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UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS

General Certificate of Education
Advanced Subsidiary Level and Advanced Level
*6081489769*

CHEMISTRY 9701/22
Paper 2 Structured Questions AS Core October/November 2012
1 hour 15 minutes
Candidates answer on the Question Paper.
Additional Materials: Data Booklet

READ THESE INSTRUCTIONS FIRST

Write your Centre number, candidate number and name on all the work you hand in.
Write in dark blue or black pen.
You may use a soft pencil for any diagrams, graphs or rough working.
Do not use staples, paper clips, highlighters, glue or correction fluid.
DO NOT WRITE IN ANY BARCODES.

Answer all questions.

You may lose marks if you do not show your working or if you do not use appropriate units.
A Data Booklet is provided.

At the end of the examination, fasten all your work securely together.
The number of marks is given in brackets [ ] at the end of each question or part question.

For Examiner’s Use

Total

This document consists of 11 printed pages and 1 blank page.

IB12 11_9701_22/FP
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For
Answer all the questions in the spaces provided. Examiner’s
Use

1 Zinc is an essential trace element which is necessary for the healthy growth of animals
and plants. Zinc deficiency in humans can be easily treated by using zinc salts as dietary
supplements.

(a) One salt which is used as a dietary supplement is a hydrated zinc sulfate, ZnSO4.xH2O,
which is a colourless crystalline solid.

Crystals of zinc sulfate may be prepared in a school or college laboratory by reacting

dilute sulfuric acid with a suitable compound of zinc.

Give the formulae of two simple compounds of zinc that could each react with dilute
sulfuric acid to produce zinc sulfate.

....................................................... and ....................................................... [2]

(b) A simple experiment to determine the value of x in the formula ZnSO4.xH2O is to heat it
carefully to drive off the water.

ZnSO4.xH2O(s) → ZnSO4(s) + xH2O(g)

A student placed a sample of the hydrated zinc sulfate in a weighed boiling tube and
reweighed it. He then heated the tube for a short time, cooled it and reweighed it when
cool. This process was repeated four times. The final results are shown below.

mass of mass of tube + mass of tube + salt

empty tube / g hydrated salt / g after fourth heating / g
74.25 77.97 76.34

(i) Why was the boiling tube heated, cooled and reweighed four times?

....................................................................................................................................

....................................................................................................................................

(ii) Calculate the amount, in moles, of the anhydrous salt produced.

(iii) Calculate the amount, in moles, of water driven off by heating.

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(iv) Use your results to (ii) and (iii) to calculate the value of x in ZnSO4.xH2O. Examiner’s
Use

[7]

(c) For many people, an intake of approximately 15 mg per day of zinc will be sufficient to
prevent deficiencies.

Zinc ethanoate crystals, (CH3CO2)2Zn.2H2O, may be used in this way.

(i) What mass of pure crystalline zinc ethanoate (Mr = 219.4) will need to be taken to
obtain a dose of 15 mg of zinc?

(ii) If this dose is taken in solution as 5 cm3 of aqueous zinc ethanoate, what would be
the concentration of the solution used?
Give your answer in mol dm–3.

[4]

[Total: 13]

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2 Each of the Group VII elements chlorine, bromine and iodine forms a hydride. Examiner’s
Use
(a) (i) Outline how the relative thermal stabilities of these hydrides change from HCl to HI.

....................................................................................................................................

....................................................................................................................................

(ii) Explain the variation you have outlined in (i).

....................................................................................................................................

....................................................................................................................................

....................................................................................................................................
[3]

Hydrogen iodide can be made by heating together hydrogen gas and iodine vapour. The
reaction is incomplete.

H2(g) + I2(g) 2HI(g)

(b) Write an expression for Kc and state the units.

Kc = ........................................... units ........................................... [2]

(c) For this equilibrium, the numerical value of the equilibrium constant Kc is 140 at 500 K and
59 at 650 K.

Use this information to state and explain the effect of the following changes on the
equilibrium position.

(i) increasing the pressure applied to the equilibrium

....................................................................................................................................

....................................................................................................................................

(ii) decreasing the temperature of the equilibrium

....................................................................................................................................

....................................................................................................................................
[4]

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(d) A mixture of 0.02 mol of hydrogen and 0.02 mol of iodine was placed in a 1 dm3 flask and Examiner’s
allowed to come to equilibrium at 650 K. Use

Calculate the amount, in moles, of each substance present in the equilibrium mixture at
650 K.

