PHYSICS

SECTION-1

1. (B)
F = 2Tcos o
F
T=
3
component of T towards each other particle
Acceleration of particle towards each other =
m
T cos 60o ( F / 3 )(1 / 2) F
= = =
m m 2 3m

2. (D)
( f1 ) max = µ1m1 g = 6 N
( f 2 ) max = µ2 m2 g = 10 N
At t = 2 s, F ' = 4 N
Net pulling force, F1 = F '−F ' = 11 N

3. (A)
x + y = constant.
dx dy
 + =0
dt dt
 dx   dy 
Or −  =  
 dt   dt 
 v1 − v0 = v2 Or v1 − v2 = v0
gx 2 dy  g 
4. (A) y = x tan  −  = (tan  ) −  2 x
2u cos 
2 2
dx  u cos  
2

dy
 versus x graph is straight line with negative slope and positive intercept.
dx
2 H 2
5. (C) t = T  =
g 
g 2g
 = 2 =
2H H
dU
6. (C) F =− Or dU = − Fdx = (ax − bx 2 )dx
dx
Assuming U = 0, and integrating the above equation we get,
 ax 2 bx 3
U= −
2 3
3a
U = 0 at x = 0 and x =
2b
3a x 3 x2
For x  ,b  a and U will become negative. So, option (C) is the most appropriate answer.
2b 3 2
7. (C) After falling on plank downward force on block is mg and upward force is kx. Kinetic energy will increase when
mg > kx and it will decrease when kx > mg. Therefore, maximum when.
mg
kx = mgor, x = and this does not depend on h.
k
h  m
8. (A) W = Mgh + mg =  M +  gh
2  2

9. (C)Vx = u 2 cos 45o = u

Vx Vx u
tan 60o =  Vy = =
Vy 3 3
2
 u  2u
 V = V +V = u + 
x
2
 =
y
2 2

 3 3
10. (C) At the time of leaving contact
N=0
mv2 m(2 gh)
 mg cos  = =
R R
R 
2 + R(1 − cos  )
=  
2h 4
 cos  =
R R
5
On solving the equation, we get cos = 5 / 6  = cos −1  
6
11. (C) a A = g sin 
v 2
2 gh 2 gR(1 − cos  )
aB = = =
R R R
Given, a A = aB
 sin  = 2 − cos 
Squaring these two equations we have,
sin 2  = 4 + 4 cos 2  Or 1 − cos 2  = 4 + 4 cos 2  − 8 cos 
3 −1  3 
On solving this equation, we get cos  = or  cos  
5 5
12. (B)
According to law of conservation of energy total energy always remain conserved but due to dissipation of energy
 kinetic energy will not be conserved in inelastic collision. As no external force is there momentum will remain
conserved.
13. (B)
Due to the work done by internal force kinetic energy of system of particles can change but both action reaction of
internal forces are there within the system so no change in momentum take place.
d 2d 1
14. (A) =  e=
u cos  u cos  2
15. (D) Let initial velocity of m1 is u and after collision, velocities of m 1 and m2 are v1 and v2 respectively.
m1 − m2 2m1
v1 = u ; v2 = u
m1 + m2 m1 + m2
2
1  2m1  1 m2 .(4m12u 2 )
Kinetic energy of m2 after collision k 2 = m2    k2 =
2  m1 + m2  2 (m1 + m2 ) 2
1
Kinetic energy of m1 before collision, k1 = m2u 2
2
k2 4m12 m2u 2 2 4m1m2
f = =   f =
k1 2(m1 + m2 ) m1u 2
2
(m1 + m2 ) 2
 3R  H
16. (B) Use m1   = m2  
 8   4
17. (C) Acceleration due to gravity = g.
2  20
18. (D) t= = 2 sec
10
R = 5  t = 5  2 = 10m; S = 102 + 202 = 10 5m
19. (C)
2mg − mg g 2mg − mg
(A) a= = (B) a= =g
3m 3 m
2mg 2mg 2 g
(C) a = = 2g (D) a = =
m 3m 3
20. (C) Let CD = l
l
r = 0.5 +
2
T sin 45 = m 2 r
o

T cos 45o = mg  mg = m 2 r
 1  1
 10 = 10 0.5 +   l = 0.5 2 = m
 2 2

SECTION-2

0 .9 3
1. (2) = tan 37 o =
a 4
 a = 1.2 m / s 2

Let N = normal reaction between rod and wedge.

