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SRI CHAITANYA IIT ACADEMY, INDIA 16‐12‐23_ Sr.Super60_NUCLEUS&STERLING_BT _Jee‐Main_RPTM‐19_KEY &SOL’S

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60_NUCLEUS&STERLING_BT JEE-MAIN Date: 16-12-2023
Time: 09.00Am to 12.00Pm RPTM-19 Max. Marks: 300
KEY SHEET
PHYSICS
1) 1 2) 3 3) 4 4) 1 5) 1
6) 3 7) 1 8) 1 9) 1 10) 1
11) 2 12) 2 13) 4 14) 1 15) 3
16) 4 17) 3 18) 2 19) 1 20) 2
21) 2 22) 2 23) 2 24) 1000 25) 500
26) 3 27) 5 28) 4 29) 5 30) 100

CHEMISTRY
31) 3 32) 3 33) 4 34) 4 35) 3
36) 1 37) 3 38) 2 39) 1 40) 4
41) 1 42) 2 43) 2 44) 1 45) 3
46) 4 47) 1 48) 3 49) 3 50) 1
51) 10 52) 6 53) 39 54) 4 55) 6
56) 6930 57) 7 58) 4 59) 6 60) 4

MATHEMATICS
61) 1 62) 2 63) 2 64) 1 65) 2
66) 3 67) 2 68) 3 69) 4 70) 1
71) 4 72) 1 73) 2 74) 4 75) 3
76) 2 77) 1 78) 4 79) 3 80) 4
81) 1 82) 0 83) 2 84) 1 85) 29
86) 1 87) 8 88) 4 89) 8 90) 21

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SOLUTIONS
PHYSICS
1. Conceptual
Z  R 2  X C2  1002  1002  100 2
2.
Vmax
 id max 
z =2.2A
c 3 108 3 108
3. v    1.8 108 ms 1
r  r 1.2  2.14 1.67
4. Speed of an e.m. wave in a medium is given by
1 1 1 1 c
v   
  r  0 r  0  0 0 r  r r  r
c2
 v2 
r  r
Hence relative permeability,
r  1
5. Here , u= -25cm, f= -10cm
1 1 1
 
As u v f
1 1 1 1 1 5  2 3
     
v f u 10 25 50 50
50
v
Or 3
v 50 2 side of image of wire (h 2 )
m  
Now u 3  25 3 = side of square wire (h1 )
2 2
h    h1    3  2cm
Side of image of wire, 2 3 3

Area enclosed by the image of wire= (2)  4cm

2 2

1
6. I   0 E 2 rms C Erms  275V / m
2

P' p' 10
7. I1  I 2   p'   110  11W
4 r1 4 r2 2
2
100

I0
I1  cos 2  
8. 2
h
0 
9. mv0

 F h
a   v  v0  at  
m mv
hc 1 hc
min   .
10. In x-ray tube eV V e

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16‐12‐23_ Sr.Super60_NUCLEUS&STERLING_BT _Jee‐Main_RPTM‐19_KEY &SOL’S

log min   log V  log

e
11.
sin r
Slope of the graph, tan  
sin i
sin i v1 v1 sin i
    cot 
sin r v2 v2 sin r
12. Energy flux  18W cm 2  18 Js 1cm 2
Area=20 cm 2 Time=30 min =1800s
Total energy falling on the surface
2
u  Energy flux  time  area =(18Js 1cm 2 )  1800 s  20cm  6.48  10 5 J
the total momentum delivered to the surface,
u 6.48  105 J
P  =2.16 103 kgms 
c 3  108 ms 1
The average force exerted on the surface ,
P 2.16  103
F=    1.2 106 N
t 1800
In case , the surface is a perfect reflector, the change of momentum =p-(-p)=2p
And F  2  1.2  106  2.4  10 6 N
13. Maximum electric field , E0  270Vm1
E0 270
Maximum magnetic field, B0    9  10 7 T ,
c 3  108
Directed along z-direction, Maximum electric force on the electron,
Fe  qE0  1.6 1019  270  4.32 1017  2.88  10 18 N
14. Here, ni  1.5 1016 m3
Doping concentration of pentavalent as atoms =1ppm=1part per million
5  10 28
 number of pentavalent As atoms, N D  6
 5 1022 atom m 3
10
Now the thermally generated electrons ( ni1016 m3) are negligibly small as compared to
2
those produced by doping ,so ne  N D  5 1022 m3 also n e nh  ni
ni 2 1.5  10161.5  1016
nh    4.5  109 m 3 .
ne 5  1022
V
15. The forward bias diode resistance is given by rfb 
I
Where V and I Are the small changes in the voltage and current near the desired values.
(2.2  1.8)V 0.4V
rfb (at  2V )    20
(80  60)mA 20  103 A
(1.2  0.8)V 0.4V
rfb (at  1V )    40
(20  10)mA 10  103 A

