3',4,5,5'-Hexachloro("C,,)biphenyl 159L 10.0 10.0 10.0 10.0 10.0 10.0
RECOVERY STANDARDS
2,3' ,4', 5-Tetrach loro("C,,)biphenyl 70L 10.0 10.0 10.0 10.0 10.0 10.0
2,2' ,3,3 ',4,4', 5-Heptach loro("C,,)biphenyl 170L 10.0 10.0 10.0 10.0 10.0 10.0
78
P48-M-CVS

P48·M-CVS P48-M-CVS; EN 1948-4:2010 1 kit
HRGC/HRMSCalibration Solutions for the Marker PCBsCS0.1-CS5 (6 ampoules)
P48·M-CS0.1 CS0.1 500 µL
P48·M-CS1 cs, 500 µL
P48·M·CS2 CS2 500 µL
P48·M-CS3 CS3 500 µL
P48·M-CS4 CS4 500 µL
P48·M·CS5 CS5 500 µL
P48•M• P48•M• P48•M• P48•M• P48•M• P48•M•

CS0.1 CS1 CS2 CS3 CS4 css
NATIVE MARKER PCBs IUPAC (pg/µL) (pg/µL) (pg/µL) (pg/µL) (pg/µL) (pg/µL)
2,4,4' -Trich lorobi phenyl 28 0.100 1.00 10.0 100 500 5000
2,2', 5,5' -Tetrach lorobi phenyl 52 0.100 1.00 10.0 100 500 5000
2,2' ,4, 5,5'-Pentachlorobi phenyl 101 0.100 1.00 10.0 100 500 5000
2,2',3,4,4',5'-Hexachlorobiphenyl 138 0.100 1.00 10.0 100 500 5000
2,2',4,4',5,5'-Hexachlorobiphenyl 153 0.100 1.00 10.0 100 500 5000
2,2',3,4,4',5,5'-Heptachlorobiphenyl 180 0.100 1.00 10.0 100 500 5000
MARKER PCB EXTRACTION STANDARDS
2,4,4' -Trich loro("C,,)bi phenyl 28L 100 100 100 100 100 100
2,2', 5,5' -Tetrach loro("C,,)biphenyl 52L 100 100 100 100 100 100
2,2',3,4,4',5'-Hexachloro("C 12)biphenyl 138L 100 100 100 100 100 100
2,2' ,3,4,4', 5,5'-Heptach loro("C,,)biphenyl 180L 100 100 100 100 100 100
SAMPLING STANDARDS

2,3,3',4,5,5'-Hexachloro("C,,)biphenyl 159L 10.0 10.0 10.0 10.0 10.0 10.0
RECOVERY STANDARDS
2,3' ,4', 5-Tetrach loro("C,,)biphenyl l0L 10.0 10.0 10.0 10.0 10.0 10.0
2,2' ,3,3' ,4,4', 5-Heptach loro("C,,)biphenyl 170L 10.0 10.0 10.0 10.0 10.0 10.0
79
WM48-CVS

WM48-CVS WM48-CVS; EN 1948-4:2010 1 kit
HRGC/HRMSCalibration Solutions for the (6 ampoules)
Dioxin-like and Marker PCBsCS1-CS6
WM48-CS1 CS1 500 µL
WM48·CS3 CS3 500 µL
WM48·CS6 CS6 500 µL
WM48- WM48- WM48- WM48- WM48- WM48-

CS1 CS2 CS3 CS4 css CS6
NATIVE DIOXIN-LIKE PCBs IUPAC (pg/1,1L) (pg/1,1L) (pg/1,1L) (pg/1,1L) (pg/1,1L) (pg/1,1L)
3,3',4,4'-Tetrachlorobiphenyl 77 0.100 0.500 2.00 10.0 40.0 200
3,4,4',5-Tetrachlorobiphenyl 81 0.100 0.500 2.00 10.0 40.0 200
2,3,3',4,4'-Pentachlorobiphenyl 105 0.100 0.500 2.00 10.0 40.0 200
2,3,4,4',5-Pentachlorobiphenyl 114 0.100 0.500 2.00 10.0 40.0 200
2,3' ,4,4', 5-Pentachlorobi phenyl 118 0.500 2.50 10.0 50.0 200 1000
2 ',3,4,4', 5-Pentachlorobi phenyl 123 0.100 0.500 2.00 10.0 40.0 200
3,3',4,4',5-Pentachlorobiphenyl 126 0.100 0.500 2.00 10.0 40.0 200
2,3,3',4,4',5-Hexachlorobiphenyl 156 0.100 0.500 2.00 10.0 40.0 200
2,3,3',4,4',5'-Hexachlorobiphenyl 157 0.100 0.500 2.00 10.0 40.0 200
2,3',4,4',5,5'-Hexachlorobiphenyl 167 0.100 0.500 2.00 10.0 40.0 200
3,3',4,4',5,5'-Hexachlorobiphenyl 169 0.100 0.500 2.00 10.0 40.0 200
2,3,3',4,4',5,5'-Heptachlorobiphenyl 189 0.100 0.500 2.00 10.0 40.0 200
NATIVE MARKER PCBs

2,4,4' -Trich lorobi phenyl 28 0.500 2.50 10.0 50.0 200 1000
2,2' ,4, 5,5'-Pentachlorobi phenyl 101 0.500 2.50 10.0 50.0 200 1000
2,2',3,4,4',5'-Hexachlorobiphenyl 138 0.500 2.50 10.0 50.0 200 1000
2,2',3,4,4',5,5'-Heptachlorobiphenyl 180 0.500 2.50 10.0 50.0 200 1000
3,4,4', 5-Tetrachloro("C,,)bi phenyl 81L 10.0 10.0 10.0 10.0 10.0 10.0
2,3,4,4', 5-Pentach loro("C,,)bi phenyl 114L 10.0 10.0 10.0 10.0 10.0 10.0
2,3' ,4,4', 5-Pentachloro("C,,)bi phenyl 118L 10.0 10.0 10.0 10.0 10.0 10.0
2,3,3',4,4',5-Hexachloro("C 12)biphenyl 156L 10.0 10.0 10.0 10.0 10.0 10.0
2,3,3',4,4',5,5'-Heptachloro("C,,)biphenyl 189L 10.0 10.0 10.0 10.0 10.0 10.0
2,4,4' -Trich loro("C 12)bi phenyl 28L 10.0 10.0 10.0 10.0 10.0 10.0
2,2' ,5, 5' -Tetrach loro("C,,)biphenyl 52L 10.0 10.0 10.0 10.0 10.0 10.0
2,2' ,4, 5,5'-Pentachloro("C,,)bi phenyl 101L 10.0 10.0 10.0 10.0 10.0 10.0
2,2',3,4,4',5'-Hexachloro("C,,)biphenyl 138L 10.0 10.0 10.0 10.0 10.0 10.0
2,2',3,4,4',5,5'-Heptachloro("C,,)biphenyl 180L 10.0 10.0 10.0 10.0 10.0 10.0
SAMPLING STANDARDS
2,3,4,4' -Tetrachloro("C,,)bi phenyl 60L 10.0 10.0 10.0 10.0 10.0 10.0
2,3,3 ',4, 5,5'-Hexach loro("C,,)bi phenyl 159L 10.0 10.0 10.0 10.0 10.0 10.0
RECOVERY STANDARDS
2,3' ,4' ,5-Tetrach loro("C,,)biphenyl 70L 10.0 10.0 10.0 10.0 10.0 10.0
2,2',3,3',4,4',5-Heptachloro("C,,)biphenyl 170L 10.0 10.0 10.0 10.0 10.0 10.0
80
P48-W-PAR: Native Dioxin-Like (WHO) PCB Solution

P48•W·PAR P48-W-PAR;EN 1948-4:2010 1.2 ml
P48-W-PAR
NATIVE DIOXIN-LIKE (WHO) PCBs IUPAC (pg/µL)
3,3'.4.4'-Tetrachlorobiphenyl 77 250
3.4.4',5-Tetrachlorobiphenyl 81 250
2,3,3'.4.4'-Pentachlorobiphenyl 105 250
2,3.4.4',5-Pentachlorobiphenyl 114 250
2',3,4,4',5-Pentachlorobiphenyl 123 250
P48-M-PAR: Native Marker PCB Solution

P48-M-PAR P48-M-PAR; EN 1948-4:2010 1.2 ml
P48-M-PAR
NATIVE MARKER PCBs IUPAC (pg/µL)
2,4,4'-Trichlorobiphenyl 28 250
2,2',4,5,5'-Pentachlorobiphenyl 101 250
2,2',3,4,4',5'-Hexachlorobiphenyl 138 250
2,2',3,4,4',5,5'-Heptachlorobiphenyl 180 250
81
SUPPORT SOLUTIONS FOR EN 1948-4:2010

P48-W-ES Dioxin-like (WHO) PCB Extraction Standard 1.2 ml
P48-M-ES Marker PCB Extraction Standard 1.2 ml
P48·SS Mass-Labelled PCBSampling Standard 1.2 ml
P48-RS Mass-Labelled PCB Recovery Standard 1.2 ml
P48-W-ES P48-M-ES P48-SS P48-RS

DIOXIN-LIKE PCB EXTRACTION STANDARD IUPAC (pg/µL) (pg/µL) (pg/µL) (pg/uL)

2,3,4,4', 5-Pentach loro("C,,)bi phenyl 114L 100
2,3' ,4,4', 5-Pentachloro("C,,)bi phenyl 118L 100
2,3,3',4,4',5-Hexachloro("C,,)biphenyl 156L 100
2,3,3',4,4',5,5'-Heptachloro("C 12)biphenyl 189L 100
MARKER PCB EXTRACTION STANDARD
2,4,4' -Trichloro("C,,)bi phenyl 28L 1000

2,2',3,4,4',5,5'-Heptachloro("C 12)biphenyl 180L 1000
MASS-LABELLED PCB SAMPLING STANDARD
2,3,4,4' -Tetrachloro("C,,)bi phenyl 60L 100

2,3,3',4,5,5'-Hexachloro("C 12)biphenyl 159L 100
MASS-LABELLED PCB RECOVERY STANDARD
2,3' ,4', 5-Tetrach loro("C,,)biphenyl lOL 100

2,2',3,3',4,4',5-Heptachloro("C 12)biphenyl 170L 100
82
PCBS:
MASS-LABELLED CONGENERS
Wellington began the preparation of 13( 12-labelled PCBsin the early 1990s and now offers an
extensive selection. This includes mass-labelled analogues of the 12 'dioxin-like' PCBsas well as
those of the more prominent congeners found in industrial mixtures and the environment.
The 13(-PCBs in the following pages were all prepared using one-product, unambiguous routes
and purified using a variety of methods. Their structures, chemical and isotopic purities were
confirmed using multiple instruments and this data is included in detailed Certificates of Analysis
{CofAs).
Additional 13(-PCBs may be added in the future, so please continue to visit our website for
updates or contact Wellington or your local distributor if you have any requests for additional
congeners.
MASS-LABELLEDPOLYCHLORINATEDBIPHENYLS
2-Chloro("C,,)biphenyl
MBP-1
1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in nonane
4-Chloro("C,,)biphenyl
MBP-3 &-0-cl
2,2'-Dichloro("C,,)biphenyl
MBP-4
2,3-Dichloro("C,,)biphenyl
MBP-5
Cl
MBP-8
a
2,5-Dichloro("C,,)biphenyl
MBP-9
MBP-11
MBP-15 Cl--0---0--0
2,2',6-Trichloro("C,,)bi phenyl
MBP-19
2,4,4'-Trichloro("C,,)biphenyl
MBP-28
84
Cl
2,4', 5-Trichloro{"C,,)bi phenyl

MBP-31
3,4,4'-Trichloro{"C,,)biphenyl
MBP-37
2,2',5,5'-Tetrachloro{"C 12)biphenyl
MBP-52
2,2' ,6,6' -Tetrach loro{"C,,)bi phenyl

MBP-54
2,3,4,4'-Tetrach loro{"C,,)biphenyl
MBP-60 a
2,3',4',5-Tetrachloro{"C,,)biphenyl
MBP-70
3,3',4,4'-Tetrachloro{"C,,)biphenyl
MBP-77
3,3',4,5'-Tetrachloro{"C,,)biphenyl
MBP-79 Cl
3,4,4',5-Tetrachloro{"C,,)biphenyl
MBP-81
C1
2,2',3,5',6-Pentachloro{"C,,)biphenyl
MBP-95
85
2,2',4,5,5'-Pentachloro("C,,)biphenyl
MBP-101
2,2' ,4, 6,6 '-Pentachloro("C,,)biphenyl

MBP-104 Cl
2,3,3',4,4'-Pentachloro("C,,)biphenyl
MBP-105
2,3,3',5,5'-Pentachloro("C,,)biphenyl
MBP-111
2,3,4,4',5-Pentachloro("C,,)biphenyl
MBP-114
Cl
2,3',4,4', 5-Pentachloro("C,,)biphenyl
MBP-118
2',3,4,4',5-Pentachloro("C,,)biphenyl
MBP-123
3,3',4,4',5-Pentachloro("C,,)biphenyl
MBP-126
3,3',4,5,5'-Pentachloro("C,,)biphenyl
MBP-127
2,2',3,3',5,5'-Hexachloro("C,,)biphenyl
MBP-133
86
2,2',3,4,4',5'-Hexachloro("C,,)biphenyl
MBP-138 a
2,2',4,4',5,5'-Hexachloro("C 12)biphenyl
MBP-153 a
MBP-155 Cl
2,3,3',4,4',5-Hexachloro("C,,)biphenyl
MBP-156 Cl
2,3,3',4,4',5'-Hexachloro("C,,)biphenyl
MBP-157
2,3,3',4,5,5'-Hexachloro("C,,)biphenyl
MBP-159 Cl
2,3,3',4',5,5'-Hexachloro("C,,)biphenyl
MBP-162
MBP-167 Cl
MBP-169 Cl
2,2',3,3',4,4', 5-Heptach loro("C,,)bi phenyl

MBP-170
87
2,2',3,3',5,5',6-Heptachloro("C 12)biphenyl
MBP-178
2,2',3,4,4',5,5'-Heptachloro("C,,)biphenyl
MBP-180 Cl
2,2',3,4',5,6,6'-Heptachloro("C 12)biphenyl
MBP-188
2,3,3',4,4',5,5'-Heptachloro("C,,)biphenyl
MBP-189
2,2',3,3',4,4',5,5'-Octachloro("C 12)biphenyl
MBP-194
2,2',3,3',5,5',6,6'-Octachloro("C,,)biphenyl
MBP-202
2,3,3',4,4',5,5',6-Octachloro("C,,)biphenyl
MBP-205
2,2',3,3',4,4',5,5',6-Nonachloro("C,,)biphenyl
MBP-206
2,2',3,3',4,5,5',6,6'-Nonachloro("C,,)biphenyl
MBP-208 Cl
Decachloro("C,,)biphenyl
MBP-209 Cl
88
PCBS:SPECIALTY
SOLUTION/MIXTURES
Additional PCBcalibration sets, and other solutions/mixtures, have been prepared and are
presented in this section.
PCB-CVS-A10 and PCB-CVS-810, and their support solutions, were designed and prepared to
be used to satisfy the requirements of the Japanese Industrial Standards JIS K 0311:2005 and
JIS K 0312:2005. Note that PCBcongeners 170 and 180, and their 13C analogues, have been
added to the 12 'dioxin-like' PCBs.Some years back these two congeners were assigned
'provisional TEFs'.
Also offered is PCB-CVS-H, a calibration set with support solutions, and solution/mixtures
containing a larger number of PCBcongeners.
All of the solutions from this section are accompanied by detailed Certificates of Analysis
{CofAs) that include HRGQLRMSand/or HRGQHRMS data as appropriate, along with RRF
summaries for each calibration set.
PCB-CVS-H

PCB-CVS-H Calibration Solutions for HRGC/HRMSAnalysis of 1 kit (6 ampoules)
Polychlorinated Biphenyls (PCBs)CS1-CS6
PCB-CS1•H cs, 200 µL
PCB•CS2•H CS2 200 µL
PCB-CS3-H CS3 200 µL
PCB-C54-H CS4 200 µL
PCB-CSS-H CS5 200 µL
PCB-CS&-H CS6 200 µL
PCB-CS1•H PCB-CS2•H PCB-CS3•H PCB-C54-H PCB-CSS•H PCB-CS&•H

NATIVE PCBs (IUPAC) (ng/mL) (ng/mL) (ng/mL) (ng/mL) (ng/mL) (ng/mL)
CHLOROBIPHENYLS 0.100 0.500 2.00 10.0 40.0 200

1, 3
DICHLOROBIPHENYLS 0.100 0.500 2.00 10.0 40.0 200
4, 6, 8, 10, 15
TRICHLOROBIPHENYLS 0.100 0.500 2.00 10.0 40.0 200
16, 18, 19, 22, 28, 31, 33, 37
TETRACHLOROBIPHENYLS 0.100 0.500 2.00 10.0 40.0 200
40, 41, 44, 49, 52, 54, 60, 66, 70,
74, 77, 81
PENTACHLOROBIPHENYLS 0.100 0.500 2.00 10.0 40.0 200
84, 85, 87, 90, 95, 97, 99, 101, 104
105, 110, 114, 118, 119, 123, 126
HEXACHLOROBIPHENYLS 0.100 0.500 2.00 10.0 40.0 200
128, 129, 135, 137, 138, 141, 149, 151,
1~1~1~1~1•1~1•1~
HEPTACHLOROBIPHENYLS 0.100 0.500 2.00 10.0 40.0 200
170,171, 174, 177, 178, 180, 183, 187,
188, 189, 191, 193
OCTACHLOROBIPHENYLS 0.100 0.500 2.00 10.0 40.0 200
194, 199, 200, 201, 202, 203, 205
NONACHLOROBIPHENYLS 0.100 0.500 2.00 10.0 40.0 200
206, 207, 208
DECACHLOROBIPHENYL 0.100 0.500 2.00 10.0 40.0 200
209
2-Chloro("C,,)biphenyl 1L 50.0 50.0 50.0 50.0 50.0 50.0
4-Chloro("C,,)biphenyl 3L 50.0 50.0 50.0 50.0 50.0 50.0
2,2'-Dichloro("C,,)biphenyl 4L 50.0 50.0 50.0 50.0 50.0 50.0
2,4'-Dichloro("C.,)biphenyl BL 50.0 50.0 50.0 50.0 50.0 50.0
4,4'-Dichloro("C,,)biphenyl 15L 50.0 50.0 50.0 50.0 50.0 50.0
2,2',6-Trichloro("C,,)biphenyl 19L 50.0 50.0 50.0 50.0 50.0 50.0
2,4,4'-Trichloro("C,,)biphenyl 28L 50.0 50.0 50.0 50.0 50.0 50.0
2,3',4',5-Tetrachloro(''C,,)biphenyl 70L 50.0 50.0 50.0 50.0 50.0 50.0
3,4,4',5-Tetrachloro("C.,)biphenyl 81L 50.0 50.0 50.0 50.0 50.0 50.0
2,2',4,6,6'-Pentachloro("C.,)biphenyl 104L 50.0 50.0 50.0 50.0 50.0 50.0
2,3,4,4',5-Pentachloro("C,,)biphenyl 114L 50.0 50.0 50.0 50.0 50.0 50.0
3,3' ,4,4', 5-Pentach loro("C,,)bi phenyl 126L 50.0 50.0 50.0 50.0 50.0 50.0
2,2',3,4,4',5'-Hexachloro("C,,)biphenyl 138L 50.0 50.0 50.0 50.0 50.0 50.0
2,2',4,4',5,5'-Hexachloro(''C,,)biphenyl 153L 50.0 50.0 50.0 50.0 50.0 50.0
2,3,3',4,4',5-Hexachloro("C,,)biphenyl 156L 50.0 50.0 50.0 50.0 50.0 50.0
2,2' ,3,3 ',4,4', 5-Heptachloro("C.,)biphenyl 170L 50.0 50.0 50.0 50.0 50.0 50.0
2,2',3,4,4',5,5'-Heptachloro("C,,)biphenyl 180L 50.0 50.0 50.0 50.0 50.0 50.0
2,2',3,4',5,6,6'-Heptachloro("C,,)biphenyl 188L 50.0 50.0 50.0 50.0 50.0 50.0
2,3,3',4,4',5,5'-Heptachloro("C,,)biphenyl 189L 50.0 50.0 50.0 50.0 50.0 50.0
2,2',3,3',5,5',6,6'-Octachloro("C,,)biphenyl 202L 50.0 50.0 50.0 50.0 50.0 50.0
2,3,3',4,4',5,5',6-Octachloro("C,,)biphenyl 205L 50.0 50.0 50.0 50.0 50.0 50.0
2,2',3,3',4,5,5',6,6'-Nonachloro("C,,)biphenyl 208L 50.0 50.0 50.0 50.0 50.0 50.0
Decachloro("C,,)biphenyl 209L 50.0 50.0 50.0 50.0 50.0 50.0
RECOVERY/INTERNAL STANDARDS
2,5-Dichloro("C,,)biphenyl 9L 50.0 50.0 50.0 50.0 50.0 50.0
3,4,4'-Trichloro("C,,)biphenyl 37L 50.0 50.0 50.0 50.0 50.0 50.0
3,3',4,5'-Tetrachloro("C,,)biphenyl 79L so.a so.a so.a so.a so.a so.a
2,3,3',4',5,5'-Hexachloro("C,,)biphenyl 162L 50.0 50.0 50.0 50.0 50.0 50.0
2,2',3,3',4,4',5,5'-Octachloro(''C,,)biphenyl 194L 50.0 50.0 50.0 50.0 50.0 50.0
2,2',3,3',4,4',5,5',6-Nonachloro("C,,)biphenyl 206L 50.0 50.0 50.0 50.0 50.0 50.0
SAMPLING/CLEANUP STANDARDS
2,3,3',4,5,5'-Hexachloro("C.,)biphenyl 159L 50.0 50.0 50.0 50.0 50.0 50.0
90
PCB-CVS-H

PCB-LCS-H Mass-Labelled PCB Extraction Standards 1.2 ml
PCB-155-H Mass-Labelled PCB Recovery/Internal Standards 1.2 ml
PCB-SCS•H Mass-Labelled PCBSampling/Cleanup Standards 1.2 ml
PCB•PAR•H Native PCBSolution 1.2 ml
PCB-LCS•H PCB-ISS•H PCB-SCS•H PCB•PAR•H

NATIVE PCBs (IUPAC) (ng/mL} (ng/mL} (ng/mL} (ng/mL}
CHLOROBIPHENYLS 500
1, 3
DICHLOROBIPHENYLS 500
4, 6, 8, 10, 15
TRICHLOROBIPHENYLS 500
16, 18, 19, 22, 28, 31, 33, 37
TETRACHLOROBIPHENYLS 500
40, 41, 44, 49, 52, 54, 60, 66, 70,
74, 77, 81
PENTACHLOROBIPHENYLS 500
84, 85, 87, 90, 95, 97, 99, 101, 104
105, 110, 114, 118, 119, 123, 126
HEXACHLOROBIPHENYLS 500
128, 129, 135, 137, 138, 141, 149, 151,
1~1~1~1~1•1~1•1~
HEPTACHLOROBIPHENYLS 500
170,171, 174, 177, 178, 180, 183, 187,
188, 189, 191, 193
OCTACHLOROBIPHENYLS 500
194, 199, 200, 201, 202, 203, 205
NONACHLOROBIPHENYLS 500
206, 207, 208
DECACHLOROBIPHENYL 500
209
2,4'-Dichloro("C,,)biphenyl BL 1000
2,2',6-Trichloro("C,,)biphenyl 791 1000
2,2',5,5'-Tetrachloro("C,,)biphenyl 521 1000
2,3',4',5-Tetrachloro("C,,)biphenyl 70L 1000
2,2',3,5',6-Pentachloro("C,,)biphenyl 951 1000
2,3,3',4,4'-Pentachloro("C,,)biphenyl 7051 1000
2,3,4,4',5-Pentachloro("C,,)biphenyl 114L 1000
3,3' ,4,4', 5-Pentach loro("C,,)bi phenyl 126L 1000
2,2',3,4,4',5'-Hexachloro("C,,)biphenyl 1381 1000
2,2',4,4',5,5'-Hexachloro("C,,)biphenyl 1531 1000
2,2',4,4',6,6'-Hexachloro("C,,)biphenyl 1551 1000
2,3,3',4,4',5-Hexachloro("C,,)biphenyl 7561 1000
2,2' ,3,3 ',4,4', 5-Heptachloro("C,,)biphenyl 170L 1000
2,2',3,4,4',5,5'-Heptachloro("C,,)biphenyl 7801 1000
2,2',3,4',5,6,6'-Heptachloro(''C,,)biphenyl 7881 1000
2,3,3',4,4',5,5'-Heptachloro("C,,)biphenyl 1891 1000
2,2',3,3',5,5',6,6'-Octachloro("C,,)biphenyl 2021 1000
2,3,3',4,4',5,5',6-Octachloro("C,,)biphenyl 205L 1000
2,2',3,3',4,5,5',6,6'-Nonachloro("C,,)biphenyl 208L 1000
RECOVERY/INTERNAL STANDARDS
2,5-Dichloro("C,,)biphenyl 91 1000
3,4,4'-Trichloro("C,,)biphenyl 371 1000
3,3',4,5'-Tetrachloro("C,,)biphenyl 791 1000
2,3,3',4',5,5'-Hexachloro("C,,)biphenyl 162L 1000
2,2',3,3',4,4',5,5'-Octachloro(''C,,)biphenyl 194L 1000
2,2',3,3',4,4',5,5',6-Nonachloro("C,,)biphenyl 206L 1000
SAMPLING/CLEANUP STANDARDS
2,3,4,4'-Tetrachloro("C,,)biphenyl 601 1000
2,3,3',4,5,5'-Hexachloro("C,,)biphenyl 1591 1000
91
PCB-CVS-A10

PCB-CVS•A10-Set1 CS1/CS3/CS5/CS7/CS9 1 kit (5 ampoules)
PCB-CVS-A10-Set2 CS2/CS4/CS6/CS8/CS10 1 kit (5 ampoules)
PCB-CVS-A10•Set3 CS3/CS5/CS7/CS9/CS11 1 kit (5 ampoules)
PCB·A10-CSL CSL Extended Calibration/Low Level 200 µL
PCB·A10-CS1 CS1 200 µL
PCB·A10·CS2 CS2 200 µL
PCB-A10- PCB-A10- PCB-A10- PCB-A10- PCB-A10-

CSL CS1 CS2 CS3 CS4
NATIVE PCBs IUPAC {ng/ml) {ng/ml) {ng/ml) {ng/ml) {ng/ml)
3,3',4,4'-Tetrachlorobiphenyl 77 0.0500 0.100 0.200 0.500 1.00

3,4,4',5-Tetrachlorobiphenyl 81 0.0500 0.100 0.200 0.500 1.00
2,3,3',4,4'-Pentachlorobiphenyl 105 0.0500 0.100 0.200 0.500 1.00
2,3,4,4',5-Pentachlorobiphenyl 114 0.0500 0.100 0.200 0.500 1.00
2,3',4,4',5-Pentachlorobiphenyl 118 0.0500 0.100 0.200 0.500 1.00
2',3,4,4',5-Pentachlorobiphenyl 123 0.0500 0.100 0.200 0.500 1.00
3,3',4,4',5-Pentachlorobiphenyl 126 0.0500 0.100 0.200 0.500 1.00
2,3,3',4,4',5-Hexachlorobiphenyl 156 0.0500 0.100 0.200 0.500 1.00
2,3,3',4,4',5'-Hexachlorobiphenyl 157 0.0500 0.100 0.200 0.500 1.00
2,3',4,4',5,5'-Hexachlorobiphenyl 167 0.0500 0.100 0.200 0.500 1.00
3,3',4,4',5,5'-Hexachlorobiphenyl 169 0.0500 0.100 0.200 0.500 1.00
2,2',3,3',4,4',5-Heptachlorobiphenyl 170 0.0500 0.100 0.200 0.500 1.00
2,2',3,4,4',5,5'-Heptachlorobiphenyl 180 0.0500 0.100 0.200 0.500 1.00
2,3,3',4,4',5,5'-Heptachlorobiphenyl 189 0.0500 0.100 0.200 0.500 1.00
EXTRACTION SPIKE
3,3' ,4,4' -Tetrach loro("C,,)biphenyl 77L 10.0 10.0 10.0 10.0 10.0
3,4,4',5-Tetrachloro("C,,)biphenyl 81L 10.0 10.0 10.0 10.0 10.0
2,3,3',4,4'-Pentachloro("C,,)biphenyl 105L 10.0 10.0 10.0 10.0 10.0
2,3,4,4', 5-Pentach loro("C,,)bi phenyl 114L 10.0 10.0 10.0 10.0 10.0
2,3' ,4,4', 5-Pentachloro("C 12)bi phenyl 118L 10.0 10.0 10.0 10.0 10.0
2 ',3,4,4', 5-Pentachloro("C,,)bi phenyl 123L 10.0 10.0 10.0 10.0 10.0
3,3' ,4,4', 5-Pentachloro("C,,)bi phenyl 126L 10.0 10.0 10.0 10.0 10.0
2,3,3',4,4',5-Hexachloro("C,,)biphenyl 156L 10.0 10.0 10.0 10.0 10.0
2,3,3',4,4',5'-Hexachloro("C,,)biphenyl 157L 10.0 10.0 10.0 10.0 10.0
2,3',4,4',5,5'-Hexachloro("C,,)biphenyl 167L 10.0 10.0 10.0 10.0 10.0
3,3',4,4',5,5'-Hexachloro("C,,)biphenyl 169L 10.0 10.0 10.0 10.0 10.0
2,2',3,3',4,4',5-Heptachloro("C,,)biphenyl 170L 10.0 10.0 10.0 10.0 10.0
2,2',3,4,4',5,5'-Heptachloro("C,,)biphenyl 180L 10.0 10.0 10.0 10.0 10.0
2,3,3',4,4',5,5'-Heptachloro("C,,)biphenyl 189L 10.0 10.0 10.0 10.0 10.0
SYRINGE SPIKE
2,3' ,4', 5-Tetrach loro("C,,)biphenyl 70L 10.0 10.0 10.0 10.0 10.0
2,3,3',5,5'-Pentachloro("C,,)biphenyl 111L 10.0 10.0 10.0 10.0 10.0
2,2',3,4,4',5'-Hexachloro("C,,)biphenyl 138L 10.0 10.0 10.0 10.0 10.0
SAMPLING SPIKE
3,3' ,4, 5' -Tetrach loro("C,,)biphenyl 79L 10.0 10.0 10.0 10.0 10.0
92
PCB-CVS-A
10

PCB·A10-CS6 CSG 200 µL
PCB·A10-CS8 css 200 µL
PCB·A10-CSH CSH Extended Calibration/High Level 200 µL
PCB-A10- PCB-A10- PCB-A10- PCB-A10- PCB-A10- PCB-A10- PCB-A10- PCB-A10-

css CS6 CS7 css CS9 CS10 CS11 CSH
(ng/ml) (ng/ml) (ng/ml) (ng/ml) (ng/ml) (ng/ml) (ng/ml) (ng/ml)
2.00 5.00 10.0 20.0 50.0 100 250 1000

2.00 5.00 10.0 20.0 50.0 100 250 1000
2.00 5.00 10.0 20.0 50.0 100 250 1000
2.00 5.00 10.0 20.0 50.0 100 250 1000
2.00 5.00 10.0 20.0 50.0 100 250 1000
2.00 5.00 10.0 20.0 50.0 100 250 1000
2.00 5.00 10.0 20.0 50.0 100 250 1000
2.00 5.00 10.0 20.0 50.0 100 250 1000
2.00 5.00 10.0 20.0 50.0 100 250 1000
2.00 5.00 10.0 20.0 50.0 100 250 1000
2.00 5.00 10.0 20.0 50.0 100 250 1000
2.00 5.00 10.0 20.0 50.0 100 250 1000
2.00 5.00 10.0 20.0 50.0 100 250 1000
2.00 5.00 10.0 20.0 50.0 100 250 1000
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0

10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0

10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
93
PCB-CVS-B10

PCB-CVS•B10-Set1 CS1/ CS2/CS3/CS4/CS5 1 kit (5 ampoules)
PCB-CVS-B1O-Set2 CS2/CS3/CS4/CS5/CS6 1 kit (5 ampoules)
PCB·B10·CS1 CS1 200 µL
PCB-B10-CS2 CS2 200 µL
PCB-810- PCB-810- PCB-810-

cs, CS2 CS3
NATIVE PCBs IUPAC (ng/ml) (ng/ml) (ng/ml)
3,3',4,4'-Tetrachlorobiphenyl 77 0.200 1.00 4.00

3,4,4',5-Tetrachlorobiphenyl 81 0.200 1.00 4.00
2,3,3',4,4'-Pentachlorobiphenyl 105 0.200 1.00 4.00
2,3,4,4', 5-Pentach lorobiphenyl 114 0.200 1.00 4.00
2,3' ,4,4', 5-Pentachlorobi phenyl 118 0.200 1.00 4.00
2 ',3,4,4', 5-Pentachlorobi phenyl 123 0.200 1.00 4.00
2,3,3',4,4',5-Hexachlorobiphenyl 156 0.200 1.00 4.00
2,3,3',4,4',5'-Hexachlorobiphenyl 157 0.200 1.00 4.00
2,2',3,3',4,4',5-Heptachlorobiphenyl 170 0.200 1.00 4.00
2,2',3,4,4',5,5'-Heptachlorobiphenyl 180 0.200 1.00 4.00
2,3,3',4,4',5,5'-Heptachlorobiphenyl 189 0.200 1.00 4.00
EXTRACTION SPIKE
3,3' ,4,4' -Tetrach loro("C,,)biphenyl 77L 10.0 10.0 10.0

3,4,4',5-Tetrachloro("C,,)biphenyl 81L 10.0 10.0 10.0
2,3,4,4', 5-Pentach loro("C,,)bi phenyl 114L 10.0 10.0 10.0
2',3,4,4',5-Pentachloro("C,,)biphenyl 123L 10.0 10.0 10.0
2,3,3',4,4',5-Hexachloro("C,,)biphenyl 156L 10.0 10.0 10.0
2,3,3',4,4',5'-Hexachloro("C,,)biphenyl 157L 10.0 10.0 10.0
3,3',4,4',5,5'-Hexachloro("C 12)biphenyl 169L 10.0 10.0 10.0
2,2',3,4,4',5,5'-Heptachloro("C,,)biphenyl 180L 10.0 10.0 10.0
2,3,3',4,4',5,5'-Heptachloro("C 12)biphenyl 189L 10.0 10.0 10.0
SYRINGE SPIKE
2,3' ,4' ,5-Tetrach loro("C,,)biphenyl 70L 10.0 10.0 10.0

2,2',3,4,4',5'-Hexachloro("C,,)biphenyl 138L 10.0 10.0 10.0
SAMPLING SPIKE
94
PCB-CVS-B10

PCB·B10·CS6 CSG 200 µL
PCB-B10- PCB-B10- PCB-B10- PCB-B10-

CS4 css CS6 CS7
NATIVE PCBs IUPAC (ng/ml) (ng/ml) (ng/ml) (ng/ml)
3,3',4,4'-Tetrachlorobiphenyl 77 20.0 100 400 1000

3,4,4',5-Tetrachlorobiphenyl 81 20.0 100 400 1000
2,3,3',4,4'-Pentachlorobiphenyl 105 20.0 100 400 1000
2,3,4,4', 5-Pentach lorobiphenyl 114 20.0 100 400 1000
2,3' ,4,4', 5-Pentachlorobi phenyl 118 20.0 100 400 1000
2 ',3,4,4', 5-Pentachlorobi phenyl 123 20.0 100 400 1000
3,3',4,4',5-Pentachlorobiphenyl 126 20.0 100 400 1000
2,3,3',4,4',5-Hexachlorobiphenyl 156 20.0 100 400 1000
2,3,3',4,4',5'-Hexachlorobiphenyl 157 20.0 100 400 1000
2,2',3,3',4,4',5-Heptachlorobiphenyl 170 20.0 100 400 1000
2,2',3,4,4',5,5'-Heptachlorobiphenyl 180 20.0 100 400 1000
2,3,3',4,4',5,5'-Heptachlorobiphenyl 189 20.0 100 400 1000
EXTRACTION SPIKE
3,3' ,4,4' -Tetrach loro("C,,)biphenyl 77L 10.0 10.0 10.0 10.0

3,4,4',5-Tetrachloro("C,,)biphenyl 81L 10.0 10.0 10.0 10.0
2,3,4,4', 5-Pentach loro("C,,)bi phenyl 114L 10.0 10.0 10.0 10.0
2,3',4,4',5-Pentachloro("C,,)biphenyl 118L 10.0 10.0 10.0 10.0
2',3,4,4',5-Pentachloro("C,,)biphenyl 123L 10.0 10.0 10.0 10.0
3,3' ,4,4', 5-Pentachloro("C,,)bi phenyl 126L 10.0 10.0 10.0 10.0
2,3,3',4,4',5-Hexachloro("C,,)biphenyl 156L 10.0 10.0 10.0 10.0
2,3,3',4,4',5'-Hexachloro("C,,)biphenyl 157L 10.0 10.0 10.0 10.0
2,3',4,4',5,5'-Hexachloro("C,,)biphenyl 167L 10.0 10.0 10.0 10.0
3,3',4,4',5,5'-Hexachloro("C,,)biphenyl 169L 10.0 10.0 10.0 10.0
2,2',3,4,4',5,5'-Heptachloro("C,,)biphenyl 180L 10.0 10.0 10.0 10.0
2,3,3',4,4',5,5'-Heptachloro("C,,)biphenyl 189L 10.0 10.0 10.0 10.0
SYRINGE SPIKE
2,3' ,4' ,5-Tetrach loro("C,,)biphenyl 70L 10.0 10.0 10.0 10.0

2,2',3,4,4',5'-Hexachloro("C,,)biphenyl 138L 10.0 10.0 10.0 10.0
SAMPLING SPIKE
95
MASS-LABELLEDPCBs:SOLUTION/MIXTURES
Support solutions for PCB-CVS-A10, PCB-CVS-810, and DFP-CVS-810

PCB-LCS-A1 Mass-Labelled PCBSolution/Mixture 1.2 ml
PCB-LCS-A100 Mass-Labelled PCBSolution/Mixture 1.2 ml
PCB-LCS·A20 Mass-Labelled PCBSolution/Mixture 1.2 ml
PCB-LCS-A1 PCB-LCS-A 100 PCB-LCS-A20

MASS-LABELLED PCBs IUPAC (ng/mL) (ng/mL) (ng/mL)
3,3',4,4'-Tetrachloro("C,,)biphenyl lll 1000 100 20.0
3,4,4',5-Tetrachloro("C,,)biphenyl 81L 1000 100 20.0
2,3,3 ',4,4' -Pentach loro("C 12)bi phenyl 105L 1000 100 20.0
2,3,4,4', 5-Pentach loro("C 12)bi phenyl 114L 1000 100 20.0
2,3 ',4,4', 5-Pentach loro("C 12)bi phenyl 11BL 1000 100 20.0
2' ,3,4,4', 5-Pentach loro("C 12)bi phenyl 123L 1000 100 20.0
3,3 ',4,4', 5-Pentach loro("C 12)bi phenyl 126L 1000 100 20.0
2,3,3',4,4',5-Hexachloro("C 12)biphenyl 156L 1000 100 20.0
2,3,3',4,4',5'-Hexachloro("C,,)biphenyl 157L 1000 100 20.0
2,3',4,4',5,5'-Hexachloro("C 12)biphenyl 167L 1000 100 20.0
3,3',4,4',5,5'-Hexachloro("C 12)biphenyl 169L 1000 100 20.0
2,2',3,3',4,4',5-Heptachloro("C,,)biphenyl 170L 1000 100 20.0
2,2',3,4,4',5,5'-Heptachloro("C,,)biphenyl 180L 1000 100 20.0
2,3,3',4,4',5,5'-Heptachloro("C, 2)biphenyl 189L 1000 100 20.0
PCB-IS-A Mass-Labelled PCBSolution 1.2 ml

PCB-IS-A100 Mass-Labelled PCBSolution 1.2 ml
PCB-IS-A20 Mass-Labelled PCBSolution 1.2 ml
PCB-IS-A PCB-IS-A100 PCB-IS-A20

2,3',4',5-Tetrachloro("C,,)biphenyl 70L 1000 100 20.0
PCB-15-B Mass-Labelled PCBSolution/Mixture 1.2 ml

PCB-IS-B100 Mass-Labelled PCBSolution/Mixture 1.2 ml
PCB-IS-B20 Mass-Labelled PCBSolution/Mixture 1.2 ml
PCB-IS-B PCB-IS-B100 PCB-IS-B20

2,3',4',5-Tetrachloro("C,,)biphenyl lOL 1000 100 20.0
2,3,3',5,5'-Pentachloro("C,,)biphenyl 111L 1000 100 20.0
2,2',3,4,4',5'-Hexachloro("C, 2)biphenyl 13BL 1000 100 20.0
PCB-15-C Mass-Labelled PCBSolution/Mixture 1.2 ml

PCB-IS-C100 Mass-Labelled PCBSolution/Mixture 1.2 ml
PCB-IS-C20 Mass-Labelled PCBSolution/Mixture 1.2 ml
PCB-IS-C PCB-IS-C100 PCB-IS-C20

2,3',4',5-Tetrachloro("C,,)biphenyl lOL 1000 100 20.0
2,3,3',5,5'-Pentachloro("C, 2)biphenyl 111L 1000 100 20.0
2,2',3,4,4',5'-Hexachloro("C, 2)biphenyl 13BL 1000 100 20.0
2,2',3,3',5,5',6-Heptachloro("C, 2)biphenyl 17BL 1000 100 20.0
PCB-55-A Mass-Labelled PCBSolution 1.2 ml

PCB-SS-A100 Mass-Labelled PCBSolution 1.2 ml
PCB-SS-A20 Mass-Labelled PCBSolution 1.2 ml
PCB-SS-A PCB-SS-A100 PCB-SS-A20

3,3',4,5'-Tetrachloro("C,,)biphenyl 79L 1000 100 20.0
96
MASS-LABELLEDPCBs:SOLUTION/MIXTURES

MBP·CP Mass-Labelled Coplanar PCBSolution/Mixture 1.2 ml
IUPAC
3,3',4,4'-Tetrachloro{"C,,)biphenyl 77L 10.0 µg/ml
3,4,4',5-Tetrachloro{"C,,)biphenyl 81L 10.0 µg/ml
3,3' ,4,4' ,5-Pentachloro{"C,,)biphenyl 126L 10.0 µg/ml
3,3' ,4,4' ,5,5'-Hexachloro{"C,,)biphenyl 169L 10.0 µg/ml
MBP-MO Mass-Labelled Mono-ortho PCBSolution/Mixture 1.2 ml

IUPAC
2,3,3',4,4' -Pentach loro{"C,,)biphenyl 105L 5.00 µg/ml
2,3,4,4',5-Pentachloro{"C,,)biphenyl 114L 5.00 µg/ml
2,3 ',4,4', 5-Pentachloro{"C,,)biphenyl 118L 5.00 µg/ml
2 ',3,4,4', 5-Pentachloro{"C,,)biphenyl 123L 5.00 µg/ml
2,3,3',4,4', 5-Hexachloro{"C,,)bi phenyl 156L 5.00 µg/ml
2,3,3',4,4',5'-Hexachloro{"C,,)biphenyl 157L 5.00 µg/ml
2,3',4,4',5,5'-Hexachloro{"C,,)biphenyl 167L 5.00 µg/ml
2,3,3',4,4',5,5'-Heptachloro{"C,,)biphenyl 189L 5.00 µg/ml
MBP·CG Mass-Labelled Mono to Decachloro PCBSolution/Mixture 1.2 ml

IUPAC
4-Chloro{"C,,)biphenyl 3L 5.00 µg/ml
4,4' -Dichloro{"C,,)biphenyl 15L 5.00 µg/ml
2,4',5-Trichloro{"C,,)bi phenyl 31L 5.00 µg/ml
2,3',4,4',5-Pentachloro{"C,,)biphenyl 118L 5.00 µg/ml
2,2',3,4,4',5,5'-Heptachloro{"C,,)biphenyl 180L 5.00 µg/ml
2,2',3,3',4,4',5,5'-Octachloro{"C,,)biphenyl 194L 5.00 µg/ml
2,2',3,3',4,4',5,5',6-Nonachloro{"C,,)biphenyl 206L 5.00 µg/ml
Decachloro{"C,,)biphenyl 209L 5.00 µg/ml
MBP·MXE Mass-Labelled PCBSolution/Mixture 1.2 ml

IUPAC
2,4,4' -Trichloro{"C,,)bi phenyl 28L 5.00 µg/ml
2,2 ',4, 5,5' -Pentach loro{"C,,)biphenyl 101L 5.00 µg/ml
2,2',3,4,4',5'-Hexachloro{"C,,)biphenyl 138L 5.00 µg/ml
2,2',3,4,4',5,5'-Heptachloro{"C,,)biphenyl 180L 5.00 µg/ml
Decachloro{ 'C,,)biphenyl
1 209L 5.00 µg/ml
97
NATIVE PCBs:SOLUTION/MIXTURES
(*) Support solutions for PCB-CVS-A10, PCB-CVS-B10, and DFP-CVS-B10

PCB-ST-A* Native PCBStock Solution/Mixture 1.2 ml
PCB-ST-A10* Native PCBStock Solution/Mixture 1.2 ml
PCB-ST·A2* Native PCBStock Solution/Mixture 1.2 ml
PCB-ST-A* PCB-ST-A10* PCB-ST-A2*

NATIVE PCBs IUPAC (ng/ml) (ng/ml) (ng/ml)
3,3',4,4'-Tetrachlorobiphenyl 77 2000 10.0 2.00

3,4,4',5-Tetrachlorobiphenyl 81 2000 10.0 2.00
2,3,3',4,4'-Pentachlorobiphenyl 105 2000 10.0 2.00
2,3,4,4',5-Pentachlorobiphenyl 114 2000 10.0 2.00
2,3',4,4',5-Pentachlorobiphenyl 118 2000 10.0 2.00
2 ',3,4,4', 5-Pentachlorobi phenyl 123 2000 10.0 2.00
3,3' ,4,4', 5-Pentachlorobi phenyl 126 2000 10.0 2.00
2,3,3',4,4',5-Hexachlorobiphenyl 156 2000 10.0 2.00
2,3,3',4,4',5'-Hexachlorobiphenyl 157 2000 10.0 2.00
2,3',4,4',5,5'-Hexachlorobiphenyl 167 2000 10.0 2.00
3,3',4,4',5,5'-Hexachlorobiphenyl 169 2000 10.0 2.00
2,2',3,3',4,4',5-Heptachlorobiphenyl 170 2000 10.0 2.00
2,2',3,4,4',5,5'-Heptachlorobiphenyl 180 2000 10.0 2.00
2,3,3',4,4',5,5'-Heptachlorobiphenyl 189 2000 10.0 2.00
BP-CP81

BP·CP81 Native Coplanar PCBSolution/Mixture 1.2 ml
NATIVE PCBs IUPAC
3,3',4,4'-Tetrachlorobiphenyl 77 10.0 µg/ml

3,4,4',5-Tetrachlorobiphenyl 81 10.0 µg/ml
3,3',4,4',5-Pentachlorobiphenyl 126 10.0 µg/ml
3,3',4,4',5,5'-Hexachlorobiphenyl 169 10.0 µg/ml
98
BP-WD

BP•WD Native PCBWindow Defining Solution/Mixture 1.2 ml
for DB-5 or Equivalent Columns
NATIVE PCBs IUPAC
Biphenyl 2.50 µg/ml

2-Chlorobiphenyl 2.50 µg/ml
4-Chlorobiphenyl 3 2.50 µg/ml
2,6-Dichlorobiphenyl 10 2.50 µg/ml
4,4'-Dichlorobiphenyl 15 2.50 µg/ml
2,2',6-Trichlorobi phenyl 19 2.50 µg/ml
3,4,4'-Trichlorobi phenyl 37 2.50 µg/ml
2,2',4,6,6'-Pentachlorobiphenyl 104 2.50 µg/ml
3,3',4,4',5-Pentachlorobiphenyl 126 2.50 µg/ml
2,2',3,4',5,6,6'-Heptachlorobiphenyl 188 2.50 µg/ml
2,3,3',4,4',5,5'-Heptachlorobiphenyl 189 2.50 µg/ml
2,2',3,3',5,5',6,6'-Octachlorobiphenyl 202 2.50 µg/ml
2,3,3',4,4',5,5',6-Octachlorobiphenyl 205 2.50 µg/ml
2,2',3,3',4,4',5,5',6-Nonachlorobiphenyl 206 2.50 µg/ml
2,2',3,3',4,5,5',6,6'-Nonachlorobiphenyl 208 2.50 µg/ml
Decachlorobiphenyl 209 2.50 µg/ml
BP-MO
BP-MO Native Mono-ortho PCBSolution/Mixture 1.2 ml
NATIVE PCBs IUPAC
2,3,3',4,4'-Pentachlorobiphenyl 105 10.0 µg/ml

2,3,4,4',5-Pentachlorobiphenyl 114 10.0 µg/ml
2,3',4,4', 5-Pentachlorobi phenyl 118 10.0 µg/ml
2',3,4,4', 5-Pentachlorobi phenyl 123 10.0 µg/ml
2,3,3',4,4',5-Hexachlorobiphenyl 156 10.0 µg/ml
2,3,3',4,4',5'-Hexachlorobiphenyl 157 10.0 µg/ml
2,3,3',4,4',5,5'-Heptachlorobiphenyl 189 10.0 µg/ml
99
BP-MS
BP-MS-PL1, BP-MS-PL2,and BP-MS-PL3were preparedto be usedin the identification/confirmation
of the PCBcongenersin
BP-MS.AlthoughDB-5data is providedwith BP-MS,therecan be changesin the elutionorderon "equivalentcapillarycolumns".

