PHYSICS

1) A,B,C 2) A,B,C 3) A,C,D 4) A,B,C,D 5) C,D 6) A 7) A,B,C 8) A,B,C

9) A,D 10) B,D 11) 2 12) 2 13) 8 14) 4 15) 1 16) 2

17) 20 18) 2 19) 3 20) 1

CHEMISTRY
21) A,B,D 22) B,C 23) B 24) C 25) B,C 26) B 27) A,C 28) B,C

29) A,C,D 30) A,B 31) 5 32) 3 33) 4 34) 3 35) 7 36) 4

37) 2 38) 3 39) 0 40) 6

MATHEMATICS
41) B,C 42) A,C 43) B,C 44) C,D 45) A,B,C 46) A,B,C,D 47) A,C,D 48) A,B,C

49) A,B,C,D 50) A,D 51) 3 52) 0 53) 4 54) 1 55) 7 56) 6

57) 5 58) 1051 59) 6 60) 2

 SOLUTIONS
PHYSICS
1) By principle of floatation (at 300K)
    2.7 
m  Vin ,  L3  hL2 , h  L      20  3.970cm
    13.6 
h1  L  h  20  3.970  16.03cm
And when temperature increases from 300K to 350K
m  Vin  Vin1 1 ; So, Vin  Vin1 1
2
h1  L   
  1   1 and L1  L 1   s   ,  1 
h L   1   L 
1
h 1   L 
   1    L  2 s  
h 1   s  2
h1
(using Binomial theorem)  1  1    L  2 s    1
h
h  h  h   L  2 s    3.970 1.8  104  2  23  106  50  2.66  10 2 cm
1

2)

3) v   p 
1
/K
273
3
E RT is same for all ideal gas gases at same temperature.
2
kT
The mean free path,   ; so it increases with decrease in pressure.
2 d 2 P
4) 5
Average kinetic energy per molecule  K BT
2
It depends only on temperature
3RT 3RT
Here Vrms  A  And Vrms  n 
MA MB
3RT
Vrms  B  M A /16
Vrms   4 Vrms  A
mA m m /2  nB 
Now n A  & nB  B  A nB  8n A PB   P0
MA M B M A /16  n A  nB 
 nA  PB nB
And PA   P0   8 ( V & T are constants)
 n A  nB  PA nA
5) During expansion an isotherm lies above an adiabat
  slope of   slope of an  C
Also   =γ    m2  P  m1   m2CV  m1CP
 an adiabat   isotherm  CV
Since   1  m2 m1
6) First law of thermodynamics is an energy conservation law. For details read basic
concept.
7) For Isobaric process
3
u  nRT W  nRT , For Isothermal u  0    w
2
Since cycle is clockwise. So W  0
8) Piston is free to move in upward direction thereby making it is boric with inc in
both volume and temperature
9) l l 1
Net resistance of two wall=  1  2 
 k1 k2  A
 
 T  l
Temperature of interface =   1000     1 ..... 1
 l1  l2  k1
k k 
 1 2 
 
 T  l
or     2  100............  2 
l l
 1  2  k2
k k 
 1 2 

equation 1 & 2 shows on increasing thermal conductivity of outer layer temp of

interface certainly decreases.
IN same way on increasing thickness of Inner layer temperature of interface
decreases.
10) a
d
A
dt
dT  eA 4 A
b
dt

mC
 T  Ts4  
m
2
dT 4 R 1 dT A 1
For sphere   . For cube  
dt 4 3 R dt At t
 R
3
as t  R  Rate of fall of temp. for sphere is less
11) For distance between A and F to remain constant, extension in CD = extension in
l1 1
AB + extension in EF l2  2l1  l2 2  2  2l11 or 
l2 2 2
12) 1
Rate of Collisions with vessel wall is N C  n0Vrms  const
6
1 N 3RT T dT
.  const,  const , T  kV 2 ,  2kV
6 V m V dV
 PdV
Molar heat Capacity C  CV 
n.dT
3R RT dV 3 R 2 1
C  . R   kV  .
  2R
2 V dT 2 V 2kV
13) 3 5
CV1  CV2 2 R  2 R
CV of the mixture is CV    2R
2 2
du d  2 d
d    du  d  du  (1)
3 2 3 2
R R 3 2 1 R 
C  for PV n process r   CV  
r 1 1  n 2 3 2  1  n 
4 R 11
  2R   8  8n  3 , n 
3 1 n 8
14) Fall in temperature in F  212  140  720
0

