SRI

CHAITANYA IIT ACADEMY, INDIA 02‐04‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐32_KEY &SOL’S

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU    MAHARASTRA  DELHI    RANCHI 
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60_NUCLEUS &ALL_BT JEE-MAIN Date: 02-04-2023
Time: 09.00Am to 12.00Pm GTM-33 Max. Marks: 300
KEY SHEET
PHYSICS
1) 1 2) 4 3) 4 4) 3 5) 1
6) 3 7) 1 8) 4 9) 1 10) 2
11) 1 12) 1 13) 3 14) 4 15) 4
16) 3 17) 4 18) 3 19) 4 20) 3
21) 4 22) 5 23) 1 24) 4 25) 2
26) 7 27) 4 28) 3 29) 5 30) 5

CHEMISTRY
31) 1 32) 1 33) 4 34) 4 35) 1
36) 2 37) 1 38) 1 39) 3 40) 4
41) 3 42) 1 43) 1 44) 3 45) 1
46) 1 47) 2 48) 2 49) 2 50) 3
51) 4 52) 4 53) 36 54) 9 55) 9
56) 500 57) 25 58) 2 59) 6 60) 22

MATHEMATICS
61) 2 62) 3 63) 2 64) 1 65) 1
66) 1 67) 3 68) 1 69) 1 70) 1
71) 1 72) 4 73) 1 74) 2 75) 3
76) 4 77) 1 78) 1 79) 3 80) 1
81) 71 82) 5 83) 9 84) 0 85) 12
86) 2000 87) 24 88) 25 89) 128 90) 1

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 SRI CHAITANYA IIT ACADEMY, INDIA 02‐04‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐32_KEY &SOL’S

SOLUTIONS
PHYSICS
1 1 1 2 L
1.     Lp 
Lp L L L 2
1.8  104
Where L is inductance of each part,   0.9  104 H
2
L 0.9  104
 Lp    0.45  104 H
2 2
6 1 1 1 2
Resistance of each part, r   3 Now ,   
2 rp 3 3 3
L 0.45  104
Time constant of circuit,  p   3  105 s
rp 1.5
2. When the spherical conductors are connected by a conducting wire, charge is
redistributed and the spheres attain a common potential V.
1 QA 1  C AV  4 0 RA  V
 Intensity E A  or E A   
4 0 RA
2
4 0 RA2 4 0 RA2 RA
V E R 2R 2
Similarly EB   A  B  
RB EB RA R 1
3. If final temp is T
Cv  4T0  T   0 0 Cv T  T0 
PV0 0 PV
4 RT0 RT0
4T0  T 8T0
 T  T0 4T0  T  4T  4T0 8T0  5T T 
4 5
8
T0
Tf 2
Final pressure In left Pf  Pi  5 P0  P0
To 4To 5
8
T0
Force   0  0  A  0
8 8P 2 P 6P A
In right Pf  5 P0  P0 ,
To 5  5 5  5
A sin   B cos 
4. Z ; Dimensions of A and B would be same as two quantities can be added
A B
only when they have same dimensions. So from given equation, we can say that Z is
dimensionless.
5. The acceleration of ball during upward motion is g  a , where a is the acceleration due to
u
resistive force. The time of accent, t1  1
ga
v
The acceleration during descent g-a and time taken is t2  ......  2
ga
The time taken can also be written as
u2
2h ga u2
t2    t22  .......  3
ga ga  g  a g  a

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 SRI CHAITANYA IIT ACADEMY, INDIA 02‐04‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐32_KEY &SOL’S
t2 u
Dividing equation (3) by equation (1) and (2) 
t1 v
 v 
6. Let velocity of car  vn '  n   ...... i 
 v  vs 
 v  vs   v  vs 
n ''  n '   ......  ii  from (i) & (ii) n ''  n  
 v   v  vs 
n ''  v  vs  v
Now  2   2  v  vs  2v  2vs  3vs  v  vs 
n  v  vs  3
7.  A  B  vA  vB , wa  w  Vg   wa  A   wa  B
8.