BP-MS Native PCBSolution/Mixture for MS Detection 1.2 ml
BP-MS2 Native PCBSolution/Mixture for MS Detection 1.2 ml
BP-MS-PL1 Native PCBSolution/Mixture for MS Detection 1.2 ml
BP-MS-PL2 Native PCBSolution/Mixture for MS Detection 1.2 ml
BP-MS·PL3 Native PCBSolution/Mixture for MS Detection 1.2 ml
BP-MS BP-MS2 BP-MS· BP-MS· BP-MS·

PL1 PL2 PL3
PCB CONGENERS IUPAC (1,1g/ml) (1,1g/ml) (1,1g/ml) (1,1g/ml) (1,1g/ml)
2-Chlorobiphenyl 1 2.00
4-Chlorobiphenyl 3 2.00
2,2'-Dichlorobiphenyl 4 2.00
2,4'-Dichlorobiphenyl 8 2.00
2,6- Dichlorobiphenyl 10 2.00
*4,4'-Dichlorobiphenyl 15 2.00
*2,2',5-Trichlorobiphenyl 18 2.00
2,2',6-Trichlorobiphenyl 19 2.00
2,3,4'-Trichlorobiphenyl 22 2.00
2',3,4-Trichlorobiphenyl 33 2.00
2,2',3,4-Tetrachlorobiphenyl 41 2.00
*2,2',3,5'-Tetrachlorobiphenyl 44 2.00
*2,2',4,5'-Tetrachlorobiphenyl 49 2.00 2.00
*2,2',6,6'-Tetrachlorobiphenyl 54 2.00
2,3,4,4'-Tetrachlorobiphenyl 60 2.00
2,3',4',5-Tetrachlorobiphenyl 70 2.00 2.00
2,4,4',5-Tetrachlorobiphenyl 74 2.00 2.00
3,4,4',5-Tetrachlorobiphenyl 81 2.00
*2,2',3,4,5'-Pentachlorobiphenyl 87 2.00 2.00
2,2',3,4',5-Pentachlorobiphenyl 90 2.00
2,2',3,5',6-Pentachlorobiphenyl 95 2.00 2.00
2,2',4,4',5-Pentachlorobiphenyl 99 2.00 2.00
*2,2',4,5,5'-Pentachlorobiphenyl 101 2.00 2.00
2,2',4,6,6'-Pentachlorobiphenyl 104 2.00
*2,3,3',4,4'-Pentachlorobiphenyl 105 2.00
2,3,3',4',6-Pentachlorobiphenyl 110 2.00 2.00
*2,3,4,4',5-Pentachlorobiphenyl 114 2.00
*2,3',4,4',5-Pentachlorobiphenyl 118 2.00
2',3,4,4',5-Pentachlorobiphenyl 123 2.00
*2,2',3,3',4,4'-Hexachlorobiphenyl 128 2.00 2.00
2,2',3,3',4,5-Hexachlorobiphenyl 129 2.00
2,2',3,4,4',5-Hexachlorobiphenyl 137 2.00
*2,2',3,4,4',5'-Hexachlorobiphenyl 138 2.00 2.00
2,2',3,4,5,5'-Hexachlorobiphenyl 141 2.00
2,2',3,4',5',6-Hexachlorobiphenyl 149 2.00 2.00
*2,2',3,5,5',6-Hexachlorobiphenyl 151 2.00 2.00
*2,2',4,4',5,5'-Hexachlorobiphenyl 153 2.00 2.00
2,2',4,4',6,6'-Hexachlorobiphenyl 155 2.00 2.00
*2,3,3',4,4',5-Hexachlorobiphenyl 156 2.00
2,3,3',4,4',5'-Hexachlorobiphenyl 157 2.00
2,3,3',4,4',6-Hexachlorobiphenyl 158 2.00 2.00
2,3',4,4',5,5'-Hexachlorobiphenyl 167 2.00
2,3',4,4',5',6-Hexachlorobiphenyl 168 2.00 2.00
3,3',4,4',5,5'-Hexachlorobiphenyl 169 2.00
*2,2',3,3',4,4',5-Heptachlorobiphenyl 170 2.00
*2,2',3,3',4,4',6-Heptachlorobiphenyl 171 2.00 2.00
2,2',3,3',4',5,6-Heptachlorobiphenyl 177 2.00 2.00
2,2',3,3',5,5',6-Heptachlorobiphenyl 178 2.00 2.00
*2,2',3,4,4',5,5'-Heptachlorobiphenyl 180 2.00 2.00
*2,2',3,4,4',5',6-Heptachlorobiphenyl 183 2.00
*2,2',3,4',5,5',6-Heptachlorobiphenyl 187 2.00
2,2',3,4',5,6,6'-Heptachlorobiphenyl 188 2.00 2.00
*2,3,3',4,4',5,5'-Heptachlorobiphenyl 189 2.00
*2,3,3',4,4',5',6-Heptachlorobiphenyl 191 2.00
2,3,3',4',5,5',6-Heptachlorobiphenyl 193 2.00
*2,2',3,3',4,4',5,5'-Octachlorobiphenyl 194 2.00
*2,2',3,3',4,5,5',6'-Octachlorobiphenyl 199 2.00
*2,2',3,3',4,5',6,6'-Octachlorobiphenyl 201 2.00 2.00
*2,2',3,3',5,5',6,6'-Octachlorobiphenyl 202 2.00 2.00
2,2',3,4,4',5,5',6-Octachlorobiphenyl 203 2.00
*2,3,3',4,4',5,5',6-Octachlorobiphenyl 205 2.00
*2,2',3,3',4,4',5,5',6-Nonachlorobiphenyl 206 2.00
*2,2',3,3',4,5,5',6,6'-Nonachlorobiphenyl 208 2.00
*Decachlorobiphenyl 209 2.00
Congeners marked with an asterisk{*) are concentration-certified by direct comparison to the NRCCCLB-1solutions.
100
PCBs:SOLUTION/MIXTURES
Solution/Mixtures for the analysis of the Dutch 7 PCBCongeners.

BP•D7 Native PCBCongener Solution/Mixture 1.2 ml
MBP•D7 Mass-Labelled PCBCongener Solution/Mixture 1.2 ml
NATIVE PCB CONGENERS IUPAC
2,4,4' -Trichlorobi phenyl 28 10.0

2,2 ',4, 5,5' -Pentachlorobi phenyl 101 10.0
2,3 ',4,4', 5-Pentachlorobi phenyl 118 10.0
2,2',3,4,4',S'-Hexachlorobiphenyl 138 10.0
2,2',4,4',S,5'-Hexachlorobiphenyl 153 10.0
2,2',3,4,4',S,5'-Heptachlorobiphenyl 180 10.0
MBP-D7
MASS-LABELLED PCB CONGENERS IUPAC (.-g/mL)
2,4,4' -Trichloro{"C,,)bi phenyl 28L 5.00

2,2',5,5'-Tetrachloro{"C,,)biphenyl 52L 5.00
2,2',4,5,S'-Pentachloro{"C,,)biphenyl 101L 5.00
2,3 ',4,4', 5-Pentachloro{"C,,)biphenyl 118L 5.00
2,2',3,4,4',S'-Hexachloro{"C,,)biphenyl 138L 5.00
2,2',4,4',S,5'-Hexachloro{"C,,)biphenyl 153L 5.00
2,2',3,4,4',S,5'-Heptachloro{"C,,)biphenyl 180L 5.00
MBP-D7 153L
52L 138L
101L
118L
180L
28L
HRGGLRMSData: MBP-D7 on a 30 m D8-5 column.
101
SOLUTION/MIXTURES
Thesethree solutions were designed and prepared as support solutions to be used with the following calibration sets:
DF-CVS-A10(see Page44)
DF-CVS-B10(see Page46)
as well as:
PCB-CVS-A
10

DFP-LCS-A Mass-Labelled PCDD/PCDF/PCB
MASS-LABELLED PCDDs
2,3,7,8-Tetrach loro("C,,)dibenzo-p-d ioxi n 10.0 ng/ml

1,2,3,7,8-Pentach loro("C,,)d i benzo-p-dioxi n 10.0 ng/ml
1,2,3,4,7,8-Hexach loro("C,,)d i benzo-p-d ioxin 10.0 ng/ml
1,2,3,6,7,8-Hexach loro("C,,)d i benzo-p-d ioxin 10.0 ng/ml
1,2,3,7,8,9-Hexachloro("C 2)dibenzo-p-dioxin 10.0 ng/ml
1,2,3,4,6,7,8-Heptachloro("C,,)d ibenzo-p-dioxi n 10.0 ng/ml
Octachloro("C,,)dibenzo-p-dioxin 20.0 ng/ml
MASS-LABELLED PCDFs
2,3,7,8-Tetrach loro("C,,)dibenzofuran 10.0 ng/ml

1,2,3,7,8-Pentach loro("C,,)d i benzofu ran 10.0 ng/ml
2,3,4,7,8-Pentach loro("C,,)d i benzofu ran 10.0 ng/ml
1,2,3,6,7,8-Hexach loro("C,,)d i benzofura n 10.0 ng/ml
2,3,4,6,7,8-Hexach loro("C,,)d i benzofura n 10.0 ng/ml
1,2,3,4,6,7,8-Heptachloro("C,,)d ibenzofu ran 10.0 ng/ml
1,2,3,4,7,8,9-Heptachloro("C,,)d ibenzofu ran 10.0 ng/ml
Octachloro("C,,)dibenzofuran 20.0 ng/ml

3,4,4',5-Tetrachloro("C 2)biphenyl 81L 10.0 ng/ml
2,3,3 ',4,4' -Pentach loro("C,,)biphenyl 105L 10.0 ng/ml
2,3,4,4',5-Pentachloro("C,,)biphenyl 114L 10.0 ng/ml
2,3 ',4,4', 5-Pentach loro("C,,)biphenyl 118L 10.0 ng/ml
2 ',3,4,4', 5-Pentach loro("C,,)biphenyl 123L 10.0 ng/ml
3,3 ',4,4', 5-Pentach loro("C,,)biphenyl 126L 10.0 ng/ml
2,3,3',4,4',5-Hexachloro("C,,)biphenyl 156L 10.0 ng/ml
2,3,3',4,4',5'-Hexachloro("C,,)biphenyl 157L 10.0 ng/ml
2,2',3,3',4,4',5-Heptachloro("C,,)biphenyl 170L 10.0 ng/ml
2,2',3,4,4',5,5'-Heptachloro("C,,)biphenyl 180L 10.0 ng/ml
2,3,3',4,4',5,5'-Heptachloro("C,,)biphenyl 189L 10.0 ng/ml
DFP-IS-A Mass-Labelled PCDF/PCBSyringe Spike 1.2 ml
IUPAC
2,3',4',5-Tetrachloro("C,,)biphenyl lOL 10.0 ng/ml
1,2,3,4,6,9-Hexachloro("C 2)dibenzofuran 10.0 ng/ml
1,2,3,4,6,8,9-Heptachloro("C,,)dibenzofuran 10.0 ng/ml
DFP-SS-A Mass-Labelled PCDD/PCBSampling Spike 1.2 ml
IUPAC
1,2,3,4-Tetrachloro("C,,)dibenzo-p-d ioxin 50.0 ng/ml
102
PBDES & PBBS:
POLYBROMINATEDDIPHENYL ETHERS(PBDES)
& POLYBROMINATEDBIPHENYLS(PBBS)
This section is primarily devoted to Polybrominated Diphenyl Ethers (PBDEs),but also includes
native and 13C-labelled standards of Polybrominated Biphenyls (PBBs). PBDEsand PBBsare both
additive flame retardants and were used in a variety of applications. As additive flame
retardants, as opposed to reactive, they can leach out of the materials to which they were added
and eventually contaminate the environment.
This section includes three sets of PBDEcalibration solutions and their support solutions, namely:
BFR-CVS: Includes an extensive PBDE list and other brominated flame retardants (BFRs)
BDE-CVS-F: Contains PBDEcongeners found in the industrial Penta- and Octa-BDE mixes.
BDE-CVS-G: Contains major components of Penta-, Octa- and Deca- PBDEindustrial mixes and
can be used for EPA Method 1614 and ISO 22032:2006.
Also included in this section are:

Individual native and mass-labelled PBDEs
Characterized PBDE industrial mixtures
Mass-labelled hydroxy-PBDEs
Native and mass-labelled methoxy-PBDEs
Individual native and mass-labelled PBBs
Charaderized PBB industrial mixtures
BFR-CVS
Catalogue Number Product (toluene solution) Qty/Cone

BFR-CVS Polybrominated Diphenyl Ethers/Brominated Flame Retardants 1 kit
Calibration Solutions CS1-CS5 (5 ampoules)
BFR•CS1,BFR•CS2,BFR•CS3,BFR•CS4,BFR•CS5 Individual Calibration Solutions 200 µLeach
BFR-CS1 BFR-CS2 BFR-CS3 BFR-CS4 BFR-CSS

NATIVE PBDEs/BFRs (ng/mL) (ng/mL) (ng/mL) (ng/mL) (ng/mL)
2-Bromodiphenyl ether 8DE-1 0.250 1.00 5.00 20.0 100
2,4-Dibromodiphenyl ether 8DE-7 0.250 1.00 5.00 20.0 100
2,6-Dibromodiphenyl ether 8DE-10 0.250 1.00 5.00 20.0 100
4,4'-Dibromodiphenyl ether 8DE-15 0.250 1.00 5.00 20.0 100
2,2',4-Tribromodiphenyl ether 8DE-17 (>96%) 0.240 0.960 4.80 19.0 96.0
2,4,4'-Tribromodiphenyl ether 8DE-28 0.250 1.00 5.00 20.0 100
2,4,6-Tribromodiphenyl ether 8DE-30 0.250 1.00 5.00 20.0 100
Pentabromoethylbenzene P8E8 0.250 1.00 5.00 20.0 100
Hexabromobenzene H88Z 0.250 1.00 5.00 20.0 100
2,2',4,4'-Tetrabromodiphenyl ether 8DE-47 0.500 2.00 10.0 40.0 200
2,3',4',6-Tetrabromodiphenyl ether 8DE-71 0.500 2.00 10.0 40.0 200
2,2',3,4,4'-Pentabromodiphenyl ether 8DE-85 0.500 2.00 10.0 40.0 200
2,2' ,4,4',5-Pentabromodiphenyl ether 8DE-99 0.500 2.00 10.0 40.0 200
3,3',4,4',5-Pentabromodiphenyl ether 8DE-126 0.500 2.00 10.0 40.0 200
2,2',3,4,4',5'-Hexabromodiphenyl ether 8DE-138 0.500 2.00 10.0 40.0 200
2,2',3,4,4',6-Hexabromodiphenyl ether 8DE-139 0.500 2.00 10.0 40.0 200
2,2',3,4,4',6'-Hexabromodiphenyl ether 8DE-140 0.500 2.00 10.0 40.0 200
2,2',4,4',5,5'-Hexabromodiphenyl ether 8DE-153 0.500 2.00 10.0 40.0 200
2,3,3',4,4',5-Hexabromodiphenyl ether 8DE-156 0.500 2.00 10.0 40.0 200
2,2',4,4',5,5'-Hexabromobiphenyl 88-153 0.500 2.00 10.0 40.0 200
1,2-8is(2,4,6-tribromophenoxy)ethane 8TBPE 0.500 2.00 10.0 40.0 200
2,2',3,3',4,4',6-Heptabromodiphenyl ether 8DE-171 1.00 4.00 20.0 80.0 400
2,2',3,4,4',5,5'-Heptabromodiphenyl ether 8DE-180 1.00 4.00 20.0 80.0 400
2,2',3,4,4',5',6-Heptabromodiphenyl ether 8DE-183 1.00 4.00 20.0 80.0 400
2,2',3,4,4',6,6'-Heptabromodiphenyl ether 8DE-184 1.00 4.00 20.0 80.0 400
2,3,3',4,4',5',6-Heptabromodiphenyl ether 8DE-191 1.00 4.00 20.0 80.0 400
2,2',3,3',4,4',5,6'-Octabromodiphenyl ether 8DE-196 1.00 4.00 20.0 B0.0 400
2,2',3,3',4,4',6,6'-Octabromodiphenyl ether 8DE-197 1.00 4.00 20.0 B0.0 400
2,2',3,3',4,5',6,6'-Octabromodiphenyl ether 8DE-201 1.00 4.00 20.0 80.0 400
2,2',3,4,4',5,5',6-Octabromodiphenyl ether 8DE-203 1.00 4.00 20.0 80.0 400
2,2',3,4,4',5,6,6'-Octabromodiphenyl ether 8DE-204 1.00 4.00 20.0 80.0 400
2,3,3',4,4',5,5',6-Octabromodiphenyl ether 8DE-205 1.00 4.00 20.0 80.0 400
2,2',3,3',4,4',5,5',6-Nonabromodiphenyl ether 8DE-206 2.50 10.0 50.0 200 1000
2,2',3,3',4,4',5,6,6'-Nonabromodiphenyl ether 8DE-207 2.50 10.0 50.0 200 1000
2,2',3,3',4,5,5',6,6'-Nonabromodiphenyl ether 8DE-208 2.50 10.0 50.0 200 1000
Decabromodiphenyl ether 8DE-209 2.50 10.0 50.0 200 1000
Decabromodiphenylethane D8DPE 5.00 20.0 100 400 2000
MASS-LABELLED PBDEs/BFRs
4-Bromo("C,,)diphenyl ether M8DE-3 25.0 25.0 25.0 25.0 25.0
4,4'-Dibromo("C,,)diphenyl ether M8DE-15 25.0 25.0 25.0 25.0 25.0
2,4,4'-Tribromo("C,,)diphenyl ether M8DE-28 25.0 25.0 25.0 25.0 25.0
Hexabromo("CJbenzene MH88Z 25.0 25.0 25.0 25.0 25.0
2,2',4,4'-Tetrabromo("C,,)diphenyl ether M8DE-47 50.0 50.0 50.0 50.0 50.0
2,2',4,4',5-Pentabromo("C,,)diphenyl ether M8DE-99 50.0 50.0 50.0 50.0 50.0
2,2',4,4',6-Pentabromo("C,,)diphenyl ether M8DE-100 50.0 50.0 50.0 50.0 50.0
3,3' ,4,4',5-Pentabromo("C,,)diphenyl ether M8DE-126 50.0 50.0 50.0 50.0 50.0
2,2',4,4',5,5'-Hexabromo("C,,)diphenyl ether M8DE-153 50.0 50.0 50.0 50.0 50.0
2,2',4,4',5,5'-Hexabromo("C,)biphenyl M88-153 50.0 50.0 50.0 50.0 50.0
1,2-8is[2,4,6-tribromo("CJphenoxy]ethane M8TBPE 50.0 50.0 50.0 50.0 50.0
2,2',3,4,4',5',6-Heptabromo("C,,)diphenyl ether M8DE-183 100 100 100 100 100
2,2',3,3',4,4',6,6'-Octabromo("C,,)diphenyl ether M8DE-197 100 100 100 100 100
2,3,3',4,4',5,5',6-Octabromo("C,,)diphenyl ether M8DE-205 100 100 100 100 100
2,2',3,3',4,4',5,6,6'-Nonabromo("C,,)diphenyl ether M8DE-207 250 250 250 250 250
Decabromo("C,,)diphenyl ether M8DE-209 250 250 250 250 250
Decabromo(''C,)diphenylethane MD8DPE 500 500 500 500 500
INTERNAUINJECTION STANDARDS
2,2',3,4,4',6-Hexabromo(''C,,)diphenyl ether M8DE-139 50.0 50.0 50.0 50.0 50.0
2,2',3,4,4',5,5'-Heptabromo("C,,)diphenyl ether M8DE-180 100 100 100 100 100
2,2',3,3',4,4',5,5',6-Nonabromo("C,,)diphenyl ether M8DE-206 250 250 250 250 250
SAMPLING/CLEANUP STANDARD
2,2',3,4,4',5'-Hexabromo("C,,)diphenyl ether M8DE-138 50.0 50.0 50.0 50.0 50.0
104
BFR-CVS

BFR-LCS Labelled Compounds Solution 1.2 ml
BFR•ISS Internal/Injection Standards 1.2 ml
BFR•SCS Sampling/Cleanup Standard 1.2 ml
BFR-PAR Native Compounds Stock Solution (nonaneltoluene solution) 1.2 ml
BFR-LCS BFR-ISS BFR-SCS BFR-PAR

NATIVE PBDEs/BFRs {ng/mL) {ng/mL) (ng/mL) {ng/mL)
2-Bromodiphenyl ether 8DE-1 200
2,4-Dibromodiphenyl ether 8DE-7 200
2,6-Dibromodiphenyl ether 8DE-10 200
4,4'-Dibromodiphenyl ether 8DE-15 200
2,2',4-Tribromodiphenyl ether 8DE-17 (>96%) 192
2,4,4'-Tribromodiphenyl ether 8DE-28 200
2,4,6-Tribromodiphenyl ether 8DE-30 200
Pentabromoethylbenzene P8E8 200
Hexabromobenzene H88Z 200
2,2',4,4'-Tetrabromodiphenyl ether 8DE-47 400
2,3',4',6-Tetrabromodiphenyl ether 8DE-71 400
2,2',3,4,4'-Pentabromodiphenyl ether 8DE-85 400
2,2' ,4,4',5-Pentabromodiphenyl ether 8DE-99 400
3,3',4,4',5-Pentabromodiphenyl ether 8DE-126 400
2,2',3,4,4',5'-Hexabromodiphenyl ether 8DE-138 400
2,2',3,4,4',6-Hexabromodiphenyl ether 8DE-139 400
2,2',3,4,4',6'-Hexabromodiphenyl ether 8DE-140 400
2,2',4,4',5,5'-Hexabromodiphenyl ether 8DE-153 400
2,3,3',4,4',5-Hexabromodiphenyl ether 8DE-156 400
2,2',4,4',5,5'-Hexabromobiphenyl 88-153 400
1,2-8is(2,4,6-tribromophenoxy)ethane 8TBPE 400
2,2',3,3',4,4',6-Heptabromodiphenyl ether 8DE-171 800
2,2',3,4,4',5,5'-Heptabromodiphenyl ether 8DE-180 800
2,2',3,4,4',5',6-Heptabromodiphenyl ether 8DE-183 800
2,2',3,4,4',6,6'-Heptabromodiphenyl ether 8DE-184 800
2,3,3',4,4',5',6-Heptabromodiphenyl ether 8DE-191 800
2,2',3,3',4,4',5,6'-Octabromodiphenyl ether 8DE-196 800
2,2',3,4,4',5,5',6-Octabromodiphenyl ether 8DE-203 800
2,2',3,4,4',5,6,6'-Octabromodiphenyl ether 8DE-204 800
2,3,3',4,4',5,5',6-Octabromodiphenyl ether 8DE-205 800
2,2',3,3',4,4',5,5',6-Nonabromodiphenyl ether 8DE-206 2000
2,2',3,3',4,4',5,6,6'-Nonabromodiphenyl ether 8DE-207 2000
2,2',3,3',4,5,5',6,6'-Nonabromodiphenyl ether 8DE-208 2000
Decabromodiphenyl ether 8DE-209 2000
Decabromodiphenylethane D8DPE 4000
MASS-LABELLED PBDEs/BFRs
4-Bromo("C.,)diphenyl ether M8DE-3 100
4,4'-Dibromo("C,,)diphenyl ether M8DE-15 100
2,4,4'-Tribromo("C,,)diphenyl ether M8DE-28 100
Hexabromo("C,)benzene MH88Z 100
2,2',4,4'-Tetrabromo("C.,)diphenyl ether M8DE-47 200
3,3',4,4'-Tetrabromo("C.,)diphenyl ether M8DE-77 200
2,2',4,4',5-Pentabromo("C.,)diphenyl ether M8DE-99 200
2,2',4,4',5,5'-Hexabromo("C,,)diphenyl ether M8DE-153 200
2,2',4,4',5,6'-Hexabromo("C.,)diphenyl ether M8DE-154 200
3,3',4,4',5,5'-Hexabromo("C,,)diphenyl ether M8DE-169 200
2,2',4,4',5,5'-Hexabromo("C,)biphenyl M88-153 200
1,2-8is[2,4,6-tribromo("C,)phenoxy]ethane M8TBPE 200
2,2',3,4,4',5',6-Heptabromo("C,,)diphenyl ether M8DE-183 400
2,2',3,3',4,4',6,6'-Octabromo("C,,)diphenyl ether M8DE-197 400
2,3,3',4,4',5,5',6-Octabromo("C.,)diphenyl ether M8DE-205 400
2,2',3,3',4,4',5,6,6'-Nonabromo("C,,)diphenyl ether M8DE-207 1000
Decabromo("C,,)diphenyl ether M8DE-209 1000
Decabromo("C,,)diphenylethane MD8DPE 2000
INTERNAUINJECTION STANDARDS
3,3',4,5'-Tetrabromo("C,,)diphenyl ether M8DE-79 200
2,2',3,4,4',6-Hexabromo(''C,,)diphenyl ether M8DE-139 200
2,2',3,4,4',5,5'-Heptabromo("C,,)diphenyl ether M8DE-180 400
2,2',3,3',4,4',5,5',6-Nonabromo("C.,)diphenyl ether M8DE-206 1000
SAMPLING/CLEANUP STANDARD
2,2',3,4,4',5'-Hexabromo("C,,)diphenyl ether M8DE-138 400
105
BDE-CVS-F
BDE•CVS•F BDE-CVS-F 1 kit
BDE-CS1-F CS1 200 µL
BDE·CS2·F CS2 200 µL
BDE·CS3-F CS3 200 µL
BDE-CS4-F CS4 200 µL
BDE·CSS·F CS5 200 µL
BDE· BDE· BDE· BDE· BDE·

CS1-F CS2-F CS3-F CS4-F CSS-F
NATIVE PBDEs IUPAC (ng/ml) (ng/ml) (ng/ml) (ng/ml) (ng/ml)
2,4,4'-Tribromodiphenyl ether 28 1.00 5.00 25.0 100 500

2,2',4,4'-Tetrabromodiphenyl ether 47 1.00 5.00 25.0 100 500
2,2',3,4,4'-Pentabromodiphenyl ether 85 1.00 5.00 25.0 100 500
2,2',4,4',5-Pentabromodiphenyl ether 99 1.00 5.00 25.0 100 500
2,2',4,4',5,5'-Hexabromodiphenyl ether 153 1.00 5.00 25.0 100 500
2,2',3,4,4',5',6-Heptabromodiphenyl ether 183 1.00 5.00 25.0 100 500
SURROGATE STANDARDS
2,4,4' -Tri bromo("C,,)d i phenyl ether 28L 20.0 20.0 20.0 20.0 20.0
2,2',4,4'-Tetrabromo("C,,)diphenyl ether 47L 20.0 20.0 20.0 20.0 20.0
2,2',4,4',5-Pentabromo("C,,)diphenyl ether 99L 20.0 20.0 20.0 20.0 20.0
2,2',4,4',6-Pentabromo("C,,)diphenyl ether 100L 20.0 20.0 20.0 20.0 20.0
2,2',4,4',5,5'-Hexabromo("C,,)diphenyl ether 153L 20.0 20.0 20.0 20.0 20.0
2,2',4,4',5,6'-Hexabromo("C, 2)diphenyl ether 154L 20.0 20.0 20.0 20.0 20.0
2,2',3,4,4',5',6-Heptabromo("C, 2)diphenyl ether 183L 20.0 20.0 20.0 20.0 20.0
RECOVERY STANDARDS
3,3',4,4'-Tetrabromo("C,,)diphenyl ether lll 20.0 20.0 20.0 20.0 20.0

2,2',3,4,4',5'-Hexabromo("C,,)diphenyl ether 138L 20.0 20.0 20.0 20.0 20.0
- BDE-28
BDE~7
-
""'
'""
,_
BDE•MXF
BDE•99
""'
BDE-100
'""
,_ BDE~5
,_
,_
,_
""'
-
BDE-154
""'
BDE-153
-
""
"" BDE-183
-
""
""
'"'
'"'
BDE-MXF; HRGC/LRMSFull Scan Chromatogram
106
BDE-CVS-F
MBDE·MXFS Mass-Labelled PBDESurrogate Stock Solution 1.2 ml
MBDE·MXFR Mass-Labelled PBDE Recovery Stock Solution 1.2 ml
BDE-MXF Native PBDEStock Solution/Mixture 1.2 ml
MBDE·MXFS MBDE·MXFR BDE·MXF

NATIVE PBDEs IUPAC (ng/ml) (ng/ml) (ng/ml)
2,4,4'-Tribromodiphenyl ether 28 2000

2,2',4,4'-Tetrabromodiphenyl ether 47 2000
2,2' ,3,4,4' -Pentabromodiphenyl ether 85 2000
2,2' ,4,4', 5-Penta bromod i phenyl ether 99 2000
2,2' ,4,4', 6-Penta bromod i phenyl ether 100 2000
2,2',4,4',S,5'-Hexabromodiphenyl ether 153 2000
2,2',4,4',5,6'-Hexabromodiphenyl ether 154 2000
2,2',3,4,4',S',6-Heptabromodiphenyl ether 183 2000
SURROGATE STANDARDS
2,4,4'-Tribromo("C,,)diphenyl ether 28L 2000

2,2',4,4'-Tetrabromo("C,,)diphenyl ether 47L 2000
2,2' ,4,4', 5-Penta bromo("C,,)di phenyl ether 99L 2000
2,2',4,4',6-Pentabromo("C,,)diphenyl ether 100L 2000
2,2',4,4',5,S'-Hexabromo("C,,)diphenyl ether 153L 2000
2,2',4,4',S,6'-Hexabromo("C,,)diphenyl ether 154L 2000
2,2',3,4,4',5',6-Heptabromo("C,,)diphenyl ether 183L 2000
RECOVERY STANDARDS

2,2',3,4,4',S'-Hexabromo("C,,)diphenyl ether 138L 2000
MBDE-47
MBDE-28
MBOE-99
MBDE-MXFS
MBDE-100
MBDE-153
MBDE-154
MBDE-183
MBDE-MXFS; HRGC/LRMSFull Scan Chromatogram.
107
BDE-CVS-G
BDE•CVS•G BDE-CVS-G 1 kit
BDE-CS1-G CS1 200 µL
BDE·CS2·G CS2 200 µL
BDE·CS3-G CS3 200 µL
BDE-CS4-G CS4 200 µL
BDE·CSS·G CS5 200 µL
NOTE: This set of calibration solutions were designed to be used with BDE-MXE as the native PBDEstock solution.
BDE· BDE· BDE· BDE- BDE·

CS1-G CS2-G CS3-G CS4-G CSS-G
NATIVE PBDEs IUPAC (ng/mL) (ng/mL) (ng/mL) (ng/mL) (ng/mL)
4-Bromodiphenyl ether 3 1.00 5.00 20.0 100 400

2,4-Dibromodiphenyl ether 7 1.00 5.00 20.0 100 400
4,4'-Dibromodiphenyl ether 15 1.00 5.00 20.0 100 400
2,2',4-Tribromodiphenyl ether 17 1.00 5.00 20.0 100 400
2,4,4'-Tribromodiphenyl ether 28 1.00 5.00 20.0 100 400
2,2 ',4, 5'-Tetrabromod i phenyl ether 49 1.00 5.00 20.0 100 400
2,3',4',6-Tetrabromodiphenyl ether 71 1.00 5.00 20.0 100 400
2,2',3,4,4'-Pentabromodiphenyl ether 85 1.00 5.00 20.0 100 400
2,2',3,4,4',5'-Hexabromodiphenyl ether 138 2.00 10.0 40.0 200 800
2,3,3',4,4',5-Hexabromodiphenyl ether 156 2.00 10.0 40.0 200 800
2,2',3,4,4',5',6-Heptabromodiphenyl ether 183 2.00 10.0 40.0 200 800
2,2',3,4,4',6,6'-Heptabromodiphenyl ether 184 2.00 10.0 40.0 200 800
2,3,3',4,4',5',6-Heptabromodiphenyl ether 191 2.00 10.0 40.0 200 800
2,2',3,3',4,4',5,6'-Octabromodiphenyl ether 196 2.00 10.0 40.0 200 800
2,2',3,3',4,4',6,6'-Octabromodiphenyl ether 197 2.00 10.0 40.0 200 800
2,2',3,3',4,4',5,5',6-Nonabromodiphenyl ether 206 5.00 25.0 100 500 2000
2,2',3,3',4,4',5,6,6'-Nonabromodiphenyl ether 207 5.00 25.0 100 500 2000
Decabromodiphenyl ether 209 5.00 25.0 100 500 2000
MASS-LABELLED PBDEs
4-Bromo("C,,)diphenyl ether 3L 100 100 100 100 100

4,4'-Dibromo("C,,)diphenyl ether 15L 100 100 100 100 100
2,4,4' -Tribromo("C,,)d i phenyl ether 28L 100 100 100 100 100
2,2',4,4'-Tetrabromo("C,,)diphenyl ether 47L 100 100 100 100 100
2,2',4,4',5-Pentabromo("C 12)diphenyl ether 99L 100 100 100 100 100
2,2',4,4',6-Pentabromo("C,,)diphenyl ether 100L 100 100 100 100 100
3,3',4,4',5-Pentabromo("C,,)diphenyl ether 126L 100 100 100 100 100
2,2',4,4',5,5'-Hexabromo("C,,)diphenyl ether 153L 200 200 200 200 200
2,2',4,4',5,6'-Hexabromo("C,,)diphenyl ether 154L 200 200 200 200 200
2,2' ,3,4,4' ,5' ,6-Heptabromo("C,,)diphenyl ether 183L 200 200 200 200 200
2,2',3,3',4,4',6,6'-Octabromo("C, 2)diphenyl ether 197L 200 200 200 200 200
2,2',3,3',4,4',5,6,6'-Nonabromo("C,,)diphenyl ether 207L 500 500 500 500 500
Decabromo("C,,)diphenyl ether 209L 500 500 500 500 500
INTERNAL STANDARDS
3,3' ,4,5'-Tetrabromo("C,,)diphenyl ether 79L 100 100 100 100 100

2,2',3,4,4',5'-Hexabromo("C,,)diphenyl ether 138L 200 200 200 200 200
2,2',3,3',4,4',5,5',6-Nonabromo("C,,)diphenyl ether 206L 500 500 500 500 500
108
BDE-CVS-G
MBDE·MXG Mass-Labelled PBDESolution/Mixture 1.2 ml
MBDE·ISS·G Mass-Labelled PBDEInternal Standard Solution/Mixture 1.2 ml
BDE-MXE Native PBDESolution/Mixture 1.2 ml
MBDE·MXG MBDE-ISS-G BDE·MXE

NATIVE PBDEs IUPAC (ng/mL) (ng/mL) (ng/mL)
4-Bromodiphenyl ether 3 1000

2,4-Dibromodiphenyl ether 7 1000
4,4'-Dibromodiphenyl ether 15 1000
2,2',4'-Tribromodiphenyl ether 17 1000
2,4,4' -Tribromodiphenyl ether 28 1000
2,3',4',6-Tetrabromodiphenyl ether 71 1000
2,2',3,4,4'-Pentabromodiphenyl ether 85 1000
2,2' ,4,4', 5-Pentabromod i phenyl ether 99 1000
2,2' ,4,4' ,6-Penta bromod i phenyl ether 100 1000
2,3 ',4,4' ,6-Penta bro modi phenyl ether 119 1000
3,3',4,4',5-Pentabromodiphenyl ether 126 1000
2,2',3,4,4',5'-Hexabromodiphenyl ether 138 2000
2,3,3',4,4',5-Hexabromodiphenyl ether 156 2000
2,2',3,4,4',5',6-Heptabromodiphenyl ether 183 2000
2,2',3,4,4',6,6'-Heptabromodiphenyl ether 184 2000
2,3,3',4,4',5',6-Heptabromodiphenyl ether 191 2000
2,2',3,3',4,4',5,6'-Octabromodiphenyl ether 196 2000
2,2',3,3',4,4',6,6'-Octabromodiphenyl ether 197 2000
2,2',3,3',4,4',5,5',6-Nonabromodiphenyl ether 206 5000
2,2',3,3',4,4',5,6,6'-Nonabromodiphenyl ether 207 5000
Decabromodiphenyl ether 209 5000
MASS-LABELLED PBDEs
4-Bromo("C,,)diphenyl ether 3L 100

4,4'-Dibromo("C,,)diphenyl ether 15L 100
2,4,4' -Tribromo("C,,)diphenyl ether 28L 100
2,2',4,4',5,5'-Hexabromo("C,,)diphenyl ether 153L 200
2,2',4,4',5,6'-Hexabromo("C,,)diphenyl ether 154L 200
2,2' ,3,4,4', 5',6-Heptabromo("C,,)d i phenyl ether 183L 200
2,2' ,3,3 ',4,4', 6,6 '-Octa bromo("C,,)d i phenyl ether 197L 200
2,2',3,3',4,4',5,6,6'-Nonabromo("C,,)diphenyl ether 207L 500
Decabromo("C, 2)diphenyl ether 209L 500
INTERNAL STANDARDS
3,3 ',4, 5'-Tetrabromo("C,,)d i phenyl ether 79L 100

2,2',3,4,4' ,5' -Hexabromo("C,,)diphenyl ether 138L 200
2,2',3,3',4,4',5,5',6-Nonabromo("C,,)diphenyl ether 206L 500
109
NATIVE POLYBROMINATEDDIPHENYL ETHERS(PBDEs)

BDE-1 2-Bromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-7 2,4-Dibromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-10 2,6-Dibromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-15 4,4'-Dibromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-17 2,2' ,4-Tribromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-21 2,3,4-Tribromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-28 2,4,4'-Tribromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-30 2,4,6-Tribromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-37 3,4,4'-Tribromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-47 2,2' ,4,4'-Tetrabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-60 2,3,4,4'-Tetrabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-71 2,3' ,4' ,6-Tetrabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-82 2,2' ,3,3',4-Pentabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-85 2,2' ,3,4,4'-Pentabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-104 2,2' ,4,6,6'-Pentabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-105 2,3,3' ,4,4'-Pentabromod i phenyl ether 1.2 ml 50.0 µg/ml
BDE-126 3,3 ',4,4', 5-Pentabromod i phenyl ether 1.2 ml 50.0 µg/ml
BDE-128 2,2 ',3,3' ,4,4 '-Hexabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-138 2,2' ,3,4,4' ,5'-Hexabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-139 2,2' ,3,4,4' ,6-Hexabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-140 2,2' ,3,4,4' ,6'-Hexabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-149 2,2' ,3,4',5',6-Hexabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-153 2,2',4,4',5,5'-Hexabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-154 2,2',4,4',5,6'-Hexabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-155 2,2 ',4,4' ,6,6'-Hexabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-156 2,3,3' ,4,4' ,5-Hexabromodiphenyl ether 1.2 ml 50.0 µg/ml
3' 2' 2 3
4' 4
5' 6' 6 5
110
NATIVE POLYBROMINATEDDIPHENYL ETHERS(PBDEs)

BDE-169 3,3' ,4,4' ,5,5'-Hexabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-170 2,2' ,3,3' ,4,4' ,5-Heptabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-176 2,2' ,3,3' ,4,6,6'-Heptabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-177 2,2' ,3,3' ,4',5,6-Heptabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-179 2,2 ', 3,3 ', 5,6,6'-Heptabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-180 2,2 ',3,4,4', 5, 5'-Heptabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-181 2,2' ,3,4,4',5,6-Heptabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-182 2,2 ', 3,4,4', 5,6'-Heptabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-183 2,2' ,3,4,4',5' ,6-Heptabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-184 2,2 ',3,4,4' ,6,6'-Heptabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-188 2,2 ', 3,4', 5,6,6'-Heptabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-189 2,3,3' ,4,4', 5, 5'-Heptabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-191 * 2,3,3' ,4,4', 5 ',6-Heptabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-194* 2,2' ,3,3' ,4,4' ,5,5'-Octabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-195* 2,2' ,3,3' ,4,4' ,5,6-Octabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-198* 2,2' ,3,3' ,4,5,5' ,6,-Octabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-199* 2,2' ,3,3' ,4,5,5',6'-Octabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-200* 2,2 ', 3,3 ',4, 5,6,6' -Octabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-203* 2,2 ', 3,4,4', 5, 5' ,6-Octabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-204* 2,2',3,4,4',5,6,6'-Octabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-205* 2,3,3' ,4,4', 5, 5' ,6-Octabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-206* 2,2',3,3' ,4,4' ,5,5',6-Nonabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-207* 2,2' ,3,3' ,4,4' ,5,6,6'-Nonabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-208* 2,2' ,3,3' ,4,5,5',6,6'-Nonabromodiphenyl ether 1.2 ml 50.0 µg/ml
BDE-209* Decabromodiphenyl ether 1.2 ml 50.0 µg/ml
4PC·BDE·208* 2,2' ,3,3 ',4, 5, 5' ,6,6'-Nona bromo-4 '-chlorodiphenyl ether 1.2 ml 50.0 µg/ml
4PC-BDE-208may be useful as an internal or surrogate standard for HRGC/ECD,HRGC/FID,and/or HRGC/MSanalyses.
* Toluene solution
3' 2' 2 3
4' 4
5' 6' 6 5
111
PBDE WINDOW DEFINING SOLUTION/MIXTURE