5
 Fall in temperature in 0 C  72   400 C
9
15) Buoyancy force [vertical equilibrium]
K 2 0.88 1
 1    L   b    L   b ,  L   L 1 103 / 0C
K1 0.84 21
16) Molar heat capacity = 
Q

Q
and Q  U  W
T t1  t1
nR T1  T2 
Q  nCv T2  T1  
n 1
17) Figure shows that on segments, 1–2 and 3–4, pressure is directly proportional to
the temperature. It follows from ideal gas equation that gas volume remains
unchanged in this case and the gas does not work. So, we must find the work
done only in isobaric processes 2–3 and 4–1.
The work W23  P2 V3  V2  and W41  P1 V1  V4 
Total work done by the gas during the cycle is, W  P2 V3  V2   P1 V1  V4 
The equation of state for three moles of ideal gas, PV
1 1  3 RT1 , PV
1 4  3RT4

2 2  3 RT2 , PV
PV 2 3  3RT3

Putting these values, we get: W  3R T3  T1  T2  T4   20kJ .

18) 
Wnet Q  Q2  Q3  Q4 2000
 1   100  20% so x = 2
Total heat supplied Q1  Q4 10000
19)  
Q1  1  T1  T0  A and QB  2 T1  T0  A
d d
Q  Q1  Q2

 1 2
   
2
20) b 3 10 6
m   3
 1000  1103
t 3 10
 CHEMISTRY
21) Mg  2 HCl  MgCl2 H 2
Zn  2 NaOH  Na2 ZnO2  H 2
Cu  H 2 SO4  O2  CuSO4  H 2O
C  H 2O  CO  H 2
22) Conceptual
23) 3%
24) 6 H 2O2 6
Cr2 O72  Cr O5
1 H 2O2 1
KI  KOH  I 2
4 H 2 O2 4
Ti  SO4  2  H 2 Ti O4
4 2
Pb O2  Pb O
25) Photochemical smog is produced when pollutants from the combustion of fossil
fuels react with sunlight. The energy in the sunlight converts the pollutants into
other toxic chemicals. In order for photochemical smog to form, there must be
other pollutants in the air, specifically nitrous oxides and other volatile organic
compounds
26) 49 g K 2Cr2O7  8gm  oxygen  3.92 g K 2Cr2O7 
8  3.92
0.64mg
49
0.64
COD of given   6.4 ppm
0.1
27) Order of stability is

> H 2C  CH  CH  CH  CH  CH 2 > H 2C  CH  CH  CH 2 > H 2C  CH 2

28) Conceptual
29) Conceptual
30) By Wurtz reaction, only symmetrical hydrocarbons with even number of carbon
atoms can be prepared.
Hence, choices (a) and (b) are correct while (c) and (d) are incorrect.
31) 6 103 g of MgSO4 ___ 103 g of H 2O
? ____ 106 g of H 2O
6  103 106
Amount of MgSO4  = 6g
103
120g of MgSO4 =100ppm
 6gm MgSO4 =?
6  100
=5ppm
120
32) Conceptual
33) degree of hardness (in ppm of CaCO 3 ) = no. of millimoles of salt/lit 100 (EQTN) as
n5
 Concentration of CaCl 2  5 10 3 moles per lit
K sp 2.4 10 5
 SO 4 2      4.8  10 3
Ca 2  5 10 3
  Na 2 SO 4  required  4.8  10 3 M
34) III, IV and V
35) H 2O2 & C2 F4 not a green house gases
36) 1090 281  90 190 281
In Cyclobutane, angle strain    90 441 .
2 2

900

37) 2CH3COOK  2HOH  C2 H6  2CO2  2KOH  H 2

(Anode) (Cathode)

2  98g of CH3COOK  22.4 lit of C 2 H 6 .

