FINAL JEE–MAIN EXAMINATION – JANUARY, 2024

(Held On Tuesday 30th January, 2024) TIME : 9 : 00 AM to 12 : 00 NOON

MATHEMATICS TEST PAPER WITH SOLUTION

SECTION-A 15 5
S15  S5   2a  14d    2a  4d 
1. A line passing through the point A(9, 0) makes an angle 2 2
of 30º with the positive direction of x-axis. If this line is 15 5
  16  70   16  20
rotated about A through an angle of 15º in the clockwise 2 2
direction, then its equation in the new position is = 405-10
y x = 395
(1) x9 (2)  y9
32 32 3. If z = x + iy, xy  0 , satisfies the equation

(3)
x
(4)
y z 2  i z  0 , then |z2| is equal to :
 y9 x9
32 32 (1) 9
Ans. (1) (2) 1
(3) 4
1
Sol. (4)
4
Ans. (2)
Sol. z 2  iz
z 2  iz
|z2| = |z|
|z|2 – |z| = 0
|z|(|z| – 1) = 0
|z| = 0 (not acceptable)
Eqn : y – 0 = tan15° (x – 9)  y = (2  3 (x  9)  |z| = 1
 |z|2 = 1
2. Let Sa denote the sum of first n terms an arithmetic
4. Let a  a i ˆi  a 2ˆj  a 3kˆ and b  b1ˆi  b2ˆj  b3kˆ be
progression. If S20 = 790 and S10 = 145, then S15 –
S5 is : two vectors such that a  1; a.b  2 and b  4. If
(1) 395
(2) 390
 
c  2 a  b  3b , then the angle between b and c
is equal to :
(3) 405
 2 
(4) 410 (1) cos 1  
 3
Ans. (1)
 1 
20 (2) cos 1  
Sol. S20   2a  19d   790 

3
2
2a + 19d = 79 …..(1)  3
(3) cos1  
 2 
S10 
10
 2a  9d   145  
2
2
2a + 9d = 29 …..(2) (4) cos1  
3
From (1) and (2) a = -8, d = 5
Ans. (3)
Sol. Given a  1, b  4, a.b  2 (0, 0)
Sol.
 
c  2 a  b  3b

Dot product with a on both sides

c.a  6 …..(1) (x, y) (-x, y)
Dot product with b on both sides Area of 
b.c  48 …..(2) 0 0 1
1
2 2   x y 1
c.c  4 a  b  9 b 2
x y 1
 2 2
 
2 2 2
c  4  a b  a.b   9 b 1
     xy  xy   xy 
2
c  4 1 4    4   9 16 
 
2 2
   Area     xy  x 2x 2  54 

c  412  144
2
d
2

dx

 6x 2  54   d
dx
 0 at x = 3
c  48  144
Area = 3 (-2 × 9 + 54) = 108
2
c  192 n
n3
6. The value of lim  is :
 cos  
b.c n  k 1
 
n 2  k  n 2  3k 2 
b c

48 (1)
2 33  
 cos   24
192.4
13
48 (2)
 cos  
8 3.4

8 4 3 3 
 cos  
3
(3)

13 2 3  3  
2 3 8
 3  3 
 cos     cos1  (4)
2

 2  
8 2 3 3 
5. The maximum area of a triangle whose one vertex Ans. (2)
is at (0, 0) and the other two vertices lie on the n
n3
curve y = -2x2 + 54 at points (x, y) and (-x, y) Sol. lim 
n  k 1 4  k 2  3k 2 
where y > 0 is : n 1  2 1  2 
 n  n 
 
(1) 88
(2) 122 1 n n3
 lim 
n  n k 1 
(3) 92 k 2  3k 2 
1  2 1  2 
(4) 108  n  n 
 
Ans. (4) 1
dx

 2 1 2
0 3 1 x   x 
 3 

 1
1 3  x 2  1   x 2  


1
3
8. The area (in square units) of the region bounded by
the parabola y2 = 4(x – 2) and the line y = 2x - 8
  dx
0
3 2
   3 
1  x 2  2 1
x  (1) 8
(2) 9
  (3) 6
1  (4) 7
1  1 1 
2   2  1 2
  dx Ans. (2)
0 1  x2 
x   Sol. Let X = x – 2
  3 
y2 = 4x, y = 2 (x + 2) – 8
   
