JEE Assignments
JEE Assignments
JEE Assignments
2. A solid particle having spherical shape is assumed to react only on its surface. However the amount of reactant
contained in it is determined by its volume. Consider the following rate law for a solid particle shrinking due to
dV
reaction kS [where S = Surface area]
dt
The order of the above reaction will be :
(A) 0 (B) 1 (C) 2/3 (D) 3/2
3. A sample of rock from South America contains equal moles of U238 and Pb206. The age of rock is :
(t1/ 2 for U 238 4.5 109 year) .
(A) 4.5 109 year (B) 9 109 year (C) 13.5 109 year (D) None of these
4. The graph of log t1/ 2 v/s log[A] is given below for the reaction :
A
product
The rate law for the reaction is :
d[A] d[A]
(A) k (B) k[A]
dt dt
d[A] d[A]
(C) k[A]2 (D) k[A]3
dt dt
5. Consider the following reaction occurring in gas phase : CHCl3 (g) Cl 2 (g)
HCl(g) CCl 4 (g)
The rate law for the reaction is experimentally found as : Rate = k[CHCl3] [Cl2]1/2
Step - 1 : Cl 2 (g)
2Cl(g) Step - 2 : Cl(g) CHCl3 (g)
HCl(g) CCl3 (g)
Step - 3 : Cl(g) CCl3 (g)
CCl 4 (g)
Based on this information, what conclusion can be drawn about this proposed mechanism :
(A) Step 1 is RDS (B) Step 2 is RDS
(C) Step 3 is RDS (D) RDS cannot be identified
6. A mixture of 2 gases ‘R’ and ‘X’ is kept in container at 300 K. X is inert and ‘R’ decomposes according to the
2A(g) 3B( ) 4C(s)
following first order reaction: R(g)
Initial pressure of the reaction in a experiment is recorded as 210 torr. After 10 min, pressure is 330 torr and after
a very long times 430 torr. The half life of ‘R’ is : [Given : Vapour Pressure of C = 20 torr under given condition)
(A) 15 min (B) 10 min (C) 12 min (D) Data insufficient
A A 16 A
7. A radioactive substance z x undergoes decay to produce Z8 y . If 1 gm atom Zx produced 67.2 L of He
A
gas at 1 atm and 273 K conditions in 34.65 hour then the disintegration constant of Zx in (hour–1) is :
(A) 2 102 (B) 4 102 (C) 8 10 2 (D) 3.6 10 3
The reaction is 1st order in both directions, with an equilibrium constant of 104, the activation energy for the forward
reaction is 57.45 kJ/mol. Assuming Arrhenius pre-exponential factor of forward reaction 1012 sec 1 .
8. What is expected forward rate constant at 300 K, if we initiate this reaction starting with only reactant ?
(A) 102 (B) 106 (C) 108 (D) 104
9. If the change in entropy of the reaction is 0.07 kJ K 1mol1 at 1 atm pressure. The temperature upto which
forward reaction would not be spontaneous is :
(A) T 285.7 K (B) T 200 K (C) T 340.2 K (D) T 200 K
Two reactions with half life periods TA and TB (in min) and kA(min–1) and k B (mol L1 min 1 ) . If half life periods
are equal at the start of the reaction, the reaction rate ratio at the start of reaction would be [assuming initial
concentrations of A and B are same] [Given : ln2 0.693 ]
k A TA
(A) 2k A TA (B) 1.386 (C) (D) 0.693
2
14. For given parallel reaction
1 k (sec 1 )
A
2B 3C
2 k (sec 1 )
A
4D E
Which of the following is/are correct for % yield of mole in product mixture?
40k1 80k 2 60 k1 10k 2
(A) %B (B) %D (C) %C (D) %E
k1 k 2 k1 k 2 k1 k 2 k1 k 2
Ea
(A) CH3COOC2 H5 NaOH
CH3COONa C2 H5 OH (P)
nd k Ae RT
(2 order)
(B) 2H 2 O2
2H 2 O O 2 (1st Order) (Q)
SUBJECTIVE QUESTIONS
17. For reaction A
B , following data observed.
Time 0 5 15
1
A 1 2 4
Determine the order of reaction
18. For a chemical reaction, A
Products , rate increases 4 times when catalyst is used. The difference in
Activation energy (in kJ / mol) of without & with catalysts at 300K is X. Find 2X?
