PARISHRAM ACADEMY

Name of Topic : GOC

Subject : Chemistry Class : XI
Batch :- Max. Marks. 180

46.Which of the following species has electron (b)Implies the transfer of lone pair of
releasing (or +I inductive) effect? electrons from lesser electronegative atom
(a)  NH 2 (b) COOH to the more electronegative atom in a
molecule
(c) –CH CH3 2 (d) C6 H 5
(c)Increases with increase in distance
47.Which of the following belongs to +I group? (d)Implies the atoms ability to cause bond
(a) OH (b) OCH3 polarizatio
(c) COOH (d) CH 3 53.The electromeric effect in organic
48.Which of the following functional group compounds is a
shows – I -effect ? (a) Temporary effect
(a)  O Θ (b)–CH3 (b)Permanent effect
(c)–D (d)  NR2 (c)Temporary or permanent effect
(d)All the above
49.The -I effect is shown by
54.+ R power of the given groups
(a) COOH (b) CH 3 Θ
(I)  O (II) –NH2
(c) CH 3CH 2 (d) CHR2
(III) –OH (IV) –NHCOCH3
50.Decreasing - I power of given groups is in decreasing order is
(I) –COOH (II) NO2 (a) I > II > III > IV (b) IV > III > II > I

(III) N H 3 (IV) –OH (c) I > III > II > IV (d) I > IV > III > II
(a) II > I > IV > III 55.Hyper conjugation is
(b)II > III > IV > I (a)  conjugation
(c)III > II > IV > I (b)Due to delocalization of  and  bonds
(d)III > II > I > IV (c)No bond resonance
51.Which of the following belongs to -I group? (d) All
56.Stability of which intermediate is not given
(a) C6 H 5 (b) CH 3
by hyperconjugation?
(c) CH 2CH 3 (d) C  CH 3 3 (a) Carbocation (b) Carbanion
52.Which of the following statements is correct (c)Carbon free radical (d) All
about inductive effect 57.Removal of hydride ion from a methane
(a) Implies the transfer of lone pair of molecule will give a
electrons from more electronegative atom (a) Methyl radical (b)Carbonium ion
to lesser electronegative atom in a molecule (c)Carbanion (d)Methyl group

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58.Among the following the true property 64.The order of –I effect of orbitals is
H 3C (a) sp3  sp2  sp (b) sp2  sp3  sp
about C–CH3 is
H 3C (c) sp  sp2  sp3 (d) sp3  sp  sp2
(a) non - planar 65.Which of the following statement is
(b)C+ is sp2 - hybridised incorrect ?
(c)Electroophile can attack on C+ (a) Inductive effect is a permanent effect.
(d)Does not undergo hydrolysis (b)Inductive effect travels through  bonds
59.Heterolysis of C-Cl bond produces
(c)–I effect decreases the charge intensity
(a) Two free radicals at carbanion
(b)Two carbonium ions (d)–I effect in chlorobenzene is minimum
(c)Two carbanions at meta position
(d)One cation and one anion 66.Which order is correct regarding the –I
60.The shape of free radicals is effect of the substitutents?
(a) Planar (b)Pyramidal
(a) NR2  OR  F (b)
(c)Tetrahedral (d)Linear
NR2  OR  F
61.Which one of the following statement is not
correct for electrophile (c) NR2  OR  F (d) NR2  OR  F
(a) Electron deficient species are electrophile 67.Incorrect order of –I effect :
(b)Electrophiles are Lewis acids
(c) All positively charged species are (a) –F < – C F3 (b) C  CH C  N
electrophiles (c) NH2  C  CH
(d) AlCl3 , and SO 3 are electrophiles
CH3 O
62.Electrophiles are
(a) Lewis bases (b)Lewis acids (d) N CH3 > N
(c)Amphoteric (d)All of these
CH3 O
63.The group showing strongest –I effect is :
CH3 68.What is the correct order of –I effect of
the following groups?
N (a) F > Cl > Br > I
(a) – F (b)
CH3
CH3 (b)RS – < R2N – < RO –
(c)–NO2 > – CN > CO2H > –OH
O O
(d)All
(c) NH  S  CH3 (d) S CH3 69.Maximum –I effect is exerted by :
(a) – F (b)–O CH3
O O
(c)  NH2 (d)–COOH

| Page No. 2 |
70.Group showing strongest +M effect 75.Hyperconjugation involves overlap of the
following orbitals :
CH3
(a)  (b)   p
(c) p  p (d)  
(a) NH2 (b) N CH3 76.Identify the group which exert –I, –M &
+M effect
(c) NH  CH3 (d)  O
(a)  N O 2 (b) – NO
71.Which of the following is correct order of
(c) –SO3H (d) C  N
+M effect
77.Identify the group which exerts –I, –M, +M
(a) NH2  OH (b) OH > O effect–
O (a) CH  CH2 (b) CCH

(c) O C CH3 > OH (c) (d) All of these

O 78.Group showing +M, –M, –I effect

O
(d) NH C CH3 > NH2
72.Which of the following show both +M and (a) NH  C  CH3 (b) NO2
–M effect
(c) SO3H (d) CH  CH2
(a) – OH (b) –NO2
79.The strongest ortho - para and strongest
(c) – F (d) meta directing groups respectively are
(a) –NO2 and –NH2
(b)–CONH2 and –NH2
73.Which of the following group when attached
to benzene ring show – M effect (c)–NH2 and –CONH2
 
(d)–NH2 and –NO2
(a)  NR3 (b)  P R 3
80.Hybridisation states of C in CH3 and CH4
(c)  C 2H 5 (d) OCH3 are
74.In the anion HCOO  , the two carbon-oxy- (a) sp2 & sp3 (b) sp3 & sp2
gen bonds are found to be equal length. (c) sp2 & sp2 (d) sp3 & sp3
What is the reason for it ? 81.Which of the following species is not
(a) The C = O bond is weaker than the C – aromatic ?
O bond (a) Benzene
(b)The anion HCOO– has two equivalent (b)Cyclooctatetraenyl dianion
resonating structures
(c)Tropylium ion
(c)The electronic orbitals of carbon atom
(d)Cyclopentadienyl cation
are hybridized
(d)The anion is obtained by removal of a
proton from the acid molecule

| Page No. 3 |
82.Among the following the aromatic 88.Mesomeric effect involves the
compound delocalisation of :
(a) protons (b)sigma electrons
(a) (b)
(c)pi electrons (d)none of these
+ + 89.Which among the following statements are
true with respect to electronic displacement
(c) (d) in a covalent bond ?
– (i) Inductive effect operates through a p-
83.Which of the following organic compounds bond
has same hybridization as its combustion (ii) Resonance effect operates through a s-
product (CO2) ? bond
(a) Ethane (b)Ethyne (iii) Inductive effect operates through a  -
bond
(c)Ethene (d)Ethanol
(iv) Resonance effect operates through a
84.What is the hybridisation state of benzyl
p-bond
carbonium ion
(a) i and ii (b)i and iii

CH2 ?
(c)ii and iii (d)iii and iv
90.CH3CH2CI undergoes homolytic fission
(a) sp 2 (b)spd 2 produces :
(c)sp 2 d (d)sp 3 •
85.Which of the following chemical system is (a) CH3 CH2 and CI•
non aromatic ? 
(b) CH3 CH2 and CI
(a) (b)