Then N sin 37o will provide the necessary ma force to the wedge
  N sin 37o = ma = (1)(1.2) = 1.2
1.2 1.2
N = o
= = 2N
sin 37 0.6
2. (8)
Maximum range is obtained at 45o
2
u
= 1.6 or u = 4m / s
g
2u sin 45o 2  4  (1 / 5 )
T= = = 0.4 2s
g 10
t 2 2
Number of jumps in given time, = n= =5
T 0.4 2
 Total distance travelled = 1.6  5 = 8 m
3. (1) h = 1m
F = mg = 110 = 10 N
W = Fh = 10 1 = 10 Joules
4. (2) Pi = F .v = 5 + 3 − 6 = 2W
5. (5) Both will show same tension
 Reading of is = 5 N.

CHEMISTRY

SECTION-1

1. (C) XeF4 : sp 3d 2

Hybridisation : square planar shape

2. (B) These are simple conceptual facts related to an adiabatic reversible process of an ideal gas.
3. (A) ΔSuniv = 0, Suniv is maximum
R f = Rb R = Rate of reaction

 a 
4. (B) A real gas will tend to behave as an ideal gas at T =   ; Boyle’s temperature.
 Rb 
5. (B) It is an isothermal process.
W = −w = −− Pext (VB − VA )
= +1 atm [20 - 15] = 5 atm × L  0.5 kJ
6. (D) For reaction having (n) g = 0 , the degree of dissociation or association depends upon value of temperature
but not on value of pressure.
For reaction :
7. (B) w → path variable
Cm , Δ f Ho intensive properties
G → extensive, state variables.
+
8. (A) Paramagnetic → O 2 , B2 , O2
 Diamagnetic → C2 H 2
1
9. (D) Rate of diffusion  (Mo = Molar mass) under identical condition of T and P. As molar mass of
o
M
N2H4 (g) and O2(g) are equal to thus their rate of diffusion will be same.
1 3
10. (D) (N  N)(g) + (H − H) (g) ⎯ ⎯→ NH3 (g)
2 2
ΔH o(N  N) 3
 Δ f H oNH3 (g) + Δ H o(H − H) − 3Δ H oN − N
2 2
900 3 1050
= + [350] − 3[450] = 450 + − 3(450) = 525 − 900 = −375 kJ/mol
2 2 2
(A) ΔU rxn = (per mole of C 6 H 6 () ) = -900 kJ/mole
o
11.
ΔHorxn = ΔUorxn + (Δ n) g RT
15
Reaction C 6 H 6 ( ) +
O 2 (g) ⎯1⎯
⎯→ 6CO 2 (g) + 3H 2 O()
atm

2 300K

(n) g = 6 − 7.5 = −1.5

RT = 8.314  300  2.5kJ/mole
1.5 RT = 3.75 kJ/mole
 ΔH orxn = −900 − 3.75 = −903.75 kJ/mole
Liberated heat (per mole) = 903.75 kJ/mole
12. (C) Addition of inert gas at constant volume has no effect on a reaction at equilibrium.
1
13. (D) KC =
[B] 5
The solids have unit concentration.
−18
14. (B) µobs = 2.4Debye = 2.4 110 esu  cm
−10
µTheoretical = 4.8 10 esu 110 −8 cm = 4.8 10 −18 esu  cm
µobs 2.4 10 −18
% ionic character = 100 = 100 = 50%
µ theo 4.8 10 −18
15. (D) NH 4 HS(s) ⎯
⎯→ NH3 (g) + H 2S
Initial state 0.5 -
At equilibrium (0.5 + p) p
PT = (0.5 + 2p) = 0.84 atm
2p = 0.34 atm
P = 0.17 atm
 K p = PNH3 PH 2S = (0.67) (0.17) = 0.114
16. (A) Theoretical hydrogenation enthalpy of benzene.
3Δ hydg of cyclohexene = 3 [-119] = - 357 kJ / mole
R.E. = Δ hydgHo − Δ hydgHo = −357 − [−206.5] = −150.5kJ/mo le
(Theo) (Exp.)