232 208
19. 92 U
82 Pb
Calculate difference between number of particles and particle emitted in the process.
20. A freshly prepared radioactive sample of half life 60 min emits radiation of intensity which is 64 times the
permissible safe level. Calculate the minimum time (in hrs) after which it would be possible to work safely with
the source.
21. Under same condition initial conc. of 2.772 M of reactant A becomes one-fourth in 100 sec and in 50 sec through
k
first order and zero order kinetics respectively. Calculate the value of Z. (Where Z 0 )
k1
k0 = rate constant for zero order kinetics.
k1 = rate constant for 1st order kinetics.
22. For first order reaction the time required for 93.75% of reaction completion is x times to the time required for half
of the reaction. The value of (x) is __________.
ELECTROCHEMISTRY
SINGLE CHOICE QUESTION
23. The reduction potential of water at 25C , in a buffer of pH = 10 is :
(Assuming partial pressure of H2 gas at 25C = 1 atm)
(A) +0.5910 V (B) –0.5910 V (C) –0.8274 V (D) +0.8274 V
25. pKa of a weak monobasic acid HA is 10. The limiting ionic conductances of H and A ions are 350 Scm2
mol1 and 40 S cm2 mol1 respectively. The molar conductance of 102 M aq . solution of HA will be :
(A) 3.9 102 Scm 2 mol1 (B) 3.9 104 Scm 2 mol1
Zn 2 (aq) H (g)
26. For the following cell at 298 K, Zn HCl (aq) 2 Pt, with E cell 0.701V and
0.01M 1L 1atm
E0 0.76 V. Which of the following amounts of NaOH will just make the pH of cathodic compartment
Zn 2 |Zn
to be equal to 7.0.
(A) 0.4 g (B) 4g (C) 10 g (D) 2g
27. The conductivity of 0.01 M HA is 3.8 105 1cm 1 and conductivity of solution formed by mixing 100 cm3
31. A dilute solution of NaCl is placed between two Pt electrodes which are 8.5 cm apart. A potential difference of
7.5 volt is applied across the electrodes, what will be the distance travelled by Na in1 Hr ?
[Given : 0 70Scm 2 mol1 ]
Na
(A) 2.3 cm (B) 4.8 cm (C) 3.5 cm (D) 7.8 cm
32. Net cell reaction taking place when amalgam is in contact with Al foil.
(A) 2H 2 O2
2H 2 O
(B) 4Al 3O2 12H
4Al3 6H 2 O
(C) 4Al 3O2 6H 2 O 4OH
4[Al(OH)4 ]
(D) 4Al 3O 2
2Al2 O3
33. E experienced by the person with dental filling of Ag, Sn and Hg amalgam is :
(A) –2.89 V (B) –0.93 V (C) + 2.89 V (D) 0.43 V
34. The standard electrode potentials E° of the following half cell reactions are :
(i) MnO4 8H 5e
Mn 2 4H 2 O E 1.51 V
(ii) Sn 2
Sn 4 2e E –0.15 V
(iv) Ce3
Ce4 e E –1.61 V
The oxidizing power of the various species are related as :
(A) Cr2 O72 MnO 4 (B) Ce 4 Sn 4 (C) Ce4 MnO 4 (D) MnO4 Sn 4
(A) (B)
(C) (D)
SUBJECTIVE QUESTIONS
38. 100 ml of 0.005 M CuSO4 solution is electrolysed by passing a current of 0.02 amp with a current efficiency of
80% for 200 min. Calculate pH of solution after completion of electrolysis.
42. 1 molal urea solution freezes at 1.86°C and depression in freezing point of 0.01 molal aqueous CH3 COOH
solution is 0.02046°C. The pH of CH3COOH solution is:
(Assume molality equal to molarity)
(A) 2 (B) 3 (C) 3.2 (D) 4.2
4
43. The Henry’s law constant for solubility of gas A in water at 25°C is 10 atm. The % by volume of gas A is 50% in
gaseous mixture. The number of moles of A, dissolved in 100 mol of water at 10 atm pressure and 298 K is :
(A) 5 10 4 (B) 10 104 (C) 5 10 2 (D) 10 102
If 50% octahedral voids occupied by Al3 and 12.5% tetrahedral void occupied by Mg , then formula of
2+
50.
compound is:
(A) MgAl2O4 (B) Mg4Al 3O4 (C) Mg2Al 2O5 (D) None of these
53. A body centered cubic lattice is made up of hollow spheres of B. Spheres of solid A are present in hollow spheres
of B. Radius of A is half of radius of B. What is the ratio of total volume of spheres of B uncoccupied by A in a
unit cell and volume of unit cell ?