16.

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A A.B
16‐12‐23_ Sr.Super60_NUCLEUS&STERLING_BT _Jee‐Main_RPTM‐19_KEY &SOL’S

B
A.B  A  B

B A.B

17.
1

1

2 1
i  A
1  10  1 6
18. Conceptual
19. Charge an element of length dx of wire AB dq   dx  kx dx
l
Total charge on wire AB q   dq   kx dx  1 kl 2
0
2
Q
Total flux through S1 = S1  1 
0
1
Q  kl 2
Qq 2
Total flux through S2  2  
0 0
20. When key K is in contact with terminal A, the condenser gets charged. Energy stored in
1
condenser U  CV 2  10 J . When key K is in contact with terminal B, the entire
2
energy stored is a dissipated as heat energy. 500, 330 are in series. Heat produced in
500
the ratio 500:330.  heat produced in 500   10  6.024 J
500  330
21. Total emf of 3 cells in series  3  = potential difference corresponding to 0 current.
  6V or   2V
    
22. B  Bab  Bbcd  Bbed  Bdf
H 120 72
23. i   2A n
n 60 1.2
0 N 2 A N2A L 
24. L0  and L      r  100
l l L0 0
25. The voltage across resistance will be maximum when
X L  X C   frequency = 500 Hz.
a 1  p 2 
On comparing y   tan   x   2 2  x 2
g
26.  u , x y 3
 2u cos   2q
27.

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16‐12‐23_ Sr.Super60_NUCLEUS&STERLING_BT _Jee‐Main_RPTM‐19_KEY &SOL’S

28.

29.

30. In full wave rectifier input frequency is f,then output frequency is 2f

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CHEMISTRY
31. Let atomic weight of other isotope is M
114.89  96  M  4
114.89=  M  113.14
100
32. Cx H y Clz Ow  O2  CO2  H 2O
41.21
Millimoles of C 
44
5.63
Millimoles of H  2
18
57.13
29.72 mg of dieldrin contains  29.72mg of AgCl
25.31
57.13  29.72
Millimoles of Cl 
25.31 143.5
57.13  29.72  35.5 
Weight of O  29.72  
41.21 5.63
 12   2 1 
 44 18 25.31 143.5 
Weight of O  29.72  11.239  0.6255  16.59
Weight of oxygen =1.265 mg
41.21 41.21 16
nC     1184  12
44 44 1.265
5.63 5.63 16
nH     7.9  8
9 9 1.265
1.265 1.265 16
nO    1
16 16 1.265
57.13  29.72 57.13  29.72
nCl     5.95  6
25.31143.5 25.31 143.5
33. Bond energy of Cl2  F2
34. A) 0.5 mole of SO2  g   32 g
Weight =1.5 N A atoms
= 11.2L at 1 atm and 273 K
B) 1 g of H 2  g   0.5 mole
H 2  11.2L at 1 atm and 273 K  N A atoms
C) 0.5 moles of O3  1.5N A atoms  11.2L at 1
Atm and 273K  24 g weight
D) 1 g molecules of O2  1 mole of O2  2 N A
Atom=22.4L at 1 atm. And 273K  32 g weight.
35. Conceptual
36. 1 mole  NH 4 3 PO4 =12 mole H-atoms=4 mole O-atoms
6 mole H-atoms= 1 mole O-atoms
37. Relative atomic mass of nitrogen is 14.
38. Equivalent volume of hydrogen is 11.2 liters.
1 mole of hydrogen is produced.
39. 64 amu of S 2  3S 2 ions
Charge on 2S 2 ions  2  charge of 2 electrons  2  2  1.6  10 19  6.4  10 19
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16‐12‐23_ Sr.Super60_NUCLEUS&STERLING_BT _Jee‐Main_RPTM‐19_KEY &SOL’S

