Solution Key Final Round - 09
Solution Key Final Round - 09
Solution Key Final Round - 09
Ml 2 l
2
Ml 2 Ml 2 2 2 t 16 12 2second .
2 2M Ml .
12 2 6 2 3 13. (2)
08. (3) 14. (3)
15. (1) For 0 < t < 4s, the position- time graph OA is a
r
09. (2) Here, T s ; max 2m/s ; x ; ? straight line inclined at an angle from time axis, which
2 2
is representing uniform motion of the particle, i.e.
the particle is moving with a constant speed. There-
2 2 1 fore, acceleration and force acting on the particle
max r r ; 2 r 4r or r m
T /2 2 will be zero.
Impulse at t = 0.
Impulse = change in momentum
FS + N – mg = ma
40. (3)
120 + N – 100 = 10(5)
N = 30 N.
hc
45. (2) hvo E
If A 0; A 1 hc
hvo 2 E
x
A 1; A 0
hc hc
E hvo 2E
B 0; B 1 x
B 1; B 0 hc
Hence, x .
E hc
Y ( A B) ( A B) (1 1) 0 46. (3) (A) mv0 mv1 2mv2 v1 2v2 v0 ......(i)
41. (1) Resolving the magnetic moments along OP and
perpendicular to OP, figure we find that components v1 u1 v2 u2 v1 v2 v0 ......(ii)
OP cancel out. Resultant magnetic moment along Use velocities with sign, i.e. velocities towards right
OP is as +ve, velocities towards left as –ve.
2M
= M cos45° + M cos45° = 2M cos45°= 2M
2
(B)
The point P lies on axial line of magnet of moment
= 2M
2mv0 mv0 2mv1 mv2 2v1 v2 v0
2( 2 M )
B 0. ......(i)
.
4 d3
v1 v0 v2 v0 v1 v2 2v0 ......(ii).
47. (1) When heat Q is supplied at constant volume
42. (4) Q QV U nCV T ........(i)
When heat Q is supplied at constant pressure
2A = 6 cm
A = 3 cm Q QP U ' W nCV (T ) ' W
5 E = 37.56 kJ mol–1
sin 1 = 30°. 64. (2) Given reaction, 2A B C
10
50. (4) Electric intensity at centre O, due to small [B][C] 2 103 3 103
Kc = Kc = 6
element dl of charged ring [A]2 (103 )2
dl (ad ) 65. (2) p-Bromophenol
dE 1 2 3
4 0a 2
40 a 2 66. (4) COOH - CH - CH2 - OH
As is clear from figure, horizontal components of OH
dE will cancel out in pairs and vertical components 2-amino-3-hydroxy propanoic acid
will add. 67. (1) Bond order cannot be negative because number
of bonding electrons, is always greater than
antibonding electrons.
E dE sin sin d [ cos ]0
4 0 a 4 0 a
0 0
68. (4) Although charge density of Li is maximum,
so it is extensively hydrated and its ionic mobility is
E ( cos cos 0)
4 0a 20 a . least and that of Cs is highest.
69. (1) Equilibrium constant is not effected by change
CHEMISTRY in conditions like P and V.
70. (3) Lewis concept
SECTION - A (35 Questions) 71. (3) Statement-1 is false, Statement-2 is true
51. (1) Sum of the figures 29.4406, 3.2 and 2.25 is 72. (3) C 2 H 5 Cl
NH3
C 2 H 5 NH 2
C2 H 5 Cl
34.8906. The sum should be reported to the first
place of decimal as 3.2 has only one decimal place.
After rounding off the sum is 34.9. Hence number C2 H 5 -NH-C2 H 5
C 2 H 5 Cl
of significant figures is three.
52. (3) Among all the given options molarity is correct
C 2H 5
because the term molarity involve volume which C2H5Cl
C 2H 5 N C 2H 5 HC 2 N C 2H 5 Cl
increases on increasing temperature.
