MAGNETIC SCIENCE INSTITUTE

Full Syllabus GUJCET-CHEMISTRY-PAPER 2 Date : 26/03/24

Total Marks-40 GUJCET Time-1:00 hrs
Section A
//X
• Choose correct answer from the given options. [Each carries 1 Mark] [40]

38)
1. The depression in freezing point for 0.01 m aqueous solution of KX[Fe(CN)6] is 0.0744 K. The molal
depression constant for solvent is 1.86 K kg mol–1. If the solute undergoes complete dissociation, what is
the correct molecular formula for the solute ?
(A) K2[Fe(CN)6] (B) K3[Fe(CN)6] (C) K[Fe(CN)6] (D) K4[Fe(CN)6]
37)
2. Which solution is isotonic with 6% w/v aqueous solution of urea ? [Molar mass of Urea = 60 gm. mol–1]
(A) 0.1 M NaCl (B) 0.5 M NaCl (C) 0.25 M NaCl (D) 1 M NaCl
24)
3. Value of Henry's constant KH _______.
(A) no effect by changing temperature
(B) decreases with increase in temperature
(C) increases with increase in temperature
(D) first decreases and then increases by increase in temperature
7)
4. Which mixture shows positive deviation from Raoult's law ?
(A) Phenol + Aniline (B) Ethanol + Acetone (C) Chloroform + Acetone (D) Nitric acid + Water
91)
5. If EoFe3+ /Fe = x v, EoFe2+ /Fe = y v then what will be the value of EoFe3+ /Fe2+ = ?
(A) x – y (B) 3x + 2y (C) 2x + y (D) 3x – 2y
105) Which of the following will be possible in electrochemical cell obtained from
6.
o
EC l |2Cl−
= 1.36 V and EoBr − = 1.09 V ?
2 2 | 2Br

(A) 2Cl– + 2Br– → Cl2 + Br2 (B) 2Br– + Cl2 → Br2 + 2Cl–
(C) Br2 + 2Cl– → 2Br– + Cl2 (D) Cl2 + Br2 → 2Cl– + 2Br–
126) For how much time, 10 ampere electric current should be passed through a dilute aqueous NiSO4 solution
7.
during electrolysis using inert electrode, in order to get 5.85 gm Nickel ? [At. mass of Ni = 58.5 gm]
(A) 1930 sec. (B) 3860 sec. (C) 965 sec. (D) 9650 sec.
89)
8. Dry cell cannot be recharged because -
(A) Mn (III) cannot be oxidised again to Mn (IV)
(B) It is a primary cell
(C) Mn (III) cannot be reduced to Mn (IV)
(D) It has paste of NH4Cl + ZnCl2
219) For Fourth Order Reaction, what is the unit of K ?
9.
(A) (mole/litre)–3 (B) (mole/litre)–3 second
(C) (mole/litre)+3 second–1 (D) (mole/litre)–3 second–1
216) The value of rate constant for a first order reaction is 2.303 × 10–2 sec–1. What will be the time required
10.
1
to reduce the concentration to th of its initial concentration ?
10
(A) 10 second (B) 100 second (C) 2303 second (D) 230.3 second
209) At 298 K temperature the activation energy for the reaction x2 + y2 → 2xy + 20 kJ is 15 kJ. What will
11.
be the activation energy for the reaction 2xy → x2 + y2 ?
(A) – 15 kJ (B) + 35 kJ (C) – 5 kJ (D) – 35 kJ
209) At 298 K temperature the activation energy for the reaction x2 + y2 → 2xy + 20 kJ is 15 kJ. What will
be the activation energy for the reaction 2xy → x2 + y2 ?
(A) – 15 kJ (B) + 35 kJ (C) – 5 kJ (D) – 35 kJ
180) Which of the following is bimolecular reaction ?
12.
(A) N2 + 3H2 → 2NH3 (B) 2NH3 → N2 + 3H2
(C) NH4NO2 → N2 + 2H2O (D) 2NO + O2 → 2NO2
276) In the electronic configuration of which of the following element-electron is arranged in 5d orbital ?
13.
(A) 64Gd (B) 63Eu (C) 65Tb (D) 66Dy
270) Which of the following is amphoteric oxide ?
14.
Mn2O7, CrO3, Cr2O3, CrO, V2O5, V2O4
(A) Mn2O7, CrO (B) CrO3, V2O4 (C) V2O5, Cr2O3 (D) Cr2O3, Mn2O7
317) Which one of the following statements related to lanthanoid is incorrect ?
15.
(A) Ce (+4) solutions are widely used as oxidizing agent in volumetric analysis.
(B) Europium shows +2 oxidation state.
(C) The basicity decreases as the ionic radius decreases from Pr to Lu.
(D) All the lanthanous are much more reactive than aluminium.
307) The incorrect statement among the following is :
16.
(A) Actinoid contraction is greater for element to element than Lanthanoid contraction.
(B) Most of the trivalent Lanthanoid ions are colorless in the solid state.
(C) Lanthanoids are good conductors of heat and electricity.
(D) Actinoids are highly reactive metals, especially when finely divided.
406) Which ligand is useful for removal of the toxic effect of lead metal in body in chelate therapy treatment.
17.
(A) CH3COO– (B) COO–
|
COO–
(C) AsO43– (D) –OOC ⋅ H2C CH2 ⋅ COO–
N – CH2 – CH2 – N
–
OOC ⋅ H2C CH2 ⋅ COO–

