5070 s09 QP 3

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UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
General Certificate of Education Ordinary Level
*9655498133*
5070/03
CHEMISTRY
May/June 2009
Paper 3 Practical Test
1 hour 30 minutes

Candidates answer on the Question Paper
Additional Materials:
As listed in the Confidential Instructions
READ THESE INSTRUCTIONS FIRST

Write your Centre number, candidate number and name on all the work you hand in.
Write in dark blue or black pen.
You may use a pencil for any diagrams, graphs or rough work.
Do not use staples, paper clips, highlighters, glue or correction fluid.
DO NOT WRITE IN ANY BARCODES.
Answer all questions.
You should show the essential steps in any calculations and record experimental results in the spaces provided
on the question paper.
Qualitative Analysis Notes are printed on page 8.
At the end of the examination, fasten all your work securely together.
The number of marks is given in brackets [ ] at the end of each question or part question.
For Examiners Use

1
2
Total
This document consists of 7 printed pages and 1 blank page.

(NH) T67847/2
UCLES 2009
[Turn over

1

Vinegar is an acidic aqueous solution.

P is a solution prepared by taking 150cm3 of vinegar and diluting the solution by adding
distilled water until the total volume is 1.00dm3.
The amount of acid present in solution P can be determined by titrating a volume of aqueous
sodium hydroxide of known concentration with P, using phenolphthalein as the indicator.
Phenolphthalein turns from pink to colourless at the end-point.
Solution Q is 0.100mol/dm3 sodium hydroxide.
(a) Put P into the burette.
Pipette a 25.0cm3 (or 20.0cm3) portion of Q into a flask and titrate with P, using the
phenolphthalein indicator provided.
Record your results in the table, repeating the titration as many times as you consider
necessary to achieve consistent results.
Results
Burette readings
titration number
final reading / cm3

initial reading / cm3
volume of P used / cm3
best titration results (3)
Summary
Tick (3) the best titration results.
Using these results, the average volume of P required was ...............cm3.
Volume of solution Q used was ......................cm3.
UCLES 2009
[12]
5070/03/M/J/09
For
Examiners
Use
(b) Q is 0.100mol/dm3 sodium hydroxide.
Using your results from (a), calculate the number of moles of hydrogen ions, H+, in
1.00dm3 of P.
moles of hydrogen ions in 1.00dm3 of P ......................................
For
Examiners
Use
[2]
(c) Using your answer from (b), determine the number of moles of hydrogen ions, H+, in
150cm3 of vinegar.
moles of hydrogen ions in 150cm3 of vinegar ......................................
[1]
(d) Assuming the only acid present in the vinegar is ethanoic acid, CH3COOH, calculate
the mass, in grams, of ethanoic acid present in 150cm3 of the vinegar.

[The relative formula mass of ethanoic acid is 60.]
mass of ethanoic acid present in 150cm3 of vinegar ...............g
[1]
(e) Given that 1.00cm3 of the vinegar has a mass of 1.00g, calculate the percentage by
mass of ethanoic acid in the vinegar.
percentage by mass of ethanoic acid in vinegar ...............
UCLES 2009
[1]
[Total: 17]
5070/03/M/J/09
[Turn over

2
Carry out the following experiments on the aqueous solution R and the solid sodium salt S
and record your observations in the table. You should test and name any gas evolved.
Tests on solution R
test
no.
1
test
observations
(a) To a portion of solution R, add

aqueous sodium hydroxide until a
change is seen.
(b) Add excess aqueous sodium

hydroxide to the mixture from (a).
(a) To a portion of solution R, add

aqueous ammonia until a change
is seen.
(b) Add excess aqueous ammonia to

the mixture from (a).
(a) To a portion of solution R, add an

equal volume of dilute nitric acid.
(b) Add aqueous silver nitrate to the

mixture from (a).
(a) To a portion of solution R, add an

equal volume of dilute nitric acid.
(b) Add aqueous barium nitrate

solution to the mixture from (a).
UCLES 2009
5070/03/M/J/09
For
Examiners
Use
Tests on solid S
test
no.
test
For
Examiners
Use
observations
To a portion of dilute hydrochloric acid

add a small amount of solid S.
(a) Put 1cm depth of solid S in a hardglass test-tube and heat strongly
for about 3 to 4 minutes. You
should test the gas evolved.

Leave the test-tube and contents to
cool.
(b) To a portion of dilute hydrochloric

acid add some of the solid residue
from (a).
To a portion of aqueous copper(II)

sulfate solution add a small amount of
solid S and mix well.
Put 1cm depth of solid S in a hard-glass

test-tube and then add to it an equal
amount of solid ammonium chloride.
Heat the mixture.
(a) Dissolve a small amount of solid S

in a portion of solution R.
(b) Warm the mixture from (a).
UCLES 2009
[20]
5070/03/M/J/09
[Turn over

Conclusions
For
Examiners
Use
Identify the anion in R.