C 2H 5 C 2H 5
53. (2) 2-methyl but-2-ene and but-2-ene contain 9
alpha H atoms and 6 alpha H atoms respectively. (Tetraethyl
Ammonium chloride)
Greater the number of alpha H atoms, greater is
delocalisation and greater is the stability. 73. (1) 2Cu+(aq) Cu2+(aq) + Cu
54. (1) a (p), b (s), c (r), d (q) Hydration energy of Cu2+ is higher than that of Cu+
55. (4) A-(q); B-(p); C-(s), D-(r) which compensates second ionisation energy of Cu.
56. (4) A3N2 74. (4) Terbium is lanthanide as it belongs to
57. (2) Nucleons are total number of protons and 4f-series having configuration [Xe]4f96s2. However
neutrons. Both of these are collectively known as the remaining member belong to
nucleons. 5f-series (actinides)
58. (1) Basic definition of quantum numbers 75. (4) OsO4
59. (2) RMgX gives alkane with acidic hydrogen Let O.N. of Os be x then 1 × (x) +4 (–2) = 0
(Ph—OH, CH3COOH & HCl) x=8
O3 OH
60. (3) O + HCHO 76. (4)
Zn+H2O
61. (3) I, IV 77. (3) In reaction
62. (3) Oxygen molecule is paramagnetic with two 2Na(s) + Cl2(g) Cl2(g) 2NaCl(s) sodium is
unpaired electrons. oxidised by loss of electrons and acts as a reducing
agent (donor of electrons).
78. (1) He-O2 mixture is used by deep sea divers in SECTION - B (Attempt Any 10 Questions)
preference to nitrogen-O2 mixture because helium 86. (3) ClCH COONa + HCl
2
is much less soluble in blood than nitrogen. ClCH COOH +NaCl 2
79. (1) For an ideal solution ΔSmix > 0 Λ CICH 2COONa HCl ClCH2COOH NaCl
80. (3) Solubility increases with decrease in the value
of KH 224 + 203 = Λ CICH 2 COOH + 38.2
CH3
Λ CICH 2 COOH = 427 – 38.2
CH 3
81. (4) + HBr
Peroxide = 388.8 ohm–1 cm2 gm eq–1
Br NH2
Anti-Markownikoff’s addition Br
87. (3)
82. (1) (eq)acid (eq) KMnO4
M × 2 × 100 = 0.1 × 5 × 50 CH 3
M = 0.125. 88. (3) Cr3+ having 3d3 configuration always have 3
1% HgSO 4 CH3MgX unpaired electrons with strong field as well as weak
83. (2) HC CH CH3CHO
H 2O
20%H 2SO 4 ligands.
(a) 4p
3d 4s
[O]
CH 3 CHOH CH3 CH 3COCH 3
(b) d2sp 3 hybridisation
[Cr(NH3)4BrCl– =
84. (4) CH3CH2CH2COOCH3 So, μ BM = 3(3 + 2) = 15 3.83
85. (4) Valence shell electronic configuration of
89. (1) Given V.PP = 80 torr
3d 4s 4p
Ni
V.PQ = 60 torr
Ptotal = V.PP × xp + V.Pq × xq
Ni(CO)4
sp 3 3 2
hybridisation 80 60 16 3 12 2
3d 5 5
Ni2+ Ptotal = 48 + 24 = 72 torr
[Ni(CN)4] 2- 90. (1) a (s), b (t), c (p), d (q)
dsp2
hybridisation 91. (2) Borax, B2O3 and borax bead test
Co 3+ 92. (2) Strongest oxidising agent = Ag+/Ag(s)
Weakest oxidising agent = Mg2+/Mg(s)
[CoF 6]3-
93. (2) Equimolar mixture of D-glucose and D-galactose
94. (1) It is potassium ammine dicyano dioxo peroxo-
chromate (VI).
sp3d 2
hybridisation
95. (1) Go = Ho–T So
Fe3+
For a spontaneous reaction Go < 0
[Fe(CN)6] 3+
ΔH o
d 2sp 3 or Ho – T So < 0 T >
hybridisation ΔSo
F– is a weak field ligand, it cannot cause forcible
pairing of electrons within d-subshell and thus forms 179.3 103
outer orbital octahedral complexes. T 1117.9 K 1118K
160.2
CO and CN– are strong field ligands, so they can
96. (2) If both Assertion & Reason are True but Reason
form inner orbital octahedral complexes after
is not a correct explanation of the Assertion
forcible pairing of electrons within d subshell.
