Final Testament-Chemistry
Final Testament-Chemistry
Final Testament-Chemistry
QUESTION 1
(ii) The CFSE for d^5 high spin octahedral complex is 0 dq and has 5
unpaired electrons.
OR
(iv) any one- (a) Phenol is acidic because of resonance stabilization of its
conjugate base. (phenoxide ion)
(b) The product formed when Sodium phenoxide is treated with CO2 at
400K under high pressure is salicylic acid and is known as kolbe’s
schmitt’s reaction.
(c) Mixture of conc HCl and anhydrous ZnCl is called Lucas reagent
which shows maximum reactivity with 3 degree alcohols.
b) MCQ
Ans) Mn
Ans) Calculate the ions of all and match with compound in ques.
degree is 8.21. How much glucose should be used per liter for an
2) Electrochemistry
i) Direct numerical on w=zit W=(atomic weight/valency*96500)*it. (answer in
seconds or unit acc to ques)
ii) Numerical- Cell numerical (Cu and Ag) (answer in volt) In the formula of emf of
cell, log [A]/[B]^2 because of the concentration
4) Chemical Kinetics
iii) Reactions-
5) Coordinate Chemistry
ii) Chemical Test- Ques) AgCl and AgBr reacts with AgNO3
Answer- X is any tertiary (gives SN1) alkyl halide and Y is primary alcohol (gives
SN2). → (Halo and halo)
i) Reason- Alcohols and ethers are isomers but have diff boiling point. Because
alcohols form intermolecular hydrogen bond with water. While ethers cannot
form intermolecular bonds. (diagram)
ii) Reason- Ethanol gives iodoform test while Methanol does not. Ethanol has
alpha Hydrogen and ethanol does not have. Iodoform test is given by compounds
having methyl carbonyl group which ethanol has and methanol does not have.
v) Chlorobenzene to Phenol
vi) Riemer-tiemann
a) CHCL3→Salicyaldehyde
vi) Ethanol with Iodine and aq Alkali on heating gives yellow ppt which Acetic acid
does not. Acetic acid with neutral ferric chloride gives wine red color.
vii) Ethanol and DI-ethyl Ether → Ethanol gives Iodoform, other does not.
x) Clemmensen's Reduction
xi) What happens when: Ethyl Alcohol is treated with Methyl MgBr
xii)
i) Reason- Aldehydes are more reactive than ketones or ethanal is more reactive
than propanone or acetaldehyde is more reactive than acetone.
c) Rosamund's reduction.
Biomolecules