(c) CH3 C H2 and CI•
(c) (d)
•
S (d) CH3 CH2 and CI
86.Which of the following is least likely to
behave as Lewis base ?
(a) H2 O (b)NH3
(c)BF 3 (d)OH–
87.The reaction intermediate produce by
homolytic cleavage of bond is called:
(a) carbocations (b)carbanions
(c)free radicals (d)carbenes

| Page No. 4 |
Answer Key :- GOC
46. (c) 47. (d) 48. (d) 49. (a) 50. (d)
51. (a) 52. (d) 53. (a) 54. (a) 55. (d)
56. (b) 57. (b) 58. (b) 59. (d) 60. (a)
61. (c) 62. (b) 63. (b) 64. (c) 65. (d)
66. (c) 67. (c) 68. (d) 69. (d) 70. (d)
71. (a) 72. (d) 73. (b) 74. (b) 75. (b)
76. (b) 77. (d) 78. (d) 79. (d) 80. (a)
81. (d) 82. (a) 83. (b) 84. (a) 85. (d)
86. (c) 87. (c) 88. (c) 89. (d) 90. (a)

| Page No. 5 |
 PARISHRAM ACADEMY

Name of Topic : GOC

Subject : Chemistry Class : XI
Batch :- Max. Marks. 180

46.Which of the following species has electron (b)Implies the transfer of lone pair of
releasing (or +I inductive) effect? electrons from lesser electronegative atom
(a)  NH 2 (b) COOH to the more electronegative atom in a
molecule
(c) –CH CH3 2 (d) C6 H 5
(c)Increases with increase in distance
47.Which of the following belongs to +I group? (d)Implies the atoms ability to cause bond
(a) OH (b) OCH3 polarizatio
(c) COOH (d) CH 3 53.The electromeric effect in organic
48.Which of the following functional group compounds is a
shows – I -effect ? (a) Temporary effect
(a)  O Θ (b)–CH3 (b)Permanent effect
(c)–D (d)  NR2 (c)Temporary or permanent effect
(d)All the above
49.The -I effect is shown by
54.+ R power of the given groups
(a) COOH (b) CH 3 Θ
(I)  O (II) –NH2
(c) CH 3CH 2 (d) CHR2
(III) –OH (IV) –NHCOCH3
50.Decreasing - I power of given groups is in decreasing order is
(I) –COOH (II) NO2 (a) I > II > III > IV (b) IV > III > II > I

(III) N H 3 (IV) –OH (c) I > III > II > IV (d) I > IV > III > II
(a) II > I > IV > III 55.Hyper conjugation is
(b)II > III > IV > I (a)  conjugation
(c)III > II > IV > I (b)Due to delocalization of  and  bonds
(d)III > II > I > IV (c)No bond resonance
51.Which of the following belongs to -I group? (d) All
56.Stability of which intermediate is not given
(a) C6 H 5 (b) CH 3
by hyperconjugation?
(c) CH 2CH 3 (d) C  CH 3 3 (a) Carbocation (b) Carbanion
52.Which of the following statements is correct (c)Carbon free radical (d) All
about inductive effect 57.Removal of hydride ion from a methane
(a) Implies the transfer of lone pair of molecule will give a
electrons from more electronegative atom (a) Methyl radical (b)Carbonium ion
to lesser electronegative atom in a molecule (c)Carbanion (d)Methyl group

| Page No. 1 |
58.Among the following the true property 64.The order of –I effect of orbitals is
H 3C (a) sp3  sp2  sp (b) sp2  sp3  sp
about C–CH3 is
H 3C (c) sp  sp2  sp3 (d) sp3  sp  sp2
(a) non - planar 65.Which of the following statement is
(b)C+ is sp2 - hybridised incorrect ?
(c)Electroophile can attack on C+ (a) Inductive effect is a permanent effect.
(d)Does not undergo hydrolysis (b)Inductive effect travels through  bonds
59.Heterolysis of C-Cl bond produces
(c)–I effect decreases the charge intensity
(a) Two free radicals at carbanion
(b)Two carbonium ions (d)–I effect in chlorobenzene is minimum
(c)Two carbanions at meta position
(d)One cation and one anion 66.Which order is correct regarding the –I
60.The shape of free radicals is effect of the substitutents?
(a) Planar (b)Pyramidal
(a) NR2  OR  F (b)
(c)Tetrahedral (d)Linear
NR2  OR  F
61.Which one of the following statement is not
correct for electrophile (c) NR2  OR  F (d) NR2  OR  F
(a) Electron deficient species are electrophile 67.Incorrect order of –I effect :
(b)Electrophiles are Lewis acids
(c) All positively charged species are (a) –F < – C F3 (b) C  CH C  N
electrophiles (c) NH2  C  CH
(d) AlCl3 , and SO 3 are electrophiles
CH3 O
62.Electrophiles are
(a) Lewis bases (b)Lewis acids (d) N CH3 > N
(c)Amphoteric (d)All of these
CH3 O
63.The group showing strongest –I effect is :
CH3 68.What is the correct order of –I effect of
the following groups?
N (a) F > Cl > Br > I
(a) – F (b)
CH3
CH3 (b)RS – < R2N – < RO –
(c) –N O 2 > – CN > CO2H > –OH
O O
(d)All
(c) NH  S  CH3 (d) S CH3 69.Maximum –I effect is exerted by :
(a) – F (b)–O CH3
O O
(c)  NH2 (d)–COOH

| Page No. 2 |
70.Group showing strongest +M effect 75.Hyperconjugation involves overlap of the
following orbitals :
CH3
(a)  (b)   p
(c) p  p (d)  
(a) NH2 (b) N CH3 76.Identify the group which exert –I, –M &
+M effect
(c) NH  CH3 (d)  O
(a)  N O 2 (b) – NO
71.Which of the following is correct order of
(c) –SO3H (d) C  N
+M effect
77.Identify the group which exerts –I, –M, +M
(a) NH2  OH (b) OH > O effect–
O (a) CH  CH2 (b) CCH

(c) O C CH3 > OH (c) (d) All of these

O 78.Group showing +M, –M, –I effect

O
(d) NH C CH3 > NH2
72.Which of the following show both +M and (a) NH  C  CH3 (b) NO2
–M effect
(c) SO3H (d) CH  CH2
(a) – OH (b) –NO2
79.The strongest ortho - para and strongest
(c) – F (d) meta directing groups respectively are
(a) –NO2 and –NH2
(b)–CONH2 and –NH2
73.Which of the following group when attached
to benzene ring show – M effect (c)–NH2 and –CONH2
 
(d)–NH2 and –NO2
(a)  NR3 (b)  P R 3
80.Hybridisation states of C in CH3 and CH4
(c)  C 2H 5 (d) OCH3 are
74.In the anion HCOO  , the two carbon-oxy- (a) sp2 & sp3 (b) sp3 & sp2
gen bonds are found to be equal length. (c) sp2 & sp2 (d) sp3 & sp3
What is the reason for it ? 81.Which of the following species is not
(a) The C = O bond is weaker than the C – aromatic ?
O bond (a) Benzene
(b)The anion HCOO– has two equivalent (b)Cyclooctatetraenyl dianion
resonating structures
(c)Tropylium ion
(c)The electronic orbitals of carbon atom
(d)Cyclopentadienyl cation
are hybridized
(d)The anion is obtained by removal of a
proton from the acid molecule

| Page No. 3 |
82.Among the following the aromatic 88.Mesomeric effect involves the
compound delocalisation of :
(a) protons (b)sigma electrons
(a) (b)
(c)pi electrons (d)none of these
+ + 89.Which among the following statements are
true with respect to electronic displacement
(c) (d) in a covalent bond ?
– (i) Inductive effect operates through a p-
83.Which of the following organic compounds bond
has same hybridization as its combustion (ii) Resonance effect operates through a s-
product (CO2) ? bond
(a) Ethane (b)Ethyne (iii) Inductive effect operates through a  -
bond
(c)Ethene (d)Ethanol
(iv) Resonance effect operates through a
84.What is the hybridisation state of benzyl
p-bond
carbonium ion
(a) i and ii (b)i and iii

