MenAMI Hydrazine 03

AMI Hydrazine
Version 6.20 and higher
Operator’s Manual
A-96.250.501 / 020720
Customer Support
SWAN and its representatives maintain a fully trained staff of technical specialists
around the world. For any technical question, contact your nearest
SWAN representative, or the manufacturer:
SWAN ANALYTISCHE INSTRUMENTE AG
Studbachstrasse 13
8340 Hinwil
Switzerland
Internet: www.swan.ch
E-mail: support@swan.ch
Document Status
Title: AMI Hydrazine Operator’s Manual
ID: A-96.250.501
Revision Issue
00 June 2007 First Edition
01 April 2015 Update to Rev. 5.40, mainboard V2.4
02 July 2017 Update to Rev. 6.10, mainboard V2.5
03 July 2020 Mainboard V2.6
© 2020, SWAN ANALYTISCHE INSTRUMENTE AG, Switzerland, all rights reserved
subject to change without notice

AMI Hydrazine
Table of Content
1. Safety Instructions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
1.1. Warning Notices . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
1.2. General Safety Regulations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
1.3. Restrictions for use. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
2. Product Description . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
2.1. Description of the System. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
2.2. Instrument Specification . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
2.3. Instrument Overview. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
3. Installation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
3.1. Installation Checklist Monitors . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
3.2. Mounting of Instrument Panel. . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
3.3. Connecting Sample and Waste . . . . . . . . . . . . . . . . . . . . . . . . . . 15
3.4. Install the Reference Electrode . . . . . . . . . . . . . . . . . . . . . . . . . . 16
3.5. Install the Temperature Sensor . . . . . . . . . . . . . . . . . . . . . . . . . . 17
3.6. Electrical Connections . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
3.6.1 Connection Diagram . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20
3.6.2 Power Supply . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
3.7. Relay Contacts . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
3.7.1 Input . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
3.7.2 Alarm Relay. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
3.7.3 Relay Contacts 1 and 2. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
3.8. Signal Outputs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25
3.8.1 Signal Output 1 and 2 (current outputs) . . . . . . . . . . . . . . . . . . 25
3.9. Interface Options . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25
3.9.1 Signal Output 3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26
3.9.2 Profibus, Modbus Interface . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26
3.9.3 HART Interface . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
3.9.4 USB Interface . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
4. Instrument Setup . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28
4.1. Install the Diisopropylamine Bottle . . . . . . . . . . . . . . . . . . . . . . . . 28
4.2. Establish Sample Flow . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29
4.3. Programming . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29
4.4. Run in period . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29
4.5. Correction of Hydrazine Sensor . . . . . . . . . . . . . . . . . . . . . . . . . . 30
A-96.250.501 / 020720 1
AMI Hydrazine
5. Operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31
5.1. Keys . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31
5.2. Display . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32
5.3. Software Structure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
5.4. Changing Parameters and values. . . . . . . . . . . . . . . . . . . . . . . . . 34
6. Maintenance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35
6.1. Maintenance Table . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35
6.2. Stop of Operation for Maintenance . . . . . . . . . . . . . . . . . . . . . . . . 36
6.3. Cleaning of the Protective Filter . . . . . . . . . . . . . . . . . . . . . . . . . . 37
6.4. Cleaning of the Hydrazine Sensor . . . . . . . . . . . . . . . . . . . . . . . . 38
6.5. Cleaning of Reference Electrode . . . . . . . . . . . . . . . . . . . . . . . . . 40
6.6. Cleaning of Flow Cell . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41
6.7. Changing the Diisopropylamine Bottle . . . . . . . . . . . . . . . . . . . . . 44
6.8. Changing the Diffusion Tube . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45
6.9. Calibration of Hydrazine Sensor . . . . . . . . . . . . . . . . . . . . . . . . . . 46
6.9.1 Calibration Procedure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46
6.9.2 Zero Hydrazine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46
6.9.3 Process Hydrazine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47
6.10. Longer Stop of Operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49
7. Troubleshooting . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50
7.1. Error List . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52
7.2. Replacing Fuses . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55
8. Program Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56
8.1. Messages (Main Menu 1) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56
8.2. Diagnostics (Main Menu 2) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57
8.3. Maintenance (Main Menu 3) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58
8.4. Operation (Main Menu 4) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58
8.5. Installation (Main Menu 5). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59
9. Program List and Explanations . . . . . . . . . . . . . . . . . . . . . . . . . 61
1 Messages. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61
2 Diagnostics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61
3 Maintenance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 62
4 Operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63
5 Installation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64
10. Default Values . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76
11. Index. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79
12. Notes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80
2 A-96.250.501 / 020720
AMI Hydrazine
Safety Instructions
AMI Hydrazine–Operator’s Manual

This document describes the main steps for instrument setup, oper-
ation and maintenance.
1. Safety Instructions
General The instructions included in this section explain the potential risks
associated with instrument operation and provide important safety
practices designed to minimize these risks.
If you carefully follow the information contained in this section, you
can protect yourself from hazards and create a safer work environ-
ment.
More safety instructions are given throughout this manual, at the
respective locations where observation is most important.
Strictly follow all safety instructions in this publication.
Target Operator: Qualified person who uses the equipment for its intended
audience purpose.
Instrument operation requires thorough knowledge of applications,
instrument functions and software program as well as all applicable
safety rules and regulations.
OM Location The AMI Operator’s Manual shall be kept in proximity of the instru-
ment.
Qualification, To be qualified for instrument installation and operation, you must:
Training  read and understand the instructions in this manual as well as
the Material Safety Data Sheets.
 know the relevant safety rules and regulations.
A-96.250.501 / 020720 3
AMI Hydrazine
Safety Instructions
1.1. Warning Notices

The symbols used for safety-related notices have the following sig-
nificance:
DANGER
Your life or physical wellbeing are in serious danger if such

warnings are ignored.
 Follow the prevention instructions carefully.
WARNING
Severe injuries or damage to the equipment can occur if such

warnings are ignored.
CAUTION
Damage to the equipment, minor injury, malfunctions or incor-

rect process can be the consequence if such warnings are ig-
nored.
Mandatory The importance of the mandatory signs in this manual.

Signs
Safety goggles
Safety gloves
4 A-96.250.501 / 020720
AMI Hydrazine
Safety Instructions
Warning Signs The importance of the warning signs in this manual.
Electrical shock hazard
Corrosive
Harmful to health
Flammable
Warning general
Attention general
A-96.250.501 / 020720 5
AMI Hydrazine
Safety Instructions
1.2. General Safety Regulations

Legal The user is responsible for proper system operation.
Requirements All precautions must be followed to ensure safe operation of the in-
strument.
Spare Parts Use only official SWAN spare parts and disposables. If other parts
and are used during the normal warranty period, the manufacturer’s
Disposables warranty is voided.
Modifications Modifications and instrument upgrades shall only be carried out by

an authorized Service Technician. SWAN will not accept responsi-
bility for any claim resulting from unauthorized modification or alter-
ation.
WARNING
Electrical Shock Hazard

If proper operation is no longer possible, the instrument must be
disconnected from all power lines, and measures must be taken
to prevent inadvertent operation.
 To prevent from electrical shock, always make sure that the
ground wire is connected.
 Service shall be performed by authorized personnel only.
 Whenever electronic service is required, disconnect instru-
ment power and power of devices connected to.
– relay 1,
– relay 2,
– alarm relay
WARNING
For safe instrument installation and operation you must read
and understand the instructions in this manual.
WARNING
Only SWAN trained and authorized personnel shall perform the

tasks described in this document.
6 A-96.250.501 / 020720
AMI Hydrazine
Safety Instructions
1.3. Restrictions for use

Alcalizing Correct the pH of the sample with Diisopropylamine only, however,
Reagent Diisopropylamine is not included in delivery. Please buy it from your
local supplier: E.g. VWR 6x 1l: 8.03646.1000, or SIGMA 38290-1L-F.
Sample No sand (or other polishing material) or oil are allowed in the sam-
Require- ple.
ments The instrument is specified for a max. pressure of 2 bar (28 psi). If
the sample pressure exceeds 2 bar, please mount a pressure re-
duction in front of the instrument inlet.
Phosphates may interfere with the hydrazine measurement.
The pH value of the sample must be equal or higher than pH 7.
Flow High concentrations of Diisopropylamine reagent may attack the

Interruption acrylic material of the flow cell. This can cause cracks and render
the flow cell completely unusable. This will not happen during nor-
mal operation. However, if the sample flow is stopped, undiluted di-
isoproylamine will diffuse through the diffusion tube and can cause
damage. Therefore, the following rules should be observed if the
sample flow is stopped for more than one day:
Remove diisopropylamine bottle and close it. Keep it in a safe
place for further use.
WARNING
Diisopropylamine is corrosive.
 Read the Safety Data Sheets (SDS) first.
 Wear suitable protective clothing, gloves and eye/face protec-
tion.
 Avoid inhalation of DIPA vapor.
 In case of contact with eyes, rinse immediately with plenty of
water eyelid wide open for at least 10 min, summon medical
advice. In case of accident or if you feel unwell, summon
medical advice immediately (show the label where possible).
 Screw an empty reagent bottle on the holder.
 Let the sample flow for another 30 minutes to rinse out the Di-
isopropylamine dissolved in the diffusion tubing material.
 Stop sample flow.
A-96.250.501 / 020720 7
AMI Hydrazine
Product Description
2. Product Description
2.1. Description of the System
Microprocessor controlled system for the determination and control
of hydrazine or carbohydrazide used as boiler feedwater oxygen
scavengers.
Application Hydrazine is used in power plants as an oxygen scavenger. It helps
to remove oxygen, which may cause corrosion in the power plant.
The reaction of hydrazine with oxygen produces nitrogen and wa-
ter.
Signal Two signal outputs programmable for measured values (freely scal-
Outputs able, linear, bilinear, log) or as continuous control output (control
parameters programmable).
Current loop: 0/4–20 mA
Maximal burden: 510 Ω
Third signal output available as an option. The third signal output
can be operated as a current source or as a current sink (selectable
via switch).
Relays Two potential-free contacts programmable as limit switches for
measuring values, controllers or timer for system cleaning with au-
tomatic hold function. Both contacts can be used as normally open
or normally closed.
Maximum load: 1 A/250 VAC
Alarm Relay One potential free contact.
Alternatively:
 Open during normal operation, closed on error and loss of
power.
 Closed during normal operation, open on error and loss of
power.
Summary alarm indication for programmable alarm values and in-
strument faults.
Input One input for potential-free contact to freeze the measuring value
or to interrupt control in automated installations. Programmable as
HOLD or OFF function.
Communica-  USB Interface for logger download.
tion interface  Third signal output (can be used in parallel to the USB interface)
(optional)  RS485 with Fieldbus protocol Modbus or Profibus DP
 HART interface
8 A-96.250.501 / 020720
AMI Hydrazine
Product Description
Safety No data loss after power failure. All data is saved in non-volatile
Features memory.
Over voltage protection of in- and outputs.
Galvanic separation of measuring inputs and signal outputs.
Reagent Reagent consumption (at 25 °C):
consumption < 1 l of diisopropylamine per month
Measuring 3-electrode amperometry:
principle The sensor consists of two platinum electrodes and a reference
electrode. A voltage is applied to the platinum electrodes and kept
on a optimum level by the reference electrode. The hydrazine in the
sample generates a small current on the platinum pin electrode,
which is proportional to the hydrazine concentration.
For an optimal sensitivity and stability, a rotor continuously cleans
the surfaces of the platinum electrodes (hydrodynamic cleaning).
To ensure a sufficient sample flow, a Hall-Sensor detects the rota-
tions of the rotor. If the rotation speed falls below a certain value, a
flow Alarm is triggered.
The signal of amperometric systems depends on flow rate. The
constant head guarantees a constant flow if the sample always
overflows into the longer constant head tube.
Temperature compensation is done automatically.
Fluidics The measurement of hydrazine requires a high pH of the sample.
The AMI Hydrazine buffers the pH to pH>10.5 by adding diisopro-
pylamine. The diisopropylamine is dissolved in the water while
flowing through a diffusion tube.
The sample enters at the sample inlet [E], passes the filter [G] and
the flow regulating valve [D], where the sample flow can be adjust-
ed. From there it flows through the diffusion tube [L] in the diisopro-
pylamine bottle [K], picking up diisopropylamine and reaching
pH>10.5. Afterwards, the sample is led directly into the shorter
overflow tube [C]. From there it flows through the hydrazine sensor
[F] and leaves the flow cell via sample outlet [H]. Excess sample
overflows from the shorter overflow tube into the constant head [A],
fills it until the sample overflows into the longer overflow tube. Sam-
ple must always overflow into the longer overflow tube to ensure
constant flow and pressure at the hydrazine sensor. The sample
leaves the flow cell via sample outlet [H].
A-96.250.501 / 020720 9
AMI Hydrazine
Product Description
A
B K
L
C
E J
A Constant head G Filter vessel

