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    P2 - L4 - Kinetic Energy of Gas - HW

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    minhtridta

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    P2 - L4 - Kinetic Energy of Gas - HW

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    minhtridta
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    P2_L4_Kinetic Energy of Gas_HW (1)

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    6 views7 pages

    P2 - L4 - Kinetic Energy of Gas - HW

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    minhtridta

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    You are on page 1of 7

    CHAPTER 3 THE KINETIC THEORY OF GASES

    Homework:
    Problems 13, 14, 20, 24, 32, 40 in Chapter 19 – Textbook

    1
    Problem 13. A sample of an ideal gas is taken through the cyclic process
    abca shown in the figure below; at point a, T=200 K. (a) How many
    moles of gas are in the sample? What are (b) the temperature of the gas
    at point b, (c) the temperature of the gas at point c, and (d) the net
    energy added to the gas as heat during the cycle?

    (a) Applying the equation of state:


    pV
    pV  nRT  n 
    RT
    At point a, p=2.5 kN/m2 or 2500 N/m2;
    V=1 m3; T = 200 K
    2500 1
    n  1.5 (mol)
    8.31 200
    (b) pV  nRT  pbVb  nRTb
    At point b, p=7.5 kN/m2 or 7500 N/m2;
    V=3 m3.
    pbVb 7500  3
    Tb    1800 (K)
    nR 1.5  8.31
    2
    pV  nRT  pcVc  nRTc
    (c) Tc=600 K;
    (d) Applying the first law of thermodynamics:

    E  Q  W
    W: work done by the system.

    For a closed cycle, E=0:


    Q W
    1
    W  ( pb  pc )(Vb  Va )
    2
    1
    W   5000.0  2  5  10 (J)
    3
    2

    3
    Problem 14. In the temperature range 310 K to 330 K, the pressure p of
    a certain non-ideal gas is related to volume V and temperature T by:
    2
    T T
    p  (24.9 J / K )  (0.00662 J / K 2 )
    V V
    How much work is done by the gas if its temperature is raised from
    315 K to 330 K while the pressure is held constant?

    Work done by the gas is computed by the following formula:

    W  VVi f pdV  p (V f  Vi ) Due to the constant pressure process

    W  pV f  pVi  24.9(T f  Ti )  0.00662(T f2  Ti2 )

    T f  330K ; Ti  315K  W  310 (J)

    4
    Problem 20. Calculate the rms speed of helium atoms at 1000 K, the
    molar mass of helium atoms is 4.0026 g/mol.

    3RT 3  8.31 1000


    vrms   3
     2 . 5  10 3
    (m/s)
    M 4.0026  10

    5
    Problem 24. At 273 K and 1.0 x 10-2 atm, the density of a gas is 1.24 x
    10-5 g/cm3. (a) Find vrms for the gas molecules. (b) Find the molar mass
    of the gas and (c) identify the gas (hint: see Table 19-1).

    (a) Root-mean-square speed:


    3RT
    vrms  (1)
    M
    M gas nM V
      M  (2)
    V V n
    3nRT 3p
    (1) and (2): vrms   pV  nRT (3)
    V 
      1.24  10 5 g/cm 3  1.24  10 2 kg/m 3
    p  1.0  10 2 atm  1.01103 Pa
    vrms  494 m/s
    6
    V
    (b) M  ( 2)
    n
    Equation of state:
    pV  nRT (3)

    V RT
    M  
    n p

     M  0.028 kg/mol  28 g/mol

    (c) From Table 19.1,


    the gas is nitrogen (N2)

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