V 
17. (C) Isothermal Rev. process ; ΔSsys = nRlog  r 
 Vi 
T 
Isobaric Rev. process ; ΔSsys = nC p log  f 
 Ti 
 T  V 
Adiabatic Irrev. Process; ΔSsys = nC V log  f  + nR log  f   0
 Ti   Vi 
18. (D) (I) Intramolecular H-bonding is MORE favourable than intermolecular H- bonding.
(II) For diatomic species up to atomic number = 7
P.E. of σ2pz is greater than of π2p x M.O.
19. (A)

2
 1 
K1 =  
 K2 
7
20. (A) C 2 H 6 + O 2 → 2CO 2 + 3H 2 O
2
‘x’ L of C2H6 gives ‘2x’ L of CO2
9
C3 H 8 + O 2 → 3CO 2 + 4H 2 O
2
(4 - x)L of C3H8 give 3(4 - x) L of CO2
Total CO2 = 10 = 2 x + 3(4 − x)  x = 2

SECTION-2

3
1. (6) 16[ Z ] = 16  = 6
8 
2. (5) XeF4 , XeF2 , SF6 , PCl5 and PF2 Cl3
3. (2) C(graphite ) ⎯
⎯→ C(diamond)
ΔH rxn = ΔC Ho(graphite − ΔCHo(Diamond) = −832.8 − [−834.8] = 2kJ/mole
ΔH C p 75
4. (3) = = =3
Δ U Cv 25
ΔH rxn [−30 + (−10) − (−60)] 20 1000
5. (1) Teq = = = = 1000K
ΔSrxn [(1 + 15) − (5 + 8)] 20

MATHEMATICS

SECTION-1

5!
1. (C) A, I, I, I, O can occur at odd places in ways, and the remaining letters N, N, D, L can be arranged at the
3!
4!  5!  4! 
remaining places in ways. Thus the required number of ways =    = 240 ways.
2!  3!  2! 
 7!
2. (D) We can permute M, I, I, I, I, P, P in ways. Corresponding to each arranged of these seven letters, we have 8
4!2!
places where S can be arranged as shown below with X.

8
We can choose 4 places out of 8 in C 4 ways.

Thus, the required number of ways = ( C ) 4!7!2!  = (7) ( C ) ( C )

8
4
8
4
6
4
 
3. (C) Letters appearing in the word COCHIN are
C, C, H, I, N, O
Words appearing before COCHIN are of the form C X ……
Where X is one of the letters C, H, I, N and the four remaining places can be filled by the remaining four letters.
Thus, the number of words before COCHIN is (4) (4!) = 96
4. (C) Arrange non-vegetarian in (6 - 1)! = 5! Ways and vegetarian in (5 - 1)! = 4! Ways
 required number of ways = (5!) (4!) = (120) (24) = 2880
5. (D) Treating w women as one block, we can permute m men and one block in (m + 1)! Ways and women in the
block in w! ways. Thus, the required number of ways is (m + 1)!w!.
6. (A) The number of paths = The number of ways of arranging 5U’s and 7R’s.
12! 12
= = C5
5!7!
7. Let x1 = x + 5, y1 = y + 5, z1 = z + 5 and find the number of non-negative integral solutions of
x1 + y1 + z1 = 15
8. (B) Let the number of yellow balls be x, that of black be 2x and that of green be y. Then
x + 2 x + y = 20 or 3x + y = 20
 y = 20 − x
As 0  y  20, we get : 0  20 − 3x  20
 0  3 y  20, or 0  x  6
 The number of ways of selecting the balls is 7.
9. (B) According to the given condition

( C )(2w) = 20
n
2  n(n − 1)w = 120
and ( C )(3w) = 240
n
3  n(n − 2) w = 480
n(n − 1)( n − 2) w 480
Thus, =
n(n − 1) w 120
 n−2= 4  n=6

10. (B) |  | = 2   = 2ei = 2(cos  + i sin  )

 1 1
 x + iy =  − = 2ei − e −i
 2
3 5 x2 y2
 x = cos  , y = sin   + = 1 which represents an ellipse
2 2 9 / 4 25 / 4
11. (A) Taking conjugate, we get :

(a + b ) 2 7
= x + y 2  (a 3
+ b 2 )
7
= x 2 + y 2

 14 (a + b )7 =  2 (x + y )  (a + b) 7 = x + y

 2 k   2k 
12. (D) sin   − i cos 
 7   7 
  2 k   2 k 
= i cos  + i sin   = −i
k
[De Moivre’s theorem]
  7   7 
 2   2 
Where  = cos  + i sin  
 7   7 
Note that 7 =1
6
− ( − 1) − i( −  7 ) − i( − 1)
 S = i = k
=i = = =i
k =1 1−  1−  1− 
1−  n 1
13. (A) We have 1 +  +  + ....... + 
2 n −1
= =
1−  1− 
 n   n 
As  n = cos  + i sin   = cos  + i sin  = −1
 n   n 
2 2(1 −  ) 2(1 −  )
Now, = =
1 −  (1 −  )(1 −  ) 1 − ( +  ) + 
2(1 −  )
=
2 − 2 Re( )
 =|  2
|= 1
1 − Re( ) + i Im(  ) Im(  )
= = 1+ i
1 − Re( ) 1 − Re( )
     
sin   2 sin   cos 
= 1+ i  n  = 1+ i  2n   2n  = 1 + i cot  
 
  2    2n 
1 − cos  2 sin  
n  2n 
14. (A) log (1/ 7 ) | z − 2 | log (1/ 7 ) | z |

 | z − 2 || z | ……(i)
 But |z - 2| = |z| represents perpendicular bisector of the segment joining 0 and 2, that is |z - 2| = |z| represents the line
Re(z) = I. As 0 does not satisfy (i), we get (i) represents Re(z) > 1.