CH2 ?
(c)ii and iii (d)iii and iv
90.CH3CH2CI undergoes homolytic fission
(a) sp 2 (b)spd 2 produces :
(c)sp 2 d (d)sp 3 •
85.Which of the following chemical system is (a) CH3 CH2 and CI•
non aromatic ? 
(b) CH3 CH2 and CI
(a) (b)

(c) CH3 C H2 and CI•
(c) (d)
•
S (d) CH3 CH2 and CI
86.Which of the following is least likely to
behave as Lewis base ?
(a) H2 O (b)NH3
(c)BF 3 (d)OH–
87.The reaction intermediate produce by
homolytic cleavage of bond is called:
(a) carbocations (b)carbanions
(c)free radicals (d)carbenes

| Page No. 4 |
Answer Key :- GOC
46. (c) 47. (d) 48. (d) 49. (a) 50. (d)
51. (a) 52. (d) 53. (a) 54. (a) 55. (d)
56. (b) 57. (b) 58. (b) 59. (d) 60. (a)
61. (c) 62. (b) 63. (b) 64. (c) 65. (d)
66. (c) 67. (c) 68. (d) 69. (d) 70. (d)
71. (a) 72. (d) 73. (b) 74. (b) 75. (b)
76. (b) 77. (d) 78. (d) 79. (d) 80. (a)
81. (d) 82. (a) 83. (b) 84. (a) 85. (d)
86. (c) 87. (c) 88. (c) 89. (d) 90. (a)

| Page No. 5 |
 PARISHRAM ACADEMY

Name of Topic : GOC

Subject : Chemistry Class : XI
Batch :- Max. Marks. 180

46.Which of the following species has electron (b)Implies the transfer of lone pair of
releasing (or +I inductive) effect? electrons from lesser electronegative atom
(a)  NH 2 (b) COOH to the more electronegative atom in a
molecule
(c) –CH CH3 2 (d) C6 H 5
(c)Increases with increase in distance
47.Which of the following belongs to +I group? (d)Implies the atoms ability to cause bond
(a) OH (b) OCH3 polarizatio
(c) COOH (d) CH 3 53.The electromeric effect in organic
48.Which of the following functional group compounds is a
shows – I -effect ? (a) Temporary effect
(a)  O Θ (b)–CH3 (b)Permanent effect
(c)–D (d)  NR2 (c)Temporary or permanent effect
(d)All the above
49.The -I effect is shown by
54.+ R power of the given groups
(a) COOH (b) CH 3 Θ
(I)  O (II) –NH2
(c) CH 3CH 2 (d) CHR2
(III) –OH (IV) –NHCOCH3
50.Decreasing - I power of given groups is in decreasing order is
(I) –COOH (II) NO2 (a) I > II > III > IV (b) IV > III > II > I

(III) N H 3 (IV) –OH (c) I > III > II > IV (d) I > IV > III > II
(a) II > I > IV > III 55.Hyper conjugation is
(b)II > III > IV > I (a)  conjugation
(c)III > II > IV > I (b)Due to delocalization of  and  bonds
(d)III > II > I > IV (c)No bond resonance
51.Which of the following belongs to -I group? (d) All
56.Stability of which intermediate is not given
(a) C6 H 5 (b) CH 3
by hyperconjugation?
(c) CH 2CH 3 (d) C  CH 3 3 (a) Carbocation (b) Carbanion
52.Which of the following statements is correct (c)Carbon free radical (d) All
about inductive effect 57.Removal of hydride ion from a methane
(a) Implies the transfer of lone pair of molecule will give a
electrons from more electronegative atom (a) Methyl radical (b)Carbonium ion
to lesser electronegative atom in a molecule (c)Carbanion (d)Methyl group

| Page No. 1 |
58.Among the following the true property 64.The order of –I effect of orbitals is
H 3C (a) sp3  sp2  sp (b) sp2  sp3  sp
about C–CH3 is
H 3C (c) sp  sp2  sp3 (d) sp3  sp  sp2
(a) non - planar 65.Which of the following statement is
(b)C+ is sp2 - hybridised incorrect ?
(c)Electroophile can attack on C+ (a) Inductive effect is a permanent effect.
(d)Does not undergo hydrolysis (b)Inductive effect travels through  bonds
59.Heterolysis of C-Cl bond produces
(c)–I effect decreases the charge intensity
(a) Two free radicals at carbanion
(b)Two carbonium ions (d)–I effect in chlorobenzene is minimum
(c)Two carbanions at meta position
(d)One cation and one anion 66.Which order is correct regarding the –I
60.The shape of free radicals is effect of the substitutents?
(a) Planar (b)Pyramidal
(a) NR2  OR  F (b)
(c)Tetrahedral (d)Linear
NR2  OR  F
61.Which one of the following statement is not
correct for electrophile (c) NR2  OR  F (d) NR2  OR  F
(a) Electron deficient species are electrophile 67.Incorrect order of –I effect :
(b)Electrophiles are Lewis acids
(c) All positively charged species are (a) –F < – C F3 (b) C  CH C  N
electrophiles (c) NH2  C  CH
(d) AlCl3 , and SO 3 are electrophiles
CH3 O
62.Electrophiles are
(a) Lewis bases (b)Lewis acids (d) N CH3 > N
(c)Amphoteric (d)All of these
CH3 O
63.The group showing strongest –I effect is :
CH3 68.What is the correct order of –I effect of
the following groups?
N (a) F > Cl > Br > I
(a) – F (b)
CH3
CH3 (b)RS – < R2N – < RO –
(c) –N O 2 > – CN > CO2H > –OH
O O
(d)All
(c) NH  S  CH3 (d) S CH3 69.Maximum –I effect is exerted by :
(a) – F (b)–O CH3
O O
(c)  NH2 (d)–COOH

| Page No. 2 |
70.Group showing strongest +M effect 75.Hyperconjugation involves overlap of the
following orbitals :
CH3
(a)  (b)   p
(c) p  p (d)  
(a) NH2 (b) N CH3 76.Identify the group which exert –I, –M &
+M effect
(c) NH  CH3 (d)  O
(a)  N O 2 (b) – NO
71.Which of the following is correct order of
(c) –SO3H (d) C  N
+M effect
77.Identify the group which exerts –I, –M, +M
(a) NH2  OH (b) OH > O effect–
O (a) CH  CH2 (b) CCH

(c) O C CH3 > OH (c) (d) All of these

O 78.Group showing +M, –M, –I effect

O
(d) NH C CH3 > NH2
72.Which of the following show both +M and (a) NH  C  CH3 (b) NO2
–M effect
(c) SO3H (d) CH  CH2
(a) – OH (b) –NO2
79.The strongest ortho - para and strongest
(c) – F (d) meta directing groups respectively are
(a) –NO2 and –NH2
(b)–CONH2 and –NH2
73.Which of the following group when attached
to benzene ring show – M effect (c)–NH2 and –CONH2
 
