JEE Advanced CRT 4 Paper 2

In JEE Advanced 2016, FIITJEE Students bag 36 in Top 100 AIR, 75 in Top 200 AIR, 183 in Top 500
AIR. 3541 Students from Long Term Classroom/ Integrated School Program & 4423
FIITJEE JEE (Advanced), 2017
CONCEPT RECAPITULATION TEST - IV
Paper 2
Time Allotted: 3 Hours Maximum Marks: 186

 Pl ea s e r ea d t h e i n s t r u c t i o n s c a r ef u l l y. Yo u a r e a l l o t t ed 5 m i n ut es
s p ec i f i c a ll y f o r t h i s p u r p o s e.
 Yo u a r e n o t a l l o wed t o l ea v e t h e E xa m i n at i o n Ha l l b ef o r e t h e en d o f
ALL INDIA TEST SERIES
t h e t es t .
INSTRUCTIONS
Students from All Programs have qualified in JEE Advanced, 2016
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each part has only one section: Section-A.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
B. Filling of OMR Sheet
1. Ensure matching of OMR sheet with the Question paper before you start marking your answers
on OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with black pen for each character of your
Enrolment No. and write your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Three Parts.
(i) Section-A (01 to 06) contains 6 multiple choice questions which have only one correct answer.
Each question carries +3 marks for correct answer and – 1 mark for wrong answer.
Section-A (07 to 14) contains 8 multiple choice questions which have one or more than one
correct answer. Each question carries +4 marks for correct answer and – 2 mark for wrong
answer.
Section-A (15 – 18) contains 4 Paragraph Type questions: Each question has FOUR options
(A), (B), (C) and (D). ONLY ONE of these four options is correct. Each question carries +3
marks for correct answer. There is no negative marking.
Name of the Candidate
Enrolment No.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
2
AITS-CRT-IV-(Paper-2)-PCM-JEE(Advanced)/17
Useful Data
PHYSICS
Acceleration due to gravity g = 10 m/s2
Planck constant h = 6.6 1034 J-s
Charge of electron e = 1.6  1019 C
Mass of electron me = 9.1  1031 kg
Permittivity of free space 0 = 8.85  1012 C2/N-m2
Density of water water = 103 kg/m3
Atmospheric pressure Pa = 105 N/m2
Gas constant R = 8.314 J K1 mol1
CHEMISTRY
Gas Constant R = 8.314 J K1 mol1

= 0.0821 Lit atm K1 mol1
= 1.987  2 Cal K1 mol1
Avogadro's Number Na = 6.023  1023
Planck’s constant h = 6.625  1034 Js
= 6.625  10–27 ergs
1 Faraday = 96500 coulomb
1 calorie = 4.2 joule
1 amu = 1.66  10–27 kg
1 eV = 1.6  10–19 J
Atomic No: H=1, He = 2, Li=3, Be=4, B=5, C=6, N=7, O=8,

N=9, Na=11, Mg=12, Si=14, Al=13, P=15, S=16,
Cl=17, Ar=18, K =19, Ca=20, Cr=24, Mn=25,
Fe=26, Co=27, Ni=28, Cu = 29, Zn=30, As=33,
Br=35, Ag=47, Sn=50, I=53, Xe=54, Ba=56,
Pb=82, U=92.
Atomic masses: H=1, He=4, Li=7, Be=9, B=11, C=12, N=14, O=16,
F=19, Na=23, Mg=24, Al = 27, Si=28, P=31, S=32,
Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59,
Ni=58.7, Cu=63.5, Zn=65.4, As=75, Br=80, Ag=108,
Sn=118.7, I=127, Xe=131, Ba=137, Pb=207, U=238.
3
Physics PART – I
SECTION – A
Straight Objective Type
This section contains 6 multiple choice questions numbered 1 to 6. Each question has 4 choices (A),
(B), (C) and (D), out of which only ONE is correct
1. A particle is projected from a point O with velocity u in a direction making an angle  with the
horizontal. At P, it is moving at right angles to its initial direction of projection. Its speed at P is
(A) u tan  (B) u cot 
(C) u cosec  (D) u sec 
2. A block of mass m moving with velocity v strikes elastically another