1 1
1 1 2
 3 tan 1 3x   tan 1 x y = 4x, y = 2x – 4
2  0 2 0
4
y2 y  4

3  1 
   


 A  4

2
2  3  2 4  2 3 8 2

13 4


8. 4 3  3 
7. Let g : R R be a non constant twice
-2

1  3
differentiable such that g'    g'   . If a real
 2  2
valued function f is defined as
=9
1
f  x   g  x   g  2  x   , then 9. Let y = y (x) be the solution of the differential
2
equation sec x dy + {2(1 – x) tan x + x(2 – x)}
(1) f”(x) = 0 for atleast two x in (0, 2)
dx = 0 such that y(0) = 2.Then y(2) is equal to :
(2) f”(x) = 0 for exactly one x in (0, 1)
(1) 2
(3) f”(x) = 0 for no x in (0, 1)
(2) 2{1 – sin (2)}
 3 1 (3) 2{sin (2) + 1}
(4) f '    f '    1
 2  2 (4) 1
Ans. (1) Ans. (1)
3 1
Sol. f '  x  
g ' x   g ' 2  x   3 
g '   g ' 
,f '     
2  2 0
Sol.
dy
dx
 2  x  1 sin x  x 2  2x cos x 
2  
2 2
Now both side integrate
1  3  
y  x    2  x  1 sin x dx   x 2  2x  sin x     2x  2  sin x dx 
g '   g '   
1  2   0, f '  1   0
Also f '     
2
2 2
 
2 
y  x   x 2  2x sin x  
3 1 y  0  0    2  
 f '   f '   0
2  2
1   3
 rootsin  ,1 and 1, 

y  x   x 2  2x sin x  2
2   2 y  2  2
1 3
 f "  x  is zero at least twice in  , 
2 2
   be the foot of perpendicular from the = 30
30 30
x  3 y 1 z  4 Required probability   
point (1, 2, 3) on the line   . 11 11 121
5 2 3
12. If the domain of the function
then 19        is equal to :
2 x  1
(1) 102 f  x   cos 1     log e  3  x   is
(2) 101  4 
(3) 99 [, )  y , then      is equal to :
(4) 100 (1) 12
Ans. (2) (2) 9
(1, 2, 3) (3) 11
Sol.
(4) 8
Ans. (3)
2 x
Sol. 1  1
4
P()
Let foot P (5k – 3, 2k + 1, 3k – 4) 2 x
 1
DR's  AP: 5k 4, 2k1, 3k  7  4
DR's  Line: 5, 2, 3 
–4  2 – |x|  4
Condition of perpendicular lines (25k-20) + (4k-2) + (9k – 21)=0 –6  – |x|  2

Then k 
43
 –2  |x|  6
38 |x|  6
Then 19        =101  x  [–6, 6] …(1)
11. Two integers x and y are chosen with replacement Now, 3 – x  1
from the set {0, 1, 2, 3, ….., 10}. Then the And x  2 …(2)
probability that | x  y | 5 is : and 3 – x > 0
30 x<3 …(3)
(1)
121 From (1), (2) and (3)
62  x  [–6, 3) – {2}
(2)
121 =6
(3)
60 =3
121 =2
31
(4)  +  +  = 11
121
13. Consider the system of linear equation x + y + z =
Ans. (1)
4, x + 2y + 2 z = 10 , x + 3y + 4  2z = 2 +15,
Sol. If x = 0, y = 6, 7, 8, 9, 10
If x = 1, y = 7, 8, 9, 10 where  ,  R . Which one of the following
If x = 2, y = 8, 9, 10 statements is NOT correct ?
If x = 3, y = 9, 10 1
(1) The system has unique solution if   and
If x = 4, y = 10 2
If x = 5, y = no possible value   1 , 15
Total possible ways = (5 + 4 + 3 + 2 + 1) × 2
 1 -3 < r < 7 ………(1)
(2) The system is inconsistent if  and   1
2 From (1) and (2)
(3) The system has infinite number of solutions if 3<r<7
1 15. If the length of the minor axis of ellipse is equal to
 and   15 half of the distance between the foci, then the
2
eccentricity of the ellipse is :
1
(4) The system is consistent if   5
2 (1)
Ans. (2) 3
Sol. x + y + z = 4, x + 2y + 2 z = 10 , x + 3y + 4  (2)
3
2 2
z = 2 +15,
1
1 1 1 (3)
3
2 =  2  1 
2
1 2 2
(4)
1 3 4 2
5