B Overflow tube to waste (long) H Sample outlet
C Overflow tube to sensor (short) I Garb sample outlet
D Flow regulating valve J Grab sample valve
E Sample inlet K Diisopropylamine
F Hydrazine sensor L Diffusion tube
10 A-96.250.501 / 020720
AMI Hydrazine
Product Description
2.2. Instrument Specification

Power Supply AC variant: 100–240 VAC (± 10%)
50 /60 Hz (± 5%)
DC variant 10 –36 VDC
Power consumption: max. 35 VA
Transmitter Housing: aluminum, with a protection degree of
specifications IP 66 / NEMA 4X
Ambient temperature: −10 to +50 °C
Storage and transport: −30 to +85 °C
Humidity: 10 –90% rel., non condensing
Display: backlit LCD, 75 x 45 mm
Measuring Range: 0.1–600 ppb
range Accuracy: 5% of reading up to 200 ppb
Hydrazine ± 15% up to 600 ppb
or ± 2 ppb (whichever is greater).
Stability: ±5% of reading per month, or ±2ppb per
month
Response time: 90% of change in 60 sec after the sample
entered the flow cell.
Measuring Measuring range: up to 60°C
range Resolution: 0.1 °C
temperature
Sample Flow rate: approx. 15 l/h
requirements Temperature: 15 to 45 °C
Sample inlet pressure: 0.15–2 bar
Sample outlet pressure: pressure free
pH value: equal or higher than pH 7.0
On-site The analyzer site must permit connections to:
requirements Sample inlet: Serto 4 x6 mm
Sample outlet: Tube adapter 15x20 mm
A-96.250.501 / 020720 11
AMI Hydrazine
Product Description
Dimensions Panel: 280x850x180 mm, stainless steel

Mounting hole distance 254x824
Screws: 8 mm diameter
Weight: 12.0 kg
280 mm / 11.02"
254 mm / 10.00"
13 mm / 0.51"
Exit Enter
AMI Hydrazine
824 mm / 32.44"
850 mm / 33.46"
4 x dia. 10 mm / 0.39"
12 A-96.250.501 / 020720
AMI Hydrazine
Product Description
2.3. Instrument Overview
C
T
S
R
E
Q
P
F
O
N
G
M
H
L I
K J
A Panel K Filter vessel

B Transmitter L Sample outlet
C Bottle holder M Sample inlet
D Diisoproylamine bottle N Hall sensor (not visible)
E Diffusion tube O Flow cell block
F Reference electrode P Constant head
G Grab sample valve Q Overflow tube to sensor (short)
H Grab sample outlet R Overflow tube to waste (long)
I Flow regulating valve S Constant head cover
J Hydrazine sensor T Temperature sensor
A-96.250.501 / 020720 13
AMI Hydrazine
Installation
3. Installation
3.1. Installation Checklist Monitors
On site AC variant: 100–240 VAC ( 10%), 50/60 Hz ( 5%)

requirements DC variant: 10–36 VDC
Power consumption: 35 VA maximum.
Protective earth connection required.
Sample line with sufficient sample flow and pressure (see Instru-
ment Specification, p. 11).
Installation Mounting of Instrument Panel, p. 15.
Connecting Sample and Waste, p. 15.
Electrodes Install the Reference Electrode, p. 16.
Install the Temperature Sensor, p. 17.
Diisopropyl- Install the Diisopropylamine Bottle, p. 28.
amine
Electrical Connect all external devices like limit switches, current loops
wiring and pumps, see Connection Diagram, p. 20.
Connect the power cord, see Power Supply, p. 21.
Power-up Establish Sample Flow, p. 29.
Switch on power.
Adjust sample flow according to flow cell specifications.
Instrument Program all necessary parameters see Programming, p. 29.
set-up Program all parameters for external devices (interface, record-
ers, etc.).
Program all parameters for instrument operation (limits, alarms).
Run-in period Let the instrument run-in for approximately 30 min continuous
operation. See Run in period, p. 29.
14 A-96.250.501 / 020720
AMI Hydrazine
Installation
3.2. Mounting of Instrument Panel

The first part of this chapter describes the preparing and placing of
the system for use.
 The instrument must only be installed by trained personnel.
 Mount the instrument in vertical position.
 For ease of operation mount it so that the display is at eye
level.
 For the installation a kit containing the following installation
material is available:
– 4 Screws 8x60 mm
– 4 Dowels
– 4 Washers 8.4/24 mm
Mounting The instrument is only intended for indoor installation.
requirements
3.3. Connecting Sample and Waste

Sample inlet Slide the knurled nut [C] and the compression ferrule [B] over the
4x6 plastic tube [E]. Push it into the serto fitting [A] and tighten the
knurled nut.
Waste Connect the 1/2” tube [F] to the hose nozzle [D] and place it into a
pressure free drain.
A Serto fitting at sample
inlet
B Compression ferrule
A C Knurled nut
D Hose nozzle at sample
B outlet
C E Plastic tube 4x6
F 1/2” tube
D
A-96.250.501 / 020720 15
AMI Hydrazine
Installation
3.4. Install the Reference Electrode

The reference electrode is delivered separately and protected with
a waterfilled protective cap. The connector is fixed to the panel with
an adhesive tape and already connected to the front end PCB in
the AMI transmitter.
D
E
A Connector D Union nut

B Protective cap E Flow cell block
C Reference sensor
To install the reference electrode proceed as follows:
1 Loosen the union nut [D].

2 Remove the protective cap [B] from the reference electrode [C].
3 Push the reference electrode through the union nut [D] into the
bore of the flow cell block [E] as far as it will go.
4 Tighten the union nut.
5 Remove the connector [A] from the panel and screw it onto the
reference electrode.
16 A-96.250.501 / 020720
AMI Hydrazine
Installation
3.5. Install the Temperature Sensor

The temperature sensor is fixed to the panel with an adhesive tape
and already connected to the front end PCB in the AMI transmitter.
A Temperature sensor
B Constant head cover
C Constant head
A
To install the temperature sensor proceed as follows:
1 Remove the temperature sensor [A] from the panel.

2 Put the temperature sensor in the designated hole of the con-
stant head cover [B].
3 Push it into the hole as far as it will go.
A-96.250.501 / 020720 17
AMI Hydrazine
Installation
3.6. Electrical Connections
WARNING
Risk of electrical shock.

Do not perform any work on electrical components if the trans-
mitter is switched on. Failure to follow safety instructions can
result in serious injury or death.
 Always turn off power before manipulating electric parts.
 Grounding requirements: Only operate the instrument from a
power outlet which has a ground connection.
 Make sure the power specification of the instrument corre-
sponds to the power on site.
Cable In order to comply with IP66, use the following cable thicknesses
thicknesses
A B C
A PG 11 cable gland: cable Øouter 5–10 mm

B PG 7 cable gland: cable Øouter 3–6.5 mm
C PG 9 cable gland: cable Øouter 4–8 mm
NOTICE: Protect unused cable glands
Wire  For Power and Relays: Use max. 1.5 mm2 / AWG 14
stranded wire with end sleeves.
 For Signal Outputs and Input: Use 0.25 mm2 / AWG 23
stranded wire with end sleeves.
18 A-96.250.501 / 020720
AMI Hydrazine
Installation
WARNING
External Voltage.
External supplied devices connected to relay 1 or 2 or to the
alarm relay can cause electrical shocks
 Make sure that the devices connected to the following con-
tacts are disconnected from the power before resuming in-
stallation.
– relay 1
– relay 2
– alarm relay
WARNING
To prevent from electrical shock, do not connect the instrument

to the power unless the groundwire (PE) is connected.
WARNING
The mains of the AMI transmitter must be secured by a main

switch and appropriate fuse or circuit breaker.
A-96.250.501 / 020720 19
AMI Hydrazine
Installation
3.6.1 Connection Diagram
CAUTION
Use only the terminals shown in this diagram, and only for the
mentioned purpose. Use of any other terminals will cause short
circuits with possible corresponding consequences to material
and personnel.
20 A-96.250.501 / 020720
AMI Hydrazine
Installation
3.6.2 Power Supply
WARNING
Electrical shock hazard

Installation and maintenance of electrical parts must be per-
formed by professionals. Always turn off power before manipu-
lating electric parts.
A
B
C
A Power supply connector

B Neutral conductor, Terminal 2
C Phase conductor, Terminal 1
D Protective earth PE
NOTICE: The protective earth wire (ground) has to be
connected to the grounding terminal.
Installation The installation must meet the following requirements.
requirements  Mains cable to comply with standards IEC 60227 or IEC
60245; flammable rating FV1
 Mains equipped with an external switch or circuit-breaker
– near the instrument
– easily accessible to the operator
– marked as interrupter for AMI Hydrazine
A-96.250.501 / 020720 21
AMI Hydrazine
Installation
3.7. Relay Contacts

Programming of the relay contacts see 5.3 Relay Contacts, p. 67
3.7.1 Input
NOTICE: Use only potential-free (dry) contacts. The total
resistance (sum of cable resistance and resistance of the relay
contact) must be less than 50 Ω.
If signal output is set to hold, measurement is interrupted if input is
active.
For programming see menu 5.3.4, p. 73
3.7.2 Alarm Relay

NOTICE: Max. load 1 AT / 250 VAC
Alarm output for system errors.
Error codes see Troubleshooting, p. 50
Programming see menu 5.3.1, p. 67
NOTICE: With certain alarms and certain settings of the AMI

transmitter the alarm relay does not switch. The error, however,
is shown on the display.
Terminals Description Relay connection

1) 1)
NC 10/11 Active (opened) during normal 11
Normally operation.
0V
Closed Inactive (closed) on error and 10
loss of power.
12
NO 12/11 Active (closed) during normal 11