(d)–NH2 and –NO2
(a)  NR3 (b)  P R 3
80.Hybridisation states of C in CH3 and CH4
(c)  C 2H 5 (d) OCH3 are
74.In the anion HCOO  , the two carbon-oxy- (a) sp2 & sp3 (b) sp3 & sp2
gen bonds are found to be equal length. (c) sp2 & sp2 (d) sp3 & sp3
What is the reason for it ? 81.Which of the following species is not
(a) The C = O bond is weaker than the C – aromatic ?
O bond (a) Benzene
(b)The anion HCOO– has two equivalent (b)Cyclooctatetraenyl dianion
resonating structures
(c)Tropylium ion
(c)The electronic orbitals of carbon atom
(d)Cyclopentadienyl cation
are hybridized
(d)The anion is obtained by removal of a
proton from the acid molecule

| Page No. 3 |
82.Among the following the aromatic 88.Mesomeric effect involves the
compound delocalisation of :
(a) protons (b)sigma electrons
(a) (b)
(c)pi electrons (d)none of these
+ + 89.Which among the following statements are
true with respect to electronic displacement
(c) (d) in a covalent bond ?
– (i) Inductive effect operates through a p-
83.Which of the following organic compounds bond
has same hybridization as its combustion (ii) Resonance effect operates through a s-
product (CO2) ? bond
(a) Ethane (b)Ethyne (iii) Inductive effect operates through a  -
bond
(c)Ethene (d)Ethanol
(iv) Resonance effect operates through a
84.What is the hybridisation state of benzyl
p-bond
carbonium ion
(a) i and ii (b)i and iii

CH2 ?
(c)ii and iii (d)iii and iv
90.CH3CH2CI undergoes homolytic fission
(a) sp 2 (b)spd 2 produces :
(c)sp 2 d (d)sp 3 •
85.Which of the following chemical system is (a) CH3 CH2 and CI•
non aromatic ? 
(b) CH3 CH2 and CI
(a) (b)

(c) CH3 C H2 and CI•
(c) (d)
•
S (d) CH3 CH2 and CI
86.Which of the following is least likely to
behave as Lewis base ?
(a) H2 O (b)NH3
(c)BF 3 (d)OH–
87.The reaction intermediate produce by
homolytic cleavage of bond is called:
(a) carbocations (b)carbanions
(c)free radicals (d)carbenes

| Page No. 4 |
Answer Key :- GOC
46. (c) 47. (d) 48. (d) 49. (a) 50. (d)
51. (a) 52. (d) 53. (a) 54. (a) 55. (d)
56. (b) 57. (b) 58. (b) 59. (d) 60. (a)
61. (c) 62. (b) 63. (b) 64. (c) 65. (d)
66. (c) 67. (c) 68. (d) 69. (d) 70. (d)
71. (a) 72. (d) 73. (b) 74. (b) 75. (b)
76. (b) 77. (d) 78. (d) 79. (d) 80. (a)
81. (d) 82. (a) 83. (b) 84. (a) 85. (d)
86. (c) 87. (c) 88. (c) 89. (d) 90. (a)

| Page No. 5 |
 PARISHRAM ACADEMY

Name of Topic : GOC

Subject : Chemistry Class : XI
Batch :- Max. Marks. 180

46.Which of the following species has electron (b)Implies the transfer of lone pair of
releasing (or +I inductive) effect? electrons from lesser electronegative atom
(a)  NH 2 (b) COOH to the more electronegative atom in a
molecule
(c) –CH CH3 2 (d) C6 H 5
(c)Increases with increase in distance
47.Which of the following belongs to +I group? (d)Implies the atoms ability to cause bond
(a) OH (b) OCH3 polarizatio
(c) COOH (d) CH 3 53.The electromeric effect in organic
48.Which of the following functional group compounds is a
shows – I -effect ? (a) Temporary effect
(a)  O Θ (b)–CH3 (b)Permanent effect
(c)–D (d)  NR2 (c)Temporary or permanent effect
(d)All the above
49.The -I effect is shown by
54.+ R power of the given groups
(a) COOH (b) CH 3 Θ
(I)  O (II) –NH2
(c) CH 3CH 2 (d) CHR2
(III) –OH (IV) –NHCOCH3
50.Decreasing - I power of given groups is in decreasing order is
(I) –COOH (II) NO2 (a) I > II > III > IV (b) IV > III > II > I

(III) N H 3 (IV) –OH (c) I > III > II > IV (d) I > IV > III > II
(a) II > I > IV > III 55.Hyper conjugation is
(b)II > III > IV > I (a)  conjugation
(c)III > II > IV > I (b)Due to delocalization of  and  bonds
(d)III > II > I > IV (c)No bond resonance
51.Which of the following belongs to -I group? (d) All
56.Stability of which intermediate is not given
(a) C6 H 5 (b) CH 3
by hyperconjugation?
(c) CH 2CH 3 (d) C  CH 3 3 (a) Carbocation (b) Carbanion
52.Which of the following statements is correct (c)Carbon free radical (d) All
about inductive effect 57.Removal of hydride ion from a methane
(a) Implies the transfer of lone pair of molecule will give a
electrons from more electronegative atom (a) Methyl radical (b)Carbonium ion
to lesser electronegative atom in a molecule (c)Carbanion (d)Methyl group

| Page No. 1 |
58.Among the following the true property 64.The order of –I effect of orbitals is
H 3C (a) sp3  sp2  sp (b) sp2  sp3  sp
about C–CH3 is
H 3C (c) sp  sp2  sp3 (d) sp3  sp  sp2
(a) non - planar 65.Which of the following statement is
(b)C+ is sp2 - hybridised incorrect ?
(c)Electroophile can attack on C+ (a) Inductive effect is a permanent effect.
(d)Does not undergo hydrolysis (b)Inductive effect travels through  bonds
59.Heterolysis of C-Cl bond produces
(c)–I effect decreases the charge intensity
(a) Two free radicals at carbanion
(b)Two carbonium ions (d)–I effect in chlorobenzene is minimum
(c)Two carbanions at meta position
(d)One cation and one anion 66.Which order is correct regarding the –I
60.The shape of free radicals is effect of the substitutents?
(a) Planar (b)Pyramidal
(a) NR2  OR  F (b)
(c)Tetrahedral (d)Linear
NR2  OR  F
61.Which one of the following statement is not
correct for electrophile (c) NR2  OR  F (d) NR2  OR  F
(a) Electron deficient species are electrophile 67.Incorrect order of –I effect :
(b)Electrophiles are Lewis acids
(c) All positively charged species are (a) –F < – C F3 (b) C  CH C  N
electrophiles (c) NH2  C  CH
(d) AlCl3 , and SO 3 are electrophiles
CH3 O
62.Electrophiles are
(a) Lewis bases (b)Lewis acids (d) N CH3 > N
(c)Amphoteric (d)All of these
CH3 O
63.The group showing strongest –I effect is :
CH3 68.What is the correct order of –I effect of
the following groups?
N (a) F > Cl > Br > I
(a) – F (b)
CH3
CH3 (b)RS – < R2N – < RO –
(c) –N O 2 > – CN > CO2H > –OH
O O
(d)All
(c) NH  S  CH3 (d) S CH3 69.Maximum –I effect is exerted by :
(a) – F (b)–O CH3
O O
(c)  NH2 (d)–COOH

| Page No. 2 |
70.Group showing strongest +M effect 75.Hyperconjugation involves overlap of the
following orbitals :
CH3
(a)  (b)   p
(c) p  p (d)  
(a) NH2 (b) N CH3 76.Identify the group which exert –I, –M &
+M effect
(c) NH  CH3 (d)  O
(a)  N O 2 (b) – NO
71.Which of the following is correct order of
(c) –SO3H (d) C  N
+M effect
77.Identify the group which exerts –I, –M, +M
(a) NH2  OH (b) OH > O effect–
O (a) CH  CH2 (b) CCH