BDE-WD PBDEWindow Defining Solution/Mixture 1.2 ml
for use with a J&W DB-5HT column
FIRST ELUTER LASTELUTER CONCENTRATION

(IUPAC) (IUPAC) (J,19/ml each)
Bromodiphenyl ethers 3 1.00

Dibromodiphenyl ethers 10 15 1.00
Tribromodiphenyl ethers 30 37 1.00
Tetrabromodiphenyl ethers 54 60 1.00
Pentabromodiphenyl ethers 104 82 1.00
Hexabromodiphenyl ethers 155 128 2.00
Heptabromodiphenyl ethers 188 170 2.00
Octabromodiphenyl ethers 202 195 2.00
Nonabromodiphenyl ethers 208 206 5.00
Decabromodiphenyl ether 209 5.00
NATIVE PBDEs: SOLUTION/MIXTURES

BDE-MXA Native PBDESolution/Mixture 1.2 ml
IUPAC
2,2',4,4'-Tetrabromodiphenyl ether 47 5.00 µg/ml
2,2',4,4',5-Pentabromodiphenyl ether 99 5.00 µg/ml
2,2',4,4',5,5'-Hexabromodiphenyl ether 153 5.00 µg/ml
BDE·MXB Native PBDESolution/Mixture 1.2 ml

IUPAC
2,4,4'-Tribromodiphenyl ether 28 5.00 µg/ml
2,2',3,4,4',5',6-Heptabromodiphenyl ether 183 5.00 µg/ml
BDE·MXD Native PBDESolution/Mixture 1.2 ml

IUPAC
2,2',4-Tribromodiphenyl ether 17 5.00 µg/ml
2,2',4,4'-Tetrabromodiphenyl ether 47 5.00 µg/ml
2,3' ,4,4'-Tetrabromodiphenyl ether 66 5.00 µg/ml
2,2' ,4,4' ,6-Penta bro modi phenyl ether 100 5.00 µg/ml
2,2',3,4,4',5',6-Heptabromodiphenyl ether 183 5.00 µg/ml
Decabromodiphenyl ether 209 10.0 µg/ml
112
NATIVE PBDEs: SOLUTION/MIXTURE

BDE-OND Solution/Mixture of Octa-, Nona-, and Deca-BDEs 1.2 ml
IUPAC
2,2',3,3',4,4',5,5'-Octabromodiphenyl ether 194 1.00 µg/ml
2,2',3,3',4,4',5,6-Octabromodiphenyl ether 195 1.00 µg/ml
2,2',3,3',4,5,5',6-Octabromodiphenyl ether 198 1.00 µg/ml
2,2',3,3',4,5,5',6'-Octabromodiphenyl ether 199 1.00 µg/ml
2,2',3,3',4,5,6,6'-Octabromodiphenyl ether 200 1.00 µg/ml
2,2',3,4,4',5,5',6-Octabromodiphenyl ether 203 1.00 µg/ml
2,2',3,4,4',5,6,6'-Octabromodiphenyl ether 204 1.00 µg/ml
2,3,3',4,4',5,5',6-Octabromodiphenyl ether 205 1.00 µg/ml
2,2',3,3',4,4',5,5',6-Nonabromodiphenyl ether 206 2.50 µg/ml
2,2',3,3',4,4',5,6,6'-Nonabromodiphenyl ether 207 2.50 µg/ml
2,2',3,3',4,5,5',6,6'-Nonabromodiphenyl ether 208 2.50 µg/ml
Decabromodiphenyl ether 209 2.50 µg/ml
198 203
10
199 200
202
201
208
197 207
20
196 195 206
194
205 209
u-,r-rrl'TT"l'TT"..,......,....TTTTTTTT"TTT"TTT"ITT"l,,..,..,,,..,..,r-rrl'TT"..,......,....TTTTTTTT"TTT"TTT"ITT"ITT"l,,..,..,
........
r-rrl'TT"..,......,....TTTTTTTT"TTT"T-r
Time
14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00
HRGC/HRMSData for BDE-OND on a 15 m DB-SHTcolumn.
113
MASS-LABELLEDPOLYBROMINATEDDIPHENYL ETHERS(PBDEs)
4-Bromo( 13C,,)diphenyl ether

MBDE-3
~ 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in nonane
4,4'-Dibromo("C,,)diphenyl ether
MBDE-15
2,4,4'-Tribromo("C,,)diphenyl ether
MBDE-28
2,2',4,4'-Tetrabromo("C,,)diphenyl ether
MBDE-47
3,3' ,4,4'-Tetrabromo( 13C12)diphenyl ether

MBDE-77
3,3',4,5'-Tetrabromo( 13 C,,)diphenyl ether

MBDE-79
2,2' ,4,4', 5-Penta bromo("C,,)d i phenyl ether

MBDE-99
2,2' ,4,4', 6-Penta bromo("C 12)d i phenyl ether

MBDE-100
3,3' ,4,4', 5-Penta bromo("C,,)d i phenyl ether

MBDE-126
~
2,2', 3,4,4', 5'-Hexa bromo("C 12)d i phenyl ether
MBDE-138
Bi
114
MASS-LABELLED POLYBROMINATED DIPHENYL ETHERS (PBDEs)
2,2 ',3,4,4', 6-Hexa bromo("C 12)d i phenyl ether

MBDE-139
2,2',4,4',5,5'-Hexabromo("C,,)diphenyl ether
MBDE-153
2,2',4,4',5,6'-Hexabromo("C )diphenyl ether

12
MBDE-154
3,3',4,4',5,5'-Hexabromo("C,,)diphenyl ether
MBDE-169
2,2',3,4,4',5,5'-Heptabromo("C,,)diphenyl ether
MBDE-180
2,2',3,4,4',5',6-Heptabromo("C,,)diphenyl ether
MBDE-183
2,2',3,3',4,4',6,6'-Octabromo("C,,)diphenyl ether
MBDE-197
2,3,3',4,4',5,5',6-Octabromo("C )diphenyl ether

12
MBDE-205
2,2',3,3',4,4',5,5',6-Nonabromo("C,,)diphenyl ether
MBDE-206
2,2',3,3',4,4',5,6,6'-Nonabromo("C,,)diphenyl ether
MBDE-207
115
MASS-LABELLEDPOLYBROMINATED DIPHENYL ETHERS(PBDEs)
Decabromo("C 12)diphenyl ether

MBDE-209
MASS-LABELLEDPBDEs:SOLUTION/MIXTURES

MBDE·MXA Mass-Labelled PBDESolution/Mixture 1.2 ml
IUPAC
2,2'AA'-Tetrabromo("C,,)diphenyl ether 47L 5.00 µg/ml
2,2'AA',5-Pentabromo("C,,)diphenyl ether 99L 5.00 µg/ml
2,2',4,4', 5,5'-Hexa bromo("C 12)d i phenyl ether 153L 5.00 µg/ml
MBDE-MXB Mass-Labelled PBDESolution/Mixture 1.2 ml
IUPAC
2,4,4'-Tribromo("C,,)diphenyl ether 2BL 5.00 µg/ml
2,2' AA', 5,6'-Hexa bromo("C 12)d i phenyl ether 154L 5.00 µg/ml
2,2',3,4,4',5',6-Heptabromo("C )diphenyl ether
12 183L 5.00 µg/ml
MBDE-MXC Mass-Labelled PBDESolution/Mixture 1.2 ml
IUPAC
4-Bromo( 13C12)diphenyl ether 3L 5.00 µg/ml
4,4'-Dibromo("C,,)diphenyl ether 15L 5.00 µg/ml
2,4,4'-Tribromo("C,,)diphenyl ether 2BL 5.00 µg/ml
2,2',4,4'-Tetrabromo("C 12)diphenyl ether 47L 5.00 µg/ml
2,2' ,4,4', 5-Pentabromo("C,,)d i phenyl ether 99L 5.00 µg/ml
2,2',4,4', 5,5'-Hexa bromo("C 12)d i phenyl ether 153L 5.00 µg/ml
2,2' AA', 5,6'-Hexa bromo("C,,)d i phenyl ether 154L 5.00 µg/ml
2,2',3,4,4',5',6-Heptabromo("C,,)diphenyl ether 183L 5.00 µg/ml
116
POLYBROMINATEDDIPHENYL ETHERTECHNICALMIXTURES

TBDE-71 Great Lakes Chemical DE-71™ Pentabromodiphenyl Oxide 1.2 ml 100 µg/ml
TBDE-79 Great Lakes Chemical DE-79™ Octabromodiphenyl Oxide 1.2 ml 100 µg/ml
TBDE-83R Great Lakes Chemical DE-83R™ Decabromodiphenyl Oxide 1.2 ml 100 µg/ml
99
DE-71™
47
100
153
85
154
6 42
28 139
17 140 18 14 183
GC/MS Data for Great Lakes Chemical DE-71™on a 30 m DB-SHT column.
183
DE-79™
197
153
196
207
203
154 184
1 2 180 171 208
138 \ 191 206 209
GC/MS Data for Great Lakes Chemical DE-79™on a 30 m DB-SHTcolumn.
209
DE-83R™
208 206
\ 207
GC/MS Data for Great Lakes Chemical DE-83R™on a 15 m DB-SHTcolumn.
117
NATIVE METHOXY-BROMODIPHENYL ETHERS (MeO-BDEs)
5MBDE47
;=/_' B~ 2,2',4,4' -Tetrabromo-5-methoxydiphenyl ether
B~r 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in nonane
<>%
6MBDE47 .r<'
B,~r
ft '), •
2,2',4,4' -Tetrabromo-6-methoxydiphenyl ether
;=/_' B~ 2,2',4' ,5-Tetrabromo-4-methoxydiphenyl ether

4PMBDE49
HJ~' 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in nonane
Br
)=(HJ B~ 2' ,3,4' ,5-Tetrabromo-2-methoxydiphenyl ether

2PMBDE68
-~
Bi
2,2',4,4',5-Pentabromo-5'-methoxydiphenyl ether
5PMBDE99
2,2',4,4',6'-Pentabromo-5-methoxydiphenyl ether
5PMBDE100
2,2',4,5,5'-Pentabromo-4'-methoxydiphenyl ether
4PMBDE101
;=/_' 8~ 2,2',4',5,6'-Pentabromo-4-methoxydiphenyl ether

4PMBDE103
HJ~r 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in nonane
Br Br
NOTE: In order to emphasize their relationship to the corresponding PBDE,these compounds have
been numbered based on the diphenyl ether as the parent molecule with bromines
retaining their BDE numbers. The methoxy groups are treated as additional substituents
and listed alphabetically.
118
METHOXY-BROMODIPHENYL ETHERS: SOLUTION/MIXTURE

MeOBDES Methoxy-Bromodiphenyl Ethers Solution/Mixture 1.2 ml
2,2',4,4'-Tetrabromo-5-methoxydiphenyl ether 5.00 µg/ml
2,2',4,4'-Tetrabromo-6-methoxydiphenyl ether 5.00 µg/ml
2,2',4',5-Tetrabromo-4-methoxydiphenyl ether 5.00 µg/ml
2',3,4',5-Tetrabromo-2-methoxydiphenyl ether 5.00 µg/ml
2,2',4,4',5-Pentabromo-5'-methoxydiphenyl ether 5.00 µg/ml
2,2 ',4,4' ,6 '-Penta bromo-5-methoxyd i phenyl ether 5.00 µg/ml
2,2 ',4, 5,5'-Pentabromo-4' -methoxyd i phenyl ether 5.00 µg/ml
2,2 ',4', 5,6'-Penta bromo-4-methoxyd i phenyl ether 5.00 µg/ml
MASS-LABELLED METHOXY-BROMODIPHENYL ETHERS
2,2',4,4'-Tetrabromo-6-methoxy("C,,)diphenyl ether
M6MBDE47
2,2 ',4,4' ,6-Pentabromo-6 '-methoxy("C,,)di phenyl ether

M6PMBDE100 Br
MASS-LABELLED HYDROXY-BROMODIPHENYL ETHERS
2,2',4,4'-Tetrabromo-6-hydroxy("C,,)diphenyl ether
M6HBDE47
M6PHBDE100 - ;:=('- b Br
2,2 ',4,4' ,6-Pentabromo-6 '-hydroxy("C,,)d i phenyl ether
~ 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene
NOTE: In order to emphasize their relationship to the corresponding PBDE,these compounds have
been numbered based on the di phenyl ether as the parent molecule with bromines
retaining their BDE numbers. The methoxy and hydroxy groups are treated as additional
substituents and listed alphabetically.
119
NATIVE POLYBROMINATEDBIPHENYLS(PBBs)
BB-1 2-Bromobiphenyl 1.2 ml 50.0 µg/ml
BB-4 2,2'-Dibromobiphenyl 1.2 ml 50.0 µg/ml
BB-7 2,4-Dibromobiphenyl 1.2 ml 50.0 µg/ml
BB-15 4,4'-Dibromobiphenyl 1.2 ml 50.0 µg/ml
BB-18 2,2 ', 5-Tri bromobi phenyl 1.2 ml 50.0 µg/ml
BB-22 2,3,4 '-Tri bromobi phenyl 1.2 ml 50.0 µg/ml
BB-26 2,3 ',5-Tri bromobi phenyl 1.2 ml 50.0 µg/ml
BB-29 2,4, 5-Tribromobi phenyl 1.2 ml 50.0 µg/ml
BB-30 2,4,6-Tribromobiphenyl 1.2 ml 50.0 µg/ml
BB-31 2,4' ,5-Tri bromobi phenyl 1.2 ml 50.0 µg/ml
BB-37 3,4,4 '-Tri bromobi phenyl 1.2 ml 50.0 µg/ml
BB-38 3,4,5-Tribromobiphenyl 1.2 ml 50.0 µg/ml
BB-49 2,2 ',4, 5 '-Tetrabromobiphenyl 1.2 ml 50.0 µg/ml
BB-52 2,2 ', 5, 5 '-Tetra bromobiphenyl 1.2 ml 50.0 µg/ml
BB-53 2,2 ',5,6'-Tetra bromobiphenyl 1.2 ml 50.0 µg/ml
BB-56 2, 3, 3 ',4' -Tetra bromobi phenyl 1.2 ml 50.0 µg/ml
BB-75 2,4,4' ,6-Tetra bromobi phenyl 1.2 ml 50.0 µg/ml
BB-77 3,3 ',4,4'-Tetra bromobiphenyl 1.2 ml 50.0 µg/ml
BB-80 3,3 ',5, 5 '-Tetrabromobiphenyl 1.2 ml 50.0 µg/ml
BB-101 2,2 ',4, 5, 5'-Pentabromobiphenyl 1.2 ml 50.0 µg/ml
BB-103 2,2 ',4, 5 ',6-Pentabromobiphenyl 1.2 ml 50.0 µg/ml
BB-153 2,2 ',4,4', 5, 5'-Hexabromobiphenyl 1.2 ml 50.0 µg/ml
BB-154 2,2 ',4,4', 5,6' -Hexa bromobiphenyl 1.2 ml 50.0 µg/ml
BB-155 2,2 ',4,4' ,6,6'-Hexabromobiphenyl 1.2 ml 50.0 µg/ml
BB-156 2,3,3' ,4,4', 5-Hexa bromobi phenyl 1.2 ml 50.0 µg/ml
BB-169 3,3 ',4,4', 5, 5 '-Hexa bromobiphenyl 1.2 ml 50.0 µg/ml
BB-180 2,2 ',3,4,4', 5, 5'-Heptabromobiphenyl 1.2 ml 50.0 µg/ml
BB-194 2,2 ',3,3 ',4,4', 5, 5 '-Octabromobiphenyl 1.2 ml 50.0 µg/ml
BB-205 2, 3, 3 ',4,4', 5, 5', 6-Octa bromob i phenyl 1.2 ml 50.0 µg/ml
BB-206* 2,2 ',3,3 ',4,4', 5, 5 ',6-Nonabromobi phenyl 1.2 ml 50.0 µg/ml
BB-209* Decabromobiphenyl 1.2 ml 50.0 µg/ml
* 50% Nonane/50% Toluene Solution
120
NATIVE PBBs:SOLUTION/MIXTURE

PBB·MXA Native PBBSolution/Mixture 1.2 ml
IUPAC
4-Bromobiphenyl 3 1.00 µg/ml
4,4'-Dibromobiphenyl 15 1.00 µg/ml
2,2',5-Tribromobiphenyl 18 1.00 µg/ml
2,2',5,5'-Tetrabromobiphenyl 52 1.00 µg/ml
2,2 ',4, 5,5'-Pentabromobi phenyl 101 2.00 µg/ml
2,2',4,4',5,5'-Hexabromobiphenyl 153 2.00 µg/ml
2,2',3,4,4',5,5'-Heptabromobiphenyl 180 2.00 µg/ml
2,2',3,3',4,4',5,5'-Octabromobiphenyl 194 2.00 µg/ml
2,2',3,3',4,4',5,5',6-Nonabromobiphenyl 206 5.00 µg/ml
Decabromobiphenyl 209 5.00 µg/ml
POLYBROMINATEDBIPHENYLTECHNICALMIXTURES

TBB·BP6 Great Lakes Chemical Firemaster BP-6™ Hexabromobiphenyl 1.2 ml 100 µg/ml
TBB-809D Chemische Fabrik Kalk Bromkal80-9D™ Nonabromobiphenyl 1.2 ml 100 µg/ml
MASS-LABELLEDPOLYBROMINATEDBIPHENYLS
2,2',5,5'-Tetrabromo("C,,)biphenyl
MBB-52 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in nonane;
isotopic purity 99% or greater
2,2' ,4,4', 5,5'-Hexa bromo("C,,)bi phenyl

MBB-153 Br 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in nonane;
2,2',3,3',4,4',5,5'-Octabromo("C,,)biphenyl
Decabromo("C,,)biphenyl
121
MASS-LABELLEDPBBs:SOLUTION/MIXTURE

MBB·MXA Mass-Labelled PBB Solution/Mixture 1.2 ml
IUPAC
2,2',5,5'-Tetrabromo("C )biphenyl
12 52L 1.00 µg/ml
2,2',4,4',5,5'-Hexabromo("C,,)biphenyl 153L 2.00 µg/ml
2,2',3,3',4,4',5,5'-Octabromo("C )biphenyl
12 194L 2.00 µg/ml
Decabromo("C 12)biphenyl 209L 5.00 µg/ml
bundance
150000
153L
140000
130000
120000
110000
100000
90000
80000
70000
209L
194L
60000
52L
50000
40000
30000
20000
10000
1me-> 18.00
HRGC/LRMSData for MBB-MXA on a 30 m DB-5 column.
122

123
HALOGENATED
FLAME RETARDANTS
& RELATED COMPOUNDS
While PBDEsand PBBshave garnered the most attention, many other halogenated flame
retartants (HFRs)were industrially produced in large quantities. In this section, we offer a wide
selection of HFRsthat have found varying levels of usage in certain applications. Mass-labelled
analogues of most of them are also available.
• Hexabromocyclododecane (HBCD or HBCDD) is an HFR added in percent levels to polystyrene

used in the construction industry.
• Tetrabromobisphenol-A (TBBPA) is a reactive HFR used in printed circuit boards and is also
added to various types of polymers.
• Dechlorane Plus®is a high production volume, chlorinated flame retardant that is used to
replace PBDEs.
As these HFRsare being phased out or stringently regulated, organophosphate flame retardants
(OPFRs)are being produced in larger quantities and have found increased usage. OPFRsare also
used as plasticizers and additives in lubricants. In this section, a large selection of OPFRsis offered
along with some selected mass-labelled OPFRs.
Finally, this section also contains standards of compounds related to the use of HFRs,namely:
Native and Mass-labelled Brominated Dibenzo-p-dioxins (PBDDs)
Native Brominated Dibenzofurans (PBDFs)
Mixed Br/Cl Dibenzo-p-dioxins and Dibenzofurans
NATIVE HEXABROMOCYCLODODECANE ISOMERS (HBCDDs)

aHBCD rac-a.-1,2,5,6,9, 10-Hexabromocyclododecane 1.2 ml 50.0 µg/ml
bHBCD rac-~-1,2,5,6,9, 10-Hexabromocyclododecane 1.2 ml 50.0 µg/ml
gHBCD rac-y-1,2,5,6,9, 10-Hexabromocyclododecane 1.2 ml 50.0 µg/ml
dHBCD o-1,2,5,6,9, 10-Hexabromocyclododecane 1.2 ml 50.0 µg/ml
eHBCD s-1,2,5,6,9, 10-Hexabromocyclododecane 1.2 ml 50.0 µg/ml
zHBCD i;-1,2,5,6,9, 10-Hexabromocyclododecane 1.2 ml 50.0 µg/ml
etaHBCD rac-17-1,2,5,6,9, 10-Hexabromocyclododecane 1.2 ml 50.0 µg/ml
tHBCD 0-1,2,5,6,9, 10-Hexabromocyclododecane 1.2 ml 50.0 µg/ml
iHBCD rac-i-1,2,5,6, 9, 10-Hexabromocyclododecane 1.2 ml 50.0 µg/ml
kHBCD rac-K-1,2,5,6,9, 10-Hexabromocyclododecane 1.2 ml 50.0 µg/ml
NATIVE HBCDD ISOMERS: SOLUTION/MIXTURE

HBCD-MXA Native HBCDD Isomer Solution/Mixture 1.2 ml
rac-a.-1,2,5,6,9, 10-Hexabromocyclododecane 10.0 µg/ml

rac-~-1,2,5,6,9, 10-Hexabromocyclododecane 10.0 µg/ml
rac-y-1,2,5,6,9, 10-Hexabromocyclododecane 10.0 µg/ml
NATIVE HBCDD ENANTIOMERS

(+)aHBCD (+)-a.-15,25, 5R,65, 95, 10R-Hexabromocyclododecane 1.2 ml 50.0 µg/ml
(-)aHBCD (-)-a.-1R,2R,55,6R,9R,105-Hexabromocyclododecane 1.2 ml 50.0 µg/ml
(+)gHBCD (+)-y-1 R,2R,5R,65, 95, 10R-Hexabromocyclododecane 1.2 ml 50.0 µg/ml
(•)gHBCD (-)-y-15,25,55,6R,9R, 105-Hexabromocyclododecane 1.2 ml 50.0 µg/ml
alpha (a) beta (13) gamma (y) delta (a) epsilon(&)
zeta (l;) eta (ri) theta (0) iota (i) kappa (K)
126
13 (-LABELLED HEXABROMOCYCLODODECANE ISOMERS

MaHBCD rac-a.-1,2, 5,6, 9, 10-Hexabromo("C,,)cyclododecane 1.2 ml 50.0 µg/ml
MbHBCD rac-p-1,2,5,6,9, 10-Hexabromo( C,,)cyclododecane
13 1.2 ml 50.0 µg/ml
MgHBCD rac-y-1,2, 5,6, 9, 10-Hexabromo("C,,)cyclododecane 1.2 ml 50.0 µg/ml
DEUTERATED HEXABROMOCYCLODODECANE ISOMERS

DaHBCD d,.-rac-a.-1,2,5,6,9, 10-Hexabromocyclododecane 1.2 ml 50.0 µg/ml
DbHBCD d,.-rac-p-1,2, 5,6, 9, 10-Hexabromocyclododecane 1.2 ml 50.0 µg/ml
DgHBCD d,.-rac-y-1,2,5,6,9, 10-Hexabromocyclododecane 1.2 ml 50.0 µg/ml
* Unless stated otherwise, isotopic purities of these compounds are 98%.
13 (-LABELLED HBCDD ISOMERS: SOLUTION/MIXTURE

MHBCD-MXA Mass-Labelled HBCDD Isomer Solution/Mixture 1.2 ml
rac-a.-1,2, 5,6, 9, 10-Hexabromocyclo("C,,)dodecane 10.0 µg/ml

rac-p-1,2,5,6,9, 10-Hexabromocyclo("C,,)dodecane 10.0 µg/ml
rac-y-1,2,5,6,9, 10-Hexabromocyclo("C,,)dodecane 10.0 µg/ml
PENTABROMOCYCLODODECENE (PBCD)
PBCD rac-(1, 5R,6S,9S, 10R)-pentabromocyclododecene 1.2 ml 50.0 µg/ml
TETRABROMOBISPHENOL-A (TBBPA)
Catalogue Number Product (methanol solution) Qty/Cone
TBBPA 3,3 ', 5, 5 '-Tetrabromobisphenol-A 1.2 ml 50.0 µg/ml
MASS-LABELLED TETRABROMOBISPHENOL-A (MTBBPA)
., ., 3,3',5,5'-Tetrabromobisphenol-A (rings: "C.,)
MTBBPA OH 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;

127
DECABROMODIPHENYLETHANE (DBDPE)
DBDPE 1,2-Bis(pentabromophenyl)ethane 1.2 ml 25.0 µg/ml
MASS-LABELLED DECABROMODIPHENYLETHANE (MDBDPE)
"C,4-1,2-Bis(pentabromophenyl)ethane
MDBDPE 1.2 ml; 25.0 µg/ml (±1.2 µg/ml); in toluene;
1,2-BIS(2,4,6-TRIBROMOPHENOXY)ETHANE (BTBPE)
BTBPE 1,2-B is(2,4, 6-tri bromophenoxy)etha ne 1.2 ml 50.0 µg/ml
MASS-LABELLED 1,2-BIS(2,4,6-TRIBROMOPHENOXY)ETHANE (MBTBPE)
1,2-Bis[2,4,6-tribromo( 13C6)phenoxy]ethane
MBTBPE 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene;

HEXABROMOBENZENE (HBBZ)
HBBZ Hexabromobenzene 1.2 ml 50.0 µg/ml
MASS-LABELLED HEXABROMOBENZENE (MHBBZ)
Hexabromo( 13C6)benzene
MHBBZ 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene;

128
PENTABROMOBENZENE
(PBBZ)
PBBZ Pentabromobenzene 1.2 ml 50.0 µg/ml
MASS-LABELLEDPENTABROMOBENZENE
(MPBBZ)
Pentabromo{"C,)benzene
MPBBZ 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene;

PENTABROMOETHYLBENZENE
(PBEB)
PBEB Pentabromoethylbenzene 1.2 ml 50.0 µg/ml
PENTABROMOTOLUENE(PBT)
PBT Pentabromotoluene 1.2 ml 50.0 µg/ml
TETRABROMO-p-XYLENE(pTBX)
pTBX 2,3, 5,6-Tetrabromo-p-xylene 1.2 ml 50.0 µg/ml
CH2CH3 CH, CH,
"'*:.,
Br
.,
Br
"'*:"'
Br
,,
Br
"'*:.,
Br
CH,
Br
Pentabromoethylbenzene Penta bromotol uene 2,3, 5,6-Tetrabromo-p-xylene
1,2,5,6-TETRABROMOCYCLOOCTANE
(TBCO)

aTBCO (1 R,2R, 55,65)-1,2, 5,6-tetrabromocycloocta ne 1.2 ml 50.0 µg/ml
bTBCO rac-(1 R,2R, 5R,6R)-1,2, 5,6-tetrabromocyclooctane 1.2 ml 50.0 µg/ml
M
r·························
-.-
... Q'\,"'
~
pl=or.,,,_ ~ 0 s s
Bi" "'
ei' Br Br \..
aTBCO bTBCO
129
TETRABROMOETHYLCYCLOHEXANE (TBECH)

bTBECH rac-(1R,2R)-1,2-dibromo-(4S)-4-[(1S)-1,2-dibromoethyl]cyclohexane 1.2 ml 50.0 µg/ml
gTBECH rac-(1R,2R)-1,2-dibromo-(4R)-4-[(1R)-1,2-dibromoethyl)cyclohexane 1.2 ml 50.0 µg/ml
TETRABROMOETHYLCYCLOHEXANE ISOMERIC SOLUTION/MIXTURES

abTBECH TBECHIsomeric Solution/Mixture 1.2 ml
aTBECH rac-(1R,2R)-1,2-dibromo-(4S)-4-[(1R)-1,2-dibromoethyl)cyclohexane 50.0 µg/ml

bTBECH rac-(1R,2R)-1,2-dibromo-(4S)-4-[(1S)-1,2-dibromoethyl)cyclohexane 50.0 µg/ml
gdTBECH TBECHIsomeric Solution/Mixture 1.2 ml
gTBECH rac-(1R,2R)-1,2-dibromo-(4R)-4-[(1R)-1,2-dibromoethyl)cyclohexane 50.0 µg/ml

dTBECH rac-(1R,2R)-1,2-dibromo-(4R)-4-[(1S)-1,2-dibromoethyl]cyclohexane 50.0 µg/ml
H H
Br Br
aTBECH bTBECH
rac-(1 R,2R)-1,2-dibromo-(4S)-4-[(1 R)-1,2-dibromoethyl]cyclohexane rac-(1 R,2R)-1,2-dibromo-(4S)-4-[(1 S)-1,2-dibromoethyl]cyclohexane
H H
Br
gTBECH dTBECH
rac-(1 R,2R)-1,2-dibromo-(4R)-4-[(1 R)-1,2-dibromoethyl]cyclohexane rac-(1 R,2R)-1,2-dibromo-(4R)-4-[(1 S)-1,2-dibromoethyl]cyclohexane
OCTABROMOTRIMETHYLPHENYLINDANE (OBIND)
OBIND 4,5,6, 7-Tetrabromo-1, 1,3-trimethyl-3-(2,3,4,5-tetrabromophenyl)indane 1.2 ml 50.0 µg/ml
OBIND
130
B15(2-ETHYLHEXYL)
TETRABROMOPHTHALATE(BEHTBP)
BEHTBP Bis(2-ethyl hexyl) tetrabromophtha late 1.2 ml 50.0 µg/ml
B1S(2-ETHYLHEXYL-d
11) TETRABROM0( C6)PHTHALATE(MBEHTBP)
13

Bis(2-ethylhexyl-d,,) tetrabromo("c_)phthalate
MBEHTBP 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene;
isotopic purity 99% or greater ("C,), 98% or greater ('H,4)
2-ETHYLHEXYL2,3,4,5-TETRABROMOBENZOATE(EHTBB)
EHTBB 2-Ethylhexyl 2,3,4,5-tetrabromobenzoate 1.2 ml 50.0 µg/ml
2-ETHYLHEXYL-d11 2,3,4,5-TETRABROM0(13C6)BENZOATE(MEHTBB)

•• 0
2-Ethylhexyl-d,, 2,3,4,5-tetrabromo("C,)benzoate
·~~ C021oc~C02C02C03
MEHTBB I n~ CDz(D3 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene;

' #
isotopic purity 99% or greater ("C,), 98% or greater ('H,,)
"
HEXACHLOROCYCLOPENTENYL-DIBROMOCYCLOOCTANE
(HCDBCO)
HCDBCO rac-(1 R,2R,5R,6R,9S, 1OS)-5,6-dibromo-1,10, 11, 12, 13, 13- 1.2 ml 50.0 µg/ml
hexachlorotricyclo[8.2.1.0'·')tridec-11-ene
TETRABROM0-0-CHLOROTOLUENE(TBCT)

TBCT Tetrabromo-o-chlorotoluene 1.2 ml 50.0 µg/ml
Cl CH3
Cl
•»o
Cl Br~Br
Cl Br
HCDBCO TBCT
131
PENTABROMOBENZYLACRYLATE(PBBA)
PBBA
,,~·~
I ~'~
o
Pentabromobenzyl acrylate
Br § St 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene
"
2,4,6-TRIBROMOPHENYLETHERS
Catalogue Number Product (toluene solution} Qty/Cone
ATE Ally! 2,4,6-tribromophenyl ether 1.2 ml 50.0 µg/ml
DPTE 2,3-Dibromopropyl 2,4,6-tribromophenyl ether 1.2 ml 50.0 µg/ml
BATE 2-Bromoallyl 2,4,6-tribromophenyl ether 1.2 ml 50.0 µg/ml
ATE DPTE BATE
DECHLORANEPLUS®
s-DP syn-Dechlorane Plus® 1.2 ml 50.0 µg/ml
a-DP anti-Dechlorane Plus® 1.2 ml 50.0 µg/ml
a a
syn-Dechlorane Plus® anti-Dechlorane Plus®
MASS-LABELLEDDECHLORANEPLUS®
anti-("C,.)Dech lorane Plus®

Ma-DP 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene;
DECHLORINATEDDECHLORANEPLUS®
aCl10DP anti-Cl 10-Dechlorane Plus® 1.2 ml 50.0 µg/ml

axxCl10DP exo-exo-anti-CI 10-Dechlorane Plus® 1.2 ml 50.0 µg/ml
aCl11DP anti-Cl 11-Dechlorane Plus® 1.2 ml 50.0 µg/ml
axCl11DP exo-anti-Cl11-Dechlorane Plus® 1.2 ml 50.0 µg/ml
132
DECHLORANEPLUS®MONO ADDUCTS

DPMA Dechlorane Plus®Mono adduct 1.2 ml 50.0 µg/ml
1,3-DPMA 1,3-Dechlorane Plus®Mono adduct 1.2 ml 50.0 µg/ml
EXPERIMENTALFLAME RETARDANTS(EFRs)

DBCD Dibromochlordene 1.2 ml 50.0 µg/ml
Dec-601 Dechlorane 601 1.2 ml 50.0 µg/ml
Dec-604CB Dechlorane 604 Component B 1.2 ml 50.0 µg/ml
CPlus Chlordene Plus 1.2 ml 50.0 µg/ml
DBALD Dibromoaldrin 1.2 ml 50.0 µg/ml
HCPN Hexach loro(phenyl)norbornene 1.2 ml 50.0 µg/ml
DPMA 1,3-DPMA DBCD
Dec-601 Dec-602 Dec-603
Dec-604 Dec-604CB CPlus
DBALD HCPN
133
TRIS(2,3-DIBROMOPROPYL)ISOCYANURATE (T23BPIC)
Tris(2, 3-d i bromopropyl) isocya nu rate

T23BPIC
2,3,4,5-TETRABROMOBENZOIC ACID (TBBA)
TBBA 2,3,4,5-Tetrabromobenzoic acid 1.2 ml 50.0 µg/ml
MASS-LABELLED 2,3,4,5-TETRABROMOBENZOIC ACID (MTBBA)
2,3,4,5-Tetrabromobenzoic acid ("C 6 -ring)

Br¢o
MTBBA I'S OH 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;
Br Br
Br
METHYL-2,3,4,5-TETRABROMOBENZOATE (MeTBBA)
0
Br¢ _.,.,-cH, Methyl-2, 3,4, 5-tetra bromobenzoate
MeTBBA I 0
Br # Br 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene

Br
TETRABROMOPHTHALIC ANHYDRIDE (TBPAn)
TBPAn Tetrabromophthalic anhydride 1.2 ml 50.0 µg/ml
MASS-LABELLED TETRABROMOPHTHALIC ANHYDRIDE (MTBPAn)
Tetrabromo("C 6 )phthalic anhydride

MTBPAn 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene;
134
NATIVE ORGANOPHOSPHORUS COMPOUNDS
0- oJ-o-O'
! - Triphenyl phosphate
TPP
6 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene
TOTP q-+b Tri-o-tolyl phosphate
(Y 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene
p-OJ-0-0,
TMTP
i- Tri-m-tolyl phosphate
-0- oJ-o-O-'
! - Tri-p-tolyl phosphate
¢
TPTP
B2tBPPP ~+~ Bis(2-tert-butylphenyl) phenyl phosphate

6
B3tBPPP 6-+-d Bis(3-tert-butylphenyl) phenyl phosphate
6
+-0-o-~-o--o+ Bis(4-tert-butylphenyl) phenyl phosphate
B4tBPPP
2tBPDPP o-+::b 2-tert-Butylphenyl diphenyl phosphate

6
3tBPDPP o-+--d 3-tert-Butylphenyl diphenyl phosphate
6
0-o-i-o--o+ 4-tert-Butylphenyl diphenyl phosphate
4tBPDPP
135
T3tBPP
b-,-r-,-d Tris(3-tert-butylphenyl) phosphate
~
+-0-,-1-,-o-+ Tris(4-tert-butylphenyl) phosphate
~
T4tBPP
~-l-~ Tris(2,4-di-tert-butylphenyl) phosphate
~
T24DtBPP
T21PPP q:,-,-~ Tris(2-isopropylphenyl) phosphate
&-- 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene
_p-,~-,-q_ Tris(3-isopropylphenyl) phosphate

T31PPP
6y 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene
>-0-,-r-,-o--< Tris(4-isopropylphenyl) phosphate

T41PPP
-9-,-1-,-q- Tris(3,4-dimethylphenyl) phosphate
~
T34DMPP
T35DMPP
p- ,J_,-q,
~-
Tris(3,5-dimethylphenyl) phosphate
B24DIPPPP ~-r-,& Bis(2,4-diisopropylphenyl) phenyl phosphate

6
B21PPPP ~,-I-~ Bis(4-isopropylphenyl) phenyl phosphate
6
136
B31PPPP
-P-"t"-q_ Bis(3-isopropylphenyl) phenyl phosphate
B41PPPP
)-0-o-i-o-O--< Bis(4-isopropylphenyl) phenyl phosphate
21PPDPP o-+=b 0
2-lsopropylphenyl diphenyl phosphate
6
31PPDPP
o-,t,-q_ 3-lsopropylphenyl diphenyl phosphate
41PPDPP
0-o-i-o-O--< 4-lsopropylphenyl diphenyl phosphate
24DIPPDPP o-+& 0
2,4-Diisopropylphenyl diphenyl phosphate
6
H,CH,c
'-o-~-o Triethyl phosphate
TEP I '-cH,OI,
H,CH,C
/ 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene
Tri-n-propyl phosphate
TPrP
Tri-n-butyl phosphate
TBP
Tris(2-butoxyethyl) phosphate
TBEP
137
Tris(2,3-dibromopropyl) phosphate
TDBPP
2-Ethylhexyl diphenyl phosphate

EHDP
Tris(2-ethylhexyl) phosphate
TEHP
Tris(2-chloroethyl) phosphate
TCEP
Tris[(2R)-1-chloro-2-propyl) phosphate
TCPP
Bis(1,3-dichloro-2-propyl) phosphate
BDCP
1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in acetonitrile
Tris(1,3-dichloro-2-propyl) phosphate
TDCPP
Abundance 251.1
250000
200000
150000
100000
55.1
70.1
94.0
50000
83.1 112.1 170.1
362.2
141.0 152.0 215.0 232.0 263.1
60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 220 230 240 250 260 270 280 290 300 310 320 330 340 350 360
HRGC/lRMS El+ Spectra Data for EHDPon a 15 m DB-5HT column.
138
MASS-LABELLED ORGANOPHOSPHORUS COMPOUNDS
0-0-1-0--0 ("C,.)Triphenyl phosphate

1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene;
0
MTPP
isotopic purity 99% or greater ("C 18)
0-0-1-0--0 Triphenyl phosphate-d 15

6
dTPP
isotopic purity 98% or greater (iH,,)
Triethyl phosphate-d 15
dTEP 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene;

isotopic purity 98% or greater (2H,,)
0
Tri-n-propyl phosphate-di,
D1CD,CO,C'o-~-O
dTPrP I '-co,co,co,
o,co,co,c/
isotopic purity 98% or greater (2Hi,)
Tri-n-butyl phosphate-di,
dTBP 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene;

isotopic purity 98% or greater (iH21)
Tris[2-butoxy("C,)ethyl] phosphate
M6TBEP 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene;

isotopic purity 99% or greater (13( 6)
Tris(2-chloroethyl) phosphate-d,,
dTCEP 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene;

isotopic purity 98% or greater (iH12)
Bis(1,3-dichloro-2-propyl) phosphate-d 10
dBDCP 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in acetonitrile;
isotopic purity 98% or greater (2H1J
Tris(1,3-dichloro-2-propyl) phosphate-d,,
dTDCPP 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene;
isotopic purity 98% or greater (2H,,)
139
NATIVE BROMINATED DIBENZO-p-DIOXINS (PBDDs)

BDD-1 1-Bromodi benzo-p-dioxi n 1.2 ml 50.0 µg/ml
BDD-27/28 2, 7/2,8-Dibromodibenzo-p-dioxin mix 1.2 ml 50.0 µg/ml
BDD-237 2,3, 7-Tribromod i benzo-p-d ioxi n 1.2 ml 50.0 µg/ml
BDD-1234 1,2,3,4-Tetrabromod i benzo-p-d ioxi n 1.2 ml 50.0 µg/ml
BDD-1378 1,3, 7,8-Tetrabromodibenzo-p-dioxin 1.2 ml 50.0 µg/ml
BDD-2378 2,3, 7,8-Tetrabromod i benzo-p-d ioxi n 1.2 ml 50.0 µg/ml
BDD-12378 1,2,3, 7,8-Pentabromodibenzo-p-dioxin 1.2 ml 50.0 µg/ml
BDD-12478 1,2,4, 7,8-Pentabromodibenzo-p-dioxin 1.2 ml 50.0 µg/ml
BDD-1234678 1,2,3,4,6, 7,8-Heptabromod i benzo-p-d ioxin 1.2 ml 25.0 µg/ml
BDD-12346789 Octabromodibenzo-p-dioxin 1.2 ml 10.0 µg/ml
MASS-LABELLED BROMINATED DIBENZO-p-DIOXIN
2,3,7,8-Tetrabromo("C,,)dibenzo-p-d ioxi n
MBDD-2378 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene;
Abundance 511.8
80000
70000
60000
50000
40000
30000
351.9
20000
80.0
134.0 175.9 255.8
10000 401.8
54.0 192.1
147.9161.9
106.111 .8 215.1 322.8
0•'r'ln!""'"~"""'1'nil'fn"l'lmTi"'r~"fl'mrn""r""/h"n/hp'l'n,,'ffl!"',t\'i'm-r,fflrTfl/l,,"l""""rlK>i'"'1'"'11'"1r=T'"~'1""1Tm'!"""T""'tfl'f!.i""'T"~'l"""'T""'l""'l""''l"""'T""'l"llfll'nl""T
m/z-> 50 60 70 80 90 100110120130140150160170180190200210220230240250260270280290300 310 320330340350360370 380 390400410420430440450460470480 490500 510520
HRGC/lRMSEl+ Spectra Data for MBDD-2378 on a 15 m DB-5HT column.
140
NATIVE BROMINATED DIBENZOFURANS (PBDFs)

BDF·4 4-Bromodi benzofuran 1.2 ml 50.0 µg/ml
BDF-24 2,4-Dibromodibenzofuran 1.2 ml 50.0 µg/ml
BDF-28 2,8-Dibromodibenzofuran 1.2 ml 50.0 µg/ml
BDF-138 1,3,8-Tribromod i benzofuran 1.2 ml 50.0 µg/ml
BDF-247 2,4, 7-Tribromod i benzofuran 1.2 ml 50.0 µg/ml
BDF-1278 1,2, 7,8-Tetrabromod i benzofuran 1.2 ml 50.0 µg/ml
BDF-2378 2,3, 7,8-Tetrabromodibenzofuran 1.2 ml 50.0 µg/ml
BDF-12378 1,2,3, 7,8-Pentabromodibenzofuran 1.2 ml 50.0 µg/ml
BDF-23478 2,3,4, 7,8-Pentabromodibenzofu ran 1.2 ml 50.0 µg/ml
BDF-1234678 1,2,3,4,6, 7,8-Heptabromodibenzofuran 1.2 ml 25.0 µg/ml
BDF-12346789 Octabromodibenzofuran 1.2 ml 25.0 µg/ml
NATIVE BROMO/CHLORO DIBENZO-p-DIOXINS

7•B·23·CDD 7-Bromo-2,3-d ich lorodibenzo-p-dioxi n (97%) 1.2 ml 48.5 µg/ml
2-B-378-CDD 2-Bromo-3, 7,8-trichlorodibenzo-p-dioxin (95%) 1.2ml 47.5µg/ml
2-B-1378-CDD 2-Bromo-1,3, 7,8-tetrach lorodibenzo-p-dioxin (95%) 1.2ml 47.5µg/ml
23·B•78•CDD 2, 3-D i bro mo- 7,8-d ich lo rod i benzo-p-d i oxi n 1.2 ml 50.0 µg/ml
MASS-LABELLED BROMO/CHLORO DIBENZO-p-DIOXIN
2,3-Dibro mo-7,8-dich loro("C,,)d i benzo-p-d ioxin

