CH3 Test ?

on lesson One• Chapter 3

First Choose the correct answer for questions 1: 10

1. Each of the following represents a physical equilibrium, except….

a. C6H12O6(s) ⇌C6H12O6(aq)

b. N2O4(g) ⇌2NO2(g)

c. Fe(OH)3(s) ⇌Fe3+(aq) +3OH-(aq)

d. Al2O3(s) ⇌2Al3+(l)+3O2-(l)

2. The opposite graphical figure represents a chemical reaction.

What is the type of this reaction, and what is the equation which represents it ?

Choices Type of reaction Reaction equation

3A + C ⇌2B
a. Complete reaction A+B →2C
b. Reversible reaction
c. Complete reaction 3A + B⇌2C
d. Reversible reaction 2C⇌3A + B

⇌2NH3(g)
3. The reaction represented by the following equation took place in a closed vessel: N 2(g)+3H2(g)

Which of the following statements represents this reaction when it is at equilibrium?

a. The amounts of ammonia, nitrogen and hydrogen are equal.

b. The rate of formation of ammonia gas equals the rate of dissociation of ammonia gas.

c. The rate of formation of ammonia gas is higher than the rate of dissociation of ammonia gas

d. Both the formation and the decomposition of ammonia gas stop.

4. The following equation represents a method for preparing nitric oxide in industry:

4NH3(g)+5O2(g)→4NO(g)+6H2O(v)

If the rate of formation of water vapour is 0.025 mol/L.min, so the rate of consumption of ammonia
gas equals …..

a. 0.004 mol/L.min

b. 0.017 mol/L.min

c. 0.038 mol/L.min

d. 0.15 mol/L.min

5. The following figures demonstrate 4 different processes:

(1) Rock decay

(2) Fuel explosion

(3) Apple rotting

(4) Baby growth

What is the descending order of the rates of these processes ?

a. (3)> (4)> (1)> (2).

b. (2)> (3) > (4)> (1).

c. (1)> (4)> (3) > (2).

d. (2)> (4)> (3) > (1).

6. In the reaction: Zn+2HCl→ ZnCl2 + H2

When the mass of zinc and the volume of the acid are constant, the rate of the reaction of zinc (1)
with hydrochloric acid which is (2) becomes the highest. What does each of (1) and (2) represent ?

Choices (1) (2)

a. Powder Dilute at 50°C
b. Powder Concentrated at 75°C
c. Piece Concentrated at 50°C
d. Piece Concentrated at 75°C
Choices When the temperature is raised When the reactants concentrations are increased
a. Increases Increases
b. Increases Does not change
c. Does not change Increases
d. Does not change Does not change
7. Which of the following shows the change occurring in the kinetic energy of the colliding molecules
when the reactants concentrations are increased and when the temperature is raised ?

8. Which of the following graphical figures represents the relation between the activation energy E,
and the rate of the chemical reaction ?

9. The opposite graphical figure represents the volume of the evolved oxygen gas over time upon
adding manganese dioxide to hydrogen peroxide. Which of the following is correct?

a. Manganese dioxide is consumed.

b. Manganese dioxide surface area increases.

c. O₂ gas evolution rate increases at the end of the experiment.

d. Hydrogen peroxide is consumed.

9. To preserve the solution of the substance (X), this requires using opaque glassware. Which of the
following represents both the chemical formula of (X) and the reason for preserving it in opaque
glassware?

Choices Substance (X) Reason

a. AgBr As falling of light on the solution results in oxidizing silver ions.
b. AgNO3 As falling of light on the solution results in reducing silver ions.
c. CuSO4 As falling of light on the solution results in reducing copper ions.
d. NaOH To prevent the reaction of the solution with the glass.

Second Answer the following essay questions 11, 12:

11. Regarding the given chart:

(1) Does this chart represent a complete or a reversible reaction ?

Explain.

(2) Write the balanced hypothetical equation which represents the

12. A student performed 4 experiments to measure the time taken in

the reaction of hydrochloric acid with an antacid dispersible tablets at different conditions, the results
were recorded in the table below: [Ca=40, C=12.O=16]

Number of Volume Concentration Reaction Reaction

experiment of HCI of HCI temperature time
(1) 50 mL 1M 25°C 132 s
(2) 50 mL 2M 25°C 65 s
(3) 100 mL 2M 25°C 65 s
(4) 50 mL 2M 35°C 33 s
Assisted by the results presented in the table, state the numbers of the two experiments which prove
that:

(1) The used volume of the acid does not affect the rate of the reaction.

(2) The acid concentration and the temperature together affect the rate of the reaction.
Test2 on lesson Two Chapter 3

First Choose the correct answer for questions 1:10

In the reversible reaction: N2O4(g) (Colourless) ⇌2NO2(g) (Reddish brown)ΔΗ = (+)ve

On adding more N₂O, gas, the mixture colour becomes…..

a. darker, due to the increase in the forward reaction rate.

b. lighter, due to the decrease in the forward reaction rate.

c. darker, due to the increase in the backward reaction rate.

d. lighter, due to the decrease in the backward reaction rate.

2. The equation below represents the dynamic equilibrium state between lead (II) sulphate salt which
is sparingly soluble in water and its saturated solution:

PbSO4(s) ⇌ Pb2+ (aq) + SO42- (aq)

Adding K₂SO₄ salt to this solution (at a constant temperature)................

a. increases [Pb2+] and increases the mass of PbSO4

b. increases [Pb2+] and does not affect the mass of PbSO4

c. decreases [Pb2+] and decreases the mass of PbSO4

d. decreases [Pb2+] and increases the mass of PbSO4

3. Which of the following reactions its equilibrium constant is represented as shown?

Kc= [NH3]4 [O2]7 ÷ [NO2]4 [H2O]6

a. 4NO2(g) + 6H2O (v) ⇌ 4NH3(g) +7O2(g)

b. 4NO2(aq) + 6H2O(l) ⇌ 4NH3(aq) +7O2(g)

c. 4NH3(g) +7O2(g)⇌ 4NO2(aq) + 6H2O(1)

d. 4NH3(g)+7O2(g) ⇌4NO2(g) + 6H2O (v)