(c) O C CH3 > OH (c) (d) All of these

O 78.Group showing +M, –M, –I effect

O
(d) NH C CH3 > NH2
72.Which of the following show both +M and (a) NH  C  CH3 (b) NO2
–M effect
(c) SO3H (d) CH  CH2
(a) – OH (b) –NO2
79.The strongest ortho - para and strongest
(c) – F (d) meta directing groups respectively are
(a) –NO2 and –NH2
(b)–CONH2 and –NH2
73.Which of the following group when attached
to benzene ring show – M effect (c)–NH2 and –CONH2
 
(d)–NH2 and –NO2
(a)  NR3 (b)  P R 3
80.Hybridisation states of C in CH3 and CH4
(c)  C 2H 5 (d) OCH3 are
74.In the anion HCOO  , the two carbon-oxy- (a) sp2 & sp3 (b) sp3 & sp2
gen bonds are found to be equal length. (c) sp2 & sp2 (d) sp3 & sp3
What is the reason for it ? 81.Which of the following species is not
(a) The C = O bond is weaker than the C – aromatic ?
O bond (a) Benzene
(b)The anion HCOO– has two equivalent (b)Cyclooctatetraenyl dianion
resonating structures
(c)Tropylium ion
(c)The electronic orbitals of carbon atom
(d)Cyclopentadienyl cation
are hybridized
(d)The anion is obtained by removal of a
proton from the acid molecule

| Page No. 3 |
82.Among the following the aromatic 88.Mesomeric effect involves the
compound delocalisation of :
(a) protons (b)sigma electrons
(a) (b)
(c)pi electrons (d)none of these
+ + 89.Which among the following statements are
true with respect to electronic displacement
(c) (d) in a covalent bond ?
– (i) Inductive effect operates through a p-
83.Which of the following organic compounds bond
has same hybridization as its combustion (ii) Resonance effect operates through a s-
product (CO2) ? bond
(a) Ethane (b)Ethyne (iii) Inductive effect operates through a  -
bond
(c)Ethene (d)Ethanol
(iv) Resonance effect operates through a
84.What is the hybridisation state of benzyl
p-bond
carbonium ion
(a) i and ii (b)i and iii

CH2 ?
(c)ii and iii (d)iii and iv
90.CH3CH2CI undergoes homolytic fission
(a) sp 2 (b)spd 2 produces :
(c)sp 2 d (d)sp 3 •
85.Which of the following chemical system is (a) CH3 CH2 and CI•
non aromatic ? 
(b) CH3 CH2 and CI
(a) (b)

(c) CH3 C H2 and CI•
(c) (d)
•
S (d) CH3 CH2 and CI
86.Which of the following is least likely to
behave as Lewis base ?
(a) H2 O (b)NH3
(c)BF 3 (d)OH–
87.The reaction intermediate produce by
homolytic cleavage of bond is called:
(a) carbocations (b)carbanions
(c)free radicals (d)carbenes

| Page No. 4 |
Answer Key :- GOC
46. (c) 47. (d) 48. (d) 49. (a) 50. (d)
51. (a) 52. (d) 53. (a) 54. (a) 55. (d)
56. (b) 57. (b) 58. (b) 59. (d) 60. (a)
61. (c) 62. (b) 63. (b) 64. (c) 65. (d)
66. (c) 67. (c) 68. (d) 69. (d) 70. (d)
71. (a) 72. (d) 73. (b) 74. (b) 75. (b)
76. (b) 77. (d) 78. (d) 79. (d) 80. (a)
81. (d) 82. (a) 83. (b) 84. (a) 85. (d)
86. (c) 87. (c) 88. (c) 89. (d) 90. (a)

| Page No. 5 |
 PARISHRAM ACADEMY

Name of Topic : GOC

Subject : Chemistry Class : XI
Batch :- Max. Marks. 180

46.Which of the following species has electron (b)Implies the transfer of lone pair of
releasing (or +I inductive) effect? electrons from lesser electronegative atom
(a)  NH 2 (b) COOH to the more electronegative atom in a
molecule
(c) –CH CH3 2 (d) C6 H 5
(c)Increases with increase in distance
47.Which of the following belongs to +I group? (d)Implies the atoms ability to cause bond
(a) OH (b) OCH3 polarizatio
(c) COOH (d) CH 3 53.The electromeric effect in organic
48.Which of the following functional group compounds is a
shows – I -effect ? (a) Temporary effect
(a)  O Θ (b)–CH3 (b)Permanent effect
(c)–D (d)  NR2 (c)Temporary or permanent effect
(d)All the above
49.The -I effect is shown by
54.+ R power of the given groups
(a) COOH (b) CH 3 Θ
(I)  O (II) –NH2
(c) CH 3CH 2 (d) CHR2
(III) –OH (IV) –NHCOCH3
50.Decreasing - I power of given groups is in decreasing order is
(I) –COOH (II) NO2 (a) I > II > III > IV (b) IV > III > II > I

(III) N H 3 (IV) –OH (c) I > III > II > IV (d) I > IV > III > II
(a) II > I > IV > III 55.Hyper conjugation is
(b)II > III > IV > I (a)  conjugation
(c)III > II > IV > I (b)Due to delocalization of  and  bonds
(d)III > II > I > IV (c)No bond resonance
51.Which of the following belongs to -I group? (d) All
56.Stability of which intermediate is not given
(a) C6 H 5 (b) CH 3
by hyperconjugation?
(c) CH 2CH 3 (d) C  CH 3 3 (a) Carbocation (b) Carbanion
52.Which of the following statements is correct (c)Carbon free radical (d) All
about inductive effect 57.Removal of hydride ion from a methane
(a) Implies the transfer of lone pair of molecule will give a
electrons from more electronegative atom (a) Methyl radical (b)Carbonium ion
to lesser electronegative atom in a molecule (c)Carbanion (d)Methyl group