97. (3) Ionic bond between Cu2+ and SO42–, covalent 116. (1) (NCERT XII, Based on Mutation)
and coordinate in SO42–; 117. (2) (NCERT XII, Pg 117, Para 2, Line 1,2,3 )
118. (1) [NCERT XI; Page No. 79 & 80; Sub-topic
5.9.1 & 5.9.2; Newly added family]
119. (3) (NCERT 11th, Paragraph 10.4.1, Page No.
169)
98. (3) For statement (i), T = The other name of Gay-
120. (3) (NCERT XIIth Pg 109, Para 1, Line
Lussac’s law is of definite proportions by volume.
7,8,9,10)
For statement (ii), F = Law of conservation of mass 121. (1) (NCERT XII, Pg 121, Para 3, Line 5)
is valid for both physical and chemical change.
122. (3) (NCERT XII, Pg 110, last line)
For statement (iii), F = Law of definite proportions 123. (4) (NCERT 11th, Paragraph 8.4.2, Page No.
is valide for each compound individually and not 129)
for comparing two different compounds.
124. (4) (NCERT 11th, Page no-24, Paragraph no-
For statement (iv), F = Equal volumes of all gases 1, Line no-1 and 2)
under similar conditions of temperature and pressure (NCERT 11 th, Page no-24, Paragraph no-3,
contain equal number of molecules. Line no-31 and 32)
99. (3)Ortho and para - nitrohenol is separated by 125. (4) [ NCERT class XI, Page no. 92 (Figure 6.7)
distillation because p–nitrophenol has higher boiling 93 (Point 6.3.1)]
point than o-nitrophenol due to H-bonding.
126. (3) [NCERT class XI, Page no. 89, Line no.
100. (2) 1 > 2 > 3 > 4 12-14]
127. (3) (NCERT 12th, Page no- 39, 1 st Paragraph,
Concept based intext question)
128. (2) (NCERT 12th, Page no-31, 2nd Paragraph,
BOTANY Line no- 34,35,36)
Section - A (35 Questions) 129. (1) (NCERT 12th, Page no- 29, 2nd paragraph,
101. (3) (NCERT XI-page no. 208, 2nd paragraph) 33,34,35,36)
102. (2) (NCERT 11th, Page no-10, Paragraph- 2, 130. (4) (NCERT 11th, Paragraph 8.5.9, Concept
Line no-14) based, Page No. 137)
103. (3) (NCERT 11 , Page no-19, Paragraph-3, 131. (1) (NCERT XI page no. 208, 4 paragraph)
th th
142. (3) (11 th NCERT PK Page no.31 to 33 168. (1) (NCERT 11 th , Page no- 144, Last
conceptual) paragraph, Line no- 3 and 4)
143. (4) (NCERT XII, Pg 116, Para 1, 2, Pg 115, 169. (1) (NCERT XI Page No. 57; Class - Amphibia)
Para 4, Pg 114, Para 3,4, Pg 122, para 1) 170. (1) (NCERT XI Page No. 336; 1st paragraph)
144. (2) [NCERT XI; Newly added family] 171. (2) (NCERT XI Page No. 298; 2nd line of last
145. (3) (XIIth NCERT Page No. 248) paragraph)
146. (4) (NCERT 11th, Page no-23, Paragraph no- 172. (4) (NCERT XI NCERT Conceptual)
3, Line no-27 and 28) 173. (2) (NCERT 12th, Page no-137, Paragraph-2,
(NCERT 11 th, Page no-24, Paragraph no-1, Line no-19)