identical mass connected to a spring as shown in figure. The
k
maximum compression produced in the spring (Assume surfaces to m v m
be smooth) is
mv 2 mv 2
(A) (B)
2k k
mv 2
(C) (D) none of these
3k
3. A block of mass 20 kg and volume 103 cm3 is suspended vertically from a ceiling by a wire. The
linear mass density of the wire is 5  10–3 kg/m and its length is 50 cm. The wire is vibrating in its
fundamental mode and producing beats with a tuning fork of frequency 190 Hz. When the block
is just completely immersed in a liquid and vibrated in its fundamental mode, it produces the
same number of beats with tuning fork as earlier. Density of the liquid is (g = 10 m/s2)
(A) 3.8 gm/cm3 (B) 7.6 gm/ cm3
3
(C) 1.9 gm/ cm (D) 5.0 gm/ cm 3
4. A vertical cylinder with a massless piston filled with one mole of an ideal gas. The piston can
move freely without friction. The piston is slowly raised so that the gas expands isothermally at
temperature 300 K. The amount of work done in increasing the volume by two times is
25
(R  J/mol/K , loge 2 =0.7)
3
(A) 1750 J (B) 2500 J
(C) 750 J (D) 4250 J
Space for rough work
4
5. In Young’s double slit experiment, double slit of separation 0.1 cm is illuminated by white light. A
coloured interference pattern is formed on a screen 100 cm away. If a pin hole is located on this
screen at a distance of 2 mm from the central fringe, the wavelength in the visible spectrum which
will be absent in the light transmitted through the pin-hole are
(A) 5714 Å and 4444 Å (B) 6000 Å and 5000 Å
(C) 5500 Å and 4500 Å (D) 5200 Å and 4200 Å
6. The figure shows the variation of photo current with anode Photo current
potential for a photo-sensitive surface for three different
radiations. Let Ia, Ib and Ic be the intensities and fa, fb and fc c
be the frequencies for the curves a, b and c respectively; b a
(A) fa  fb and I a  I b
(B) fa  fc and Ia  IC
O Anode potential
(C) fa  fb and I a  Ib
(D) f b  f c and Ib  Ic
Multiple Correct Choice Type

This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for
its answer, out of which only ONE OR MORE THAN ONE is/are correct
7. A particle is acted upon by a force of constant magnitude which is always perpendicular to the
velocity of the particle. The motion of the particle takes place in a plane. It follows that
(A) its velocity is constant (B) its acceleration is constant
(C) its kinetic energy is constant (D) it moves in a circular path
8. A rod of mass ' M  m' carries an insect of mass ‘m’ at its bottom end
and its top end is connected with a string which passes over a smooth
pulley and the other end of the string is connected to a counter mass M.
Initially the insect is at rest. Choose the correct option(s).
(A) As insect starts moving up relative to rod, the acceleration of centre of M
mass of the system (insect + rod + counter mass) becomes non-zero M m
(B) As insect starts moving up relative to rod, tension in the string remains
constant and is equal to Mg. m
(C) As insect starts moving up relative to rod, the tension in the string becomes more than Mg.
(D) Acceleration of centre of mass of the system (insect + rod +counter mass) is zero when insect
moves with constant velocity.
5
9. A particle of mass m moves in a straight line. If v is the velocity at a distance x from a fixed point
2 2
on the line and v  a  bx , where a and b are constant, then
(A) The motion continues along the positive x-direction only
(B) The motion is simple harmonic
b
(C) The particle oscillates with a frequency equal to
2
(D) The total energy of the particle is ma
10. 10 gms of ice at 00C is mixed with 5 gms of steam at 1000C. If latent heat of fusion of ice is 80
cal/gm and latent heat of vaporization is 540 cal/gm. Then at thermal equilibrium
(A) temperature of mixture is 00C
(B) temperature of mixture is 1000C
(C) mixture contains 13.33 gms of water and 1.67 gms of steam
(D) mixture contains 5.3 gms of ice and 9.7 gms of water
11. In the given circuit the value of m is varying. The correct statements x
about the circuit are +
(A) The condition for maximum current flowing from x is m =2.
V mr
(B) The maximum current is . mr
2r V
(C) The condition for maximum current flowing from x is m = 2.
(r/m)
3V
(D) The maximum current is . y
2r –
12. Two straight conducting rails form a right angle where their ends are
joined. A conducting bar in contact with the rails start at the vertex at
t  0 and moves with a constant velocity v along them as shown. A 
magnetic field B is directed into the page. The induced emf in the v
circuit at any time t is proportional to
(A) t 0 (B) t
(C) v (D) v 2
6
13. The value of d for which the final image coinside with the object is/are:
f  15 cm R  20cm