Normally operation. 0V
Open Inactive (opened) on error and 10
loss of power.
12
1) usual use
22 A-96.250.501 / 020720
AMI Hydrazine
Installation
3.7.3 Relay Contacts 1 and 2

NOTICE: Rated load 1 AT / 250 VAC
Relay 1 and 2 can be configured as normally open or as normally
closed. Standard for both relays is normally open. To configure a
Relay as normally closed, set the jumper in the upper position.
NOTICE: Some error codes and the instrument status may
influence the status of the relays described below.
Relay Jumper
config. Terminals pos. Description Relay configuration
Normally 6/7: Relay 1 Inactive (opened) during
Open 8/9: Relay 2 normal operation and 6
loss of power.
Active (closed) when a 0V
programmed function is 7
executed.
Normally 6/7: Relay 1 Inactive (closed) during
Closed 8/9: Relay 2 normal operation and 6
loss of power.
Active (opened) when a 0V
programmed function is 7
executed.
A
B
A Jumper set as normally open (standard setting)

B Jumper set as normally closed
For programming see Menu Installation 5.3.2 and 5.3.3, p. 69
A-96.250.501 / 020720 23
AMI Hydrazine
Installation
CAUTION
Risk of damage of the relays in the AMI Transmitter due to

heavy inductive load.
Heavy inductive or directly controlled loads (solenoid valves,
dosing pumps) may destroy the relay contacts.
 To switch inductive loads > 0.1 A use an AMI relay box avail-
able as an option or suitable external power relays.
Inductive load Small inductive loads (max 0.1 A) as for example the coil of a pow-
er relay can be switched directly. To avoid noise voltage in the
AMI Transmitter it is mandatory to connect a snubber circuit in par-
allel to the load. A snubber is not necessary if an AMI relaybox is
used.
A A AC or DC power supply
B C B AMI Transmitter
C External power relay
D E D Snubber
E Power relay coil
Resistive load Resistive loads (max. 1 A) and control signals for PLC, impulse
pumps and so on can be connected without further measures
A B A AMI Transmitter
B PLC or controlled pulse pump
C C Logic
Actuators Actuators, like motor valves, are using both relays: One relay con-
tact is used for opening, the other for closing the valve, i.e. with the
2 relay contacts available, only one motor valve can be controlled.
Motors with loads bigger than 0.1 A must be controlled via external
power relays or an AMI relay box.
A A AC or DC power supply
B C B AMI Transmitter
C Actuator
24 A-96.250.501 / 020720
AMI Hydrazine
Installation
3.8. Signal Outputs
3.8.1 Signal Output 1 and 2 (current outputs)

NOTICE: Max. burden 510 Ω
If signals are sent to two different receivers, use signal isolator
(loop isolator).
Signal output 1: Terminals 14 (+) and 13 (-)
Signal output 2: Terminals 15 (+) and 13 (-)
For programming see Chapter 9, 5.2 Signal Outputs, p. 64, Menu
Installation
3.9. Interface Options

A AMI Transmitter
A B Slot for interfaces
C Frontend PCB
D Screw terminals
B
The slot for interfaces can be used to expand the functionality of

the AMI instrument with either:
 Third signal output
 a Profibus or Modbus connection
 an USB Interface
 a HART interface
A-96.250.501 / 020720 25
AMI Hydrazine
Installation
3.9.1 Signal Output 3

Terminals 38 (+) and 37 (-).
Requires the additional board for the third signal output 0/4–20 mA.
The third signal output can be operated as a current source or as a
current sink (switchable via switch [A]). For detailed information see
the corresponding installation instruction.
NOTICE: Max. burden 510 Ω.
A
Third signal output 0/4 - 20 mA PCB
A Operating mode selector switch
3.9.2 Profibus, Modbus Interface

Terminal 37 PB, Terminal 38 PA
To connect several instruments by means of a network or to config-
ure a PROFIBUS DP connection, consult the PROFIBUS manual.
Use appropriate network cable.
NOTICE: The switch must be ON, if only one instrument is
installed, or on the last instrument in the bus.
OFF
ON
Profibus, Modbus Interface PCB (RS 485)

A On - OFF switch
26 A-96.250.501 / 020720
AMI Hydrazine
Installation
3.9.3 HART Interface

Terminals 38 (+) and 37 (-).
The HART interface PCB allows for communication via the HART
protocol. For detailed information, consult the HART manual.
HART Interface PCB
3.9.4 USB Interface

The USB Interface is used to store Logger data and for Firmware
upload. For detailed information see the corresponding installation
instruction.
The optional third signal output 0/4 – 20 mA PCB [B] can be
plugged onto the USB interface and used in parallel.
USB Interface
A USB interface PCB
B Third signal output 0/4 - 20 mA PCB
A-96.250.501 / 020720 27
AMI Hydrazine
Instrument Setup
4. Instrument Setup
4.1. Install the Diisopropylamine Bottle

Only install the diisopropylamine bottle if you intend to start opera-
tion immediately. Do not it install if no sample in available!
Fill the Diisopropylamine into the glass bottle (G45 thread), deliv-
ered with the instrument. If you want to connect a Merck bottle di-
rectly, you need a thread adapter which can be ordered at SWAN,
order number C-83.591.010.
WARNING
 Wear suitable protective clothing, gloves and eye/face pro-
tection.
 Avoid inhalation of DIPA vapor. To prevent formation of re-
agent vapors:
– close the reagent bottle firmly
– check the EPDM seal regularly
A Bottle holder
A B Screw cover G 45
C EPDM seal mounted on the bottle holder
B
D Reagent bottle
C
E Steel tube
F Diffusions tube
D
E
28 A-96.250.501 / 020720
AMI Hydrazine
Instrument Setup
1 Fill roughly 750 ml high purity water into a 1 l beaker.

2 Dip the diffusion tube [F] into the beaker filled with high purity
water and rinse it some seconds.
3 Push the diffusion tube over the steel tubes [E].
4 Open the reagent bottle [D], add 20 ml of high purity water.
5 Screw the reagent bottle into the screw cover [B], fixed to the
bottle holder [A]
6 Make sure that the diffusions tube [F] is placed in the reagent
bottle as shown in the picture above.
7 Tighten the screw cover well.
4.2. Establish Sample Flow

1 Make sure, that the grab sample valve is closed.
2 Open the flow regulating valve.
3 Wait until the flow cell is completely filled.
4 Switch on power.
4.3. Programming
Program all parameters for external devices (interface, recorders,
etc.). Program all parameters for instrument operation (limits,
alarms).
For explanations, see Program List and Explanations, p. 61.
4.4. Run in period

Let the instrument run-in for approximately 30 min continuous oper-
ation (flow on, power on). The Diisopropylamine needs roughly 30
min to penetrate the walls of new diffusion tubes.
A-96.250.501 / 020720 29
AMI Hydrazine
Instrument Setup
4.5. Correction of Hydrazine Sensor

If necessary, correct the instrument after at least 30 min running-in.
To correct the instrument the concentration of hydrazine in the sam-
ple has to be known. Hydrazine reacts with dimethylaminobenzal-
dehyde in an acid solution and forms a yellow color. The color
intensity can be measured by a photometer. Refer to an appropri-
ate standard method (e.g. DIN 38413).
The manual sample must be taken from the grab sample outlet of
the flow cell. Let the sample flow out for roughly 1 minute before
grabbing the sample for the manual analysis.
See Calibration of Hydrazine Sensor, p. 46.
30 A-96.250.501 / 020720
AMI Hydrazine
Operation
5. Operation
5.1. Keys
A B C D
Exit Enter
A to exit a menu or command (rejecting any changes)

to move back to the previous menu level
B to move DOWN in a menu list and to decrease digits
C to move UP in a menu list and to increase digits
D to open a selected sub-menu
to accept an entry
Program
RUN 14:10:45 Main Menu 1
Access, Exit Enter
R1 Messages
Diagnostics
R2
0.45 ppm Maintenance
Exit Operation
9 l/h 25.4°C Installation
A-96.250.501 / 020720 31
AMI Hydrazine
Operation
5.2. Display
A B C D
RUN 15:20:18
R1
0.45 ppb E
R2
H 360 rpm 24.8°C F

G
A RUN normal operation

HOLD input closed or cal delay: Instrument on hold (shows
status of signal outputs).
OFF input closed: control/limit is interrupted (shows status
of signal outputs).
B ERROR Error Fatal Error
C Keys locked, transmitter control via Profibus
D Time
E Process values
F Sample temperature
G Sample flow
H Relay status
Relay status, symbols

upper/lower limit not yet reached
upper/lower limit reached
control upw./downw. no action
control upw./downw. active, dark bar indicates control intensity
motor valve closed

motor valve: open, dark bar indicates approx. position
timer
timer: timing active (hand rotating)
32 A-96.250.501 / 020720
AMI Hydrazine
Operation
5.3. Software Structure
Main Menu 1
Messages
Diagnostics
Maintenance
Operation
Installation
Menu Messages 1
Messages 1.1
Pending Errors Reveals pending errors as well as an event history
Message List (time and state of events that have occurred at an
earlier point of time).
It contains user relevant data.
Menu Diagnostics 2
Diagnostics 2.1
Identification Provides user relevant instrument and sample data.
Sensors
Sample
I/O State
Interface
Menu Maintenance 3
Maintenance 3.1
Calibration For instrument calibration, relay and signal output
Simulation
simulation, and to set the instrument time.
It is used by the service personnel.
Set Time 23.09.06 16:30:00
Menu Operation 4
Operation 4.1
Sensors User relevant parameters that might need to be
Relay Contacts modified during daily routine. Normally password
Logger protected and used by the process-operator.
Subset of menu 5 - Installation, but process-related.
Menu Installation 5
Installation 5.1
Sensors For initial instrument set up by SWAN authorized
Signal Outputs person, to set all instrument parameters. Can be
Relay Contacts protected by means of password.
Miscellaneous
Interface
A-96.250.501 / 020720 33
AMI Hydrazine
Operation
5.4. Changing Parameters and values

Changing The following example shows how to change the logger interval:
parameters 1 Select the parameter you want to
Logger
Sensors 5.1.2
4.4.1
change.
Sensor
Log type
interval FOME
30 min
Disinf.logger Free chlorine 2 Press [Enter]
Clear no
Temperature NT5K
Standards
3 Press [ ] or [ ] key to
Logger 4.1.3
highlight the required parameter.
Log interval Interval. 30min
Clear logger5 min no 4 Press [Enter] to confirm the selec-
10 min tion or [Exit] to keep the previous
30 min parameter.
1 Hour
 The selected parameter is

Logger 4.1.3
highlighted (but not saved yet).
Log interval 10 min
Clear logger no 5 Press [Exit].
 Yes is highlighted.
Logger 4.1.3
Log interval
Save ?
6 Press [Enter] to save the new pa-
Clear logger
Yes
no rameter.
No  The system reboots, the new
parameter is set.
Changing 1 Select the value you want to

values Alarm Hydrazine 5.3.1.1.1
change.
Alarm High 10.0 ppm
Alarm Low 0.000 ppm 2 Press [Enter].
Hysteresis 10.0 ppm 3 Set required value with [ ] or
Delay 5 Sec
[ ] key.
4 Press [Enter] to confirm the new

Alarm Hydrazine 5.3.1.1.1
value.
Alarm High 6.00 ppm
Alarm Low 0.000 ppm 5 Press [Exit].
Hysteresis 10.0 ppm  Yes is highlighted.
Delay 5 Sec
6 Press [Enter] to save the new val-
ue.
34 A-96.250.501 / 020720
AMI Hydrazine
Maintenance
6. Maintenance
6.1. Maintenance Table
Weekly Check sample supply for dirt.

