Section-I: IIT - JEE 2014 TW Test MARKS: 65 Time: 1Hr Topics:Chemical Equilibrium
Section-I: IIT - JEE 2014 TW Test MARKS: 65 Time: 1Hr Topics:Chemical Equilibrium
Section-I: IIT - JEE 2014 TW Test MARKS: 65 Time: 1Hr Topics:Chemical Equilibrium
TIME: 1HR
TW TEST
TOPICS:CHEMICAL EQUILIBRIUM
MARKS: 65
SECTION-I
This section contains 10multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D) for its answer, out which ONLY ONE is correct.
(+3, - 1)
1.
The graph below shows the variation of concentration with time for the reaction
3A(aq) B(aq) + 2C(aq) at 25oC.
C
A
B
(d) 0.222
2.
Consider the reaction: 2CO(g) + O2(g) 2CO2(g). If the equilibrium concentrations of CO(g) is 1.6
10-2 m/L, O2 is 9.0 10-2 m/L and CO2 is 6.4 10-2 m/L, what was the initial O2 concentration
before the reaction started to form any CO2(g)?
(a) 1.2 M
(b) 12 M
(c) 0.12 M
(d) 0.012 M
3.
Calculate the equilibrium concentration of H2 in a 1.0 L container initially containing 0.118 mole of
HBr at 1400 K. Kc = 1.5 10-5 at 1400 K for the reaction
2HBr(g) H2(g) + Br2(g)
(a) 1.8 10-6 M
(b) 0.118 M
(c) 1.5 10-5 M
(d) 4.5 10-4 M
4.
5.
10
Conc. (M)
8
6
Z
Y
Time (Minutes)
6.
1 mol of N 2 is mixed with 3 mol of H 2 in a litre container. If 50% of N 2 is converted into ammonia
by thereaction N 2 g 3H 2 g 2NH3 g , then the number of moles of gas at the equilibrium are
(a) 1.5
(b) 4.5
(c) 3.0
(d) 6.0
7.
8.
9.
(b) 12 103 M
(c) 12 102 M
(d) 12 101 M
8 mol of gas AB3 are introduced into a 1.0dm3 vessel. It dissociates as 2AB3 g A 2 g 3B2 g
At equilibrium , 2 mol of A 2 is found to be present. The equilibrium constant for the reaction is
(a) 2mol 2 L2
10.
(b) 3mol2 L2
(c) 27mol 2 L2
(d) 36mol 2 L2
FeO s CO g Fe s CO2 g
If the value of K c 5.0 ?
(a) 0.125M
(b) 0.0125M
(c) 1.25M
(d) 12.5M
SECTION-II
This section contains 7 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D) for its answer, out which ONE OR MORE is/are correct.
(+3, 0)
11.
K1
2NO;
K2
NO
K3
2NO
N2 + O2,
1
1
K4
NO
N 2 O2
2
2
Correct relation between K1, K2, K3 and K4 is
(a) K1 K3 = 1
(b)
K1 K 4 1
(c)
K3 K 2 1
Dd
is correctly matched for : ( is the degree of dissociation, D and d are the
(n 1)d
vapour densities before and after dissociation)
n
n
n
2n
(a) A B C
(b) A B C
2
3
3
3
n
n
n
(c) A B C
(d) A B C
2
4
2
12.
The equation
13.
14.
For the reaction H2 g I2 g 2HI g , the equilibrium can be shifted in favour of product by
15.
16.
17.
For which of the following reactions at equilibrium at constant temperature, doubling the volume
will cause a shift to the right?
(a) N 2O4 g 2NO2 g
(d) N 2 g O2 g 2NO g
SECTION-III
(Paragraph Type)
This section contains 2 groups of questions. Each question has 4 choices (A), (B), (C) and (D)
for its answer, out of which ONLY ONE is correct.
(+3, -1)
N 2 g 3H 2 g 2NH3 g ; H 22.4kJ
The pressure inside the chamber is 100 atm and temperature at 300K.
18.
If K p for the given reaction is 1.44 105 , then the value of Kc will be:
(a)
1.44 105
0.082 500
mol L1
(b)
1.44 105
8.314 200
mol L1
(c)
19.
1.44 10
mol L1
2
0.082 700 s
The preparation of ammonia by Habers process is an exothermic reaction. If the preparation follows
the following temperature-pressure relationship for its % yield. Then for temperature T1 ,T2 , and T3
the correct option is:
(a) T3 T2 T1
(b) T1 T2 T3
SECTION-IV
(c) T3 T2 T1 (d) T1 T2 T3
This section contains 2 questions. The answer to each of the questions is a single digit integer,
ranging from 0 to 9. The correct digit below the question number in the ORS is be bubbled.
(+4, 0)
20.
For the reaction A B C , the rate constants for the forward and the reverse reactions are 4 102
and 2 102 respectively. The value of equilibrium constant K for the reaction would be
21.
One mole of ethanol is treated with one mole of ethanoic acid at 25o C . Half of the acid changes into
ester at equilibrium. The equilibrium constant for the reaction will be.
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
a, b, c
12.
13.
a, c
14.
a, c
15.
16.
a, b
17.
a, b, d
18.
19.
20.
2.
21.