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Assignment-3 - LS Coupling and JJ Coupling

This document contains 10 questions regarding LS and JJ coupling schemes for various electron configurations. It asks the student to determine spectroscopic terms, states, and order the states by energy. It also asks the student to determine selection rules and draw energy level diagrams for specific configurations coupled under LS and JJ schemes.

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m9461309595
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275 views

Assignment-3 - LS Coupling and JJ Coupling

This document contains 10 questions regarding LS and JJ coupling schemes for various electron configurations. It asks the student to determine spectroscopic terms, states, and order the states by energy. It also asks the student to determine selection rules and draw energy level diagrams for specific configurations coupled under LS and JJ schemes.

Uploaded by

m9461309595
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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fiziks

Institute for NET/JRF, GATE, IIT-JAM, M.Sc. Entrance, JEST, TIFR and GRE in Physics

Assignment - 03
LS Coupling and JJ Coupling

Q1. Find the spectroscopic terms of the 3 p3d configuration and arrange them in the
increasing order of energy

Q2.  
Find the spectroscopic terms of carbon 1s 2 2s 2 2 p 2 and arrange them in the increasing

order of energy

Q3. Find all the spectroscopic terms for the d 2 configuration and arrange the states in the
increasing order of energy.

Q4. Find the ground states for the following electronic configurations.
(i) d 1 (ii) d 2 (iii) d 3 (iv) d 4 (v) d 5
(vi) d 6 (vii) d 7 (viii) d 8 (ix) d 9 (x) d 10

Q5. (a) What are the terms arising from the electronic configuration 2 p 3 p in an L - S
coupled atom? Sketch the level structure, roughly show the splitting and label the effect
causing the splitting.
(b) What are the electric-dipole transition selection rules for these terms?
(c) To which of your forbidden term could electric dipole transition from a 3 p1 term be

made?

Q6. Apply the L  S coupling scheme to obtain all the states associated with the electron
configuration 1s 2 2s 2 2 p5 3 p .

Q7. The ground configuration of scandium (Sc) is 1s 2 2s 2 2 p 6 3s 2 3 p 6 3d 4s 2 . To what term


does this configuration give rise?

Q8. Apply the j  j coupling scheme to obtain all the states associated with the electronic
configuration 2 p 3 p and also draw the energy level diagram also.

H.No. 40-D, Ground Floor, Jia Sarai, Near IIT, Hauz Khas, New Delhi-110016
Phone: 011-26865455/+91-9871145498
Website: www.physicsbyfiziks.com | Email: fiziks.physics@gmail.com
Revised Edition 2019 1
fiziks
Institute for NET/JRF, GATE, IIT-JAM, M.Sc. Entrance, JEST, TIFR and GRE in Physics

Q9. For the p 2 configuration, find the possible states in the j  j coupling. Draw the energy
level diagram of the states and compare it with the states arises due to the L  S
coupling.

Q10. Couple a P - state and an S - state electron via (a) L  S coupling (b) j j coupling
and identify the resultant states with the approximate quantum numbers and also sketch
side by side the energy level diagram for the two cases.

H.No. 40-D, Ground Floor, Jia Sarai, Near IIT, Hauz Khas, New Delhi-110016
Phone: 011-26865455/+91-9871145498
Website: www.physicsbyfiziks.com | Email: fiziks.physics@gmail.com
Revised Edition 2019 2
fiziks
Institute for NET/JRF, GATE, IIT-JAM, M.Sc. Entrance, JEST, TIFR and GRE in Physics

H.No. 40-D, Ground Floor, Jia Sarai, Near IIT, Hauz Khas, New Delhi-110016
Phone: 011-26865455/+91-9871145498
Website: www.physicsbyfiziks.com | Email: fiziks.physics@gmail.com
Revised Edition 2019 3

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