M23·B•78-CDD 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene;
141
NATIVE BROMO/CHLORO DIBENZOFURANS
Catalogue Number Product {toluene solution) Qty/Cone

8-B-23-CDF 8-B romo-2, 3-d ich lo rod i benzofu ran 1.2 ml 50.0 µg/ml
3-B-278-CDF 3-Bromo-2, 7,8-trich lorodibenzofuran 1.2 ml 50.0 µg/ml
8-B-234-CDF 8-B romo-2, 3,4-trich lo rod i benzofu ran 1.2 ml 50.0 µg/ml
4-B-2378-CDF 4-Bromo-2,3, 7,8-tetrach lorodibenzofu ran 1.2 ml 50.0 µg/ml
12·B• 78•CDF 1,2-Dibromo-7,8-dichlorod i benzofuran 1.2 ml 50.0 µg/ml
23-B-78-CDF 2, 3-D i bro mo- 7,8-d ich lo rod i benzofu ran 1.2 ml 50.0 µg/ml
13-B-278-CDF 1,3-Dibromo-2, 7,8-trichlorod i benzofuran 1.2 ml 50.0 µg/ml
MASS-LABELLED BROMO/CHLORO DIBENZOFURANS
Bt CI 8-Bromo-2,3-dichloro("C 12)dibenzofuran
MS-B-23-CDF 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene;
CI
CI CI 3-Bromo-2, 7,8-trich loro("C 12)d i benzofuran

M3·B•278-CDF 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene;
CI Br
CI CI
4-Bromo-2,3, 7,8-tetrach loro("C,,)dibenzofura n
M4-B-2378-CDF 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene;
CI CI
Br
CI Br 2,3-Dibromo- 7,8-dich loro("C,,)d i benzofura n

M23·B•78-CDF 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene;
CI Br
Br
1,3-Dibromo-2, 7,8-trichloro("C,,)dibenzofuran
CI CI
M13-B-278-CDF 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene;
CI Br
142
PER- & POLYFLUOROALKYL
SUBSTANCES (PFAS)
Wellington started the synthesis of PFASreference standards in 2004. Since then, primarily due to
reports in the literature and client requests, we have regularly added new native and mass-
labelled standards to our inventory. Included in our inventory, which is continually expanding, are
the following:
Perfluoroalkanesulfonates (PFSA)
Perfluoroethylcyclohexanesulfonate (PFECHS)
Perfluoroalkylcarboxylic acids (PFCA)
Perfluoroalkanesulfonamides (FASA)
Perfluoroalkanesulfonamidoethanols (N-MeFASE and N-EtFASE)
Perfluorooctanesulfonamidoacetic Acids (FOSAA)
Fluorotelomer Alcohols (X:2FTOH)
Fluorotelomer Carboxylic Acids and Sulfonates (FTCA and X:2FTS)
Fluorotelomer Unsaturated Carboxylic Acids (FTUCA)
Chloroperfluoroalkyl Ether Sulfonates (CI-PFESA)
Per- and Polyfluoroalkyl Ether Carboxylic Acids (PFECA)
Perfluoroalkyl Ether Sulfonate (PFESA)
Perfluoroalkylphosphonic Acids (PFAPA)
Perfluoroalkylphosphinic Acids (X:XPFPi)
Polyfluoroalkyl Phosphate Esters (PAP, diPAP, and SAmPAP)
Fluorotelomer Acrylates and Acetates (X:2FTAcr and X:2FTOAc)
We have also continued to add new PFASstandards as they are confirmed to be present in AFFF
mixtures, introduced as replacements for PFOSor PFOA (e.g. GenX}, or produced for other
applications. We also offer several solution/mixtures of native and mass-labelled PFASto be used
according to prescribed methods such as EPA Methods 533 and 537. However, it is highly possible
that new methods will be developed with expanded lists of target analytes. Thus, our inventory
of PFASwill continue to grow and we urge you to visit our website for announcements of new
products.
PFC-CVS-C

PFC-CVS-C PFC-CVS-C 1 kit
PFC·C·CS1 CS1 200 µL
PFC-C-CS2 CS2 200 µL
PFC-C-CS3 CS3 200 µL
PFC·C·CS4 CS4 200 µL
PFC-C-CSS CS5 200 µL
PFC-C- PFC-C- PFC-C- PFC-C- PFC-C-

CS1 CS2 CS3 CS4 css
NATIVE PFCs (ng/mL) (ng/mL) (ng/mL) (ng/mL) (ng/mL)
Perfluoro-n-butanoic acid PFBA 2.00 10.0 50.0 200 1000
Perfluoro-n-pentanoic acid PFPeA 2.00 10.0 50.0 200 1000
Perfluoro-n-hexanoic acid PFHxA 2.00 10.0 50.0 200 1000
Perfluoro-n-heptanoic acid PFHpA 2.00 10.0 50.0 200 1000
Perfluoro-n-octanoic acid PFOA 2.00 10.0 50.0 200 1000
Perfluoro-n-nonanoic acid PFNA 2.00 10.0 50.0 200 1000
Perfluoro-n-decanoic acid PFDA 2.00 10.0 50.0 200 1000
Perfluoro-n-undecanoic acid PFUdA 2.00 10.0 50.0 200 1000
Perfluoro-n-dodecanoic acid PFDoA 2.00 10.0 50.0 200 1000
Perfluoro-n-tridecanoic acid PFTrDA 2.00 10.0 50.0 200 1000
Perfluoro-n-tetradecanoic acid PFTeDA 2.00 10.0 50.0 200 1000
Perfluoro-n-hexadecanoic acid PFHxDA 2.00 10.0 50.0 200 1000
Perfluoro-n-octadecanoic acid PFODA 2.00 10.0 50.0 200 1000
Potassium perfluoro-1-butanesulfonate L-PFBS 2.00 10.0 50.0 200 1000

Sodium perfluoro-1-pentanesulfonate L-PFPeS 2.00 10.0 50.0 200 1000
Sodium perfluoro-1-hexanesulfonate L-PFHxS 2.00 10.0 50.0 200 1000
Sodium perfluoro-1-heptanesulfonate L-PFHpS 2.00 10.0 50.0 200 1000
Sodium perfluoro-1-octanesulfonate L-PFOS 2.00 10.0 50.0 200 1000
Sodium perfluoro-1-nonanesulfonate L-PFNS 2.00 10.0 50.0 200 1000
Sodium perfluoro-1-decanesulfonate L-PFDS 2.00 10.0 50.0 200 1000
Sodium perfluoro-1-dodecanesulfonate L-PFDoS 2.00 10.0 50.0 200 1000
MASS-LABELLED PFC EXTRACTION STANDARDS

Perfluoro-n-{"C.)butanoic acid MPFBA 50.0 50.0 50.0 50.0 50.0
Perfluoro-n-{"C,)pentanoic acid M5PFPeA 50.0 50.0 50.0 50.0 50.0
Perfluoro-n-(1,2,3,4,6-"C,)hexanoic acid M5PFHxA 50.0 50.0 50.0 50.0 50.0
Perfluoro-n-(1,2,3,4-"C.)heptanoic acid M4PFHpA 50.0 50.0 50.0 50.0 50.0
Perfluoro-n-{"C 8)octanoic acid MBPFOA 50.0 50.0 50.0 50.0 50.0
Perfluoro-n-{"C 9)nonanoic acid M9PFNA 50.0 50.0 50.0 50.0 50.0
Perfluoro-n-{1,2,3,4,5,6-"C.)decanoic acid M6PFDA 50.0 50.0 50.0 50.0 50.0
Perfluoro-n-(1,2,3,4,5,6, 7-"C,)undecanoic acid M7PFUdA 50.0 50.0 50.0 50.0 50.0
Perfluoro-n-(1,2-"C,)dodecanoic acid MPFDoA 50.0 50.0 50.0 50.0 50.0
Perfluoro-n-(1,2-"C,)tetradecanoic acid M2PFTeDA 50.0 50.0 50.0 50.0 50.0
Sodium perfluoro-1-(2,3,4-"C,)butanesulfonate M3PFBS 50.0 50.0 50.0 50.0 50.0

Sodium perfluoro-1-(1,2,3-"C,)hexanesulfonate M3PFHxS 50.0 50.0 50.0 50.0 50.0
Sodium perfluoro-1-("C.)octanesulfonate M8PFOS 50.0 50.0 50.0 50.0 50.0
MASS-LABELLED PFC INJECTION STANDARDS

Perfluoro-n-(2,3,4-"C,)butanoic acid M3PFBA 50.0 50.0 50.0 50.0 50.0
Perfluoro-n-(1,2-"C,)octanoic acid M2PFOA 50.0 50.0 50.0 50.0 50.0
Perfluoro-n-(1,2-"C,)decanoic acid MPFDA 50.0 50.0 50.0 50.0 50.0
Sodium perfluoro-1-{1,2,3,4-"C 4)octanesulfonate MPFOS 50.0 50.0 50.0 50.0 50.0
NOTE:Listedconcentrationsfor the perfluoroalkanesulfonates

are reportedas the salt.
144
PFC-CVS-C

MPFAC-C-ES Mass-Labelled PFASExtraction Standards Solution 1.2 ml
MPFAC·C-15 Mass-Labelled PFASInjection Standards Solution 1.2 ml
PFAC-MXC Native PFASStock Solution 1.2 ml
MPFAC-C-ES MPFAC-C-IS PFAC-MXC

NATIVE PFCs (ng/mL) (ng/mL) (ng/mL)
Perfluoro-n-butanoic acid PFBA 2000
Perfluoro-n-pentanoic acid PFPeA 2000
Perfluoro-n-hexanoic acid PFHxA 2000
Perfluoro-n-heptanoic acid PFHpA 2000
Perfluoro-n-octanoic acid PFOA 2000
Perfluoro-n-nonanoic acid PFNA 2000
Perfluoro-n-decanoic acid PFDA 2000
Perfluoro-n-undecanoic acid PFUdA 2000
Perfluoro-n-dodecanoic acid PFDoA 2000
Perfluoro-n-tridecanoic acid PFTrDA 2000
Perfluoro-n-tetradecanoic acid PFTeDA 2000
Perfluoro-n-hexadecanoic acid PFHxDA 2000
Perfluoro-n-octadecanoic acid PFODA 2000
Potassium perfluoro-1-butanesulfonate L-PFBS 2000

Sodium perfluoro-1-pentanesulfonate L-PFPeS 2000
Sodium perfluoro-1-hexanesulfonate L-PFHxS 2000
Sodium perfluoro-1-heptanesulfonate L-PFHpS 2000
Sodium perfluoro-1-octanesulfonate L-PFOS 2000
Sodium perfluoro-1-nonanesulfonate L-PFNS 2000
Sodium perfluoro-1-decanesulfonate L-PFDS 2000
Sodium perfluoro-1-dodecanesulfonate L-PFDoS 2000
MASS-LABELLED PFC EXTRACTION STANDARDS

Perfluoro-n-("C.)butanoic acid MPFBA 2000
Perfluoro-n-("C,)pentanoic acid MSPFPeA 2000
Perfluoro-n-(1,2,3,4,6-"C,)hexanoic acid MSPFHxA 2000
Perfluoro-n-(1,2,3,4-"C 4)heptanoic acid M4PFHpA 2000
Perfluoro-n-("C 8)octanoic acid MSPFOA 2000
Perfluoro-n-("C,)nonanoic acid M9PFNA 2000
Perfluoro-n-(1,2,3,4,5,6-"C.)decanoic acid MGPFDA 2000
Perfluoro-n-(1,2,3,4,5,6, 7-"C,)undecanoic acid M7PFUdA 2000
Perfluoro-n-(1,2-"C,)dodecanoic acid MPFDoA 2000
Perfluoro-n-(1,2-"C,)tetradecanoic acid M2PFTeDA 2000
Sodium perfluoro-1-(2,3,4-"C,)butanesulfonate M3PFBS 2000

Sodium perfluoro-1-(1,2,3-"C,)hexanesulfonate M3PFHxS 2000
Sodium perfluoro-1-("C.)octanesulfonate MSPFOS 2000
MASS-LABELLED PFC INJECTION STANDARDS

Perfluoro-n-(2,3,4-"C,)butanoic acid M3PFBA 2000
Perfluoro-n-(1,2-"C,)octanoic acid M2PFOA 2000
Perfluoro-n-(1,2-"C,)decanoic acid MPFDA 2000
Sodium perfluoro-1-(1,2,3,4-"C 4)octanesulfonate MPFOS 2000
NOTE:Listedconcentrationsfor the perfluoroalkanesulfonates

145
NATIVE LINEAR PERFLUOROALKANESULFONATES
(PFSA)

L·PFPrS Sodium perfluoro-1-propanesulfonate 1.2 ml 50.0 µg/ml
L·PFBS Potassium perfluoro-1-butanesulfonate 1.2 ml 50.0 µg/ml
L-PFPeS Sodium perfluoro-1-pentanesulfonate 1.2 ml 50.0 µg/ml
L·PFHxS Sodium perfluoro-1-hexanesulfonate 1.2 ml 50.0 µg/ml
L·PFHpS Sodium perfluoro-1-heptanesulfonate 1.2 ml 50.0 µg/ml
L-PFOS Sodium perfluoro-1-octanesulfonate 1.2 ml 50.0 µg/ml
L·PFOSK Potassium perfluoro-1-octanesulfonate 1.2 ml 50.0 µg/ml

L·PFNS Sodium perfluoro-1-nonanesulfonate 1.2 ml 50.0 µg/ml
L·PFDS Sodium perfluoro-1-decanesulfonate 1.2 ml 50.0 µg/ml
L·PFUdS Sodium perfluoro-1-undecanesulfonate 1.2 ml 50.0 µg/ml
L·PFDoS Sodium perfluoro-1-dodecanesulfonate 1.2 ml 50.0 µg/ml
L·PFTrDS Sodium perfluoro-1-tridecanesulfonate 1.2 ml 50.0 µg/ml
NATIVE PERFLUOROALKANESULFONATES:
SOLUTION/MIXTURE

PFS·MXA Native PFASSolution/Mixture 1.2 ml
Potassium perfl uoro-1-butanesu lfonate L-PFBS 2.00 µg/ml

Sodium perfl uoro-1-hexanesu lfonate L-PFHxS 2.00 µg/ml
Sodium perfl uoro-1-hepta nesulfonate L-PFHpS 2.00 µg/ml
Sodium perfluoro-1-octanesulfonate L-PFOS 2.00 µg/ml
Sodium perfl uoro-1-decanesu lfonate L-PFDS 2.00 µg/ml
NATIVE PERFLUOROETHYLCYCLOHEXANESULFONATE
(PFECHS)
PFECHS Perfluoro-4-ethylcyclohexanesulfonate (isomeric mixture) 1.2 ml 50.0 µg/ml
L.PFHpS
100- LwPFHxS
L-PFOS
L.PFDS
l•PFBS
--
I ~ "--' - Time
1.00 2.00 3.00 4.00 5.00 6.00 7.00
LC/MS Data for PFS-MXAon an Acquity UPLCBEH Shield RP,8 column.
146
NATIVE CHLORO-PERFLUOROALKANESULFONATE
CI\FF.\FF.\FF.\F
/ / / / so,Na' Sodium 8-chloroperfluoro-1-octanesulfonate
/c........_.,,...-c........__,...-c........__,...-c........_/
SCI-PFOS
F ;\ ;\ ;\ ;\ 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol
F F F F F F F F
NATIVE BRANCHEDPERFLUOROALKANESULFONATES

br-PFHxSK l-PFHxS with branched isomers (Potassium Salt) 1.2 ml 50.0 µg/ml
br-PFOSK l-PFOSK with branched isomers (Potassium Salt) 1.2 ml 50.0 µg/ml
T-PFOS Potassium perfl uorooctanesulfonate (Techn ica I Grade) 1.2 ml 50.0 µg/ml
NaP3MHpS Sodium perfluoro-3-methyl heptanesu lfonate 1.2 ml 50.0 µg/ml
NaP6MHpS Sodium perfluoro-6-methyl heptanesu lfonate 1.2 ml 50.0 µg/ml
ipPFNS Sodium perfluoro-7-methyloctanesu lfonate 1.2 ml 50.0 µg/ml
MASS-LABELLEDPERFLUOROALKANESULFONATES
Sodium perfluoro-1-(2,3,4- 13 C}butanesulfonate

M3PFBS 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;
>99% linear; >99% 2,3,4-13( 3
F. F F. F F F Sodium perfluoro-1-hexane( 1•0 2)sulfonate

\ / \ / \ / 51•01•o·Na•
MPFHxS _,...-c........_ _,...-c........_ _,...-c........_ / 2 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;
F ;\ ;\ ;\ >99% linear; 94% 180
F F F F F F 2
F. F F F F F
Sodium perfluoro-1-(1,2,3- 13 C3)hexanesulfonate
M3PFHxS
)I........_
)1........,,,)/........,,,/so,-Na•
1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;
F C C C
F
/\ F F
/\ F F
/\ F >99% linear; >99% 1,2,3-13( 3
Sodium perfluoro-1-(1,2,3,4- 13 C4)octanesulfonate

MPFOS 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;
>99% linear; >99% 1,2,3,4-13( 4
Sodium perfluoro-1-( 13 C8)octanesulfonate

MSPFOS 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;
>99% linear; >99% 13 C8
NOTE:Listedconcentrations
for the perfluoroalkanesulfonates
are reportedasthe salt.
147
NATIVE LINEARPERFLUOROALKYLCARBOXYLIC
ACIDS (PFCA)

PFBA Perfluoro-n-butanoic acid 1.2 ml 50.0 µg/ml
PFPeA Perfluoro-n-pentanoic acid 1.2 ml 50.0 µg/ml
PFHxA Perfluoro-n-hexanoic acid 1.2 ml 50.0 µg/ml
PFHpA Perfluoro-n-heptanoic acid 1.2 ml 50.0 µg/ml
PFOA Perfluoro-n-octanoic acid 1.2 ml 50.0 µg/ml
PFNA Perfluoro-n-nonanoic acid 1.2 ml 50.0 µg/ml
PFDA Perfluoro-n-decanoic acid 1.2 ml 50.0 µg/ml
PFUdA Perfluoro-n-undecanoic acid 1.2 ml 50.0 µg/ml
PFDoA Perfluoro-n-dodecanoic acid 1.2 ml 50.0 µg/ml
PFTrDA Perfluoro-n-tridecanoic acid 1.2 ml 50.0 µg/ml
PFTeDA Perfluoro-n-tetradecanoic acid 1.2 ml 50.0 µg/ml
PFHxDA Perfluoro-n-hexadecanoic acid 1.2 ml 50.0 µg/ml
PFODA Perfluoro-n-octadecanoic acid 1.2 ml 50.0 µg/ml
NATIVE PERFLUOROALKYLCARBOXYLIC
ACIDS: SOLUTION/MIXTURE

PFC-MXA Native PFCASolution/Mixture 1.2 ml
Perfluoro-n-butanoic acid PFBA 2.00 µg/ml

Perfluoro-n-pentanoic acid PFPeA 2.00 µg/ml
Perfluoro-n-hexanoic acid PFHxA 2.00 µg/ml
Perfluoro-n-heptanoic acid PFHpA 2.00 µg/ml
Perfluoro-n-octanoic acid PFOA 2.00 µg/ml
Perfluoro-n-nonanoic acid PFNA 2.00 µg/ml
Perfluoro-n-decanoic acid PFDA 2.00 µg/ml
Perfluoro-n-undecanoic acid PFUdA 2.00 µg/ml
Perfluoro-n-dodecanoic acid PFDoA 2.00 µg/ml
Perfluoro-n-tridecanoic acid PFTrDA 2.00 µg/ml
Perfluoro-n-tetradecanoic acid PFTeDA 2.00 µg/ml
NATIVE BRANCHEDPERFLUOROALKYLCARBOXYLIC
ACIDS

T·PFOA Ammonium perfluorooctanoate (Technical Grade) 1.2 ml 50.0 µg/ml
P3MHpA Perfluoro-3-methylheptanoic acid 1.2 ml 50.0 µg/ml
P4MOA Perfluoro-4-methyloctanoic acid 1.2 ml 50.0 µg/ml
ipPFNA Perfluoro-7-methyloctanoic acid 1.2 ml 50.0 µg/ml
P355TMHxA Perfl uoro-3, 5,5-trimethyl hexanoic acid 1.2 ml 50.0 µg/ml
P37DMOA Perfluoro-3, 7-dimethyloctanoic acid 1.2 ml 50.0 µg/ml
148
MASS-LABELLEDPERFLUOROALKYLCARBOXYLIC
ACIDS
Perfluoro-n-(2,3,4- 13C3)buta noic acid
M3PFBA 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;
>99% linear; >99% 2,3,4-13C3
Perfluoro-n-( 13C4)butanoic acid
MPFBA 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;
>99% linear; >99% 13 C4
Perfl uoro-n-(3,4, 5-13C)pentanoic acid
M3PFPeA 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;

>99% linear; >99% 3,4,5-13( 3
Perfluoro-n-(1 3C5)pentanoic acid
MSPFPeA 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;
>99% linear; >99% 13 C5
Perfluoro-n-(1,2- 13C)hexanoic acid

F F F F OIi
\/ \I ,,
MPFHxA F-....._ ......-c-....._
----~1:......-c-....._ 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;
;\ ;\ /\ OH
F F F F F F >99% linear; >99% 1,2-13( 2
F F F F 0 Perfluoro-n-(1,2,3,4,6- 13C5)hexanoic acid

\/ ~/ ,,II
MSPFHxA 3 ...,..-c
F-.....J. ••.
..,13 ......-c-......J.
3 ......-c-........... 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;
;\ ;\ ;\ OH
F F F F F F >99% linear; >99% 1,2,3,4,6-13( 5
Perfluoro-n-(1,2,3,4- 13C4)heptanoic acid
M4PFHpA 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;
>99% linear; >99% 1,2,3,4-13C4
Perfluoro-n-(1,2- 13C)octanoic acid
M2PFOA 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;

>99% linear; >99% 1,2-13( 2
Perfluoro-n-(1,2,3,4- 13C4)octanoic acid
MPFOA 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;

>99% linear; >99% 1,2,3,4-13C4
Perfluoro-n-( 13C8)octanoic acid
MSPFOA 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;

>99% linear; >98% 13C
8 and 1.0% 13C
4
Perfluoro-n-(1,2,3,4,5- 13C5)nonanoic acid
MPFNA 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;

>99% linear; >99% 1,2,3,4,5-13( 5
149
MASS-LABELLEDPERFLUOROALKYLCARBOXYLIC
ACIDS
Perfluoro-n-(1 3 C9)nonanoic acid
M9PFNA 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;

>99% linear; >99% 13(
9
Perfluoro-n-(1,2- 13C}decanoic acid
MPFDA 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;

>99% linear; >99% 1,2-13( 2
Perfluoro-n-(1,2,3,4,5,6- 13C6}decanoic acid
M6PFDA 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;

>99% linear; >99% 1,2,3,4,5,6-13( 6
Perfluoro-n-(1,2- 13C2)undecanoic acid
MPFUdA
\/ \/ \/ \/ \/ J
.,........c......._
.,........c........_
__ c........,,............c........._
,......-c p _............c.........._
......... 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;
F ;\ ;\ ;\ ;\ ;\ OH
FFFFFFFFFF >99% linear; >99% 1,2-13C2
Perfluoro-n-(1,2,3,4,5,6, 7-13C7)undecanoic acid
M7PFUdA 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;

>99% linear; >99% 1,2,3,4,5,6,7-13( 7
Perfluoro-n-(1,2- 13C2)dodecanoic acid

F\ F F\ F F\ F F\ F F\ F OIi
F / / / / /,,
MPFDoA , ,........c..........
.,........c........._
.....-c........._
_.-c........._
_....c..........
13__ c, 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;
;\ ;\ ;\ ;\ ;\ ;\ OH
FFFFFFFFFFFF >99% linear; >99% 1,2-13( 2
Perfluoro-n-(1,2- 13C2)tetradecanoic acid
M2PFTeDA 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;

>99% linear; >99% 1,2-13( 2
Perfluoro-n-(1,2- 13C2)hexadecanoic acid
M2PFHxDA 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;
>99% linear; >99% 1,2-13C2
150
MIXED NATIVE PFAS: SOLUTION/MIXTURES

PFAC·MXA Native PFCAand PFSASolution/Mixture 1.2 ml
Perfluoro-n-butanoic acid PFBA 5.00 µg/ml
Perfluoro-n-pentanoic acid PFPeA 5.00 µg/ml
Perfluoro-n-hexanoic acid PFHxA 5.00 µg/ml
Perfluoro-n-heptanoic acid PFHpA 5.00 µg/ml
Perfluoro-n-octanoic acid PFOA 5.00 µg/ml
Perfluoro-n-nonanoic acid PFNA 5.00 µg/ml
Perfluoro-n-decanoic acid PFDA 5.00 µg/ml
Potassium perfl uoro-1-butanesu lfonate l-PFBS 5.00 µg/ml

Sodium perfl uoro-1-hexanesu lfonate l-PFHxS 5.00 µg/ml
Sodium perfluoro-1-octanesulfonate l-PFOS 5.00 µg/ml
PFAC-MXB Native PFCAand PFSASolution/Mixture 1.2 ml

Perfluoro-n-butanoic acid PFBA 2000 ng/ml
Perfluoro-n-pentanoic acid PFPeA 2000 ng/ml
Perfluoro-n-hexanoic acid PFHxA 2000 ng/ml
Perfluoro-n-heptanoic acid PFHpA 2000 ng/ml
Perfluoro-n-octanoic acid PFOA 2000 ng/ml
Perfluoro-n-nonanoic acid PFNA 2000 ng/ml
Perfluoro-n-decanoic acid PFDA 2000 ng/ml
Perfluoro-n-undecanoic acid PFUdA 2000 ng/ml
Perfluoro-n-dodecanoic acid PFDoA 2000 ng/ml
Perfluoro-n-tridecanoic acid PFTrDA 2000 ng/ml
Perfluoro-n-tetradecanoic acid PFTeDA 2000 ng/ml
Perfluoro-n-hexadecanoic acid PFHxDA 2000 ng/ml
Perfluoro-n-octadecanoic acid PFODA 2000 ng/ml
Potassium perfl uoro-1-butanesu lfonate l-PFBS 2000 ng/ml

Sodium perfl uoro-1-hexanesu lfonate l-PFHxS 2000 ng/ml
Sodium perfluoro-1-octanesulfonate l-PFOS 2000 ng/ml
Sodium perfl uoro-1-decanesu lfonate l-PFDS 2000 ng/ml
PFAC·MXF Native Replacement PFASSolution/Mixture 1.2 ml

2,3,3,3-Tetrafluoro-2-(1, 1,2,2,3,3,3-heptafluoroproproxy)propanoic acid HFPO-DA 2000 ng/ml
Sodium dodecafluoro-3H-4,8-dioxanonanoate NaDONA 2000 ng/ml
Potassium 9-chlorohexadecafluoro-3-oxanonane-1-sulfonate 9CI-PF3ONS 2000 ng/ml
Potassium 11-chloroeicosafl uoro-3-oxau ndecane-1-su lfonate 11CI-PF3OUdS 2000 ng/ml
PFAC-MXG Native Perfluoroalkyl Ether Carboxylic Acids and Sulfonate Solution/Mixture 1.2 ml
Perfluoro-4-oxapentanoic acid PF4OPeA 2000 ng/ml
Perfluoro-5-oxahexanoic acid PFSOHxA 2000 ng/ml
Perfluoro-3,6-dioxaheptanoic acid 3,6-OPFHpA 2000 ng/ml
Potassium perfluoro(2-ethoxyethane)sulfonate PFEESA 2000 ng/ml
151
MIXED NATIVE PFAS: SOLUTION/MIXTURES

PFAC-MXH Native PFASSolution/Mixture 1.2 ml
Perfl uoro-1-octanesu lfona mide FOSA 1000 ng/ml
N-methylperfluorooctanesulfonamidoacetic acid (linear and branched isomers) br-NMeFOSAA 1000 ng/ml
N-ethylperfluorooctanesulfonamidoacetic acid (linear and branched isomers) br-NEtFOSAA 1000 ng/ml

Sodium perfl uoro-1-penta nesulfonate l-PFPeS 1000 ng/ml
Potassium perfluorohexanesulfonate (linear and branched isomers) br-PFHxSK 1000 ng/ml
Sodium perfl uoro-1-hepta nesulfonate l-PFHpS 1000 ng/ml
Potassium perfluorooctanesulfonate (linear and branched isomers) br-PFOSK 1000 ng/ml
Sodium perfl uoro-1-nona nesulfonate l-PFNS 1000 ng/ml
Sodium perfluoro-1-dodecanesulfonate l-PFDoS 1000 ng/ml
Sodium 1H,1H,2H,2H-perfluorohexanesulfonate 4:2FTS 4000 ng/ml
Sodium 1H,1H,2H,2H-perfluorooctanesulfonate 6:2FTS 4000 ng/ml
Sodium 1H,1H,2H,2H-perfluorodecanesulfonate 8:2FTS 4000 ng/ml
PFAC·MXI Native N-Me/EtFOSA & N-Me/EtFOSESolution/Mixture 1.2 ml

N-methylperfluoro-1-octanesulfonamide N-MeFOSA 1.00 µg/ml
N-ethylperfluoro-1-octanesulfonamide N-EtFOSA 1.00 µg/ml
2-(N-methylperfluoro-1-octanesulfonamido)ethanol N-MeFOSE 10.0 µg/ml
2-(N-ethyl perfl uoro-1-octanesu lfonam ido )ethanol N-EtFOSE 10.0 µg/ml
PFAC-MXJ Native X:3 Fluorotelomer Carboxylic Acid Solution/Mixture 1.2 ml
3-Perfluoropropyl propanoic acid FPrPA 4.00 µg/ml
3-Perfluoropentyl propanoic acid FPePA 20.0 µg/ml
3-Perfluoroheptyl propanoic acid FHpPA 20.0 µg/ml
152
MIXED MASS-LABELLED PFAS: SOLUTION/MIXTURES
Catalogue Number Product {methanol solution) Qty/Cone

MPFAC·HIF-ES Mass-Labelled PFASExtraction Standard Solution/Mixture 1.2 ml
Perfluoro-n-("C 4)butanoic acid MPFBA 2000 ng/ml
Perfluoro-n-("C,)pentanoic acid M5PFPeA 1000 ng/ml
Perfluoro-n-(1,2,3,4,6-"C,)hexanoic acid M5PFHxA 500 ng/ml
Perfluoro-n-(1,2,3,4-"C 4)heptanoic acid M4PFHpA 500 ng/ml
Perfluoro-n-("C 8)octanoic acid MSPFOA 500 ng/ml
Perfluoro-n-("C 9)nonanoic acid M9PFNA 250 ng/ml
Perfl uoro-n-( 1,2,3,4,5,6-"C 6)decanoic acid M6PFDA 250 ng/ml
Perfluoro-n-(1,2,3,4,5,6, 7-"C,)undecanoic acid M7PFUdA 250 ng/ml
Perfluoro-n-(1,2-"C,)dodecanoic acid MPFDoA 250 ng/ml
Perfl uoro-n-( 1,2-"C,)tetradecanoic acid M2PFTeDA 250 ng/ml
Perfluoro-1-("C 8)octanesulfonamide MSFOSA 500 ng/ml
N-methyl-d,-perfluoro-1-octanesulfonamide d-N-MeFOSA 500 ng/ml
N-ethyl-d,-perfluoro-1-octanesulfonamide d-N-EtFOSA 500 ng/ml
N-methyl-d,-perfluoro-1-octanesulfonamidoacetic acid d3-N-MeFOSAA 1000 ng/ml
N-ethyl-d,-perfluoro-1-octanesulfonamidoacetic acid d5-N-EtFOSAA 1000 ng/ml
2-(N-methyl-d, -perfluoro-1-octanesulfonam ido)etha n-d4-ol d7-N-MeFOSE 5000 ng/ml
2-(N-ethyl-d,-perfl uoro-1-octanesu lfonam ido )ethan-d 4 -ol d9-N-EtFOSE 5000 ng/ml
2,3,3,3-Tetrafluoro-2-(1, 1,2,2,3,3,3-heptafluoropropoxy)("C,)propanoic acid M3HFPO-DA 2000 ng/ml
Sodium perfluoro-1-(2,3,4-"C,)butanesulfonate M3PFBS 500 ng/ml

Sodium perfluoro-1-(1,2,3-"C,)hexanesulfonate M3PFHxS 500 ng/ml
Sodium perfl uoro-1-("C.)octanesu lfonate MSPFOS 500 ng/ml
Sodium 1H, 1H,2H,2H-perfluoro(1,2-"C,)hexanesulfonate M2-4:2FTS 1000 ng/ml
Sodium 1H, 1H,2H,2H-perfluoro(1,2-"C,)octanesulfonate M2-6:2FTS 1000 ng/ml
Sodium 1H, 1H,2H,2H-perfluoro(1,2-"C,)decanesulfonate M2-8:2FTS 1000 ng/ml
Catalogue Number Product {methanol solution) Qty/Cone

MPFAC-HIF-15 Mass-Labelled PFASInjection Standard Solution/Mixture 1.2 ml
Perfluoro-n-(2,3,4-"C,)butanoic acid M3PFBA 1000 ng/ml
Perfluoro-n-(1,2-"C,)hexanoic acid MPFHxA 500 ng/ml
Perfluoro-n-(1,2,3,4-"C.)octanoic acid MPFOA 500 ng/ml
Perfl uoro-n-( 1,2,3,4,5-"C,)nonanoic acid MPFNA 250 ng/ml
Perfluoro-n-(1,2-"C,)decanoic acid MPFDA 250 ng/ml
Sodium perfl uoro-1-hexane( 1•0 2)sulfonate MPFHxS 500 ng/ml

Sodium perfluoro-1-(1,2,3,4-"C.)octanesulfonate MPFOS 500 ng/ml
153
MIXED NATIVE PFAS: SOLUTION/MIXTURE

EU-5813-NSS 5813/20 PFASNative Solution/Mixture 1.2 ml
Potassium perfl uoro-1-butanesu lfonate L-PFBS 2000 ng/ml

Sodium perfl uoro-1-penta nesulfonate L-PFPeS 2000 ng/ml
Sodium perfl uoro-1-hexanesu lfonate L-PFHxS 2000 ng/ml
Sodium perfl uoro-1-hepta nesulfonate L-PFHpS 2000 ng/ml
Sodium perfl uoro-1-octa nesulfonate L-PFOS 2000 ng/ml
Sodium perfl uoro-1-nona nesulfonate L-PFNS 2000 ng/ml
Sodium perfl uoro-1-decanesu lfonate L-PFDS 2000 ng/ml
Sodium perfluoro-1-undecanesulfonate L-PFUdS 2000 ng/ml
Sodium perfluoro-1-dodecanesulfonate L-PFDoS 2000 ng/ml
Sodium perfluoro-1-tridecanesulfonate L-PFTrDS 2000 ng/ml
MIXED MASS-LABELLED PFAS: SOLUTION/MIXTURE

MPFAC·MXA Mass-Labelled PFCAand PFSASolution/Mixture 1.2 ml
Perfluoro-n-(1,2,3,4-"C 4)octanoic acid MPFOA 2000 ng/ml
Perfluoro-n-(1,2,3,4,5-"C,)nonanoic acid MPFNA 2000 ng/ml
Perfluoro-n-(1,2-"C,)undecanoic acid MPFUdA 2000 ng/ml
Sodium perfl uoro-1-hexane( 1•0 2)sulfonate MPFHxS 2000 ng/ml

Sodium perfluoro-1-(1,2,3,4-"c.)octanesulfonate MPFOS 2000 ng/ml
154
PFAC-24PAR Native PFASPrecision and Recovery Standard Solution 1.2 ml
Perfluoro-n-butanoic acid PFBA 2000 ng/mL
Perfluoro-n-pentanoic acid PFPeA 2000 ng/mL
Perfluoro-n-hexanoic acid PFHxA 2000 ng/mL
Perfluoro-n-heptanoic acid PFHpA 2000 ng/mL
Perfluoro-n-octanoic acid PFOA 2000 ng/mL
Perfluoro-n-nonanoic acid PFNA 2000 ng/mL
Perfluoro-n-decanoic acid PFDA 2000 ng/mL
Perfluoro-n-undecanoic acid PFUdA 2000 ng/mL
Perfluoro-n-dodecanoic acid PFDoA 2000 ng/mL
Perfluoro-n-tridecanoic acid PFTrDA 2000 ng/mL
Perfluoro-n-tetradecanoic acid PFTeDA 2000 ng/mL
Perfl uoro-1-octanesu lfona m ide FOSA 2000 ng/mL
N-methylperfluoro-1-octanesulfonamidoacetic acid N-MeFOSAA 2000 ng/mL
N-ethylperfluoro-1-octanesulfonamidoacetic acid N-EtFOSAA 2000 ng/mL
Potassium perfl uoro-1-butanesu lfonate L-PFBS 2000 ng/mL

Sodium perfl uoro-1-penta nesulfonate L-PFPeS 2000 ng/mL
Potassium perfluorohexanesulfonate {linear and branched isomers) br-PFHxSK 2000 ng/mL
Sodium perfl uoro-1-hepta nesulfonate L-PFHpS 2000 ng/mL
Potassium perfluorooctanesulfonate {linear and branched isomers) br-PFOSK 2000 ng/mL
Sodium perfl uoro-1-nona nesulfonate L-PFNS 2000 ng/mL
Sodium perfl uoro-1-decanesu lfonate L-PFDS 2000 ng/mL
Sodium 1H, 1H,2H,2H-perfluorohexanesulfonate 4:2FTS 2000 ng/mL
Sodium 1H, 1H,2H,2H-perfluorooctanesulfonate 6:2FTS 2000 ng/mL
Sodium 1H, 1H,2H,2H-perfluorodecanesulfonate 8:2FTS 2000 ng/mL
MIXED MASS-LABELLED PFAS: SOLUTION/MIXTURE

MPFAC-24ES Mass-Labelled PFASExtraction Standard Solution 1.2 ml
Perfluoro-n-{"C 4)butanoic acid MPFBA 1000 ng/mL
Perfluoro-n-{"C,)pentanoic acid MSPFPeA 1000 ng/mL
Perfluoro-n-(1,2,3,4,6-"C,)hexanoic acid MSPFHxA 1000 ng/mL
Perfluoro-n-(1,2,3,4-"C.)heptanoic acid M4PFHpA 1000 ng/mL
Perfluoro-n-{"C 8)octanoic acid MSPFOA 1000 ng/mL
Perfluoro-n-{"C 9)nonanoic acid M9PFNA 1000 ng/mL
Perfluoro-n-{1,2,3,4,5,6-"C 6)decanoic acid M6PFDA 1000 ng/mL
Perfluoro-n-(1,2,3,4,5,6, 7-"C,)undecanoic acid M7PFUdA 1000 ng/mL
Perfluoro-n-{ 1,2-"C,)dodecanoic acid MPFDoA 1000 ng/mL
Perfluoro-n-{ 1,2-"C,)tetradecanoic acid M2PFTeDA 1000 ng/mL
Perfluoro-1-{ 13C8)octanesulfonamide MSFOSA 1000 ng/mL
N-methyl-d,-perfluoro-1-octanesulfonamidoacetic acid d3-N-MeFOSAA 1000 ng/mL
N-ethyl-d,-perfluoro-1-octanesulfonamidoacetic acid dS-N-EtFOSAA 1000 ng/mL
Sodium perfluoro-1-(2,3,4-"C,)butanesulfonate M3PFBS 1000 ng/mL

Sodium perfluoro-1-(1,2,3-"C,)hexanesulfonate M3PFHxS 1000 ng/mL
Sodium perfl uoro-1-{"C 8)octanesu lfonate MSPFOS 1000 ng/mL
Sodium 1H, 1H,2H,2H-perfluoro{1,2-"C,)hexanesulfonate M2-4:2FTS 1000 ng/mL
Sodium 1H, 1H,2H,2H-perfluoro{1,2-"C,)octanesulfonate M2-6:2FTS 1000 ng/mL
Sodium 1H, 1H,2H,2H-perfluoro{1,2-"C,)decanesulfonate M2-8:2FTS 1000 ng/mL
155
PFAC30PAR Native PFASPrecision and Recovery Standard Solution 1.2 ml
Perfluoro-1-butanesulfonamide FBSA 1000 ng/ml
Perfluoro-1-hexanesulfonamide FHxSA 1000 ng/ml
Perfl uoro-1-octanesu lfona mide FOSA 1000 ng/ml

Sodium perfl uoro-1-hepta nesulfonate l-PFHpS 1000 ng/ml
Sodium perfluoro-1-nonanesulfonate l-PFNS 1000 ng/ml
Potassium 9-chlorohexadecafluoro-3-oxa nonane-1-su lfonate 9CI-PF3ONS 1000 ng/ml
Potassium 11-chloroeicosafl uoro-3-oxau ndecane-1-sulfonate 11CI-PF3OUdS 1000 ng/ml
EPA METHOD 537.1 SOLUTION/MIXTURES

EPA-5375S·R1 EPA Method 537.1 Surrogate Primary Dilution Standard (SURPDS) 1.2 ml
2,3,3,3-Tetrafluoro-2-(1, 1,2,2,3,3,3-heptafluoroproproxy)("C,)propanoic acid M3HFPO-DA 1000 ng/ml
N-ethyl-d,-perfluoro-1-octanesulfonamidoacetic acid d5-N-EtFOSAA 4000 ng/ml
EPA-537I5 EPA Method 537.1 Internal Standard Primary Dilution Standard (IS PDS) 1.2 ml
Perfluoro-n-(1,2-"C,)octanoic acid M2PFOA 1000 ng/ml
Sodium perfluoro-1-(1,2,3,4-"C.)octanesulfonate MPFOS 3000 ng/ml
156
EPA METHOD 537.1 SOLUTION/MIXTURES
EPA-537PDS-R1 EPA Method 537.1 Analyte Primary Dilution Standard (branched/linear mix) 1.2 ml
Potassium perfluoro-1-butanesulfonate l-PFBS 2000 ng/ml

Potassium perfluorooctanesulfonate (linear and branched isomers) br-PFO5K 2000 ng/ml
Potassium 11-chloroeicosafluoro-3-oxaundecane-1-sulfonate 11CI-PF3OUdS 2000 ng/ml
EPA-537PDSL-R1 EPA Method 537.1 Analyte Primary Dilution Standard (linear isomers only) 1.2 ml
2,3,3,3-Tetrafl uoro-2-( 1,1,2,2,3,3,3-heptafl uoroproproxy)propanoic acid HFPO-DA 2000 ng/ml
N-methylperfluoro-1-octanesulfonamidoacetic acid N-MeFOSAA 2000 ng/ml
N-ethylperfluoro-1-octanesulfonamidoacetic acid N-EtFOSAA 2000 ng/ml
Potassium perfluoro-1-butanesulfonate l-PFBS 2000 ng/ml

Sodium perfluoro-1-hexanesulfonate l-PFHxS 2000 ng/ml
Sodium perfluoro-1-octanesulfonate l-PFOS 2000 ng/ml
Potassium 9-chlorohexadecafluoro-3-oxa nonane-1-su lfonate 9CI-PF3ONS 2000 ng/ml
Potassium 11-chloroeicosafl uoro-3-oxau ndecane-1-sulfonate 11CI-PF3OUdS 2000 ng/ml
157
ISO 21675:2019 SOLUTION/MIXTURES
ISO 21675-NSS ISO 21675:2019 Native Stock Solution 1.2 ml
Perfluoro-n-hexadecanoic acid PFHxDA 100 ng/ml
Perfluoro-n-octadecanoic acid PFODA 100 ng/ml
Perfluoro-1-octanesulfonamide FOSA 100 ng/ml
N-methylperfluoro-1-octanesulfonamide N-MeFOSA 100 ng/ml
N-ethylperfluoro-1-octanesulfonamide N-EtFOSA 100 ng/ml
N-methylperfluoro-1-octanesulfonamidoacetic acid N-MeFOSAA 100 ng/ml
N-ethylperfluoro-1-octanesulfonamidoacetic acid N-EtFOSAA 100 ng/ml
2H-Perfluoro-2-decenoic acid FOUEA 100 ng/ml
2,3,3,3-Tetrafl uoro-2-( 1,1,2,2,3,3,3-heptafl uoroproproxy)propanoic acid HFPO-DA 100 ng/ml
Potassium perfluoro-1-butanesulfonate L-PFBS 100 ng/ml

