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CH 3 Xi

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CHEMISTRY PRACTICE TEST FOR MCQ’S

CHAPTER NO: 03
THEORIES OF CHEMICAL BONDING
i. The is ______ % in ionic character
(A) 72 (C) 92
(B) 100 (D) 0
ii. A bond is formed between two atoms in which the shared pair of electrons is
donated by one of the bonded atoms called
(A) Ionic bond (C) Hydrogen bond
(B) Co-ordinate covalent bond (D) none of these
iii. The number of bond in oxygen (O2) molecule is:
(A) one sigma and one pi-bond (C) two sigma bonds
(B) two pi-bonds (D) one sigma and two pi-bond
iv. During the formation of a stable chemical bond
(A) Energy is release (C) Energy is absorbed
(B) Energy neither released nor absorbed (D) none of these
v. In which pair the molecular shape is same
(A) NF3 and H2O (C) NH3 and H2S
(B) H2O and H2S (D) CH4 and PH3

vi. Which one has one lone pair on the central atom?
(A) H2O (C) H2S
(B) BCl3 (D) PH3
vii. The lone pair - lone pair repulsion is ______ than bond pair – bond pair repulsions.
(A) Greater (C) Less
(B) Equal to (D) None of these
viii. The molecules containing four electron pairs with no lone pair to form a shape:
(A) Regular tetrahedron (C) Regular triangle
(B) Trigonal pyramidal (D) Regular linear
ix. Which of the following statement is not correct?
(A) double bonds is stronger than single bond (C) sigma bond is stronger than pi bond
(B) triple bonds is shorter than double bonds (D) sigma bond is weaker than pi bond
x. The bond angles in molecules containing four electron Paris, with one lone pair &
three bond pairs in NF3 is:
(A) 105.5o (C) 104.5o
(B) 102o (D) 120o
xi. The shape of benzene molecule is explain by:
(A) Sp3 orbital hybridization (C) Sp2 orbital hybridization
(B) Sp orbital hybridization (D) None of these

xii. The number of coordinate covalent bond in NH4+ is


(A) One (C) three
(B) Two (D) four
xiii. The electron cloud density is symmetrical along the bond axis in:
(A) Sigma bond (C) Pi bond
(B) Both of these (D) None of these

PROF.KHURRAM SHAHBAZ CHEM PCAPC


CHEMISTRY PRACTICE TEST FOR MCQ’S
CHAPTER NO: 03
THEORIES OF CHEMICAL BONDING

xiv. Which is the example of AB4 TYPE?


(A) BH3 (C) AlCl3
(B) SnCl2 (D) NF3
xv. Element X is strongly electropositive and Y is strongly electronegative. Both are
univalent the compound formed would be:
(A) X+Y– (C) X–Y+
(B) X – Y (D) X  Y
xvi. If ‘A” represent central atom and ‘B’ represent bond pair and ‘L’ lone pair which
of the following represent the Trigonal pyramidal geometry:
(A) AB2L (C) AB3L
(B) AB2L2 (D) ABL2
xvii. Which one is the correct statement?
(A) A sigma bond is formed when two s-orbitals overlap
(B) A pi bond is formed when two p-orbitals end to end overlap
(C) A  bond is weaker than  bond
(D) A  bond is only formed after the formation of  bond.
xviii. Which of the following molecules contain eight bonding electrons?
(A) C2H4 (C) CO2
(B) BF3 (D) H2S

xix. A  bond is formed by the overlap of


(A) S – S orbital (C) S – P orbital
(B) P – P orbital in end to end fashion (D) P – P orbitals in side wise manner
xx. The shape of CO2 molecule is similar to:
(A) H2S (C) BeCl2
(B) SO2 (D) SnCl2

xxi. The total number of  bond is present in C2H4 is:


(A) Three (C) Five
(B) Four (D) Six
xxii. The bond angle in ethane molecule is :
(A) 109.50 (C) 1200
(B) 107.50 (D) 1800
xxiii. Which of the following show minimum bond angle :
(A) H2O (C) H2S
(B) NH3 (D) NF3

PROF.KHURRAM SHAHBAZ CHEM PCAPC


CHEMISTRY PRACTICE TEST FOR MCQ’S
CHAPTER NO: 03
THEORIES OF CHEMICAL BONDING

xxiv. Which of the following molecule have greater percentage of s character in the
hybrid orbital used?
(A) CH4 (C) C2H2
(B) C2H6 (D) C2H4
xxv. Which of the following species has unpaired electrons in anti-bonding molecular
orbitals:

+2 2
A. O2 C. N2

B. B2 D. F2
xxvi. Arrange the following molecules in decreasing bond length.
A) O2 > O2– > O2+ > O22- C) O22- > O2– > O2+ > O2
B) O22- > O2– > O2 > O2+ D) O2– > O2+ > O22- > O
xxvii. 3. Bond Order of O2, F2, N2 respectively are __________:
A. +1, +2, +3 C. +2, +3, +1
B. +2, +1, +3 D. +3, +2, +1
xxviii. Arrange the following molecules in the order of increasing stability.
A) N2+ < N2 < N2– < N22- C) N22- < N2– = N2+ < N2
B) N22- < N2– < N2 < N2+ D) N2 < N2+ = N2– < N22-
xxix. The relative energies of molecular orbitals in increasing order have been found to
be as follows.
(σ1s) < (σ*1s) < (σ2s) < (σ*2s) < [(π2py)(π2pz)] < (σ 2px) < [(π*2py)(π*2pz)] < (σ*2px)
A) For O2 to Ne2 C) For H2 to Ne2
B For H2 to N2 D) For N2 to Ne2
xxx. According to Molecular Orbital Theory, the shape and size of a molecular orbital
depends upon _________:
A) Shape and size of the combining atomic orbitals
B) Numbers of the combining atomic orbitals
C) Orientation of the combining atomic orbitals
D) All of the mentioned

PROF.KHURRAM SHAHBAZ CHEM PCAPC

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