The anion in R is ......................................
S is a sodium salt. Suggest two other elements present in S.
...................................... and ......................................

UCLES 2009
[3]
[Total: 23]
5070/03/M/J/09

BLANK PAGE
Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.
University of Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of
Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.
UCLES 2009
5070/03/M/J/09

NOTESFORUSEINQUALITATIVEANALYSIS
Tests for anions
anion
test
test result
carbonate (CO32)
add dilute acid
effervescence, carbon dioxide

produced
chloride (Cl )
[in solution]
acidify with dilute nitric acid, then add

aqueous silver nitrate
white ppt.
iodine (I)
[in solution]

aqueous lead(II) nitrate
yellow ppt.
nitrate (NO 3)
[in solution]
add aqueous sodium hydroxide, then

add aluminium foil; warm carefully
ammonia produced
sulfate (SO 42)

[insolution]

aqueous barium nitrate
white ppt.
Tests for aqueous cations

cation
effect of aqueous sodium hydroxide
effect of aqueous ammonia
aluminium (Al 3+)
white ppt., soluble in excess giving a

colourless solution
white ppt., insoluble in excess
ammonium (NH4 )
ammonia produced on warming
calcium (Ca2+)
white ppt., insoluble in excess
no ppt., or very slight white ppt.
copper (Cu 2+)
light blue ppt., insoluble in excess
light blue ppt., soluble in excess

giving a dark blue solution
iron(II) (Fe 2+)
green ppt., insoluble in excess
green ppt., insoluble in excess
iron(III) (Fe3+)
red-brown ppt., insoluble in excess
red-brown ppt., insoluble in excess
zinc (Zn2+)
white ppt., soluble in excess giving

acolourless solution
white ppt., soluble in excess giving

a colourless solution
Tests for gases

gas
test and test result
ammonia (NH3)
turns damp red litmus paper blue
carbon dioxide (CO2)
turns limewater milky
chlorine (Cl 2)
bleaches damp litmus paper
hydrogen (H2)
pops with a lighted splint
oxygen (O2)
relights a glowing splint
sulfur dioxide (SO2)
turns aqueous potassium dichromate(VI) from orange to green
UCLES 2009
5070/03/M/J/09

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Paper 3 Practical Test

As listed in the Confidential Instructions

READ THESE INSTRUCTIONS FIRST

For Examiners Use

This document consists of 7 printed pages and 1 blank page.

Vinegar is an acidic aqueous solution.

Solution Q is 0.100mol/dm3 sodium hydroxide.

(a) Put P into the burette.

final reading / cm3

Tick (3) the best titration results.

Using these results, the average volume of P required was ...............cm3.

Volume of solution Q used was ......................cm3.

(b) Q is 0.100mol/dm3 sodium hydroxide.

moles of hydrogen ions in 1.00dm3 of P ......................................

moles of hydrogen ions in 150cm3 of vinegar ......................................

mass of ethanoic acid present in 150cm3 of vinegar ...............g

percentage by mass of ethanoic acid in vinegar ...............

(a) To a portion of solution R, add

(b) Add excess aqueous sodium

(a) To a portion of solution R, add

(b) Add excess aqueous ammonia to

(a) To a portion of solution R, add an

(b) Add aqueous silver nitrate to the

(a) To a portion of solution R, add an

(b) Add aqueous barium nitrate

To a portion of dilute hydrochloric acid

(b) To a portion of dilute hydrochloric

To a portion of aqueous copper(II)

Put 1cm depth of solid S in a hard-glass

(a) Dissolve a small amount of solid S

(b) Warm the mixture from (a).

Identify the anion in R.

add dilute acid

effervescence, carbon dioxide

acidify with dilute nitric acid, then add

acidify with dilute nitric acid, then add

add aqueous sodium hydroxide, then

sulfate (SO 42)

acidify with dilute nitric acid, then add

Tests for aqueous cations

effect of aqueous sodium hydroxide

effect of aqueous ammonia

aluminium (Al 3+)

white ppt., soluble in excess giving a

white ppt., insoluble in excess

ammonia produced on warming

white ppt., insoluble in excess

no ppt., or very slight white ppt.

copper (Cu 2+)

light blue ppt., insoluble in excess

light blue ppt., soluble in excess

iron(II) (Fe 2+)

green ppt., insoluble in excess

green ppt., insoluble in excess

red-brown ppt., insoluble in excess

red-brown ppt., insoluble in excess

white ppt., soluble in excess giving

white ppt., soluble in excess giving

Paper 3 Practical Test

moles of hydrogen ions in 1.00dm3 of P ......................................

moles of hydrogen ions in 150cm3 of vinegar ......................................

mass of ethanoic acid present in 150cm3 of vinegar ...............g

percentage by mass of ethanoic acid in vinegar ...............