7 3 7 3 7
(A) (B) (C) (D) None of these
64 128 24
that of the residual liquid has mole fraction of A (X A ) is 0.30. If the vapour pressure of the residual liquid at
80°C is 600 torr. Which of the following is/are true ?
(A) The composition of the original liquid was XA = 0.6
(B) The composition of the original liquid was XA = 0.4
2500
(C) PA0 torr (D) PB0 500 torr
3
63. In a F.C.C. unit cell, atoms are numbered as shown below. Identify the pair in which distance
between the atoms is same. [Atoms 2, 3, 4 are present face centre]
(A) (1 & 4) and (1 & 3) (B) (1 & 2) and (4 & 3)
(C) (1 & 2) and (1 & 4) (D) (1 & 2) and (2 & 3)
64. The HCP and CCP structure for a given element would be expected to have :
(A) The same co-ordination number (B) The same volume of unit cell
(C) the same packing fraction (D) The same effective number of atoms per unit cell
65. A solution having osmotic pressure 5 atm (X) is separated by a SPM from another solution having osmotic
pressure 6 atm (Y)
(A) Solution X is hypertonic with respect to Y and solvent flows from X to Y
(B) If additional pressure on Y is increased by 1 atm that of X by 0.5 atm, solvent flow from Y to X
(C) Additional pressure of 1 atm when applied on solution Y stops net flow of solvent across SPM
(D) If concentration of (non-dissociative or associative) solute in X is 0.1 M than in Y it can be 0.12 M.
(C) Vapour pressure of binary solution of two immiscible and volatile liquids. (R) PB0 A (PA0 PB0 )
Vapour pressure of binary solution having non-volatile solute (B) and PA0 P
(D) (S) B
volatile solvent (A). PA0
72. Metal element “M” of radius 50 nm is crystallized in FCC format and made cubic crystal such that face of unit
cell is aligned with face of cubical crystal. If total number of metal atoms of “M” at all faces of cubic crystal is
6 1030 , then area of one face of cubical crystal is (A 1016 ) m 2 . Then the value of A is :
73. 526.3 ml of 0.5 M HCl is shaken with 0.5g of activated charcoal and filtered. The concentration of the filtrate is
reduced to 0.4 M. What is the amount of adsorption (x/m) ?
74. For ABC ABC ABC ….. closed packed structure if the distance between two successive tetrahedral void is ‘X’
2Y 2
and distance between two successive octahedral voids is ‘Y’ in a unit cell then
is:
X
1 1 1
75. For body centred orthorhombic unit cell of atoms (M = 20 amu) a nm, b nm, c nm . Find the value
2 5 10
amu
of density in the form of .
(A)3
76. To 250 ml of water, x g of acetic acid is added. If 11.5% of acetic acid is dissociated, the depression in freezing
point comes out 0.416. What will be the value of x?
Given : Kf(water) = 1.86 K kg–1 mol–1 and density of water is 0.997 g ml–1.
ANSWERS KEY
JEE Advanced Final Practice Assignment
Physical Chemistry Class XIIth
1 2 3 4 5 6 7 8 9 10 11 12 13 14
C C A C B B B A A A AC ACD AB ABC
15 16 17 18 19 20 21
A -P ; B - P R S ; C - P Q; D - P R S A - Q ; B - R ; C - S; D - P 2 7 4 6 3
22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
37 38 39 40 41 42 43 44 45 46 47
A - P Q S ; B -P Q S ; C - PQ; D – PQS 2 3 B D B C C A C C
48 49 50 51 52 53 54 55 56 57 58
59 60 61 62 63 64 65 66 67
68 69 70
71 72 73 74 75 76
A -P ; B - S ; C - R; D - Q 1 4 4 4 3