0
B  2  2M  cos 60
4 d 3
 A  B   0.5 0.01 
9. Error in AB=     AB      0.25  0.075  0.08
 A B   2.5 0.10 
 AB   0.25  0.08 m
10.

mv
d 2qB 1 T m
sin        45, t  
r mv 2 8 4qB
q2
11.

b bx
tan   y  mx  c y  b
f f
12. For potential to be made zero both capacitor must have equal charge and positive plate of
one must be connected to –Ve plate of other
120C1  200C2
3C1  5C2
P  100 
13. ig  3   P  Vi ig  3  ig  1.36 A
V   200 
14. For process (2) U  0 (isothermal zero) so 1 & 2 options are wrong so 4th option correct
V
15. i  neAU d  neAe E  neAe
l
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 SRI CHAITANYA IIT ACADEMY, INDIA 02‐04‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐32_KEY &SOL’S
1.5  1016  1.6  1019  1 cm 2  0.14  2
  6.72  107 A
10 cm
16. Applying loop law to the outermost loop,
VBE  I B RB  Vcc  0
 VBE  5.5  10 5  5  105
 0.5V
bt ln 2 20
 A0
17. A  A0 e 2 m A  A0 e10 2 2
 A0 e  ln 2

2
18. f  f 2  f1  220 Hz. These many number of beats are formed but cannot be heard.
19. Applied emf e  e0 sin  t
1
L 
Produced current I  I0 sin  t    where tan   C
R

If    res then tan   0  0    current lags behind e. But in given graph, ‘I’ leads
2
ahead of e. So ‘1’ is wrong statement
20. WNC   TE 
If WNC  0, then TE  PE  KE is conserved. Work done by non conservative force can be +
ve or – ve or zero.
2
 3R 
21. I Ab  I disc  I plate  M  
 2
2
1 MR 2  3R  31
(From Parallel Axis Theorem) MR 2   M    MR 2
4 12  2 12
22.

V  20 V
  V  5  0  V  20  V  2 V  5  0
2 2
30 15 15  10 5
 4V  20  10  0  V   V,I   A  2I  5 A
4 2 2 2
23. 64   T  2 rl  r  10 m  1mm
4 3

power
24. F ('c'is speed of light)
c
60 F
F  2  107.Pressure =Force/area =
3  10 8
4 R 2
25. 20VSD  16MSD  5VSD  4MSD
1MSD 1mm
LC    2  101 mm
no.of divisions on vernier scale 5
2
 30 
10   
gT 2  20  9
26. l   m
4 2
4  10 16

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 SRI CHAITANYA IIT ACADEMY, INDIA 02‐04‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐32_KEY &SOL’S
l l l
g  4 2 2
 4 2 2
 4 2 N 2 2
T  t t
 
N
dg dl 2dt
 
g l t
 
 dg   10 3
1  2 1.6 20 
 g  100    2   10    
 9  30   9 3
  16  
61.6
 7
9
 9  108
27. V   1.5  108 m / s
k 6
C 3  108
Refractive index    K 
V 1.5  108
 K 4
1 hc
28. mu12    0 ______ 1
2 1
1 hc
mu22    0 ______  2
2 2
1240
1  2  496   0
 2 1240
 0
620
1240 1240  1 1 
  2 0    0   0  1240  
310 496  310 496 
x
 0  1.5ev   x  3ev
2
29. H  B / 0
ni  2  104
40  100i  2  104
20
i A  5A
4
dy
30.    1 t0 
D
D
y     1 t0  velocity of central maxima,
d
dy 2.4  104  2
v   2t  12 
dt 2  103
At t = 4 sec
v  4.8 m / s

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 SRI CHAITANYA IIT ACADEMY, INDIA 02‐04‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐32_KEY &SOL’S

CHEMISTRY
31. Alkali metal hydrides are ionic hydrides due to more difference in electronegativity. So
their fused hydrides can conduct electricity due to movement if ions in liquid state.
32. The intense blue colour is due to charge transfer between Fe(II) and Fe(III) in out but side
of the coordination sphere.
33. Oxidation states of Co in (A) is + 3, (B) is – 1 (C) is + 2 and (D) is 0.
34. Internal energy of CD molecule is less than AB since C – D bond distance is smaller tan
A–B
35. Quartz contain three dimensional diamond like structure in which all the atoms form
strong covalent with all the neighbouring atoms.
36.
O

HOS OOH

O
Contain four S – O and one O – O bonds
37. The coordination isomers of same complex compound have same coordination numbers
and have same empirial formula
38. Primary pollutants include ammonia, sulfur dioxide, nitrogen dioxide and carbon
monoxide. Secondary pollutants include ground-level ozone, acid rain and nutrient
enrichment compounds. So, the correct option is O3 .

