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SP (SJF3292) S77886/4
UCLES 2005 [Turn over
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
General Certificate of Education Ordinary Level
CHEMISTRY 5070/03
Paper 3 Practical Test
May/June 2005
1 hour 30 minutes
Candidates answer on the Question Paper.
Additional Materials: As listed in the Instructions to Supervisors.
READ THESE INSTRUCTIONS FIRST
Write your Centre number, candidate number and name in the spaces at the top of this page.
Write in dark blue or black pen in the spaces provided on the Question Paper.
You may use a pencil for any diagrams, graphs or rough work.
Do not use staples, paper clips, highlighters, glue or correction fluid.
You may use a calculator.
Answer all questions.
The number of marks is given in brackets [ ] at the end of each question or part question.
Qualitative analysis notes are printed on page 8.
You should show the essential steps in any calculation and record experimental results in the spaces
provided on the question paper.
Centre Number Candidate Number Name
For Examiners Use
1
2
TOTAL
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2
5070/03/M/J/05
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3
5070/03/M/J/05 [Turn over
For
Examiners
Use
UCLES 2005
1 P is a solution of hydrochloric acid (HCl) of unknown concentration. You are to determine its
concentration by titrating it against solution Q, which is 0.100 mol/dm
3
sodium hydroxide.
(a) Determination of the concentration of the acid in P
Put P into the burette.
Pipette a 25.0 cm
3
(or 20.0 cm
3
) portion of Q into a flask and titrate with P, using the
indicator provided.
Record your results in the table, repeating the titration as many times as you consider
necessary to achieve consistent results.
Results
Burette readings
Summary
Tick () the best titration results.
Using these results, the average volume of P required was cm
3
.
Volume of solution Q used cm
3
. [12]
(b) Q is 0.100 mol/dm
3
sodium hydroxide.
Using your results from (a), calculate the concentration, in mol/dm
3
, of the hydrochloric
acid in P.
Concentration of hydrochloric acid in P......................... mol/dm
3
. [2]
Titration number 1 2
Final reading / cm
3
Initial reading / cm
3
Volume of P used / cm
3
Best titration results ()
4
5070/03/M/J/05
For
Examiners
Use
UCLES 2005 5070/03/M/J/05
2 You are provided with solutions of two sodium salts, R and S. Carry out the following tests
and record your observations in the table. You should test and name any gas evolved.
Tests on Solution R
[15]
Test
no.
1
2
Test
(a) To a portion of solution R, add an
equal volume of dilute
hydrochloric acid and allow the
mixture to stand for a few
minutes.
To a portion of acidified potassium
manganate(VII), add an equal volume
of solution R and allow the mixture to
stand for a few minutes.
3
4
To a portion of aqueous silver nitrate,
add an equal volume of solution R and
leave to stand until no further change
is seen.
(a) To a portion of solution R, add an
equal volume of aqueous lead(II)
nitrate.
(b) Add dilute nitric acid to the
mixture from (a).
(b) Warm the mixture from (a) gently.
Observations
5
5070/03/M/J/05
For
Examiners
Use
UCLES 2005
Tests on Solution S
[9]
Conclusion
Give the formula of the anion (negative ion) present in S
In Test 5, S is acting as a .. and R is acting as
a .. [2]
Test
no.
5
6
Test
(a) To a portion of acidified potassium
manganate(VII), add an equal
volume of solution S.
To a portion of aqueous silver nitrate,
add an equal volume of solution S.
7 (a) To a portion of solution S, add an
equal volume of aqueous lead(II)
nitrate.
(b) Add dilute nitric acid to the mixture
from (a).
(c) Transfer a portion of the mixture
from (b) to a boiling tube, add an
equal volume of water and heat
carefully until the mixture just
boils. Allow to cool.
(b) To a portion of the mixture from
(a), add an equal volume of
solution R and allow the mixture
to stand for a few minutes.
Observations
6
5070/03/M/J/05
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5070/03/M/J/05
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5070/03/M/J/05
NOTES FOR USE IN QUALITATIVE ANALYSIS
Tests for anions
Tests for aqueous cations
Tests for gases
UCLES 2005
anion
cation
gas test and test result
turns damp red litmus paper blue
turns limewater milky
bleaches damp litmus paper
pops with a lighted splint
relights a glowing splint
turns aqueous potassium dichromate(VI) from orange to green
ammonia (NH
3
)
carbon dioxide (CO
2
)
chlorine (Cl
2
)
hydrogen (H
2
)
oxygen (O
2
)
sulphur dioxide (SO
2
)
effect of aqueous sodium hydroxide effect of aqueous ammonia
white ppt., soluble in excess giving a
colourless solution
white ppt., insoluble in excess
ammonia produced on warming
white ppt., insoluble in excess no ppt. or very slight white ppt.
light blue ppt., insoluble in excess light blue ppt., soluble in excess giving
a dark blue solution
green ppt., insoluble in excess green ppt., insoluble in excess
red-brown ppt., insoluble in excess red-brown ppt., insoluble in excess
white ppt., soluble in excess giving a
colourless solution
white ppt., soluble in excess giving a
colourless solution
aluminium (Al
3
+
)
ammonium (NH
4
+
)
calcium (Ca
2
+
)
copper(II) (Cu
2
+
)
iron(II) (Fe
2
+
)
iron(III) (Fe
3
+
)
zinc (Zn
2
+
)
carbonate (CO
2
3

)
chloride (Cl

)
[in solution]
iodide (I

)
[in solution]
nitrate (NO
3

)
[in solution]
sulphate (SO
2
4

)
[in solution]
test
add dilute acid
acidify with dilute nitric acid, then add
aqueous silver nitrate
acidify with dilute nitric acid, then add
aqueous lead(II) nitrate
add aqueous sodium hydroxide then
aluminium foil; warm carefully
acidify with dilute nitric acid, then add
aqueous barium nitrate
test result
effervescence, carbon dioxide
produced
white ppt.
yellow ppt.
ammonia produced
white ppt.
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