 1 Ans. (4)
 For unique solution   0, 2  1  0,     Sol. 2b = ae
 2
b e
1 
Let   0,   a 2
2
e2
4 1 1 e  1
4
 y  0,  x   z  10 2 1
2
 2  15 3 1 e
5
    15   1 16. Let M denote the median of the following
1 frequency distribution.
For infinite solution   ,   1 or 15 Class 0-4 4-8 8-12 12-16 16-20
2
Frequency 3 9 10 8 6
Then 20 M is equal to :
14. If the circles  x  12   y  22  r 2 and (1) 416
x 2  y 2  4x  4y  4  0 intersect at exactly two (2) 104
(3) 52
distinct points, then
(4) 208
(1) 5 < r < 9
Ans. (4)
(2) 0 < r < 7 Sol.
(3) 3 < r < 7 Class Frequency Cumulative
(4)
1
r7 frequency
2 0-4 3 3
Ans. (3) 4-8 9 12
Sol. If two circles intersect at two distinct points 8-12 10 22
 r1  r2  C1C2  r1  r2 12-16 8 30
16-20 6 36
r  2  9  16  r  2
|r – 2 | < 5 and r + 2 > 5
-5 < r – 2 < 5 r > 3 ……….(2)
 N  Sol. Area = AC  BD
 2 C
M l h ˆi ˆj
 f  kˆ
   5 1 7
18  12 1 2 3
M 8 4
10
1 1
M = 10.4  17iˆ  8jˆ  11kˆ  474
2 2
20M = 208
19. If 2sin3x + sin 2x cos x + 4sinx – 4 = 0 has exactly
2cos4 x 2sin 4 x 3  sin 2 2 x
 n 
17. If f  x   3  2cos4 x 2sin 4 x sin 2 2 x then 3 solutions in the interval 0,  , n  N , then the
 2
4
2cos x 3  2sin x
4
sin 2 2 x
roots of the equation x2  nx   n  3  0 belong
1
f '  0  is equal to ______
5 to :
(1) 0 (1)  0, 
(2) 1 (2)  ,0 
(3) 2
 17 17 
(4) 6 (3)  
 2 , 2 
Ans. (1)  
(4) Z
2cos4 x 2sin 4 x 3  sin 2 2x
Ans. (2)
Sol. 3  2cos4 x 2sin 4 x sin 2 2x
Sol. 2sin3 x  2sin x.cos2 x  4sin x  4  0
2cos4 x 3  2sin 2 4x sin 2 2x

R 2  R 2  R1, R3  R3  R1
 
2sin 3 x  2sin x. 1  sin 2 x  4sin x  4  0

6sin x  4  0
2cos 4 x 2sin 4 x 3  sin 2 2x 2
sin x 
3 0 3 3
0 3 3 n = 5 (in the given interval)
f(x) = 45 x 2  5x  2  0
f ' x   0 5  17
x
18. Let A (2, 3, 5) and C(-3, 4, -2) be opposite vertices 2
of a parallelogram ABCD if the diagonal Required interval  ,0 
BD  iˆ  2 ˆj  3kˆ then the area of the parallelogram   
20. Let f :  ,   R be a differentiable function
is equal to  2 2
x
(1)
1
410 1 x  f  t  dt
2 such that f  0   , If the lim 0 2  ,
2 x 0 e x  1
1
(2) 474
2 then 8 2 is equal to :
1 (1) 16
(3) 586
2 (2) 2
1 (3) 1
(4) 306
2 (4) 4
Ans. (2) Ans. (2)
 x x  11
x  f  t  dt
Sol. lim 0
x 0  e x1  2 x =11 does not satisfy the data.
2

  x
 x2  For x = 10
 
x
 f  t  dt  ex  1 
2

lim 0  lim  1
x 0 x  x 0 x 2 
 
f x
= lim (using L Hospital)
x 0 1
1
f  0 
2
1

2
Hence maximum number of students passed in all
8 2  2
the three subjects is 10.
SECTION-B
22. If d1 is the shortest distance between the lines
21. A group of 40 students appeared in an examination x + 1 = 2y = -12z, x = y + 2 = 6z – 6 and d2 is the
shortest distance between the lines
of 3 subjects – Mathematics, Physics & Chemistry.
x 1 y  8 z  4 x 1 y  2 z  6
It was found that all students passed in at least one   ,   , then the
2 7 5 2 1 3
of the subjects, 20 students passed in Mathematics, 32 3d1
value of is :
25 students passed in Physics, 16 students passed d2

in Chemistry, at most 11 students passed in both Ans. (16)