403) Which complex compound possesses sp3d2 hybridisation ?

18.
(A) [Fe(Cl)6]3– (B) [Fe(CN)6]3– (C) [Fe(CN)6]4– (D) [Fe(NH3)6]3+
400) Which of the following complex does not show optical isomerism ?
19.
(A) [Cr(C2O4)3]3– (B) Cis[Pt(Br)2(en)2]2+ (C) [CrCl2(NH3)2en]+ (D) [Cr(NH3)4SO4]+
397) Which of the following spectrochemical series is true ?
20.
(A) SCN– < F– < NH3 < en < CO (B) SCN– < NH3 < F– < en < CO
(C) SCN– < F– < en < NH3 < CO (D) SCN– < F– < en < CO < NH3
25)
21. What is the IUPAC name of the following compound ?
H 3C H

H H Cl
(A) 4-chloro pent -2-ene (B) 1-chloro but -3- ene
(C) 3-chloro 2-methyl but-1-ene (D) 1-chloro but-2-ene
24)
22. Which of the following statement is incorrect for bimolecular nucleophylic substiturion reaction (SN2) ?
(A) It is a second order reaction
(B) In SN2 reaction the substrate does not undergo heterocylic fission
(C) The rate of SN2 reaction does not depends on concentrations of both substrate and nucleophilic reagent.
Happy Ending...
(D) SN2 reaction occurs in single step without proming inter mediate.
 (A) It is a second order reaction
(B) In SN2 reaction the substrate does not undergo heterocylic fission
(C) The rate of SN2 reaction does not depends on concentrations of both substrate and nucleophilic reagent.
(D) SN2 reaction occurs in single step without proming inter mediate.
57)
23. Which of the following is not chiral ?
(A) 2-hydroxypropanoic acid (B) 2-Butanol
(C) 2, 3-Di bromo pentane (D) 3-bromo pentane
27)
24. The order of polarity of CH3I, CH3Br and CH3Cl molecules follows the order :
(A) CH3Br > CH3Cl > CH3l (B) CH3I > CH3Br > CH3Cl
(C) CH3Cl > CH3Br > CH3I (D) CH3Cl > CH3I > CH3Br
166) How many σ (sigma) and π (pie) bonds are present respectively in the final product obtained by the Reimer-Tiemann
25.
reaction of phenol ?
(A) 15 and 3 (B) 14 and 4 (C) 15 and 4 (D) 14 and 3
37)
26. What is the C-O-H bond angle in phenol?
(A) 111.7° (B) 108° (C) 109° (D) 120°
142) Which compound has highest value of pka ?
27.
(A) p-cresol (B) phenol (C) o-nitrophenol (D) m-nitrophenol
(i) B2H6 H 3O +
13) Q
28. CH2 products P and Q are respectively?
(ii) H2O2/OH–
CH3
(A) both CH2OH (B) both
OH
CH3 CH3
(C) P = CH2OH and Q = (D) P = and Q = CH2OH
OH OH
253) Which reagent is useful in the conversion of ethanenitrile to ethanol ?
29.
(A) Anhydrus CrO3 (B) PCC (C) DIBAL-H (D) LiAlH4
259) What will be the main product in the following reaction ?
30.
–
CHO + CH3CHO OH ?
∆