Check sample flow.
Perform a process calibration, see Process
Hydrazine, p. 47.
Monthly Exchange Diisopropylamine bottle if there is

less than 150 ml (half of the diffusion tube
has to be covered with Diisopropylamine),
see Changing the Diisopropylamine Bottle, p.
44.
Half-yearly Replace sealing of reagent bottle (EPDM)
Yearly Exchange diffusion tube, see Changing the

Diffusion Tube, p. 45.
A-96.250.501 / 020720 35
AMI Hydrazine
Maintenance
6.2. Stop of Operation for Maintenance
WARNING
 Wear suitable protective clothing, gloves and eye/face pro-
tection.
 Avoid inhalation of DIPA vapor.
1 Wear safety gloves and safety glasses!

2 Remove the diisopropylamine bottle and close it well.
3 Screw an empty bottle on the holder. Let the sample run for 30
min.
4 Stop sample flow by closing the flow regulating valve.
5 Wait until the rotor stops and hydrazine reading is 0 ppb.
6 Shut off power of the instrument.
7 Empty the constant head by opening the grab sample tap.
36 A-96.250.501 / 020720
AMI Hydrazine
Maintenance
6.3. Cleaning of the Protective Filter
A Flow regulating valve

B Filter
C Filter vessel
If the protection filter shows deposits, proceed as follows:
1 Close the flow regulating valve [A].

2 Close the sample main tap before the filter.
3 Unscrew and remove the filter vessel [C] from the flow cell
block.
4 Unscrew and remove the filter from [B] the flow cell block.
5 Backwash the filter under pressure of tap water. Clean the out-
side of the filter.
6 Install the filter and filter vessel again.
7 Open sample supply and flow regulating valve again.
A-96.250.501 / 020720 37
AMI Hydrazine
Maintenance
6.4. Cleaning of the Hydrazine Sensor
B
C
D
B
E C
D
F
E
F
G
H H
A Flow regulating valve E Orifices

B Threaded bolt F Hydrazine sensor
C Rotor G BNC connector
D O-Ring H Knurled nut
1 Close the flow regulating vale [A].

2 Wait until rotor [C] stops and hydrazine reading is 0 ppm.
3 Shut off power of the instrument.
4 Disconnect the BNC connector [G] from the hydrazine sensor
[F].
Prevent the connector from getting wet.
5 Unscrew and remove one of the two knurled nuts [H].
38 A-96.250.501 / 020720
AMI Hydrazine
Maintenance
CAUTION
 Avoid damaging of the hydrazine sensor during removal.

Once damaged, the sensor needs to be replaced.
 Do not touch the platinum ring in the center of the hydrazine
sensor with your fingers or metallic objects.
6 Hold the hydrazine sensor [F] with one hand while unscrewing
and removing the 2nd knurled nut.
7 Remove the hydrazine sensor from the flow cell.
Take care not to spill the sample remaining in the sensor.
Cleaning 1 Remove the rotor [C] from the hydrazine sensor.

2 Clean the tow orifices [E] with a pipe cleaner or a toothpick
3 Clean the rotor with a soft tissue.
4 Cautiously wipe the sensor with a soft tissue, mainly the plati-
num parts and the whole area which is in contact with water.
5 After cleaning rinse all parts well with clean water.
Install 1 Put rotor on the sensor.

2 Install the sensor into the flow cell.
3 Fasten the knurled nuts hand-tight.
4 Connect the BNC connector to the hydrazine sensor.
5 Open the sample flow.
6 As soon as the rotor is turning, switch on power.
NOTICE: After cleaning the sensor, the measured value may be

too high. Let the instrument run for about 24 h.
A-96.250.501 / 020720 39
AMI Hydrazine
Maintenance
6.5. Cleaning of Reference Electrode
B
C
D
A Reference electrode E Washer

B Union screw F O-Ring
1 Close the flow regulating vale.

2 Loosen the union screw [B].
3 Pull the reference electrode out.
4 Wipe sensor tip cautiously with a soft tissue. If necessary use
alcohol to remove oily deposits.
Do not use any acid!
5 Push the reference electrode through the union screw into the
flow cell as far as it will go.
6 Tighten the union screw.
40 A-96.250.501 / 020720
AMI Hydrazine
Maintenance
6.6. Cleaning of Flow Cell

A Temperature senor
A B Tube from sample inlet
C Tube to hydrazine
B sensor
C
D Constant head cover
D E Constant head tube
F Constant head tube
E
fixation
F
G Overflow tube to waste
G H Overflow tube to sensor
I Flow cell block
H J Grab sample tap
K Fixing screw
L Flow regulating valve
M Sample Inlet
N Hall sensor
O Filter
P Filter vessel
I Q Hydrazine sensor
J R Sample outlet
K
L
M
N
O
P
Q
CAUTION
 Never use organic solvents or scrubbing materials to clean

acrylic glass parts.
 Use soft detergent and rinse well. Eliminate calcareous de-
posits with a common household deliming agent in standard
concentration.
A-96.250.501 / 020720 41
AMI Hydrazine
Maintenance
Disassemble 1 Switch off the instrument.

the flow cell 2 Stop the sample flow at the main tap before the sample inlet.
3 Open the grab sample tap [J] to empty the flow cell.
4 Remove all sensors, see Cleaning of the Hydrazine Sensor, p.
38, Cleaning of Reference Electrode, p. 40 and temperature
sensor.
5 Put the rubber cap on the tip of the reference electrode and
plug cap on sensor plug.
6 Remove the following parts from the flow cell block [I], but with-
out however removing the flow cell block from the panel:
–Tube from sample inlet to DIPA bottle [B]
–Tube from DIPA bottle to hydrazine sensor [C]
–Constant head cover [D]
–Constant head tube [E]
–Overflow tube to waste (long) [G]
–Overflow tube to sensor (short) [H]
–Grab sample tap [J]
–Sample inlet [M] and grab sample outlet (not visible)
–Filter vessel [P]
–Filter [O]
–Sample outlet [R]
–Hall-Effect sensor [N]
–Flow regulating valve [L]
7 Clean all acrylic parts with a soft brush (e.g. a bottle cleaner)
and soapy water. Remove calcareous deposits with a common
household deliming agent with standard concentrations.
8 Clean the bores of the flow cell block with pipe cleaners.
42 A-96.250.501 / 020720
AMI Hydrazine
Maintenance
Assemble the A Teflon band

A
flow cell B Hose nozzle at sample outlet
B C Serto fitting at sample inlet and
C grab sample outlet
1 Wrap 7 turns of teflon tape around the hose nozzle thread

2 Replace all o-rings and grease them with teflon paste.
3 Assemble the flow cell.
4 Install all sensors.
5 Open the main tap and wait until the flow cell is filled
6 Check all connection for leakage, if necessary retighten leaky
points.
7 Switch on the instrument.
A-96.250.501 / 020720 43
AMI Hydrazine
Maintenance
6.7. Changing the Diisopropylamine Bottle

Shut down the instrument as described in Stop of Operation for
Maintenance, p. 36.
Consider the Warning concerning Diisopropylamine handling.
1 Fill roughly 750 ml high purity water into a 1 l beaker.

2 Unscrew and remove the almost empty reagent bottle [D].
3 Close the reagent bottle immediately.
4 Check the EPDM seal [C] for cracks an replace it if necessary.
5 Remove the diffusion tube [F] from the steel tubes [E].
6 Dip the diffusion tube into the beaker filled with high purity wa-
ter. Rinse some seconds.
7 Push the diffusion tube over the steel tubes.
8 Open the new reagent bottle and add 20 ml of high purity water.
NOTICE: If you fill up Diisopropylamine into the almost empty
bottle, no high purity water needs to be added.
9 Slide the reagent bottle over the diffusions tube and ensure that
it lies pretzel-shaped in the reagent bottle.
10 Fasten bottle to the bottle holder.
11 The liquid in the almost empty Diisopropylamine bottle must be
disposed as chemical waste.
A Bottle holder
B Screw cover G 45
A C EPDM seal mounted on the bottle holder
B D Reagent bottle
C E Steel tube
F Diffusions tube
D
E
44 A-96.250.501 / 020720
AMI Hydrazine
Maintenance
6.8. Changing the Diffusion Tube

Shut down the instrument as described in Stop of Operation for
Maintenance, p. 36.
1 Fill roughly 750 ml high purity water into a 1 l bea-

ker.
2 Unscrew and remove Diisopropylamine bottle
from the holder.
3 Close the bottle immediately.
4 Remove the old diffusion tube from the steel
tubes.
5 Dip the new diffusion tube into the beaker filled
with high purity water and rinse it some seconds.
6 Push the new diffusion tube over the steel tubes.
7 Open the reagent bottle and slide it over the diffu-
sions tube.
NOTICE: Ensure that the diffusions tube lies
pretzel-shaped in the reagent bottle as shown in
the picture.
8 Screw the bottle into the holder.
The correct measuring value will appear after 30 min of continuous

operation (flow and power on). Diisopropylamine needs roughly
30 min to penetrate the walls of the new diffusion tube.
A-96.250.501 / 020720 45
AMI Hydrazine
Maintenance
6.9. Calibration of Hydrazine Sensor
6.9.1 Calibration Procedure

Manual Hydrazine reacts with dimethylaminobenzaldehyde in an acid solu-
Measurement tion and forms a yellow colour. The colour intensity is proportional
to the concentration and can be determined by a photometer. Refer
to an appropriate standard method.
Correction The adjustment of the slope is called correction. The zero remains
unchanged.
6.9.2 Zero Hydrazine

A zero point calibration is not necessary.
If your quality procedure specifies a zero point calibration, please
proceed as described below:
NOTICE: Let the instrument run continuously for at least 5 days
in normal operation before doing a zero point calibration!
1 Navigate to menu <Maintenance>/<Calibration>/<Zero Hydra-
zine>.
2 Press [Enter].
3 Follow the instructions on the screen.
During a zero calibration, the sample flow is turned off and the re-
sidual hydrazine in the small water volume around the sensor is
consumed within 15–20 min. 0 ppb remains and after 30 min, a
zero calibration is performed.
Current value / offset (Progress of zero cal. is shown). Wait until fin-
ished.
Open tap of the water inlet and regulate the sample flow.
46 A-96.250.501 / 020720
AMI Hydrazine
Maintenance
6.9.3 Process Hydrazine

The sample must always overflow into the longer overflow tube of
the constant head. Only perform process calibration if the differ-
ence is significant.
Grab sample Take a grab sample directly from the flow cell. Open the grab sam-
ple valve and drain water for a minute before taking the sample.
Observe the displayed value of the AMI Hydrazine while taking the
grab sample. The measuring value has to be stable.
Determine the hydrazine concentration of the sample by manual
analysis.
Compare the result with the measuring value of the AMI Hydrazine.
If the measuring value of the AMI Hydrazine has changed while
performing the manual analysis, enter the difference between the
measuring values of the AMI Hydrazine.
Example Displayed measuring value of AMI Hydrazine during grab sample:
10 ppb.
Displayed measuring value of AMI Hydrazine after concentration
determination: 15 ppb.
Determined hydrazine concentration: 8 ppb.
There is a change of the measurement value of 50% during the
concentration determination. This means, you have to correct the
determined hydrazine concentration also with a factor of 50%.
This will result in a value of 8 ppb + (50% of 8 ppb) = 12 ppb.
Finally, you have to enter 12 ppb as a process value at the AMI
transmitter.
Example of 1 Navigate to menu
Process Maintenance 3.1
<Maintenance>/<Calibration>.
Calibration Calibration
Simulation 2 Press [Enter].
Set Time 01.01.05 16:30:00
1 Select Process Hydrazine.

