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Part I : Multiple choice 10 points
1- When 8.00 g of (NH4)2C2O4 dissolves in 30.0 g of water (specific
heat = 4.18 J/g°C), the temperature rises 17.0°C. Calculate the heat of solution of (NH4)2C2O4?
A. -264 kJ/mol B. -125 kJ/mol
C. -33.1 kJ/mol D. -2.13 kJ/mol
2. The specific heat of iron is greater than that of copper. If the same amount of heat is transferred to equal masses of these two metals, both initially at 25°C. Therefore;
A. The final temperature of the iron sample will be greater than that of copper. B. The final temperature of the copper sample will be greater than that of iron. C. The final temperature will depend on the rate of heating. D. Both iron and copper sample will be at the same temperature.
3. The DH°f for CO2(g) is -393.5 kJ/mol. This represents the heat flow at 25°C and 1 atm for;
A. C(s) + O2(g) ® CO2(g)
B. C(s) + 2O(g) ® CO2(g) C. CO(g) + l/2O2(g) ® CO2(g) D. C(g) + O2(g) ® CO2(g)
4- A system has 60 J of heat added to it and at the same time does 50 J of
work. What is the change in energy of the system?
A. -110 J B. -10 J C. +10 J D. +110 J
5. Determine the oxidation number of rhenium (Re) in KReO4:
A. +1 B. +2 C. +4 D. +7 2
6- In the reaction ;
2BCl3(g) + 3H2(g) ® 2B(s) + 6HCl(g)
the reducing agent is:
A. B B. Cl C. BCl3 D. H2
7-When a system is at equilibrium,
A. the reaction stops.
B. the pressures of the reactants equal those of the products. C. the rates of the forward and reverse reaction are equal. D. the sum of all reactant and product partial pressures equal unity.
8- At a particular temperature , K = 0.0224 for the equilibrium;
PCl5(g) ====== PCl3(g) + Cl2(g)
Determine the value of K for the equilibrium;
2PCl3(g) + 2Cl2(g) ====== 2PCl5(g)
A. 4.46x10 B. 8.93x10 C. 2.24x102 D. 1.99x103
9- For the system ;
SiO2(s) + 4HF(g) ====== SiF4(g) + 2H2O(g)
initially at equilibrium, a shift to produce more SiF4(g) would occur if,
A. more H2O(g) is added to the system. B. more HF(g) is added to the system. C. more SiO2(s) is added to the system. D. the volume of the container is increased.
10- The pH of a hydrochloric acid solution is 4.32. The pOH of this
solution is;
A. 2.68 B. 7.43 C.9.68 D.11.32
Part II : Problems 10 points 3
11- Use the information given to determine DH for the following
reaction:
2ZnO(s) + 2S(s) ® 2ZnS(s) + O2(g)
Zn(s) + O2(g) ® ZnO(s) DH = -348kJ
H2(g) + S(s) ® H2S(g) DH = -21kJ Zn(s) + H2S(g) ® ZnS(s) + H2(g) D H = -185kJ
2- Given the bond energies ( in kJ / mol) for H-H, Br-Br, and H-Br as 436, 193, and 368 respectively, estimate the heat of formation of HBr from gaseous H2 and Br2? 4
3-Balance the following equation:
- Cr2O (aq) + I (aq) ® Cr3+(aq) + I2(s)
4- Consider the equilibrium:
N2(g) + O2(g) ===== 2NO2(g) 5
with K = 0.102 at 2000 C. Suppose the initial partial pressure of N 2 , O2
and NO in the reaction vessel are 0.110 atm, 0.150 atm , and 0 atm, respectively. What is the equilibrium partial pressure of O2. 6
Student : ID number : Section number :
بسم هللا الرحمن الرحيم
United Arab Emirates University
Faculty of Science Chemistry Department 7
MIDTERM EXAM Second term 1997- 1998
Course : General Chemistry II.
Course number: 50230110 Date : 20 April 1998 Time allowed :one hour
