Chemistry: University of Cambridge International Examinations General Certificate of Education Ordinary Level

This document consists of 8 printed pages.
SJF3671 T11532/2
UCLES 2006 [Turn over
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
General Certificate of Education Ordinary Level
CHEMISTRY 5070/03
Paper 3 Practical Test
October/November 2006
1 hour 30 minutes
Candidates answer on the Question Paper.
Additional Materials: As listed in the Instructions to Supervisors.
READ THESE INSTRUCTIONS FIRST
Write your Centre number, candidate number and name on all the work you hand in.
Write in dark blue or black pen.
You may use a pencil for any diagrams, graphs or rough work.
Do not use staples, paper clips, highlighters, glue or correction fluid.
Answer all questions.
Qualitative analysis notes are printed on page 8.
You should show the essential steps in any calculation and record experimental results in the spaces
provided on the question paper.
At the end of the examination, fasten your work securely together.
The number of marks is given in brackets [ ] at the end of each question or part question.
Centre Number Candidate Number Name
For Examiners Use
1
2
TOTAL
2
5070/03/O/N/06
1 Hydrogen peroxide, H
2
O
2
, is a widely used bleach.
Solution P is acidified hydrogen peroxide and you are to determine its concentration by
titrating it with potassium manganate(VII).
No indicator is necessary since the products of the reaction are almost colourless and one
drop of potassium manganate(VII) in excess produces an easily seen pale pink colour.
Solution Q is 0.0200 mol/dm
3
potassium manganate(VII), KMnO
4
.
(a) Fill the burette with solution Q. Because the colour of Q is so intense, you may find it
easier to read the top of the meniscus.
Pipette a 25.0 cm
3
(or 20.0 cm
3
) portion of P into a flask and titrate with Q. At first the
purple colour disappears rapidly. As the titration proceeds, this disappearance is less
rapid. At the end-point, one drop of Q produces a pink colour that does not disappear
on swirling.
Record your results in the table, repeating the titration as many times as you consider
necessary to achieve consistent results.
Results
Burette readings
Summary
Tick () the best titration results.
Using these results, the average volume of Q required was cm
3
.
Volume of P used was cm
3
. [12]
For
Examiners
Use
UCLES 2006
titration number 1 2
final reading / cm
3
initial reading / cm
3
volume of Q used / cm
3
best titration results ()
3
5070/03/O/N/06 [Turn over
(b) Q is 0.0200 mol/dm
3
potassium manganate(VII).
Five moles of hydrogen peroxide react with two moles of potassium manganate(VII).
Using your results from (a), calculate the concentration, in mol/dm
3
, of the hydrogen
peroxide in P.
Concentration of hydrogen peroxide in P is mol/dm
3
. [2]
For
Examiners
Use
UCLES 2006
4
5070/03/O/N/06
2 R and S are solutions of two sodium salts. Carry out the following tests and record your
observations in the table. You should test and name, where possible, any gases evolved.
After testing the gases, discard the mixtures and wash out the test-tubes. You are not
expected to identify R and S.
Tests on R
For
Examiners
Use
UCLES 2006
test
no.
1
2
3
test
To a portion of R, add a few drops of
concentrated hydrochloric acid and
warm the mixture gently.
To a portion of acidified aqueous
potassium manganate(VII), add an equal
volume of R.
(a) To a portion of R, add a few drops
of aqueous potassium iodide.
(b) Carefully add an equal volume of
dilute hydrochloric acid to the
mixture from (a).
observations
5
5070/03/O/N/06 [Turn over
[13]
For
Examiners
Use
UCLES 2006
test
no.
4
test
(a) To a portion of R, add an equal
volume of aqueous iron(II)
sulphate.
5 To a portion of R, add an equal volume of
aqueous sodium hydroxide and a piece
of aluminium foil. Warm the mixture
gently.
(b) Warm the mixture from (a) gently.
(c) When no further reaction takes
place, allow the mixture from (b) to
cool. Then, to a portion of this
mixture, add aqueous sodium
hydroxide until a change is seen.
observations
6
5070/03/O/N/06
Tests on S
[10]
For
Examiners
Use
UCLES 2006
test
no.
6
test
To a portion of acidified aqueous
potassium manganate(VII), add an equal
volume of S.
observations
7
8
9
To a portion of S, add a few drops of
aqueous potassium iodide.
(a) To a portion of S, add an equal
volume of aqueous barium nitrate.
(a) To a small portion of aqueous
iron(III) chloride, add three times
the volume of S. Divide this mixture
into two portions.
(c) To the other portion of the mixture
from (a), add an equal volume of
dilute hydrochloric acid and warm
gently. Allow this mixture to cool
and then add aqueous sodium
hydroxide until a change is seen.
(b) Add dilute hydrochloric acid to the
mixture from (a).
(b) Warm one of the portions of the
mixture from (a) gently.
7
5070/03/O/N/06
Conclusions
Substances can be classified as only oxidising agents, only reducing agents, both oxidising and
reducing agents or neither oxidising nor reducing agents. Using your results, tick the appropriate
box to classify R and the appropriate box to classify S.
An element present in the anion in R is [3]
For
Examiners
Use
UCLES 2006
only an oxidising agent
R S
only a reducing agent
both an oxidising agent and a reducing agent
neither an oxidising agent nor a reducing agent
8
5070/03/O/N/06
NOTES FOR USE IN QUALITATIVE ANALYSIS
Tests for anions
Tests for aqueous cations
Tests for gases
UCLES 2006
anion
cation
gas test and test result
turns damp red litmus paper blue
turns limewater milky
bleaches damp litmus paper
pops with a lighted splint
relights a glowing splint
turns aqueous potassium dichromate(VI) from orange to green
ammonia (NH
3
)
carbon dioxide (CO
2
)
chlorine (Cl
2
)
hydrogen (H
2
)
oxygen (O
2
)
sulphur dioxide (SO
2
)
effect of aqueous sodium hydroxide effect of aqueous ammonia
white ppt., soluble in excess giving a
colourless solution
white ppt., insoluble in excess
ammonia produced on warming
white ppt., insoluble in excess no ppt. or very slight white ppt.
light blue ppt., insoluble in excess light blue ppt., soluble in excess giving
a dark blue solution
green ppt., insoluble in excess green ppt., insoluble in excess
red-brown ppt., insoluble in excess red-brown ppt., insoluble in excess
colourless solution
colourless solution
aluminium (Al
3
+
)
ammonium (NH
4
+
)
calcium (Ca
2
+
)
copper(II) (Cu
2
+
)
iron(II) (Fe
2
+
)
iron(III) (Fe
3
+
)
zinc (Zn
2
+
)
carbonate (CO
2
3
)
chloride (Cl
)
[in solution]
iodide (I
)
[in solution]
nitrate (NO
3
)
[in solution]
sulphate (SO
2
4
)
[in solution]
test
add dilute acid
acidify with dilute nitric acid, then add
aqueous silver nitrate
aqueous lead(II) nitrate
add aqueous sodium hydroxide then
aluminium foil; warm carefully
aqueous barium nitrate
test result
effervescence, carbon dioxide
produced
white ppt.
yellow ppt.
ammonia produced
white ppt.
Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.
University of Cambridge International Examinations is part of the University of Cambridge Local Examinations Syndicate (UCLES), which is itself a department of
the University of Cambridge.

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