39.
Nitriles are selectively reduced by DIBAL–H to imines followed by hydrolysis to
aldehydes similarly, esters are also reduced to aldehyde with DIBAL–H.
h
40. 
mv
According to Einstein’s theory of photoelectric effect :
1 2h  v  v0 
hv  hv0  KE hv  hv0  mv 2 2h  v  v0   mv 2  v2
2 m
1
h 1
v   v  v0  2  1
 1
 v  v0  2  v  v0  2
41.

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 SRI CHAITANYA IIT ACADEMY, INDIA 02‐04‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐32_KEY &SOL’S

42. STotal  C p ln
T1  T2   C ln
T1  T2 
p
2T1 2T2
43. Co  Vitamin B12
Zn  Carbonic anhydrase
Rh  Wilkinson catalyst
Mg  Chlorophyll
44.

45.

46. Formula of the compounds

No. of octahedral voids are equal to the number of atoms forming lattice
A occupy octahedral void i.e. 2/3 of them
B forms crystal lattice
A2/3 B  A2 B3
47. Electron withdrawing group enhances the rate of hydrolysis.
48.

49.   COCH 3 is present it will show both 2, 4-DNP & iodoform test. Due to steric inhibition
of resonance. I.P of ‘N’ is not involved in delocalization so coupling reaction will not
take place.
50. A2  g   B2  g  
  2 AB  g  ______ 1

K1

6 AB  g  
  3 A2  g   3B2  g  ______  2

K2

3
 1
Reaction(2) = - 3 × reaction (1)  K 2     K 2  K13
 K1 
51. H 2SO 4  H 2 NCONH 2  H 2 NSO 3 H
Sulphamic acid NH 2SO3H can react with nitrite ion liberating N 2 gas, so used to remove
from the mixture of NO 2 and NO 3 before testing for NO 3 by brown ring test.
H 2 NSO 2 OH  HNO 2  N 2  H 2SO 4  H 2 O

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 SRI CHAITANYA IIT ACADEMY, INDIA 02‐04‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐32_KEY &SOL’S
H2 NSO4OH  H2O  NH4 HSO4
can give ppt with BaCl2 .
NH4 HSO4
52. Antimony pentafluoride has also been used in the first discovered chemical reaction that
produced fluorine gas from fluoride compounds
4 SbF5  2 K 2 MnF6  4 KSbF6  2 MnF3  F2
Fe2O3  3CO  2 Fe  3CO2
53.
36 118
To get 118 gm of Fe we required 36 gm of CO
To get 118 tons of Fe we required 36 tons.
54.

55. H 2O  s   H 2O  l   H 2O  l   H 2O  g   H 2O  g 
1kg 1kg 1kg
at 273 k at 273 k at 373 k at 273 k at 383 k

S  S1  S 2  S3  S 4
334 373 2491 383
  4.2 ln   2 ln  9.267 kJ Kg 1 K 1
273 273 373 373
 2n  3
56. n1T1  n2T2 , n  300   n   T2 , 300  T2  T2  500 K
 5 5
57. Apply law of equivalence 25  N  30  0.1  2
30  0.2 6 1.2
N HCl    0.2 
25 5 5
1.2
For the 2nd titration  VHCl  30  0.2
5
6  5 30
VHCl    25 ml
1.2 1.2
58. 2A + B products 
Rate = K[A]x[B]y
r = K[A]x[B]y ______(i)
0.3 = K[A]x[B]y - - - - (1)
2.4 = K[2A]x[2B]y - - - - (2)
0.6 = K [2A]x[B]y - - - - (3)
From (1), (2) & (3)
x = 1, y = 2
Overall order = 2 + 1 = 3
Order w.r.t A = 1
Order w.r.t B = 2
59.

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 SRI CHAITANYA IIT ACADEMY, INDIA 02‐04‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐32_KEY &SOL’S

60.