Sol. L : x  1  y  z x

y  2

z – 1
Mathematics and Physics, at most 15 students 1
1 1/ 2 1/ 12
, L2 :
1 1 1
passed in both Physics and Chemistry, at most 15 6
d1 = shortest distance between L1 & L2
students passed in both Mathematics and
Chemistry. The maximum number of students
 a 2  a1 . b1  b2 
=
passed in all the three subjects is ________.  b1  b2 
d1  2
Ans. (10)
x 1 y  8 z  4 x 1 y  2 z  6
M P L3 :   , L4 :  
2 7 5 2 1 3
d2 = shortest distance between L3 & L4
Sol.
12
x d2  Hence
3
32 3d1 32 3  2
   16
d2 12
3

11 – x  0 (Maths and Physics)

 x 2 y2 Sol. f : A  P(A)
23. Let the latus rectum of the hyperbola  1
9 b2
a  f (a)

subtend an angle of at the centre of the
3 That means ‘a’ will connect with subset which

hyperbola. If b2 is equal to
l
m
 
1  n , where l
contain element ‘a’.

and m are co-prime numbers, then l2 + m2 + n2 is Total options for 1 will be 26. (Because 26 subsets
contains 1)
equal to __________
Ans. (182) Similarly, for every other element
Sol. LR subtends 60º at centre
Hence, total is 26 × 26 × 26× 26× 26× 26× 26 = 242

Ans. 2+42 = 44

9
 10x 
30º 25. The value 9   dx , where [t] denotes the
x 1
0
greatest integer less than or equal to t, is _____.
Ans. (155)
b2 / a b2 1
 tan 30   2  10x 1
ae a e 3 Sol. 1 x
x 1 9

3b 2
e 10x
4 x
2
9 x 1 3

b2 b 2 3b 4 10x
Also, e2  1   1  9 x 9
9 9 81 x 1

 b4 = 3b2 + 27  1/9 2/3 9


I  9   0dx   1.dx   2dx 
0 
 b4 - 3b2 – 27 = 0
1/9 2/3

= 155
3
 b2  (1  13)
2 26. Number of integral terms in the expansion of
824
  3, m  2, n  13  1 1
  2   
7  11 6   is equal to ________.
 2 2 2
+ m + n = 182  
 
24. Let A = {1, 2, 3,….7} and let P(1) denote the Ans. (138)
power set of A. If the number of functions Sol. General term in expansion of  (7)1/ 2  (11)1/6 
824
is
f : A  P  A  such that a  f  a  , a  A is m , m
n
824  r
tr + 1 = 824Cr (7) 2
(11) r /6
and n  N and m is least, then m + n is equal to
For integral term, r must be multiple of 6.
_______.
Ans. (44) Hence r = 0, 6, 12, ……….822
27. Let y = y(x) be the solution of the differential  = 5,  = 65,  = 325

equation (1 – x2) dy =  xy  x 3  2 3 1  x 2  dx,

  
    By putting value of we get the required
value 60.
1 m
1  x  1, y  0  =0. If y    , m and n are co-
2 n
 1
 , x 2
prime numbers, then m + n is equal to ________.,
29. If the function f x   x is
 2
Ans. (97) ax  2b, x  2
dy xy (x 3  2) 3(1  x 2 ) differentiable on R, then 48 (a + b) is equal to
Sol.  
dx 1  x 2 1 x2 _____.

 
x
dx 1
 ln(1 x 2 ) Ans. (15)
IF = e 1 x 2
e 2  1 x2
 1
 ; x2
x
y 1  x 2  3  (x 3  2) dx  2
Sol. f (x) ax  2b;  2  x  2
 1
  ; x  2
 x4   x
y 1  x 2  3   2x   c
 4  1 a
Continuous at x = 2    2b
2 4
 y(0)  0 c  0
1 a
 1  65 m Continuous at x = -2    2b
y    2 4
 2  32 n
Since, it is differentiable at x = 2
m  n  97