40. Mn   100  64  x  1.93

55  16 x
41. Mass of a drop of water = 0.0018g
0.0018
Moles of water =  104 mole
18
Number of water molecules in one drop  104 N A
Number of water molecule in ten drops  10 104  N A  103
1.3673
42. m  113 1  x  32  113 x  80
0.0121
OH OH
Cl H
 H 2O +
S
43.
R

96% recemisation means 48% R and 48% S and 4% inversion (s) taken place.
44.
Br CH 3 CH 3
Br Br
CH 3 MgBr
 CH 2  C  O 
 CH  C  O
CH 3 MgBr
CH 2  C  O 
Br2
 MgBr2
Br  CH  C  CH 3

OMgBr

MgBr2

45. If carbonyl compound contains acid sensitive group then clemmesen’s readuction is not
used.
46. Idoform test is not given by NH4OH and not all compounds with CH 3CH  OH   . Can give
iodoform test.
47. Gem dicarboxylic acid and   keto acids give out CO2 easily.
48.
Cl  a   Mn  N 1
1
N Cl  a   Mn  N  2 

a Cl N  2 Cl  a   Mn  N  4 
Mn Cis
Cl  b   Mn  N  4 
N  3
b Cl
Cl  b   Mn  N  3
N
 4 Cl  b   Mb  N 1

 X  6, Y  2; X Y  4
49. Para magnetic behavior is given wrong order.
VH X Z /n 1/ 2 6 2x
50.   H H    1.5   2  1.5  3
VHe Y Z He / nHe 2 / 6 4 y
51. The ppt reaction is Fe3  3NH 3  3H 2O  Fe  OH 3  3NH 4
1.6  0.5
Moles of Fe2O3   5  103
160
0.986  1000  5
Moles of Fe 3  2  5  103  104 M NH   2.9
3
17  100
3  104
3  nFe3  1 nNH3  2.9  v  lit   v  1 104 lit  10ml
2.9

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52. CO2  0.5mol of CO2  2mole of C.
H 2O  1mol of H 2O  2mol of H
Mass of C + Mass of H + Mass of O =22
12+2+x=22  x  8
x y 24
So molecular formula = C2 H 4O  6
z 1
40  10
53. %Ca   100  38.83 approximately 39.
1030
54. i,iii,vi,v are correct order.
i) Electron with drawing more the stability
ii) More hyper conjugations more the staibility
iii) Smaller the ring size more the acidic nature EWG  acidic nature
iv) Heat of hydrogen equation  no. of  obonds.
v) More inter molecular H-bonding more the B-P
vi) Resonance energy  conjuation.
x y 24
55. x  2; y  4; 2  2   3
z 2
x  i, viii : y  i, iv, vi, viii; z  iii, vii
0.693 a 2K1 0.6931
56. K1  K2     30  0.693  693  104
30 2t112 2  30 30
K2 30
0.0591 0.0591 10
57. ECl0  / AgCl / Ag  E Ag
0
 
/ Ag
0.209  0.80 
log K SP log K SP KSP  10
1 1
Let solubility of AgCl in 0.01M solution is y then 1010  y  y  0.01  y  108
 moles of AgCl dissolved in 10 L  10 8  10  10 7
58. P  PA0  X B  PB0  PA0 
1
80 
1 20  4
99  100  X B  80  100   X B   YB 
20 99 99
4
% moles of B in vapour phase =  100  4
49
T T  wTotal 500  350  wtotal
59.  2 1 
T2 q2 500 10
Work done in one cycle =3, in two cycles = 2  3  6
60. Concept of simultaneous solubility
80% AgCl  AgBr AgCl  Ag   Cl 
(0.01-9) (a+b) a …….(1)
AgBr  Ag   Br 
0.08 (a+b) b ………(2)
K sp AgCl  a  b  a 10 10 a 1000
     250  a  250b
K sp AgBr  a  b  b 4  1013 b 4
Substitute a in 2 eq., for Br  conc.,
 a  b  b  4 1013  250b  b  b  4 1013 250b 2  b 2  4  10 13 251b 2  4  10 13
b 2  15.936  10 16  b  3.99  108 So b  4  108