| Page No. 1 |
58.Among the following the true property 64.The order of –I effect of orbitals is
H 3C (a) sp3  sp2  sp (b) sp2  sp3  sp
about C–CH3 is
H 3C (c) sp  sp2  sp3 (d) sp3  sp  sp2
(a) non - planar 65.Which of the following statement is
(b)C+ is sp2 - hybridised incorrect ?
(c)Electroophile can attack on C+ (a) Inductive effect is a permanent effect.
(d)Does not undergo hydrolysis (b)Inductive effect travels through  bonds
59.Heterolysis of C-Cl bond produces
(c)–I effect decreases the charge intensity
(a) Two free radicals at carbanion
(b)Two carbonium ions (d)–I effect in chlorobenzene is minimum
(c)Two carbanions at meta position
(d)One cation and one anion 66.Which order is correct regarding the –I
60.The shape of free radicals is effect of the substitutents?
(a) Planar (b)Pyramidal
(a) NR2  OR  F (b)
(c)Tetrahedral (d)Linear
NR2  OR  F
61.Which one of the following statement is not
correct for electrophile (c) NR2  OR  F (d) NR2  OR  F
(a) Electron deficient species are electrophile 67.Incorrect order of –I effect :
(b)Electrophiles are Lewis acids
(c) All positively charged species are (a) –F < – C F3 (b) C  CH C  N
electrophiles (c) NH2  C  CH
(d) AlCl3 , and SO 3 are electrophiles
CH3 O
62.Electrophiles are
(a) Lewis bases (b)Lewis acids (d) N CH3 > N
(c)Amphoteric (d)All of these
CH3 O
63.The group showing strongest –I effect is :
CH3 68.What is the correct order of –I effect of
the following groups?
N (a) F > Cl > Br > I
(a) – F (b)
CH3
CH3 (b)RS – < R2N – < RO –
(c) –N O 2 > – CN > CO2H > –OH
O O
(d)All
(c) NH  S  CH3 (d) S CH3 69.Maximum –I effect is exerted by :
(a) – F (b)–O CH3
O O
(c)  NH2 (d)–COOH

| Page No. 2 |
70.Group showing strongest +M effect 75.Hyperconjugation involves overlap of the
following orbitals :
CH3
(a)  (b)   p
(c) p  p (d)  
(a) NH2 (b) N CH3 76.Identify the group which exert –I, –M &
+M effect
(c) NH  CH3 (d)  O
(a)  N O 2 (b) – NO
71.Which of the following is correct order of
(c) –SO3H (d) C  N
+M effect
77.Identify the group which exerts –I, –M, +M
(a) NH2  OH (b) OH > O effect–
O (a) CH  CH2 (b) CCH

(c) O C CH3 > OH (c) (d) All of these

O 78.Group showing +M, –M, –I effect

O
(d) NH C CH3 > NH2
72.Which of the following show both +M and (a) NH  C  CH3 (b) NO2
–M effect
(c) SO3H (d) CH  CH2
(a) – OH (b) –NO2
79.The strongest ortho - para and strongest
(c) – F (d) meta directing groups respectively are
(a) –NO2 and –NH2
(b)–CONH2 and –NH2
73.Which of the following group when attached
to benzene ring show – M effect (c)–NH2 and –CONH2
 
(d)–NH2 and –NO2
(a)  NR3 (b)  P R 3
80.Hybridisation states of C in CH3 and CH4
(c)  C 2H 5 (d) OCH3 are
74.In the anion HCOO  , the two carbon-oxy- (a) sp2 & sp3 (b) sp3 & sp2
gen bonds are found to be equal length. (c) sp2 & sp2 (d) sp3 & sp3
What is the reason for it ? 81.Which of the following species is not
(a) The C = O bond is weaker than the C – aromatic ?
O bond (a) Benzene
(b)The anion HCOO– has two equivalent (b)Cyclooctatetraenyl dianion
resonating structures
(c)Tropylium ion
(c)The electronic orbitals of carbon atom
(d)Cyclopentadienyl cation
are hybridized
(d)The anion is obtained by removal of a
proton from the acid molecule

| Page No. 3 |
82.Among the following the aromatic 88.Mesomeric effect involves the
compound delocalisation of :
(a) protons (b)sigma electrons
(a) (b)
(c)pi electrons (d)none of these
+ + 89.Which among the following statements are
true with respect to electronic displacement
(c) (d) in a covalent bond ?
– (i) Inductive effect operates through a p-
83.Which of the following organic compounds bond
has same hybridization as its combustion (ii) Resonance effect operates through a s-
product (CO2) ? bond
(a) Ethane (b)Ethyne (iii) Inductive effect operates through a  -
bond
(c)Ethene (d)Ethanol
(iv) Resonance effect operates through a
84.What is the hybridisation state of benzyl
p-bond
carbonium ion
(a) i and ii (b)i and iii

CH2 ?
(c)ii and iii (d)iii and iv
90.CH3CH2CI undergoes homolytic fission
(a) sp 2 (b)spd 2 produces :
(c)sp 2 d (d)sp 3 •
85.Which of the following chemical system is (a) CH3 CH2 and CI•
non aromatic ? 
(b) CH3 CH2 and CI
(a) (b)

(c) CH3 C H2 and CI•
(c) (d)
•
S (d) CH3 CH2 and CI
86.Which of the following is least likely to
behave as Lewis base ?
(a) H2 O (b)NH3
(c)BF 3 (d)OH–
87.The reaction intermediate produce by
homolytic cleavage of bond is called:
(a) carbocations (b)carbanions
(c)free radicals (d)carbenes

| Page No. 4 |
Answer Key :- GOC
46. (c) 47. (d) 48. (d) 49. (a) 50. (d)
51. (a) 52. (d) 53. (a) 54. (a) 55. (d)
56. (b) 57. (b) 58. (b) 59. (d) 60. (a)
61. (c) 62. (b) 63. (b) 64. (c) 65. (d)
66. (c) 67. (c) 68. (d) 69. (d) 70. (d)
71. (a) 72. (d) 73. (b) 74. (b) 75. (b)
76. (b) 77. (d) 78. (d) 79. (d) 80. (a)
81. (d) 82. (a) 83. (b) 84. (a) 85. (d)
86. (c) 87. (c) 88. (c) 89. (d) 90. (a)

| Page No. 5 |
 PARISHRAM ACADEMY

Name of Topic : GOC

Subject : Chemistry Class : XI
Batch :- Max. Marks. 180

46.Which of the following species has electron (b)Implies the transfer of lone pair of
releasing (or +I inductive) effect? electrons from lesser electronegative atom
(a)  NH 2 (b) COOH to the more electronegative atom in a
molecule
(c) –CH CH3 2 (d) C6 H 5
(c)Increases with increase in distance
47.Which of the following belongs to +I group? (d)Implies the atoms ability to cause bond
(a) OH (b) OCH3 polarizatio
(c) COOH (d) CH 3 53.The electromeric effect in organic
48.Which of the following functional group compounds is a
shows – I -effect ? (a) Temporary effect
(a)  O Θ (b)–CH3 (b)Permanent effect
(c)–D (d)  NR2 (c)Temporary or permanent effect
(d)All the above
49.The -I effect is shown by
54.+ R power of the given groups
(a) COOH (b) CH 3 Θ
(I)  O (II) –NH2
(c) CH 3CH 2 (d) CHR2
(III) –OH (IV) –NHCOCH3
50.Decreasing - I power of given groups is in decreasing order is
(I) –COOH (II) NO2 (a) I > II > III > IV (b) IV > III > II > I