28. Let ,  N be roots of equation x2 – 70x +  = 0, 

1
 2ax
x2
 
where ,  N . If  assumes the minimum
2 3 1 1
Differentiable at x = 2   4a  a  ,b
 
4 16
  1    1    35 
possible value, then is 3
  =
8
equal to :
30. Let   12  42  82  132  192  262  ...... upto
Ans. (60)
10
Sol. x 2  70x    0 10 terms and    n 4 . If 4   55k  40 ,
n 1
 = 70
then k is equal to __________.
= 
Ans. (353)
(70 – ) =  Sol.  = 12 + 42 + 82 ….

Since, 2 and 3 does not divide  tn = an2 + bn + c

 1=a+b+c

4 = 4a + 2b + c

8 = 9a + 3b + c

1 3
On solving we get, a = ,b = ,c= -1
2 2

2
10
 n 2 3n 
     1
n 1  2 2 

4    n 2  3n  2  ,    n 4
10 2 10

n 1 n 1

10
4     (6n 3  5n 2  12n  4) = 55(353) + 40
n 1
 PHYSICS TEST PAPER WITH SOLUTION
SECTION-A Sol.
31. Match List-I with List-II.
List-I List-II T
2 –2
A. Coefficient of viscosity I. [M L T ] 2a
g
2k
B. Surface Tension II. [M L2T–1] 2T
30º Fixed a
–1 –1 4 kg
C. Angular momentum III. [M L T ]
40 – 2T = 4a
D. Rotational kinetic energy IV. [M L0T–2]
T – 10 = 4a  20 = 12 a
(1) A–II, B–I, C–IV, D–III
(2) A–I, B–II, C–III, D–IV g
 a = 5/3  2a =
(3) A–III, B–IV, C–II, D–I 3
(4) A–IV, B–III, C–II, D–I 33. A potential divider circuit is shown in figure. The
Ans. (3)
dv output voltage V0 is
Sol. F  A 4V
dy
 MLT 2     L2  T 1 
3.3k 100 100 100 100 100 100 100
   ML1 T 1 
F  MLT 2  V0
S .T     ML0T 2 
 
L (1) 4V (2) 2 mV
(3) 0.5 V (4) 12 mV
L  mvr   ML2T 1 
Ans. (3)
1 2
K .E  I    ML2T 2  Sol. Req  4000 
2
32. All surfaces shown in figure are assumed to be 4 1
frictionless and the pulleys and the string are light.
i  A
4000 1000
The acceleration of the block of mass 2 kg is :
1
V0  i.R   500  0.5V
1000
34. Young’s modules of material of a wire of length
‘L’ and cross-sectional area A is Y. If the length of
the wire is doubled and cross-sectional area is
halved then Young’s modules will be :
g
(1) g (2) Y
3 (1) (2) 4Y
4
g g
(3) (4) (3) Y (4) 2Y
2 4
Ans. (2) Ans. (3)
Sol. Young’s modulus depends on the material not Sol. By COME
length and cross sectional area. So young’s KEA + UA = KEB + UB
modulus remains same. 1
35. The work function of a substance is 3.0 eV. The 0 + mg(1) = mv 2  mg  0.5
2
longest wavelength of light that can cause the
emission of photoelectrons from this substance is v  g  10 m / s
approximately: 38. The electric field of an electromagnetic wave in
(1) 215 nm (2) 414 nm free space is represented as E  E0 cos t  kz  iˆ .
(3) 400 nm (4) 200 nm
Ans. (2) The corresponding magnetic induction vector will
hc be :
Sol. For P.E.E. :  
We (1) B  E0C cos t  kz  ˆj
1240 nm  eV E0
 (2) B  cos t  kz  ˆj
3 eV C
  413.33nm (3) B  E0 Ccos t  kz  ˆj
max  414 nm for P.E.E. E0
36. The ratio of the magnitude of the kinetic energy to (4) B  cos t  kz  ˆj
C
the potential energy of an electron in the 5th excited
Ans. (2)
state of a hydrogen atom is :
1 Sol. Given E  E0 cos t  kz  iˆ
(1) 4 (2)
4 E0
B cos t  kz  ˆj
1 C
(3) (4) 1
2 Cˆ  Eˆ  Bˆ
Ans. (3) 39. Two insulated circular loop A and B radius ‘a’
1
Sol. PE  KE for each value of n (orbit) carrying a current of ‘I’ in the anti clockwise
2 direction as shown in figure. The magnitude of the
KE 1 magnetic induction at the centre will be :
 
