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Solutions to JEE Main - 7 | JEE-2022

PHYSICS
SECTION-1
L
1.(D) Time period of a simple pendulum, T  2
g
LC L
So, TC  2 and TH  2 H
g g
Also, LH  LC 1    35  5   LH  LC 1  30
1/2
TC  LC  1 TC
Therefore,    1/2
  1  15
TH  LH  1  30  TH
2.(C) Work done in isothermal process,
V 
W  nRT log e  2   W  1 R  300  log e  8    900log e 2  R  900(0.693)(8.31)  5183 J
 V1 
3.(C) Let the equation of the SHM be:
x(t )  A sin  2ft 
A
So, we can see that the particle is at its mean position at t  0 and at x  for the first time at
2
1
t
12 f
4.(C) Rate of radiation of heat from the surface of a block body is given by Stefan’s law:
dQ
 AT 4
dt
Here,  is the Stefan-Boltzmann constant, and A is the surface area of the body
dQ
Therefore, for a sphere,  r 2T 4
dt
 dQ   dQ 
Since we are given that     ,
 dt  A  dt  SUN
rA2TA4  rSUN
2 4
TSUN
4 2
 TA   rSUN 
    
 TSUN   rA 
1/2
TA r  1 1
   SUN    TA  TSUN  3000 K
TSUN  rA  2 2
5.(B) Work = Area under P-V curve
1
 (3 P0  P0 )(3V0  V0 )  P0 (3V0  V0 )  4P0V0
2
6.(A) Restoring force, F    kx  2kx     3k  x
m
Therefore, the time period, T  2
3k

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7.(C) Let the area of cross-section of the blocks be A0

Let the temperature at the interface be T
KA0  TA  T   3K  A0  T  TB 
Since the rate of heat flow through the blocks must be equal, 
L 2L
1
Solving, we get T   2TA  3TB 
5
8.(D) Tension in wire 1, T1   m A  mB  g  6 g
Tension in wire 2, T2  mB g  2 g
Stress T
We know that Strain  
Young's modulus AY
2
Strain1  T1  A2Y2   T1  A2  Y2   6g   2   1 
Therefore,                4
Strain 2  AY
1 1  T2   T2  A1  Y1   2 g   1   3 
1
9.(B) We know that for linear SHM, KEmax  m2 A2
2
1 2 2 1 g 1
Therefore, analogously for angular SHM, KEmax  I  m  ( mL2 )   2m  mgL 2m
2 2 L
  2

L   mgL 
10.(A) Restoring torque (about O) acting on the rod,   mg  sin     
4   4 
2
1 L 7
Moment of inertia of the rod about O, I mL2  m    mL2
12 4
  48
I
We know that if restoring torque is   C , the time period of angular SHM is 2 
C
 7 2
I  mL 
Therefore, the time period of angular SHM of the rod, T    2  48   2 7 L
C  mgL  12 g
 
 4 
Molar specific heat
11.(C) We know that Specific heat 
Molar mass
Therefore, the specific heat at constant volume of Argon gas (which is a monoatomic gas) is
 3R 
 2  75R
C   311.63 J/kg
0.04 2
12.(D) Since the block is initially at rest, the initial position is the upper extreme
The mean position is where the block is in equilibrium. Therefore, at the mean position, the
mg  0.310 
elongation in the spring is   2.5 cm
k 120
Since initially the spring was in its natural length, the amplitude of the SHM is 2.5 cm
k 120
Now, the angular frequency of the SHM,     20 rad/s
m 0.3
So, the maximum velocity of the block during the SHM,
vmax  A   0.025 20  0.5 m/s  50 cm/s

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Since the initial velocity is zero, and the velocity is negative for the next half time period before
becoming zero again at the lower extreme position, the variation with time is v  t   vmax sin  t 
[This can be visualised readily using the graph of the sine function]
 