Calibration 3.1.1
Zero Hydrazine 2 Press [Enter].
Process Hydrazine
A-96.250.501 / 020720 47
AMI Hydrazine
Maintenance
Process Hydrazine 3.1.4.1 The following values are displayed:

Current Value 18.80 ppb  Current value
Raw value x µA  Raw value
 Process value
Process Value 18.80 ppm Current value and Process value are
Save <Enter> equal.
3 Press [Enter].
4 Enter the calculated value.
Process Hydrazine 3.1.2.5
 Use the [ ] or [ ] keys
Current Value 18.8 ppb
to increase or decrease the
Raw value x nA
Process value.
Process Value 24.0 ppb
Save <Enter>
5 Press [Enter] to save.
Current Value 18.80 ppb
Raw value x µA
Process Value 24.0 ppb

Save <Enter>

Current Value 15 ppb
Raw value x µA
Calibration successful
During calibration, control is interrupted. The signal outputs are fro-

zen if hold after calibration has been programmed (menu 4.3.4.2).
Otherwise the outputs track the measuring value. Hold after calibra-
tion is indicated by Hold in the display.
Possible error message see Troubleshooting, p. 50.
48 A-96.250.501 / 020720
AMI Hydrazine
Maintenance
6.10. Longer Stop of Operation

Do not switch off the instrument if your operation is suspended for
less than a week. Power consumption is very low, and the sensors
remain ready for use.
Shut-down the instrument as described in chapter Stop of Opera-
tion for Maintenance, p. 36.
Then:
1 Remove the Diisopropylamine bottle from the bottle holder and
close it well.
2 Remove the diffusion tube from the steel tubes and dip it into a
beaker filled with high purity water. Rinse it some seconds.
3 Unscrew and remove the filter vessel from the flow cell block,
empty and dry it, then screw it onto the flow cell block again.
4 Loosen the connector from the reference electrode and put the
connector cap on the electrode plug.
Do not spill water on connector.
5 Remove the reference electrode from the flow cell block, fill wa-
ter in the protective cap and put the protective cap on the elec-
trode tip.
6 Store it dry and frost protected with tip pointing downwards.
7 Remove the BNC connector from the hydrazine sensor.
Do not spill water on connector.
8 Hold the hydrazine sensor with one hand while unscrewing and
removing the 2nd knurled nut.
9 Remove the hydrazine sensor from the flow cell.
10 Dry it with a soft, clean tissue, and store dry.
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Troubleshooting
7. Troubleshooting
This chapter provides some hints to make troubleshooting easier.
For any detailed information how to handle or clean parts please see
Maintenance, p. 35. For any detailed information how to program the
instrument please see Program List and Explanations, p. 61.
Process Possible error message
calibration  Current value too low or no sample flow.
 Offset Error
 Slope Error
Current value too low or no sample flow:

Possible cause Corrective action
The ppb value of the sample is  Process value used for
too low, thereby, the current dif- calibration should be higher.
ference to zero is too small.  Check the diagnostic value of
the zero point.
Low sample flow resulting in no Check sample inlet pressure, if
signal difference to zero. necessary readjust sample flow
to min. 170 rpm.
Hydrazine sensor contaminated Clean sensor, see Cleaning of
Sensor does not provide enough the Hydrazine Sensor, p. 38.
current for the value measured In case of repeated sensor con-
with the manual analysis. tamination, check for water treat-
ment chemicals such as
phosphates.
Offset Error:
Run-in time of sensor to short. Let the sensor run-in at least 30
min
Zero point calibration was too Repeat the zero point calibration
short.
50 A-96.250.501 / 020720
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Troubleshooting
Slope Error:
Diisopropylamine bot- Exchange Diisopropylamine bottle, see
tle empty Changing the Diisopropylamine Bottle, p.
44 or Install the Diisopropylamine Bottle,
p. 28.
Insufficient immersion Place the diffusion Tube correct, see
depth of the diffusion Changing the Diffusion Tube, p. 45.
tube.
Orifices at sensor inlet Clean the senor, see Cleaning of the
clogged Hydrazine Sensor, p. 38.
Run-in time of diffu- After replacing the diffusions tube let the
sions tube too short instrument run in at least 30 min
Too much water in the Check diffusion tube for leakage and
Diisopropylamine bot- replace it if necessary, see Changing the
tle. Diffusion Tube, p. 45.
Install a new DIPA-bottle, see Install the
Diisopropylamine Bottle, p. 28.
Sample flow too high. Readjust the sample flow to min. 170 rpm
Sample flow too low Sample flow must not be smaller than
170 rpm.
Readjust sample flow to min. 170 rpm.
Reference The reference electrode may be old or damaged. Under the follow-
electrode ing conditions the reference voltage should be:
In water < 10 ppb oxygen and about 70 ppb hydrazine: ~ 1300 mV
In water with oxygen: ~ 400 mV
CE (counter electrode) value: 200–400 mV
Lower values indicate coated hydrazine sensors.
Diagnostic Offset: The offset is approx. 50 nA
values An offset calibration is only necessary for Hydrazine values lower
than 0.05 ppb. Running Time at least 24 hours.
Slope: The slope is approx. 55 nA/ppb.
NOTICE: Observe the running in time.

A decreasing slope value over several process calibrations
indicates coating of sensor.
Slope (and Zero) too high usually indicates that the running in time
was too short.
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Troubleshooting
7.1. Error List

Error
Non-fatal Error. Indicates an alarm if a programmed value is ex-
ceeded.
Such Errors are marked E0xx (bold and black).
Fatal Error (blinking symbol)
Control of dosing devices is interrupted.
The indicated measured values are possibly incorrect.
Fatal Errors are divided in the following two categories:
 Errors which disappear if correct measuring conditions are re-
covered (i.e. Sample Flow low).
Such Errors are marked E0xx (bold and orange)
 Errors which indicate a hardware failure of the instrument.
Such Errors are marked E0xx (bold and red)
HOLD 14:10:45 Error or fatal Error

R1 Error not yet acknowledged.
R2 0.5 ppb Check Pending Errors 1.1.5 * and
take corrective action.
80 rpm 23 °C Press [ENTER].
Messages 1.1 Navigate to menu <Messages>/

Pending Errors <Pending Errors>.
Maintenance List
Message List
Pending Errors 1.1.5 Press [ENTER] to acknowledge the

Error Code E002 Pending Errors.
 The Error is reset and saved in
Alarm low the Message List.
<Enter> to Acknowledge
52 A-96.250.501 / 020720
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Troubleshooting
Error Description Corrective action

E001 Hyd. Alarm high – check process
– check programmed value 5.3.1.1.1, p.
68
E002 Hyd. Alarm low – check process
68
E007 Sample Temp. high – check process
69
E008 Sample Temp. low – check process
68
E009 Sample Flow high – check Inlet pressure
– readjust sample flow
68
E010 Sample Flow low – check Inlet pressure
– readjust sample flow
– clean instrument
69
E011 Temp. shorted – Check wiring of temperature sensor,
see Connection Diagram, p. 20.
– Check sensor
E012 Temp. disconnected – Check wiring of temperature sensor,
see Connection Diagram, p. 20.
– Check sensor
E013 Case Temp. high – check case/environment temperature
– check programmed value 5.3.1.4, p. 69
E014 Case Temp. low – check case/environment temperature
– check programmed value 5.3.1.5, p. 69
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Troubleshooting
Error Description Corrective action

E015 Reference – Check conductivity value of sample
(must be > 5 µS/cm)
– Check gain of hydrazine sensor. If too
small, clean hydrazine sensor.
– Exchange reference electrode.
E017 Control Timeout – check control device or programming in
Installation, Relay contact, Relay 1/2
see 5.3.2 and 5.3.3, p. 69
E024 Input active – See If Fault Yes is programmed in
Menu see 5.3.4, p. 73
E026 IC LM75 – call service
E028 Signal output open – check wiring on signal outputs 1 and 2
E030 EEProm Frontend – call service
E031 Calibration Recout – call service
E032 Wrong Frontend – call service
E033 Power-on – none, normal status
E034 Power-down – none, normal status
54 A-96.250.501 / 020720
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Troubleshooting
7.2. Replacing Fuses
WARNING
External Voltage.
External supplied devices connected to relay 1 or 2 or to the
alarm relay can cause electrical shocks.
 Make sure that the devices connected to the following con-
tacts are disconnected from the power before resuming in-
stallation.
– relay 1
– relay 2
– alarm relay
When a fuse has blown, find out the cause and fix it before replac-
ing it with a new one.
Use tweezers or needle-nosed pliers to remove the defective fuse.
Use original fuses provided by SWAN only.
A B C D E F G
A AC variant: 1.6 AT/250 V Instrument power supply

DC variant: 3.15 AT/250 V Instrument power supply
B 1.0 AT/250V Relay 1
C 1.0 AT/250V Relay 2
D 1.0 AT/250V Alarm relay
E 1.0 AF/125V Signal output 2
F 1.0 AF/125V Signal output 1
G 1.0 AF/125V Signal output 3
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Program Overview
8. Program Overview
For explanations about each parameter of the menus see Program
List and Explanations, S. 61.
 Menu 1 Messages informs about pending errors and mainte-

nance tasks and shows the error history. Password protection
possible. No settings can be modified.
 Menu 2 Diagnostics is always accessible for everybody. No
password protection. No settings can be modified.
 Menu 3 Maintenance is for service: Calibration, simulation of
outputs and set time/date. Please protect with password.
 Menu 4 Operation is for the user, allowing to set limits, alarm
values, etc. The presetting is done in the menu Installation
(only for the System engineer). Please protect with password.
 Menu 5 Installation: Defining assignment of all inputs and
outputs, measuring parameters, interface, passwords, etc.
Menu for the system engineer. Password strongly recom-
mended.
8.1. Messages (Main Menu 1)

Pending Errors Pending Errors 1.1.5* * Menu numbers
1.1*
Message List Number 1.2.1*
1.2* Date, Time
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Program Overview
8.2. Diagnostics (Main Menu 2)

Identification Designation AMI Hydrazine * Menu numbers
2.1* Version V6.20-05/18
Factory Test Instrument 2.1.3.1*
2.1.3* Motherboard
Front End
Operating Time Years / Days / Hours / Minutes / Seconds 2.1.4.1*
2.1.4*
Sensors Hydrazine Sensor Current Value
2.2* 2.2.1* (Raw value)
Ref. voltage
Cal. History Number 2.2.1.5.1*
2.2.1.5* Date, Time
Offset
Slope
Miscellaneous Case Temp. 2.2.2.1*
2.2.2*
Sample Sample ID 2.3.1*
2.3* Temperature °C
Nt5K Ohm
Sample Flow
(Raw value)
I/O State Alarm Relay 2.4.1*
2.4* Relay 1 and 2 2.4.2*
Input
Signal Output 1 and 2
Interface Protocol 2.5.1* (only with RS485
2.5* Baud rate interface)
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Program Overview
8.3. Maintenance (Main Menu 3)