15. (D) Using  k +  k +1 +  k + 2 = 0k  I .

60
We get : k =1
k
=0

30
1
Next, 
k =1
k
=  m = where m = 1 + 2 + .... + 30 =
2
(30)(31) = 465

30
 
k =1
k
=  465 = 1

1 1 1
16. (D) , , , .... are in A.P.
a1 a2 a3
1 1
Let d be the common difference of − = 19d
a20 a1
1 1 4
 − = 19d d =−
25 5 475
1 (n − 1)4
Now, an  0  − 0
5 475
95
 n −1   n  25
4
Thus, least value of n is 25.
r +1
17. (A) Let t r = r log = r log( r + 1) − log r  = (r + 1) log( r + 1) − r log r − log( r − 1)
r
n n n
  tr = (r + 1)log( r + 1) − r log r−  log( r + 1)
r =1 r =1 r =1

(n + 1) n+1 (n + 1) n
= (n + 1) log( n + 1) − log 1 − log( n + 1)! = log = log
(n + 1)! n!
18. (C) We have 2(2b) = a + 3c and b 2 = ac
1
 (a + 3c) 2 = ac
16
 a 2 + 9c 2 + 6ac = 16ac  a 2 − 10ac + 9c 2 = 0
 (a − c)( a − 9c) = 0  a = 9c [ a  c]
c 1 1 1
 = or r 2 = r = [ a, b, c  0]
a 9 9 3
19. (C) If tn denotes the nth term of the series, then
 1
n(n + 1)
1 + 2 + 3 + ... + n 2 2 1 1 
tn = 3 3 3 = = = 2 −
1 + 2 + 3 + ... + n n 2 (n + 1) 2 n(n + 1)  n n + 1
3
1
4
n
 1   1 1  1 1   1  2n
 t k = 21 −  +  −  + .... +  −  = 21 − =
 n n + 1   n + 1  n + 1
k =1  2   2 3 
3
20. (C) We have a + c = 2b  3b + a + b + c =
2
1
 b=
2
1
Thus, a + c = 1 and a 2 c 2 = b 4 =
16
1
 a 2 (1 − a) 2 =
16
1
 a(1 − a ) = 
4
 4a 2 − 4a  1 = 0  (2a − 1) 2 = 0 or (2a − 1) 2 = 2
1 1 1
 a= or a = 
2 2 2
1 1 1
As a < b < c and b= , we get : a = −
2 2 2

SECTION-2

 
49 49
1. (6)  |_n (n 2 + 2n + 1 − n) =  |_n (n + 1) 2 − n
n =1 n =1

49

 ((n + 1) n + 1 − n |_n )
n =1
= 50 |_50 − 1

50 − r
2. (1) Let tr = ,r  2
r (r + 1)
49
50 − r
We have  r (r + 1)
r =2

49
1 1  49 1
= 50  − −
r =2  r r + 1  r =2 r + 1
  1 1  49 1
= 50 −  − 
 2 50  r =1 r + 1
50
1  1  51 50 1
= 24 −  + 1 +  = −
r =1 r  2  2 r =1 r
 k = −1
a a
3. (7) Let five terms in G.P. be 2
, , a, ar , ar 2
r r

Then,
(
a r −2 + r −1 + 1 + r + r 2 )
= 49  a 2 = 49  a = 7
1 2
(
  r + r +1+ r + r
−1 −2
)
a
a
Also, + a = 35
r2
Therefore, a = -7 is not possible

 a  7
Now, fifth term = ar = a − = p 4p = 7
2

 28  4
4. (5) Any number 5-digit formed by 2, 3, 5, 7, 9, exceeds 20000. Therefore, p = 5! = 120
A number will lie between 30000 and 90000 if it begins with 3, 5 or 7.
 q = (3) (4!) . Thus p : q = 5 : 3  3 p : q = 5

5. (3) 2 2 n +1 − 1 − 1 = 126
22 n+1 = 27
2n + 1 = 7
n=3