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SP (SC/SLM) S60731/3
UCLES 2004 [Turn over
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
General Certificate of Education Ordinary Level
CHEMISTRY 5070/04
Paper 4 Alternative to Practical
May/June 2004
1 hour
Candidates answer on the Question Paper.
No Additional Materials are required.
READ THESE INSTRUCTIONS FIRST
Write your name, Centre number and candidate number in the spaces at the top of this page.
Write in dark blue or black pen in the spaces provided on the Question Paper.
You may use a pencil for any diagrams, graphs, or rough working.
Do not use staples, paper clips, highlighters, glue or correction fluid.
Answer all questions.
The number of marks is given in brackets [ ] at the end of each question or part question.
You should use names, not symbols, when describing all reacting chemicals and products formed.
You may use a calculator.
Centre Number Candidate Number Name
For Examiners Use
If you have been given a label, look at the
details. If any details are incorrect or
missing, please fill in your correct details
in the space given at the top of this page.
Stick your personal label here, if
provided.
2
5070/04/M/J/04
1 (a) Name the apparatus shown below.
......................................................................................................................................[1]
(b) (i) What safety item should be used with this apparatus?
...................................................................................................................................
(ii) Why is this safety item used?
...............................................................................................................................[2]
25
cm
3
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2 A student was given a test-tube containing a small piece of sodium in oil.
(a) Why was the sodium in oil?
......................................................................................................................................[1]
The piece of sodium was transferred from the test-tube to a beaker half-filled with water.
The reaction produced a gas.
(b) Name this gas and give a test to confirm the presence of this gas.
gas
test and observation
......................................................................................................................................[2]
(c) Give two observations that were made when the sodium reacted with the water.
1. ......................................................................................................................................
2. ..................................................................................................................................[2]
(d) Name the solution that remained in the beaker when the reaction had finished.
......................................................................................................................................[1]
(e) A piece of litmus paper was placed in this solution. What was the colour of the litmus
paper in this solution?
......................................................................................................................................[1]
(f) Write an equation for the reaction between sodium and water.
......................................................................................................................................[1]
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3 A student added 100cm
3
of 0.10 mol/dm
3
hydrochloric acid to 0.5 g of calcium carbonate
contained in a conical flask. The reaction produced carbon dioxide. The equation for the
reaction is shown.
CaCO
3
+ 2HCl

CaCl
2
+ H
2
O + CO
2
(a) Name the piece of apparatus which should be attached to the flask, for collecting and
measuring the volume of carbon dioxide produced.
......................................................................................................................................[1]
(b) Give a test to confirm the presence of carbon dioxide.
test and observation
......................................................................................................................................[1]
(c) (i) Calculate the number of moles of calcium carbonate in 0.5 g.
[A
r
: Ca, 40; C, 12; O, 16]
..........................................moles
(ii) Calculate the number of moles of hydrochloric acid in 100 cm
3
of 0.10 mol/dm
3
.
..........................................moles
(iii) Was one of the reagents in excess?
Explain your answer.
...............................................................................................................................[4]
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(d) Using your answers in (c) calculate the volume of carbon dioxide produced when the
reaction reached completion. (One mole of a gas occupies 24 dm
3
at room temperature
and pressure).
..........................................dm
3
[1]
(e) The experiment was repeated using 0.5 g of magnesium carbonate instead of 0.5 g of
calcium carbonate. Calculate the volume of carbon dioxide produced.
[A
r
: Mg, 24; C, 12; O, 16]
..........................................dm
3
[2]
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In questions 4 to 8 inclusive, place a tick in the box against the best answer.
4 In which of the following cells will the current be the greatest?
(a) (b) (c) (d)
[1]
Mg Cu
distilled water
Mg Cu
dilute sulphuric
acid
Zn Fe
distilled water
Zn Fe
dilute sulphuric
acid
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5 A student measured the rate of reaction between a given mass of zinc and an excess of
hydrochloric acid by recording the volume of hydrogen produced.
The results are shown in the graph below.
How long did it take for half of the zinc to react?
(a) 1.0 min
(b) 1.5 min
(c) 2.0 min
(d) 2.5 min
[1]
6 A student is asked to make copper(II) sulphate. Which of the following methods should he
use?
(a) Add dilute sulphuric acid to copper.
(b) Add copper to aqueous zinc sulphate.
(c) Add dilute sulphuric acid to copper(II) oxide.
(d) Add copper(II) carbonate to aqueous sodium sulphate.
[1]
0
20
40
60
80
1 2 3 4 5
total
volume
of hydrogen
/ cm
3
time / min
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7 Samples of sulphur dioxide are passed through acidified potassium dichromate(VI) and
aqueous potassium iodide. Which of the following results is obtained?
[1]
8 Which of the following pairs of substances produces the compound shown below?
(a) ethene and ethanoic acid
(b) methanol and ethanoic acid
(c) ethene and propanoic acid
(d) ethanol and propanoic acid
[1]
CH
3
CH
2
C
OCH
2
CH
3
O
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acidified potassium
dichromate (VI) aqueous potassium iodide
(a) green to orange brown to colourless
(b) orange to green no change in colour
(c) no change in colour colourless to brown
(d) no change in colour no change in colour
9
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9 The formula for iron(II) sulphate crystals is FeSO
4
.xH
2
O where x is a whole number.
A student determined the value of x using 0.0200 mol/dm
3
potassium manganate(VII). This
was solution G.
(a) A sample of iron(II) sulphate crystals was added to a previously weighed container,
which was then reweighed.
Calculate the mass of iron(II) sulphate crystals used in the experiment.