(A) CH2 – CH – CHO (B) CH = CH – CHO

OH
(C) CH2 – CH2 – CHO (D) CH = CH – COOH

279) The solution of Fehling B contains _____

31.
(A) Alkaline sodium potassium citrate (B) Acidified Rochelle salt
(C) Alkaline sodium potassium tartarate (D) Acidified sodium potassium citrate

KMnO4/KOH CH3Cl
Sodalime
267) P
32. Q ∆ R Anhyrous AlCl3 S If P and S are tolune; Q and R are ________ and ________
respectively
(A) Benzoic acid, Benzene (B) Benzaldehyde, Benzoic Acid
(C) Benzaldehyde, sodium benzoate (D) Benzene, Benzoic Acid
315) In a set of reaction m-bromo benzoic acid gave a product D identify the product D.
33.
COOH
SOCl2 NH3 NaOH
B C D
Br Br2
CONH2 SO2NH2 COOH NH2
(A) (B) (C) (D)
Br Br NH2 Br

Happy Ending...
295) compound A, C8H10O is found to react with NaOI (produced by reacting Y with NaOH) and yields a yellow precipitate
34.
with characteristic smell. A and Y respectively

(A) H3C CH2 – OH and I2 (B) CH – CH3 and I2

OH
CH3

(C) CH2 – CH2 – OH and I2 (D) CH3 OH and I2

419) Which order is improper for amine compounds ?

35.
(A) order of basicity in aq. medium
CH3–NH–CH3 > CH3NH2 > CH3–N–CH3
CH3
(B) order of boiling point
CH3–N–CH3 > CH3–CH2–NH–CH3 > CH3–CH2 –CH2–NH2
CH3

(C) order of basicity in gaseous state

CH3–N–CH3 > CH3NH–CH3 > CH3NH2
CH3
(D) The order of aqueous solubility.
CH3–N–CH3 < CH3–CH2–NH–CH3 < CH3–CH2 –CH2–NH2
CH3

424) Which of the following reaction is not taking place ?

36.
(A) Tripropyl amine + Benzene sulphonyl chloride (B) Dipropyl amine + Benzene sulphonyl chloride
(C) Propyl amine + Benzene sulphonyl chloride (D) Proply amine + para toluene sulphonyl chloride

AgCN LiAlH4
68)
37. 2-Bromopropane x y, then IUPAC name of y is _________.
Alcoholic
∆
(A) Butane-2-amine (B) N-Methyl propane amine
(C) N-Methyl propane-2-amine (D) N-Isopropyl Methane amine
531) Which glycosidic linkage occurs in 'Amylopectin'
38.
(A) C1 – C3 and C1 – C4 (B) C1 – C4 and C1 – C6
(C) C1 – C2 and C1 – C6 (D) C2 – C4 and C4 – C6
220) Which hormone controls the amount of water and salts excreted by the kidneys ?
39.
(A) Mineralocorticoides (B) Glucocorticoides (C) Testosterone (D) Estradiol
185) Connect vitamins with diseases caused by its deficiency :
40.
Section X Section Y
(1) Vitamin – A (A) Pernicious Anemia
(2) Vitamin – B1 (B) Bleeding
(3) Vitamin – E (C) Beriberi
(4) Vitamin – K (D) Impotence
(E) Nightblindness
(A) (1) - (D), (2) - (A), (3) - (C), (4) - (B) (B) (1) - (C), (2) - (B), (3) - (A), (4) - (D)
(C) (1) - (E), (2) - (C), (3) - (D), (4) - (B) (D) (1) - (B), (2) - (E), (3) - (D), (4) - (A)

Happy Ending...
 MAGNETIC SCIENCE INSTITUTE
Full Syllabus GUJCET-CHEMISTRY-PAPER 2 Date : 26/03/24
Total Marks-40 GUJCET Time-1:00 hrs