O
30cm d
(A) 10 cm (B) 20cm
(C) 30 cm (D) 40cm
14. Hydrogen gas absorbs radiations of wavelength 0 and consequently emit radiations of 6 different
wavelengths of which two wavelengths are shorter than 0. Choose the correct statement(s).
(A) The final excited state of the atom is n = 4
(B) The initial state of the atom may be n = 2
(C) The initial state of the atom may be n = 3
(D) There are three transitions belonging to Lyman series.
Comprehension Type
This section contains 2 groups of questions. Each group has 2 multiple choice question based on a
paragraph. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which only ONE is
correct
Paragraph for Questions 15 & 16
Two capacitors of capacity 6 F and 3F are charged to 100V and 50V separately and connected as
shown in figure. Now all the three switches S1, S2 and S3 are closed.
6F 3F
1 +– 2 3 +– 4
+ –– + ––
+ S2 +
100V 50V
S1
S3
200V
15. Charges on the 6F capacitor in steady state will be

(A) 400 C (B) 700 C
(C) 800 C (D) 250 C
7
16. Suppose q1, q2 and q3 be the magnitudes of charges flown from switches S1, S2 and S3 after they
are closed. Then
q2
(A) q1  q 3 and q2 = 0 (B) q 1  q 3 
2
(C) q1  q 3  2q 2 (D) q1  q 2  q 3
Paragraph for Questions 17 & 18
In physics laboratory, Peter is trying to calculate the focal lengths of a convex lens. He measures the
distance between a screen and a light source lined up on the optical bench to be 120 cm. When Peter
shifts the convex lens along the axis of optical bench, sharp images of the source is obtained at two lens
positions. He also measures the ratio of these two magnifications to be 1 : 9.
17. The focal length of the convex lens measured by Peter is

(A) 22.5 cm (B) 30 cm
(C) 45 cm (D) none of these
18. Which image, as seen by Peter is brighter?

(A) smaller (B) bigger
(C) both are equally bright (D) cannot be judged
8
Chemistry PART – II
SECTION – A
1. In a crystal structure of an element, atoms are present in fcc arrangement as well as in

tetrahedral voids. Which of the following relation between the atomic radius and the edge length
is correct?
(A) 2 a  4r (B) 3a  8r
(C) 3a  4r (D) a  2r
2. Which of the following does not contain transition metal?

(A) Haemoglobin (B) Vitamin B12
(C) Cis – platin (D) Chlorophyll
3. Which one of the following reactions is not correct?

(A) CH 3COOK  CF3COOH   CH 3COOH  CF3COOK
(B) OH ONa
NO2 NO2 NO2 NO2
+ NaHCO3 + CO     H O
2 2
NO2 NO2
(C)

+ NH4
+ + NH3
N N
N H N
(D)  CH 3CH 3ONa  H 2O  CO2   

CH 3CH 2OH  NaHCO3 
9
4. The stopping potentials in an experiment of photoelectric effect are V1 and V2 , with incident light

of wavelength  and respectively. The correct relation between V1 and V2 may be:
2
(A) V2  2V1  V1 (B) V1  V2  2V1
(C) V2  2V1 (D) V2  2V1
5. Cl Cl
Cl Cl
The dipole moment of is 1.5 D . The dipole moment of is :
Cl Cl Cl
Cl
(A) zero (B) 1.5 D
(C) 2.6 D (D) 2.12 D
6. Which of the following is not the compound of aluminium?