Calibration Zero Hydrazine * Menu numbers
3.1* 3.1.1*
Process Hydrazine
3.1.2*
Simulation Alarm Relay 3.2.1*
3.2* Relay 1 3.2.2*
Relay 2 3.2.3*
Signal Output 1 3.2.4*
Signal Output 2 3.2.5*
Set Time (Date), (Time)
3.3*
8.4. Operation (Main Menu 4)

Sensors Filter Time Const. 4.1.1*
4.1* Hold after Cal. 4.1.2*
Relay Contacts Alarm Relay Alarm Alarm High 4.2.1.1.1*
4.2* 4.2.1* 4.2.1.1* Alarm Low 4.2.1.1.26*
Hysteresis 4.2.1.1.36*
Delay 4.2.1.1.46*
Relay 1 and 2 Setpoint 4.2.x.100*
4.2.2* and 4.2.3* Hysteresis 4.2.x.200*
Delay 4.2.x.30*
Input Active 4.2.4.1*
4.2.4* Signal Outputs 4.2.4.2*
Output / Control 4.2.4.3*
Fault 4.2.4.4*
Delay 4.2.4.5*
Logger Log Interval 4.3.1*
4.3* Clear Logger 4.3.2*
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Program Overview
8.5. Installation (Main Menu 5)

Sensors Temp.comp 5.1.1* * Menu numbers
5.1*
Signal Outputs Signal Output 1 and 2 Parameter 5.2.1.1 - 5.2.2.1*
5.2* 5.2.1* and 5.2.2* Current Loop 5.2.1.2 - 5.2.2.2*
Function 5.2.1.3 - 5.2.2.3*
Scaling Range Low 5.2.x.40.10/10*
5.2.x.40 Range High 5.2.x.40.20/20*
Relay Contacts Alarm Relay Alarm Hydrazine Alarm High 5.3.1.1.1*
5.3* 5.3.1* 5.3.1.1* Alarm Low 5.3.1.1.26
Hysteresis 5.3.1.1.36
Delay 5.3.1.1.46
Sample Flow Flow Alarm 5.3.1.2.1
5.3.1.2* Alarm High 5.3.1.2.2*
Alarm Low 5.3.1.2.36*
Sample Temp. Alarm High 5.3.1.3.1*
5.3.1.3* Alarm Low 5.3.1.3.26*
Case Temp. high 5.3.1.4*
Case Temp. low 5.3.1.5*
Relay 1 and 2 Function 5.3.2.1–5.3.3.1*
5.3.2* - 5.3.3* Parameter 5.3.2.20–5.3.3.20*
Setpoint 5.3.2.300–5.3.3.301*
Hysteresis 5.3.2.400–5.3.3.401*
Delay 5.3.2.50–5.3.3.50*
Input Active 5.3.4.1*
5.3.4* Signal Outputs 5.3.4.2*
Output/Control 5.3.4.3*
Fault 5.3.4.4*
Delay 5.3.4.5*
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Program Overview
Miscellaneous Language 5.4.1* * Menu numbers

5.4* Set defaults 5.4.2*
Load Firmware 5.4.3*
Password Messages 5.4.4.1*
5.4.4* Maintenance 5.4.4.2*
Operation 5.4.4.3*
Installation 5.4.4.4*
Sample ID 5.4.5*
Line break detection 5.4.6*
Interface Protocol 5.5.1* (only with RS485,
5.5* Device Address 5.5.21* interface)
Baud Rate 5.5.31*
Parity 5.5.41*
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Program List and Explanations
9. Program List and Explanations
1 Messages
1.1 Pending Errors
1.1.5 Provides the list of active errors with their status (active, acknowl-
edged). If an active error is acknowledged, the alarm relay is active
again. Cleared errors are moved to the Message list.
1.2 Message List
1.2.1 Shows the error history: Error code, date / time of issue and status
(active, acknowledged, cleared). 65 errors are memorized. Then
the oldest error is cleared to save the newest error (circular buffer).
2 Diagnostics
In diagnostics mode, the values can only be viewed, not modified.
2.1 Identification
Desig.: Designation of the instrument.
Version: Firmware of instrument (e.g. V6.20-05/18)
2.1.3 Factory Test: Test date of the Instrument and Motherboard.
2.1.4 Operating Time: Shows the operating time in Years, Days, Hours,
Minutes and Seconds.
2.2 Sensors
2.2.1 Hydrazine Sensor:
Current value: Actual measuring value in ppb
(Raw value) measuring value in nA
Ref. Voltage: Applied voltage at the counter electrode (CE) in mV
2.2.1.5 Cal. History: Shows the diagnostic values of the last calibrations of
the hydrazine sensor. Only for diagnostic purpose.
Number: Calibration counter
Date, Time: Date and time of calibration
Offset: Zero point displacement from the reference position in nA
Slope: Steepness of the straight line in nA
Max. 65 data records are memorized.
2.2.2 Miscellaneous:
2.2.2.1 Case Temp: Shows the actual temperature in °C inside the trans-
mitter.
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2.3 Sample
2.3.1 Sample ID: Shows the assigned sample identification. This
identification is defined by the user to identify the location of the
sample
Temperature: Shows temperature in °C.
(Nt5K): Shows raw value of the temperature in Ω.
Sample Flow: Shows the sample Flow in rpm
(Raw value) Shows the sample Flow in Hz
2.4 I/O State
Shows actual status of all in- and outputs.
2.4.1 Alarm Relay: Active or inactive
Relay 1 and 2: Active or inactive
Input: Open or closed
Signal Output 1 and 2: Actual current in mA
Signal Output 3 (option): Actual current in mA
2.5 Interface
Only available if optional interface is installed.
Review programmed communication settings.
3 Maintenance
3.1 Calibration
3.1.1 Zero Hydrazine
Zero calibration (0 ppb). See Zero Hydrazine, p. 46 for more de-
tails.
3.1.2 Process Hydrazine
For a process calibration of the hydrazine sensor follow the instruc-
tions on the screen. Save the value with the [Enter] key. See Pro-
cess Hydrazine, p. 47.
3.1 Simulation
To simulate a value or a relay state, select the
 alarm relay,
 relay 1or 2
 signal output 1or 2
with the [ ] or [ ] key.
Press the [Enter] key.
62 A-96.250.501 / 020720
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Change the value or state of the selected item with the [ ] or

[ ] key.
Press the [Enter] key.
 The value is simulated by the relay/signal output.
3.4.1 Alarm Relay: Active or inactive
3.4.2 Relay 1: Active or inactive
3.4.3 Relay 2 Active or inactive
3.4.4 Signal Output 1: Actual current in mA
3.4.5 Signal Output 2 Actual current in mA
At the absence of any key activities, the instrument will switch back
to normal mode after 20 min. If you quit the menu, all simulated val-
ues will be reset and the transmitter reboots.
3.2 Set Time
Adjust date and time.
4 Operation
4.1 Sensors
4.1.1 Filter Time Constant: Used to damp noisy signals. The higher the
filter time constant, the slower the system reacts to changes of the
measured value.
Range: 5–300 Sec
4.1.2 Hold after Cal: Delay permitting the instrument to stabilize again af-
ter calibration. During calibration plus hold-time, the signal outputs
are frozen (held on last valid value), alarm values, limits are not ac-
tive.
Range: 0–6‘000 Sec
4.2 Relay Contacts
See Relay Contacts 1 and 2, p. 23
4.3 Logger
The instrument is equipped with an internal logger. The logger data
can be copied to a PC with an USB stick if option USB interface is
installed.
The logger can save approx. 1500 data records. The Records con-
sists of: Date, time, alarms, measuring value, measuring value un-
compensated, case temperature, flow.
4.3.1 Log Interval: Select a convenient log interval. Consult the table be-
low to estimate the max logging time. When the logging buffer is
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full, the oldest data record is erased to make room for the newest
one (circular buffer).
Range: 1 Second to 1 hour
Interval 1s 5s 1 min 5 min 10 min 30 min 1h
Time 25 min 2h 25 h 5d 10 d 31 d 62 d
4.3.2 Clear Logger: If confirmed with yes, the complete logger data is de-
leted. A new data series is started.
5 Installation
5.1 Sensors
5.1.1 Temp Comp
Temperature compensation in %.
Range: 0.0–5.0%
5.2 Signal Outputs
NOTICE: The navigation in the menu <Signal Output 1> and
<Signal Output 2> is identical. For reason of simplicity only the
menu numbers of Signal Output 1 are used in the following.
5.2.1 and 5.2.2 Signal Output 1 and 2: Assign process value, the current loop
range and a function to each signal output.
5.2.1.1 Parameter: Assign one of the process values to the signal output.
Available values:
 Hydrazine
 Temperature
 Sample Flow
5.2.1.2 Current Loop: Select the current range of the signal output. Make
sure the connected device works with the same current range.
Available ranges: 0–20 mA or 4–20 mA
5.2.1.3 Function: Define if the signal output is used to transmit a process
value or to drive a control unit. Available functions are:
 Linear, bilinear or logarithmic for process values.
See As process values, p. 65
 Control upwards or control downwards for controllers.
See As control output, p. 66
64 A-96.250.501 / 020720
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As process The process value can be represented in 3 ways: linear, bilinear or

values logarithmic. See graphs below.
[mA]
20
(0 - 20 [mA])
(4 - 20 [mA])
B A
10 12
0/4 X
0.0 0.1 0.2 0.3 0.4 0.5
A linear X Measured value

B bilinear
[mA]
20
(0 - 20 [mA])
(4 - 20 [mA])
10 12
0/4 X
2 4 6
1 10 100 1’000 10’000
0 1 2 3 4
X Measured value (logarithmic)
5.2.1.40 Scaling: Enter beginning and end point (Range low & high) of the
linear or logarithmic scale. In addition, the midpoint for the bilinear
scale.
If Parameter = Hydrazine
5.2.1.40.10 Range low: 0.00–1000 ppb
5.2.1.40.20 Range high: 0.00–1000 ppb
If Parameter = Temperature
5.2.1.40.11 Range low: -30.0 to +120 °C
5.2.1.40.21 Range high: -30.0 to + 120 °C
If Parameter = Sample flow
5.2.1.40.12 Range low: 0–300 rpm
5.2.1.40.22 Range high: 0–300 rpm
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As control Signal outputs can be used for driving control units. We distinguish
output different kinds of controls:
 P-controller: The controller action is proportional to the devia-
tion from the setpoint. The controller is characterized by the
P-Band. In the steady-state, the setpoint will never be
reached. The deviation is called steady-state error.
Parameters: setpoint, P-Band
 PI-controller: The combination of a P-controller with an I-con-
troller will minimize the steady-state error. If the reset time is
set to zero, the I-controller is switched off.
Parameters: setpoint, P-Band, reset time.
 PD-controller: The combination of a P-controller with a
D-controller will minimize the response time to a fast change
of the process value. If the derivative time is set to zero, the
D-controller is switched off.
Parameters: setpoint, P-Band, derivative time.
 PID-controller: The combination of a P-, an I - and a D-con-
troller allows a proper control of the process.
Parameters: setpoint, P-Band, reset time, derivative time.
Ziegler-Nichols method for the optimization of a PID controller:
Parameters: Setpoint, P-Band, Reset time, Derivative time
Y
B A
X
a
A Response to maximum control output Xp = 1.2/a

