-

CHAMP-2024
CHEMISTRY REVISION DPP
TARGET : JEE (Main) 2024
NO. 05
Syllabus : Chemical Equilibrium

SECTION - I
Multiple Choice Questions (MCQ)
This section contains 20 multiple choice questions. Each question has 4 choices (1), (2), (3) and (4) for its
answer, out of which ONLY ONE is correct.

1. A chemical reaction is at equilibrium when

(A) Reactants are completely transformed into products
(B) The rates of forward and backward reactions are equal
(C) Formation of products is minimised
(D) Equal amounts of reactants and products are present
2. Molar concentration of 96 g of O2 contained in a 2 litre vessel is :
(A) 16 mol/litre (B) 1.5 mol/litre (C) 4 mol/litre (D) 24 mol/litre
3. Rate of reaction curve for equilibrium can be like : [rf = forward rate , rb = backward rate]

(A) (B) (C) (D) All of these

4. The equilibrium concentration of X, Y and YX2 are 4, 2 and 2 moles respectively for the
equilibrium 2X(g) + Y(g) YX2(g). The value of KC is -

(A) 0.625 (B) 0.0625 (C) 6.25 (D) 0.00625

5. The reaction A(g) + B(g) C(g) + D(g) is studied in a one litre vessel at 250°C. The initial
concentration of A was 3n and that of B was n. When equilibrium was attained, equilibrium
concentration of C was found to the equal to the equilibrium concentration of B. What is the
concentration of D at equilibrium?
(A) n/2 (B) (3n – 1/2) (C) (n – n/3) (D) n
6. The figure show the change in concentration of species A and B as a fuctional of time . The
equilibrium constant KC for the reaction A(g) 2B (g) is :

(A) Kc > 1 (B) K < 1 (C) K = 1 (D) data insufficient

PAGE # 1
7. N2 and H2 are taken in 1 : 3 molar ratio in a closed vessel to attained the following equilibrium
P
N2(g) + 3H2(g) 2NH3(g) . Find Kp for reaction at total pressure of 2P if at equilibrium is 3
1 4 4P 2
(A) (B) (C) (D) None
3P2 3P2 3

8. The value of Kp for the reaction, 2H2O(g) + 2Cl2(g) 4HCl(g) + O2(g) is 0.03 atm at 427º C,
when the partial pressure are expressed in atmosphere then the value of KC for the same
reaction is :
(A) 5.23 × 10–4 (B) 7.34 × 10–4 (C) 3.2 × 10–3 (D) 5.43 × 10–5
9. The reaction quotient Q for

N2(g) + 3H2(g) 2NH3(g)

[NH3 ]2
is given by Q = . The reaction will proceed in backward direction, when
[N2 ][H2 ]3

(A) Q = KC (B) Q < KC (C) Q > KC (D) A = 0

10. At a certain temperature, the following reactions have the equilibrium constant as shown
below :

S(s) + O2 (g) SO2 (g); Kc1 = 5 × 1052

2S(s) + 3O2 (g) 2SO3(g); Kc2=1029  

 What is the equilibrium constant Kc for the reaction at the same temperature ?

2SO2(g) + O2 (g) 2SO3(g)

(A) 2.5 × 1076 (B) 4 × 1023 (C) 4 × 10–77 (D) None of these
11. For the reaction, 2NO2(g) 2NO(g) + O2(g), KC = 1.8 × 10–6 at 185ºC. At 185ºC, the
value of KC for the reaction -
1
NO(g) + 2 O2(g) NO2(g) is -
(A) 0.9 × 106 (B) 7.5 × 102 (C) 1.95 × 10–3 (D) 1.95 × 103
12. XeF6 + H2O XeOF4 + 2HF ; Keq = K1
XeO4 + XeF6 XeOF4 + XeO3F2 ; Keq= K2
Then equilibrium constant for the reaction XeO4 + 2HF XeO3F2 + H2O will be :
K1 K2 K1
(A) (B) K1 + K2 (C) (D)
K2 K1 (K 2 )2

D
13. In the dissociation of N2O4 into NO2, (1 + ) values with the vapour densities ratio   is as
d
given by :
[-degree of dissociation, D-vapour density before dissociation, d-vapour density after
dissociation]