Sodium perfluoro-1-hexanesulfonate L-PFHxS 100 ng/ml
Sodium perfluoro-1-heptanesulfonate L-PFHpS 100 ng/ml
Sodium perfluoro-1-octanesulfonate L-PFOS 100 ng/ml
Sodium perfluoro-1-decanesulfonate L-PFDS 100 ng/ml
Sodium 1H, 1H,2H,2H-perfluorooctanesulfonate 6:2FTS 100 ng/ml
Sodium 1H, 1H,2H,2H-perfluorodecanesulfonate 8:2FTS 100 ng/ml
Sodium bis(1H,1H,2H,2H-perfluorodecyl) phosphate 8:2diPAP 100 ng/ml
158
ISO 21675:2019 SOLUTION/MIXTURES
ISO 21675-LSS ISO 21675:2019 Labelled Stock Solution 1.2 ml
Perfluoro-n-("C,)pentanoic acid MSPFPeA 100 ng/ml
Perfl uoro-n-( 1,2,3,4,6-"C,)hexa noic acid MSPFHxA 100 ng/ml
Perfluoro-n-(1,2,3,4-"C.)heptanoic acid M4PFHpA 100 ng/ml
Perfluoro-n-("C 0)octanoic acid MSPFOA 100 ng/ml
Perfluoro-n-("C.)nonanoic acid M9PFNA 100 ng/ml
Perfluoro-n-(1,2,3,4,5,6-"C.)decanoic acid M6PFDA 100 ng/ml
Perfl uoro-n-( 1,2-"C,)tetradecanoic acid M2PFTeDA 100 ng/ml
Perfluoro-n-(1,2-"C,)hexadecanoic acid M2PFHxDA 100 ng/ml
Perfluoro-1-("C 0)octanesulfonamide MSFOSA 100 ng/ml
N-methyl-d,-perfluoro-1-octanesulfonamide d-N-MeFOSA 100 ng/ml
N-ethyl-d,-perfluoro-1-octanesulfonamide d-N-EtFOSA 100 ng/ml
N-ethyl-d,-perfluoro-1-octanesulfonamidoacetic acid dS-N-EtFOSAA 100 ng/ml
2H-Perfluoro-(1,2-"C,)-2-decenoic acid MFOUEA 100 ng/ml

Sodium perfluoro-1-("C.)octanesulfonate MSPFOS 100 ng/ml
Sodium bis[1 H,1H,2H,2H-(1,2-"C,)perfluorodecyl] phosphate M4-8:2diPAP 100 ng/ml
159
EPA METHOD 533 SOLUTION/MIXTURES
EPA-533ES EPA Method 533 Isotope Dilution Standard PDS 1.2 ml
Perfluoro-n-("C.)butanoic acid MPFBA 500 ng/ml
Perfluoro-n-("C,)pentanoic acid M5PFPeA 500 ng/ml
Perfluoro-n-(1,2,3,4.6-"C,)hexanoic acid M5PFHxA 500 ng/ml
Perfluoro-n-(1,2,3,4-"C.)heptanoic acid M4PFHpA 500 ng/ml
Perfluoro-n-( C8)octanoic acid
13 MSPFOA 500 ng/ml
Perfluoro-n-("C 9)nonanoic acid M9PFNA 500 ng/ml
Perfluoro-n-(1,2,3,4,5,6-"C.)decanoic acid M6PFDA 500 ng/ml

Sodium perfl uoro-1-("C.)octanesu lfonate MSPFOS 500 ng/ml
Sodium 1H, 1H,2H,2H-perfluoro(1,2-"C,)hexanesulfonate M2-4:2FTS 2000 ng/ml
EPA-53315 EPA Method 533 Isotope Performance Standard (IS PDS) 1.2 ml
Perfluoro-n-(2,3,4-"C,)butanoic acid M3PFBA 1000 ng/ml
Perfluoro-n-(1,2-"C,)octanoic acid M2PFOA 1000 ng/ml
Sodium perfluoro-1-(1,2,3,4-"C 4)octanesulfonate MPFOS 3000 ng/ml
EPA-533PAR EPA Method 533 Native Analyte Primary Dilution Standard (br/linear mix) 1.2 ml
Perfluoro-4-oxapentanoic acid PF4OPeA 500 ng/ml
Perfluoro-5-oxahexanoic acid PF5OHxA 500 ng/ml
Perfluoro-3,6-dioxaheptanoic acid 3,6-OPFHpA 500 ng/ml

Sodium perfluoro-1-heptanesulfonate l-PFHpS 500 ng/ml
Potassium 11-chloroeicosafluoro-3-oxaundecane-1-sulfonate 11CI-PF3OUdS 500 ng/ml
Potassium perfluoro(2-ethoxyethane)sulfonate PFEESA 500 ng/ml
160
PFOS/PFOAISOMERS
Catalogue Number Product (methanol solution) Qty/Anion Cone
P1MHpS Sodium Perfluoro-1-methylheptanesu lfonate 200 µL 1.00 µg/ml
Sodium Perfluoro-3-methylheptanesulfonate 200 µL 1.00 µg/ml

P3MHpS
Perfluoro-3-methylheptanoic acid 1.90 µg/ml

P4MHpS
Sodium Perfluoro-S-methylheptanesulfonate 200 µL 1.00 µg/ml

PSMHpS

P6MHpS
Perfluoro-6-methylheptanoic acid 3.10µg/ml
Sodium Perfluoro-5,5-dimethylhexanesulfonate 200 µL 1.00 µg/ml

PSSDMHxS
Perfluoro-5,5-dimethylhexanoic acid 1.95 µg/ml
Sodium Perfluoro-4,5-dimethylhexanesulfonate 200 µL 1.00 µg/ml

P45DMHxS
Sodium Perfluoro-3,5-dimethylhexanesulfonate 0.50 µg/ml
F\FF\FF\F
I I I
F-......_,.......,-......_,.......c-......_,.......c-......_,.......
R'
F-......_
\/ \/ \/
/C-......_ /C-......_ /C-......_
C C C C C C C R
F
/\ F
/\
F F
I\
F F
I\
F CF3
/\
FFFFFCF
/\ I\ 3
linear Perfluoro-1-methyl- Perfluoro-3-methyl-
F-......_
\/ \;3 \/
/C-......_/C-......_/C-......_ F-......_
\/ \/ \/
/C-......_ /C-......_ /C-......_ F-......_
\J3 \/ \/
/C-......_ /C-......_ /C-......_
C C C R C C C R C C C R
/\ /\ I\ F
/\ F
/\
F CF3 F
/\ F
/\ /\ /\
F F F F F F F F F F F F
Perfluoro-4-methyl- Perfluoro-5-methyl- Perfluoro-6-methyl-
Perfluoro-5,5-dimethyl- Perfluoro-4,5-dimethyl- Perfluoro-3,5-dimethyl-
NOTE: R= CO and CF S0 2
-
2 3
-
R'= SQ only 3
-
161
NATIVE PERFLUOROALKANESULFONAMIDES (FASA)
FBSA-1 Perfluoro-1-butanesulfonamide (in isopropanol) 1.2 ml 50.0 µg/ml
FHxSA-1 Perfluoro-1-hexanesulfonamide (in isopropanol) 1.2 ml 50.0 µg/ml
FHpSA-1 Perfluoro-1-heptanesulfonamide (in isopropanol) 1.2 ml 50.0 µg/ml
FOSA-1 Perfluoro-1-octanesulfonamide (in isopropanol) 1.2 ml 50.0 µg/ml
FDSA-1 Perfluoro-1-decanesulfonamide (in isopropanol) 1.2 ml 50.0 µg/ml
N-MeFBSA-M N-methyl perfluoro-1-butanesu lfonam ide 1.2 ml 50.0 µg/ml
N-MeFOSA-M N-methyl perfluoro-1-octanesulfonamide 1.2 ml 50.0 µg/ml
N,N-Me2FOSA-M N, N-d i methylperfl uoro-1-octanesulfonam ide 1.2 ml 50.0 µg/ml
N-EtFOSA-M N-ethylperfl uoro-1-octanesu lfonam ide 1.2 ml 50.0 µg/ml
MASS-LABELLED PERFLUOROALKANESULFONAMIDES
Perfluoro-1-(13C8)octanesulfonamide
MSFOSA-1 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in isopropanol;
>99% linear; >99% C8
13
\/ \/ \/ \/
/c'-.... /c'-.... /c'-.... /c'-....
/
,,.,.....so.,N
N-methyl-d 3-perfluoro-1-octanesulfonamide
d-N-MeFOSA-M
F C C C C \
/\ /\ /\ /\ CD3 >99% linear; 98% 2 H3
F FF FF FF F
d-N-EtFOSA-M
\/ \/ \/ \/
/c'-.... /c'-.... /c'-.... /c'-.... N
/
,,.,.....so
2
N-ethyl-d 5-perfluoro-1-octanesulfonamide
F C C C C \
I \ I \ I\ I \ C2D5 >99% linear; 98% 2 H5
F FF FF FF F
NATIVE PERFLUOROALKANESULFONAMIDOETHANOLS
(N-MeFASE and N-EtFASE)
N-MeFBSE-M 2-(N-methylperfl uoro-1-butanesu lfonamido)ethanol 1.2 ml 50.0 µg/ml
N-MeFOSE-M 2-(N-methylperfl uoro-1-octanesulfonam ido)etha nol 1.2 ml 50.0 µg/ml
N-EtFOSE-M 2-(N-ethyl perfl uoro-1-octanesu lfonamido)ethanol 1.2 ml 50.0 µg/ml
162
MASS-LABELLEDPERFLUOROALKANESULFONAMIDOETHANOLS
2-(N-methyl-d 3-perfluoro-1-octane-
sulfonamido)ethan-d 4 -ol
d7-N-MeFOSE·M
>99% linear; 98% 2 H7
2-(N-ethyl-d 5-perfluoro-1-octane-
sulfonamido)ethan-d 4 -ol
d9•N•EtFOSE·M
>99% linear; 98% 2 H9
NATIVE PERFLUOROOCTANESULFONAMIDOACETIC
ACIDS (FOSAA)

FOSAA Perfluoro-1-octanesulfonamidoacetic acid 1.2 ml 50.0 µg/ml
N•MeFOSAA N-methyl perfl uoro-1-octanesu lfonam idoacetic acid 1.2 ml 50.0 µg/ml
N•EtFOSAA N-ethylperfluoro-1-octanesulfonamidoacetic acid 1.2 ml 50.0 µg/ml
br-NMeFOSAA N-methylperfluorooctanesulfonamidoacetic acid isomeric mix 1.2 ml 50.0 µg/ml
br•NEtFOSAA N-ethylperfluorooctanesulfonamidoacetic acid isomeric mix 1.2 ml 50.0 µg/ml
MASS-LABELLEDPERFLUOROOCTANESULFONAMIDOACETIC
ACIDS

N-methyl-d 3-perfl uoro-1-octa ne-
\/ ,.......,.c........,_
\/ ,.......,.c........,_
,.......,.c........,_
\/ ,.......,.c........,_
\/ ,.......,.s0 /~
N,
2
sulfonamidoacetic acid
d3•N•MeFOSAA
F C C C C '-. 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;
I\ I\ I\ I\ CH2CO,H
F FF FF FF F >99% linear; 98% 2 H3
N-ethyl-d 5-perfluoro-1-octane-
sulfonamidoacetic acid
d5-N-EtFOSAA
>99% linear; 98% 2 H5
NATIVE FLUOROTELOMERALCOHOLS(X:2FTOH)

FBET 2-Perfluorobutyl ethanol (4:2) 1.2 ml 50.0 µg/ml
5:2sFTOH 1-Perfluoropentyl ethanol (5:2 secondary) 1.2 ml 50.0 µg/ml
FHET 2-Perfluorohexyl ethanol (6:2) 1.2 ml 50.0 µg/ml
7:2sFTOH 1-Perfluoroheptyl ethanol (7:2 secondary) 1.2 ml 50.0 µg/ml
FOET 2-Perfluorooctyl ethanol (8:2) 1.2 ml 50.0 µg/ml
FDET 2-Perfluorodecyl ethanol (10:2) 1.2 ml 50.0 µg/ml
163
MASS-LABELLEDFLUOROTELOMERALCOHOLS
\/ ,.......-c-......,_
\/ ,.......-c-......,_
,.......-c-......,_
\/ ,.......-oH 2-Perfluorobutyl (1, 1,2,2-2 H4)ethanol (>97%)
MFBET 1.2 ml; 48.5 µg/ml (±2.4 µg/ml); in methanol;

F C C C
F
/\ F F
/\ F D
/\ D 98% 1,1,2,2-2 H4
f Ff Ff Ff\H 2-Perfluorohexyl (1, 1-2 H2, 1,2-13C2)ethanol

\/ \/ \/ ,'}/ OH
MFHET /c-......,_,.......-c-......,_,.......-c-......,_,.......-c,,,!3/ 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;
F ;\ ;\ ;\ ;\
F FF FF FD D 98% 1,1-2 H2, >99% 1,2-"C,
f Ff Ff Ff\H 2-Perfluorohexyl (1,2-13C)ethanol

\/ \/ \/ ,'}/ OH
M2FHET /c........,_,.......-c........,_,.......-c........,_,.......-c
...,p/ 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;
F ;\ ;\ ;\ ;\
F FF FF FH H >99% 1,2-"C,
\/ ,.......-c-......,_
\/ ,.......-c-......,_
,.......-c-......,_
\/ ,.......-c-......,_
\/ / \;H ~ ,.......-oH
2-Perfluorooctyl (1,1-2 H2, 1,2-13C)ethanol
MFOET F C C C C
3
C
F
/\ FF
/\ FF
/\ FF
/\ FD
/\ D 98% 1,1-2 H2, >99% 1,2-"C,
\/ \/ \/ \/ \;H ,.......-oH
,.......-c-......,_
,.......-c-......,_
,.......-c-......,_
,.......-c-......,_
/ ~
2-Perfluorooctyl (1,2-13C2)ethanol
M2FOET F C C C C
3
C
F
/\ FF
/\ FF
/\ FF
/\ F H
/\ H >99% 1,2-"C,
f\F f\F f\F f\F f\F H\ H 2-Perfluorodecyl (1, 1-2 H2, 1,2-13C)ethanol
I I I I I ~/
MFDET ,.......-c-......,_
,.......-c-......,_
,.......-c-......,_
,.......-c-......,_
,.......-c-......,_
,.......-c~3 ,.......-oH 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;
F ;\ ;\ ;\ ;\ ;\ ;\
F FF FF FF FF FD D 98% 1,1-2 H2, >99% 1,2-"C,
NATIVE FLUOROTELOMERCARBOXYLICACIDS (FTCA)
Catalogue Number Product (isopropanol solution} Qty/Cone

FHEA 2-Perfluorohexyl ethanoic acid (6:2) 1.2 ml 50.0 µg/ml
FOEA 2-Perfluorooctyl ethanoic acid (8:2) 1.2 ml 50.0 µg/ml
FDEA 2-Perfluorodecyl ethanoic acid (10:2) 1.2 ml 50.0 µg/ml
FPrPA 3-Perfluoropropyl propanoic acid (3:3) 1.2 ml 50.0 µg/ml
FPePA 3-Perfluoropentyl propanoic acid (5:3) 1.2 ml 50.0 µg/ml
FHpPA 3-Perfluoroheptyl propanoic acid (7:3) 1.2 ml 50.0 µg/ml
NATIVE FLUOROTELOMERCARBOXYLICACIDS: SOLUTION/MIXTURE
Catalogue Number Product (isopropanol solution} Qty/Cone

FTA-MXA Native FTASolution/Mixture 1.2 ml
2-Perfluorohexyl ethanoic acid (6:2) FHEA 2.00 µg/ml

2-Perfluorooctyl ethanoic acid (8:2) FOEA 2.00 µg/ml
2-Perfluorodecyl ethanoic acid (10:2) FDEA 2.00 µg/ml
164
MASS-LABELLEDFLUOROTELOMERCARBOXYLICACIDS
F.\ F F.\ F F.\ F 11

0 2-Perfluorohexyl (1,2-13C)ethanoic acid
F / / / 13
MFHEA -........_
.....---c-....._
.....---c-....._
.....---c~3.....---c....,____ 1.2 ml; 50.0 µg/ml (±2.S µg/ml);
;\ ;\ ;\ ;\ OH
F FF FF FH H in isopropanol; >99% 13(
2
F.\ F F.\ F F.\ F F.\ F 11

0 2-Perfluorooctyl (1,2-13C2)ethanoic acid
F / / / / u
MFOEA -........_
,....,c......_
.....---c-.......
.....---c-.......
.....---c~3.....---c....,____ 1.2 ml; 50.0 µg/mL (±2.S µg/mL);
;\ ;\ ;\ ;\ ;\ OH
F FF FF FF F H H in isopropanol; >99% 13C2
0 2-Perfluorodecyl (1,2-13C)ethanoic acid

F
F.\ F F.\ F F.\ F F.\ F F.\ F
/ / / / / 13
II
MFDEA -........_
,....,c...___
,....,c......_
.....---c......_
.....---c......_
.....---c~3.....---c....,____ 1.2 ml; 50.0 µg/ml (±2.S µg/ml);
;\ ;\ ;\ ;\ ;\ ;\ OH
F FF FF FF FF F H H in isopropanol; >99% 13C2
MASS-LABELLEDFLUOROTELOMERCARBOXYLICACIDS:
SOLUTION/MIXTURE
Catalogue Number Product (isopropanol solution) Qty/Cone

MFTA·MXA Mass-Labelled FTA Solution/Mixture 1.2 ml
2-Perfluorohexyl (1,2-13C)ethanoic acid (6:2) MFHEA 2.00 µg/ml

2-Perfluorooctyl (1,2- C2)ethanoic acid (8:2)
13 MFOEA 2.00 µg/ml
2-Perfluorodecyl (1,2-13C)ethanoic acid (10:2) MFDEA 2.00 µg/ml
10
MFHEA
MFOEA
LC/MSData for MFTA-MXA on an Acquity UPLCBEH Shield RP,. column.
165
NATIVE FLUOROTELOMERUNSATURATEDCARBOXYLICACIDS (FTUCA)
Catalogue Number Product (isopropanol solution) Qty/Cone

FHUEA 2H-Perfluoro-2-octenoic acid (6:2) 1.2 ml 50.0 µg/ml
FOUEA 2H-Perfluoro-2-decenoic acid (8:2) 1.2 ml 50.0 µg/ml
FDUEA 2H-Perfluoro-2-dodecenoic acid (10:2) 1.2 ml 50.0 µg/ml
MASS-LABELLEDFLUOROTELOMERUNSATURATED
CARBOXYLICACIDS
F. F F. F F. F H 2H-Perfluoro-(1,2- 13C)-2-octenoic acid

\/ .,,.,..c.......,_
\/ .,,.,..c-......,_
.,,.,..c-......,_
\/ ~c~,,,I /
OH
MFHUEA 1.2 ml; 50.0 µg/ml (±2.5 µg/ml);
F C C C C
F
I\ F F
I\ F
I
F
II
O
in isopropanol; >99% C2
13
F.\FF.\FF.\FF.\F HI 2H-Perfluoro-(1,2- 13C2)-2-decenoic acid

I I I I 13 OH
MFOUEA .,,.,..c.......,_
.,,.,..c-......,_
.,,.,..c-......,_
.,,.,..c-......,_
~c~ 3 / 1.2 ml; 50.0 µg/ml (±2.5 µg/ml);
F C C C C C
F
I\ FF
I\ FF
I\ FF
I II
o in isopropanol; >99% C2
13
F.\FF.\FF.\FF.\FF.\F HI 2H-Perfluoro-(1,2- 13C2)-2-dodecenoic acid

I I I I I a oo
MFDUEA .,,.,..c-......,_
.,,.,..c-......,_
.,,.,..c-......,_
.,,.,..c-......,_
.,,.,..c-......,_
~c~ 3 / 1.2 ml; 50.0 µg/ml (±2.5 µg/ml);
FCC CCC C
F
I \ FF I\ FF
I\ FF
I\ FF
I II
O in isopropanol; >99% C2
13
NATIVE CHLOROPERFLUOROALKYL
ETHERSULFONATES(CI-PFESA)

9CI-PF30NS Potassium 9-chlorohexadecafluoro-3-oxanonane-1-sulfonate 1.2 ml 50.0 µg/ml
11Cl•PF30Ud5 Potassium 11-chloroeicosafluoro-3-oxaundecane-1-sulfonate 1.2 ml 50.0 µg/ml
NATIVE PER-AND POLYFLUOROALKYLETHERCARBOXYLICACIDS

(PFECA)

NaDONA * Sodium dodecafluoro-3H-4,8-dioxanonanoate 1.2 ml 50.0 µg/ml
PF40PeA Perfluoro-4-oxapentanoic acid (PFMPA) 1.2 ml 50.0 µg/ml
PFSOHxA Perfluoro-5-oxahexanoic acid (PFMBA) 1.2 ml 50.0 µg/ml
3,6-0PFHpA Perfluoro-3,6-dioxaheptanoic acid (NFDHA) 1.2 ml 50.0 µg/ml
*NOTE: Listedconcentration
is reportedasthe salt.
166
NATIVE PERFLUOROALKYLETHERSULFONATES(PFESA)
PFEESA Potassium perfl uoro(2-ethoxyetha ne)su lfonate 1.2 ml 50.0 µg/ml
NOTE:Listedconcentrationis reportedas the salt.
NATIVE HEXAFLUOROPROPYLENE
OXIDE DIMER ACID (HFPO-DA)
HFPO·DA 2,3,3,3-Tetrafl uoro-2-(1, 1,2,2,3,3,3-heptafluoropropoxy)- 1.2 ml 50.0 µg/ml

propanoic acid (GenX)
MASS-LABELLEDHEXAFLUOROPROPYLENE
OXIDE DIMER ACID

2,3,3,3-Tetrafluoro-2-(1, 1,2,2,3,3,3-
heptafluoropropoxy)(1 3C3)propanoic acid
M3HFPO-DA
1.2 ml; 50.0 µg/ml (±2.5 µg/ml);
in methanol; > 99% 13C3
NATIVE FLUOROTELOMERSULFONATES(X:2FTS)

4:2FTS Sodium 1 H, 1H,2H,2H-perfluorohexanesulfonate (4:2) 1.2 ml 50.0 µg/ml
6:2FTS Sodium 1 H, 1H,2H,2H-perfluorooctanesulfonate (6:2) 1.2 ml 50.0 µg/ml

8:2FTS Sodium 1 H, 1H,2H,2H-perfluorodecanesulfonate (8:2) 1.2 ml 50.0 µg/ml
10:2FTS Sodium 1 H, 1H,2H,2H-perfluorododecanesulfonate (10:2) 1.2 ml 50.0 µg/ml
MASS-LABELLEDFLUOROTELOMERSULFONATES

Sodium 1H,1H,2H,2H-perfluoro(1,2-
13C)hexanesulfonate (4:2)
M2-4:2FTS
>99% 13(2
13C)octanesulfonate (6:2)
M2-6:2FTS
>99% 13(2
13C)decanesulfonate (8:2)
M2-8:2FTS
>99% 13(2
167
NATIVE PERFLUOROALKYLPHOSPHONIC
ACIDS (PFAPA)
Perfluorohexylphosphonic acid
PFHxPA
1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol
Perfluorooctylphosphonic acid
PFOPA
Perfluorodecylphosphonic acid
PFDPA
6-Chloroperfluorohexylphosphonic acid
CI-PFHxPA
8-Chloroperfluorooctylphosphonic acid
CI-PFOPA
NATIVE SODIUM PERFLUOROALKYLPHOSPHINATES(X:XPFPi)
Sodium bis(perfluorohexyl)phosph i nate

6:6PFPi
Sodium perfluorohexyl perfl uorooctyl phosph i nate

6:BPFPi
Sodium bis(perfluorooctyl)phosphinate
8:SPFPi
NATIVE POLYFLUOROALKYLPHOSPHATEMONO-ESTERS(PAP)

6:2PAP Sodium 1H, 1H,2H,2H-perfluorooctyl phosphate 1.2 ml 50.0 µg/ml
8:2PAP Sodium 1H, 1H,2H,2H-perfluorodecyl phosphate 1.2 ml 50.0 µg/ml
168
NATIVE POLYFLUOROALKYLPHOSPHATEDI-ESTERS(diPAP)

6:2diPAP Sodium bis(1 H, 1 H,2H,2H-perfluorooctyl) phosphate 1.2 ml 50.0 µg/ml
6:2/8:ZdiPAP Sodium (1 H, 1H,2H,2H-perfluorooctyl-1 H, 1H,2H,2H- 1.2 ml 50.0 µg/ml
perfl uorodecyl) phosphate
8:2diPAP Sodium bis(1 H, 1 H,2H,2H-perfluorodecyl) phosphate 1.2 ml 50.0 µg/ml
MASS-LABELLEDPOLYFLUOROALKYLPHOSPHATEMONO-ESTERS
Sodium 1H,1H,2H,2H-(1,2-13C)perfluorooctyl phosphate

M2-6:2PAP 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;
>99% 13(2
Sodium 1H,1H,2H,2H-(1,2-13C2)perfluorodecyl phosphate

M2-8:2PAP 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;
>99% 13(2
MASS-LABELLEDPOLYFLUOROALKYLPHOSPHATEDI-ESTERS

Sodium bis[1H,1H,2H,2H-(1,2-13C)perfluorooctyl]
0
phosphate
M4-6:2diPAP 13CH213CH2--....,)'-.
CF3(CF2)s _;:CH213CH2(CF2)sCF3
o I o 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;
ONa
>99% 13(4
Sodium bis[1H,1H,2H,2H-(1,2-13C2)perfluorodecyl]
0
phosphate
M4-8:2diPAP 13CH213CH2--.....,,J--.... _;:CH213CH2(CF2l,CF3
CF3(CF2),
o I o 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;
ONa
>99% 13(4
NATIVE POLYFLUOROALKYLPHOSPHATEESTERS(SAmPAP)

SAmPAP Sodium 2-(N-ethylperfluorooctane-1-sulfonamido)ethyl phosphate 1.2 ml 50.0 µg/ml
diSAmPAP Sodium bis[2-(N-ethylperfluorooctane-1-sulfonamido)ethyl] phosphate 1.2 ml 50.0 µg/ml
169
NATIVE FLUOROTELOMERACRYLATES(X:2FTAcr)

8:2FTAcr 1H, 1 H,2H,2H-Perfluorodecyl acrylate 1.2 ml 50.0 µg/ml
10:2FTAcr 1H, 1 H,2H,2H-Perfluorododecyl acrylate (>95%) 1.2 ml 47.9 µg/ml
NATIVE FLUOROTELOMERACETATES(X:2FTOAc)

8:2FTOAc 1H, 1 H,2H,2H-Perfluorodecyl acetate (>97%) 1.2 ml 48.5 µg/ml
10:2FTOAc 1H, 1 H,2H,2H-Perfluorododecyl acetate 1.2 ml 50.0 µg/ml
8:2FTAer
10:2FTAer
8:2FTOAe
10:2FTOAe
170
NATIVE CATIONIC/ZWITTERIONIC PFAS

N-AP-FHxSA N-(3-dimethylaminopropan-1-yl)perfluoro-1-hexanesulfonamide 1.2 ml 50.0 µg/ml
N-TAmP-FHxSA N-[3-(perfluoro-1-hexanesulfonamido)propan-1-yl]- 1.2 ml 50.0 µg/ml

N,N,N-trimethylammonium
N-CMAmP-6:2FOSA N-(carboxymethyl)-N,N-dimethyl-N-[3-(1 H, 1H,2H,2H- 1.2 ml 50.0 µg/ml
perfluoro-1-octanesu lfonamido)propan-1-yl]ammoni um (6:2FTAB)
S:3FTB 2-((4,4, 5,5,6,6, 7, 7,8,8,8-Undecafl uorooctyl)di methylammon io] 1.2 ml 50.0 µg/ml
acetate
S:1:2FTB 2-((3,4,4,5,5,6,6, 7, 7,8,8,8-Dodecafluorooctyl)dimethylammonio] 1.2 ml 50.0 µg/ml
acetate
NOTE:Thechargeof thesecompounds
will dependon pH.
5:3FTB
5:1:2FTB
171
ORGAN OCH LORINE
PESTICIDES (OCPS)
In 2018, Wellington introduced a series of Organochlorine Pesticide (OCP) standards, both native
and mass-labelled.
These OCPswere mostly used as insecticides in agriculture or forestry to control such things as
termites, fire ants, grasshoppers, grubs, and mosquitos. Some also found use as rodenticides and
pesticides. Most of their production and use has been banned due to their persistence in the
environment and the resulting detrimental effects. Almost all are listed in the Stockholm
Convention.
Some OCPsare still in use as there are no effective alternatives available. For example, DDT is
used for mosquito control to prevent malaria, and Lindane (y-HCH) is used in lice/scabies
The OCP standards and solution/mixtures that are currently available from Wellington are given in
the following section.
NATIVE ORGANOCHLORINEPESTICIDES(OCPs)

PeCB Pentachlorobenzene 1.2 ml 100 µg/ml
HxCB Hexachlorobenzene 1.2 ml 100 µg/ml
aHCH a.-1,2,3,4,5,6-Hexachlorocyclohexane 1.2 ml 100 µg/ml
bHCH f3-1,2,3,4,5,6-Hexachlorocyclohexane 1.2 ml 100 µg/ml
gHCH y-1,2,3,4,5,6-Hexachlorocyclohexane 1.2 ml 100 µg/ml
dHCH o-1,2,3,4,5,6-Hexachlorocyclohexane 1.2 ml 100 µg/ml
24P-DMDT o,p' -Methoxychlor 1.2 ml 100 µg/ml
44P-DMDT p,p' -Methoxychlor 1.2 ml 100 µg/ml
24P-DDD 1,1-Dichloro-2-(2-chlorophenyl)-2-(4-ch lorophenyl)ethane 1.2 ml 100 µg/ml
44P-DDD 1,1-Dichloro-2,2-bis(4-chlorophenyl)ethane 1.2 ml 100 µg/ml
24P-DDE 1,1-Dichloro-2-(2-chlorophenyl)-2-(4-ch lorophenyl)ethene 1.2 ml 100 µg/ml
44P-DDE 1,1-Dichloro-2,2-bis(4-chlorophenyl)ethene 1.2 ml 100 µg/ml
24P-DDT 1,1,1-Trichloro-2-(2-chlorophenyl)-2-(4-chlorophenyl)ethane 1.2 ml 100 µg/ml
44P-DDT 1,1,1-Trichloro-2,2-bis(4-chlorophenyl)ethane 1.2 ml 100 µg/ml
HxChlor Chlordene 1.2 ml 100 µg/ml
1H-HxChlor 1-Hydroxychlordene 1.2 ml 100 µg/ml
HpChlor Heptachlor 1.2 ml 100 µg/ml
HpChlor-nEp Heptachlor-endo-epoxide (isomer A) 1.2 ml 100 µg/ml
HpChlor-xEp Heptachlor-exo-epoxide (isomer B) 1.2 ml 100 µg/ml
cChlorD cis-Chlordane (a.) 1.2 ml 100 µg/ml
tChlorD trans-Chlordane (y) 1.2 ml 100 µg/ml
OxyChlorD Oxychlordane 1.2 ml 100 µg/ml
cNChlor cis-Nonachlor 1.2 ml 100 µg/ml
tNChlor trans-Nonachlor 1.2 ml 100 µg/ml
ALD Aldrin 1.2 ml 100 µg/ml
ISOD lsodrin 1.2 ml 100 µg/ml
DELD Dieldrin 1.2 ml 100 µg/ml
END Endrin 1.2 ml 100 µg/ml
END-Aid Endrin Aldehyde 1.2 ml 100 µg/ml
END-Ket Endrin Ketone 1.2 ml 100 µg/ml
KEP Kepone 1.2 ml 100 µg/ml
MRX Mirex 1.2 ml 100 µg/ml
aENDOS Endosulfan I (a.) 1.2 ml 100 µg/ml
bENDOS Endosulfan II (13) 1.2 ml 100 µg/ml
ENDOS-5 Endosulfan Sulfate 1.2 ml 100 µg/ml
174
NATIVE ORGANOCHLORINE PESTICIDESOLUTION/MIXTURE

OCP-MXA Native OCPSolution/Mixture 1.2 ml
Pentachlorobenzene PeCB 2.00 µg/ml

Hexachlorobenzene HxCB 2.00 µg/ml
o,p' -Methoxychlor 24P-DMDT 2.00 µg/ml
p,p' -Methoxychlor 44P-DMDT 2.00 µg/ml
Chlordene HxChlor 2.00 µg/ml
1-Hydroxychlordene 1H-HxChlor 2.00 µg/ml
Heptachlor HpChlor 2.00 µg/ml
cis-Chlordane (a) cChlorD 2.00 µg/ml
trans-Chlordane (y) tChlorD 2.00 µg/ml
Aldrin AlD 2.00 µg/ml
lsodrin ISOD 2.00 µg/ml
Dieldrin DElD 2.00 µg/ml
Endrin END 2.00 µg/ml
Endrin Aldehyde END-Aid 2.00 µg/ml
Endrin Ketone END-Ket 2.00 µg/ml
Kepone KEP 2.00 µg/ml
Mirex MRX 2.00 µg/ml
NATIVE DDT & RELATEDCOMPOUNDS SOLUTION/MIXTURE

DET-MXA Native DDT & Related Compound Solution/Mixture 1.2 ml
1,1-Dichloro-2-(2-chlorophenyl)-2-(4-ch lorophenyl)ethane 24P-DDD 2.00 µg/ml

1,1-Dichloro-2,2-bis(4-chlorophenyl)ethane 44P-DDD 2.00 µg/ml
1,1-Dichloro-2-(2-chlorophenyl)-2-(4-chlorophenyl)ethene 24P-DDE 2.00 µg/ml
1,1-Dichloro-2,2-bis(4-chlorophenyl)ethene 44P-DDE 2.00 µg/ml
1,1,1-Trichloro-2-(2-chlorophenyl)-2-(4-chlorophenyl)ethane 24P-DDT 2.00 µg/ml
1,1,1-Trichloro-2,2-bis(4-chlorophenyl)ethane 44P-DDT 2.00 µg/ml
NATIVE HCH SOLUTION/MIXTURE

HCH-MXA Native HCH Solution/Mixture 1.2 ml
a-1,2,3,4,5,6-Hexachlorocyclohexane aHCH 2.00 µg/ml

!3-1,2,3,4,5,6-Hexachlorocyclohexane bHCH 2.00 µg/ml
y-1,2,3,4,5,6-Hexachlorocyclohexane gHCH 2.00 µg/ml
o-1,2,3,4,5,6-Hexachlorocyclohexane dHCH 2.00 µg/ml
175
MASS-LABELLEDORGANOCHLORINE PESTICIDES
MPeCB Pentach loro("C 6) benzene 1.2 ml 100 µg/ml

MHxCB Hexachloro("C 6) benzene 1.2 ml 100 µg/ml
MaHCH u-1,2,3,4, 5,6-Hexachloro("C 6)cyclohexane 1.2 ml 100 µg/ml
MbHCH ~-1,2,3,4,5,6-Hexachloro("C 6)cyclohexane 1.2 ml 100 µg/ml
MgHCH y-1,2,3,4,5,6-Hexachloro("C 6)cyclohexane 1.2 ml 100 µg/ml
MdHCH o-1,2,3,4,5,6-Hexachloro("C.)cyclohexane 1.2 ml 100 µg/ml
M44P·DMDT p,p' -("C, 2 )Methoxych lor 1.2 ml 100 µg/ml
M24P·DDD 1,1-Dichloro-2-(2-ch loro("C 6) p he nyl]-2-( 4-chloro("C 6) phenyl]etha ne 1.2 ml 100 µg/ml
M44P·DDD 1,1-Dichloro-2,2-bis[4-chloro("C 6) phenyl]ethane 1.2 ml 100 µg/ml

M24P·DDE 1,1-Dichloro-2-(2-ch loro( 13C6 ) p he nyl]-2-[ 4-chloro( 13C6) phenyl]ethene 1.2 ml 100 µg/ml
M44P·DDE 1,1-Dichloro-2,2-bis[4-chloro("C 6) phenyl]ethene 1.2 ml 100 µg/ml
M24P·DDT 1,1,1-Trichloro-2-[2-chloro("C 6) phenyl]-2-(4-chloro("C.)phenyl]ethane 1.2 ml 100 µg/ml

M44P·DDT 1,1,1-Trichloro-2,2-bis[4-chloro( 13C6 )phenyl]ethane 1.2 ml 100 µg/ml
MHxChlor ("C, 0)Chlordene 1.2 ml 100 µg/ml
MHpChlor ("C,.)Heptachlor 1.2 ml 100 µg/ml

McChlorD cis-("C,.)Chlordane (a) 1.2 ml 100 µg/ml
MtChlorD trans-("C, 0)Chlordane (y) 1.2 ml 100 µg/ml
McNChlor cis-("C,.)Nonachlor 1.2 ml 100 µg/ml

MALD ("C,,)Aldrin 1.2 ml 100 µg/ml
MISOD ("C,,)lsodrin 1.2 ml 100 µg/ml
MDELD ("C,,)Dieldrin 1.2 ml 100 µg/ml

MEND ("C,,)Endrin 1.2 ml 100 µg/ml
MKEP ("C, 0)Kepone 1.2 ml 100 µg/ml
MMRX ("C,.)Mirex 1.2 ml 100 µg/ml
176
MASS-LABELLED ORGANOCHLORINE PESTICIDE SOLUTION/MIXTURE

MOCP·MXA Mass-Labelled OCP Solution/Mixture 1.2 ml
Pentachloro(''C,)benzene MPeCB 2.00 µg/ml

Hexachloro( 'C 6 )benzene
1 MHxCB 2.00 µg/ml
p,p' -("C,,)Methoxych lor M44P-DMDT 2.00 µg/ml
("C,.)Chlordene MHxChlor 2.00 µg/ml
("C,.)Heptachlor MHpChlor 2.00 µg/ml
cis-("C,.)Chlordane (a) McChlorD 2.00 µg/ml
trans-("C, 0 )Chlordane (y) MtChlorD 2.00 µg/ml
("C,,)Aldrin MALD 2.00 µg/ml
("C,,)lsodrin MISOD 2.00 µg/ml
("C,,)Dieldrin MDELD 2.00 µg/ml
("C,,)Endrin MEND 2.00 µg/ml
( 13 C10)Kepone MKEP 2.00 µg/ml
("C,.)Mirex MMRX 2.00 µg/ml
MASS-LABELLED DDT & RELATED COMPOUNDS SOLUTION/MIXTURE

MDET-MXA Mass-Labelled DDT & Related Compound Solution/Mixture 1.2 ml
1,1-Dichloro-2-[2-chloro("C 6) phenyl]-2-[4-chloro("C 6 )phenyl]ethane M24P-DDD 2.00 µg/ml

1,1-Dichloro-2,2-bis[4-chloro("C 6)ph enyl)ethane M44P-DDD 2.00 µg/ml
1,1-Dichloro-2,2-bis[4-chloro("C 6)phenyl]ethene M44P-DDE 2.00 µg/ml
1,1,1-Trichloro-2-[2-chloro("C 6) phenyl]-2-[4-chloro("C 6)phenyl]ethane M24P-DDT 2.00 µg/ml
1,1,1-Trichloro-2,2-bis[4-chloro("C 6)phenyl)ethane M44P-DDT 2.00 µg/ml
MASS-LABELLED HCH SOLUTION/MIXTURE

MHCH-MXA Mass-Labelled HCH Solution/Mixture 1.2 ml
a-1,2,3,4, 5,6-Hexachloro("C 6)cyclohexane MaHCH 2.00 µg/ml

j3-1,2,3,4,5,6-Hexachloro("C 6)cyclohexane MbHCH 2.00 µg/ml
y-1,2,3,4,5,6-Hexachloro("C 6 )cyclohexane MgHCH 2.00 µg/ml
o-1,2,3,4,5,6-Hexachloro("C 6)cyclohexane MdHCH 2.00 µg/ml
177
ENVIRONMENTAL REFERENCE
MATERIALS (ERMs)
Wellington currently offers five Environmental Reference Materials (ERMs). These are primarily
used to test an analytical laboratory's ability to generate accurate and reproducible data using
real, as opposed to fortified, samples.
Currently, we offer one lake sediment ERM, three fish tissue ERMs, and one fish tissue extract
ERM. A summary for each, including the target analytes and their concentrations, are given in
this section.
With each ERM, a more detailed certificate of analysis (CofA) is provided which includes reference
values (robust means), uncertainties, and other information essential for their use.
Additional ERMs are in production or being planned. Once available, these will be announced on
~"«Al'.-..•our website. Moreover, if you have any suggestions for future ERMs, please contact us.
WMF-02: REFERENCEFISH TISSUE for ORGANIC CONTAMINANT ANALYSIS
Catalogue Number Product Qty/Cone

WMF-02 Reference "Freeze-Dried" Fish Tissue (Naturally Fortified Salmon) 1 X 10 g
Certified
Polychlorinated Dibenzo-p-dioxins (PCDDs) Reference value Reference Value
(pg/g) (pg/g)
2,3,7,8-Tetrachlorodibenzo-p-d ioxi n 0.865±0.047 0.826±0.067

1,2,3,7,8-Pentachlorodibenzo-p-dioxin 2.27±0.08 2.28±0.06
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 0.910±0.039 0.916±0.041
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 2.27±0.10 2.27±0.08
Octachlorodibenzo-p-dioxin 2.97±0.11 3.34±0.23
Polychlorinated Dibenzofurans (PCDFs)

2,3,7,8-Tetrachlorodibenzofuran 13.0±0.4 13.2±0.5
1,2,3,7,8-Pentachlorodibenzofuran 2.94±0.16 2.97±0.12
1,2,3,4,7,8-Hexachlorodibenzofuran 1.55±0.07 1.59±0.06
2,3,4,6,7,8-Hexach lo rod i benzofuran 1.23±0.06 1.23±0.06
1,2,3,4,6,7,8-Heptachlorodibenzofuran 1.10±0.07 1.12±0.07
Octachlorodibenzofuran 1.37±0.09 1.50±0.13
Polychlorinated Biphenyls (PCBs-lUPAC)

2,2',6-Trichlorobiphenyl (19) - 123±14
2,4,4'-Trichlorobiphenyl (28) - 3730±380
2',3,4-Trichlorobiphenyl (33) - 1550±190
2,2',3,5'-Tetrachlorobiphenyl (44) - 1420±250
2,2',5,5'-Tetrachlorobiphenyl (52) 2340±190 2470±200
2,3',4',5-Tetrachlorobiphenyl (70) - 4370±430
3,4,4',5-Tetrachlorobiphenyl (81) 9.44±0.57 9.47±0.64
2,2',4,5,5'-Pentachlorobiphenyl (101) - 6650±590
2,3,3' ,4,4'-Pentachlorobiphenyl (105) 8560±250 8520±210
2,3,4,4',5-Pentachlorobiphenyl (114) 548±16 551±16
2,3',4,4',5-Pentachlorobiphenyl (118) 22500±900 22600±800
2' ,3,4,4',5-Pentachlorobiphenyl (123) 431±25 432±37
2,2' ,3,3' ,4,4'-Hexachlorobiphenyl (128) - 7830±710
2,2',3,4,4',5'-Hexachlorobiphenyl (138) - 47500±2900
2,2',4,4',5,5'-Hexachlorobiphenyl (153) - 69500±3300
2,3,3',4,4',5-Hexachlorobiphenyl (156) 3460±140 3450±120
2,3,3',4,4',5'-Hexachlorobiphenyl (157) 953±65 953±50
2,3',4,4',5,5'-Hexachlorobiphenyl (167) 1810±70 1830±60
3,3' ,4,4' ,5,5'-Hexachlorobiphenyl (169) 47.2±2.8 46.6±2.5
2,2',3,3',4,4',5-Heptachlorobiphenyl (170) - 7580±610
2,2',3,4,4',5,5'-Heptachlorobiphenyl (180) - 23900±1200
2,3,3',4,4',5,5'-Heptachlorobiphenyl (189) 497±12 502±14
2,2',3,3',4,4',5,5'-Octachlorobiphenyl (194) - 3220±280
2,2',3,3',4,4',5,6-Octachlorobiphenyl (195) - 1090±170
2,2',3,3',4,5,5',6'-Octachlorobiphenyl (199) - 2690±320
2,3,3',4,4',5,5',6-Octachlorobiphenyl (205) - 209±19
2,2',3,3',4,4',5,5',6-Nonachlorobiphenyl (206) - 1220±120
2,2',3,3',4,5,5',6,6'-Nonachlorobiphenyl (208) - 401±23
Decachlorobiphenyl (209) - 463±27
180
Reference value
Polybrominated Diphenyl Ethers (PBDEs-lUPAC) (pg/g)
2,4,4'-Tribromodiphenyl ether (28) 330±33
2,2',4,4'-Tetrabromodiphenyl ether (47) 13200±800
2,2',4,4',5-Pentabromodiphenyl ether {99) 6420±340
2,2',4,4',6-Pentabromodiphenyl ether (100) 2980±130
2,2',4,4',5,5'-Hexabromodiphenyl ether {153) 834±54
2,2',4,4',5,6'-Hexabromodiphenyl ether (154) 1700±110
2,2',3,4,4',5',6-Heptabromodiphenyl ether (183) 46.8±5.3
2,2',3,3',4,4',5,5',6-Nonabromodiphenyl ether (206) 301±24
2,2',3,3',4,4',5,6,6'-Nonabromodiphenyl ether (207) 255±34
Decabromodiphenyl ether (209) 2020±140
Reference value
Organochlorine Pesticides (OCPs) (ng/g)
a-1,2,3,4,5,6-Hexachlorocyclohexane {aHCH) 5.96±0.54
f3-1,2,3,4,5,6-Hexachlorocyclohexane {bHCH) 5.11±0.35
y-1,2,3,4,5,6-Hexachlorocyclohexane {gHCH) 3.94±0.59
cis-Chlordane {a) {cChlorD) 15.5±1.3
trans-Chlordane {y) {tChlorD) 5.58±0.54
1,1-Dichloro-2-(2-ch lorophenyl)-2-(4-chlorophenyl)ethene (24P-DDE) 1.13±0.06
1,1,1-Trichloro-2-{2-chlorophenyl)-2-(4-chlorophenyl)ethane {24P-DDT) 7.00±0.44
1,1-Dichloro-2,2-bis(4-chlorophenyl)ethane (44P-DDD) 6.56±0.41
1,1-Dichloro-2,2-bis(4-chlorophenyl)ethene (44P-DDE) 133±6
1,1,1-Trichloro-2,2-bis(4-chlorophenyl)ethane (44P-DDT) 13.0±0.9
Dieldrin (DELD) 19.2±3.2
Heptachlor-exo-epoxide {HpChlor-xEp) 6.48±0.47
Hexachlorobenzene (HxCB) 6.94±0.48
Mirex (MRX) 5.67±0.28
cis-Nonachlor (cNchlor) 27.9±1.1
trans-Nonachlor (tNchlor) 43.7±2.3
Oxychlordane (OxyChlorD) 13.4±0.9
181