Line no-1 and 2) 174. (2) (12th NCERT Page no.236)
147. (3) (NCERT 11th, Page no- 8, 2 nd paragraph, 175. (4) (NCERT XI Page No. 296; 5th line)
Line no- 17 and 18) 176. (4) [NCERT P.No.312 Disorders ]
148. (4) (NCERT XII, Pg 89, Based on sex linkage 177. (1) [NCERT P.No.310 Fig.20.7 ]
(Colour Blidness) 178. (3) [NCERT P.No.211,Gene Therapy 2nd para ]
149. (2) (NCERT XII, Pg 85, 5.5 PLEIOTROPY) 179. (3) [NCERT P.No.209, last para]
150. (2) (NCERT 12th, Page no-35, Paragraph no-
180. (2) (NCERT Pg. No.152 Immunity section)
last, Line no-40 and 41 )
181. (4) [NCERT P.No.127, 2nd Point]
182. (4) [NCERT P.No.321 From Line 18 Onwords ]
ZOOLOGY 183. (2) [NCERT P.No.201, Last para ]
Section - A (35 Questions) 184. (2) (NCERT Page No - 153 Immune system)
151. (4) (12th NCERT Page no. 234 to 235, Conceptual ) 185. (2) (NCERT Pg. No.156-157)
152. (3) [NCERT P.No.315 second para and p316 SECTION - B (Attempt Any 10 Questions)
first & second Para ]
186. (4) (12 th NCERT Page no.266 to 267)
153. (2) (NCERT12th, Page No. 59; Paragraph 3,
line 1st) 187. (2) (NCERT11th, Animal tissue)
188. (2) (NCERT12th, Page No. 45; Paragraph 1, line 2)
154. (3) (NCERT12th, Page No.54; Paragraph 3, line 7)
189. (2) (NCERT12th, Page No.43; Paragraph 1, line
155. (3) (NCERT12th, Page No. 64, Paragraph 2, line 7) 10)
156. (2) (NCERT 12th, Paragraph 10.2.2, Page No.
190. (3) (NCERT Pg. No. 270 - Mechanism of
182)
respiration)
157. (3) (NCERT 12th, Page no-129, Paragraph no-
1, Line no-9,10,11) 191. (1) (NCERT 12th, Page no-134, Paragraph-2,
Line no- 33 to 39 and Page no-135, Paragraph-
158. (3) (12 Th NCERT Page no.232 to 235
conceptual) 2)
159. (3) (NCERT 12th, Paragraph 10.2.3, Page No. 192. (3) (NCERT XI Page No. 298, 3rd line of 2nd
183) paragraph)
160. (2) (NCERT Pg. No. 284 - Cardiar cycle) 193. (1)(NCERT XI Page No. 56; class
161. (2) (NCERT Pg. No. 271 - Mechanism of chondrichthyes)
respiration) 194. (4) (NCERT 11th, Page no- 152, 1st paragraph,
162. (3) (NCERT Pg. No. 152 - Vaccination) Line no- 1 ,2)
163. (3) (NCERT11th, Page No.111; Paragraph 3, 195. (2) Competitive inhibition of enzyme is
line 1st) responsible for the synthesis of cholesterol.
164. (2) (NCERT12th, Page No. 57; Paragraph 1) 196. (4) (NCERT Pg. No. 284 - Conducting system)
165. (2) (NCERT12th, Page No. 61; Fig. 4.3) 197. (1) (NCERT Pg. No. 196 )
166. (2) (NCERT 12th, Page no-137, Paragraph no- 198. (1) [NCERT P.No.312 Synovial Joints ]
2, Line no-19 to 22) 199. (2) [NCERT P.No.321, Midbrain para 3rd Line ]
167. (2) (NCERT 11th, Page no- 148, Sub chapter 200. (3) (NCERT XIIth Page No. 197, First para )
9.5, Line no- 6,7,8)