Therefore, v  t   50sin  20t   50cos  0t  
 2
13.(C) Let the final temperature be T f
Heat gained by ice = Heat lost by water
L
m2T  m1  
m1L  m1C  T f  0   m2C  T  T f   Tf  C
 m1  m2 
14.(C) Work done by the gas is positive if and only if the gas expands, regardless of the type of the process
For adiabatic expansion, Q  0 and W  0
Therefore, U  0
For isobaric expansion, W 0
Cv
And, U  nCv T  P V  0
R
15.(A) Net restoring force,
 GMm   y  2G M m y
Fnet  2 F sin   Fnet  2  2     Fnet  3/2
2 
 a  y   a  y 
2 2
a2  y 2  
 2GMm 
Since y  a, Fnet   y
 a3 
1 k
We know that if Frestoring  ky, the frequency of the SHM is
2 m
1 2GM
Therefore, the frequency, f 
2 a3
 m  m 1  1 
16.(C) Considering a mass m of the metal,      1    T2  T1       1
 2   1   T2  T1   2 
3
P1 P V 
17.(B) Since  2  P2   2  P1
V13 V23  V1 
R 5 R 11R
For PV 3  constant , C  CV   R 
3  1 2 4 4
11 11 11  V23  11 P
 Q  nC T  1 1) 
nR(T2  T1 )  ( P2V2  PV 1 2  PV
 3 PV 1 1
  3
V24  V14  
4 4 4  V1  4 V1
P
18.(D) Bulk modulus is defined as: B  
 V 
 
 V 
 P 
Therefore, the change in volume due to the difference in pressure,  V  Pressure    V
 B 
And, the change in volume due to the difference in temperature,  V Thermal  V T
P
Therefore, the total change in volume,  V Total   V  Pressure   V Thermal  V   
 T 
 B 

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So, the fractional change in volume,

   10  10  300 

3
 V Total  P 
f 
V
 
 B
 T   
  150  109
  3  10 6
 10  20      5  105 


19.(C) Remember that according to Newton’s law of cooling, the time taken by a body to cool from
 T T 
temperature T1 to temperature T2 in a room at temperature T0 is proportional to log e  1 0 
 T2  T0 
But when T1 and T2 are very close together (or more properly, T1  T2  T1 ), the rate of cooling
dT
(i.e. ) can be considered constant for the brief time it takes the body to cool from temperature
dt
T1 to T2 . And since we know that according to Newton’s law of cooling, the rate of cooling is
proportional to  T  T0  , the rate of cooling during cooling from T1 to T2 is very nearly proportional to
 T1  T0  [or  T2  T0  , since T1 and T2 are very close together].
And, it is intuitive that if the rate of cooling is constant, the time taken to cool from T1 to T2 is
T1  T2
t12 
The constant rate of cooling
 T T 
Therefore, t1 2   1 2 
 T1  T0 
 80.0  79.9 
So, the time taken to cool from 80.0 oC to 79.9 oC , t1   
 80.0  20.0 
 40.0  39.9 
And, the time taken to cool from 40.0 o C to 39.9 oC , t2   
 40.0  20.0 
t1 1
Therefore, 
t2 3
20.(D) We know that the heat absorbed by the gas in an isobaric process, Q  nCP T  nCP  T f  Ti 

3RT
Also, we know that the rms speed of the molecules at temperature T, vRMS 
M0
Here, M 0 is the mass of one mole of the gas
M0 2
Therefore, T  v RMS
3R
nM 0C P 2 7m 2
So, Q 
3R
 2
v RMS , f  vRMS ,i  
6
 2
vRMS , f  vRMS ,i 

7R
[because nM 0 is simply the total mass of the gas, m, and for a diatomic gas, C P  ]
2
7
Therefore, Q     0.1  700 2  5002   28 kJ
6