WMF-03 Reference "Freeze-Dried" Fish Tissue (Low Level Salmon) 1 X 10 g
Certified
Polychlorinated Dibenzo-p-dioxins (PCDDs) Reference value Reference Value
and Polychlorinated Dibenzofurans (PCDFs) (pg/g) (pg/g)
Octachlorodibenzo-p-dioxin - 0.914±0.29

3,3',4,4'-Tetrachlorobiphenyl (77) 13.1±0.9 14.0±0.9
3,4,4',5-Tetrachlorobiphenyl (81) - 0.863±0.20
2,3,3' ,4,4'-Pentachlorobiphenyl (105) 296±17 303±15
2,3,4,4',5-Pentachlorobiphenyl (114) 21.9±1.4 23.2±1.2
2',3,4,4',5-Pentachlorobiphenyl (123) 16.2±2.4 16.4±2.4
3,3',4,4',5-Pentachlorobiphenyl (126) 3.80±0.27 3.91±0.28
2,3,3',4,4',5-Hexachlorobiphenyl (156) 90.9±4.8 92.2±3.8
2,3,3',4,4',5'-Hexachlorobiphenyl (157) 25.3±1.6 25.7±1.2
2,3',4,4',5,5'-Hexachlorobiphenyl (167) 42.1±2.1 43.4±1.9
3,3',4,4',5,5'-Hexachlorobiphenyl (169) - 1.11±0.12
2,3,3',4,4',5,5'-Heptachlorobiphenyl (189) 6.50±0.30 6.64±0.34
2,2',3,3',4,4',5,5'-Octachlorobiphenyl (194) - 30.1±3.5
182
Reference value
Polybrominated Diphenyl Ethers (PBDEs-lUPAC) (pg/g)
2,3',4,4'-Tetrabromodiphenyl ether (66) 35.9±3.4
2,2',3,4,4'-Pentabromodiphenyl ether (85) 26.0±2.6
2,2',4,4',5-Pentabromodiphenyl ether (99) 417±23
2,2',4,4',6-Pentabromodiphenyl ether {100) 153±16
2,2',4,4',5,5'-Hexabromodiphenyl ether (153) 32.7±3.5
2,2',4,4',5,6'-Hexabromodiphenyl ether {154) 39.5±4.1
Decabromodiphenyl ether (209) 299±58
Reference value
Organochlorine Pesticides (OCPs) (ng/g)
a-1,2,3,4,5,6-Hexachlorocyclohexane {aHCH) 4.79±0.39
f3-1,2,3,4,5,6-Hexachlorocyclohexane {bHCH) 3.91±0.32
y-1,2,3,4,5,6-Hexachlorocyclohexane {gHCH) 1.32±0.32
cis-Chlordane {a) {cChlorD) 2.62±0.09
trans-Chlordane {y) {tChlorD) 0.693±0.083
1,1-Dichloro-2,2-bis{4-chlorophenyl)ethane {44P-DDD) 2.12±0.22
1,1-Dichloro-2,2-bis{4-chlorophenyl)ethene {44P-DDE) 9.19±0.60
Hexachlorobenzene {HxCB) 7.24±0.44
trans-Nonachlor {tNChlor) 3.33±0.15
183
WMF-EX: REFERENCEFISH TISSUE for ORGANIC CONTAMINANT ANALYSIS

WMF·EX Reference Fish Tissue Extract (lsooctane/20% Salmon Oil) 1x3g
Certified
Reference value Reference Value
Polychlorinated Dibenzo-p-dioxins (PCDDs) (pg/g)
(pg/g)
2,3,7,8-Tetrachlorodibenzo-p-dioxin 1.91±0.16 1.84±0.16
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin - 0.613±0.11
1,2,3,6,7,8-Hexach lo rod i benzo-p-dioxi n 3.56±0.16 3.55±0.15
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin - 0.806±0.089
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin - 1.25±0.14

2,3,4,7,8-Pentach lorodibenzofuran 11.3±0.9 11.5±0.8
1,2,3,4,7,8-Hexach lo rod i benzofu ran 2.45±0.22 2.44±0.18
2,3,4,6,7,8-Hexach lo rod i benzofu ran 1.45±0.18 1.44±0.17

2',3,4-Trichlorobiphenyl (33) - 2190±160
3,4,4', 5-Tetrach lorobi phenyl (81) 21.1±2.4 21.7±2.8
2,3,3',4,4'-Pentachlorobiphenyl (105) 31500±1100 31200±1000
2,3,4,4',5-Pentachlorobiphenyl (114) 2020±80 2050±50
2',3,4,4',5-Pentachlorobiphenyl (123) 1490±120 1510±120
2,3,3',4,4',5-Hexachlorobiphenyl (156) 13200±800 13000±600
2,3,3',4,4',5'-Hexachlorobiphenyl (157) 3720±300 3650±200
2,3',4,4',5,5'-Hexachlorobiphenyl (167) 6830±310 6830±260
3,3' ,4,4' ,5,5'-Hexachlorobiphenyl (169) 192±12 191±11
2,3,3',4,4',5,5'-Heptachlorobiphenyl (189) 1880±100 1870±80
2,2',3,3',4,4',5,6-Octachlorobiphenyl (195) - 4430±400
2,2',3,3',4,5,5',6'-Octachlorobiphenyl (199) - 10900±500
2,3,3',4,4',5,5',6-Octachlorobiphenyl (205) - 795±52
2,2',3,3',4,4',5,5',6-Nonachlorobiphenyl (206) - 4880±330
2,2',3,3',4,5,5',6,6'-Nonachlorobiphenyl (208) - 1480±90
Decachlorobiphenyl (209) - 1830±70
184
WMF-EX: REFERENCEFISH TISSUE for ORGANIC CONTAMINANT ANALYSIS
Reference value
Polybrominated Diphenyl Ethers (PBDEs-lUPAC) (ng/g)
2,4,4'-Tribromodiphenyl ether (28) 0.898±0.054
2,2',4,4',5-Pentabromodiphenyl ether (99) 23.8±1.3
2,2',4,4',6-Pentabromodiphenyl ether (100) 10.6±0.6
Decabromodiphenyl ether (209) 2.74±0.17
Organochlorine Pesticides (OCPs)
a.-1,2,3,4,5,6-Hexachlorocyclohexane (aHCH) 9.68±0.87
cis-Chlordane (a) (cChlorD) 48.4±4.2
trans-Chlordane (y) (tChlorD) 8.72±0.79
1, 1-Dichloro-2-(2-chlorophenyl)-2-(4-chlorophenyl)ethene (24P-DDE) 1.51±0.07
1,1,1-Trichloro-2-(2-chlorophenyl)-2-(4-chlorophenyl)ethane (24P-DDT) 15.4±1.6
1,1-Dichloro-2,2-bis(4-chlorophenyl)ethane (44P-DDD) 5.35±0.76
1,1-Dichloro-2,2-bis(4-chlorophenyl)ethene (44P-DDE) 451±35
1,1,1-Trichloro-2,2-bis(4-chlorophenyl)ethane (44P-DDT) 40.0±1.8
Dieldrin (DELD) 54.3±5.4
Heptachlor-exo-epoxide (HpChlor-xEp) 13.1±0.5
Hexachlorobenzene (HxCB) 10.3±0.5
Mirex (MRX) 11.9±0.7
cis-Nonachlor (cNChlor) 116±6
trans-Nonachlor (tNChlor) 183±12
Oxychlordane (OxyChlorD) 47.7±2.4
185
WMS-01: REFERENCELAKE SEDIMENT for ORGANIC CONTAMINANT ANALYSIS

WMS-01 Reference Lake Sediment 1 X 10 g
Certified
Reference value Reference Value
Polychlorinated Dibenzo-p-dioxins (PCDDs)
(pg/g) (pg/g)
2,3,7,8-Tetrachlorodibenzo-p-dioxin 16.7±0.4 17.7±5.6

Total Tetrachlorodibenzo-p-dioxins 52.2±1.1 60.1±25

Total Pentachlorodibenzo-p-dioxins 49.8±1.3 69.5:t23

Total Hexachlorodibenzo-p-dioxins 217:tB 238:t86
1,2,3,4,6,7,8-Heptach lo rod i benzo-p-dioxin 296±5 293±63

Total Heptachlorodibenzo-p-dioxins 630:t9 608:t152
Octachlorodibenzo-p-dioxin 1990±40 1899±456
2,3,7,8-Tetrachlorodibenzofuran 65.2±1.1 52.5±16

Total Tetrachlorodibenzofurans 372:tB 374:t162
1,2,3,7,8-Pentachlorodibenzofuran 13.5±0.5 12.6±5

2,3,4,7,8-Pentachlorodibenzofuran 19.3±0.4 18.5±6
Total Pentachlorodibenzofurans 224:t13 225:t113
1,2,3,4,7,8-Hexachlorodibenzofuran 74.0±1.3 67.3±24

1,2,3,7,8,9-Hexachlorodibenzofuran 2.68*±4.0 2.68*±4.0
2,3,4,6,7,8-Hexachlorodibenzofuran 21.4±0.5 16±8
Total Hexachlorodibenzofurans 251:tB 262:t95
1,2,3,4,6,7,8-Heptachlorodibenzofuran 283±6 299±73

Total Heptachlorodibenzofurans 393:t9 411:t100
Octachlorodibenzofuran 491±14 509±157

3,4,4',5-Tetrachlorobiphenyl (81) - 75*±79
2,3,3' ,4,4'-Pentachlorobiphenyl (105) - 3998±951
2,3,4,4',5-Pentachlorobiphenyl (114) - 207±128
2,3',4,4',5-Pentachlorobiphenyl (118) - 8115±1663
2',3,4,4' ,5-Pentachlorobiphenyl (123) - 209±191
3,3',4,4',5-Pentachlorobiphenyl (126) - 84.9±35
2,3,3',4,4',5-Hexachlorobiphenyl (156) - 715±248
2,3,3',4,4',5'-Hexachlorobiphenyl (157) - 186±81
3,3',4,4',5,5'-Hexachlorobiphenyl (169) - 7.97±5.3
2,3,3',4,4',5,5'-Heptachlorobiphenyl (189) - 85.2±17.8
* Provisional value for information purposes only. Any negative deviation is inadmissable.
The concentrations of these analytes may be certified at a later date as more data becomes available.
186
CARP-2: REFERENCEFISH TISSUE for ORGANIC CONTAMINANT ANALYSIS

CARP-2 Reference Fish Tissue 6x9g
Polychlorinated Biphenyls (PCBs) Certified Concentration

Congener (IUPAC) µg/kg (wet weight basis)
18 27.3±4.0
28 34.0±7.2
44 86.6±25.9
52 138±43
118 148±33
128 20.4±4.4
153 105±22
180 53.3±13.0
194 10.9±3.1
206 4.4±1.1
Polychlorinated Biphenyls (PCBs) Reference Concentration*

Congener (IUPAC) µg/kg (wet weight basis)
8 4.8±1.8
66/95 174±52
101/90 145±48
105 53.2±15.6
138/163/164 103±30
170/190 20.6±2.9
187/182 37.1±6.3
209 4.6±2.0
Polychlorinated Dibenzo-p-dioxins (PCDDs) ng/kg (wet weight basis)*
2,3, 7,8-Tetrach lorodibenzo-p-d ioxi n 7.4±0.7

1,2,3,7,8-Pentachlorodibenzo-p-dioxin 5.3±1.3
1,2,3,4,7,8-Hexachlorodi benzo-p-d ioxin 1.6±0.3
1,2,3,6,7,8-Hexachlorodi benzo-p-d ioxin 5.8±0.8
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin 0.78±0.12
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 6.4±0.9
Octachlorodibenzo-p-dioxin 9.4±1.7
Polychlorinated Dibenzofurans (PCDFs) ng/kg (wet weight basis)*
2,3, 7,8-Tetrachlorodibenzofuran 18.2±1.6

1,2,3,7,8-Pentachlorodibenzofuran 5.6±0.3
Pesticides µg/kg (wet weight basis)*
gamma-chlordane 4.5±0.7
2,4'-DDE 2.9±0.5
trans-nonachlor 11.0±0.9
dieldrin 8.3±0.8
4,4'-DDE 158±14
2,4'-DDD 21.8±0.7
4,4'-DDD 90.9±8.5
* Not Certified
CARP-2 was prepared and certified by the National Research Council of Canada (NRCC),Institute for Environmental
Research and Technology.
187
ADDITIONAL PRODUCTS
Chlorinated Naphthalenes (PCNs): Native and Mass-Labelled Individuals and Solution/Mixtures
PAH Calibration Sets: Native and Mass-Labelled Support Solutions
Chlorinated Biphenylols (HO-PCBs): Native and Mass-Labelled Individuals; Mass-Labelled Solution/Mixture
Methoxy Chlorobiphenyls (MeO-PCBs): Native and Mass-Labelled Individuals and Solution/Mixtures
Chlorinated Biphenylenes (PCBPs): Native and Mass-Labelled
Triclocarban: Native and Mass-Labelled
Triclosan and Methyl Triclosan: Native, Mass-Labelled, and Chlorinated Derivatives
Tris(4-chlorophenyl) Methane and Methanol: Native and Mass-Labelled
Chlorinated Diphenyl Ethers (PCDEs): Native and Mass-Labelled
Chlorobenzene and Chlorophenol Solution/Mixtures: Native and Mass-Labelled
Melamine and Cyanuric Acid: Native and Mass-Labelled
Bisphenol A and Native Bisphenol Analogues: Native and Mass-Labelled
Tetrachlorodibenzothiophenes: Native and Mass-Labelled
Halogenated Carbazoles: Native and Mass-Labelled

PAH-CVS-B
Catalogue Number Product (isooctane/toluene solution) Qty/Cone

PAH-CVS•B PAH-CVS-B 1 kit
PAH·B·CS1 CS1 1.0 ml
PAH·B-CS2 CS2 1.0 ml
PAH·B·CS4 CS4 1.0 ml
PAH-B- PAH-B- PAH-B- PAH-B- PAH-B-

CS1 CS2 CS3 CS4 css
NATIVE PAHs (ng/mL) (ng/mL) (ng/mL) (ng/mL) (ng/mL)
Naphthalene 2.00 10.0 50.0 250 1000
2-Methylnaphthalene 2.00 10.0 50.0 250 1000
Acenaphthylene 2.00 10.0 50.0 250 1000
Acenaphthene 2.00 10.0 50.0 250 1000
Fluorene 2.00 10.0 50.0 250 1000
Phenanthrene 2.00 10.0 50.0 250 1000
Anthracene 2.00 10.0 50.0 250 1000
Fluoranthene 2.00 10.0 50.0 250 1000
Pyrene 2.00 10.0 50.0 250 1000
Benzo[c]fluorene 2.00 10.0 50.0 250 1000
Benzo[a]anthracene 2.00 10.0 50.0 250 1000
Cyclopenta[cd]pyrene 2.00 10.0 50.0 250 1000
Chrysene 2.00 10.0 50.0 250 1000
5-Methylchrysene 2.00 10.0 50.0 250 1000
Benzo[b]fluoranthene 2.00 10.0 50.0 250 1000
Benzo[k]fluoranthene 2.00 10.0 50.0 250 1000
Benzo[/lfluoranthene 2.00 10.0 50.0 250 1000
Benzo[e)pyrene 2.00 10.0 50.0 250 1000
Benzo[a)pyrene 2.00 10.0 50.0 250 1000
Perylene 2.00 10.0 50.0 250 1000
lndeno[1,2,3-cd]pyrene 2.00 10.0 50.0 250 1000
Dibenzo[a,h]anthracene 2.00 10.0 50.0 250 1000
Benzo[ghtlperylene 2.00 10.0 50.0 250 1000
Dibenzo[a,/]pyrene 2.00 10.0 50.0 250 1000
Dibenzo[a,e]pyrene 2.00 10.0 50.0 250 1000
Dibenzo[a,,lpyrene 2.00 10.0 50.0 250 1000
Dibenzo[a,h]pyrene 2.00 10.0 50.0 250 1000
DEUTERATED PAHs
Naphthalene-d 0 100 100 100 100 100
2-Methylnaphthalene-d, 0 100 100 100 100 100
Acenaphthylene-d 8 100 100 100 100 100
Phenanthrene-d, 0 100 100 100 100 100
Anthracene-d, 0 100 100 100 100 100
Fluoranthene-d 10 100 100 100 100 100
Benzo[a]anthracene-d 12 100 100 100 100 100
Chrysene-d12 100 100 100 100 100
Benzo[b]fluoranthene-d 12 100 100 100 100 100
Benzo[k)fluoranthene-d, 2 100 100 100 100 100
Benzo[a)pyrene-d 12 100 100 100 100 100
Perylene-d 12 100 100 100 100 100
lndeno[1,2,3-cd]pyrene-d 12 100 100 100 100 100
Dibenzo[a,h]anthracene-d, 4 100 100 100 100 100
Benzo[gh1lperylene-d 12 100 100 100 100 100
Dibenzo[a,tlpyrene-d, 4 100 100 100 100 100
INTERNAL STANDARDS
Acenaphthene-d 10 100 100 100 100 100
Pyrene-d10 100 100 100 100 100
Benzo[e]pyrene-d 12 100 100 100 100 100
SAMPLING STANDARDS
Fluorene-d 10 100 100 100 100 100
p-Terphenyl-d, 4 100 100 100 100 100
190
PAH-CVS-B

PAH-LCS-8 PAH Labelled Compound Solution 1.2 ml
PAH-155-B PAH Internal Standard Spiking Solution 1.2 ml
PAH-55-B PAH Sampling Standard Solution 1.2 ml
PAH-STK-8 PAH Native Stock Solution 1.2 ml
PAH-LCS-B PAH-ISS-B PAH-SS-B PAH-STK-B

(ng/mL) (ng/mL) (ng/mL) (ng/mL)
NATIVE PAHs
Naphthalene 2500
2-Methylnaphthalene 2500
Acenaphthylene 2500
Acenaphthene 2500
Fluorene 2500
Phenanthrene 2500
Anthracene 2500
Fluoranthene 2500
Pyrene 2500
Benzo[c]fluorene 2500
Benzo[a]anthracene 2500
Cyclopenta[cd]pyrene 2500
Chrysene 2500
5-Methylchrysene 2500
Benzo[b ]fl uoranthene 2500
Benzo[k]fluoranthene 2500
Benzo[/lfluoranthene 2500
Benzo[e]pyrene 2500
Benzo[aI pyrene 2500
Perylene 2500
lndeno[1,2,3-cd]pyrene 2500
Dibenzo[a,h]anthracene 2500
Benzo[ghtlperylene 2500
Dibenzo[a,/]pyrene 2500
Dibenzo[a,e]pyrene 2500
Dibenzo[a,tlpyrene 2500
Dibenzo[a,h]pyrene 2500
DEUTERATED PAHs
Naphthalene-d 8 5000
2-Methylnaphthalene-d, 0 5000
Acenaphthylene-d 0 5000
Phenanthrene-d 10 5000
Anthracene-d, 0 5000
Fluoranthene-d 10 5000
Benzo[a]anthracene-d, 2 5000
Chrysene-d12 5000
Benzo[b]fluoranthene-d 12 5000
Benzo[k]fluoranthene-d 12 5000
Benzo[aI pyrene-d, 2 5000
Perylene-d,2 5000
lndeno[1,2,3-cd]pyrene-d 12 5000
Dibenzo[a,h]anthracene-d, 4 5000
Benzo[gh1lperylene-d 12 5000
Dibenzo[a,tlpyrene-d, 4 5000
INTERNAL STANDARDS
Acenaphthene-d, 0 5000
Pyrene-d10 5000
Benzo[e]pyrene-d 12 5000
SAMPLING STANDARDS
Fluorene-d, 0 5000
p-Terphenyl-d, 4 5000
191
METHOD 429: HRGC/LRMS CALIBRATION SOLUTIONS FOR PAHs

L429-CVS l429-CVS 1 kit
L429·CS1 CS1 1.0 ml
L429-CS2 CS2 1.0 ml
L429-CS3 CS3 1.0 ml
L429·CS4 CS4 1.0 ml
L429-CSS CS5 1.0 ml
L429-CS1 L429-CS2 L429-CS3 L429-CS4 L429-CS5

NATIVE PAHs (ng/µL) (ng/µL) (ng/µL) (ng/µL) (ng/µL)
Naphthalene 0.250 0.500 1.00 2.50 5.00
2-Methylnaphthalene 0.250 0.500 1.00 2.50 5.00
Acenaphthylene 0.250 0.500 1.00 2.50 5.00
Acenaphthene 0.250 0.500 1.00 2.50 5.00
Fluorene 0.250 0.500 1.00 2.50 5.00
Phenanthrene 0.250 0.500 1.00 2.50 5.00
Anthracene 0.250 0.500 1.00 2.50 5.00
Fluoranthene 0.250 0.500 1.00 2.50 5.00
Pyrene 0.250 0.500 1.00 2.50 5.00
Benzo[a]anthracene 0.250 0.500 1.00 2.50 5.00
Chrysene 0.250 0.500 1.00 2.50 5.00
Benzo[b]fluoranthene 0.250 0.500 1.00 2.50 5.00
Benzo[k]fluoranthene 0.250 0.500 1.00 2.50 5.00
Benzo[e]pyrene 0.250 0.500 1.00 2.50 5.00
Benzo[a]pyrene 0.250 0.500 1.00 2.50 5.00
Perylene 0.250 0.500 1.00 2.50 5.00
lndeno[1,2,3-cd]pyrene 0.250 0.500 1.00 2.50 5.00
Dibenzo[a,h]anthracene 0.250 0.500 1.00 2.50 5.00
Benzo[gh11perylene 0.250 0.500 1.00 2.50 5.00
SURROGATE STANDARDS
Fluorene-d 10 1.00 1.00 1.00 1.00 1.00
p-Terphenyl-d, 4 1.00 1.00 1.00 1.00 1.00
INTERNAL STANDARDS
Naphthalene-d 8 1.00 1.00 1.00 1.00 1.00
2-Methylnaphthalene-d, 0 1.00 1.00 1.00 1.00 1.00
Acenaphthylene-d 8 1.00 1.00 1.00 1.00 1.00
Phenanthrene-d, 0 1.00 1.00 1.00 1.00 1.00
Fluoranthene-d 10 1.00 1.00 1.00 1.00 1.00
Benzo[a]anthracene-d 12 1.00 1.00 1.00 1.00 1.00
Chrysene-d12 1.00 1.00 1.00 1.00 1.00
Benzo[b]fluoranthene-d 12 1.00 1.00 1.00 1.00 1.00
Benzo[k]fluoranthene-d 12 1.00 1.00 1.00 1.00 1.00
Benzo[a]pyrene-d,, 1.00 1.00 1.00 1.00 1.00
Perylene-d 12 1.00 1.00 1.00 1.00 1.00
lndeno[1,2,3-cd]pyrene-d 12 1.00 1.00 1.00 1.00 1.00
Dibenzo[a,h]anthracene-d, 4 1.00 1.00 1.00 1.00 1.00
Benzo[gh11perylene-d12 1.00 1.00 1.00 1.00 1.00
ALTERNATE STANDARD
Anthracene-d, 0 1.00 1.00 1.00 1.00 1.00
RECOVERY STANDARDS
Acenaphthene-d, 0 1.00 1.00 1.00 1.00 1.00
Pyrene-d10 1.00 1.00 1.00 1.00 1.00
Benzo[e]pyrene-d,, 1.00 1.00 1.00 1.00 1.00
192
METHOD 429: HRGC/LRMS CALIBRATION SOLUTIONS FOR PAHs

L429-SS Method 429 Surrogate Standard Stock Solution 1.2 ml
L429-IS Method 429 Internal Standard Stock Solution 1.2 ml
L429-AS Method 429 Alternate Standard Stock Solution 1.2 ml
L429-RS Method 429 Recovery Standard Stock Solution 1.2 ml
L429-PAR Method 429 Native PAH Stock Solution 1.2 ml
L429-SS L429-IS L429-AS L429-RS L429-PAR

NATIVE PAHs h.1g/mL) (.,.g/mL) (.,.g/mL) (.,.g/mL) (.,.g/mL)
Naphthalene 2.00
2-Methylnaphthalene 2.00
Acenaphthylene 2.00
Acenaphthene 2.00
Fluorene 2.00
Phenanthrene 2.00
Anthracene 2.00
Fluoranthene 2.00
Pyrene 2.00
Benzo[a]anthracene 2.00
Chrysene 2.00
Benzo[b ]fl uoranthene 2.00
Benzo[k]fluoranthene 2.00
Benzo[e]pyrene 2.00
Benzo[a]pyrene 2.00
Perylene 2.00
lndeno[1,2,3-cd]pyrene 2.00
Dibenzo[a,h]anthracene 2.00
Benzo[ghtlperylene 2.00
SURROGATE STANDARDS
Fluorene-d 10 100
p-Terphenyl-d, 4 100
INTERNAL STANDARDS
Naphthalene-d 8 100
2-Methylnaphthalene-d, 0 100
Acenaphthylene-d 8 100
Phenanthrene-d 10 100
Fluoranthene-d 10 100
Benzo[a]anthracene-d, 2 100
Chrysene-d,2 100
Benzo[b]fluoranthene-d 12 100
Benzo[k]fluoranthene-d 12 100
Benzo[a]pyrene-d 12 100
Perylene-d12 100
lndeno[1,2,3-cd]pyrene-d 12 100
Dibenzo[a,h]anthracene-d, 4 100
Benzo[ghtlperylene-d, 2 100
ALTERNATE STANDARD
Anthracene-d 10 100
RECOVERY STANDARDS
Acenaphthene-d, 0 100
Pyrene-d10 100
Benzo[e] pyrene-d 12 100
193
EPA PAH SOLUTION/MIXTURES

EPA·PAH-STK Native PAH Solution/Mixture 1.2 ml
Naphthalene 5.00 µg/ml

Acenaphthylene 5.00 µg/ml
Acenaphthene 5.00 µg/ml
Fluorene 5.00 µg/ml
Phenanthrene 5.00 µg/ml
Anthracene 5.00 µg/ml
Fluoranthene 5.00 µg/ml
Pyrene 5.00 µg/ml
Benzo[a)anthracene 5.00 µg/ml
Chrysene 5.00 µg/ml
Benzo[b)fluoranthene 5.00 µg/ml
Benzo[k)fluoranthene 5.00 µg/ml
Benzo[a)pyrene 5.00 µg/ml
lndeno[1,2,3-cd)pyrene 5.00 µg/ml
Benzo[ghtlperylene 5.00 µg/ml
Dibenzo[a,h)anthracene 5.00 µg/ml

EPA-PAH-LeS Deuterated PAH Solution/Mixture 1.2 ml
Naphthalene-d 8 5.00 µg/ml

Acenaphthylene-d 8 5.00 µg/ml
Acenaphthene-d 10 5.00 µg/ml
Fluorene-d 10 5.00 µg/ml
Phenanthrene-d 10 5.00 µg/ml
Anthracene-d 10 5.00 µg/ml
Fluoranthene-d 10 5.00 µg/ml
Pyrene-d10 5.00 µg/ml
Benzo[a)anthracene-d 12 5.00 µg/ml
Chrysene-d12 5.00 µg/ml
Benzo[b)fluoranthene-d 12 5.00 µg/ml
Benzo[k)fluoranthene-d 12 5.00 µg/ml
Benzo[a)pyrene-d 12 5.00 µg/ml
lndeno[1,2,3-cd)pyrene-d 12 5.00 µg/ml
Benzo[gh1lperylene-d 12 5.00 µg/ml
Dibenzo[a,h)anthracene-d 14 5.00 µg/ml
* The solutions above can be used with the PAH-CVS-B calibration solutions.
194
EPA & EU PAH SOLUTION/MIXTURE

EPA•EU•PAH·ISS Deuterated PAH Solution/Mixture 1.2 ml
2-Methylnaphthalene-d 10 5.00 µg/ml

p-Terphenyl-d, 4 5.00 µg/ml
Benzo[e]pyrene-d 12 5.00 µg/ml
EU PAH SOLUTION/MIXTURES

EU-PAH-STK Native PAH Solution/Mixture 1.2 ml
Benzo[c]fluorene 5.00 µg/ml

Cyclopenta[cd]pyrene 5.00 µg/ml
Benzo[a]anthracene 5.00 µg/ml
Chrysene 5.00 µg/ml
5-Methylchrysene 5.00 µg/ml
Benzo[b]fluoranthene 5.00 µg/ml
Benzo[k]fluoranthene 5.00 µg/ml
Benzo[Jlfluoranthene 5.00 µg/ml
Benzo[a]pyrene 5.00 µg/ml
lndeno[1,2,3-cd]pyrene 5.00 µg/ml
Benzo[ghtlperylene 5.00 µg/ml
Dibenzo[a,h]anthracene 5.00 µg/ml
Dibenzo[a,/]pyrene 5.00 µg/ml
Dibenzo[a,e]pyrene 5.00 µg/ml
Dibenzo[a,tlpyrene 5.00 µg/ml
Dibenzo[a,h]pyrene 5.00 µg/ml

EU-PAH-LCS Deuterated PAH Solution/Mixture 1.2 ml
Benzo[a]anthracene-d 12 5.00 µg/ml

Chrysene-d12 5.00 µg/ml
Benzo[b]fluoranthene-d 12 5.00 µg/ml
Benzo[k]fluoranthene-d 12 5.00 µg/ml
Benzo[a]pyrene-d 12 5.00 µg/ml
lndeno[1,2,3-cd]pyrene-d 12 5.00 µg/ml
Benzo[gh1lperylene-d 12 5.00 µg/ml
Dibenzo[a,h]anthracene-d,. 5.00 µg/ml
Dibenzo[a,,lpyrene-d,. 5.00 µg/ml
* The solutions above can be used with the PAH-CVS-B calibration solutions.
195
NATIVE CHLORINATEDBIPHENYLOLS(HO-PCBs)

4H107 2,3,3' ,4', 5-Pentach loro-4-biphenylol 1.2 ml 50.0 µg/ml
4H108 2' ,3,3 ',4', 5-Pentach loro-4-biphenylol (96.5%) 1.2 ml 48.3 µg/ml
3H118 2,3 ',4,4', 5-Pentach loro-3-biphenylol 1.2 ml 50.0 µg/ml
4H130 2,2 ',3,3' ,4' ,5-Hexachloro-4-bi phenylol 1.2 ml 50.0 µg/ml
3H138 2,2 ',3 ',4,4' ,5-Hexachloro-3-bi phenylol 1.2 ml 50.0 µg/ml
4H146 2,2 ',3,4', 5,5'-Hexachloro-4-bi phenylol 1.2 ml 50.0 µg/ml
3H153 2,2 ',4,4', 5, 5'-Hexachloro-3-bi phenylol 1.2 ml 50.0 µg/ml
4H172 2,2 ',3,3' ,4' ,5, 5 '-Heptachloro-4-bi phenylol 1.2 ml 50.0 µg/ml
3H180 2,2 ',3 ',4,4' ,5, 5 '-Heptachloro-3-bi phenylol 1.2 ml 50.0 µg/ml
4H187 2,2 ',3,4', 5, 5' ,6-Heptachloro-4-bi phenylol 1.2 ml 50.0 µg/ml
MASS-LABELLEDCHLORINATEDBIPHENYLOLS

a
a-0-&
3',4' -Dichloro-4-("C,,)bi phenylol
M4H12 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene;
2',4', 5'-Trichloro-4-("C,,)bi phenylol

a isotopic purity 99% or greater
2',3',4',5'-Tetrachloro-4-("C,,)biphenylol
a isotopic purity 99% or greater
2',3,4',5,5'-Pentachloro-4-("C,,)biphenylol
M4H120 OH 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene;
a a isotopic purity 99% or greater
2',3,3',4',5,5'-Hexachloro-4-("C,,)biphenylol
2,2',3,3',4',5,5'-Heptachloro-4-("C,,)biphenylol
2,2',3,4',5,5',6-Heptachloro-4-("C,,)biphenylol
a a a isotopic purity 99% or greater
196
MASS-LABELLEDCHLORINATEDBIPHENYLOLS:SOLUTION/MIXTURE

MHPCB·MXA Mass-Labelled Chlorinated Biphenylol Solution/Mixture 1.2 ml
3' ,4' -Dichloro-4-("C,,)biphenylol M4H 12 5.00 µg/ml

2',4',5'-Trichloro-4-("C,,)biphenylol M4H29 5.00 µg/ml
2',3',4',5'-Tetrachloro-4-("C,,)biphenylol M4H61 5.00 µg/ml
2',3,4',5,5'-Pentachloro-4-("C,,)biphenylol M4H120 5.00 µg/ml
2',3,3',4',5,5'-Hexachloro-4-("C,,)biphenylol M4H159 5.00 µg/ml
2,2',3,3',4',5,5'-Heptachloro-4-("C,,)biphenylol M4H172 5.00 µg/ml
2,2',3,4',5,5',6-Heptachloro-4-("C,,)biphenylol M4H187 5.00 µg/ml
M4H29
M4H120
M4H12 M4H159
M4H61
M4H172
M4H187
HRGC/LRMSData for MHPCB-MXA on a 30m DB-XLB Column.
197
NATIVE METHOXY-CHLOROBIPHENYLS (MeO-PCBs)

4PM79 3,3' ,4', 5-Tetrachloro-4-methoxybiphenyl 1.2 ml 50.0 µg/ml
4PM97 2,2 ', 3,4', 5 '-Pentach Ioro-4-methoxybi phenyl 1.2 ml 50.0 µg/ml
4PM101 2,2 ',4, 5, 5 '-Penta ch loro-4' -methoxybi phenyl 1.2 ml 50.0 µg/ml
4M107 2,3,3 ',4', 5-Pentach loro-4-methoxybi phenyl 1.2 ml 50.0 µg/ml
4PM108 2,3,3 ',4, 5'-Pentach loro-4'-methoxybi phenyl 1.2 ml 50.0 µg/ml
3M118 2,3 ',4,4', 5-Pentach loro-3-methoxyb i phenyl 1.2 ml 50.0 µg/ml
4PM120 2, 3 ',4, 5, 5 '-Penta ch loro-4' -methoxybi phenyl 1.2 ml 50.0 µg/ml
4PM127 3,3 ',4, 5, 5 '-Penta ch loro-4' -methoxybi phenyl 1.2 ml 50.0 µg/ml
4PM130 2,2' ,3,3' ,4', 5-Hexachloro-4-methoxybiphenyl 1.2 ml 50.0 µg/ml
4M134 2,2 ', 3, 3 ', 5, 6-H exach Ioro-4-methoxybi phenyl 1.2 ml 50.0 µg/ml
3PM138 2,2' ,3 ',4,4', 5-Hexachloro-3-methoxybiphenyl 1.2 ml 50.0 µg/ml
4M146 2,2 ', 3,4', 5, 5' -H exach loro-4-methoxybi phenyl 1.2 ml 50.0 µg/ml
33PDM155 2,2',4,4',6,6'-Hexachloro-3,3'-dimethoxybiphenyl 1.2 ml 50.0 µg/ml
4PM159 2,3,3 ',4, 5, 5'-Hexachloro-4 '-methoxybiphenyl 1.2 ml 50.0 µg/ml
4M162 2,3,3 ',4', 5, 5'-Hexachloro-4-methoxybiphenyl 1.2 ml 50.0 µg/ml
4M163 2,3,3 ',4', 5,6-Hexachloro-4-methoxybi phenyl 1.2 ml 50.0 µg/ml
4PM172 2,2 ', 3, 3 ',4, 5, 5 '-Heptach loro-4' -methoxyb i phenyl 1.2 ml 50.0 µg/ml
4M177 2,2' ,3,3' ,4', 5,6-Heptach loro-4-methoxybiphenyl 1.2 ml 50.0 µg/ml
4M178 2,2' ,3,3', 5, 5' ,6-Heptach loro-4-methoxybiphenyl (>97%) 1.2 ml 48.5 µg/ml
3PM180 2,2' ,3,4,4', 5, 5 '-Heptach loro-3'-methoxybiphenyl 1.2 ml 50.0 µg/ml
3PM182 2,2' ,3,4,4', 5,6'-Heptach loro-3'-methoxybiphenyl 1.2 ml 50.0 µg/ml
3PM183 2,2' ,3 ',4,4', 5,6'-Heptach loro-3-methoxybiphenyl 1.2 ml 50.0 µg/ml
3PM184 2,2 ', 3,4,4', 6, 6 '-Heptach loro-3' -methoxyb i phenyl 1.2 ml 50.0 µg/ml
4M187 2,2' ,3,4', 5, 5' ,6-Heptach loro-4-methoxybiphenyl 1.2 ml 50.0 µg/ml
4M193 2,3,3 ',4', 5, 5' ,6-Heptach loro-4-methoxybiphenyl 1.2 ml 50.0 µg/ml
4PM198 2,2' ,3,3' ,4, 5, 5 ',6-Octach loro-4'-methoxybi phenyl 1.2 ml 50.0 µg/ml
4PM199 2,2' ,3,3' ,4', 5, 5 ',6-Octach loro-4-methoxybi phenyl 1.2 ml 50.0 µg/ml
4PM200 2,2 ', 3, 3 ',4, 5, 6, 6' -Octa ch loro-4' -methoxybi phenyl 1.2 ml 50.0 µg/ml
4PM201 2,2' ,3,3' ,4', 5,6,6 '-Octach loro-4-methoxybi phenyl 1.2 ml 50.0 µg/ml
4M202 2,2' ,3,3', 5, 5' ,6,6'-Octach loro-4-methoxybi phenyl 1.2 ml 50.0 µg/ml
44PDM202 2,2 ', 3, 3 ', 5, 5', 6, 6 '-Octa ch Ioro-4,4' -di methoxybi phenyl 1.2 ml 50.0 µg/ml
3PM203 2,2' ,3,4,4', 5, 5 ',6-Octach loro-3 '-methoxybi phenyl 1.2 ml 50.0 µg/ml
4PM208 2,2' ,3,3' ,4, 5, 5 ',6,6'-Nonach loro-4'-methoxybiphenyl 1.2 ml 50.0 µg/ml
198
NATIVE METHOXY-CHLOROBIPHENYLS: SOLUTION/MIXTURES

MPCB-MXA Native Chlorinated Methoxybiphenyl Solution/Mixture 1.2 ml
2,3,4,5-Tetrachloro-4' -methoxybi phenyl 4PM61 5.00 µg/ml

2,3',4, 5,5' -Pentachloro-4' -methoxybi phenyl 4PM120 5.00 µg/ml
2,2',4,4',6,6'-Hexachloro-3,3'-dimethoxybiphenyl 33PDM155 5.00 µg/ml
2,2',3,4,4',6,6'-Heptachloro-3'-methoxybiphenyl 3PM184 5.00 µg/ml
2,2',3,3',5,5',6,6'-Octachloro-4-methoxybiphenyl 4M202 5.00 µg/ml
MPCB-MXB Native Chlorinated Methoxybiphenyl Solution/Mixture 1.2 ml
3,3',4',5-Tetrachloro-4-methoxybiphenyl 4PM79 5.00 µg/ml

2,2',4, 5,5'-Pentachloro-4' -methoxybi phenyl 4PM101 5.00 µg/ml
2,2',3,3',5,6-Hexachloro-4-methoxybiphenyl 4M134 5.00 µg/ml
2,2',3,3',5,5',6-Heptachloro-4-methoxybiphenyl 4M178 4.85 µg/ml
2,2',3,3 ',4', 5,6,6'-Octachloro-4-methoxybi phenyl 4PM201 5.00 µg/ml
MPCB-MXC Native Chlorinated Methoxybiphenyl Solution/Mixture 1.2 ml
2,3,4,4', 5-Pentachloro-2' -methoxybiphenyl 2PM114 5.00 µg/ml

2,2',3,4',5,5'-Hexachloro-4-methoxybiphenyl 4M146 5.00 µg/ml
2,2',3,4,4',5,5',6-Octachloro-3'-methoxybiphenyl 3PM203 5.00 µg/ml
2,2',3,3',4,5,5',6,6'-Nonachloro-4'-methoxybiphenyl 4PM208 5.00 µg/ml
MPCB-MXD Native Chlorinated Methoxybiphenyl Solution/Mixture 1.2 ml
2,3',4,4', 5-Pentachloro-3-methoxybi phenyl 3M118 5.00 µg/ml

2,2',3 ',4,4', 5-Hexachloro-3-methoxybi phenyl 3PM138 5.00 µg/ml
2,2',3',4,4',5,6'-Heptachloro-3-methoxybiphenyl 3PM183 5.00 µg/ml
2,2',3,3',4,5,5',6-Octachloro-4'-methoxybiphenyl 4PM198 5.00 µg/ml
MPCB-MXE Native Chlorinated Methoxybiphenyl Solution/Mixture 1.2 ml
2,3,3',4,5' -Pentachloro-4' -methoxybi phenyl 4PM108 5.00 µg/ml

2,2',3,3',4',5-Hexachloro-4-methoxybiphenyl 4PM130 5.00 µg/ml
2,2',3,4',5,5',6-Heptachloro-4-methoxybiphenyl 4M187 5.00 µg/ml
2,2',3,3',4',5,5',6-Octachloro-4-methoxybiphenyl 4PM199 5.00 µg/ml
MPCB-MXF Native Chlorinated Methoxybiphenyl Solution/Mixture 1.2 ml
2,3,3',4', 5-Pentachloro-4-methoxybi phenyl 4M107 5.00 µg/ml

2,3,3',4', 5,6-Hexachloro-4-methoxybiphenyl 4M163 5.00 µg/ml
2,2',3,3',4',5,6-Heptachloro-4-methoxybiphenyl 4M177 5.00 µg/ml
2,2',3,3',4,5,6,6'-Octachloro-4'-methoxybiphenyl 4PM200 5.00 µg/ml
199
NATIVE METHOXY-CHLOROBIPHENYLS:
SOLUTION/MIXTURES

MPCB·MXG Native Chlorinated Methoxybiphenyl Solution/Mixture 1.2 ml
2,2' ,3,4', 5' -Pentach loro-4-methoxybi phenyl 4PM97 5.00 µg/ml

2,3,3',4,5,5'-Hexachloro-4'-methoxybiphenyl 4PM159 5.00 µg/ml
2,2',3,3',5,5',6,6'-Octachloro-4,4'-dimethoxybiphenyl 44PDM202 5.00 µg/ml
MPCB-MXH Native Chlorinated Methoxybiphenyl Solution/Mixture 1.2 ml
3,3',4, 5,5'-Pentachloro-4' -methoxybi phenyl 4PM127 5.00 µg/ml

2,2',3,3',4,5,5'-Heptachloro-4'-methoxybiphenyl 4PM172 5.00 µg/ml
MPCB-MXI Native Chlorinated Methoxybiphenyl Solution/Mixture 1.2 ml
2,3,3',4',5,5'-Hexachloro-4-methoxybiphenyl 4M162 5.00 µg/ml

2,3,3',4', 5,5',6-Heptach loro-4-methoxybi phenyl 4M193 5.00 µg/ml
MASS-LABELLEDM ETHOXY-CHLOROBIPHENYLS
2,4,5-Trichloro-4' -methoxy("C 12)bi phenyl

M4M29
Cl
2,3,4,5-Tetrachloro-4'-methoxy("C,,)biphenyl
M4M61
Cl
2,3',4,5,5'-Pentachloro-4'-methoxy("C,,)biphenyl
M4M120
Cl
2,3,3',4,5,5'-Hexachloro-4'-methoxy("C,,)biphenyl
M4M159
Cl Cl
2,2',3,3',4,5,5'-Heptachloro-4'-methoxy("C,,)biphenyl
M4M172
Cl Cl
2,2',3,4',5,5',6-Heptachloro-4-methoxy("C,,)biphenyl
M4M187
Cl Cl Cl
200
MASS-LABELLEDMETHOXY-CHLOROBIPHENYLS:
SOLUTION/MIXTURE

MMPCB-MXA Mass-Labelled Chlorinated Methoxybiphenyl Solution/Mixture 1.2 ml
2,4, 5-Trichloro-4' -methoxy("C,,)bi phenyl M4M29 5.00 µg/ml

2,3,4,5-Tetrachloro-4'-methoxy("C,,)biphenyl M4M61 5.00 µg/ml
2,3',4,5,5'-Pentachloro-4'-methoxy("C,,)biphenyl M4M120 5.00 µg/ml
2,3,3',4,5,5'-Hexachloro-4'-methoxy("C,,)biphenyl M4M159 5.00 µg/ml
2,2',3,3',4,5,5'-Heptachloro-4'-methoxy("C,,)biphenyl M4M172 5.00 µg/ml
2,2',3,4',5,5',6-Heptachloro-4-methoxy("C,,)biphenyl M4M187 5.00 µg/ml
NATIVE CHLORINATEDBIPHENYLENES(PCBPs)
Chlorinated Biphenylenes have been detected in samples taken in the aftermath of PCBfires. It is
thought that they may be formed as the result of incomplete combustion of the PCBs.
In microsomal enzyme studies, the 2,3,6,7-tetrachlorobiphenylene has shown similar potency to

that of 2,3,7,8-tetrachlorodibenzo-p-dioxin in its toxicological effects.