4. The equilibrium constant of this reaction: SnO2(s) + 2CO(g) ⇌ Sn(s) + 2CO2(g) is ….

a. Kc=[CO₂]÷ [CO]

b. Kc=[CO₂]²÷ [CO]²

c. K= [Sn][CO2]² ÷[SnO2][CO]²

d. K = [Sn] [CO2]² ÷[CO]²

5. Which of the following choices indicates the most stable nitrogen oxide?

a. 2NO2(g) ⇌N2(g) +2O2(g) Kc = 6.7 x 1018

b. 2NO(g) ⇌ N2(g) + O2(g) Kc = 2.2 x 1030

c. 2N2O5(g) ⇌2N2(g) +5O2(g) Kc = 1.2 x 1024

d. 2N2O(g) ⇌2N2(g) + O2(g) Kc = 3.5 x 1033

6. At the equilibrium point of the reaction:

N2(g) + 3H2(g) ⇌2NH3(g)

The volume of the gaseous mixture is 1 L containing 0.3 mol of nitrogen gas, 0.2 mol of hydrogen gas
and 0.6 mol of ammonia gas. What is the equilibrium constant of this reaction?

a. 0.03

b. 1.5

c. 10

d. 150

7. The following equation represents a reversible chemical reaction:

2SO2(g) + O2(g) ⇌2SO3(g)

What is the effect of increasing the external pressure on this reaction when it is at equilibrium?

Choices Amount of SO3 Amount of SO2 Equilibrium constant

a. Increases Decreases Does not change
b. Decreases Increases Increases
c. Increases Decreases Increases

8. In the equilibrium reaction: 2XY3(g) ⇌ X2(g)+3Y2(g) Kp = 3

d. Decreases Increases Does not change

What is the probable value of the partial pressure of each component in this reaction mixture at
equilibrium ?

Choices Px2 (atm) Py2 (atm) Pxy3 (atm)

a. 1.5 1 1
b. 6 2 4
c. 1 2 6

9. In the reversible reaction: 4NH3(g), +5O2(g) ⇌4ΝΟ(g) + 6H2O(l) ΔΗ = (+)

d. 3 2 3

The following factors change [NH3], except ….

a. increasing the external pressure.

b. increasing the volume of the reaction vessel.

c. adding a catalyst.

d. decreasing the temperature.

10. The reversible reaction: W+X⇌Y+Z is represented by the
opposite graphical figure. What is the activation energy of the
catalytic backward reaction?

a. -40 kJ

b. -10 kJ

c. +30 kJ

d. +40 kJ

Second Answer the following essay questions 11, 12:

11. The shown chart represents the change in the concentrations of the contents
of a mixture of NO2(g) and N2O4(g) until the occurring reaction reaches equilibrium.

(1) Deduce the equation of the chemical reaction represented by the chart.

(2) Do you expect K of this reaction to be greater or less than 1 ? Explain.

12. The given table exhibits the results of two experiments on the reaction:

2A(g) ⇌B(g) + C(g) ∆H =+9.6 kJ

(1) Are the two experiments 1 and 2 performed at the same temperature ? Explain.

(2) What can be concluded from the results in the table ?

Experiment Concentration at equilibrium

A B C
1 0.934 M 0.033 M 0.033 M
2 0.773 M 0.114 M 0.114 M
Test ? on lesson Three Chapter 3

First Choose the correct answer for questions 1: 10

1. The solution produced from dissolving HCl gas in water is a good electric conductor. What is the
scientific explanation for this ? Due to

a. the dissolution of HCl in water without ionization.

b. the dissolution of HCl in water forming ions.

c. the reaction of the impurities found in water with HCl forming ions.

d. the dissociation of HCl in water as it is an ionic compound.

2. The opposite table shows some Ka values of different substances. What is the correct graduation of
the strength of the acidic character of these substances ?

Substance Ka (at 25°C)

C6H5COOH 6.5 x 10-5
C6H5OH 1.3 x 10-10
H₂O 1 x 10-14
H₂CO₃ 4.3 x 10-7
a. H₂O > H₂CO₃ > C6H5COOH > C6H5OH

b. H₂CO₃ > H₂O> C6H5OH > C6H5COOH

c. C6H5COOH > C6H5OH>H2CO3 > H2O

d. C6H5COOH >H2CO3 > C6H5OH > H₂O

3. What is the concentration of H3O+ ions in 0.075 M H2CO3 solution, whose ionization constant K
equals 4.3 x 10-7 (at 25°C) ?

a. 6.1 x 10-4 M

b. 1.8 × 10-4M

c. 6 x 10-5 M

d. 4.8 x 10-8 M

4. What is the relation between the strength of a weak base and the value of its Kb as well as H + ions
concentration in its aqueous solution relative to OH- ions concentration?

Choices Strength of the weak base [H+]

a. Increases by increasing Kb value Higher
b. Increases by increasing Kb value Higher
c. decreases by increasing Kb value Lower
d. decreases by increasing Kb value Lower
5. Which of the following represents the ionic equilibrium arising after adding a base to distilled water
(at 25°C) ?

a. pH < pOH and K w = 1 x 10-14

b. pH > pOH and K = 1 x 10-14

c. pH < pOH and K <1 × 10-14

d. pH > pOH and K > 1 × 10-14

6. What is the pH value of a mixture formed from 200 mL of HCl acid whose pH is 2 with 300 mL of
NaOH solution whose pH is 12?

a. 9.3

b. 10.3

c. 11.3

d. 11.8

7. pOH of 0.05 M KOH solution equals

a. 1

b. 1.3

c. 12.7

d. 13

8. The opposite figure shows two pH values of two types of soils (X) and (Y). Which of these soils
should be treated with quicklime ? X:pH=7 , (Y):pH=5.5

a. Soil (X), as quicklime is acidic.

b. Soil (X), as quicklime is basic.

c. Soil (Y), as quicklime is acidic.

d. Soil (Y), as quicklime is basic.

9. [OH-] in 0.025 M HCI acid equals

a. 2.5 x 10-16 M

b. 4 x 10-13 M

c. 2.5 x 10-2 M

d. 2.5 x 1012 M
10. Which of the following graphical figures represents the correct relation between Ka and Kb, values
of an aqueous solution (at 25°C) ?