(A) anhydrite (B) bauxite
(C) corundum (D) Diaspore
7. Which of the following relation is/are correct about NaCl structure ( a is the edge length and r is
the radius of atom)?

(A)  a   2  rCl  
(B)   
2  a  4  rCl  

(C)  a   2 rCl   rNa  
(D) Cl  ions have expended fcc arrangement
10
8. When 5 mL of a 1.0 M HCl solution is mixed with 5 mL of a 0.1M NaOH solution,

temperature of solution increases by t C . Which of the following(s) can be predicted from this
observation:
(A) If 5 mL of 0.1M HCl is mixed with 5 mL 0.1 M NH 3 solution, the temperature rise will be
less than t C
(B) If 5 mL 0.1 M CH 3COOH is mixed with 5 mL 0.1 M NaOH , the temperature rise will be
less than t C
(C) If 10 mL of 1.0 M HCl is mixed with 10 mL of 0.1 M NaOH, the temperature rise will be 2t C .
(D) If 10 mL of 0.1 M HCl is mixed with 10 mL of 0.1 M NaCl, the temperature rise will be t C
9. Identify correct statement/statements from the following options:
(A) has aromatic system
(B) has cyclic 6  e  system


N
H H
(C)
Marked hydrogen in is more acidic then marked hydrogen in
(D) is unstable at room temperature
11
10. Which will show geometrical isomerism?

(A) H3C CH Me Me Me Me
NOH
(B)
Et Me Me Et
H3C (D) HO N
(C)
C NOH N OH
H3C
11. Identify the chiral molecule/molecules:

(A) H3C H
CH3
H (B) C C C C
NO2
O2N
(C) H3C CH3
(D)
CH3
12. Which of the following is/are can produce H2O2 on hydrolysis?

(A) BaO2 (B) PbO2
(C) MnO2 (D) Na2O2
12
13. The correct statement/statements is/are:

(A) The distance between two octahedral voids of a cubic close packing of atoms with radius r
is 2r
(B) The distance between two tetrahedral voids of a cubic close packing of atoms with radius r is
6  r at the body diagonal axes
3
(C) The distance between tetrahedral and octahedral void is  r , where is the radius of atom
2
forming the close packing
(D) The distance between the surface of atoms fcc arrangement along an edge is 2  
2 1 r
14. Identify the correct relationship:

2
(A) Cu  NH 3  4  with Hybridization of Cu  dsp 2
(B) Fe  CO  x with x  5
(C) Zn 2 Complexes with sp 3d 2 hybridization are diamagnetic in nature
3
(D) Cr Complexes with Paramagnetic nature
Comprehension Type
correct
Paragraph for Question Nos. 15 to 16
Assume that water vapour behaves as an ideal gas and the volume occupied by the liquid water is
negligible compared to the volume of the container. A sample of liquid water of mass 3 g is injected into
an evacuated 76 L flask maintained at 320 K. At this temperature the vapour pressure of water is 32 mm
of Hg:
Now give the answers to following questions:
15. What % of the water will be vaporised, when the system comes to equilibrium:
(A) 18% (B) 73%
(C) 30% (D) 64%
16. What should be the minimum volume of the flask if no liquid water is to be present at equilibrium?
(A) 174L (B) 150L
(C) 104L (D) 126L
13
White phosphorus is a tetra atomic solid  P4  s   at room temperature and on strong heating in absence
of oxygen, it polymerizes into red phosphorus as:
P P P
P P P P P P H=-104KJ/mol of P4
P P P
White  g  red  g 
The enthalpy of sublimation  P4  s  
 P4  g   white is 59 KJ/mol and enthalpy of atomization is
316.25 KJ/mol of P  g  .
Now give the answers of following questions:
17. The average P  P bond enthalpy in P4 molecule is:

(A) 102 KJ (B) 201KJ
(C) 104 KJ (D) 120 KJ
18. The P  P bond enthalpy in red phosphorus joining the two tetrahedral is:
(A) 201KJ (B) 104 KJ
(C) 305 KJ (D) 80 KJ
14
Mathematics PART – III
SECTION – A
1. If z0 =
1 i
2
  2
  n