CBP-2 2-Ch lorobi phenylene 1.2 ml 50.0 µg/ml
CBP-23 2,3-Dich lorobi phenylene 1.2 ml 50.0 µg/ml
CBP-236 2, 3, 6-Trich lorobi phenyl ene 1.2 ml 50.0 µg/ml
CBP-2367 2,3,6, 7-Tetrachlorobiphenylene 1.2 ml 50.0 µg/ml
MASS-LABELLEDCHLORINATEDBIPHENYLENE
2,3,6,7-Tetrachloro("C,,)bi phenylene
Cl~CI
MCBP-2367 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in nonane;
Cl~CI
201
NATIVE TRICLOCARBAN
Triclocarban, like Triclosan, is an antimicrobial additive used in a variety of personal care products.

TCC N-(4-ch lorophenyl)-N '-(3,4-d ich lorophenyl) urea 1.2 ml 50.0 µg/ml
MASS-LABELLED TRICLOCARBAN
N-(4-chloro("c.)phenyl)-N'-(3,4-dichloro("c.)phenyl)("C)urea
MTCC 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;

NATIVE TRICLOSAN AND METHYL TRICLOSAN
Triclosan is a widely used antibacterial and antifungal agent that has been incorporated into many
common consumer products including toothpastes, deodorants, antibacterial soaps, and
detergents.
The increasing use of these products over the last 30 years has led to Triclosan, and its
biotransformation product, Methyl Triclosan, being found in the environment.

TCS 5-Chloro-2-(2,4-dichlorophenoxy)phenol 1.2 ml 50.0 µg/ml
TCS·M 5-Chloro-2-(2,4-dichlorophenoxy)phenol (in methanol) 1.2 ml 50.0 µg/ml

MeTCS 5-Chloro-2-(2,4-dichlorophenoxy)anisole 1.2 ml 50.0 µg/ml
MASS-LABELLED TRICLOSAN AND METHYL TRICLOSAN
OH
5-Chloro-2-(2,4-dichloro("c.)phenoxy)("C 6 )phenol
MTCS 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in nonane;
5-Chloro-2-(2,4-dichloro("C 6)phenoxy)("C 6)phenol
MTCS·M 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;

5-Chloro-2-(2,4-dichloro("C 6)phenoxy)(1,2,3,4,5,6-"C,)anisole
MMeTCS 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in nonane;

202
CHLORINATED DERIVATIVES OF TRICLOSAN AND METHYL TRICLOSAN
The reaction of Triclosan with free chlorine in water, or during wastewater treatment processes,
may result in the formation of further chlorinated Triclosan isomers.
6TeS 2,3-Dichloro-6-(2,4-dichlorophenoxy)phenol (6-Chlorotriclosan) 1.2 ml 50.0 µg/ml
6MeTCS 2, 3-D ich loro-6-(2,4-d ich lorophenoxy)an isole (6-Chloro-methyltriclosan} 1.2 ml 50.0 µg/ml
4TCS 4, 5-D ich loro-2-(2,4-d ich lorophenoxy)phenol (4-Chlorotriclosan) 1.2 ml 50.0 µg/ml
4MeTCS 4, 5-D ich loro-2-(2,4-d ich lorophenoxy)an isole (4-Chloro-methyltriclosan) 1.2 ml 50.0 µg/ml
46TCS 2, 3,4-Trich loro-6-(2,4-d ich lorophenoxy)phenol (4,6-Dichlorotriclosan) 1.2 ml 50.0 µg/ml
46MeTCS 2, 3,4-Trich loro-6-(2,4-d ich lorophenoxy)an isole (4,6-Dichloro-methyltriclosan) 1.2 ml 50.0 µg/ml
NATIVE CHLOROXANTHENE
The tetrachloroxanthene was originally suspected to be an environmental contaminant due to
pulp bleaching.
XE-2367-5 2,3,6, 7-Tetrach loroxa nthene 1.2 ml 50.0 µg/ml
ClyYYyCI
Cl~I
2,3,6, 7-Tetrachloroxanthene
NATIVE TRIS(4-CHLOROPHENYL)METHANE AND

TRIS(4-CHLOROPHENYL)METHANOL
These two compounds have been found in a variety of environmental samples including fish,
marine mammals and birds.
It is possible that they may originate from DDT or other agrochemicals.
T4CPM Tris(4-chlorophenyl)methane 1.2 ml 50.0 µg/ml
T4CPME Tris(4-chlorophenyl)methanol 1.2 ml 50.0 µg/ml
MASS-LABELLED TRIS(4-CHLOROPHENYL)METHANE AND

TRIS(4-CHLOROPHENYL)METHANOL
Tris(4-chlorophenyl)metha ne- "C,.
MT4CPM 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in nonane;
Tris(4-chlorophenyl)metha nol- "C,,
MT4CPME 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in nonane;
203
PCN-CVS-A

PCN-CVS•A PCN-CVS-A 1 kit
PCN•CS1·A CS1 200 µL
PCN-CS2·A CS2 200 µL
PCN-CS3-A CS3 200 µL
PCN•CS4·A CS4 200 µL
PCN-CSS·A CS5 200 µL
PCN- PCN- PCN- PCN- PCN-

CS1-A CS2-A CS3-A CS4-A CSS-A
NATIVE PCNs Congener# (ng/mL) (ng/mL) (ng/mL) (ng/mL) (ng/mL)
1-Chloronaphthalene 1 1.00 5.00 20.0 100 500
2-Chloronaphthalene 2 1.00 5.00 20.0 100 500
1,3-Dichloronaphthalene 4 1.00 5.00 20.0 100 500
1,2,3-Trichloronaphthalene 13 1.00 5.00 20.0 100 500
1,4,6-Trich loronaphtha lene 24 1.00 5.00 20.0 100 500
1,2,3,5-Tetrachloronaphthalene 28 1.00 5.00 20.0 100 500
1,2,5,7-Tetrach lorona phtha lene 37 1.00 5.00 20.0 100 500
2,3,6,7-Tetrach lorona phtha lene 48 1.00 5.00 20.0 100 500
1,2,3,5,7-Pentachloronaphthalene 52 1.00 5.00 20.0 100 500
1,2,3,5,8-Pentach loronaphthalene 53 1.00 5.00 20.0 100 500
1,2,3,4,5,6-Hexachloronaphthalene 63 1.00 5.00 20.0 100 500
1,2,3,4,5,6,7-Heptachloronaphthalene 73 1.00 5.00 20.0 100 500
1,2,3,4,5,6,8-Heptachloronaphthalene 74 1.00 5.00 20.0 100 500
Octachloronaphthalene 75 1.00 5.00 20.0 100 500
1-Chloro{"C,.)naphthalene 1L 10.0 10.0 10.0 10.0 10.0
1,4-Dichloro{"C,.)naphthalene SL 10.0 10.0 10.0 10.0 10.0
1,4, 6-Trich loro{"C,.)na phtha lene 24L 10.0 10.0 10.0 10.0 10.0
2,3,6,7-Tetrach loro{"C,.)naphthalene 48L 10.0 10.0 10.0 10.0 10.0
1,2,3,6,7-Pentach loro{"C,.)naphtha lene 54L 10.0 10.0 10.0 10.0 10.0
1,2,3,5,6,7-Hexachloro{"C,.)naphthalene 67L 10.0 10.0 10.0 10.0 10.0
1,2,3,4,5,6,7-Heptach loro{"C,.)naphtha lene 73L 10.0 10.0 10.0 10.0 10.0
Octachloro{"C,.)naphthalene 75L 10.0 10.0 10.0 10.0 10.0
INJECTION STANDARDS
1,4, 5-Trich loro{"C 10)na phtha lene 23L 10.0 10.0 10.0 10.0 10.0
1,2,3,4,5,6,8-Heptachloro{"C,.)naphthalene 74L 10.0 10.0 10.0 10.0 10.0
SAMPLING STANDARD
204
PCN-CVS-A

PCN-LCS-A PCN Extraction Standard Solution 1.2 ml
PCN-155-A PCN Injection Standard Solution 1.2 ml
PCN-SS·A PCN Sampling Standard Solution 1.2 ml
PCN-STK-A PCN Native Stock Solution 1.2 ml
PCN-LCS-A PCN-ISS-A PCN-SS-A PCN-STK-A

NATIVE PCNs Congener# {ng/mL) {ng/mL) {ng/mL) {ng/mL)
1-Chloronaphthalene 1 1000
2-Chloronaphthalene 2 1000
1,3-Dichloronaphthalene 4 1000
1,2,3-Trichloronaphthalene 13 1000
1,4,5-Trichloronaphtha lene 23 1000
1,2,3,5-Tetrachloronaphthalene 28 1000
1,2,5,7-Tetrach lorona phtha lene 37 1000
1,2,3,5,7-Pentachloronaphthalene 52 1000
1,2,3,5,8-Pentach loronaphthalene 53 1000
1,2,3,4,5,6-Hexachloronaphthalene 63 1000
1,2,3,4,5,6,7-Heptachloronaphthalene 73 1000
1,2,3,4,5,6,8-Heptachloronaphthalene 74 1000
Octachloronaphthalene 75 1000
1-Chloro("C,.)naphthalene 1L 1000
1,4-Dichloro("C,Jnaphthalene SL 1000
1,4,6-Trichloro("C 10)na phtha lene 24L 1000
2,3,6,7-Tetrach loro("C,.)naphthalene 48L 1000
1,2,3,6,7-Pentach loro("C,Jnaphtha lene 54L 1000
1,2,3,5,6,7-Hexach loro("C 10)na phtha lene 67L 1000
1,2,3,6,7,8-Hexachloro("C 10)naphthalene 70L 1000
1,2,4,5,7,8-Hexachloro("C,Jnaphthalene 72L 1000
1,2,3,4,5,6,7-Heptachloro("C,.)naphthalene 73L 1000
Octachloro("C,.)naphthalene 75L 1000
INJECTION STANDARDS
1,4,5-Trichloro("C 10)na phtha lene 23L 1000
1,2,4,5,8-Pentach loro("C,Jnaphtha lene 59L 1000
1,2,3,4,5,6,8-Heptach loro("C,.)naphtha lene 74L 1000
SAMPLING STANDARD
1,2,3,7,8-Pentachloro("C,.)naphthalene 56L 1000
205
NATIVE POLYCHLORINATED NAPHTHALENES: SOLUTION/MIXTURES

PCN-MXA Native PCNSolution/Mixture 1.2 ml
Congener#
2-Chloronaphthalene 2 5.00 µg/ml
1,5-Dichloronaphthalene 6 5.00 µg/ml
1,2,3-Trichloronaphthalene 13 5.00 µg/ml
1,2,3,5-Tetrachloronaphthalene 28 5.00 µg/ml
1,2,3,5,7-Pentachloronaphthalene 52 5.00 µg/ml
1,2,3,4,6,7-Hexachloronaphthalene 66 5.00 µg/ml
1,2,3,4,5,6,7-Heptachloronaphthalene 73 5.00 µg/ml
Octachloronaphthalene 75 5.00 µg/ml
PCN-MXC Native PCNSolution/Mixture 1.2 ml
Congener#
2,3,6,7-Tetrachlorona phtha lene 48 5.00 µg/ml
PCN-WD PCNWindow Defining Solution/Mixture 1.2 ml
Congener#
1-Chlorona phtha lene 2.00 µg/ml
1,2,3,4,6,7-Hexachloronaphtha lene 66 2.00 µg/ml
206
NATIVE POLYCHLORINATEDNAPHTHALENES:SOLUTION/MIXTURES

PCN•HWX PCNMajor Halowax Congeners Solution/Mixture 1.2 ml
Congener#
1-Chloronaphthalene 2.00 µg/ml
PCN-INC PCNMajor Incineration Congeners Solution/Mixture 1.2 ml
Congener#
PCN•TOX PCNPotentially Toxic Congeners Solution/Mixture 1.2 ml
Congener#
207
NATIVE POLYCHLORINATEDNAPHTHALENES(PCNs)

PN-15 1-Chloronaphthalene 1.2 ml 50.0 µg/ml
PN-25 2-Chloronaphthalene 1.2 ml 50.0 µg/ml
PN-45 1,3-Dichloronaphthalene 1.2 ml 50.0 µg/ml
PN-135 1,2,3-Trichloronaphthalene 1.2 ml 50.0 µg/ml
PN-275 1,2,3,4-Tetrachlorona phtha lene 1.2 ml 50.0 µg/ml
PN-285 1,2,3,5-Tetrachloronaphthalene 1.2 ml 50.0 µg/ml
6 3
5 4
208
NATIVE POLYCHLORINATEDNAPHTHALENES(PCNs)

PN-465 1,4,5,8-Tetrachloronaphthalene (96% pure) 1.2 ml 48.0 µg/ml
PN-505 1,2,3,4,6-Pentachloronaphthalene 1.2 ml 50.0 µg/ml
PN-635 1,2,3,4,5,6-Hexachloronaphtha lene 1.2 ml 50.0 µg/ml
PN-665 1,2,3,4,6,7-Hexachloronaphthalene 1.2 ml 50.0 µg/ml
PN-735 1,2,3,4,5,6,7-Heptachloronaphthalene 1.2 ml 50.0 µg/ml
PN-745 1,2,3,4,5,6,8-Heptachloronaphthalene 1.2 ml 50.0 µg/ml
PN-755 Octachloronaphthalene 1.2 ml 50.0 µg/ml
8 1
5 4
209
MASS-LABELLEDPOLYCHLORINATEDNAPHTHALENES(PCNs)
1-Chloro("C 10)na phtha lene

MPN•1
1,4-Dichloro("C,Jnaphthalene
MPN-5
1,4.5-Trichloro("C,Jnaphthalene
MPN-23
1,4.6-Trichloro("C,Jnaphthalene
MPN-24
H H
I I
),3C......_
Cl......._,3e 13( /3C ~ 13C/d
2,3,6,7-Tetrachloro("C,Jnaphthalene
MPN-48
Cl
_)~__
J, ~t,
,3e 11(: d
I
H
I
H
H d
I I
Cl........_,3e 13( ~}C. ~,3e /d
;,3C ......_
1,2,3,6,7-Pentachloro("C,Jnaphthalene
MPN-54
Cl
_)~), ~t,
,3e 11(: a
I
H
I
H
1,2,3,7,8-Pentachloro("C,Jnaphthalene
MPN-56
1,2,4,5,8-Pentachloro("C,Jnaphtha lene
MPN-59
1,2,3,5,6,7-Hexachloro("C,Jnaphthalene
MPN-67
210
MASS-LABELLEDPOLYCHLORINATEDNAPHTHALENES(PCNs)
1,2,3,6,7,8-Hexachloro("C 10)naphthalene
MPN-70
1,2,4,5,7,8-Hexachloro("C 10)naphthalene
MPN-72
1,2,3,4,5,6,7-Heptach loro("C 10)naphthalene

MPN-73
1,2,3,4,5,6,8-Heptach loro("C,Jnaphthalene
MPN-74
Octa ch loro("C 10)na phtha lene

MPN-75
211
NATIVE POLYCHLORINATEDDIPHENYL ETHERS(PCDEs)

DPE-0 Diphenyl ether 1.2 ml 50.0 µg/ml
DPE-3 4-Chlorodiphenyl ether 1.2 ml 50.0 µg/ml
DPE-15 4,4'-Dichlorodiphenyl ether 1.2 ml 50.0 µg/ml
DPE-28 2,4,4'-Trichlorodiphenyl ether 1.2 ml 50.0 µg/ml
DPE-74 2,4,4', 5-Tetrach lorodiphenyl ether 1.2 ml 50.0 µg/ml
DPE-77 3,3' ,4,4'-Tetrachlorodiphenyl ether 1.2 ml 50.0 µg/ml
DPE-99 2,2' ,4,4' ,5-Pentachlorodiphenyl ether 1.2 ml 50.0 µg/ml
DPE-209 Decachlorodiphenyl ether 1.2 ml 50.0 µg/ml
MASS-LABELLEDPOLYCHLORINATEDDIPHENYL ETHERS(PCDEs)
("C,,)Diphenyl ether
MCDE-0
0-a-0 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in nonane
4-Chloro("C,,)diphenyl ether
MCDE-3
Cl
3,4-Dichloro("C,,)diphenyl ether
MCDE-12
0-a-0-a 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in nonane
d
3,4,4'-Trichloro("C 12)d i phenyl ether
MCDE-37
a--0-o-0-cl 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in nonane
d Cl
2,3,4,5-Tetrachloro("C,,)diphenyl ether
MCDE-61
&·*· Cl
a a c1
2,2',3,4,5-Pentachloro("C,,)diphenyl ether
MCDE-86
0-·* Cl
2,2',3,4,5,5'-Hexachloro("C,,)diphenyl ether
MCDE-141
d d d
2,2',3,4,4', 5,5'-Heptach loro("C 12)d i phenyl ether

MCDE-180
·-¢-*
Cl d
212
NATIVE CHLOROBENZENES:SOLUTION/MIXTURE

CBS Native Chlorobenzene Solution/Mixture 1.2 ml
Chlorobenzene 100 µg/ml

1,2-Dichlorobenzene 100 µg/ml
1,2,3-Trichlorobenzene 100 µg/ml
1,2,3,4-Tetrachlorobenzene 100 µg/ml
Pentachlorobenzene 100 µg/ml
Hexachlorobenzene 100 µg/ml
MASS-LABELLEDCHLOROBENZENES:SOLUTION/MIXTURE

MCBS Mass-Labelled Chlorobenzene Solution/Mixture 1.2 ml
Chloro{"C,)benzene 100 µg/ml

1,4-Dichloro{"C,)benzene 100 µg/ml
1,2,3-Trichloro{"C,)benzene 100 µg/ml
1,2,3,4-Tetrachloro{"C,)benzene 100 µg/ml
Pentachloro{"C,)benzene 100 µg/ml
Hexachloro{"C,)benzene 100 µg/ml
MASS-LABELLEDCHLOROBENZENES
MBZ-1235
Cl h" I Cl
1,2,3,5-Tetrachloro{"C,)benzene
1.2 ml; 100 µg/ml {±5.0 µg/ml); in isooctane
Jyc1 1,2,3,4,5-Pentachloro{"C,)benzene
MCBZ-12345
Cl~CI
1.2 ml; 100 µg/ml (±5.0 µg/ml); in isooctane
a
213
NATIVE CHLOROPHENOLS:SOLUTION/MIXTURE

CPS Native Chlorophenol Solution/Mixture 1.2 ml
2-Chlorophenol 100 µg/ml

2,3-Dichlorophenol 100 µg/ml
2,3,4-Trichlorophenol 100 µg/ml
2,3,4,5-Tetrachlorophenol 100 µg/ml
Pentachlorophenol 100 µg/ml
MASS-LABELLEDCHLOROPHENOLS:SOLUTION/MIXTURE

MCPS Mass-Labelled Chlorophenol Solution/Mixture 1.2 ml
4-Chloro("C 6)phenol 100 µg/ml

2,4-Dichloro("C 6)phenol 100 µg/ml
2,4,5-Trichloro("C 6)phenol 100 µg/ml
2,3,4,5-Tetrachloro("C 6)phenol 100 µg/ml
Pentachloro("C 6)phenol 100 µg/ml
214
MASS-LABELLEDCHLOROPHENOLS
Cl~OH Cl 2,4,6-Trichloro("C,)phenol
MCP-246 '¾I
...... 1.2 ml; 100 µg/ml (±5.0 µg/ml); in isooctane
Cl
MCP-345
Cl~CI
Jn 3,4,5-Trichloro("C,)phenol
1.2 ml; 100 µg/ml (±5.0 µg/ml); in isooctane
Cl
Cl*OH Cl Pentachloro("C,)phenol
MCP-23456 '¾I 1.2 ml; 100 µg/ml (±5.0 µg/ml); in isooctane
Cl Cl
Cl
NATIVE MELAMINE AND CYANURICACID
Catalogue Number Product (water solution) Qty/Cone

MEL Melamine 1.2 ml 100 µg/ml
CYA Cyanuric Acid 1.2 ml 100 µg/ml
MASS-LABELLEDMELAMINE

M3-MEL ("(,)Melamine 1.2ml 100µg/ml
MASS-LABELLEDCYANURICACID

M3-CYA ("C,)Cyanuric Acid 1.2ml 100µg/ml
M6-CYA ("C,, "N,)Cyanuric Acid 1.2 ml 100 µg/ml
("C,, "N,)Cyanuric Acid
215
NATIVE BISPHENOL-A

BPA 2, 2-B is(4-hyd roxyphenyl) propane 1.2 ml 50.0 µg/ml
MASS-LABELLEDBISPHENOL-A
2,2-Bis[4-hydroxy-("(.)-phenyl]propane
MBPA 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol;
OH isotopic purity 99% or greater ("C 12-rings)
NATIVE BISPHENOLANALOGUES
~
2,2-Bis(4-hydroxyphenyl)hexafluoropropane
BPAF
'- 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol
~
4,4' -( 1-Phenylethyl idene)bisphenol
BPAP
I 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol
'-
~
2,2-Bis(4-hydroxyphenyl)butane
BPB
'- 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in methanol
4,4'-Dihydroxydiphenylmethane
BPF
4,4'-(1,4-Phenylenediisopropylidene)bisphenol
BPP
Bis(4-hydroxyphenyl) sulfone
BPS
1,1-Bis(4-hydroxyphenyl)cyclohexane
BPZ
216
NATIVE TETRACHLORODIBENZOTHIOPHENES

TCDT-83 2,3, 7,8-Tetrach lorodibenzoth iophene 1.2 ml 50.0 µg/ml
TCDT-85 2,4,6,8-Tetrach lorodibenzoth iophene 1.2 ml 50.0 µg/ml
MASS-LABELLEDTETRACHLORODIBENZOTHIOPHENE
Cl Cl
2,4,6,8-Tetrachloro("C,,)dibenzothiophene
MTCDT-85 1.2 ml; 50.0 µg/ml (±2.5 µg/ml); in toluene;
Cl Cl isotopic purity 99% or greater
NATIVE CHLORINATEDCARBAZOLES
CCZ-3 3-Ch loro-9H-carbazole 1.2 ml 50.0 µg/ml

CCZ-36 3, 6-D ich loro-9H-ca rbazole 1.2 ml 50.0 µg/ml
CCZ-1368 1,3,6,8-Tetrach loro-9H-carbazole 1.2 ml 50.0 µg/ml
CCZ-2367 2,3,6, 7-Tetrach loro-9H-carbazole 1.2 ml 50.0 µg/ml
NATIVE BROMINATED CARBAZOLES

BCZ-3 3-B romo-9 H-ca rbazo le 1.2 ml 50.0 µg/ml
BCZ-27 2, 7-Dibromo-9H-carbazole 1.2 ml 50.0 µg/ml
BCZ-36 3, 6-D i bromo-9 H-ca rbazol e 1.2 ml 50.0 µg/ml
BCZ-136 1,3,6-Tri bromo-9H-carbazole 1.2 ml 50.0 µg/ml
BCZ-1368 1,3,6,8-Tetrabromo-9H-carbazole 1.2 ml 50.0 µg/ml
NATIVE BROMO/CHLORO CARBAZOLES

1·B·36·CCZ 1-Bromo-3,6-d ich loro-9H-carbazole 1.2 ml 50.0 µg/ml
18-B-36-CCZ 1,8-Dibromo-3,6-dich loro-9H-carbazole 1.2 ml 50.0 µg/ml
217
NATIVE HALOGENATEDCARBAZOLES:SOLUTION/MIXTURE

CBCZ-MXB Native Halogenated Carbazoles Solution/Mixture 1.2 ml
3-Chloro-9H-carbazole CCZ-3 2.50 µg/ml

3,6-Dichloro-9H-carbazole CCZ-36 2.50 µg/ml
1,3,6,8-Tetrachloro-9H-carbazole CCZ-1368 2.50 µg/ml
2,3,6,7-Tetrachloro-9H-carbazole CCZ-2367 2.50 µg/ml
3-Bromo-9H-carbazole BCZ-3 2.50 µg/ml
2,7-Dibromo-9H-carbazole BCZ-27 2.50 µg/ml
3,6-Dibromo-9H-carbazole BCZ-36 2.50 µg/ml
1,3,6-Tribromo-9H-carbazole BCZ-136 2.50 µg/ml
1,3,6,8-Tetrabromo-9H-carbazole BCZ-1368 2.50 µg/ml
1-Bromo-3, 6-d ich loro-9 H-ca rbazo le 1-8-36-CCZ 2.50 µg/ml
1,8-Di b romo-3, 6-d ich loro-9H-ca rbazol e 18-8-36-CCZ 2.50 µg/ml
MASS-LABELLEDCHLORINATEDCARBAZOLES
Cl Cl
~
I 3,6-Dichloro-9H-{"C,,)carbazole
MCCZ-36 13Ce
~
Cl Cl
~
13Ce I 1,3,6,8-Tetrachloro-9H-{"C,,)carbazole
MCCZ-1368 ~
Cl Cl
General Structure and

Numbering System for Carbazoles
218

219
APPENDIX
Some of the information provided in this Appendix can also be found in our Reference and
Handling Guide: GC/MS Characterization and Analysis of Selected Halogenated Aromatic
Compounds, which is available separately in hard copy and is also posted on our website. On the
following pages you will find:
Guidelines for the Use and Handling of Wellington Products

General Structure and Numbering System of Selected Aromatic Hydrocarbons
Number of Possible Isomers for Selected Halogenated Aromatic Compounds
Molecular Weights for Selected Chlorinated and Brominated Aromatic Hydrocarbons
Exact Mass & Relative Ion Abundance of Selected Chlorinated Aromatic Hydrocarbons
Molecular Ion Clusters for Chlorinated Aromatic Hydrocarbons & Brominated Aromatic
Hydrocarbons
Exact Mass & Relative Ion Abundance of Selected Brominated Aromatic Hydrocarbons
Systematic Numbering of Chlorinated Dibenzo-p-dioxins, Chlorinated Dibenzofurans,
Chlorinated Biphenyls, and Chlorinated Naphthalenes
We also have a Reference and Handling Guide for Perfluoroalkyl Compounds, which can be
downloaded from our website, and a Quick Reference Guide for Perfluoroalkyl Compounds,
available in hard copy.
If you would like to receive copies of either Reference Guide, please contact us or one of our
distributors. In addition, if you have suggestions for future guides, please contact us.
GUIDELINES FOR THE USE AND HANDLING OF WELLINGTON PRODUCTS
HAZARDS
Themajorityof our productsare halogenatedaromatichydrocarbons in solutionin organicsolvents
suchas nonane,tolueneand isooctane.Althoughthe maximumconcentrationis 100µg/ml, that is
0.01% (w/v),thesecompoundsmustbe considered toxic and potentiallycarcinogenicand shouldbe
handledaccordingly.
With all of our productsduecareshouldbe exercisedto preventhumancontactand ingestion.The

absenceof a toxicitywarningfor anyof our productsmustnot be interpretedas an indicationthat
thereis no possiblehealthhazard.
NOTE:
THESEMATERIALSSHOULDONLYBEUSEDBY
PERSONNELTRAINEDIN THEHANDLINGOF
HAZARDOUSCHEMICALS.
ALL PROCEDURESSHOULDBEPERFORMED IN
A FUMEHOODAND SUITABLE GLOVES,EYE
PROTECTIONAND CLOTHINGSHOULDBE
WORNAT ALLTIMES.
RECEIPT,
INSPECTION,HANDLINGAND STORAGE
Unlesscrystallinematerialis provided,all of our referencestandardsolutionscomein flame-sealed,
pre-scored amberglassampoules.Uponreceipt,inspectthe ampoulesfor breakageand leakage,and
then storethem uprightuntil needed.Theampoulescanbe storedat ambienttemperatureuntil
openedunlessotherstoragerequirements are statedon the Certificateof Analysis.
Priorto opening,allow the solutionto drain into the bottomof the ampoule,lightlytappingthe
ampouleif necessary.Usingthe plasticampoulecollarprovided,holdthe ampouleuprightandsnap
the top off, breakingawayfrom the body.
Transferthe solutionto an amberglasscontainerthat canbe tightly sealedfor storage.Toprevent

evaporationof the solvent,it is suggestedthat this solution,andsubsequent
mixturesand/or
dilutions,be storedat refrigeratortemperatures.
222
GUIDELINES FOR THE USE AND HANDLING OF WELLINGTON PRODUCTS
DISPOSAL
All wastematerialsgeneratedduringthe useof thesesolutionsshouldbe treatedas hazardousin
accordance with nationaland regionalregulations.A licenseddisposalcompanyshouldbe employed.
Someoptionsfor the destructionof thesematerialsincludehightemperatureincineration,photolysis,or
chemicaltreatmentusingreagentssuchas sodiumnaphthaleneor KPEGreagent. Literaturereferences
for someof thesemethodscan be provideduponrequest.
ACCURACY
All of our stocksolutionsare preparedfrom crystallinematerialthat hasbeenwell characterized
as to
its structureand purity.
Thecrystallinematerialis weighedusingmicrobalances whosecalibrationis verifiedusingexternal

weightstraceableto an ISO/IEC 17025accreditedlaboratory.Solutionsare preparedby completely
dissolvingthe crystallinematerialin ultrapure,distilled-in-glass
solvents.Thevolumetricflasksand
pipetsusedfor individualstocksolutionpreparationand subsequentmixturesand/ordilutionsare all of
ClassA toleranceand calibratedand traceableto an ISO/IEC 17025accreditedlaboratory.
Themaximumpercentrelativecombineduncertaintyfor solutionpreparationis calculatedto be ±5%.
INTERLABORATORY CERTIFICATION
Wellingtoncontinuesto submitits standardsfor independentinterlaboratorytestingand certification.
Since1991,our standardshavebeentestedover30 internationalround-robins.
Todate,solutionsof the compoundslistedbelowhavebeenrepeatedlytestedandthe approximate

total numberof analysesare given.
• 2,3,7,8-substitutedPCDDs and PCDFs ......................................

1750HRMSanalyses
• Dioxin-like(WHO)PCBcongeners ............................................
1200HRMSanalyses
• PBDEs .........................................................................................
350 HRMSanalyses
• PFCs............................................................................................
350 LCMSanalyses
Theoverallaveragesof the data receivedfor all of the compoundswerefoundto be well within ± 10%
of the designvalues.
EXPIRYDATE/SHELF LIFE
In orderto accuratelydeterminethe shelflife of productssuchas ours,testingmustrevealsignificant
degradationor lossin concentrationof the particularanalyte. In comparingfreshlypreparedsolutions
to oldersolutionsby GC/MSor LC/MS, we havenot detectedany significantchanges.Manyof these
oldersolutionswere preparedand ampouledmorethan 15 yearsago. Thusour stabilitystudies,as they
should,remainongoing.
Forour productswherethe expirydateon the CofAstates,"stability studiesongoing",we considerthat

our referencestandardsolutionsretaintheir accuracyfor a periodof 5 yearsfrom deliveryin the
unopenedampoule.
NOTE:Thepredominantdegradationpathwayfor our compoundsis likelyphotolysisandthus protection

from light is critical.
223
GENERALSTRUCTUREAND NUMBERINGSYSTEMOF SELECTEDAROMATIC HYDROCARBONS
OH
1 8 1
~ I ~ ~
602 70)~2
6612
5 ~ 3 5 3 6 I 3
4 4 5 4
phenol benzene naphthalene
[ oXJ'
[, 9 1
s(X'
7 ~ ~ 3 3
2
0 0
6 4 6 4
dibenzo-p-dioxin dibenzofuran
3' 2' 2 3 3' 2' 2 3
•·O-o-0•
5' 6' 6 5 5' 6' 6 5
OH
diphenyl ether 4-hydroxybiphenyl
3' 2' 2 3 5 4
6 3
2
5' 6' 6 5 N
8 H 1
biphenyl carbazole
3 11
2 11 3' 2' 2 3
p-terphenyl
311 411
5' 6' 6 5 5' 6' 6 5
m-terphenyl o-terphenyl
224
NUMBER OF POSSIBLEISOMERS FOR SELECTEDHALOGENATEDAROMATIC COMPOUNDS
.s
~
- ;; C
f! ~
.s ~ ,i: .!!!
~ a,
t 11
! 'E
117
#of X Terphenyl §
-c
3- 3-
a,
-c §
:9
C)
:9
C) ~
-c
ff l
,: ~
0
§
ortho meta para
1 5 6 4 3 19 2 4 2 1 3
2 28 28 21 12 64 10 16 10 3 6
3 80 87 55 24 136 14 28 14 3 6
4 211 211 139 42 198 22 38 22 3 3
5 355 382 226 46 198 14 28 14
6 544 544 351 42 136 10 16 10
7 596 638 358 24 64 2 4 2
8 544 544 351 12 19
9 355 382 226 3 3
10 211 211 139
11 80 87 55
12 28 28 21
13 5 6 4
14
X = Halogen (does not apply to mixed halogenated compounds)
For diphenyl ethers use the biphenyl values
MOLECULAR WEIGHTS FOR SELECTED CHLORINATED AND BROMINATED AROMATIC HYDROCARBONS
# of
PCTs PCBs PCDEs PCDDs PCDFs PCNs CBs CPs PBBs PBDEs PBDDs PBDFs
Cl/Br
0 230.31 154.21 170.21 184.19 168.19 128.17 78.11 94.11 154.21 170.21 184.19 168.19
264.75 188.66 204.66 218.64 202.64 162.62 112.56 128.56 233.11 249.11 263.09 247.09
2 299.20 223.10 239.10 253.08 237.09 197.06 147.00 163.00 312.00 328.00 341.99 325.99
3 333.64 257.55 273.55 287.53 271.53 231.51 181.45 197.45 390.90 406.90 420.88 404.88
4 368.09 291.99 307.99 321.97 305.98 265.95 215.89 231.89 469.80 485.80 499.78 483.78
5 402.53 326.44 342.44 356.42 340.42 300.40 250.34 266.34 548.69 564.69 578.67 562.68
6 436.98 360.88 376.88 390.86 374.87 334.84 284.78 627.59 643.59 657.57 641.57
7 471.42 395.33 411.33 425.31 409.31 369.29 706.48 722.48 736.47 720.47
8 505.87 429.77 445.77 459.75 443.76 403.73 785.38 801.38 815.36 799.36
9 540.31 464.22 480.22 864.28 880.28
10 574.76 498.66 514.66 943.17 959.17
11 609.20
12 643.65
13 678.09
14 712.54
Note: The molecular weight for PCHBs (C12 H9 • 0 Cl0 OH) is the same as the PCDEs(C12 H,..0 ClnO), but the maximum # of Chlorines
is one lessfor the PCHBs.
= = =
PCTs polychlorinated terphenyls, PCBs polychlorinated biphenyls, PCDEs polychlorinated diphenyl ethers
= =
PCHBs polychlorinated hydroxybiphenyls (biphenylols), PCDDs polychlorinated dibenzo-p-dioxins,
= = =
PCDFs polychlorinated dibenzofurans, PCNs polychlorinated naphthalenes, CBs chlorobenzenes, CPs chlorophenols, =
= =
PBBs polybrominated biphenyls, PBDEs polybrominated diphenyl ethers,
= =
PBDDs polybrominated dibenzo-p-dioxins, PBDFs polybrominated dibenzofurans
225
EXACT MASS & RELATIVE ION ABUNDANCE OF SELECTEDCHLORINATED AROMATIC HYDROCARBONS
PCTs PCBs PCHBs PCDDs

12C1a C1aH14-nCln13C1a 12<:12 C12H10-nCln 13(12 12c12 C12H9-
0 Cl0 OH 13(12 12c,2 C12H
... c1.o, 13C12
#of Exact Relative Exact Exact Relative Exact Exact Relative Exact Exact Relative Exact
Cl Mass Abundance Mass Mass Abundance Mass Mass Abundance Mass Mass Abundance Mass
0 230.1096 100 248.1699 154.0783 100 166.1185 170.0732 100 182.1134 184.0524 100 196.0927
264.0706 100 282.1310 188.0393 100 200.0795 204.0342 100 216.0745 218.0135 100 230.0537
266.0676 34.4 284.1280 190.0363 33.2 202.0766 206.0312 33.5 218.0715 220.0105 33.7 232.0508
2 298.0316 100 316.0920 222.0003 100 234.0406 237.9952 100 250.0355 251.9745 100 264.0147
300.0287 66.8 318.0890 223.9974 65.6 236.0376 239.9923 65.9 252.0325 253.9715 66.1 266.0118
302.0257 11.8 320.0861 225.9944 11.0 238.0347 241.9893 11.2 254.0296 255.9686 11.3 268.0088
3 331.9926 100 350.0530 255.9613 100 268.0016 271.9562 100 283.9965 285.9355 100 297.9758
333.9897 99.2 352.0501 257.9584 98.0 269.9986 273.9533 98.2 285.9936 287.9326 98.5 299.9728
335.9867 33.4 354.0471 259.9554 32.3 271.9957 275.9503 32.5 287.9906 289.9296 32.7 301.9699
337.9838 4.0 356.0442 261.9525 3.7 273.9927 277.9474 3.7 289.9877 291.9267 3.8 303.9669
4 365.9537 76.0 384.0141 289.9224 76.7 301.9626 305.9173 76.5 317.9575 319.8965 76.4 331.9368
367.9507 100 386.0111 291.9194 100 303.9597 307.9143 100 319.9546 321.8936 100 333.9339
369.9478 49.8 388.0082 293.9165 49.1 305.9567 309.9114 49.3 321.9516 323.8906 49.4 335.9309
371.9448 11.3 390.0052 295.9135 10.8 307.9538 311.9084 10.9 323.9487 325.8877 11.0 337.9280
399.9147 61.0 417.9751 323.8834 61.4 335.9237 339.8783 61.3 351.9186 353.8576 61.3 365.8978
401.9117 100 419.9721 325.8804 100 337.9207 341.8754 100 353.9156 355.8546 100 367.8949
403.9088 66.0 421.9692 327.8775 65.3 339.9178 343.8724 65.4 355.9127 357.8517 65.5 369.8919
405.9058 22.0 423.9662 329.8745 21.4 341.9148 345.8695 21.5 357.9097 359.8487 21.6 371.8890
6 433.8757 50.9 451.9361 357.8444 51.2 369.8847 373.8393 51.2 385.8796 387.8186 51.1 399.8589
435.8728 100 453.9332 359.8415 100 371.8817 375.8364 100 387.8766 389.8156 100 401.8559
437.8698 82.1 455.9302 361.8385 81.5 373.8788 377.8334 81.6 389.8737 391.8127 81.7 403.8530
439.8669 36.2 457.9273 363.8356 35.5 375.8758 379.8305 35.6 391.8707 393.8097 35.8 405.8500
467.8367 43.7 485.8971 391.8054 43.9 403.8457 407.8004 43.9 419.8406 421.7796 43.9 433.8199
469.8338 100 487.8942 393.8025 100 405.8428 409.7974 100 421.8377 423.7767 100 435.8169
471.8308 98.3 489.8912 395.7995 97.7 407.8398 411.7945 97.8 423.8347 425.7737 97.9 437.8140
473.8279 53.9 491.8883 397.7966 53.1 409.8369 413.7915 53.3 425.8318 427.7708 53.4 439.8110
475.8249 17.9 493.8853 399.7936 17.4 411.8339 415.7886 17.5 427.8288 429.7678 17.6 441.8081
8 501.7978 33.5 519.8582 425.7665 33.8 437.8067 441.7614 33.7 453.8016 455.7407 33.7 467.7809
503.7948 87.4 521.8552 427.7635 87.8 439.8038 443.7584 87.7 455.7987 457.7377 87.6 469.7780
505.7919 100 523.8523 429.7606 100 441.8008 445.7555 100 457.7957 459.7348 100 471.7750
507.7889 65.6 525.8493 431.7576 65.2 443.7979 447.7525 65.2 459.7928 461.7318 65.3 473.7721
509.7860 27.0 527.8464 433.7547 26.6 445.7949 449.7496 26.7 461.7898 463.7289 26.8 475.7691
9 535.7588 26.1 553.8192 459.7275 26.3 471.7678 475.7224 26.3 487.7627
537.7559 76.5 555.8162 461.7246 76.9 473.7648 477.7195 76.8 489.7597
539.7529 100 557.8133 463.7216 100 475.7619 479.7165 100 491.7568
541.7500 76.4 559.8103 465.7187 75.9 477.7589 481.7136 76.0 493.7538
543.7470 37.6 561.8074 467.7157 37.1 479.7560 483.7106 37.2 495.7509
10 569.7198 20.9 587.7802 493.6885 21.1 505.7288
571.7169 68.1 589.7773 495.6856 68.4 507.7258
573.7139 100 591.7743 497.6826 100 509.7229
575.7110 87.2 593.7714 499.6797 86.7 511.7199
577.7080 50.0 595.7684 501.6767 49.4 513.7170
11 603.6809 17.1 621.7412
605.6779 61.3 623.7383
607.6750 100 625.7353
609.6720 98.0 627.7324
611.6691 64.1 629.7294
613.6661 29.4 631.7265
12 637.6419 13.1 655.7023
639.6389 51.3 657.6993
641.6360 92.0 659.6964
643.6330 100 661.6934
645.6301 73.5 663.6905
647.6271 38.5 665.6875
13 671.6029 10.1 689.6633
673.6000 42.8 691.6604
675.5970 83.7 693.6574
677.5941 100 695.6545
679.5911 81.6 697.6515
681.5882 48.0 699.6486
14 705.5639 8.0 723.6243
707.5610 36.3 725.6214
709.5580 76.7 727.6184
711.5551 100 729.6155
713.5521 89.7 731.6125
715.5492 58.6 733.6096
226
EXACT MASS & RELATIVE ION ABUNDANCE OF SELECTEDCHLORINATED AROMATIC HYDROCARBONS
PCDFs PCNs CBs CPs