Second Answer the following essay questions 11, 12:

11. Compare between strong acids and weak acids in terms of :

(1) lionization in water.

(2) Ka value.

12. Calculate Kb of 5 × 10-3 M weak basic solution, its pOH equals 4.05

Nagwa

6mol of N₂ gas and 20mol of were allowed to react at 650 K and 50 atm of pressure. At equilibrium,

3H₂(g)⇌2NH3(g) Kp=……..
4mol of N₂ gas had been converted into ammonia according to the following equation: N₂ (g)+

N₂(g) H₂(g) NH3(g)

Initial moles 6 20 0
Changed moles -4 -12 +8
Equilibrium moles 2 8 8
X(mole fraction) 0.111 0.444 0.444
Partial pressure 0.111*50 atm=5.55 atm 0.444*50 atm=2.22 atm 0.444*50 atm=2.22 atm
Kp: equilibrium constant for partial pressures

Kp=(pNH3)2 / p(N2)*(pH2)3 =2.222/5.55*2.223=8.12*10-3

=========
Test? on lesson Four• Chapter 3

First Choose the correct answer for the questions 1: 10

1. What is the salt solution which acquires a yellow colour upon addition of bromothymol blue to it ?

a. Sodium acetate solution.

b. Sodium sulphate solution.

c. Ammonium acetate solution.

d. Ammonium sulphate solution.

2. Which of the following solutions, equally concentration, whose pH is above 8?

a. 0.01 M HCI

b. 0.1 M NH4CI

c. 0.1 M HNO3

d. 0.1 M CH3COONa

3. The opposite figure represents the titration of ….

a. a strong acid with a strong base.

b. a strong acid with a weak base.

c. a strong base with a strong acid.

d. a weak base with a strong acid.

4. What is the type of the solution produced from mixing 0.1 mol of NaOH with 0.1 mol of acetic acid,
when they both have the same volume ?

a. An acidic solution.

b. A basic solution.

c. A neutral solution.

d. A solution that does not contain free OH ions.

5. The hydrolysis of the salt produced through the titration of NH 4OH solution with HCI acid results in
a solution whose approximate pH is

a. 1.2

b. 5.5
d. 8.5

c. 9.5

6. The colour of litmus indicator does not change when it is added to….

a. K2CO3 solution.

b. FeCl3 solution.

c. KNO3 solution.

d. NH4Cl solution.

7. The opposite table shows

the solubility of different types of salts in water at a certain temperature. Which of these salts is the
least soluble in water at 60°C?

Salt Solubility in water at 60°C

W 10g/50 g of water
X 20 g/60 g of water
Y 30 g/120 g of water
Z 40g/80 g of water
a. Salt (W).

b. Salt (X).

c. Salt (Y).

d. Salt (Z).

8. What is the solubility product of silver phosphate Ag3PO4 salt?

a. Ksp = [Ag+] [PO43-]

b. Ksp = [Ag+] [PO43-]³

c. Ksp = [Ag+]³ [PO43-]

d. Ksp = 3[Ag+] [PO43-]

9. If the solubility product of AgCl equals 1.8 × 10-10, then a precipitate of it is formed by adding equal
volumes of ….

a. 10-4 M Ag+, 10-4 M Сl-

b. 10-5 M Ag+, 10-5 M Сl-

c. 10-6M Ag+, 10-6 M Сl-

d. 10-10 M Ag+, 10-10 М Сl-

10. If the solubility product of Mg3(PO4)2 salt is 1.08 × 10-13 , then [Mg2+] in a saturated solution of it
equals…..
a. 3 x 10-2 M

b. 3 x 10-3 M

d. 3 x 10-4 M

d. 3 x 10-6 M

Second Answer the following essay questions 11, 12:

11. Discuss, with explanation, the effect of each of the following on pH of the solution :

(1) Adding NH4Cl to ammonia solution.

(2) Adding NaCl to hydrochloric acid.

12. Calculate Ksp of calcium fluoride CaF2 solution, knowing that its solubility degree equals 2 x 10-4 M
Examination model? on Chapter3

First Choose the correct answer for the questions 1: 27

1. The opposite chart represents the concentrations of three gases in a

reversible reaction reaches equilibrium. Which reaction is represented by
this chart ?

a. 2SO2(g) +O2(g) ⇌2SO3(g)

b. 2HBr(g) ⇌H2(g) + Br2(v)

c.2SO3(g) ⇌2SO2(g) + O2(g)

d. H2(g) + Br2(v) ⇌2HBr(g)

2. All the following equations represent chemical equilibrium processes, except ……..

a. 2I-(aq) ⇌I2(s)

b. 3O2(g) ⇌2O3(g)

c. I 2(s)⇌I2 (v)

d. Ag+(aq) + Cl-(aq)⇌AgCl(s)

3 The opposite graph represents the concentration of reactant (A) over

time in the hypothetical reaction: A→B What is the rate of this
reaction at (0 to 10) s time span ?

a. -0.07 M/s

b. -0.007 M/s

c. -0.86 M/s

d. -0.014 M/s

4. One of the students carried out three experiments to produce

carbon dioxide gas by using excess of zinc carbonate with dilute sulphuric acid
(at 30°C):

The form of Sulphuric acid

Experiment
zinc carbonate Volume Concentration
(1) Powder 20 ml 1M In
(2) Small pieces 40 ml 0.5 M
(3). Small pieces 10 m 1M terms of the previous
figure and table. Which of
the following choices represents the curve of each of the three experiments ?

Choices Experiment (1) Experiment (2) Experiment (3)

a. X Y Z
 b. Y X Z
c. Y Z X
d. Z X Y
5. The following table shows the factors affecting the rate of the reaction of nitric acid with excess of
zinc carbonate in two experiments (P) and (Q):

Experiment Temperature
(P) 35°C 2 mol/L 50 mL
(Q) 25°C 1 mol/L 150 mL
Which of the following graphical figures represents the results of these two experiments ?

