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    Practical-1 Sodium Hydroxide

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    Abdulbhai
    The document describes a procedure to standardize a 0.1M sodium hydroxide solution by titrating it against potassium hydrogen phthalate using phenolphthalein as an indicator. It provides the chemical reaction, calculations to determine the molarity, and the steps to standardize the sodium hydroxide solution and calculate its exact concentration.

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    Practical-1 Sodium Hydroxide

    Uploaded by

    Abdulbhai
    13 views2 pages
    The document describes a procedure to standardize a 0.1M sodium hydroxide solution by titrating it against potassium hydrogen phthalate using phenolphthalein as an indicator. It provides the chemical reaction, calculations to determine the molarity, and the steps to standardize the sodium hydroxide solution and calculate its exact concentration.

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    Medicinal chemistry

    Original Title

    Practical-1 sodium hydroxide

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    The document describes a procedure to standardize a 0.1M sodium hydroxide solution by titrating it against potassium hydrogen phthalate using phenolphthalein as an indicator. It provides the chemical reaction, calculations to determine the molarity, and the steps to standardize the sodium hydroxide solution and calculate its exact concentration.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    13 views2 pages

    Practical-1 Sodium Hydroxide

    Uploaded by

    Abdulbhai
    The document describes a procedure to standardize a 0.1M sodium hydroxide solution by titrating it against potassium hydrogen phthalate using phenolphthalein as an indicator. It provides the chemical reaction, calculations to determine the molarity, and the steps to standardize the sodium hydroxide solution and calculate its exact concentration.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    Aim: To Prepare And Standardize 0.1M Sodium Hydroxide Solution.

    Requirements: Conical flask, burette, pipette, volumetric flask, funnel


    Reagents: sodium hydroxide, phenolphthalein, potassium hydrogen phthalate (KHP)

    Theory: The principle involved in standardization of sodium hydroxide neutralization titration.


    It is standardized against acidic primary standard potassium hydrogen phthalate, using
    phenolphthalein as an indicator (acidimetry-alkalimetry or neutralization reaction).
    Primary standard compound, potassium hydrogen phthalate of analytical grade has purity of
    99.9% and almost non hygroscopic. standardization of sodium hydroxide is necessary because it
    is hygroscopic in nature (i.e..absorbs moisture and gets liquefied) Further, it available in the form
    of pellets. Hence, exact concentration of solution cannot be prepared.

    Chemical reaction:

    Factor:
    From reaction,
    1 mole NaOH = 1 mole KHP
    1000ml of 1M sodium hydroxide = 204.23g of KHP
    1ml of 1M sodium hydroxide = 0.20423g of KHP
    1ml of 0.1M sodium hydroxide= 0.020423g of KHP

    Procedure:
    Preparation of 0.1M sodium Hydroxide: Weigh accurately 4 g of sodium hydroxide, transfer
    to 1000 ml volumetric flask, dissolve in a small quantity of water and make up the volume upto
    the mark with distilled water.
    Standardization of sodium hydroxide: Weigh accurately 0.2 g of potassium hydrogen
    phthalate; dissolve in 10ml of carbon dioxide free water. Add 2-3drops of phenolphthalein and
    titrate with the prepared sodium hydroxide solution until the color changes from colorless to
    pink.
    Each ml of 0.1 M sodium hydroxide is equivalent to 0.02046g of KHP, C8H5O4K

    Result: The exact molarity of prepared 0.1M sodium hydroxide is ……………..M.


    Preparation of 0.1M sodium hydroxide:
    Molecular weight of sodium hydroxide= 40g/mole
    Molarity,

    𝑤𝑒𝑖𝑔ℎ𝑡 𝑖𝑛 𝑔 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒 1
    M = 𝑀𝑜𝑙𝑒𝑐𝑢𝑙𝑎𝑟 𝑤𝑒𝑖𝑔ℎ𝑡 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒 ∗ 𝑣𝑜𝑙𝑢𝑚𝑒 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛 (𝐿)

    weight of solute (g) = 0.1 * 40 * 1


    = 4.0 g sodium hydroxide
    Standardization of 0.1M sodium hydroxide:
    Observations:
    Burette: ..x..M sodium hydroxide
    Conical flask: 0.2 g potassium hydrogen phthalate (KHP) + 10 ml water
    Indicator: Phenolphthalein
    End point: Colorless to light pink

    Observation Table:

    Sr. Burette Reading (ml) Average


    No. Final Initial Difference (ml)

    Burette reading: ………… ml of …x… M sodium hydroxide

    Calculations:

    Each ml of 0.1 M sodium hydroxide is equivalent to 0.020423g of KHP, C8H5O4K

    1 ml of 0.1 M sodium hydroxide  0.020423g of KHP


    …B.R.…ml of …x… M sodium hydroxide = 0.2 g KHP

    …B.R….. * x * 0.020423 = 1 * 0.1 * 0.2


    x = 0.1 * 0.2/ B.R * 0.020423
    = …… M sodium hydroxide
    OR

    Exact molarity of sodium hydroxide,


    weight in mg of PSC 1
    M= equivalent weight of PSC ∗ burette reading (mL)

    = 200 / (204.23 * B.R)

    = ……………..M sodium hydroxide

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