17.5g  2 lit
38) CaO
1CH 3CH 2COONa  NaOH  1CH 3CH 3  Na2CO3
96 gr _____________30 gr
9.6 __________ ?
39) 2,3-dimethyl 2-Butene is formed as a rearranged products, which has no ‘ sp 2  s ’
bond.
40)
 MATHEMATICS
41) The given relation can be written as
 m  2  tan    2m  1   2m  1 sec 
2 2
  m  2  tan 2   2  m  2  2m  1 tan    2m  1
2
  2m  1 1  tan 2  
2 2
  m  2    2m  1  tan 2   2  m  2 
 
2 2
 2m  1 tan    2m  1   2m  1 0
 3 1  m 2  tan 2    4m 2  6m  4  tan   8m  0
  3 tan   4  1  m 2  tan   2m   0
4 2m
Which is true if tan   or tan   2
3  m 1
42) Applying R1  R1  R3 and R2  R2  R3 on the LHS, the given equation can be written
as
1 0 1
0 1 1 0
sin 2  2
cos  1  4sin 4
Expanding the LHS along R1 , we get
1  4 sin 4  cos 2   sin 2   0
 4 sin 4  2  sin 4  1 / 2
 4  7 / 6 or 11 / 6
  
 0    2  0  4  2 
   7 / 24 or 11 / 24
43)  1 3
2

y  cos x  cos x  1 cos 2 x    .

4 2

 2 4
2
3  1
 ymin  and y is maximum when  cos 2 x   is the maximum
4  2
1 3
 ymax    1.
4 4
44) T T T T sin 4   sin 6   cos4   cos6 
Here, 6 4   4 6  
T6 T6 sin 6   cos6 
sin 4  cos 2   cos 4  sin 2 
 3
 sin 2
  cos 2    3sin 2  cos 2   sin 2   cos 2  
sin 2  cos 2  sin 2 2
   m
1  3sin 2  cos 2  4  3sin 2 2
 4m
sin 2 2 
1  3m
4m
 0  1  m   1, 0
1  3m
45) The given equation can be written as
2
cos 2 x  sin 2 x   cos x  sin x  = 2 cos x  sin x
 cos x  sin x  cos x  sin x  cos x  sin x   2 cos x  sin x
 Either cos x  sin x  0  tan x  1

 x  n   n  I    a  and  c  are correct
4
or cos x  sin x  cos x  sin x  2
2
 2cos x  2 2cos2  sin 2 x  4  cos 2 x  sin 2 x   2  cos x 
4  16  20
 cos 2 x  4 cos x  5  0  cos x   5 or 1
2
But cos x  5 so cos x  1
 x  2n and thus (b) is correct.
46)

At

At
At

47) 3 3a 2
a 2  b2  c 2  ab 3  0  a 2  2.a .b  b 2   c 2  ca  0
2 4
2
 3a   a 2 ca
   b      c 2  2.  0
 2  2 2
2 2
 3a  a 
  b     c   0
 2  2  b
 
3 c 1
and 
a 2 a 2
0 0 0
A  90 , B  60 , C  30
48) Applying A.M  G.M for s, s  a , s  b, s  c and also for s  a, s  b, s  c we get
s  s a  s b  s c 4 2 s a  s b  s c
   3
 s  a  s  b  s  c 
4 3
s2 s 3 2 s2 s2
   
4 3 s 3 3 3
49) From the given equation, we get
tan A  tan B  c 2 / ab
tan A  tan B
And tan A tan B  1. Since tan  A  B  
1  tan A tan B

We get A  B   / 2 and C   / 2. Therefore triangle ABC is right-angled at C Hence.

tan A  a / b, tan B  b / a, cos C  0,
s sin A  a / c, sin B  b / c and sin C  1, so that
a2 b2 a2  b2
sin 2 A  sin 2 B  sin 2 C    1  1  11  2
c2 c2 c2
a 2  b 2  c 2 
50) cos  
a  b sin A  sin B
 [by the law of sine]
c sin C
2 cos 1/ 2  A  B   sin 1/ 2  A  B  