6. In terms of the equation : A +B⇌ AB ΔΗ = -85 kJ/mol

If the activation energy of the forward reaction equals 120 kJ/mol

What is the value of the activation energy of the backward reaction ?

a. 35 kJ/mol

b. 85 kJ/mol

c. 120 kJ/mol

d. 205 kJ/mol

7. The following graphical figures represent the reaction: X2(g) +3Y2(g) ⇌2XY3(g)

What do the numbers (1:4) in these two figures refer to ?

Choices (1) (2) (3) (4)

a. Y2 XY3 X2 Y2
b. X2 Y2 XY3 Y2
 c. XY3 X2 Y2 XY3
d. Y2 XY3 Y2 X2
8. Methane gas combusts slowly in the atmospheric air at room temperature, but when a piece of
platinum is added to the vessel of the reaction which contains a mixture of methane and air, then
methane combusts instantaneously.

What is the role of platinum in this reaction?

a. Decreasing the activation energy of the reaction.

b. Increasing the value of AH of the reaction.

c. Releasing the stored energy in the reactants.

d. Decreasing the rate of the reaction.

9. In terms of this reversible reaction: N2(g) + 3H2(g) ⇌2NH3(g) K=16

What is the value of Kc of the reaction: NH3(g) ⇌N2(g)+

3
H2(g) at the same temperature ?
2
a. 0.25

b. 0.4

c. 0.5

d. 4

10. In the equilibrium reaction: C(s) + CO2(g) ⇌2CO(g) What is the Kp value of the reaction when the
partial pressure of CO2 gas is 2 atm and that of CO gas is 4 atm ?

a. 0.5

b. 4

b. 8

d. 32

11. At a certain temperature, the equilibrium constant of this reaction equals 49: H 2(g) + I2(v) ⇌ 2HI(g)

What is the value of the equilibrium constant of the same reaction upon doubling the concentration
of HI at the same temperature?

a. 24.5

b. 49

d. 73.5

c. 98

12. In the equilibrium reaction: X2(g) + 3Y2(g) ⇌ 2XY3(g)

What is the graphical figure which represents the relation between the rate of each of forward and
backward reactions upon adding a catalyst to this reaction?

13. In the equilibrium system: PbCO3(s) ⇌Pb2+(aq) + CO32-(aq)

What is the effect of adding Na2CO3 solution to this system ?

a. Both [Pb2+] and PbCO3,mass decrease.

b. [Pb2+] decreases and PbCO3 mass increases.

c. [Pb2+] increases and PbCO3 mass decreases.

d. Both [Pb2+] and PbCO3 mass increase.

14. The saturated solution of potassium chromate is represented by the equation:

K2CrO4(s) + Energy⇌ 2K+(aq) + CrO42-(aq) In the opposite graphical figure.

What did happen at the time t ?

a. KNO3 was added to the reaction mixture.

b. The temperature of the reaction mixture was raised.

c. K2CrO4 was removed from the reaction mixture.

d. The temperature of the reaction mixture was lowered.

15. On the reaction of two similar volumes of the acids (X) and (Y), each
individually, with 1 cm strip of magnesium, it was noticed that:

The rate of production of H₂ gas in case of acid (X) is faster than in case of acid (Y).

• The final volume of H, gas is the same in both cases.

Which of the following statements explains these observations?

a. pH of the acid (X) is higher than that of the acid (Y).

b. Acid (X) is an organic acid.

c. Acid (X) is stronger than acid (Y).

d. Acid (X) is less concentrated than acid (Y).

16. What is the pH value of 0.005 M sulphuric acid (at 25°C) ?

a. 0.005

b. 0.1

c. 1

d. 2

17. Which of the following solutions its pH is not 12?

a. 50 mL of 0.005 M KOH solution.

b. 100 mL of 0.01 M KOH solution.

c. 200 mL of 0.01 M KOH solution.

d. 400 mL of 0.005 M Ba(OH)2 solution.

18. What would be added to 25 mL of 1 M sodium hydroxide solution to bring about the biggest
change in the pH value ?

a. 25 mL of 1 M HCl acid.

b. 25 mL of 0.5 M HCl acid.

c. 25 mL of 2 M HCl acid.

d. 25 mL of distilled water.

19 What is the pH value of the solution produced from mixing 40 mL of 0.1 M HCI acid with 10 mL of
0.45 M NaOH solution ?

a. 6

b. 8

c. 10

d. 12

20. In terms of the table :

Comparing the acidity of 0.1 M HPO42- to that of 0.1 M HC₂O42- reveals that ….

HC₂O4- ⇌H++C₂O42-
Acid ionization Ka

HPO42- ⇌H++PO43-
1.8*10-5
2.2*10-13
a. HC₂O4- is a weaker acid as its pH is higher.

b. HPO42- is a stronger acid as its pH is higher.

c. HPO42- is a weaker acid as its pH is lower.

d. HC₂O4- is a stronger acid as its pH is lower.

21. What is the volume of water required to be added to 1 L of 0.05 M H₂SO₄ acid in order for its pH
value to become 2?

a. 10 L

b. 9L

c. 1L

d. 0.9 L

22. The opposite figures show three experiments

to compare the electrical conductivity of three different

solutions, the concentration of each of them is 1 M Which of the following identifies these solutions ?

Choices Experiment (1) Experiment (2) Experiment (3)

a. Table salt solution Hydrochloric acid Nitric acid
b. Sulphuric acid Acetic acid Glucose solution
c. Nitrous acid Hydrochloric acid Table salt solution
d. Nitric acid Boric acid Acetic acid
23. The opposite figure shows the pH curve of the titration of…..

a. 0.1 M HCl acid with 0.05 M ammonia solution.

b. 0.05 M ammonia solution with 0.1 M HCl acid.

c. 1 M NaOH solution with 0.1 M HCl acid.

d. 0.1 M CH3COOH acid with 0.05 M ammonia solution.