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SECTION-2
21.(30) Let the specific heat of the liquids be S X and SY
Then, for the first mixing,
Heat lost by liquid X = Heat gained by liquid Y
 10 S X  80  32   20 SY  32  20   2 S X  SY
Now, let the final temperature after the second mixing be T
So, for the second mixing,
Heat lost by the mixture = Heat gained by liquid Y
 10S X  20SY 32  T   5SY T  20
Replacing SY  2S X and solving, we get T  30 o C
22.(8) If the heat absorbed and the heat rejected per cycle are QH and QL , we know that
QH TH 500 5
  
QL TL 300 3
We are given that QH  20 kJ  QL  12 kJ
By the first law of thermodynamics (energy conservation), the work done by the gas per cycle,
W  QH  QL  20  12  8 kJ
23.(84) We can use the result for speed as a function of position,
v  y    A2  y 2
2
Therefore,  A2   1  24 and  A2  52  12 2
Diving the equations and squaring,
A2  1
2  A  7 cm
A2  25
24
Therefore,   12 rad/s
72  1
So, the maximum acceleration, amax  2 A  12  7   84 cm/s2
dQ KA  T1  T2  11.2  T1  14 
24.(21.50)   1800  2
 T1  21.5 oC
dt L 0.5 10
25.(62.50)
Let the number of moles of each gas be n and let the temperature be T
5
Total KE of Nitrogen molecules, K1  nRT
2
3
Total KE of Helium molecules, K2  nRT
2
K1
Therefore, the required percentage   100  62.5
K1  K 2

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Chemistry

SECTION-1
1.(D) Compound D is aromatic as it obey Huckel rule of cyclic conjugation of (4n  2) e 
(n  0, 1, 2...........)

2.(C) Compound 3 is optically inactive due to presence of P.O.S and C.O.S

[H  ]2 (S2 )
3.(B) Ka1  Ka 2 
[H 2S]
[10 1 ]2 (S2  )
10 20 
0.1
20
10  0.1
S2   2
 1019
10
4.(B) NH 4Cl  salt of S.A/W.B (pH < 7)
Na 2 CO3  salt of W.A/S.B (pH > 7)
K 2SO 4  salt of S.A./S.B (pH = 7)

5.(A) It is a disproportionation redox reaction

 5Z  ZO3 ................n factor of Z2  5 / 3
3Z 2 
M 3
 Equivalent mass of Z2   [160]  96
5/3 5

6.(B)  Ag(NH3 ) 2 Cl

AgCl(s)  2NH 3 (aq) 
K  K sp  K f  10 4

7.(A)

8.(C) Acidic buffer having pH = pKa has maximum buffer capacity.

9.(C) As at half neutralization point

pOH  14 – pH  14 – 8  6
 pK b  6...... for AgOH

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10.(A)
S2 O82 H 2SO5
O O O
_ || || ||
O S  O  O  S  O  H  O  S  O  O  H
|| || ||
O O O
(1peroxidelinkage) (1peroxide linkage)

11.(B) As for a H 2O 2 solution volume strength  N  5.6

2.8 1
 N   0.5
5.6 2

12.(B) KMnO 4 will oxidise Fe2 into Fe3 (in the acidic medium)
meq of KMnO 4 = meq of Fe2
M  5  0.01  (0.01  1)
1
Molarity of KMnO 4   0.20 M
5
13.(C) O2 F2 H 2O 2
( 1) ( 1)

OF2
( 2)

 increasing order of oxidation of the oxygen atoms is option (C).

14.(B) On adding HCl, pH of the solution will decrease slowly initially; and sharply near the equivalent
point.
1
15.(A) pH  7  [ pK a  pK b ]
2 (CH3COOH) ( NH4OH)
 pH  7 [as pK a  pK b  5 ]
16.(C) (C) is not redox reaction

CaCO3 
 CaO  CO 2
(A) C6 H12 O6  6O 2  6CO 2  6H 2 O
1
(B) H 2 O2   H 2 O  O2
2
h
(D) AgBr  Ag  Br2

17.(A)

18.(D)

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19.(B) Eclipsed conformer of 1, 2-dichloro ethane is less stable than its anti-conformer; twisted boat form of
cyclohexane is more stable than its Boat form. Chair form of cyclohexane is optically inactive;
Gauche conformer of ethane-1, 2-diol is more stable due to intra H-bonding.