(A) (B) (C) (D)

PAGE # 2
14. In the above question,  varies with according to :

(A) (B) (C) (D)

15. Which of the following is not a general characteristic of equilbria involving physical process.
(1) Equilibrium is possible only in a closed system at a given temperature.
(2) All measurable properties of the system remain constant.
(3) All the physical processes stop at equilibrim
(4) The opposing process occcur at the same rate and there is dynamic but stable condition
16. When hydrochloric acid is added to cobalt nitrate solution at room temperature, the following reaction
takes place and the reaction mixture becomes blue, On cooling the mixture it becomes pink. On the
basis of the information mark the correct answer.
[Co(H2O6)]3+(aq)+4CI–(aq) [CoCl4]2–(aq) +6H2O(I)
Pink Blue
(A) H > for the reaction
(B) H < for the reaction
(C) H = for the reaction
(D) The sign of H cannot be predicted on the basis of this information.
17. In which of the following reactions, the equilibrium remains unaffected on addition of small amount of
argon at constant volume.
(A) H2 + l2 2Hl(g)
(B) PCI5 (g) PCI3 (g) + Cl2(g)
(C) N2 + 3H2 2NH3(g)
(D) The equilibrium will be remain unaffected in all the three cases.
18. For the reaction CO(g) + H2O(g) CO2(g) + H2(g) at a given temperature, the equilibrium amount of
CO2(g) can be incresed by
(A) Adding a suitable catalyst (B) Adding an inert gas
(C) Decreasing the volume of the container (D) Increasing the amount CO(g)
19. 5 moles of SO2 and 5 moles of O2 are allowed to react. At equilibrium, it was found that 60% of SO2 is
used up. If the partial presure of the equilibrium mixture is one atmosphere, the partical pressure of O 2
is
(A) 0.52 atm (B) 0.21 atm (C) 0.41 atm (D) 0.82 atm
20. For the reaction
CH4(g) + 2O2(g) CO2(g) + 2H2O(I),
H =–170.8kJ mol–1
Which of the following statements is not true
(A) Addition of CH4(g) on O2(g) at equilibrium will cause a shift to the right
(B) The reaction is exothermic
(C) At equilibrium, the concentration of CO2(g) and H2O(I) are not equal
[CO2 ]
(D) The equilibrium constant for the reaction is given by =
[CH4 ][O2 ]

PAGE # 3
 SECTION-II
(NUMERICAL VALUE TYPE QUESTIONS)
This section contains Fifteen (5) questions. The answer to each question is NUMERICAL VALUE with twodigit
integer and decimal upto one digit.

21. A(s) + B(l) C(g) Kp = 3 atm

A(s) A(g) Kp = 2 atm
How many minimum moles of A(s) should be taken in a 25 litre vessel at 300K along with excess B()

so that both reactions reach equilibrium ?

184
22. For N2O4 (g) 2 NO2(g). The observed molar mass is gms . Then the percentage
3
dissociation would be :
23 Consider the reaction AB2(g) ABg + B(g). It the initial pressure of AB2 is 100 torr and equilibrium
pressure is 120 torr. The equilibrium constant Kp in terms of torr is.
24. Calculate the change in pressure (in atm) when 2 mole of NO and 16 gram O 2 in a 6.25 litre originally at
27°C react to produce the maximum quantity of NO2 possible according to the equation –
2NO(g) + O2(g)  2NO2(g)
1
(Take R = ltr. Atm/mol-K)
12
25. An equimolar mixture of PCl3 and Cl2 is taken. Then find the equilibrium pressure, if 75% of PCl3 is
converted into PCl5 ?
PCl5(g) PCl3(g) + Cl2(g) Kp = 5 atm

ANSWER KEY_DPP_5

1. (B) 2. (B) 3. (D) 4. (B) 5. (A) 6. (A) 7. (B)

8. (A) 9. (C) 10. (C) 11. (B) 12. (C) 13. (A) 14. (B)
15. (C) 16. (A) 17. (D) 18. (D) 19. (C) 20. (D) 21. 5
22. 50 23. 5 24. 2 25. 75

PAGE # 4