QUIZ VII

The following x-y-T data are at 1 atm of a binary solution of ethanol(1) and water(2):
x1 y1 T (oC) x1 y1 T (oC)
0.0190 0.1700 95.5 0.3273 0.5826 81.5
0.0721 0.3891 89.0 0.3965 0.6122 80.7
0.0966 0.4375 86.7 0.5079 0.6564 79.8
0.1238 0.4704 85.3 0.5198 0.6599 79.7
0.1661 0.5089 84.1 0.5732 0.6841 79.3
0.2337 0.5445 82.7 0.6763 0.7385 78.74
0.2608 0.5580 82.3 0.7472 0.7815 78.15
The vapour pressure for the pure species are given as follows:
3578.91 3841.20
ln P1sat = 18.5242 - ln P2sat = 18.3443 -
(T - 50.51) (T - 45.16 )
with, Pisat in mm Hg and T in K.
Margules equations assume that GE/RT as a function of x1, as follows:
GE = x1x2 [B12 + (B21 - B12 )x1 ]
RT
And, also to the van Laar equations:
x1 x2 1 æ 1 1 ö
= + ç - ÷ x1
[G E RT ]
A12 çè A21 A12 ÷ø 20
 QUIZ VII - contd
(a) By plotting suitable diagram in ExcelÒ, determine the Margules and van Laar
constants.
(b) Determine the bubblepoint and the equilibrium composition at 760 mm Hg for a
liquid that consists of 9.66% mol ethanol through both Margules and van Laar
equations.
(c) Determine the dewpoint and the equilibrium composition at 760 mm Hg for a
vapour that consists of 61.22% mol ethanol through both Margules and van Laar
equations.
(d) Determine the total pressure and the vapour composition for a mixture of 50%
mol at 25oC through both Margules and van Laar equations.
(e) With the help of Symmetry/HysisÒ software, repeat parts (b), (c) and (d) by
setting different methods to estimate the activity coefficients and phi. Compare
the answers in the form of table. Attach the analysis sheet from the
Symmetry/Hysis Ò.

Due date for submission: 31st Dec 2021

21
b) Bubble T

Given P = 76ommit X ,
= 0 .
0966
,
X2 = 0 9034
.

Find T & Y
,

C) Dew T

Given P= 76ommig , y1 =
0 6122
.

Yo =
0 3878
.

Find T ,
XI

d) Bubble P

29815k :50 X2 0 50
T 25 %
.

X
=
= .
=
=
/

Find P , Y
Margules
Margules
Margules
 You haar

P =
760mmHy X1 = 0 . 0966 Xc = 0 90st .

In (760) 18 5242 3578 91 In 760 18 3443 3841 20

. -
= .
- .
= .

T , Sat-50 .
5,
TzSat - 45 16.

↑Sat
Sat 373 1598k
T 351 4894k
.
=
, = .

Sat +
Toss

Van Laar
T.
Tguess =
X, + X2

= (0 . 0966) (351 4894) ·

+ 10 .
9034) (373 1598) ·

Tguess = 371 . 066 K

(nd
Am)1 + ( In 62
As)1 + 7
=
=

L 2

07245)(1
(0
30)(1 133000ano
- -

(3 10.0754(0 9034)
0966)
= .
=
+
- .

(2 30)(0
.
.

Ind = 0 .
0958 (nd2 = 0 . 04987

Y = 1 .
1005 Ja = 1 0511
.

St *+
In P , = 18 .
5242 -

3578 91 .
In 42 = 18 3443 .
-

3841 .
20

(271 066) .
-
50 51.

(371 . 06) -
45.
/6)
Sat Sat
p
, ↑ 704 9166 motty
= 1571 .
0566 mmHg = .

↓=
= 1571 . 0586

704 9166 .

X = 2 .
1287
Van Laar
Margules
Indi = (05568/27 :
4994 + 2(0 9645
.
- 1 .
4994)(0 4432) -

1n02 = (0 .
44323% . 9845 + 2(1 - 4994 -
0 .
9845)(0 ·

5568)
- -

In + 1
= 0 . 3033) In 62 = 0 -

3060

61 = 1 .
3818 ↓2 = 1 3580
.

+ ( jr)
Margules
4
, =
+

(760) 0 6124
03878
= .

+ (2A

-13818 -

p sat
, -
867 .
8337 mmHg

3578 91
In (87 8337) 5242
.

- =
18 .
-

Tcak -50 .
1

Trak = 353 . 2590k + Tguess

Margules
Van Laar
Van Laar
Van Laar
Van Laar
Margules
Van Laar
 VLE Given values Manual / iCON Method for Gamma Method for Phi Calculated
Calculations values
P x T y
BUBBLE T Manual Margules -
Manual Van Laar -
iCON

VLE Given values Manual / iCON Method for Gamma Method for Phi Calculated values
Calculations P y T x
DEW T Manual Margules -
Manual Van Laar -
iCON

VLE Given values Manual / iCON Method for Gamma Method for Phi Calculated values
Calculations T x P y
BUBBLE P Manual Margules -
Manual Van Laar -
iCON

22