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 SRI CHAITANYA IIT ACADEMY, INDIA 02‐04‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐32_KEY &SOL’S

MATHEMATICS
ln 2 ln 2

f "  x  dx f '  x  0  2  e2 x f '  x dx

ln 2
61. e   e
2 x 2 x

0 0

1  ln 2
  f '  ln 2  3  2 e 2 x f  x   2 e 2 x f  x  dx   13
4  0

62. Conceptual
63. Conceptual
64. The line can be written as y  mx and curve as x 2  y 2  4
Let C(h, k) be a point on the circles and A  3,1 be given point, then
h2 3

3

 h  3  2 3
k2
 m  k  3m  2
3
Now, this point (h, k) lies on the circle
 
2
 3  2 3   3m  2  4
2

9 2  12  12 3  9m 2 2  4  12m  4

 9 1  m 2  2  12   3  m  12  0

3 1  m 2  2  4   3m 40 
   
2
16 3  m  4  3 1  m 2  4  0

   
2
3  m  3 1  m2  0
2 3m  2m 2  0
2m 2  2 3m  0
m  0, 3  
65. Conceptual
2
abcd a 2  b2  c2  d 2
66.   
4 4
 8  e 2  16  e2 64  e2  16e  64  4e2
16 4
16
5e2  16e  0 0e
5
1 1 2 3 
67.  2e     .....   2eS
x  3! 5! 7! 

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 SRI CHAITANYA IIT ACADEMY, INDIA 02‐04‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐32_KEY &SOL’S

r 1   2  r  1  1 1   1 1 
S      
r 1  2  r  1 ! 2 r 1  2  r  1 ! 2 r 1   2  r  !  2  r  1 !
1 1 1 1 1  1 1 1 2 e
      .......   e1    2eS  1
2 2 ! 3 ! 4 ! 5 !  2 2 e x 2 e
ex sin 2 x 2 x sec 2 x 2
ex 2 cos 2 x 2 x sec 2 x 2 ex sin 2 x tan x 2
1
68.  '  x  ln 1  x cos x sin x   sin x cos x  ln 1  x cos x sin x
1  x
cos x 2
e 1
x
sin x 2
2 x sin x 2
e x
2 x cos x 2
cos x 2 ex  1 sin x 2
 B  2Cx  .....
1 2 0 1 0 0 1 0 0
Put x  0, B  0 1 0  1 0 1  0 1 0  0
1 0 0 1 0 0 0 1 0
69. Perfect square   100   1  9  excluding one
Perfect cubes  1001/3   1  3
Perfect 4th powers  1001/4   1  2
Perfect 5th powers  1001/5   1  1
Perfect 6th powers  1001/6   1  1
Now, perfect 4th powers have already been counted in perfect squares and perfect 6th
powers have been counted with perfect squares as well as with perfect cubes
Hence the total ways = 9 + 3 + 1 – 1 = 12
dV  t  K T  t 
2

70.   K T  t  V t   C
dt 2
KT 2
At t  0,V  I  C  I 
2
KT 2
 Scrap value V T   V  t  T   C  I 
2
  
71. OAB  APO   AP  BP  r cot and AB  2r cos .
2 2 2
  
 Perimeter of APB, L  2r  cot  cos 
 2 2

dL   
 r   cos ec 2  sin   0
dr  2 2
  2 
for all    ,  .
3 3 
 
 L is maximum when   and then OP  r cos ec  2r.
3 2
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 SRI CHAITANYA IIT ACADEMY, INDIA 02‐04‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐32_KEY &SOL’S
So, the co-ordinates of P are  2r cos 45, 2r sin 45 .
72. q  2and p  3

ln x  ln x
73. x
0
2
t 2
dt 
2x
74. Let origin be centre of larger circle and O ' be the centre of smaller circle.

Equation of (1) : x 2  y 2  2
5 7
Equation of (2) :  x  2  y 2  1
2
 A , 
4 4 
x A  xC y  yC
xB  , yB  A  xC2  yC2  2
2 2
2
  7
2
 5
xC   yC 

  4  2  4  1  AC 
7
  
2 2 2
   
 
75. Ortho-centres of triangles formed by three tangents and corresponding normals to a
parabola are equidistant from axis of parabola.
76.  PQT  QT PT  QP  PQ
PQ is symmetric  PQP 1  QPP 1  Q
 P 1 PQP 1  P 1Q  QP 1  P 1Q
 P Q  
1 T T
 QT P 1  P 1Q
77. Conceptual
78. Consider statement 2.
p  n  n 7  n is divisible by 7.  n N
 p 1  1  1  0 is divisible by 7.
7

 p 1  1is true.