Mass of container + crystals = 12.38 g
Mass of empty container = 5.42 g
Mass of iron(II) sulphate crystals = g
[1]
(b) The sample was dissolved in 100 cm
3
of dilute sulphuric acid and the solution was
made up to 250 cm
3
with distilled water. This was solution H.
A 25.0 cm
3
sample of H was measured into a titration flask.
Solution G was run from a burette into the flask containing H until an end-point was
reached. Potassium manganate(VII) is purple.
What was the colour change at the end-point?
from ......................................................to .................................................................[1]
(c) Three titrations were done. The diagrams below show parts of the burette before and
after each titration.
titration 1
1
0
27
26
25
titration 2
24
23
49
48
titration 3
7
8
6
33
32
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Use these diagrams to complete the table of results.
Summary.
Tick () the best titration results. Using these results, the average volume of G was
.................. cm
3
. [4]
(d) G is 0.0200 mol/dm
3
potassium manganate (VII).
Calculate how many moles of KMnO
4
were present in the titrated volume of G
calculated in (c).
..........................................moles [1]
(e) Five moles of FeSO
4
react with one mole of KMnO
4
.
Calculate how many moles of FeSO
4
were present in 25.0 cm
3
of H.
..........................................moles [1]
(f) Calculate how many moles of FeSO
4
were present in the 250 cm
3
of H.
..........................................moles [1]
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titration number 1 2 3
final
reading/cm
3
first
reading/cm
3
volume of
solution G/cm
3
best titration
results ()
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(g) Using your answers to (f), calculate the mass of FeSO
4
in the original sample of
FeSO
4
.xH
2
O. [M
r
: FeSO
4
, 152.]
..........................................g [1]
(h) Using your answer to (a) and (g) calculate the mass of water in the sample of
FeSO
4
.xH
2
O.
..........................................g [1]
(i) Using our answer to (h) calculate the number of moles of water in the sample of
FeSO
4
.xH
2
O.
[A
r
:H,1; O, 16]
..........................................moles [1]
(j) Using your answers to (f) and (i) calculate the value of x in FeSO
4
.xH
2
O.
......................................................................................................................................[1]
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10 The following table shows the tests a student did on substance T and the conclusions made
from the observations. Complete the table by describing these observations and suggest the
test and observations which lead to the conclusion from test 4.
Conclusion: the formula for substance T is ...............................................................................[10]
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test observation conclusion
1 T was dissolved in water
and the solution divided
into three parts for tests
2, 3 and 4
2 (a) To the first part,
aqueous sodium
hydroxide was added
until a change was
seen
(b) An excess of aqueous
sodium hydroxide was
added to the mixture
from (a)
3 (a) To the second part,
aqueous ammonia
was added until a
change was seen.
(b) An excess of aqueous
ammonia was added
to the mixture from (a)
4
T contains a
transition metal
T may contain Cu
2+
ions.
The presence of
Cu
2+
ions is
confirmed.
T contains Cl

ions.
13
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11 The alcohol butan-1-ol has the formula C
4
H
9
OH. When it is burnt it gives out heat.
A student used the apparatus shown below to find the amount of heat produced when
butan-1-ol was burnt.
Some butan-1-ol was put into the burner, which was weighed. The temperature of the water
was noted. The burner was lit and allowed to burn for several minutes. The flame was
extinguished and the final temperature of the water was noted. The burner was reweighed.
The diagrams below show parts of the thermometer stem for each of the temperature
readings.
24
25
26
27
28
initial temperature
34
35
36
37
38
final temperature
240 cm
3
of water
thermometer
metal can
burner containing alcohol
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(a) Use the weighings and the thermometer readings to complete the following tables.
(i) initial mass of burner + butan-1-ol = 14.34 g
final mass of burner + butan-1-ol = 13.88 g
mass of butan-1-ol burnt = g
(ii) final temperature of water = C
initial temperature of the water = C
rise in temperature = C [3]
(b) (i) Draw the structure of butan-1-ol, C
4
H
9
OH.
(ii) Calculate the relative molecular mass of butan-1-ol.
[A
r
: C, 12; H, 1; O, 16.]
..........................................moles
(iii) Using your answers to (a)(i), calculate the number of moles of butan-1-ol burnt in
the experiment.
..........................................moles
(iv) Using your answers to (a)(ii) and (b)(iii), calculate H, the heat produced when
one mole of butan-1-ol was burnt. Use the formula.
H =
rise in temperature kJ/mol
_____________________________
number of moles of butan-1-ol burnt
..........................................kJ/mol [4]
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(c) A similar experiment was done to compare 5 different alcohols. The mass of alcohol
which burned to increase the temperature by 15 C was measured.
The following results were obtained.
Plot the points on the grid below, connecting the points with a smooth curve.
[2]
0.4
0.5
0.6
0.7
0.8
0.9
1.0
mass of
alcohol burned
/ g
0 1 2
number of carbon atoms
3 4 5
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alcohol formula mass of alcohol
burned / g
methanol CH
3
OH 0.96
ethanol C
2
H
5
OH 0.74
propan-1-ol C
3
H
7
OH
butan-1-ol C
4
H
9
OH 0.54
pentan-1-ol C
5
H
11
OH 0.50
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(d) (i) Using your graph suggest the mass of propan-1-ol required to raise the
temperature by 15 C.
..........................................g
(ii) The actual mass was found to be 0.66 g, which was higher than the mass of
propan-1-ol required on the graph. The student accidentally used a different isomer
of propanol.
Give the structure of this isomer.
...............................................................................................................................[2]
(e) Suggest a reason why the same temperature rise was used in each experiment.
......................................................................................................................................[1]
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