B Tangent on the inflection point Tn = 2L
X Time Tv = L/2
The point of intersection of the tangent with the respective axis will
result in the parameters a and L.
Consult the manual of the control unit for connecting and program-
ming details. Choose control upwards or downwards.
66 A-96.250.501 / 020720
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If Control upwards or Control downwards is active

Setpoint: User-defined process value (Measured value or flow)
P-Band: Range below (upwards control) or above (downwards
control) the set-point, within the dosing intensity is reduced from
100% to 0% to reach the set-point without overshooting.
5.2.1.43 Control Parameters: if Parameter = Hydrazine
5.2.1.43.10 Setpoint
Range: 0.00–1000 ppb
5.2.1.43.20 P-Band
Range:0.00–1000 ppb
5.2.1.43 Control Parameters: if Parameter = Temperature
Range: -30 to +120 °C
5.2.1.43.21 P-Band
Range: 0 to +100 °C
5.2.1.43 Control Parameters: if Parameter = Sample Flow
Range: 0–300 rpm
5.2.1.43.22 P-Band
Range: 0–300 rpm
5.2.1.43.3 Reset time: The reset time is the time till the step response of a sin-
gle I-controller will reach the same value as it will be suddenly
reached by a P-controller.
Range: 0–9’000 sec
5.2.1.43.4 Derivative time: The derivative time is the time till the ramp re-
sponse of a single P-controller will reach the same value as it will
be suddenly reached by a D-controller.
Range: 0–9’000 sec
5.2.1.43.5 Control timeout: If a controller action (dosing intensity) is constantly
over 90% during a defined period of time and the process value
does not come closer to the setpoint, the dosing process will be
stopped for safety reasons.
Range: 0–720 min
5.3 Relay Contacts
5.3.1 Alarm Relay: The alarm relay is used as cumulative error indicator.
Under normal operating conditions the contact is active.
The contact is inactive at:
 Power loss
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 Detection of system faults like defective sensors or electronic

parts
 High case temperature
 Process values out of programmed ranges.
Program alarm levels for the following parameters:
 Alarm Hydrazine
 Sample Flow
 Sample Temp.
 Case Temp. high
 Case Temp. low
5.3.1.1 Alarm Hydrazine
5.3.1.1.1 Alarm High: If the measured value rises above the alarm high val-
ue, the alarm relay is activated and E001, is displayed in the mes-
sage list.
5.3.1.1.25 Alarm Low: If the measured value falls below the alarm low value,
the alarm relay is activated and E002 is displayed in the message
list.
5.3.1.1.35 Hysteresis: Within the hyst. range, the relay does not switch. This
prevents damage of relays contacts when the measured value fluc-
tuates around the alarm value.
Range. 0.00–1000 ppb
5.3.1.1.45 Delay: Duration, the activation of the alarm relay is retarded after
the measuring value has risen above/fallen below the programmed
alarm.
5.3.1.2 Sample Flow: Define at which sample flow a flow alarm should be
issued.
5.3.1.2.1 Flow Alarm: Program if the alarm relay should be activated if there
is a flow alarm. Choose between yes or no. The flow alarm will al-
ways be indicated in the display, pending error list, saved in the
message list and the logger.
Available values: Yes or no
NOTICE: Sufficient flow is essential for a correct measurement.
We recommend to program yes.
5.3.1.2.2 Alarm High: If the measuring values rises above the programmed
value E009 will be issued.
Range: 150–300 rpm
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5.3.1.2.35 Alarm Low: If the measuring values falls below the programmed
value E010 will be issued.
Range: 150–300 rpm
5.3.1.3 Sample Temp.: Define at which sample temperature an alarm
should be issued.
5.3.1.3.1 Alarm High: If the measured value rises above the alarm high val-
ue, the alarm relay is activated and E007 is issued.
Range: 30–70 °C
5.3.1.3.25 Alarm Low: If the measured value rises above the alarm high value,
the alarm relay is activated and E008 is issued.
Range: 0–20 °C
5.3.1.4 Case Temp. high: Set the alarm high value for temperature of elec-
tronics housing. If the value rises above the programmed value
E013 is issued.
Range: 30–75 °C
5.3.1.5 Case Temp. low: Set the alarm low value for temperature of elec-
tronics housing. If the value falls below the programmed value
E014 is issued.
Range: -10 to + 20 °C
5.3.2 and 5.3.3 Relay 1 and 2: The contacts can be set as normally open or nor-
mally closed with a jumper. See Relay Contacts 1 and 2, p. 23. The
function of relay contacts 1 or 2 are defined by the user.
NOTICE: The navigation in the menu <Relay 1> and <Relay 2>
is identical. For reason of simplicity only the menu numbers of
Relay 1 are used in the following.
1 First select the functions as:

- Limit upper/lower
- Control upwards/downwards
- Timer
- Fieldbus
2 Then enter the necessary data depending on the selected func-
tion.
5.3.2.1 Function = Limit upper/lower:
When the relays are used as upper or lower limit switches, program
the following:
5.3.2.20 Parameter: select a process value
5.3.2.300 Setpoint: If the measured value rises above respectively falls below
the set-point, the relay is activated.
A-96.250.501 / 020720 69
AMI Hydrazine
Parameter Range
Hydrazine 0.00–1000 ppb
Temperature -30 to +120 °C
Sample flow 0–300 rpm
5.3.2.400 Hysteresis: within the hysteresis range, the relay does not switch.
This prevents damage of relay contacts when the measured value
fluctuates around the alarm value.
Parameter Range
Hydrazine 0.00–1000 ppb
Temperature 0 to +100 °C
Sample flow 0–300 rpm
5.3.2.50 Delay: Duration, the activation of the alarm relay is retarded after
the measuring value has risen above/fallen below the programmed
alarm.
Range. 0–600 Sec
5.3.2.1 Function = Control upwards/downwards:
The relays may be used to drive control units such as solenoid
valves, membrane dosing pumps or motor valves. When driving a
motor valve both relays are needed, relay 1 to open and relay 2 to
close the valve.
5.3.2.22 Parameter: select a process value:
 Hydrazine
 Temperature
 Sample flow
5.3.2.32 Settings
Choose the respective actuator:
 Time proportional
 Frequency
 Motor valve
Actuator = Time proportional
Examples of metering devices that are driven time proportional are
solenoid valves, peristaltic pumps.
Dosing is controlled by the operating time.
70 A-96.250.501 / 020720
AMI Hydrazine
5.3.2.32.20 Cycle time: duration of one control cycle (on/off change).

Range: 0–600 sec.
5.3.2.32.30 Response time: Minimal time the metering device needs to react.
Range: 0–240 sec.
5.3.2.32.4 Control Parameters:
Range for each Parameter same as 5.2.1.43, p. 67
Actuator = Frequency
Examples of metering devices that are pulse frequency driven are
the classic membrane pumps with a potential free triggering input.
Dosing is controlled by the repetition speed of dosing shots.
5.3.2.32.21 Pulse frequency: Max. pulses per minute the device is able to re-
spond to. Range: 20–300/min.
Actuator = Motor valve
Dosing is controlled by the position of a motor driven mixing valve.
5.3.2.32.22 Run time: Time needed to open a completely closed valve
Range: 5–300 Sec.
5.3.2.32.32 Neutral zone: Minimal response time in % of the runtime. If the re-
quested dosing output is smaller than the response time, no
change will take place.
Range: 1–20 %
5.3.2.1 Function = Timer
The relay will be active repetitively depending on the programmed
time scheme.
5.3.2.24 Mode: Operating mode
Mode
interval
daily
weekly
5.3.2.24 Interval
5.3.2.340 Interval: The interval can be programmed within a range
of 1–1440 min.
A-96.250.501 / 020720 71
AMI Hydrazine
5.3.2.44 Run Time: Enter the time the relay stays active.
Range: 5–32400 sec.
5.3.2.54 Delay: during run time plus the delay time the signal and control
outputs are held in the operating mode programmed below.
Range: 0–6’000 sec.
5.3.2.6 Signal Outputs: Select operating mode of the signal output:
Cont.: Signal outputs continue to issue the measured value.
Hold: Signal outputs hold the last valid measured value.
Measurement is interrupted. Errors, except fatal errors,
are not issued.
Off: Signal outputs are switched off (set to 0 or 4 mA).
Errors, except fatal errors, are not issued.
5.3.2.7 Output/Control: Select operating mode of the controller output:
Cont.: Controller continues normally.
Hold: Controller continues based on the last valid value.
Off: Controller is switched off.
5.3.2.24 daily
The relay contact can be activated daily, at any time of a day.
5.3.2.341 Start time: to set the start time proceed as follows:
1 Press [Enter], to set the hours.
2 Set the hour with the [ ] or [ ] keys.
3 Press [Enter], to set the minutes.
4 Set the minutes with the [ ] or [ ] keys.
5 Press [Enter], to set the seconds.
6 Set the seconds with the [ ] or [ ] keys.
Range: 00:00:00–23:59:59
5.3.2.44 Run Time: see Interval
5.3.2.54 Delay: see Interval
5.3.2.6 Signal Outputs: see Interval
5.3.2.7 Output/Control: see Interval
5.3.2.24 weekly
The relay contact can be activated at one or several days, of a
week. The daily starting time is valid for all days.
72 A-96.250.501 / 020720
AMI Hydrazine
5.3.2.342 Calendar:
5.3.2.342.1 Start time: The programmed start time is valid for each of the pro-
grammed days. To set the start time see 5.3.2.341, p. 72.
Range: 00:00:00–23:59:59
5.3.2.342.2 Monday: Possible settings, on or off
to
5.3.2.342.8 Sunday: Possible settings, on or off
5.3.2.44 Run Time: see Interval
5.3.2.54 Delay: see Interval
5.3.2.6 Signal Outputs: see Interval
5.3.2.7 Output/Control: see Interval
5.3.2.1 Function = Fieldbus
The relay will be switched via the Profibus input. No further param-
eters are needed.
5.3.4 Input: The functions of the relays and signal outputs can be de-
fined depending on the position of the input contact, i.e. no function,
closed or open.
NOTICE: If the option 2nd Sample Stream is connected to the
AMI Hydrazine and <Channel Selection> is set to <External>,
the Input will be set to “Active = no” and no further settings are
possible.
5.3.4.1 Active: Define when the input should be active:
No: Input is never active.
When closed: Input is active if the input relay is closed
When open: Input is active if the input relay is open
5.3.4.2 Signal Outputs: Select the operation mode of the signal outputs
when the relay is active:
Continuous: Signal outputs continue to issue the measured value.
Hold: Signal outputs issue the last valid measured value.
Measurement is interrupted. Errors, except fatal
errors, are not issued.
Off: Set to 0 or 4 mA respectively. Errors, except fatal
errors, are not issued.
A-96.250.501 / 020720 73
AMI Hydrazine
5.3.4.3 Output/Control: (relay or signal output):