24. What is the nature of the aqueous solution of CuSO4 ?

a. Acidic.

b. Basic.

c. Neutral

d. Amphoteric

25. The opposite figure shows two pH curves of two titrations. What does
each of the curves (A) and (B) represent ?

Choices Curve (A) Curve (B)

a. Titration of a strong acid Titration of a strong acid
b. Titration of a weak acid Titration of a weak acid
c. Titration of a weak acid Titration of a strong acid
d. Titration of a strong acid Titration of a weak acid
26. Solubility product of magnesium phosphate salt is calculated from the relation

a. Ksp = [Mg2+] [PO43-]

b. Ksp = [Mg2+]³ [PO43-]3

c. Ksp = [Mg2+]3 [PO43-]2

Ksp=[Mg2+] [PO43-]÷ [Mg3(PO4)2]

27. What is the value of Ksp of Ba(OH)2 salt if the pH value of its saturated solution equals 12 ?

a. 3.3 x 10-7

b. 4 x 10-6

c. 5 x 10-7

d. 5 x 10-6

Second Answer the essay questions 28:30

28. A colourless solution whose pOH is 12 is divided into 2 portions, and when :

• Indicator (X) is added to the first portion, the solution remains colourless.

• Indicator (Y) is added to the second portion, the solution acquires a yellow colour.

(1) Calculate [H+] in the solution.

(2) Deduce the names of the indicators (X) and (Y).

29. The shown graph represents the reaction:

NO(g)+O3(g) →NO2(g) + O2(g)

(1) Write the mathematical formula of the reaction rate (r).

(2) Deduce the difference between the two temperatures T, and T

30. The molar mass of AgCl is 143.5 g/mol, and its solubility product at 25°C is 1.8 x 10-10

Calculate the maximum mass of AgCl that can be dissolved in 100 g of water at the same temperature
(the volume of pure water in mL equals its mass(in g)).

****** ******* ******* ******

Questions of the experimental tests and the exams of the previous years until 1st session 2023? on
Chapter3

First Multiple choice questions (MCQ)

1. Which of the following is a complete reaction ? (1st session 21)

a. CH3COOH(l) + H2O(l) = CH3COO(aq) + H3O+(aq)

b. HCOOH(aq) + CH3OH(aq) = HCOOCH3(aq) + H2O(l)

c. NaOH(aq) + HCl(aq) = NaCl(aq) + H2O(l)

d. NH3(g) + H2O(l) = NH4(aq) + OH-(aq)

2. (A): AgNO3(aq) + NaBr(aq) = AgBr(s) + NaNO3(aq)

(B): 2NO(g) + O2(g) = 2NO2(g) (Closed vessel)

(C): CH3COOH(l) + C2H5OH(l) = CH3COOC2H5(aq) + H2O(l)

(D): N2(g) + 3H2(g) = 2NH3(g) (Closed vessel)

Which of the previous reactions is considered a complete reaction? (Exp./ June 21)

a. (A).

b. (B).

c. (C).

d. (D).

3. All of the following are reversible reactions, except …(2nd session 21)

a. CO2(g)+H2(g)=CO(g) + H₂O(v) (Closed vessel)

b. CH3COOH(l)+C2H5OH(l) = CH3COOC2H5(aq) + H2O(l)

c. 2Na(s) + 2HCl(aq) = 2NaCl(aq) + H2(g)

d. 2NO2(g) = N2O4(g) (Closed vessel)

4. Which of the following systems is irreversible ? (2nd session 22)

a. CH3COOH(aq) + H2O(l) = CH3COO-(aq) + H₂O (aq)

b. AgCl(s) = Ag+(aq) + Cl-(aq) (Saturated solution)

c. N2O4(g) = 2NO2(g) (Closed vessel)

d. Zn(s) + 2HCl(aq) = ZnCl2(aq) + H2(g)

5. Which one of the following represents a complete reaction ? (Exp./ March 23)

a. CH3COOH(aq) + NH4OH(aq) = CH3COONH4(aq) + H2O(l)

b. HCOOH(aq) + H2O(l)=HCOO (aq) + H2O(aq)

c. AgBr(s) = Ag+(aq) + Br-(aq)

d. N2(g) + O2(g) = 2NO(g)

6. Which of the following statements describes chemical reaction at equilibrium state ? (Exp./ May 21)

a. Rate of forward reaction is always higher than that backward reaction.

b. The reaction is always static not dynamic.

c. Concentration of reactants and products are always constant.

d. Concentration of reactants and products are always equal.

7. Which one of the following choices expresses the opposite diagram ? (1st session 22)

a. 2A + B⇌2C+4D

b. A+3C⇌2B + 4D

c. 2A + B→2C+4D

d. A+3C→2B + 4D

8. Which of the following reactions expresses the

opposite graph? (Exp./ March 23)

Sodium chloride solution + silver nitrate solution.

Iron nail covered by oil.

Iron nail in water.

Pieces from magnesium + dil. hydrochloric acid.

9. Which of the following reactions is the fastest?(2nd

session 22)

a. (Piece of) Mg(s) + 2HCl(aq) = MgCl2(aq) + H2(g)

b. FeSO4(aq) + 2NaOH(aq) = Fe(OH)2(s) + Na2SO4(aq)

c. CH3COOH + CH3OH(l) = CH3COOCH3(aq) + H2O(l)

d. Fe(s) +2O2(g)+3/2H2O(l) = 2Fe(OH)3(s)

10. On performing a reaction of active metal (X) with strong mineral acid (Y). What is the modification
which can be performed to make the reaction occurs in a shorter time ?...(Exp./ June 21)

a. Dividing the metal.

b. Decreasing the acid volume.

c. Decreasing the reaction temperature.

d. Increasing the pressure.

11. In the following equilibrium reaction:

A2(g) + B2(g) ⇌2AB(g)

If the rate formation of AB gas is equal (3 L/sec) at (25°C).