PE 2 B
37. A particle is placed at the point A of a frictionless
track ABC as shown in figure. It is gently pushed
toward right. The speed of the particle when it
O
reaches the point B is : (Take g = 10 m/s2).
A C A

B
1m
0.5m 2 0 I 0 I
(1) (2)
a 2a
(1) 20 m/s (2) 10 m / s 0 I 20 I
(3) (4)
(3) 2 10 m / s (4) 10 m/s 2a a
Ans. (2) Ans. (3)
Sol. 1 N1 100
Sol.     2  22V
Bnet  2 N 2 10
22
I  1 mA, V0  7V
22  103
42. The gravitational potential at a point above the
surface of earth is 5.12 107 J / kg and the

2 0 I acceleration due to gravity at that point is 6.4 m/s2.

Bnet  Assume that the mean radius of earth to be
2a
40. The diffraction pattern of a light of wavelength 400 6400 km. The height of this point above the earth’s
nm diffracting from a slit of width 0.2 mm is surface is :
focused on the focal plane of a convex lens of focal (1) 1600 km
length 100 cm. The width of the 1st secondary (2) 540 km
maxima will be :
(3) 1200 km
(1) 2 mm (2) 2 cm
(3) 0.02 mm (4) 0.2 mm (4) 1000 km
Ans. (1) Ans. (1)
 GM E
Sol. Width of 1st secondary maxima = .D Sol.   5.12 107 …. (i)
a RE  h
Here
GM E
a  0.2 103 m  6.4 …. (ii)
 RE  h 
2

  400 109 m
By (i) and (ii)
D  100 102
Width of 1st secondary maxima
 h  16 105 m  1600 km
400 109 43. An electric toaster has resistance of 60  at room
 3
100 102
0.2 10 temperature (27ºC). The toaster is connected to a
 2 mm 220 V supply. If the current flowing through it
41. Primary coil of a transformer is connected to reaches 2.75 A, the temperature attained by toaster
220 V ac. Primary and secondary turns of the
is around : (if   2 104 /º C )
transforms are 100 and 10 respectively. Secondary
(1) 694ºC
coil of transformer is connected to two series
resistance shown in shown in figure. The output (2) 1235ºC
voltage (V0) is : (3) 1694ºC
15k
(4) 1667ºC
V0
Ans. (3)
~ 7k
220
220V Sol. RT=27 = 60, RT   80
2.75
(1) 7 V (2) 15 V R = R0 (1+ T)
(3) 44 V (4) 22 V 80 = 60 [1+ 2 × 10–4(T–27)]
Ans. (1) T  1694ºC
44. A Zener diode of breakdown voltage 10V is used (1) CB  , C A  0
as a voltage regulator as shown in the figure. The (2) C A  0 and CB  
current through the Zener diode is
200 (3) CP  CV  C A  CB
500
(4) C A  CP  CV
Ans. (Bonus)
Sol. For process A
20V log P   logV  P  V  ,    1
PV   Constant
R
(1) 50 mA (2) 0 CA  CV  …. (i)
(3) 30 mA (4) 20 mA 1 
Ans. (3) Likewise for process B  PV 1  Cons tan t
200 I1 500 I3 R
C B  Cv 
11
Sol. I2 R
C B  Cv  … (ii)
2
10V
20V CP  Cv  R …. (iii)
By (i), (ii) & (iii)
CP  CB  C A  Cv [No answer matching]
Zener is in breakdown region.
46. The electrostatic potential due to an electric dipole
10 1
I3   at a distance ‘r’ varies as :
500 50 1
10 1 (1) r (2)
I1   r2
200 20
1 1
I 2  I1  I 3 (3) (4)
r3 r
 1 1   3  Ans. (2)
I2         30 mA
 20 50   100  kP cos 
Sol. V
45. Two thermodynamical process are shown in the r2
figure. The molar heat capacity for process A and & can also checked dimensionally
B are CA and CB. The molar heat capacity at 47. A spherical body of mass 100 g is dropped from a
height of 10 m from the ground. After hitting the
constant pressure and constant volume are
ground, the body rebounds to a height of 5m. The
represented by CP and CV, respectively. Choose the
impulse of force imparted by the ground to the
correct statement. body is given by : (given g = 9.8 m/s2)
log P (1) 4.32 kg ms–1 (2) 43.2 kg ms–1
–1
(3) 23.9 kg ms (4) 2.39 kg ms–1
Ans. (4)
tan–1  Sol. I  P  Pf  Pi
M = 0.1 kg
A
B
45º I  P  0.1  
2  9.8  5   2  9.8 10 
O
log V  
 0.1 14  7 2  2.39 kg ms–1
48. A particle of mass m projected with a velocity ‘u’ Sol. E = 25 sin (1000 t)
making an angle of 30º with the horizontal. The 1
magnitude of angular momentum of the projectile cos  
2
about the point of projection when the particle is at
LR circuit
its maximum height h is :
3 mu 3 3 mu 2
(1) (2) XL
16 g 2 g