Section [ A ] : 1 Mark MCQ

No Ans Chap Sec Que Universal_QueId

1. B Chap 1 S5 38 QP23P13B1212_P1C1S5Q38
2. B Chap 1 S5 37 QP23P13B1212_P1C1S5Q37
3. C Chap 1 S5 24 QP23P13B1212_P1C1S5Q24
4. B Chap 1 S5 7 QP23P13B1212_P1C1S5Q7
5. D Chap 2 S5 91 QP23P13B1212_P1C2S5Q91
6. B Chap 2 S5 105 QP23P13B1212_P1C2S5Q105
7. A Chap 2 S5 126 QP23P13B1212_P1C2S5Q126
8. A Chap 2 S4 89 QP23P13B1212_P1C2S4Q89
9. D Chap 3 S5 219 QP23P13B1212_P1C3S5Q219
10. B Chap 3 S5 216 QP23P13B1212_P1C3S5Q216
11. B Chap 3 S5 209 QP23P13B1212_P1C3S5Q209
12. B Chap 3 S5 180 QP23P13B1212_P1C3S5Q180
13. A Chap 4 S5 276 QP23P13B1212_P1C4S5Q276
14. C Chap 4 S5 270 QP23P13B1212_P1C4S5Q270
15. C Chap 4 S6 317 QP23P13B1212_P1C4S6Q317
16. B Chap 4 S6 307 QP23P13B1212_P1C4S6Q307
17. D Chap 5 S5 406 QP23P13B1212_P1C5S5Q406
18. A Chap 5 S5 403 QP23P13B1212_P1C5S5Q403
19. D Chap 5 S5 400 QP23P13B1212_P1C5S5Q400
20. A Chap 5 S5 397 QP23P13B1212_P1C5S5Q397
21. D Chap 6 S5 25 QP23P13B1212_P2C6S5Q25
22. C Chap 6 S5 24 QP23P13B1212_P2C6S5Q24
23. D Chap 6 S6 57 QP23P13B1212_P2C6S6Q57
24. C Chap 6 S4 27 QP23P13B1212_P2C6S4Q27
25. C Chap 7 S5 166 QP23P13B1212_P2C7S5Q166
26. C Chap 7 S4 37 QP23P13B1212_P2C7S4Q37
27. A Chap 7 S5 142 QP23P13B1212_P2C7S5Q142
28. D Chap 7 S4 113 QP23P13B1212_P2C7S4Q113
29. C Chap 8 S5 253 QP23P13B1212_P2C8S5Q253
30. B Chap 8 S5 259 QP23P13B1212_P2C8S5Q259
31. C Chap 8 S5 279 QP23P13B1212_P2C8S5Q279
32. A Chap 8 S5 267 QP23P13B1212_P2C8S5Q267

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33. D Chap 8 S6 315 QP23P13B1212_P2C8S6Q315
34. B Chap 8 S6 295 QP23P13B1212_P2C8S6Q295
35. B Chap 9 S5 419 QP23P13B1212_P2C9S5Q419
36. A Chap 9 S5 424 QP23P13B1212_P2C9S5Q424
37. C Chap 9 S4 68 QP23P13B1212_P2C9S4Q68
38. B Chap 10 S5 531 QP23P13B1212_P2C10S5Q531
39. A Chap 10 S4 220 QP23P13B1212_P2C10S4Q220
40. C Chap 10 S4 185 QP23P13B1212_P2C10S4Q185

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 MAGNETIC SCIENCE INSTITUTE
Full Syllabus GUJCET-CHEMISTRY-PAPER 2 Date : 26/03/24
Total Marks-40 GUJCET Time-1:00 hrs
Section A
//X
• Choose correct answer from the given options. [Each carries 1 Mark] [40]

1.

2.

//X
 Ans : (B)
3.

//X
 Ans : (C)
4.

//X
 Ans : (B)
5.

//X
 Ans : (D)
6.

//X
 Ans : (B)
7.

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//X
 Ans : (A)
8.

//X
 Ans : (A)
9.

10.

11.

12.

//X
 Ans : (B)
13.

//X
 Ans : (A)
14.

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//X
 Ans : (C)
15.

//X
 Ans : (C)
16.

//X
 Ans : (B)
17.

//X
 Ans : (D)
18.

//X
 Ans : (A)
19.

//X
 Ans : (D)
20.

//X
 Ans : (A)
21.

//X
 Ans : (D)
22.

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//X
 Ans : (C)
23.

//X
 Ans : (D)
24.

//X
 Ans : (C)
25.

26.

//X
 Ans : (C)
27.

//X
 Ans : (A)

28.

//X
 Ans : (D)
29.

//X
 Ans : (C)
30.

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//X
 Ans : (B)
31.

//X
 Ans : (C)

32.

//X
 Ans : (A)
33.

34.

//X
 Ans : (B)
35.

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//X
 Ans : (B)
36.

37.

38.

//X
 Ans : (B)
39.

//X
 Ans : (A)
40.

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//X
 Ans : (C)

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