(III) N H 3 (IV) –OH (c) I > III > II > IV (d) I > IV > III > II
(a) II > I > IV > III 55.Hyper conjugation is
(b)II > III > IV > I (a)  conjugation
(c)III > II > IV > I (b)Due to delocalization of  and  bonds
(d)III > II > I > IV (c)No bond resonance
51.Which of the following belongs to -I group? (d) All
56.Stability of which intermediate is not given
(a) C6 H 5 (b) CH 3
by hyperconjugation?
(c) CH 2CH 3 (d) C  CH 3 3 (a) Carbocation (b) Carbanion
52.Which of the following statements is correct (c)Carbon free radical (d) All
about inductive effect 57.Removal of hydride ion from a methane
(a) Implies the transfer of lone pair of molecule will give a
electrons from more electronegative atom (a) Methyl radical (b)Carbonium ion
to lesser electronegative atom in a molecule (c)Carbanion (d)Methyl group

| Page No. 1 |
58.Among the following the true property 64.The order of –I effect of orbitals is
H 3C (a) sp3  sp2  sp (b) sp2  sp3  sp
about C–CH3 is
H 3C (c) sp  sp2  sp3 (d) sp3  sp  sp2
(a) non - planar 65.Which of the following statement is
(b)C+ is sp2 - hybridised incorrect ?
(c)Electroophile can attack on C+ (a) Inductive effect is a permanent effect.
(d)Does not undergo hydrolysis (b)Inductive effect travels through  bonds
59.Heterolysis of C-Cl bond produces
(c)–I effect decreases the charge intensity
(a) Two free radicals at carbanion
(b)Two carbonium ions (d)–I effect in chlorobenzene is minimum
(c)Two carbanions at meta position
(d)One cation and one anion 66.Which order is correct regarding the –I
60.The shape of free radicals is effect of the substitutents?
(a) Planar (b)Pyramidal
(a) NR2  OR  F (b)
(c)Tetrahedral (d)Linear
NR2  OR  F
61.Which one of the following statement is not
correct for electrophile (c) NR2  OR  F (d) NR2  OR  F
(a) Electron deficient species are electrophile 67.Incorrect order of –I effect :
(b)Electrophiles are Lewis acids
(c) All positively charged species are (a) –F < – C F3 (b) C  CH C  N
electrophiles (c) NH2  C  CH
(d) AlCl3 , and SO 3 are electrophiles
CH3 O
62.Electrophiles are
(a) Lewis bases (b)Lewis acids (d) N CH3 > N
(c)Amphoteric (d)All of these
CH3 O
63.The group showing strongest –I effect is :
CH3 68.What is the correct order of –I effect of
the following groups?
N (a) F > Cl > Br > I
(a) – F (b)
CH3
CH3 (b)RS – < R2N – < RO –
(c) –N O 2 > – CN > CO2H > –OH
O O
(d)All
(c) NH  S  CH3 (d) S CH3 69.Maximum –I effect is exerted by :
(a) – F (b)–O CH3
O O
(c)  NH2 (d)–COOH

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70.Group showing strongest +M effect 75.Hyperconjugation involves overlap of the
following orbitals :
CH3
(a)  (b)   p
(c) p  p (d)  
(a) NH2 (b) N CH3 76.Identify the group which exert –I, –M &
+M effect
(c) NH  CH3 (d)  O
(a)  N O 2 (b) – NO
71.Which of the following is correct order of
(c) –SO3H (d) C  N
+M effect
77.Identify the group which exerts –I, –M, +M
(a) NH2  OH (b) OH > O effect–
O (a) CH  CH2 (b) CCH

(c) O C CH3 > OH (c) (d) All of these

O 78.Group showing +M, –M, –I effect

O
(d) NH C CH3 > NH2
72.Which of the following show both +M and (a) NH  C  CH3 (b) NO2
–M effect
(c) SO3H (d) CH  CH2
(a) – OH (b) –NO2
79.The strongest ortho - para and strongest
(c) – F (d) meta directing groups respectively are
(a) –NO2 and –NH2
(b)–CONH2 and –NH2
73.Which of the following group when attached
to benzene ring show – M effect (c)–NH2 and –CONH2
 
(d)–NH2 and –NO2
(a)  NR3 (b)  P R 3
80.Hybridisation states of C in CH3 and CH4
(c)  C 2H 5 (d) OCH3 are
74.In the anion HCOO  , the two carbon-oxy- (a) sp2 & sp3 (b) sp3 & sp2
gen bonds are found to be equal length. (c) sp2 & sp2 (d) sp3 & sp3
What is the reason for it ? 81.Which of the following species is not
(a) The C = O bond is weaker than the C – aromatic ?
O bond (a) Benzene
(b)The anion HCOO– has two equivalent (b)Cyclooctatetraenyl dianion
resonating structures
(c)Tropylium ion
(c)The electronic orbitals of carbon atom
(d)Cyclopentadienyl cation
are hybridized
(d)The anion is obtained by removal of a
proton from the acid molecule

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82.Among the following the aromatic 88.Mesomeric effect involves the
compound delocalisation of :
(a) protons (b)sigma electrons
(a) (b)
(c)pi electrons (d)none of these
+ + 89.Which among the following statements are
true with respect to electronic displacement
(c) (d) in a covalent bond ?
– (i) Inductive effect operates through a p-
83.Which of the following organic compounds bond
has same hybridization as its combustion (ii) Resonance effect operates through a s-
product (CO2) ? bond
(a) Ethane (b)Ethyne (iii) Inductive effect operates through a  -
bond
(c)Ethene (d)Ethanol
(iv) Resonance effect operates through a
84.What is the hybridisation state of benzyl
p-bond
carbonium ion
(a) i and ii (b)i and iii

CH2 ?
(c)ii and iii (d)iii and iv
90.CH3CH2CI undergoes homolytic fission
(a) sp 2 (b)spd 2 produces :
(c)sp 2 d (d)sp 3 •
85.Which of the following chemical system is (a) CH3 CH2 and CI•
non aromatic ? 
(b) CH3 CH2 and CI
(a) (b)

(c) CH3 C H2 and CI•
(c) (d)
•
S (d) CH3 CH2 and CI
86.Which of the following is least likely to
behave as Lewis base ?
(a) H2 O (b)NH3
(c)BF 3 (d)OH–
87.The reaction intermediate produce by
homolytic cleavage of bond is called:
(a) carbocations (b)carbanions
(c)free radicals (d)carbenes

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Answer Key :- GOC
46. (c) 47. (d) 48. (d) 49. (a) 50. (d)
51. (a) 52. (d) 53. (a) 54. (a) 55. (d)
56. (b) 57. (b) 58. (b) 59. (d) 60. (a)
61. (c) 62. (b) 63. (b) 64. (c) 65. (d)
66. (c) 67. (c) 68. (d) 69. (d) 70. (d)
71. (a) 72. (d) 73. (b) 74. (b) 75. (b)
76. (b) 77. (d) 78. (d) 79. (d) 80. (a)
81. (d) 82. (a) 83. (b) 84. (a) 85. (d)
86. (c) 87. (c) 88. (c) 89. (d) 90. (a)

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 PARISHRAM ACADEMY

Name of Topic : GOC

Subject : Chemistry Class : XI
Batch :- Max. Marks. 180

46.Which of the following species has electron (b)Implies the transfer of lone pair of
releasing (or +I inductive) effect? electrons from lesser electronegative atom
(a)  NH 2 (b) COOH to the more electronegative atom in a
molecule
(c) –CH CH3 2 (d) C6 H 5
(c)Increases with increase in distance
47.Which of the following belongs to +I group? (d)Implies the atoms ability to cause bond
(a) OH (b) OCH3 polarizatio
(c) COOH (d) CH 3 53.The electromeric effect in organic
48.Which of the following functional group compounds is a
shows – I -effect ? (a) Temporary effect
(a)  O Θ (b)–CH3 (b)Permanent effect
(c)–D (d)  NR2 (c)Temporary or permanent effect
(d)All the above
49.The -I effect is shown by
54.+ R power of the given groups
(a) COOH (b) CH 3 Θ
(I)  O (II) –NH2
(c) CH 3CH 2 (d) CHR2
(III) –OH (IV) –NHCOCH3
50.Decreasing - I power of given groups is in decreasing order is
(I) –COOH (II) NO2 (a) I > II > III > IV (b) IV > III > II > I