mu 3
(3) (4) zero R
2g
R 1 1
Ans. (1) Initially   1
1 L tan  tan 45º
Sol. L = mu cos  H
X L  1 L
u 2 sin 2 
 mu cos  
2g 2  21 , given
2
mu 3 3 1 3mu 3
     2 L 21 L
2g 2 2 16 g tan  '  
R R
49. At which temperature the r.m.s. velocity of a
tan '  2
hydrogen molecule equal to that of an oxygen
molecule at 47ºC? 1
cos  ' 
(1) 80 K (2) –73 K 5
(3) 4 K (4) 20 K SECTION-B
Ans. (4)
51. The horizontal component of earth’s magnetic field
3RT 3R  320 
Sol.  at a place is 3.5 105 T . A very long straight
2 32
320 conductor carrying current of 2A in the
T  20 K
16 direction from South east to North West is placed.
50. A series L,R circuit connected with an ac source
The force per unit length experienced by the
1
E = (25 sin 1000 t) V has a power factor of . If conductor is ……… × 10–6 N/m.
2
the source of emf is changed to E = (20 sin 2000 Ans. (35)
t)V, the new power factor of the circuit will be :
Sol. BH  3.5 105 T
1 1
(1) (2)
2 3 F  i B sin  , i  2 A
F 1
(3)
1
(4)
1  iB sin   2  3.5 105 
5 7 2
6
Ans. (3)  35 10 N / m
52. Two cells are connected in opposition as shown. 54. Each of three blocks P, Q and R shown in figure
has a mass of 3 kg. Each of the wire A and B has
Cell E1 is of 8 V emf and 2  internal resistance;
cross-sectional area 0.005 cm2 and Young’s
the cell E2 is of 2 V emf and 4  internal modulus 2 × 1011 N m–2. Neglecting friction, the
longitudinal strain on wire B is _____ × 10–4.
resistance. The terminal potential difference of cell
(Take g = 10 m/s2)
E2 is: A B
P Q
E1 B E2
A C

R
Ans. (2)
Ans. (6)
T2 T1
8V
P Q
2 B 4 2V
A C Sol.
Sol.
I

R
82 6 10
I   1A a m / s2
24 6 3
Applying Kirchhoff from C to B 30  T1  3  a
T1  20 N
VC  2  4  1  VB
stress
VC  VB  6V strain 
Y
= 6V  2 104
53. A electron of hydrogen atom on an excited state is 55. The distance between object and its two times
magnified real image as produced by a convex lens
having energy En = – 0.85 eV. The maximum is 45 cm. The focal length of the lens used is
number of allowed transitions to lower energy ______ cm.
Ans. (10)
level is ….. . .
v
Sol.  2
Ans. (6) u
13.6 v  2u …(i)
En    0.85 v  u  45 ...(ii)
Sol. n2
n4  u  15 cm
v  30 cm
No of transition
1 1 1
 
n  n  1 4  4  1 f v u
  6
2 2 f  10 cm
56. The displacement and the increase in the 58. Consider a Disc of mass 5 kg, radius 2m, rotating
with angular velocity of 10 rad/s about an axis
velocity of a moving particle in the time interval
perpendicular to the plane of rotation. An identical
of t to (t + 1) s are 125 m and 50 m/s, disc is kept gently over the rotating disc along the

respectively. The distance travelled by the same axis. The energy dissipated so that both the
discs continue to rotate together without slipping is
particle in (t + 2) th s is ____ m.
_____ J.
Ans. (175) = 10 rad/sec