Suppose p  k  : k 7  k is divisible by 7 is true. Let k 7  k  7 m, m  N 1
 7 6  7 5
 k  1 7   k  1  k 7   k    k  .....  7 k  1  k  1
 1  2
 7  7  7
  1

 k 7  k    k 6    k 5  .....    k
 2  6
 7
k 7  k is divisible by 7 and   is divisible by 7. For1  r  6.
 r
 By 1
 p  k  1 is true.
 p  n  is true,n  N.
 Statement (2) is true.

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 SRI CHAITANYA IIT ACADEMY, INDIA 02‐04‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐32_KEY &SOL’S
Now consider statement 1.
From statement 2, n2  n is divisible by 7.  n N
  n  1   n  1 is divisible by 7.
7

  n  1   n  1 =7m, m  N and n 7  n  7 p.
7
p N
  n  1  n7  n7  n  1  7m
7

  n  1  n7  1  n7  n  7m

7
  
  n  1  n7  1  7  m  P
7

  n  1  n7  1 is divisible by 7. n  N
7

 Statement 1 is also true.

 Statement 1 and statement 2 both are true and statement 2 is the correct explanation for
statement 1.
79. l = 20, N/2 = 20, c.f. = 13, f = 14, h = 10
use formula
80. ~  p  q    ~ p  q 
  ~ p  ~ q   ~ p  q
~ p   ~ q  q
~ p
81. Probability that calculator of brand r is selected and is defective
6
 7  r k 6 8k
   kr      7r  r 2 
 21  21 r 1 3

_____ 1 
1

 Let Er denote the event that calculator of brand r is selected P  Er   kr

Since Er   r  1, 2,...., 6 are mutually exclusive and exhaustive events we must have
6 6
1
 P  Er   1   kr  1  k 
r 1 r 1 21
8k 8 p
 required probability   
3 63 q
  p  q   71

82. lim
t 2
2  1
 1 1
 
x 
1 1
t  2   2  1  2 
2
2 1
 t t t t 
Now x  1  6  k has four distinct solutions if k   0, 6
 Number of integral values of k is 5
83. Conceptual
84. Second curve is parabola with focus  3, 3 and directrix x  y  2  0 equation of axis is
x  y  0 and foot of directrix 1, 1
Vertex =  2, 2
 Shortest distance = 0
85. Let first term of G.P. be a then
t1  t2  ......  t109  t1  t2  ......  t100  12
t101  t102  ......  t109  12

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 SRI CHAITANYA IIT ACADEMY, INDIA 02‐04‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐32_KEY &SOL’S
aq100  aq101  .....  aq108  12 _______  i 

a  aq  aq 2  .....  aq108 
q100
  12
a 1  q  q 2  .....  q8   100
_____  ii  100
   12
q q q100
86. PQ is focal chord  t1t2  1

 1  200 1 10
a  t1     t1  
 t1  9 t1 3
3 3
a2 1  10  2000
Area of PQR  t1   2  
2 t1  3  27
87. x  75600  24335271
Let divisor is 2a1.3b1.5c1.7 d1 and 2a2 .3b2 .5c2 .7 d2
Product of divisors = 26.33.51.71
 a1  a2  6  3 ways  b1  b2  3  4 ways
 c1  c2  1  2 ways  d1  d 2  1  2 ways
3 4 2 2
Total way N   24
2
88. k
Cr  k Cr 1  k 1 Cr
n
1 1
89. 2 lim L  2 lim 
r 1 n    2r   3r 
n n  r
 1   1    1  
n n n
1 1
1 1/ 2 4 9/2
 2 dx  2   dx
0 
1  x1  2 x1  3 x 0 
1  x  1  2 x 1  3 x
1
1 3  128 lim 2 L 128
 2  ln 1  x   2 ln 1  2 x   ln 1  3 x   ln 2  4 ln 3  3ln 4  ln  en   1.58
2 2 0 81 81
90. x2  2x  4  2  x x 2  3x  2  0
1

x  1, 2 Required area =   2  x   x 2  2 x  4 dx

2

1 1
3x 2 x3
  
2  3 x  x dx  2 x  
2

2
2 3 2
1
 3x x 2
 3
3 1  8   5  2  1
   2x        2      4  6             
 2 3  2  2 3  3   6  3  6

Sec: Sr.Super60_NUCLEUS & ALL_BT Page 14