12(12 c,,H...,Cl.o 13(12 12C10 C,oHs-nCln 13C10 ''C. C.H...,Cln "C. 12(6 C.H,.. CI.OH "C.
Cl Mass Abundance Mass Mass Abundance Mass Mass Abundance Mass Mass Abundance Mass
0 168,0575 100 180,0978 128,0626 100 138,0962 78,0470 100 84,0671 94.0419 100 100,0620
202,0185 100 214,0588 162,0236 100 172,0572 112.0080 100 118,0281 128,0029 100 134,0230
204,0156 33.5 216,0559 164,0207 33,0 174,0542 114,0050 32,6 120,0252 129,9999 32,8 136,0201
235,9796 100 248,0198 195,9847 100 206,0182 145,9690 100 151,9891 161,9639 100 167,9841
237,9766 65,8 250,0169 197,9817 65.4 208,0153 147,9661 65,0 153,9862 163,9610 65,2 169,9811
239.9737 11.2 252.0139 199.9788 10.9 210.0123 149.9631 10.6 155.9832 165.9580 10.8 171.9782
3 269,9406 100 281.9809 229,9457 100 239,9792 179,9300 100 185,9502 195,9249 100 201.9451
271.9376 98,2 283,9779 231,9427 97,8 241.9763 181.9271 97.4 187,9472 197,9220 97,6 203,9421
273,9347 32.5 285,9750 233,9398 32,0 243,9733 183,9241 31,7 189,9443 199,9190 31,9 205,9392
275,9317 3,7 287,9720 235,9368 3,6 245,9704 185,9212 3.5 191.9413 201.9161 3.5 207,9362
4 303,9016 76.5 315,9419 263,9067 76,8 273,9403 213,8911 77.1 219,9112 229,8860 76,9 235,9061
305,8987 100 317,9389 265,9038 100 275,9373 215,8881 100 221.9082 231,8830 100 237,9032
307,8957 49,2 319,9360 267,9008 49,0 277.9344 217,8852 48,7 223,9053 233,8801 48,8 239,9002
309,8928 10,9 321.9330 269,8979 10,7 279,9314 219,8822 10,6 225,9023 235,8771 10,7 241,8973
337.8627 61.3 349.9029 297.8677 61.5 307.9013 247.8521 61.7 253.8722 263.8470 61.6 269.8671
339,8597 100 351.9000 299,8648 100 309,8983 249,8491 100 255,8693 265,8441 100 271,8642
341,8568 65.4 353,8970 301.8618 65,1 311.8954 251.8462 64,9 257,8663 267,8411 65,0 273,8612
343,8538 21.5 355,8941 303,8589 21.3 313,8924 253,8432 21.1 259,8634 269,8382 21.2 275,8583
6 371,8237 51.2 383,8639 331,8288 51.3 341,8623 281,8131 51,4 287,8332
373,8207 100 385,8610 333,8258 100 343,8594 283,8102 100 289,8303
375.8178 81.6 387.8580 335.8229 81.3 345.8564 285.8072 81.1 291.8273
377.8148 35,6 389,8551 337,8199 35.3 347,8535 287,8043 35,1 293,8244
405,7847 43,9 417,8250 365,7898 44,0 375,8233
407.7818 100 419,8220 367.7868 100 377.8204
409,7788 97,8 421.8191 369.7839 97.5 379,8174
411.7759 53.3 423,8161 371.7809 52,9 381,8145
413.7729 17.5 425.8132 373.7780 17.3 383.8115
8 439,7457 33,7 451.7860 399,7508 33,9 409,7844
441,7428 87,7 453,7830 401.7479 87,9 411.7814
443.7398 100 455,7801 403.7449 100 413.7785
445.7369 65,2 457,7771 405.7420 65,0 415,7755
447.7339 26,7 459,7742 407.7390 26.5 417,7726
PCTs = polychlorinated
terphenyls
PCBs = polychlorinated
biphenyls
PCHBs = polychlorinated
hydroxybiphenyls
PCDDs = polychlorinated
dibenzo-p-dioxins
PCDFs = polychlorinated
dibenzofurans
PCNs = polychlorinated
naphthalenes
CBs = chlorobenzenes
CPs = chlorophenols
Accuratemasses:
12C=12.000000,
"C=13.003355,'H=1.007825,"Cl= 34.968853,"Cl=36.965903,"0=15.994915
Relativeabundances of isotopesweredeterminedusingthe methoddescribedin: Pretsch,Clerc,Seibl,Simon,

Tablesof SpectralDatafor StructureDetermination
of OrganicCompounds, Springer-Verlag,
1983.
Thefollowingnaturalisotopicabundances wereusedin all calculations:
"C=98.89%,"C=1.11%, 'H=99.985%,'H=0.015%,
"Cl=75.53%,"Cl=24.47%,"0=99.759%,170=0.037%,"0=0.204%,
227
MOLECULARION CLUSTERSFOR CHLORINATEDAROMATIC HYDROCARBONS
100
90
80
Cl)
70
u
C:
l'tl
"C 60
C:
::,
.0
<( 50
Cl)
>
·,.:;
l'tl 40
ai
er:
30
20
10
0
0 2 3 4 5 6 7
Number of Chlorines
MOLECULARION CLUSTERSFOR CHLORINATEDAROMATIC HYDROCARBONS
100
90
80
Cl) 70
u
C:
l'tl
"C 60
C:
::,
.0
<( 50
Cl)
>
·,.:;
l'tl 40
ai
er:
30
20
10
0
8 9 10 11 12 13 14
Number of Chlorines
Ions shown are M, M+1, M+2, M+3, M+4, M+S, M+6, M+7, M+S, M+9, M+10, M+11, M+12, and are
representative of chlorinated terphenyls (C18H14_nCIn)
228
MOLECULAR ION CLUSTERS FOR BROMINATED AROMATIC HYDROCARBONS
100
90
80
70
QI
u
C
rtJ
-0 60
C
::,
..0
<( 50
QI
>
·.;::;
rtJ 40
ai
a::
30
20
10
0
0 2 3 4 5
Number of Bromines
MOLECULAR ION CLUSTERS FOR BROMINATED AROMATIC HYDROCARBONS
100
90
80
QI 70
u
C
rtJ
-0 60
C
::,
..0
<( 50
QI
>
·.;::;
rtJ 40
ai
a::
30
20
10
0
6 7 8 9 10
Number of Bromines
Ions shown are M, M+1, M+2, M+3, M+4, M+S, M+6, M+7, M+S, M+9, M+10, M+11, M+12, M+13, M+14
and are representative of brominated diphenyl ethers (C12H10_nBrnO)
229
EXACT MASS & RELATIVE ION ABUNDANCE OF SELECTEDBROMINATED AROMATIC HYDROCARBONS
PBBs PBDEs PBDDs PBDFs

12(12 C12H10-nBrn 13(12 12(12 C12H10-nBrnO
13(12 12(12 C12Hs-.,Br,02 13(12 12(12 C12Ha-nBrnO 13(12
Br Mass Abundance Mass Mass Abundance Mass Mass Abundance Mass Mass Abundance Mass
0 154.0783 100 166.1185 170.0732 100 182.1134 184.0524 100 196.0927 168.0575 100 180.0978
231.9887 100 244.0290 247.9836 100 260.0239 261.9629 100 274.0032 245.9680 100 258.0083
233.9867 98.7 246.0270 249.9816 98.9 262.0219 263.9609 99.1 276.0012 247.9660 98.9 260.0063
309.8992 50.9 321.9395 325.8941 50.8 337.9344 339.8734 50.8 351.9136 323.8785 50.8 335.9187
311.8972 100 323.9375 327.8921 100 339.9324 341.8714 100 353.9116 325.8765 100 337.9167
313.8952 49.6 325.9355 329.8901 49.7 341.9304 343.8694 49.9 355.9096 327.8745 49.7 339.9147
387.8097 34.0 399.8499 403.8046 33.9 415.8449 417.7839 33.9 429.8241 401.7889 33.9 413.8292
389.8077 100 401.8479 405.8026 100 417.8429 419.7819 100 431.8221 403.7869 100 415.8272
391.8057 98.4 403.8459 407.8006 98.6 419.8409 421.7799 98.7 433.8201 405.7849 98.6 417.8252
393.8037 32.7 405.8439 409.7986 32.8 421.8389 423.7779 33.0 435.8181 407.7829 32.8 419.8232
4 465.7202 17.3 477.7604 481.7151 17.3 493.7553 495.6943 17.3 507.7346 479.6994 17.3 491.7397
467.7182 67.9 479.7584 483.7131 67.8 495.7533 497.6923 67.8 509.7326 481.6974 67.8 493.7377
469.7162 100 481.7564 485.7111 100 497.7513 499.6903 100 511.7306 483.6954 100 495.7357
471.7142 65.7 483.7544 487.7091 65.8 499.7493 501.6883 65.9 513.7286 485.6934 65.8 497.7337
473.7122 16.4 485.7524 489.7071 16.5 501.7473 503.6863 16.6 515.7266 487.6914 16.5 499.7317
543.6306 10.4 555.6709 559.6255 10.4 571.6658 573.6048 10.4 585.6451 557.6099 10.4 569.6502
545.6286 51.0 557.6689 561.6235 50.9 573.6638 575.6028 50.9 587.6431 559.6079 50.9 571.6482
547.6266 100 559.6669 563.6215 100 575.6618 577.6008 100 589.6411 561.6059 100 573.6462
549.6246 98.3 561.6649 565.6195 98.4 577.6598 579.5988 98.5 591.6391 563.6039 98.4 575.6442
551.6226 48.5 563.6629 567.6175 48.7 579.6578 581.5968 48.8 593.6371 565.6019 48.7 577.6422
553.6206 9.7 565.6609 569.6155 9.8 581.6558 583.5948 9.9 595.6351 567.5999 9.8 579.6402
6 621.5411 5.3 633.5814 637.5360 5.3 649.5763 651.5153 5.3 663.5555 635.5204 5.3 647.5606
623.5391 31.2 635.5794 639.5340 31.1 651.5743 653.5133 31.1 665.5535 637.5184 31.1 649.5586
625.5371 76.4 637.5774 641.5320 76.4 653.5723 655.5113 76.3 667.5515 639.5164 76.4 651.5566
627.5351 100 639.5754 643.5300 100 655.5703 657.5093 100 669.5495 641.5144 100 653.5546
629.5331 73.8 641.5734 645.5280 73.9 657.5683 659.5073 73.9 671.5475 643.5124 73.9 655.5526
631.5311 29.2 643.5714 647.5260 29.3 659.5663 661.5053 29.4 673.5455 645.5104 29.3 657.5506
7 699.4516 3.0 711.4918 715.4465 3.0 727.4868 729.4258 3.0 741.4660 713.4308 3.0 725.4711
701.4496 20.8 713.4898 717.4445 20.8 729.4848 731.4238 20.8 743.4640 715.4288 20.8 727.4691
703.4476 61.2 715.4878 719.4425 61.1 731.4828 733.4218 61.1 745.4620 717.4268 61.1 729.4671
705.4456 100 717.4858 721.4405 100 733.4808 735.4198 100 747.4600 719.4248 100 731.4651
707.4436 98.2 719.4838 723.4385 98.3 735.4788 737.4178 98.4 749.4580 721.4228 98.3 733.4631
709.4416 58.0 721.4818 725.4365 58.1 737.4768 739.4158 58.2 751.4560 723.4208 58.1 735.4611
8 777.3621 1.5 789.4023 793.3570 1.5 805.3972 807.3362 1.5 819.3765 791.3413 1.5 803.3816
779.3601 12.1 791.4003 795.3550 12.1 807.3952 809.3342 12.1 821.3745 793.3393 12.1 805.3796
781.3581 41.6 793.3983 797.3530 41.5 809.3932 811.3322 41.5 823.3725 795.3373 41.5 807.3776
783.3561 81.5 795.3963 799.3510 81.5 811.3912 813.3302 81.4 825.3705 797.3353 81.5 809.3756
785.3541 100 797.3943 801.3490 100 813.3892 815.3282 100 827.3685 799.3333 100 811.3736
787.3521 78.6 799.3923 803.3470 78.7 815.3872 817.3262 78.7 829.3665 801.3313 78.7 813.3716
789.3501 38.7 801.3903 805.3450 38.8 817.3852 819.3242 38.9 831.3645 803.3293 38.8 815.3696
9 855.2725 0.9 867.3128 871.2674 0.9 883.3077
857.2705 7.6 869.3108 873.2654 7.6 885.3057
859.2685 29.7 871.3088 875.2634 29.7 887.3037
861.2665 68.0 873.3068 877.2614 68.0 889.3017
863.2645 100 875.3048 879.2594 100 891.2997
865.2625 98.1 877.3028 881.2574 98.2 893.2977
867.2605 64.3 879.3008 883.2554 64.4 895.2957
869.2585 27.2 881.2988 885.2534 27.3 897.2937
10 933.1830 0.4 945.2233 949.1779 0.4 961.2182
935.1810 4.3 947.2213 951.1759 4.3 963.2162
937.1790 19.0 949.2193 953.1739 18.9 965.2142
939.1770 49.5 951.2173 955.1719 49.5 967.2122
941.1750 85.0 953.2153 957.1699 84.9 969.2102
943.1730 100 955.2133 959.1679 100 971.2082
945.1710 81.8 957.2113 961.1659 81.9 973.2062
947.1690 46.0 959.2093 963.1639 46.0 975.2042
949.1670 17.0 961.2073 965.1619 17.1 977.2022
PBBs = polybrominated
biphenyls
PBDEs = polybrominated
dighenylethers
PBDDs = polybrominated
di enzo-p-dioxins
PBDFs = polybrominated
dibenzofurans
Accuratemasses:
"(=12.000000,"(=13.003355,'H=1.007825,798r= 78.918300,
"Br=80.916300,"0=15.994915
Relativeabundances of isotopesweredeterminedusingthe methoddescribedin: Pretsch,Clerc,Seibl,Simon,

Tablesof SpectralDatafor StructureDetermination
of OrganicCompounds, Springer-Verlag,
1983.
Thefollowingnaturalisotopicabundances wereusedin all calculations:
"(=98.89%, "(=1.11 %, 'H=99.985%,'H=0.015%,
79Br=50.54%,"Br=49.46%,"0=99.759%,"0=0.037%,"0=0.204%.
Note:ID numbersfor PBBsand PBDEs

areanalogousto the IUPACnumberingsystemdevelopedfor PCBs.
230
SYSTEMATIC NUMBERING OF CHLORINATED DIBENZO-p-DIOXINS
ID Number* Congener CAS Number

1-Chlorodibenzo-p-dioxin 39227-53-7
2 2-Ch lorodibenzo-p-dioxi n 39227-54-8
3 1,2-Dich lorodibenzo-p-dioxi n 54536-18-4

7 1,7-Dichlorodibenzo-p-dioxin 82291-26-7
10 2, 3-D ich lo rod i be nzo-p-d i oxi n 29446-15-9
11 2, 7-Dichlorodibenzo-p-dioxin 33857-26-0
12 2, 8-D ich lo rod i be nzo-p-d i oxi n 38964-22-6
13 1,2,3-Trich lorodibenzo-p-dioxin 54536-17-3

16 1,2, 7-Trich lorodibenzo-p-dioxin 82291-30-3
25 1,7,8-Trichlorodibenzo-p-dioxin 82306-65-8
27 1,2,3,4-Tetrach lorodibenzo-p-dioxi n 30746-58-8

28 1,2,3,6-Tetrach lorodibenzo-p-dioxin 71669-25-5
29 1,2,3, 7-Tetrachlorodibenzo-p-dioxin 67028-18-6
31 1,2,3, 9-Tetrach lorodibenzo-p-dioxin 71669-26-6
* Ballschmiter et. al. 9 1
8 2
7
6 4
231


39 1,2, 7,8-Tetrach lorodibenzo-p-dioxi n 34816-53-0
40 1,2, 7, 9-Tetrach lorodibenzo-p-dioxi n 71669-23-3

41 1,2,8, 9-Tetrach lorodibenzo-p-dioxi n 62470-54-6
42 1,3,6,8-Tetrach lorodibenzo-p-dioxin 33423-92-6

45 1,3, 7, 9-Tetrach lorodibenzo-p-dioxin 62470-53-5

48 2,3, 7,8-Tetrach lorodibenzo-p-dioxin 1746-01-6
49 1,2,3,4,6-Pentachlorod i benzo-p-d ioxin 67028-19-7

50 1,2,3,4, 7-Pentachlorod i benzo-p-d ioxin 39227-61-7

54 1,2,3, 7,8-Pentachlorodibenzo-p-dioxin 40321-76-4



63 1,2,3,4,6, 7-Hexach lorodibenzo-p-dioxin 58200-66-1

64 1,2,3,4,6,8-Hexach lorodibenzo-p-dioxin 58200-67-2

8 2
7 3
6 4
232

66 1,2,3,4, 7,8-Hexach lorodibenzo-p-dioxin 39227-28-6
67 1,2,3,6, 7,8-Hexach lorodibenzo-p-dioxin 57653-85-7
68 1,2,3,6, 7, 9-Hexach lorodibenzo-p-dioxin 64461-98-9
70 1,2,3, 7,8, 9-Hexach lorodibenzo-p-dioxin 19408-74-3
71 1,2,4,6, 7, 9-Hexach lorodibenzo-p-dioxin 39227-62-8
73 1,2,3,4,6, 7,8-Heptach lorodibenzo-p-dioxin 35822-46-9

74 1,2,3,4,6, 7, 9-Heptach lorodibenzo-p-dioxin 58200-70-7
75 Octachlorod i benzo-p-d ioxi n 3268-87-9

* Ballschmiter et. al. 9
8 2
7
6 4
SYSTEMATIC NUMBERING OF CHLORINATED DIBENZOFURANS

1-Chlorodibenzofuran 84761-86-4
2 2-Ch lorodibenzofu ran 51230-49-0
5 1,2-Dich lorodibenzofu ran 64126-85-8

9 1,7-Dichlorodibenzofuran 94538-02-0
* Ballschmiter et. al.
9 1
8 2
7 3
6 4
233
SYSTEMATICNUMBERING OF CHLORINATEDDIBENZOFURANS

13 2,4-Dich lorodibenzofu ran
15 2, 7-Dichlorodibenzofuran 74992-98-6
19 3, 7-Dichlorodibenzofuran 58802-21-4
20 4,6-Dich lorodibenzofu ran
21 1,2,3-Trich lorodibenzofuran 83636-47-9

24 1,2, 7-Trich lorodibenzofuran 83704-37-4
38 1,7,8-Trichlorodibenzofuran 58802-18-9
8 2
7 3
6 4
234

49 1,2,3,4-Tetrach lorodibenzofuran 24478-72-6

51 1,2,3, 7-Tetrachlorodibenzofuran 83704-22-7
53 1,2,3, 9-Tetrach lorodibenzofuran 83704-23-8



61 1,2, 7,8-Tetrach lorodibenzofuran 58802-20-3

62 1,2, 7, 9-Tetrach lorodibenzofuran 83704-26-1



72 1,3, 7, 9-Tetrach lorodibenzofuran 64560-17-4


78 2, 3,4, 6-Tetrach Iorod i benzof u ran 83704-30-7

8 2
7 3
6 4
235

80 2, 3,4, 8-Tetrach Iorod i benzof u ran 83704-32-9
82 2, 3, 6, 8-Tetrach Iorod i benzof u ran 57117-37-0

85 2,4, 6, 8-Tetrach Iorod i benzof u ran 58802-19-0
87 1,2,3,4,6-Pentachlorod i benzofuran 83704-47-6

88 1,2,3,4, 7-Pentachlorod i benzofuran 83704-48-7


94 1,2,3, 7,8-Pentachlorodibenzofuran 57117-41-6






113 2, 3,4, 6,8-Pe ntach Iorod i benzofu ran 67481-22-5

* Ballschmiter et. al. 9
8 2
7 3
6 4
236

115 1,2,3,4,6, 7-Hexachlorodibenzofuran 79060-60-9

116 1,2,3,4,6,8-Hexach lorodibenzofuran 69698-60-8
117 1,2,3,4,6, 9-Hexach lorodibenzofuran 91538-83-9
118 1,2,3,4, 7,8-Hexach lorodibenzofuran 70648-26-9
119 1,2,3,4, 7, 9-Hexach lorodibenzofuran 91538-84-0


123 1,2,3,6,8, 9-Hexach lorodibenzofuran
124 1,2,3, 7,8,9-Hexachlorodibenzofuran 72918-21-9


131 1,2,3,4,6, 7,8-Heptach lorodibenzofuran 67562-39-4

132 1,2,3,4,6, 7, 9-Heptach lorodibenzofuran 70648-25-8
133 1,2,3,4,6,8, 9-Heptach lorodibenzofuran 69698-58-4

134 1,2,3,4, 7,8, 9-Heptach lorodibenzofuran 55673-89-7
135 Octachlorod i benzofura n 39001-02-0

* Ballschmiter et. al.
9
8 2
7 3
6 4
237
SYSTEMATICNUMBERING OF CHLORINATEDBIPHENYLS

2-Chlorobiphenyl 2051-60-7
2 3-Chlorobiphenyl 2051-61-8
3 4-Chlorobiphenyl 2051-62-9
4 2,2 '-Dich lorobi phenyl 13029-08-8

5 2,3-Dich lorobiphenyl 16605-91-7
8 2,4'-Dichlorobiphenyl 34883-43-7
9 2, 5-Dich lorobiphenyl 34883-39-1
13 3,4'-Dich lorobi phenyl 2974-90-5
14 3, 5-Dich lorobiphenyl 34883-41-5
15 4,4' -Dich lorobiphenyl 2050-68-2
16 2,2' ,3-Trichlorobiphenyl 38444-78-9

20 2,3,3'-Trich lorobiphenyl 38444-84-7
21 2,3,4-Trich lorobiphenyl 55702-46-0
23 2,3, 5-Trich lorobiphenyl 55720-44-0
33 2' ,3,4-Trich lorobiphenyl 38444-86-9
* Ballschmiter and Zell
4' 4
5' 6' 6 5
238

34 2' ,3,5-Trichlorobiphenyl 37680-68-5

37 3,4,4'-Trichlorobiphenyl 38444-90-5

40 2,2 ',3,3 '-Tetrachlorobiphenyl 38444-93-8

41 2,2 ',3,4-Tetrach lorobiphenyl 52663-59-9
43 2,2 ',3, 5-Tetrach lorobiphenyl 70362-46-8

44 2,2 ',3, 5 '-Tetrachlorobiphenyl 41464-39-5
46 2,2 ',3,6'-Tetrachlorobiphenyl 41464-47-5


52 2,2 ', 5, 5 '-Tetrachlorobiphenyl 35693-99-3
53 2,2 ', 5,6'-Tetrachlorobiphenyl 41464-41-9

55 2,3,3' ,4-Tetrach lorobiphenyl 74338-24-2
56 2,3,3',4'-Tetrachlorobiphenyl 41464-43-1
57 2,3,3', 5-Tetrach lorobiphenyl 70424-67-8
58 2,3,3', 5 '-Tetrachlorobiphenyl 41464-49-7

60 2,3,4,4'-Tetrachlorobiphenyl 33025-41-1
61 2,3,4, 5-Tetrach lorobiphenyl 33284-53-6

62 2,3,4,6-Tetrachlorobiphenyl 54230-22-7
65 2,3, 5,6-Tetrach lorobiphenyl 33284-54-7


4' 4
5' 6' 6 5
239


70 2,3 ',4' ,5-Tetrachlorobiphenyl 32598-11-1
71 2,3 ',4' ,6-Tetrachlorobiphenyl 41464-46-4
73 2,3 ', 5 ',6-Tetrachlorobiphenyl 74338-23-1
75 2,4,4',6-Tetrachlorobiphenyl 32598-12-2
76 2' ,3,4, 5-Tetrach lorobiphenyl 70362-48-0

81 3,4,4',5-Tetrachlorobiphenyl 70362-50-4
82 2,2 ',3,3 ',4-Pentach lorobi phenyl 52663-62-4
83 2,2 ',3,3 ', 5-Pentach lorobi phenyl 60145-20-2

84 2,2 ',3,3 ',6-Pentach lorobi phenyl 52663-60-2
85 2,2 ',3,4,4'-Pentach lorobi phenyl 65510-45-4
86 2,2 ',3,4, 5-Pentachlorobi phenyl 55312-69-1

87 2,2 ',3,4, 5 '-Pentach lorobi phenyl 38380-02-8
88 2,2 ',3,4,6-Pentachlorobi phenyl 55215-17-3
89 2,2 ',3,4,6 '-Pentach lorobi phenyl 73575-57-2
90 2,2 ',3,4', 5-Pentach lorobi phenyl 68194-07-0

91 2,2 ',3,4' ,6-Pentach lorobi phenyl 68194-05-8
92 2,2 ',3, 5, 5 '-Pentach lorobi phenyl 52663-61-3
93 2,2 ',3, 5,6-Pentachlorobi phenyl 73575-56-1

94 2,2 ',3, 5,6 '-Pentach lorobi phenyl 73575-55-0
95 2,2 ',3, 5 ',6-Pentach lorobi phenyl 38379-99-6
96 2,2 ',3,6,6'-Pentach lorobi phenyl 73575-54-9

97 2,2 ',3 ',4, 5-Pentach lorobi phenyl 41464-51-1
98 2,2 ',3 ',4,6-Pentach lorobi phenyl 60233-25-2


4'
240

102 2,2 ',4, 5,6 '-Pentach lorobi phenyl 68194-06-9
104 2,2 ',4,6,6 '-Pentach lorobi phenyl 56558-16-8
105 2,3,3' ,4,4'-Pentach lorobi phenyl 32598-14-4
106 2, 3, 3 ',4, 5-Pentach lorobi phenyl 70424-69-0
107 (BZ #108) 2,3,3' ,4, 5 '-Pentach lorobi phenyl 70362-41-3
108 (BZ #109) 2, 3, 3 ',4, 6-Pentach lorobi phenyl 74472-35-8
109 (BZ #107) 2,3,3' ,4', 5-Pentach lorobi phenyl 70424-68-9
110 2,3,3' ,4' ,6-Pentach lorobi phenyl 38380-03-9
111 2,3,3', 5, 5 '-Pentach lorobi phenyl 39635-32-0
112 2, 3, 3 ', 5, 6-Pentach lorobi phenyl 74472-36-9

113 2,3,3', 5 ',6-Pentach lorobi phenyl 68194-10-5
114 2,3,4,4', 5-Pentachlorobi phenyl 74472-37-0
115 2,3,4,4' ,6-Pentachlorobi phenyl 74472-38-1

116 2, 3,4, 5, 6-Pentach Iorob i phenyl 18259-05-7
117 2, 3,4', 5, 6-Pentach lorobi phenyl 68194-11-6


122 2' ,3,3 ',4, 5-Pentach lorobi phenyl 76842-07-4
123 2' ,3,4,4', 5-Pentach lorobi phenyl 65510-44-3
124 2' ,3,4, 5, 5 '-Pentach lorobi phenyl 70424-70-3

125 2' ,3,4, 5,6'-Pentach lorobi phenyl 74472-39-2
128 2,2 ',3,3 ',4,4 '-Hexachlorobiphenyl 38380-07-3
129 2,2 ',3,3 ',4,5-Hexach lorobiphenyl 55215-18-4

130 2,2 ',3,3' ,4, 5'-Hexachlorobiphenyl 52663-66-8
131 2,2 ',3,3 ',4,6-Hexach lorobiphenyl 61798-70-7
132 2,2 ',3,3 ',4,6'-Hexachlorobiphenyl 38380-05-1

133 2,2 ',3,3', 5, 5'-Hexachlorobiphenyl 35694-04-3
134 2,2 ',3,3 ', 5,6-Hexach lorobiphenyl 52704-70-8
135 2,2 ',3,3 ', 5,6'-Hexachlorobiphenyl 52744-13-5

5' 6' 6 5
241

136 2,2 ',3,3 ',6,6'-Hexachlorobiphenyl 38411-22-2
137 2,2 ',3,4,4' ,5-Hexach lorobiphenyl 35694-06-5
138 2,2 ',3,4,4' ,5'-Hexachlorobiphenyl 35065-28-2
139 2,2 ',3,4,4' ,6-Hexach lorobiphenyl 56030-56-9
140 2,2 ',3,4,4' ,6'-Hexachlorobiphenyl 59291-64-4
141 2,2 ',3,4, 5, 5 '-Hexachlorobiphenyl 52712-04-6
142 2,2 ',3,4, 5,6-Hexach lorobiphenyl 41411-61-4
143 2,2 ',3,4, 5,6'-Hexach lorobiphenyl 68194-15-0
144 2,2 ',3,4, 5 ',6-Hexachlorobiphenyl 68194-14-9
145 2,2 ',3,4,6,6'-Hexach lorobiphenyl 74472-40-5
147 2,2 ',3,4', 5,6-Hexach lorobiphenyl 68194-13-8
148 2,2 ',3,4', 5,6'-Hexachlorobiphenyl 74472-41-6
149 2,2 ',3,4', 5 ',6-Hexachlorobiphenyl 38380-04-0
150 2,2 ',3,4' ,6,6'-Hexachlorobiphenyl 68194-08-1
151 2,2 ',3, 5, 5' ,6-Hexach lorobiphenyl 52663-63-5
152 2,2 ',3, 5,6,6'-Hexach lorobiphenyl 68194-09-2
155 2,2 ',4,4' ,6,6'-Hexachlorobiphenyl 33979-03-2
156 2, 3, 3 ',4,4', 5-Hexach Iorob i phenyl 38380-08-4
157 2,3,3' ,4,4' ,5'-Hexachlorobiphenyl 69782-90-7
158 2,3,3' ,4,4' ,6-Hexach lorobiphenyl 74472-42-7
159 2,3,3' ,4, 5, 5 '-Hexach lorobiphenyl 39635-35-3
160 2,3,3' ,4, 5,6-Hexach lorobiphenyl 41411-62-5
161 2,3,3' ,4, 5' ,6-Hexach lorobiphenyl 74472-43-8
162 2, 3, 3 ',4', 5, 5 '-Hexach Iorob i phenyl 39635-34-2
163 2,3,3' ,4', 5,6-Hexach lorobiphenyl 74472-44-9
164 2,3,3' ,4', 5 ',6-Hexachlorobiphenyl 74472-45-0
165 2,3,3', 5, 5 ',6-Hexach lorobiphenyl 74472-46-1
166 2,3,4,4', 5,6-Hexach lorobiphenyl 41411-63-6
168 2,3 ',4,4', 5 ', 6-Hexachlorobiphenyl 59291-65-5
4'
242

170 2,2 ',3,3 ',4,4', 5-Heptachlorobiphenyl 35065-30-6
171 2,2 ',3,3 ',4,4' ,6-Heptachlorobiphenyl 52663-71-5
172 2,2 ',3,3' ,4, 5, 5 '-Heptachlorobiphenyl 52663-74-8
173 2,2 ',3,3 ',4,5,6-Heptach lorobiphenyl 68194-16-1
174 2,2 ',3,3 ',4, 5,6'-Heptachlorobiphenyl 38411-25-5
175 2,2 ',3,3 ',4, 5' ,6-Heptachlorobiphenyl 40186-70-7
176 2,2 ',3,3' ,4,6,6 '-Heptachlorobiphenyl 52663-65-7
177 2,2 ',3,3 ',4' ,5,6-Heptachlorobiphenyl 52663-70-4

178 2,2 ',3,3 ', 5, 5' ,6-Heptachlorobiphenyl 52663-67-9
179 2,2 ',3,3 ', 5,6,6 '-Heptachlorobiphenyl 52663-64-6
180 2,2 ',3,4,4' ,5, 5 '-Heptachlorobiphenyl 35065-29-3

181 2,2 ',3,4,4', 5,6-Heptach lorobiphenyl 74472-47-2
182 2,2 ',3,4,4', 5,6 '-Heptachlorobiphenyl 60145-23-5
183 2,2 ',3,4,4' ,5' ,6-Heptachlorobiphenyl 52663-69-1

184 2,2 ',3,4,4' ,6,6'-Heptachlorobiphenyl 74472-48-3
185 2,2 ',3,4, 5, 5 ',6-Heptach lorobiphenyl 52712-05-7
186 2,2 ',3,4, 5,6,6 '-Heptach lorobiphenyl 74472-49-4

187 2,2 ',3,4', 5, 5' ,6-Heptachlorobiphenyl 52663-68-0
188 2,2 ',3,4', 5,6,6 '-Heptachlorobiphenyl 74487-85-7
189 2, 3, 3 ',4,4', 5, 5 '-H eptach Iorob i pheny I 39635-31-9

190 2,3,3' ,4,4', 5,6-Heptach lorobiphenyl 41411-64-7
191 2,3,3' ,4,4', 5' ,6-Heptachlorobiphenyl 74472-50-7
192 2, 3, 3 ',4, 5, 5 ', 6-H eptach Iorob i phenyl 74472-51-8

193 2, 3, 3 ',4', 5, 5 ', 6-H eptach Iorob i pheny I 69782-91-8
194 2,2 ',3,3 ',4,4', 5,5'-Octach lorobiphenyl 35694-08-7

195 2,2 ',3,3 ',4,4', 5,6-Octach lorobi phenyl 52663-78-2
196 2,2 ',3,3 ',4,4', 5, 6'-Octach lorobiphenyl 42740-50-1
197 2,2 ',3,3 ',4,4' ,6,6'-Octach lorobiphenyl 33091-17-7

198 2,2 ',3,3 ',4, 5, 5 ',6-Octach lorobi phenyl 68194-17-2
199 (BZ #201) 2,2 ',3,3 ',4, 5, 5 ',6'-Octach lorobiphenyl 52663-75-9
200 (BZ #199) 2,2 ',3,3 ',4,5,6,6'-Octach lorobi phenyl 52663-73-7
201 (BZ #200) 2,2 ',3,3 ',4, 5' ,6,6'-Octach lorobiphenyl 40186-71-8
202 2,2 ',3,3 ', 5, 5' ,6, 6'-Octach lorobiphenyl 2136-99-4
203 2,2 ',3,4,4' ,5, 5 ',6-Octach lorobi phenyl 52663-76-0

5' 6' 6 5
243
SYSTEMATIC NUMBERING OF CHLORINATED BIPHENYLS

204 2,2 ',3,4,4', 5,6,6'-Octach lorobi phenyl 74472-52-9
205 2,3,3' ,4,4' ,5, 5 ',6-Octach lorobi phenyl 74472-53-0
206 2,2 ',3,3 ',4,4', 5,5' ,6-Nonachlorobi phenyl 40186-72-9
207 2,2 ',3,3 ',4,4', 5,6,6'-Nonachlorobi phenyl 52663-79-3

208 2,2 ',3,3 ',4,5, 5 ',6,6'-Nonachlorobi phenyl 52663-77-1
209 Decachlorobiphenyl 2051-24-3

4'
SYSTEMATIC NUMBERING OF CHLORINATED NAPHTHALENES

1-Ch loronaphtha lene 90-13-1
2 2-Ch loronaphtha lene 91-58-7
3 1,2-Dich loronaphthalene 2050-69-3

6 1, 5-Dich loronaphthalene 1825-30-5

8 1,7-Dichloronaphthalene 2050-73-9

10 2, 3-D ich lorona phtha le ne 2050-75-1
11 2, 6-D ich lorona phtha le ne 2065-70-5

12 2, 7-Dichloronaphthalene 2198-77-8
13 1,2,3-Trich lorona phtha lene 50402-52-3

* Wiedmann and Ballschmiter
8 1
'~'
6~3
5 4
244
SYSTEMATICNUMBERING OF CHLORINATEDNAPHTHALENES

15 1,2, 5-Trich lorona phtha lene 55720-33-7


27 1,2,3,4-Tetrach lorona phtha lene 20020-02-4

28 1,2,3, 5-Tetrach loronaphtha lene 53555-63-8
29 1,2,3,6-Tetrach loronaphtha lene
30 1,2,3, 7-Tetrachloronaphthalene 55720-41-7
31 1,2,3,8-Tetrach loronaphtha lene 149864-81-3

36 1,2, 5,6-Tetrach loronaphtha lene 67922-22-9

37 1,2, 5, 7-Tetrach loronaphtha lene 67922-23-0

42 1,3, 5, 7-Tetrach loronaphtha lene 53555-64-9



* Wiedmann and Ballschmiter 8 1
7:¢¢c1" 2
6 ' ,,p 3
5 4
245
SYSTEMATICNUMBERING OF CHLORINATEDNAPHTHALENES

49 1,2,3,4, 5-Pentachloronaphthalene 67922-25-2
50 1,2,3,4,6-Pentachloronaphthalene 67922-26-3
51 1,2,3, 5,6-Pentachloronaphthalene
52 1,2,3, 5, 7-Pentachloronaphthalene 53555-65-0
53 1,2,3, 5,8-Pentachloronaphthalene 150224-24-1
58 1,2,4, 5, 7-Pentachloronaphthalene 150224-19-4
62 1,2,4, 7,8-Pentachloronaphthalene
63 1,2,3,4, 5,6-Hexach loronaphtha lene 58877-88-6

64 1,2,3,4, 5, 7-Hexach loronaphtha lene 67927-27-4
66 1,2,3,4,6, 7-Hexachloronaphthalene 103426-96-6
67 1,2,3,5,6, 7-Hexachloronaphthalene 103426-97-7
68 1,2,3, 5,6,8-Hexach loronaphtha lene 103426-95-5
69 1,2,3, 5, 7,8-Hexach loronaphtha lene 103426-94-4
71 1,2,4, 5,6,8-Hexach loronaphtha lene 90948-28-0
72 1,2,4, 5, 7,8-Hexach loronaphtha lene 103426-92-2
73 1,2,3,4, 5,6, 7-Heptach loronaphtha lene 58863-14-2

74 1,2,3,4, 5,6,8-Heptach loronaphtha lene 58863-15-3
75 Octachloronaphthalene 2234-13-1
* Wiedmann and Ballschmiter
8 1
'~'
6~3
5 4
246
REFERENCEMETHODS
U.S.EPAMethod 1613B:
Tetra-throughOcta-Chlorinated - RevisionB,
Dioxinsand Furansby IsotopeDilutionHRGC/HRMS
October1994
U.S.EPAMethod 513:
Determination
of 2,3,7,8-Tetrachlorodibenzo-p-dioxin
in DrinkingWaterby GasChromatography
with
HighResolutionMassSpectrometry - July1990
U.S.EPAMethod 8280B:
Polychlorinated
Dibenzo-p-dioxins
(PCDDs)
and Polychlorinated
Dibenzofurans
(PCDFs)
by
High-Resolution
GasChromatography/Low-Resolution
MassSpectrometry (HRGC/LRMS)
- Revision2,
February
2007
U.S.EPAMethod 8290A:
Polychlorinated
Dibenzodioxins
(PCDDs)
and Polychlorinated
Dibenzofurans
(PCDFs) by High-Resolution
GasChromatography/High-Resolution
MassSpectrometry(HRGC/HRMS) - Revision1, January1998
U.S.EPAMethod 23:
Determination
of Polychlorinated
Dibenzo-p-dioxins
and Polychlorinated
Dibenzofurans
from Stationary
Sources
EuropeanStandard EN 1948-4:2010:
StationarySourceEmissions- Determination
of the MassConcentration
of PCDDs/PCDFs
and
Dioxin-LikePCBs- October2010
JapaneseIndustrialStandardJIS K 0311:2005:
Methodfor Determination
of Tetra-ThroughOctachlorodibenzo-p-dioxins,
Tetra-Through
Octachlorodibenzofurans
and Dioxin-LikePolychlorinatedbiphenyls
in StationarySourceEmissions
- January2008
JapaneseIndustrialStandardJIS K 0312:2005:
Methodfor Determination
of Tetra-ThroughOctachlorodibenzo-p-dioxins,
Tetra-Through
Octachlorodibenzofurans
and Dioxin-LikePolychlorinatedbiphenyls
in IndustrialWaterandWasteWater
- January2008
U.S.EPAMethod 1668C:
ChlorinatedBiphenylCongeners
in Water,Soil,Sediment,Biosolids,
andTissueby HRGC/HRMS
-April 2010
U.S.EPAMethod 1668:
ToxicPolychlorinated
Biphenylsby IsotopeDilutionHighResolution
GasChromatography/High
ResolutionMassSpectrometry- March1997
EnvironmentCanadaReport EPS1/RM/31:
Reference
Methodfor theAnalysisof Polychlorinated - March1997
Biphenyls(PCBs)
247
REFERENCEMETHODS
CaliforniaEnvironmentalProtectionAgencyAir ResourcesBoardMethod 429:

Determination
of Polycyclic
AromaticHydrocarbon
(PAH)Emissions
from StationarySources- July1997
U.S.EPAMethod 537.1:
Determinationof SelectedPer-and Polyfluorinated
Alkyl Substances
in DrinkingWaterby SolidPhase
Extractionand LiquidChromatography/Tandem MassSpectrometry (LC/MS/MS) - November2018
International StandardISO 21675:2019:

Waterquality- Determinationof Perfluoroalkyl
and Polyfluoroalkyl
Substances
(PFAS)
in Water
- MethodUsingSolidPhaseExtractionand LiquidChromatography-Tandem MassSpectrometry
(LC-MS/MS) - October2019
U.S.EPAMethod 533:
Determinationof Per-and Polyfluoroalkyl
Substances
in DrinkingWaterby IsotopeDilutionAnion
ExchangeSolidPhaseExtractionand LiquidChromatography/Tandem MassSpectrometry
- November2019
U.S.EPADraft Method 1633:

Analysisof Per-and Polyfluoroalkyl
Substances
(PFAS)
in Aqueous,Solid,Biosolids,andTissueSamples
by LC-MS/MS -August 2021

248
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REFERENCE MATERI AL PRODUCER

This certificate is valid only when accompanied hy a current scope of accreditation document.
The current scope of accreditation can be verified at www.anab.org.
,...
I{. DouglasLeon,srdJr., VP. l'JLR $LIU

Expiry Duw: 17 L\~bruary2023
Ccnificalc Numhcr: t\R-1523
ANSI NIJ!iona( A.ccredital}()l) BOil!()
This rcfCrcncc material pr<><luccr

i!»accn::ditcd in accor<lanccwith the recognized Jntcmalirnrnl Sum<lar<lISO l 7034:20I6.
This nccreditationdernonscrares
technicalcompetencefo1·a defined scopeanj the openicionofa refel'encernaterial~)roducer
lfUalilynumag.:mcnl sy~tt..11n.
WELLINGTON LABORATORIES INC.
345 SOUTHGATE DRIVE. GUELPH, ONTARIO. CANADA N 1G 3M5
PHONE: 519-822-2436 TOLL FREE: 1-800-578-6985 FAX: 519-822-2849
GRowwi-rtt us
WVJW.WF.Lt-LABs.coM
Greyhound Chromatography and

Allied Chemicals
6 Kelvin Park, Birkenhead
Merseyside, CH41 1LT, UK
Tel: +44 (0)151 649 4000

Email: info@greyhoundchrom.com
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CERTIFICATE

Wellington Laboratories Inc.

Quality Management System

ISO 9001 :2015

Certificate No.: CERT-0106807 Original Certification Date: December 30, 2004

Some of the new products in this catalogue include:

President Analytical Support Reference Standards Division

PCDD/PCDF ANALYTICAL METHOD SOLUTIONS

This has been achieved due to:

OTHER PRODUCTS/CUSTOM REQUESTS

Wellington Laboratories Inc.

Telephone: (519) 822-2436

When ordering, please provide as much information as possible, including:

• Detailed shipping address and billing address

TERMS & CONDITIONS OF SALE

Note: We may also accept credit card payments.

Safety Data Sheets ( SDSs) are supplied upon request.

END USE ONLY/NOT FOR RESALE

DISTRIBUTOR HEADOFFICE CONTACTINFORMATION

WELLINGTON LABORATORIES JAPAN 1-22-12 Fujimidai

WELLINGTON UNITED STATES 7208 West 80th Street, Suite 206

GREYHOUND CHROMATOGRAPHY ENGLAND 6 Kelvin Park, Birkenhead,

BCP INSTRUMENTS FRANCE 12 avenue des Saules

CHEMICAL RESEARCH 2000 S.RL. ITALY Via Santa Margherita di Belice, 16

CAMPRO SCIENTIFIC GMBH GERMANY Goerzallee 299

DISTRIBUTOR HEADOFFICE CONTACTINFORMATION

TECHNOSPEC SPAIN Calle Pau Alsina, 112

LABICOM, CZECH REPUBLIC NaJetelce 69/2,

SMART E INTERNATIONAL CHINA 3107 Building D,

AURORA BOREALIS TECHNOLOGY TAIWAN 4F, No. 42, Huaining Street

BYMAZ PTY. LTD. SOUTH AFRICA 61C 13th Avenue

SCANTEC NORDIC AB SWEDEN Fabriksstraket 29

U.S. EPA Method 1613B

CS3WT: EPA-1613CS3 calibration solution combined with PCDD/PCDFwindow

In this edition. we have added solution/mixtures of 13C-labelled. window-defining PCDDs

Catalogue Number Product (nonane solution) Qty/Cone

1613CSL 1613CS0.5 1613CS1 1613CS2 1613CS3 1613CS4 1613CS5

2,3,7,8-Tetrachlorodibenzofuran 0.100 0.250 0.500 2.00 10.0 40.0 200

MASS-LABELLED PCDDs & PCDFs

2,3,7,8-Tetrachloro("C,,)dibenzofuran 100 100 100 100 100 100 100

Catalogue Number Product (nonane solution) Qty/Cone

1613LCS 1613CSS 1613155 1613PAR 1613STOCK

2,3,7,8-Tetrachlorodibenzofuran 40.0 400

MASS-LABELLED PCDDs & PCDFs

Catalogue Number Product (nonane solution) Qty/Cone

16130CSL 16130CS05 16130CS1 16130CS2 16130CS3 16130CS4 16130CS5

2,3,7,8-Tetrachlorodibenzofuran 0.0100 0.0250 0.0500 0.200 1.00 4.00 20.0

MASS-LABELLED PCDDs & PCDFs

2,3,7,8-Tetrachloro("C 12)dibenzofuran 10.0 10.0 10.0 10.0 10.0 10.0 10.0

Catalogue Number Product (nonane solution) Qty/Cone

QUANTITATIVE ANALYTES (ng/mL) SEMI-QUANTITATIVE ANALYTES (ng/mL)

MASS-LABELLED PCDDs & PCDFs

2,3,7,8-Tetrachloro("C 12)d i benzofu ran 100

(WD) - Window Definer

Catalogue Number Product (nonane solution) Qty/Cone

8280CC1 8280CC2 8280CC3 8280CC4 8280CC5

2,3,7,8-Tetrach lorodibenzofuran 0.100 0.250 0.500 1.00 2.00

2,3,7,8-Tetrach loro("C,,)d i benzofu ran 0.500 0.500 0.500 0.500 0.500