When the temperature of reaction is increased to (45°C), the rate formation of AB gas is equal…..(1 st
session 23)

a. 12 L/sec

b. 6 L/sec

c. 5.4 L/sec

d. 9 L/sec

12. Four flasks are equal in volume putted in them the quantities as shown in the following shapes:

The correct arrangement of these reactions according to their rate is…..(1 st session 22)

a. (2)> (1)> (3) > (4)

b. (2)> (3) > (1) > (4)

c. (3) > (2)> (4)> (1)

d. (4)> (1)> (2) > (3)

13. On adding a solution of substance (Y) to a solution of substance (X) which has a pale yellow color,
a solution with a certain color is produced, and when excess of the substance (Y) solution is added to
the same reaction, the produced color increases. So, the two substances (X) and (Y) are …..(2nd
session 21)

(X): FeCl3 , (Y): NH4SCN

(X): NH4SCN, (Y): FeCl3

(X): NH4OH , (Y): FeCl3

(X): FeCl3, (Y): NH4OH

14. In the opposite reaction: N2O4(g) (Colorless)⇌2NO2(g) (Reddish brown)

On adding excess of N2O4…..(Exp./ June 21)

a. the color increases and K value remains constant.

b. the color increases and K value increases.

c. the color decreases and K value remains constant.

d. the color decreases and K, value decreases.

15. Adding drops of dil. hydrochloric acid to equilibrium system for sodium acetate solution
causes..............(Exp./ March 23)

a. decreasing the concentration of sodium cations.

b. decreasing the concentration of acetic acid.

c. increasing the concentration of sodium cations.

d. increasing the concentration of sodium acetate.

16. In the following equilibrium system :

K2CO3(s) + 2H2O(l) ⇌ 2K+(aq) + 2OH-(aq) + H2CO3(aq)

On adding drops from CaCl2 solution to it, So the system proceeds ….(1st session 23)

a. forward and solubility of K₂CO₃ increases.

b. forward and solubility of K2CO3 decreases.

c. backward and solubility of K2CO3 increases.

d. backward and solubility of K2CO3 decreases.

17. In the following equilibrium reaction:

4NH3(g) +3O2(g) ⇌ 2N2(g) + 6H2O (v)

Adding a few amount from mixture (O2(g) + 2N2(g)) to the previous equilibrium reaction, so reaction is
activated to ….(1st session 23)

a. forward and [NH₃] is increased.

b. backward and [O2] is decreased.

c. backward and [NH3] is increased.

d. forward and [N2] is decreased.

18. In the following reaction: H2(g) + I2(g) ⇌ 2HI(g) -Heat. Kc value increases by ….(2nd session 21)

a. decreasing the temperature.

b. increasing the concentration of H₂ gas.

c. decreasing the concentration of H₂ gas.

d. increasing the temperature.

19. In the opposite equilibrium reaction: 2NO2(g) ⇌ N2O4(g) + Heat

The value of equilibrium constant changes with the change of …… (1st session 21)

a. the pressure and catalyst.

b. the temperature only.

c. the concentration and catalyst.

d. the pressure only.

20. In the opposite reaction: H₂N-NH2(g) ⇌N2(g) + 2H2(g), ΔΗ = (-)

The amount of evolved hydrogen gas can be increased by….. (1st session 21)

a. increasing the temperature.

b. increasing the container volume.

c. adding excess of N₂ to the reaction medium.

d. adding catalyst to the reaction medium.

21. In the following equilibrium reaction : N2(g) + 3H2(g) ⇌2NH3(g) ΔΗ = -92 kJ

The reaction is activated in the direction of formation of ammonia gas by …(2nd session 22)

a. adding excess of nitrogen gas and decreasing the temperature.

b. withdrawing of nitrogen gas and increasing the pressure.

c. adding excess of hydrogen gas with increasing the temperature.

d. withdrawing of hydrogen gas and decreasing the pressure.

22. The law of mass action is applied to all of the following, except…..(2nd session 21)

a. H2SO3(aq)

b. HCl(aq)

c. HF (aq)

d. H2CO3(aq)

23. In the following equilibrium reaction: PCl5(g) ⇌PCl3(g) + Cl2(g)

If you know that the number of moles of PCI, PCI, and Cl₂ at equilibrium are (0.008, 0.0114 and 0.0114)
respectively and the volume of container = 10 L then the value of equilibrium constant K, is…(1 st
session 22)
a. 615.5

b. 1.62 x 10-3

c. 16.24 x 10-3

d. 61.55

24. When equal concentrations of H₂ and A₂ are mixed, the following equilibrium occurs:

H2(g) + A2(g) ⇌2HA(g)

If the value of [HA] = 1.563 M, and the equilibrium constant equals 40 so [A₂] equals ……(Exp./ June
21)

a. 0.247 M

d. 0.039 M

c. 62.52 M

d. 42.52 M

25. During preparation of ammonia gas from its elements at a certain temperature, it is found that K =
3.7 × 10-4, [H2] = 0.7 M, [N2] = 0.5 M

So [NH3] =…….(Exp./ May 21)

a. 7.96 × 10-3 M

b.3.36 x 10-6 M

c. 3.9 x 10-2 M

d. 7.8 x 104 M

26. In the opposite reaction: I2(g) + H2(g) ⇌ 2HI(g)

If the equilibrium constant for this reaction equals 1.55, and the concentration of hydrogen iodide is
1.035 M, so the concentration of hydrogen and iodine respectively equals … (1st session 21)

[H2] = 0.79 M , [I2] = 0.83 M

[H2] = 0.83 M , [I2] = 0.79 M

[H2] = 0.83 M , [I2] = 0.83 M

[H2] = 0.135 M, [I2] = 0.135 M

27. Given the value of the equilibrium constant for the reaction:

H2(g) + Cl2(g) ⇌ 2HCl(g), K = 4.4 × 1032

So, the equilibrium constant for the reaction + ½H2(g) + ½Cl2(g) ⇌HCl(g)

Equals ….(2nd session 21)

a. 2.2 x 1032

b. 4.4 x 1032

c. 2.1 x 1016

d. 1.1 x 1016

28. In the following two equilibrium reactions:

(1) N2O4(g) ⇌2NO2(g), Kc₁ (2) 2NO2(g) ⇌ N2O4(g), KC2

The mathematical relationship between equilibrium constants is…(2nd session 22)

Kc1+Kc2=1

Kc₁xKc₂=1

Kc₁÷Kc₂ = 1

Kc₁-Kc₂ = 1

⇌2C So the value of K equals….(Exp./ March 23)