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MATHEMATICS
  
A= 3sin 1 
6 1  6 
61.   3sin    3.   A 
 11   12  6 2 2
4 4 
B  3cos 1    3cos 1    3.  
9 8 3
3
B   , A+B>
2
 sin B  0, cos(A+B)>0
62. n1  20, 1  5, x1  17, n2  20,  2  5, x2  22
n1 12  n2 22 n1n2  x1  x2 
2

 
n1  n2  n1  n2 
2

x2 1
63.  1
x 1
2
1  x2
x2 1  x
2
 
0 2  1  0  sin  2  
x 1  x 1  2
 x2 
 0  2sin  2   
1

 x 1
64. 8sin 20 sin 400 sin 800
0

1  1 3
 8  .sin 60   8. .  3
4  4 2
cos  1  cos 2
65. cot   
sin  sin 2
  3 1
1  cos   1 
   12   2 2
cot   
 24  
  3 1
sin  
 
12 2 2
 6 2 3 2
1
66. Tan 1      cot 1 ( x), x  0
x
 6y   6 y  2
Tan 1  2 
   Tan 1  2 

9 y  9 y  3
 6y  
2Tan 1  2 

9 y  3
 6y  1
 2 

9 y  3
y2  6 3 y  9  0
y 3 3 6
67. AM  GM
sin x  cos x 1
2sin x  2cos x 
2 2
2 2
2
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 
 cos 1 x    1
  
68.  , now sin    sin  
 sin x      1 
1

  
sin 1[2sin 1 x]  2 x 1  x 2
     
69. sin 1  sin   cos 1   cos   tan 1  tan 
 3  6  4
     17
        
3 6 4 6 4 12
1
70. Let Tan    Cot  2
2
 1  1 
71. Tan Tan 1    2 tan 1   
 2  3 
1 3

 1  1  1  3   2 4  10  2
Tan Tan    tan    
 2  4  1 3 5
1
24
72. x* y  x  y
2 3

x * y *1  ( x 2  1) *1  ( x 2  1)2  1  x 4  2 x 2  2
x * (1*1)  x * (1  1)  x * 2  x 2  8  x 4  2 x 2  2  x 2  8
x4  x2  6
 62 1  1  
5sin 1    5sin    5
62 2 6
73. ( A)  3   3C , 2  3C 2   150
5 5

( B)   5  3  2  C2  6
150
(C )   25
3!
( D)  2 1,1,3and1, 2, 2 
dx dy 1  2  
75. x x 12

y y 1
2
 sec 1 x  sec 1 y  c so, sec 
 3
cc  6

  1
 y = sec  sec1 x   
 6  1 
cos cos 1  
 x 6
1

1 3 1 1
 1 2
x 2 x 2
1
1 2
1 3 x
  
y 2x 2
sin x
76.  x dx can not be evaluated as there does not exists any method for evaluating this.
sin x
However is differentiable function
x

Sec: Sr.Super60_ NUCLEUS&STERLING_BT Page 10

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 /4  /4
16‐12‐23_ Sr.Super60_NUCLEUS&STERLING_BT _Jee‐Main_RPTM‐19_KEY &SOL’S
1
77.   tan x  tan n  2 x dx   tan
n2
I n  I n2  n
x sec n x dx=
0 0
n 1
1
 In 2  I n 
n 1
 
tan n 2 x  tan n x  tan n2 x for x   0, 
 4
 /4  /4  /4

 tan n  2 x dx <   tan

n2
tan n x dx < x dx
0 0 0

1 1
I n 2  I n  2 I n  I n  I n2  2In 
n 1 n 1
10 9 8
  10Cr2  210Cr 10Cr 1  2 10Cr 10Cr  2
78. No. of favourable ways r 1 r 1 r 1