 Ag   Cl
20.(C) AgCl 
C O
(C  S) (S)
K sp  (C  S) (S)
Neglecting “S” compared to “C”
K sp  C(S)

1010
S  10 9 M
10 1
SECTION-2

21.(18) 14H  Cr2 O7 2  2FeC 2 O 4 
 2Cr 3
 2Fe3  4CO 2  7H 2 O
 n1  1, n 2  2, n 3  2, n 4  2, n 5  4, n 6  7
And (n1  n 2  n 3  n 4  n 5  n 6 )  18

22.(3) The compound consists of only 2 identical chiral centres thus number of possible stereoisomers is 3.

23.(7.50) At end point we will obtain an aqueous solution of KH 2 PO 2

by the reaction H3PO2  KOH 
 KH 2 PO 2  H 2 O
(Monoprotic)

10  1 / 5 1
Here [KH 2 PO2 ]    0.1
(10  10) 10
1 1
pH  7  [pka  log[H 2 PO 2 ]salt ]  7  [2 – 1]  7  0.5  7.5
2 2

24.(6) Least soluble metal chloride out of the given two is Hg 2Cl2 (Ksp  1016 )
To just start precipitation of Hg 2 Cl2 let concentration of HCl required is “ C ”, such that
1016  10 4 [C]2
10 16
(or) C2   10 12 (or) C  106 M  [H  ]  pH of the solution = 6
104
17
25.(7.75) NO31 
 NH3 [V. D. of NH3   8.5 ]
( 5) ( 3) 2
Hence for NO3 [Mº  62]
62
Equivalent mass   7.75
8

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Mathematics
SECTION-1
2 2
x 1)
1.(B) 2(2 cos  3.2cos x
4
cos2 x
2 t
t2
 3  t  4  t 2  6t  8  0 t  2, t  4
2
2
2cos x
 21 or 22
cos 2 x  1 or 2 (not possible)
x  n , 2 , 3.....100
Sum = 5050 
10 2a
2.(B) S10  (2a  9 d )  0  d 
2 9
S 20  S10  Next 10 terms sum
 200
20
 (2a  19d )  200
2
 2a 
2 a  19     20
 9 
20a
  20  a  9
9
3.(A) tan   cot   (tan   cot )2  2
tan   cot   t
t2  t  2  0
  
(t  2) (t  1)  0  t  2 or (t  1) Rejected as   , 
4 2 
tan   cot   2  tan   1
1 1
sin   , cos  
2 2
26
Cr r 2 (27  r )
4.(B) Tr  r 2  26
  r (27  r )
Cr 1 r
Tr  27r  r 2
10
27  10  11 10  11  21 10  11
S  27 r  r 2    [27  7]  55  20  1100
r 1
2 6 2
5.(A)

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6.(A) y2  8x
2
P (4, 6) y  mx 
m
2
6  4m   4m 2  6m  2  0
m
 2 m2  3m  1  0
2 m 2  2m  m  1  0
2 m ( m  1)  1(m  1)  0
1
m  1, m 
2
x
y  x  2 or y   4  2y  x  8
2
7.(C) (21/2  31/5 )10
Tr 1  10 cr (21/2 )10 r (31/5 )r
For rational terms
r  0, r  10
T1  32 T11  9
Sum = 41
x2 y 2
8.(C)  1
9 4
4 x  2 y  5  0 ( m  2)
Slope of Normal = 2
3x 2y
 5
cos  sin 
3sin  4
Slope  2  tan  
2 cos  3

x y
9.(A) Tangent  1
3 2 2 2
Normal 3 x 2  2 y 2  5
5 1 12
P1  , P2  
18  8 1 1 26

18 8
60 30
Area  P1P2  
26 13
10.(D) Total number of triangle   12
c3   3
c3  4 c3  5 c3 