, then the value of the product 1  z 0  1  z 02 1  z 20 ..........1  z 20 must be
2 n 1  1 
(A) 2 (B) 1  i 1  n , if n  1
 22 
5
(C) 1  i , if n  1 (D) 0
4
N
2. Let N be any four digit number say x 1 x2 x3 x4. Then maximum value of is equal
x1  x 2  x3  x 4
to
1111
(A) 1000 (B)
4
(C) 800 (D) None of these
e cot x
3.  sin2 x [2 ln cosec x + sin 2x] dx is equal to
(A)  2ecotx ln (cosec x) + c (B) ecotx ln x + c

(C) ecotx (ln (cosec x) + c (D) none of these
4. Let P be any moving point on the circle x 2 + y2  2x = 1. AB be the chord of contact of this point
w.r.t the circle x 2 + y2  2x = 0. The locus of the circumcentre of the triangle CAB, (C being centre
of the circles) is
(A) 2x2 + 2y2  4x + 1 = 0 (B) x2 + y2  4x + 2 = 0
(C) x2 + y2  4x + 1 = 0 (D) 2x2 + 2y2  4x + 3 = 0
15
5. ABCD is a quadrilateral with side lengths AB = 4, BC = 10, CD = 6 and AD = 6, and diagonal BD

= 8 units. If the incircles of triangles ABD and BCD touch BD at P and Q respectively, then area
of quadrilateral C1PC2Q (where C1 and C2 are incentres of triangle ABD and BCD respectively), is
5 15
(A) 3  sq. units (B) 3 sq. Units
2
15
(C) sq. units (D) none of these
6
sin 1 x  tan 1 x
6. lim is equal to
x 0 x3
1 1
(A) (B)
6 2
1
(C) 2 (D) 
2
7. Consider the equation tan (5 cos ) = cot (5 sin ) for   (0, 2), then
(A) number of real solution is 28 (B) number of real solution is 14
2n  1 2n  1
(C) sin  + cos  = (D) sin  – cos  =
10 10
8. Three straight lines are drawn through a point ‘P’ lying in the interior of the ABC and parallel to
its sides. The areas of the three resulting triangles with P as the vertex are s1, s2 and s3 then area
of ABC =
2
(A)  s1  s2  s3  (B) (s1 + s2 + s3)
(C) s1s2  s2 s3  s3 s1 (D) s1 + s2 + s3 + 2  s1s2  s2 s3  s3 s1 

200
9. If k denotes the remainder on dividing  r ! by n then (k, n) can be
r 1
(A) (5, 14) (B) (1, 3)
(C) (3, 10) (D) (3, 15)
16
 1 0
10. The square roots of the matrix   are
0 1
 1 0  1 0 
(A)    (B)   
 0 1  0 1 
1 0 1 1
(C)    (D)   
 0 1 1 1
1 | x |
11. Range of the function f ( x )  contains
2 | x |
(A) [0,1) (B) [1, 2)
(C) (1, 2) (D) (2,  )
12. In ABC , if A  45, B  75 then

(A) a  2c  2b (B) 3a  2c
(C) a   
3 1 b (D) 3a  5b

13. Equation of plane through A(1,0, 0), B (0,1, 0) and making an angle with the plane x  y  3
4
can be
(A) x  y  2 z  1 (B) x  y  2 z  1
(C) x  y  2 z  1 (D) x  y  2 z  1
9
14. If the area bounded by the curve y  x  x 2 and the line y = mx equals . Then the value of
2
m is:
(A)  4 (B) 2
(C) 2 (D) 4
17
Comprehension Type
correct

7
Locus of the centre of a circle touching the circle x2 + y2 – 4y – 2x = internally and tangents on which
4
from (1, 2) is making an angle 60o with each other is director circle (C) of a variable ellipse E. On this
basis given answers to the following questions
15. The equation of the director circle (C) is