(difference0) (difference1) (difference2)

10C10  1  2  20C11  10   2  20C8  10C2 
 20C10  2  20C11  20C12   111
1 1
BBT   I  A I  A  I  A   I  A   I  A I  A  I  A   I  A
1 1
79.
T T T
   
1
  I  A  I  A   I  A    I  A  =I
1

Z1  Z3 Z  Z4
80.  1, 2 1  Z1  Z 2  Z3  Z4  4
2 2
cos( A  B ) cos( A  B )  1 1 
81.   2 cos( A  B )  
cos B sin B sin A cos A  Sin 2 B sin 2 A 
4 cos( A  B)[2sin( A  B) cos( A  B )] 8cos( A  B ) sin( A  B ) cos( A  B)
 
cos 2( A  B )  cos 2( A  B) 2 cos 2 ( A  B )  1  1  2sin 2 ( A  B )
4 1
4. .
4 cos 2 ( A  B) sin( A  B ) 9 3 4 16
       [ ]  1
cos ( A  B)  sin ( A  B)  1 4  1  1
2 2
3 4
9 9
82. cos B[2  cos A]  1  2 cos A
1  2 cos A cos B  1 3(1  cos A)
cos B  
2  cos A cos B  1 cos A  1
1  cos B 3(1  cos A) B A A B
   cot 2  3cot 2  Tan 2  3Tan 2
1  cos B 1  cos A 2 2 2 2
   k    ( k  1)  
2sin      
13
 4 6   4 6  
83.    k    ( k  1) 
K 1
sin    sin   
4 6  4 6 
    k 
= 2 cot   (k  1)   cot    
13

k 1  4 6  4 6 
   13    5 
= 2 cot  cot   
   2  cot  cot  = 2 1  (2  3)   2  3  1
 4 4 6   4 12 
3r 1 1
84. x  3  r  pB  sin 30   r 
3r 2 3

Sec: Sr.Super60_ NUCLEUS&STERLING_BT Page 11

 Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA
A
16‐12‐23_ Sr.Super60_NUCLEUS&STERLING_BT _Jee‐Main_RPTM‐19_KEY &SOL’S

3 3

p 300

B C
3

 1  1 
85. 50Tan  Tan 1   4 2  
 2  2
 25  4
 29
 sin x  1  sin x 
86. tan 1    sin  
 cos 2 x   sin x  cos 2 x 
2

 sin x  1  sin x 
 sin 1    sin    f ( x)  sin[sin 1 (tan x)]  Tanx
2
 cos x   cos x 
d [ f ( x)]
1
d (Tanx)
4 2 . 2sin 2 x cos x
87. lt
 3 x 5x 3x
x
2 2sin 2 x sin  cos  cos  2 1  cos 2 x 
2 2 2
8 2.2sin 2 x cos x
lt
 3x x
x
2 2sin 2 x sin  2sin 2 x sin  2 .2cos 2 x
2 2
8 2 sin 2 x cos x
lt
x
  3x x
2 2sin 2 x sin  sin   2 2cos 2 x
 2 2
16 2 sin x cos 2 x
lt
x
  x 
2 2sin x cos x  2sin cos x   2 2cos 2 x
 2 
16 2 sin x 16 2
lt  8
x

2 8sin x sin
x
 2 2 4 2  2 2
2
r2
log 3  
 r 1    1 
160 160
1
88. 
r 1 log 3
 r 1    
.log 3 r  2 r 1  log 3 r 1 log 3 r  2 
1 1 4
  
2
log 3 log 3 162
 log 3  log 32 
162

89. A2  2 AB  BA  2 B 2  0
 A  B  A  2 B   0 A  2 B  0
1
AB  2 I AB 1  8
90.  7  1   7  1  49  21
2007 2007
 49 K  2007  7  2

Sec: Sr.Super60_ NUCLEUS&STERLING_BT Page 12