29. The opposite graph represents equilibrium system: A+3B

a. 6.66

b. 14.81

c. 0.9

d. 15.49

30. In the following equilibrium reaction:

N2H4(g) ⇌ N2(g) + 2H2(g) + Heat K = 0.04

If [N₂H₄] = 0.1 M, [H2] = 0.2 M

So [N2] after increasing temperature becomes …(1st session 23)

a. 0.08 M

b. 0.2 M

c. 0.3 M

d. 0.1 M

31. In the opposite equilibrium reaction: Br2(g) + H2(g) ⇌2HBr (g) If the partial pressure of bromine,
hydrogen and hydrogen bromide gases are 0.5 atm, 1 atm, 1.5 atm respectively. So the equilibrium
constant for dissociation of hydrogen bromide to its elements equals …(1 st session 21)
a. 2.2

b. 0.22

c. 0.45

d. 4.5

32.In the following reaction : A(g) ⇌2B(g)

If the values of partial pressures are as follow:

(A) = 0.213 atm (B)=0.213 atm. So the equilibrium constant for the reaction equals….(2 nd session 21)

a. 0.213

b. 4.69

c. 0.426

d. 0.1065

33. In the following equilibrium reaction: 2NO2(g) ⇌N2O4(g), (Kp=20)

The value of Kp for decomposition of 2 mol of N₂O4 equals ….(1st session 22)

a. 40

b. 25 x 10-3

c. 2.5 x 10-3

d. 400

34. In the following equilibrium reaction: PCl3(g) + Cl2(g) ⇌PCl5(g), (Kp1 = 0.013) So the value of Kp2 for
this reaction: PCl5(g) ⇌ PCl3(g) + Cl2(g) equals............... (Exp./ June 21)

a. 76.92

b. 67.29

c. 61.79

d. 82.6

35. In the opposite reaction: 2H2O(l) +O2(g) ⇌ 2H2O2(l), Kp = 0.2 The partial pressure of oxygen equals….
(2nd session 22)

a. 0.2 atm

b. 0.02 atm

c. 5 atm

d. 0.5 atm
36. In the following equilibrium reaction:

4NH3(g) +302(g) 2N2(g) + 6H2O (v) Kp = 15.47 If you know that partial pressure of ammonia 1.5 atm
and oxygen 1.16 atm and water vapour 2.4 atm, so the partial pressure of nitrogen gas equal….(Exp./
March 23)

a. 2.4 atm

b. 1.6 atm

c. 0.64 atm

d. 0.8 atm

37. The aqueous solution of sulphurous acid contains ….(1st session 22)

a. H2SO3, H3O+, SO32-, HSO3-, OH-

b. H2SO3, H3O+, OH-

c. H3O+, HSO3-, OH-

d. H2SO3, H3O+, SO3, HSO3-, OH-

38. In the opposite figure : Which of the following represents the change occurs in the ionization
degree (a) after adding equal amount of water to each tube ?b(Exp./ May 21)

Tube (A): Aqueous solution of weak acid

Tube (B): Aqueous solution of strong acid

Choices Tube (A) Tube (b)

a. Increases Does not affect
b. Does not affect Decreases
c. Decreases Increases
d. Increases Decreases
39 At constant temperature, on dilution of a weak electrolyte… (1 st session 21)

a. the degree of ionization decreases, and the solution concentration increases.

b. the degree of ionization increases, and the solution concentration increases.

c. the degree of ionization increases, and the solution concentration decreases.

d. the degree of ionization decreases, and the solution concentration decreases.

40. The following table illustrates three solutions having the same concentration:

(A) (B) (C)

Terephthalic acid Hydroiodic acid Ethanoic acid
The correct arrangement of these solutions according to the concentration of hydrogen ion …(1 St
session 22)

a. C>A>B
b. B>A>C

c. A>C>B

d. A>B>C

41. In the following equilibrium system :

CH3COOH + H2O⇌ CH3COO-(aq) + H3O+(aq), (Ka=1.8 × 10-5) On adding drops of HCl(aq) to the reaction, the
value of Ka of acetic acid equals…..(Exp./ June 21)

a. 1.8 x 10-5

b. 0.9 x 10-5

c. 3.6 x 10-6

d. 3.6 x 10-4

(A) (B) (C) (D)

1.7 x 10-3 1.8 x 10-5 4.4 x 10-7 1.2 x 10-2
42 The following table shows the values of ionization constants of some acids :

Which of the following is correct? (2nd session 22)

a. (B) is weaker than (C) and stronger than (A).

b. (C) is weaker than (B) and stronger than (D).

c. (D) is stronger than (B) and (C).

d. (A) is stronger than (B) and (D).

43. 7.258 g of HCN acid is dissolved in water, the volume of solution becomes 100 mL, if you know that
(K = 7.2 x 10-10). So, the degree of ionization of the acid equals…[H=1,C=12, N = 14] (2 nd session 21)

a. 2.56 x 10-4

b. 1.63 x 10-3

c. 2.56 x 10-6

d.1.63 x 10-5

44. If you know the ionization constant (Ka) for monoprotic weak acid = 5.1 x 10 -4 and its conc. = 0.2 M
in solution its volume is (200 mL) So number of dissociated moles equals….(1st session 23)

a. 0.04 x 10-2 mol

b. 1.01 x 10-3 mol

c. 5.05 x 10-2 mol

d. 2.02 x 10-3 mol

45. If the value of pOH for weak acid equals 10 and its equilibrium constant Ka = 5.1 x 10 -4. So the
degree of ionization of the acid equals……(Exp./ March 23)

a. 6.3

b. 4.8

c. 7.2

d. 5.1

46. 11 g of C5H11COOH acid is dissolved in certain amount of water till the volume of solution becomes
1 L if the pH value of the solution at 25°C is 2.94 Then the ionization constant of the acid equals….
[H=1,C=12,O=16] (2nd session 22)

a. 1.39 x 10-5

b. 1.148 x 10-3

c. 1.318 x 10-6

d. 1.39 x 10-4

47. If you know that the concentration of methyl amine solution CH 3NH2 is 0.4 M and its pH = 9 Then,
the value of Kb for the compound (at 25°C) equal….(1st session 23)

a. 2.5 x 10-18

b. 2 x 10-9

c. 4.47 x 10-5

d. 2.5 x 10-10

48. If the pH value of an aqueous solution is 3.7, so the concentration of hydroxide ion [OH -] for that
solution is….(Exp./ May 21)

a. 1.99 x 10-4 M

b. 10.3 M

c. 5.01 x 10-11 M

d. 7.3 M

49. A solution its pOH = 11 is added to two indicators (X) and (Y), notice that: (X): Colourless.

(Y): Red colour.