2 2 2 2
(A)  x  2    y  1  3 (B)  x  1   y  2   3
2 2 2 2
(C)  x  1   y  2   3 (D)  x  1   y  2   3
16. Locus of focus of variable ellipse(E) when major axis is parallel to x–axis, is
 3 
(A)  x, y  /
2
| x  1 | 3 and y  2  (B) x, y  / 0 | x | 3 and y  2
 

(C)  x , y  / 0 | x  1 | 3 and y  2  (D)  x , y  / 0 | x  1 | 3 and y  2
18
Let S = {1, 2, 3,…..n} be a set and two numbers x and y are drawn with replacement from S. Let Pk be the
probability that x2 – y2 is divisible by k & [x] denotes greatest integer less than or equal to x.
17. The value of P2 is equal to

2
 n 
 
1  2 
(A) (B)
2  n 
 
 
2 2
n  n   n  n 
 2    2   
2 2 2
 2    
(C) 1  2. (D) 1   2   
n  n  n  n 
   
   
18. The value of P3 is equal to

2
n   n 
3  
(A)
  (B)
 3 
n  n 
 
 
2 2
n   n   n  n 
 3    3    3    3  
(C) 1    (D) 1  2.  
n  n  n  n 
   
   

JEE Advanced CRT 4 Paper 2

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JEE Advanced CRT 4 Paper 2

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In JEE Advanced 2016, FIITJEE Students bag 36 in Top 100 AIR, 75 in Top 200 AIR, 183 in Top 500

Time Allotted: 3 Hours Maximum Marks: 186

Name of the Candidate

Planck constant h = 6.6 1034 J-s

Charge of electron e = 1.6  1019 C

Mass of electron me = 9.1  1031 kg

Permittivity of free space 0 = 8.85  1012 C2/N-m2

Density of water water = 103 kg/m3

Atmospheric pressure Pa = 105 N/m2

Gas constant R = 8.314 J K1 mol1

Gas Constant R = 8.314 J K1 mol1

Atomic No: H=1, He = 2, Li=3, Be=4, B=5, C=6, N=7, O=8,

Straight Objective Type

2. A block of mass m moving with velocity v strikes elastically another

Space for rough work

Multiple Correct Choice Type

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Space for rough work

Paragraph for Questions 15 & 16

15. Charges on the 6F capacitor in steady state will be

Space for rough work

Paragraph for Questions 17 & 18

17. The focal length of the convex lens measured by Peter is

18. Which image, as seen by Peter is brighter?

Space for rough work

Straight Objective Type

1. In a crystal structure of an element, atoms are present in fcc arrangement as well as in

2. Which of the following does not contain transition metal?

3. Which one of the following reactions is not correct?

(D)  CH 3CH 3ONa  H 2O  CO2   

Space for rough work

6. Which of the following is not the compound of aluminium?

Multiple Correct Choice Type

8. When 5 mL of a 1.0 M HCl solution is mixed with 5 mL of a 0.1M NaOH solution,

9. Identify correct statement/statements from the following options:

(A) has aromatic system

(B) has cyclic 6  e  system

(D) is unstable at room temperature

Space for rough work

10. Which will show geometrical isomerism?

11. Identify the chiral molecule/molecules:

12. Which of the following is/are can produce H2O2 on hydrolysis?

Space for rough work

13. The correct statement/statements is/are:

14. Identify the correct relationship:

Paragraph for Question Nos. 15 to 16

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Paragraph for Question Nos. 17 to 18

17. The average P  P bond enthalpy in P4 molecule is:

Space for rough work

Mathematics PART – III

Straight Objective Type

(A)  2ecotx ln (cosec x) + c (B) ecotx ln x + c

Space for rough work

5. ABCD is a quadrilateral with side lengths AB = 4, BC = 10, CD = 6 and AD = 6, and diagonal BD

Multiple Correct Choice Type

(C) s1s2  s2 s3  s3 s1 (D) s1 + s2 + s3 + 2  s1s2  s2 s3  s3 s1 

Space for rough work

12. In ABC , if A  45, B  75 then

Space for rough work

Paragraph for Question Nos. 15 to 16

15. The equation of the director circle (C) is

Space for rough work

Paragraph for Question Nos. 17 to 18