H2(g) + I2(g) 2HI(g)

initial moles 0.02 0.02 0

[4]

[Total: 13]

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3 Ammonia is an important industrial chemical which is manufactured on a large scale by using Examiner’s
the Haber process. Use

(a) (i) Write a balanced equation, with state symbols, for the reaction occurring in the
Haber process.

....................................................................................................................................

(ii) Give three essential operating conditions that are used in the Haber process.

....................................................................................................................................

....................................................................................................................................

....................................................................................................................................

(iii) State one large scale use of ammonia.

....................................................................................................................................
[5]

(b) Ammonia may be prepared in a school or college laboratory by using the apparatus
below.

ammonia

ammonium chloride
and calcium hydroxide

heat
drying tower

The reaction involves the displacement of ammonia from one of its compounds.

(i) Give the formulae of the two reactants that are heated together to produce ammonia.

........................................ and ........................................

(ii) Construct a balanced equation for the reaction between your two reagents.

....................................................................................................................................

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(iii) Common drying agents include calcium oxide, concentrated sulfuric acid and Examiner’s
phosphorus(V) oxide. Use
Which one of these would be used in the drying tower in this experiment? Explain
your answer.

....................................................................................................................................

....................................................................................................................................
[5]

(c) Ammonia is a weak base which forms salts containing the ammonium ion.

Describe, with the aid of an equation, the formation and structure of the ammonium ion.
You should use displayed formulae in your answer.

[3]

[Total: 13]

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4 Many organic compounds, including alcohols, carbonyl compounds, carboxylic acids and Examiner’s
esters, contain oxygen. Use

(a) The table below lists some oxygen-containing organic compounds and some common
laboratory reagents.

(i) Complete the table as fully as you can.

If you think no reaction occurs, write ‘no reaction’ in the box for the structural
formula(e).

organic structural formula(e) of

reaction reagent
compound organic product(s)

Cr2O72– / H+
A (CH3)3COH
heat under reflux

Fehling’s reagent
B CH3CH2CHO
warm

NaOH(aq)
C HCO2CH(CH3)2
warm

D CH2 CHCHO NaBH4

E (CH3)3COH NaBH4

MnO4– / H+
F CH3CH2COCH3
heat under reflux

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(ii) During some of the reactions in (i) a colour change occurs. Examiner’s
Complete the table below for any such reactions, stating the letter of the reaction Use
and what the colour change is.

colour at the beginning colour at the end

reaction
of the reaction of the reaction

[10]

(b) Some oxygen-containing compounds react with 2,4-dinitrophenylhydrazine.

O2N

H2NNH NO2

2,4-dinitrophenylhydrazine

(i) Draw the structural formula of the organic compound formed when HOCH2CH2CHO
reacts with 2,4-dinitrophenylhydrazine reagent.

(ii) Suggest the colour of the organic product.

......................................................
[2]

[Total: 12]

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5 Compound X has the molecular formula C4H8O2. Examiner’s
Use
(a) (i) Treatment of X with sodium metal produces a colourless flammable gas.
What does this result tell you about the functional groups that could be present in X?

....................................................................................................................................

....................................................................................................................................

(ii) There is no reaction when X is treated with sodium hydrogencarbonate, NaHCO3.

What does this result tell you about the functional groups that could be present in X?

....................................................................................................................................

....................................................................................................................................

(iii) When X is shaken with aqueous bromine the orange colour disappears.
What does this result tell you about the functional groups that could be present in X?

....................................................................................................................................

....................................................................................................................................
[3]

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(b) The molecule of X has the following features. Examiner’s
Use
● The carbon chain is unbranched and the molecule is not cyclic.
● No oxygen atom is attached to any carbon atom which is involved in π bonding.
● No carbon atom has more than one oxygen atom joined to it.

There are five possible isomers of X which fit these data. Four of these isomers exist as
two pairs of stereoisomers.

(i) Draw displayed formulae of each of these two pairs.

pair 1

pair 2

(ii) These four isomers of X show two types of stereoisomerism.

State which type of isomerism each pair shows.

pair 1 .......................................................................

pair 2 .......................................................................
[6]

[Total: 9]

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