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SPA (SHW 00121 12/07) T73991/3

UCLES 2009 [Turn over
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
General Certificate of Education Ordinary Level
READ THESE INSTRUCTIONS FIRST
Write your Centre number, candidate number and name on all the work you hand in.
Write in dark blue or black pen.
You may use a soft pencil for any diagrams, graphs or rough working.
Do not use staples, paper clips, highlighters, glue or correction fluid.
DO NOT WRITE IN ANY BARCODES.
Answer all questions.
Write your answers in the spaces provided in the Question Paper.
At the end of the examination, fasten all your work securely together.
The number of marks is given in brackets [ ] at the end of each question or part question.
*
4
6
2
2
7
5
7
1
6
6
*
CHEMISTRY 5070/04
Paper 4 Alternative to Practical October/November 2009
1 hour
Candidates answer on the Question Paper.
No Additional Materials are required.
For Examiners Use
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5070/04/O/N/09 UCLES 2009
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Examiners
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1 Dry ammonia gas can be made in the laboratory using the apparatus shown below, by
heating a solid mixture of calcium hydroxide, Ca(OH)
2
and ammonium chloride, NH
4
Cl.
heat
tube A containing
calcium oxide
ammonium chloride
and
calcium hydroxide
ammonia
The equation for the reaction is
Ca(OH)
2
+ 2NH
4
Cl CaCl
2
+ 2H
2
O + 2NH
3
(a) By referring to the equation suggest why tube A, which contains calcium oxide, is
included in the apparatus.
.................................................................................................................................... [1]
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(b) Which method, X, Y or Z, is most suitable for collecting ammonia?
Explain your answer.
X
Z
Y
method of collection .....................................
explanation ......................................................................................................................
.................................................................................................................................... [3]
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(c) The fertiliser ammonium phosphate, (NH
4
)
3
PO
4
, contains nitrogen, one of the essential
elements for the growth of plants.
(i) Which other essential element is found in ammonium phosphate?
............................................................................................................................ [1]
(ii) Given an aqueous solution of ammonium phosphate, describe a test to confirm the
presence of the ammonium ion.
..................................................................................................................................
..................................................................................................................................
..................................................................................................................................
............................................................................................................................ [3]
(iii) Calculate the mass of nitrogen contained in 1 kg of ammonium phosphate.
[A
r
: N,14; H,1; P, 31; O,16]
.............................................. g [2]
[Total: 10]
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5070/04/O/N/09 UCLES 2009 [Turn over
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Examiners
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2 A student produced zinc oxide by heating zinc nitrate.
Some zinc nitrate was placed in a previously weighed crucible which was then reweighed.
mass of crucible + zinc nitrate = 11.79 g
mass of crucible = 9.90 g
(a) Calculate the mass of zinc nitrate.
.............................................. g [1]
The solid zinc nitrate was heated in a fume cupboard. The following reaction took place.
2Zn(NO
3
)
2
(s) 2ZnO(s) + 4NO
2
(g) + O
2
(g)
(b) Describe the appearance of zinc oxide.
.................................................................................................................................... [1]
(c) Why was the heating done in a fume cupboard?
.................................................................................................................................... [1]
(d) Using your answer to (a) calculate the number of moles of zinc nitrate used in the
reaction.
[A
r
: Zn, 65; N,14; O,16]
....................................... moles [1]
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(e) Using the equation for the reaction and your answer to (d) calculate the total volume of