(III) N H 3 (IV) –OH (c) I > III > II > IV (d) I > IV > III > II
(a) II > I > IV > III 55.Hyper conjugation is
(b)II > III > IV > I (a)  conjugation
(c)III > II > IV > I (b)Due to delocalization of  and  bonds
(d)III > II > I > IV (c)No bond resonance
51.Which of the following belongs to -I group? (d) All
56.Stability of which intermediate is not given
(a) C6 H 5 (b) CH 3
by hyperconjugation?
(c) CH 2CH 3 (d) C  CH 3 3 (a) Carbocation (b) Carbanion
52.Which of the following statements is correct (c)Carbon free radical (d) All
about inductive effect 57.Removal of hydride ion from a methane
(a) Implies the transfer of lone pair of molecule will give a
electrons from more electronegative atom (a) Methyl radical (b)Carbonium ion
to lesser electronegative atom in a molecule (c)Carbanion (d)Methyl group

| Page No. 1 |
58.Among the following the true property 64.The order of –I effect of orbitals is
H 3C (a) sp3  sp2  sp (b) sp2  sp3  sp
about C–CH3 is
H 3C (c) sp  sp2  sp3 (d) sp3  sp  sp2
(a) non - planar 65.Which of the following statement is
(b)C+ is sp2 - hybridised incorrect ?
(c)Electroophile can attack on C+ (a) Inductive effect is a permanent effect.
(d)Does not undergo hydrolysis (b)Inductive effect travels through  bonds
59.Heterolysis of C-Cl bond produces
(c)–I effect decreases the charge intensity
(a) Two free radicals at carbanion
(b)Two carbonium ions (d)–I effect in chlorobenzene is minimum
(c)Two carbanions at meta position
(d)One cation and one anion 66.Which order is correct regarding the –I
60.The shape of free radicals is effect of the substitutents?
(a) Planar (b)Pyramidal
(a) NR2  OR  F (b)
(c)Tetrahedral (d)Linear
NR2  OR  F
61.Which one of the following statement is not
correct for electrophile (c) NR2  OR  F (d) NR2  OR  F
(a) Electron deficient species are electrophile 67.Incorrect order of –I effect :
(b)Electrophiles are Lewis acids
(c) All positively charged species are (a) –F < – C F3 (b) C  CH C  N
electrophiles (c) NH2  C  CH
(d) AlCl3 , and SO 3 are electrophiles
CH3 O
62.Electrophiles are
(a) Lewis bases (b)Lewis acids (d) N CH3 > N
(c)Amphoteric (d)All of these
CH3 O
63.The group showing strongest –I effect is :
CH3 68.What is the correct order of –I effect of
the following groups?
N (a) F > Cl > Br > I
(a) – F (b)
CH3
CH3 (b)RS – < R2N – < RO –
(c) –N O 2 > – CN > CO2H > –OH
O O
(d)All
(c) NH  S  CH3 (d) S CH3 69.Maximum –I effect is exerted by :
(a) – F (b)–O CH3
O O
(c)  NH2 (d)–COOH

| Page No. 2 |
70.Group showing strongest +M effect 75.Hyperconjugation involves overlap of the
following orbitals :
CH3
(a)  (b)   p
(c) p  p (d)  
(a) NH2 (b) N CH3 76.Identify the group which exert –I, –M &
+M effect
(c) NH  CH3 (d)  O
(a)  N O 2 (b) – NO
71.Which of the following is correct order of
(c) –SO3H (d) C  N
+M effect
77.Identify the group which exerts –I, –M, +M
(a) NH2  OH (b) OH > O effect–
O (a) CH  CH2 (b) CCH

(c) O C CH3 > OH (c) (d) All of these

O 78.Group showing +M, –M, –I effect

O
(d) NH C CH3 > NH2
72.Which of the following show both +M and (a) NH  C  CH3 (b) NO2
–M effect
(c) SO3H (d) CH  CH2
(a) – OH (b) –NO2
79.The strongest ortho - para and strongest
(c) – F (d) meta directing groups respectively are
(a) –NO2 and –NH2
(b)–CONH2 and –NH2
73.Which of the following group when attached
to benzene ring show – M effect (c)–NH2 and –CONH2
 
(d)–NH2 and –NO2
(a)  NR3 (b)  P R 3
80.Hybridisation states of C in CH3 and CH4
(c)  C 2H 5 (d) OCH3 are
74.In the anion HCOO  , the two carbon-oxy- (a) sp2 & sp3 (b) sp3 & sp2
gen bonds are found to be equal length. (c) sp2 & sp2 (d) sp3 & sp3
What is the reason for it ? 81.Which of the following species is not
(a) The C = O bond is weaker than the C – aromatic ?
O bond (a) Benzene
(b)The anion HCOO– has two equivalent (b)Cyclooctatetraenyl dianion
resonating structures
(c)Tropylium ion
(c)The electronic orbitals of carbon atom
(d)Cyclopentadienyl cation
are hybridized
(d)The anion is obtained by removal of a
proton from the acid molecule

| Page No. 3 |
82.Among the following the aromatic 88.Mesomeric effect involves the
compound delocalisation of :
(a) protons (b)sigma electrons
(a) (b)
(c)pi electrons (d)none of these
+ + 89.Which among the following statements are
true with respect to electronic displacement
(c) (d) in a covalent bond ?
– (i) Inductive effect operates through a p-
83.Which of the following organic compounds bond
has same hybridization as its combustion (ii) Resonance effect operates through a s-
product (CO2) ? bond
(a) Ethane (b)Ethyne (iii) Inductive effect operates through a  -
bond
(c)Ethene (d)Ethanol
(iv) Resonance effect operates through a
84.What is the hybridisation state of benzyl
p-bond
carbonium ion
(a) i and ii (b)i and iii

CH2 ?
(c)ii and iii (d)iii and iv
90.CH3CH2CI undergoes homolytic fission
(a) sp 2 (b)spd 2 produces :
(c)sp 2 d (d)sp 3 •
85.Which of the following chemical system is (a) CH3 CH2 and CI•
non aromatic ? 
(b) CH3 CH2 and CI
(a) (b)

(c) CH3 C H2 and CI•
(c) (d)
•
S (d) CH3 CH2 and CI
86.Which of the following is least likely to
behave as Lewis base ?
(a) H2 O (b)NH3
(c)BF 3 (d)OH–
87.The reaction intermediate produce by
homolytic cleavage of bond is called:
(a) carbocations (b)carbanions
(c)free radicals (d)carbenes

| Page No. 4 |
Answer Key :- GOC
46. (c) 47. (d) 48. (d) 49. (a) 50. (d)
51. (a) 52. (d) 53. (a) 54. (a) 55. (d)
56. (b) 57. (b) 58. (b) 59. (d) 60. (a)
61. (c) 62. (b) 63. (b) 64. (c) 65. (d)
66. (c) 67. (c) 68. (d) 69. (d) 70. (d)
71. (a) 72. (d) 73. (b) 74. (b) 75. (b)
76. (b) 77. (d) 78. (d) 79. (d) 80. (a)
81. (d) 82. (a) 83. (b) 84. (a) 85. (d)
86. (c) 87. (c) 88. (c) 89. (d) 90. (a)

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