Chemical Equilibrium DTS-1

Date Planned : __ / __ / __ Daily Tutorial Sheet-1 Expected Duration : 90 Min
Actual Date of Attempt : __ / __ / __ Level-1 Exact Duration :_________
1. A vessel at 1000 K contains CO2 with a pressure of 0.5 atm. Some of the CO2 is converted into CO on the
addition of graphite. If the total pressure at equilibrium is 0.8 atm, the value of Kp is:
(A) 1.8 atm (B) 3 atm (C) 0.3 atm (D) 0.18 atm
2. Four moles of PCl5 are heated in a closed 4 dm3 container to reach equilibrium at 400 K. At equilibrium
50% of PCl5 is dissociated. What is the value of Kc for the dissociation of PCl5 into PCl3 and Cl2 at 400 K ?
(A) 0.50 (B) 1.00 (C) 1.15 (D) 0.05
3. Consider the following gaseous equilibria with equilibrium constant K1 and K2 respectively.
1
 
SO2 g 
2
 
O2 g ↽ ⇀ SO3 g ;    
2SO3 g ↽ ⇀ 2SO2 g  O2 g    
The equilibrium constant are related as :
1 1 2
(A) 2K1  K 2
2 (B) K12  (C) K2
2 (D) K2 
K2 K1 K12
4. 
NH4 HS s ↽ ⇀ NH3 g  H2S g    
In the above reaction, if the pressure at equilibrium and at 300 K is 100 atm then what will be the
equilibrium constant Kp?
(A) 2500 atm2 (B) 50 atm2 (C) 100 atm2 (D) 200 atm2
5. 3 moles of A and 4 moles of B are mixed together and allowed to come into equilibrium according to the
following reaction.
   
3A g  4B g ↽ ⇀ 2C g  3D g    
When equilibrium is reached, there is 1 mole of C. The equilibrium constant of the reaction is :
4 3 4
1 1 1
(A)   (B)   (C)   (D) 1
4 3 2
     
6. Which of the following is a wrong statement about equilibrium state ?

(A) Rate of forward reaction = Rate of backward reaction
(B) Equilibrium is dynamic
(C) Catalysts increase value of equilibrium constant
(D) Free energy change is zero
7. A B↽ ⇀CD
Initially moles of A and B are equal. At equilibrium, moles of C are three times of A. The equilibrium
constant of the reaction will be :
(A) 1 (B) 2 (C) 4 (D) 9
8. Which of the following is not a physical equilibrium ?
(A) Ice ↽ ⇀ Water (B) I2 (s) ↽ ⇀ I2 (g)
(C) S(ℓ ) ↽ ⇀ S(g) (D) 3O2 (g) ↽ ⇀ 2O3 (g)
VMC | Chemical Equilibrium 78 DTS-1 | Level-1

9. 2HI(g) ↽ ⇀ H2 (g)  I2 (g)
The equilibrium constant of the above reaction is 6.4 at 300 K. If 0.25 mole each of H2 and I2 are added to
the system, the equilibrium constant will be :
(A) 6.4 (B) 0.8 (C) 3.2 (D) 1.6
10. For a reaction at equilibrium which of the following is correct ?

(A) Concentration of reactant = concentration of product
(B) Concentration of reactant is always greater than product
(C) Rate of forward reaction = rate of backward reaction
(D) Qc = k
11. For the following three reactions I, II, and III, equilibrium constants are given
I.      
CO g  H2O g ↽ ⇀ CO2 g  H2 g ; K1  
II.      
CH4 g  H2O g ↽ ⇀ CO g  3H2 g ; K 2  
III.      
CH4 g  2H2O g ↽ ⇀ CO2 g  4H2 g ; K 3  
Which of the following relations is correct ?
(A) K1 K 2  K 3 (B) K 2K 3  K1 (C) K 3  K1K 2 (D) K 3K 3 2
2  K1
1
12. For the following reaction in gaseous phase CO(g)  O2 (g) ↽ ⇀ CO2 (g) K p / K c is :
2
(A) (RT)1/2 (B) (RT )1/2 (C) (RT) (D) (RT )1
13. Three moles of PCl5, three moles of PCl3 and two moles of Cl2 are taken in a closed vessel. If at
equilibrium the vessel has 1.5 moles of PCl5, the number of moles of PCl3 present in it is :
(A) 5 (B) 3 (C) 6 (D) 4.5
14. 1 mole of H2 and 2 moles of I2 are taken initially in a 0.2 L container. Then, the number of moles of H2 at
equilibrium is 0.2. Then, the number of moles of I2 and HI at equilibrium are :
(A) 1.2, 1.6 (B) 1.8, 1.0 (C) 0.4, 2.4 (D) 0.8, 2.0
15. On doubling P and V at constant temperature, the equilibrium constant will :

(A) Remain constant (B) Become double
(C) Become one-fourth (D) None of these
VMC | Chemical Equilibrium 79 DTS-1 | Level-1

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Date Planned : / / __ Daily Tutorial Sheet-1 Expected Duration : 90 Min

Actual Date of Attempt : / / Level-1 Exact Duration :_______

6. Which of the following is a wrong statement about equilibrium state ?

8. Which of the following is not a physical equilibrium ?

(A) Ice ↽ ⇀ Water (B) I2 (s) ↽ ⇀ I2 (g)

(C) S(ℓ ) ↽ ⇀ S(g) (D) 3O2 (g) ↽ ⇀ 2O3 (g)

VMC | Chemical Equilibrium 78 DTS-1 | Level-1

10. For a reaction at equilibrium which of the following is correct ?

15. On doubling P and V at constant temperature, the equilibrium constant will :

VMC | Chemical Equilibrium 79 DTS-1 | Level-1

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