Continuous: Controller continues normally.
Hold: Controller continues on the last valid value.
Off: Controller is switched off.
5.3.4.4 Fault:
No: No message is issued in pending error list and the
alarm relay does not close when input is active.
Message E024 is stored in the message list.
Yes: Message E024 is issued and stored in the mes-
sage list. The Alarm relay closes when input is
active.
5.3.4.5 Delay: Time which the instrument waits, after the input is deactivat-
ed, before returning to normal operation.
5.4 Miscellaneous
5.4.1 Language: Set the desired language.
Language
German
English
French
Spanish
5.4.2 Set defaults: Reset the instrument to factory default values in three
different ways:
Set defaults
no
Calibration
In parts
Completely
 Calibration: Sets calibration values back to default. All other
values are kept in memory.
 In parts: Communication parameters are kept in memory. All
other values are set back to default values.
 Completely: Sets back all values including communication
parameters.
74 A-96.250.501 / 020720
AMI Hydrazine
5.4.3 Load Firmware: Firmware updates should be done by instructed

service personnel only.
Load Firmware
no
yes
5.4.4 Password: Select a password different from 0000 to prevent unau-
thorized access to the following menus:
5.4.4.1 Messages
5.4.4.2 Maintenance
5.4.4.3 Operation
5.4.4.4 Installation.
Each menu may be protected by a different password.
If you forgot the passwords, contact the closest SWAN representative.
5.4.5 Sample ID: Identify the process value with any meaning full text,
such as KKS number.
5.4.6 Line Break Detection: Define if message E028 should be issued in
case of a line break on signal output 1 or 2.
Choose between <Yes> or <No>.
5.5 Interface
Select one of the following communication protocols. Depending on
your selection, different parameters must be defined.
5.5.1 Protocol: Profibus
5.5.20 Device address: Range: 0–126
5.5.30 ID-Nr.: Range: Analyzer; Manufacturer; Multivariable
5.5.40 Local operation: Range: Enabled, Disabled
5.5.1 Protocol: Modbus RTU
5.5.21 Device address: Range: 0–126
5.5.31 Baud Rate: Range: 1200–115 200 Baud
5.5.41 Parity: Range: none, even, odd
5.5.1 Protocol: USB-Stick:
Only visible if an USB interface is installed. No further settings are
possible.
5.5.1 Protocol: HART
Device address: Range: 0–63
A-96.250.501 / 020720 75
AMI Hydrazine
Default Values
10. Default Values

Operation:
Sensors: Filter Time Const.:...................................................................... 30 s
Hold after Cal.:......................................................................... 300 s
Alarm Relay ...................................................................... same as in Installation
Relay 1 and 2 ...................................................................... same as in Installation
Input ...................................................................... same as in Installation
Logger: Logger Interval:..................................................................... 30 min
Clear Logger: ................................................................................ no
Installation:
Sensors Temp. comp.: .............................................................................. 3%
Signal Output 1 Parameter: ........................................................................Hydrazine
Current loop: ......................................................................4–20 mA
Function: .................................................................................. linear
Scaling: Range low: ............................................................0.00 ppb
Scaling: Range high:............................................................100 ppb
Signal Output 2 Parameter: ....................................................................Temperature
Current loop: .....................................................................4 –20 mA
Function: .................................................................................. linear
Scaling: Range low: ................................................................0.0 °C
Scaling: Range high:.............................................................50.0 °C
Alarm Relay: Alarm Hydrazine:
Alarm high:.........................................................................1000 ppb
Alarm low: ........................................................................... 0.00 ppb
Hysteresis: .............................................................................10 ppb
Delay:........................................................................................... 5 s
Sample Flow; Flow Alarm ........................................................... yes
Sample Flow; Alarm high .....................................................300 rpm
Sample Flow; Alarm low ......................................................150 rpm
Sample Temp; Alarm high: .......................................................55 °C
Sample Temp; Alarm low: ..........................................................5 °C
Case temp. high:......................................................................65 °C
Case temp. low: .........................................................................0 °C
Relay 1 and 2 Function: .......................................................................... limit upper
Parameter: ........................................................................Hydrazine
Setpoint:.............................................................................1000 ppb
Hysteresis: .............................................................................10 ppb
Delay:......................................................................................... 30 s
76 A-96.250.501 / 020720
AMI Hydrazine
Default Values
If Function = Control upw. or dnw:

Parameter:....................................................................... Hydrazine
Settings: Actuator: .......................................................... Frequency
Settings: Pulse Frequency: ..............................................120/min
Settings: Control Parameters: Setpoint:......................... 1000 ppb
Settings: Control Parameters: P-band: .............................. 10 ppb
Parameter:...................................................................Temperature
Settings: Control Parameters: Setpoint:............................... 30 °C
Settings: Control Parameters: P-band: .................................. 1 °C
Parameter:................................................................... Sample flow
Settings: Control Parameters: Setpoint:...........................300 rpm
Settings: Control Parameters: P-band: .............................. 10 rpm
Common Settings
Settings: Control Parameters: Reset time:............................... 0 s
Settings: Control Parameters: Derivative Time: ....................... 0 s
Settings: Control Parameters: Control Timeout:................... 0 min
Settings: Actuator: ................................................ Time proportional
Cycle time: ............................................................................ 60 s
Response time: ..................................................................... 10 s
Settings: Actuator ......................................................... Motor valve
Run time: ............................................................................... 60 s
Neutral zone: ...........................................................................5%
If Function = Timer:
Mode:.................................................................................... Interval
Interval: ................................................................................ 1 min
Mode: ........................................................................................daily
Start time:........................................................................ 00.00.00
Mode:..................................................................................... weekly
Calendar; Start time: ....................................................... 00.00.00
Calendar; Monday to Sunday:.................................................. Off
Run time: ................................................................................... 10 s
Delay: .......................................................................................... 5 s
Signal output:............................................................................. cont
Output/Control: .......................................................................... cont
Input: Active............................................................................ when closed
Signal Outputs ........................................................................... hold
A-96.250.501 / 020720 77
AMI Hydrazine
Default Values
Output/Control .............................................................................. off

Fault..............................................................................................no
Delay.......................................................................................... 10 s
Miscellaneous Language:............................................................................. English
Set default:....................................................................................no
Load firmware: .............................................................................. no
Password: ........................................................... for all modes 0000
Sample ID: ....................................................................... - - - - - - - -
Line break detection .....................................................................no
78 A-96.250.501 / 020720
AMI Hydrazine
Index
11. Index
A Instrument Overview .... 13
Alarm Hydrazine . . . . . . . 68 Interface . . . . . . . ..... 8
Alarm Relay . . . . . . . . 8, 22 HART . . . . . . .... 27
Modbus . . . . . .... 26
C Profibus . . . . . .... 26
Cable thicknesses . . . . . . 18 USB . . . . . . . .... 27
Cal. History . . . . . . . . . . 61
Calendar . . . . . . . . . . . 73 L
Changing values . . . . . . . 34 Logger . . . . . . . . . . . . 63
Checklist . . . . . . . . . . . 14 Longer Stop of Operation. . 49
Cleaning
Flow Cell . . . . . . . . 41 M
Hydrazine sensor. . . . 38 Modbus . . . . . . . . . . .. 26
Reference Electrode . . 40 Mounting requirements . .. 15
Connect
O
Sample inlet . . . . . . . 15
Waste . . . . . . . . . . 15
On-site requirements .... 11
Control Parameters . . . . . 67 P
D Power Supply . . . . . . 11, 21
Profibus . . . . . . . . . . . . 27
Default Values ........ 76
R
E
Relays. ........... 8, 23
EPDM seal .......... 44
Error List . .......... 50 S
Sample Flow . . . . . . . 29, 68
F
Sample Temp. . . . . . . . . 69
Flow . . . . . . . . . . . . . . 41
Setup . . . . . . . . . . . . . 28
Fluidics . . . . . . . . . . . . . 9
Signal Outputs . . . . 8, 25, 64
Function
Simulation . . . . . . . . . . 62
Control upwards / downwards 70
Software . . . . . . . . . . . 33
Limit upper / lower . . . 69
System, Description of . . . . 8
Timer . . . . . . . . . . . 71
T
H
Technical Data . . . . . . . . 13
HART ............. 27
Terminals . . . . 20, 22–23, 26
I
U
Input . ......... 8, 22, 73
USB Interface ........ 27
A-96.250.501 / 020720 79
AMI Hydrazine
Notes
12. Notes
80 A-96.250.501 / 020720
AMI Hydrazine
Notes
A-96.250.501 / 020720 81
AMI Hydrazine
SWAN
is represented worldwide by subsidiary companies
and distributors.
cooperates with independent representatives

all over the world.
SWAN Products
Analytical Instruments for:
High Purity Water
Feedwater, Steam and Condensate
Potable Water
Pool and Sanitary Water
Cooling Water
Waste Water and Effluents
Made in Switzerland
82 A-96.250.501 / 020720

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AMI Hydrazine

Version 6.20 and higher

Title: AMI Hydrazine Operator’s Manual

00 June 2007 First Edition

01 April 2015 Update to Rev. 5.40, mainboard V2.4

02 July 2017 Update to Rev. 6.10, mainboard V2.5

03 July 2020 Mainboard V2.6

© 2020, SWAN ANALYTISCHE INSTRUMENTE AG, Switzerland, all rights reserved

subject to change without notice

AMI Hydrazine–Operator’s Manual

1.1. Warning Notices

Your life or physical wellbeing are in serious danger if such

Severe injuries or damage to the equipment can occur if such

Damage to the equipment, minor injury, malfunctions or incor-

Mandatory The importance of the mandatory signs in this manual.

Warning Signs The importance of the warning signs in this manual.

Electrical shock hazard

1.2. General Safety Regulations

Modifications Modifications and instrument upgrades shall only be carried out by

Electrical Shock Hazard

Only SWAN trained and authorized personnel shall perform the

1.3. Restrictions for use

Flow High concentrations of Diisopropylamine reagent may attack the

A Constant head G Filter vessel

2.2. Instrument Specification

Dimensions Panel: 280x850x180 mm, stainless steel

2.3. Instrument Overview

A Panel K Filter vessel

3.1. Installation Checklist Monitors

On site AC variant: 100–240 VAC ( 10%), 50/60 Hz ( 5%)

3.2. Mounting of Instrument Panel

3.3. Connecting Sample and Waste

3.4. Install the Reference Electrode

A Connector D Union nut

To install the reference electrode proceed as follows:

1 Loosen the union nut [D].

3.5. Install the Temperature Sensor

To install the temperature sensor proceed as follows:

1 Remove the temperature sensor [A] from the panel.

3.6. Electrical Connections

Risk of electrical shock.

A PG 11 cable gland: cable Øouter 5–10 mm

To prevent from electrical shock, do not connect the instrument

The mains of the AMI transmitter must be secured by a main

3.6.1 Connection Diagram

3.6.2 Power Supply

Electrical shock hazard

A Power supply connector

3.7. Relay Contacts

3.7.2 Alarm Relay

NOTICE: With certain alarms and certain settings of the AMI

Terminals Description Relay connection

NO 12/11 Active (closed) during normal 11

3.7.3 Relay Contacts 1 and 2

A Jumper set as normally open (standard setting)

Risk of damage of the relays in the AMI Transmitter due to

3.8. Signal Outputs

3.8.1 Signal Output 1 and 2 (current outputs)

3.9. Interface Options