So the two indicators (X), (Y) are….(1st session 23)

a. (X) is phenolphthalein, (Y) is methyl orange.

b. (X) is phenolphthalein, (Y) is bromothymol.

c. (X) is methyl orange (Y) is litmus.

d. (X) is litmus, (Y) is bromothymol.

50. If you know that the ionization constant of periodic acid is (14.44 x 10 -5) (at 25°C) and the
concentration of the acid is (3.8 x 10-3 M).So, its pOH value is….(1st session 22)

a. 2.22

b. 3.13

c. 10.87

d. 11.78

51. When drops of bromothymol blue added to sodium oxalate solution Na 2C2O4 The color of the
solution is… (Exp./ June 21)

a. blue.

b. yellow.

c. green.

d. red.

52. You have two solutions, one of them has litmus and the other has methyl orange and both of
them have red colour in each medium. Which one of the following salt solutions distinguishes
between them? (Exp./ March 23)

a. Na2CO3

b. CaCO3

c. KNO3

d. (NH4)2SO4

63. From the following scheme :

Black ppt. (B) + Acidic solution Gas ( X ) Salt solution Na₂ SO₄→solutio n White ppt. (A) + Alkaline
←
solution

The white ppt. (A), black ppt. (B) and gas (X) are…..(1st session 23)

Choices ppt. (A) ppt. (B) Gas (X)

a. Ag2SO4 AgCl HCI

b. BaSO4 BaCl2 HCI
c. PbSO4 PbS H₂S
d. CuSO4 CuS H₂S
54. When drops of blue litmus solution added to potassium nitrate solution, the color of the indicator
is…. (1st session 21)

a. blue.

b. violet.

c. red.

d. green.

55. The aqueous solution of potassium acetate is distinguished from the aqueous solution of
ammonium acetate which has the same volume and concentration by….(Exp./ May 21)

a. [OH-] value in case of potassium acetate is lower.

b. pOH value of ammonium acetate is lower.

c. [H3O+] value in case of potassium acetate solution is lower.

d. pH value in case of potassium acetate is lower.

56. The correct arrangement of the following solutions according to their pOH values is… (Exp./ March
23)

a. NaCl > CH3COOK > NH4NO3

b. NH4NO3 > NaCl > CH3COOK

c. CH3COOK > NaCl > NH4NO3

d. NH4NO3 > CH3COOK > NaCl

57. (A) and (B) are two salt solutions, when the methyl orange is added for each one individually:

• The colour of indicator changes in the solution (A) into red.

• The colour of indicator does not change in the solution (B).

Which of the following is correct for (A) and (B) ?(1st session 23)

a. (A): NH4NO3,(B): Na₂S

b. (A): (NH4)2SO4,(B): KNO3

c. (A): K2CO3(B): NaBr

d. (A): Na2CO3,(B): NH4HCO3

58. If the solubility product of the salt (XY2) is 1.6 x 10-10, the concentration of [Y] equals… (1st session
22)

a. 3.41 x 104 M

b. 6.82 x 104 M
c. 2.36 x 10-5 M

d. 2.14 x 10-5 M

59. If you know that the solubility degree of silver chromate (Ag 2CrO4) is 6.62 x 10-5 M, the solubility
product of this compound equals…(1st session 21)

a. 0.58 x 10-12

b. 1.16 x 10-12

c. 2.32 x 10-12

d. 3.48 x 10-12

60. If you know that the solubility product of silver chloride salt in saturated solution its volume is (0.1
L) at a certain temperature equals 2.56 x 106, the mass of silver chloride dissolving in the solution
equals…[Ag=108, Cl=35.5] (2nd session 21)

a. 0.023 g

b. 0.0115 g

c. 2.3 x 10-6g

d. 1.15 x 10-6 g

61. If the solubility product of lead hydroxide Pb(OH)2 is 2.5 × 10-6 then, the solubility degree of it
equals…(2nd session 22)

a. 0.27 M

b. 0.0135 M

c. 4.27 x 10-3 M

d. 8.54 x 10-3 M

62. If you know that the solubility product of zinc sulphide, Ksp = 1 x 10 -21, and its molar mass is (97
g/mol) at 25°C then the mass of zinc sulphide which dissolve in 100 g of pure water is… (1st session
23)

a. 6.034 x 10-10 g

b. 31.6 x 10-12 g

c. 2 x 10-21 g

d. 3.067 x 10-10 g

63. On adding HCI to the equilibrium system that is expressed by the following equation:

AgCl(s) ⇌Ag(aq) + Cl(aq) The change that occurs is ….(1st session 22)

a. the concentration of Ag+ increases and the amount of AgCl(s) decreases.

b. the value of K increases.

c. the value of K decreases.

d. the concentration of Ag+ decreases and the amount of AgCl(s) increases.

64. The following equation represents a system at equilibrium state:

AgCl(s) ⇌Ag+ (aq) + Cl-(aq)

Which of the following changes takes place by adding drops of lead acetate to that system?

(Exp./May 21)

a. The rate of backward reaction increases and concentration of silver ions increases.

b. The rate of backward reaction decreases and concentration of silver ions decreases.

c. The rate of forward reaction increases and concentration of chloride ion decreases.

d. The rate of forward reaction decreases and concentration of chloride ion increases.

65. In the opposite saturated solution: AgCl (s) ⇌Ag(aq) + Cl(aq)

All of the following decrease the solubility of AgCl when they are added to it except…(Exp./ June 21)

a. NH4OH (aq)

b. AgNO3(aq)

c. NaCl(aq)

d. HCl(aq)

Second Essay question

66. Dihydroxide basic compound that is sparingly soluble in water, if pH value equal 8 Calculate Ksp
for this compound. (Exp./ March 23)