 220  (1  4  10)  205

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x2
11.(D) x 2  8 y  y2  1
3
8y
 y2  1
3
3y2  8 y  3  0
y  3  0 (Rejected)
3y 1  0
2 1
12.(C) e1  1  
3 3
1
e1e2 
2
3 3 b2 b2 3
e2    1  1   b2  4
2 2 16 16 4
Length of minor axis of E2  4
3
13.(C) a  25 d 
5
For maximum sum Tn  0
 3  (n  1) 3 125 128
25  ( n  1)    0  25  n  1   n n  42.66
 5  5 3 3
r
 cos  
14.(D) Tr 1  10 Cr ( x sin )10 r  
 x 
 10 Cr (sin )10 r (cos ) r x10 2 r
10  2r  0  r  5
10
C5
T6  10C5 (sin )5 (cos )5  (sin 2)
25
10
C5
(T6 ) max 
25
15.(B) C A R A, O, E , C , S , S , N , N
6! 7 6! 7!
 C3  3!    3!
2! 2! 2! 2! 4!3!
65
  7  6  5!  15  21  5!
4
 11  1 1  1 
16.(A) S  1   1       1   2   2   ....
 52  5 5 2 
S 1  1 1
     1    2  ....
2 2  5 2
S 1 1 1 1 1
 1   2 2  3  3  ....
2 5 2 5 2 5 2
S 1 S 10 20
    S
2 1 2 9 9
1
10

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 1  1 
17.(B) E   a 4  4  4   b 2  2  3  ((c  1)2  1)
 a  b 
Emin  6  5  30

(sin 7   sin 5)  5(sin 5  5sin 3)  12(sin 3  sin )

18.(B)
sin 6  5sin 4  12sin 2
2sin 6 cos   5  2sin 4 cos   12  2sin 2  cos 
sin 6  5sin 4  12sin 2
  3 
 2cos   2 cos    2sin  
5
   10 
19.(B) ( y  2) 2  16( x  1)
Focus (5, 2)
Focal chord  ( y  2)  m( x  5)
Tangent to x 2  y 2  14 x  4 y  51  0
Centre (7, 2) r  2
2m
 2  4m 2  2m 2  2
2
1 m
2 m2  2
m  1 or  1
4
20.(D) Distance b/w L.R. and TAV 
2
4 16
 L. R.  4   8 2
2 2
SECTION-2
1 1 nr r 
21.(3) Tr 1  nCr ( x ) n r r 1/4 r
 n Cr
r
 x  
2  (x ) 2  2 4
Coefficient of first three terms are in A.P.
n 1 1 1
C0 0 , nC1 , nC2 2  A.P.
2 2 2
n
n C2
C1  1 
4
n (n  1)
4n  4   n 2  9n  8  0  n  8 or n  1 . (Not possible)
2
16  3r
Exponent of x  r  0, 4, 8
4
6r  1 6r  1
22.(4) Tr  2 2

(3r  1) (3r  2) (9r  6r  1) (9 r 2  12r  4)
2

1  (9r 2  12r  4)  (9r 2  6r  1) 

  
3  (9r 2  12r  4) (9 r 2  6 r  1) 
1 1 1 
Tr   2
 2 
3  (3r  1) (3r  2) 
1 1 1
T1   2  2 
3 2 5 

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11 1
T2  
3  52 82 

1 1 1 
T10    
3  (29) 2
(32) 2 
11 1  85
Sum   2   Sum 
3 2 (32) 2  1024

x
23.(32) y   12 3 (Tangent)
3
x 24 12
y   (Normal)
3 3 3 3
4
20 3 
Distance  3  32
1
1
3
5
24.(5400) C2  4 C2  6 C2  4C2
10  6  15  6  5400
ax by a b a 2  b2
25.(10)   a2  b2 ;  
cos  sin  cos 4a sin 3b 24
4 24
tan    , a 2  b 2  
3  4
3 
 5
a 2  b 2  10

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