2sin 1/ 2  C  cos 1/ 2  C 
2sin 1/ 2  C  sin 1/ 2  A  B   sin 1/ 2  A  B  
 
2sin 1/ 2  C  sin 1/ 2  A  B   sin  1/ 2  A  B  

sin 2 1/ 2  A  B    sin 2 1/ 2  A  B  

 sin  
sin 1/ 2  A  B  

sin A sin B

sin 1/ 2  A  B 


 a  b  sin  sin A  sin B sin A sin B

2 ab 2 sin A sin B sin 1/ 2  A  B  
2sin 1/ 2  A  B   cos 1/ 2  A  B  

2sin 1/ 2  A  B  

c sin  sin C sin A sin B

 cos 1/ 2  A  B   and 
2 ab 2 sin A sin B sin 1/ 2  A  B  
 

2sin  C / 2  cos C / 2   cos   A  B  / 2
2sin  A  B  / 2 
51) Given A  B  C  
A B C A B C
 cot cot cot  cot   cot …(i)
2 2 2 2 2 2
A B C
But tan , tan , tan are in H.P.
2 2 2
A B C A C B
 cot , cot , cot are in A.P.  cot  cot  2cot
2 2 2 2 2 2
A B C B
From (i) and(ii), we get cot .cot .cot  3cot
2 2 2 2
A C
A C cot  cot
 cot .cot  3 , Now, 2 2  cot A cot C
2 2 2 2 2
B
2 cot
2  3 B
 [From (ii)an (iii)]  cot  3
2 2
52)  x y  x y 4  x y  x y  2
2 cos   cos   ,  2sin   sin  
 2   2  5  2   2  7
53) We have
2 2

 d tan   a 2  1 tan     a 2  1 tan   a 2  1 tan  

2


 a tan   a 2  1 tan   0

a 2
 a 2  1  a 2  1 tan 2   tan 2   tan 2  
2


 a tan   a 2  1 tan   a 2  1 tan   0
4a 2
 tan 2   tan 2   tan 2   2
 3 tan 2   4
3a
54) 1  5 1 1  5
Solving cosx=1,-1/2,  cos x   ,  x   0,  
4 2 4
2 4 4 28
x , , 
3 10 5 15
55) We have
1

1

1
 3 2
sin sin sin
n n n
3  2 
sin sin 2 cos sin
n n  1 n n  1
 
 3 2  3 2
sin sin sin sin sin sin
n n n n n n
 2 2 3 4 3 7x 
 2sin
cos  sin  sin  sin  0  2cos sin 0
n n n n n 2n 2n
7  7  
 cos  0 or sin 0   2k  1 or  2 k
2n 2n 2n 2 2n
7 1
Where k  z  n  or n 
2k  1 4k
1
(n  not possible for any integral value of k )
4k
56) From the given equation we have,
x y x y x y x y
2sin cos  2sin cos
2 2 2 2
x y x y x  y x y x y
 sin  cos  cos   0  sin  2sin sin  0
2  2 2  2 2 2
x y x y
Which holds if either sin  0 or sin  0 or sin  0
2 2 2
Also since x  y  1  x  1, y  1 . So, the required solution is
either x  y  0 or x  0 or y  0
1
if x  0, y  1 , and if y  0, x  1 and if x  y  0  y   x  y   x  x 
2
so that the required pairs  x, y  are
1 1  1 1
 0, 1 ,  1,0  , ,   ,   ,  which are 6 in number.
2 2  2 2
57) cot A b 2  c 2  a 2 2010a 2 cot A
 2 2
 1005  103  5
cot B  cot C 2a 2a cot B  cot C
58) Let  be the smallest angle then 2 is largest.
sin  sin 2 a 1
So from the triangle we have    2 cos 
a 1 a 1 a 1
2 2

Also cos  
 a  1  a 2   a  1 a 2  4a

a 1 a  4

 a5
2  a  1 a 2  a  1 a a  1 a  1
Hence 3a 3  20a 2  35a  1  375  500  175  1  1051

59) Radius of the circle r   s  a  tan

A

a
. If the side of the square be x then x 
a
2 2 3 6
60) S  s  b S  s  c s 2s abc 4a
G.E  .     2
  s  a 2 s  2a a  b  c  2a 2a