each gas produced from the reaction.
[1 mole of a gas occupies a volume of 24 dm
3
at room temperature and pressure.]
volume of NO
2
............................................... cm
3
volume of O
2
................................................ cm
3
[2]
(f) Name a compound that will react with zinc oxide to make zinc nitrate.
.................................................................................................................................... [1]
[Total: 7]
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In questions 3 to 7 inclusive, place a tick () in the box against the best answer.
3 On a bottle of which of the following substances would you expect this hazard warning sign
to appear?
(a) aqueous ammonia
(b) aqueous sodium chloride
(c) ethanol
(d) hydrochloric acid
[Total: 1]
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4 A student made four esters by reacting different alcohols and carboxylic acids together, as
shown in the table below.
ester alcohol carboxylic acid
P methanol butanoic acid
Q ethanol methanoic acid
R propanol ethanoic acid
S butanol propanoic acid
Which two esters have the same relative molecular mass?
(a) P and Q
(b) R and S
(c) P and R
(d) Q and S
[Total: 1]
5 A student made oxygen by adding hydrogen peroxide to a weighed sample of powdered
manganese(IV) oxide, which acts as a catalyst.
Which of the following graphs represents how the mass of manganese(IV) oxide varied as
the experiment proceeded?
mass
time
(a)
mass
time
(b)
mass
time
(c)
mass
time
(d)
[Total: 1]
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5070/04/O/N/09 UCLES 2009 [Turn over
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6 A student did three experiments in which equal volumes of hydrochloric acid were added
to equal masses (an excess) of calcium carbonate. The gas produced was collected in a
syringe and the volume of gas recorded at one minute intervals.
The results were used to plot the graphs shown below.
time / minutes
volume of
gas / cm
3
1
2
3
Which statement is correct?
(a) In experiment 1 the number of moles of acid was less than in experiment 2.
(b) In experiment 3 the calcium carbonate was more finely powdered than in
experiment 1.
(c) In experiments 2 and 3 the number of moles of acid was the same.
(d) In experiment 3 the concentration of the acid was higher than in experiment 2.
[Total: 1]
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7 Two experiments were done using the cell shown in the diagram below.
+
graphite
electrodes
electrolyte
E
In experiment 1 the electrolyte was molten sodium chloride and in experiment 2 it was
concentrated aqueous sodium chloride.
What were the products at the electrode labelled E?
experiment 1
molten sodium
chloride
experiment 2
concentrated
aqueous sodium
chloride
(a) chlorine oxygen
(b) sodium hydrogen
(c) chlorine hydrogen
(d) sodium oxygen
(e) sodium chlorine
[Total: 1]
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8 A student was given a sample of a carbonate, M
2
CO
3
, where M is a metal. He was asked to
determine the relative atomic mass of M and to suggest its identity.
A sample of the carbonate was added to a previously weighed container which was then
reweighed.
mass of container + M
2
CO
3
= 5.12 g
mass of container = 3.42 g
(a) Calculate the mass of M
2
CO
3
.
.............................................. g [1]
The sample was placed in a volumetric flask and 50.0 cm
3
of 1.00 mol / dm
3
hydrochloric acid
(an excess) was added. A gas was produced.
(b) Name the gas and give a test to confirm its presence.
gas ....................................................
test ............................................................................................................................. [2]
When the reaction had finished, the solution was made up to 250 cm
3
with distilled water.
This was solution G.
Using a pipette, 25.0 cm
3
of G was transferred to a conical flask and a few drops of methyl
orange indicator were added.
A burette was filled with 0.100 mol / dm
3
aqueous sodium hydroxide. Aqueous sodium
hydroxide was run into the titration flask until the end-point was reached.
(c) What was the colour change of the methyl orange during the titration?
The colour changed from ......................................... to ............................................. [1]
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Three titrations were done. The diagrams below show parts of the burette with the liquid
levels at the beginning and end of each titration.
1
0
49
48
24
23
33
32
26
25
27
7
6
8
titration 1 titration 2 titration 3
(d) Use the diagrams to complete the following table.
titration number 1 2 3
final burette reading / cm
3
initial burette reading / cm
3
volume of 0.100 mol / dm
3

sodium hydroxide / cm
3
best titration results ()
Summary:
Tick () the best titration results.
Using these results, the average volume of 0.100 mol / dm
3

sodium hydroxide was ................. cm
3
. [4]
(e) Calculate the number of moles of sodium hydroxide in the average volume of
0.100 mol / dm
3
sodium hydroxide in (d).
....................................... moles [1]
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(f) Using the equation, calculate the number of moles of hydrochloric acid in 25.0 cm
3

of G.
NaOH + HCl NaCl + H
2
O
....................................... moles [1]
(g) Calculate the number of moles of hydrochloric acid in 250 cm
3
of G.
....................................... moles [1]
(h) Calculate the number of moles of hydrochloric acid contained in the original 50.0 cm
3
of
1.00 mol / dm
3
hydrochloric acid.
....................................... moles [1]
(i) By subtracting your answer in (g) from your answer in (h), calculate the number of moles
of hydrochloric acid that reacted with the sample of M
2
CO
3
.
....................................... moles [1]
(j) Using the equation, calculate the number of moles of M
2
CO
3
that reacted with the
number of moles of hydrochloric acid in your answer (i).
M
2
CO
3
+ 2HCl MCl
2
+ CO
2
+ H
2
O
....................................... moles [1]
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(k) Using your answers in (a) and (j) calculate the relative formula mass of M
2
CO
3
and
hence the relative atomic mass of M.
[A
r
: C,12; O,16]
relative formula mass of M
2
CO
3
......................................................
relative atomic mass of M is ......................................................
[2]
(l) Given that the relative atomic mass of sodium is 23 suggest the identity of M, giving a
reason for your choice.
M is .................................................................
Reason ...................................................................................................................... [2]
[Total: 18]
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9 The following table shows the tests a student did on compound C. Complete the table by
giving the conclusions to tests (a), (b) and (c), stating the observations in tests (b)(ii) and
(c)(ii) and suggesting both the test and observation that led to the conclusion in test (d).
test observation conclusion
(a) C was dissolved in water
and the solution was
divided into three parts.
A coloured solution was
produced.
(b) (i) To the first part,
aqueous sodium
hydroxide was
added until a
change was seen.
(ii) An excess of
aqueous sodium
hydroxide was
added to the
mixture from (i).
A red-brown precipitate was
produced.
(c) (i) To the second part
aqueous ammonia
was added until a
change was seen.
(ii) An excess of
aqueous ammonia
was added to the
mixture from (i).
A red brown precipitate was
produced.
(d)
C contains NO
3

ions.
Conclusion: the formula of compound C is .............................................
[Total: 8]
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10 When alcohols burn they give out heat. A student used the apparatus below to investigate
the amount of heat produced when propanol was burnt.
metal can
thermometer
200 cm
3
of water
burner containing alcohol
Some propanol was put into the burner which was then weighed.
The temperature of the water was noted.
The burner was lit and allowed to burn for several minutes.
The flame was extinguished and the final temperature of the water was noted. The burner
was reweighed.
The diagrams below show parts of the thermometer stem for each of the temperature
readings.
28
27
26
25
24
initial temperature
37
36
35
34
33
final temperature
17
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(a) Use the weighings and the thermometer readings to complete the following tables.
(i) initial mass of burner + propanol = 70.12 g
final mass of burner + propanol = 69.87 g
mass of propanol burnt = g
(ii) final temperature of water = C
initial temperature of water = C
rise in temperature = C
[3]
(b) (i) Calculate the relative molecular mass of propanol, C
3
H
7
OH.
[A
r
: H,1; C,12; O,16]
............................................................................................................................ [1]
(ii) Using your answers to (a)(i) and (b)(i), calculate the number of moles of propanol
burnt.
....................................... moles [1]
(iii) Using your answers to (a)(ii) and (b)(ii), calculate H, the heat produced when one
mole of propanol was burnt by using the formula:
H =
0.84 rise in temperature
number of moles of propanol burnt
kJ / mol.
..................................... kJ / mol [1]
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(c) What general name is given to a reaction having a negative value of H ?
.................................................................................................................................... [1]
(d) A reference book gives the value of H as 2010 kJ / mol.
Suggest two reasons why the value obtained in the experiment was less than this.
1. ......................................................................................................................................
2. ................................................................................................................................ [2]
The experiment was repeated using four different alcohols. Each burner in turn was weighed
and then the alcohol was allowed to burn until the temperature of the water had risen by
15 C. The flame was then extinguished and the burner reweighed.
The following results were obtained.
alcohol formula mass of alcohol
burned / g
methanol CH
3
OH 0.90
ethanol C
2
H
5
OH 0.70
propanol C
3
H
7
OH 0.62
pentanol C
5
H
11
OH 0.57
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(e) Plot the points on the grid below and draw a smooth curve through the points.
0.5
0
number of carbon atoms
in the formula of the alcohol
mass of
alcohol / g
1 2 3 4 5
0.6
0.7
0.8
0.9
1.0
[2]
(f) Predict the mass of butanol, C
4
H
9
OH, which, on combustion, would raise the temperature
of the water by 15 C.
.............................................. g [1]
[Total: 12]
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5070/04/O/N/09
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