Sol. Considering acceleration is constant Mass = 5kg

2m
v  u  at
u  50  u  a  a  50 m / s 2
1
125  ut  at 2
2
a Ans. (250)
125  u 
2
MR 2
 u  100 m / s Sol. Li  I i  .  100 kgm2 / s
2
a 1 MR 2 2
 S nth  u   2n  1 Ei  . .  500 J
2 2 2

= 175 m Li  L f  100  2 I  f

f = 5 rad/sec
57. A capacitor of capacitance C and potential V has
1 5  2
2

Ef  2 . .  5   250 J
2
energy E. It is connected to another capacitor of
2 2
capacitance 2 C and potential 2V. Then the loss of E  250 J

x 59. In a closed organ pipe, the frequency of

energy is E , where x is _____ .
3 fundamental note is 30 Hz. A certain amount of

Ans. (2) water is now poured in the organ pipe so that the
fundamental frequency is increased to 110 Hz. If
1 C1C2
V1  V2 
2
Sol. Energy loss = the organ pipe has a cross-sectional area of 2 cm2,
2 C1  C2
the amount of water poured in the organ tube is
2 _______ g. (Take speed of sound in air is 330 m/s)
 .E
3 Ans. (400)
x  2
 V 11 60. A ceiling fan having 3 blades of length 80 cm each
Sol.  30  1  m
4 1 4 is rotating with an angular velocity of 1200 rpm.
V 3 The magnetic field of earth in that region is 0.5 G
 110  2  m
4 2 4 and angle of dip is 30º. The emf induced across the
  2m, blades is N 105V . The value of N is _____ .

Change in volume = A  400 cm3 Ans. (32)

M = 400 g ;    1 g / cm3  Sol.

1
Bv  B sin 30  10 4
4
2
  2  f   1200 rad / s
60
1
 BV  2

2
 32 105 V
 CHEMISTRY TEST PAPER WITH SOLUTION
SECTION-A 63. Sugar which does not give reddish brown precipitate
61. Given below are two statements: with Fehling‟s reagent is:
Statement-I: The gas liberated on warming a salt (1) Sucrose (2) Lactose
with dil H2SO4, turns a piece of paper dipped in
(3) Glucose (4) Maltose
lead acetate into black, it is a confirmatory test for
Ans. (1)
sulphide ion.
Statement-II: In statement-I the colour of paper Sol. Sucrose do not contain hemiacetal group.
turns black because of formation of lead sulphite. Hence it does not give test with Fehling solution.
In the light of the above statements, choose the While all other give positive test with Fehling
most appropriate answer from the options given
solution
below:
64. Given below are the two statements: one is labeled as
(1) Both Statement-I and Statement-II are false
(2) Statement-I is false but Statement-II is true Assertion (A) and the other is labeled as Reason (R).
(3) Statement-I is true but Statement-II is false Assertion (A): There is a considerable increase in
(4) Both Statement-I and Statement-II are true. covalent radius from N to P. However from As to
Ans. (3)
Bi only a small increase in covalent radius is
Sol. Na2S + H2SO4  Na2SO4 + H2S
observed.
(CH3COO)2Pb + H2S  PbS + 2CH3COOH
Black lead Reason (R): covalent and ionic radii in a particular
sulphide oxidation state increases down the group.
O
In the light of the above statement, choose the
C CHO most appropriate answer from the options given
Cl H2
below:
62. Pd-BaSO4
(1) (A) is false but (R) is true
This reduction reaction is known as:
(1) Rosenmund reduction (2) Both (A) and (R) are true but (R) is not the
(2) Wolff-Kishner reduction correct explanation of (A)
(3) Stephen reduction (3) (A) is true but (R) is false
(4) Etard reduction (4) Both (A) and (R) are true and (R) is the correct
Ans. (1)
explanation of (A)
Sol.
O
O Ans. (2)
CHO
Cl
H2
Sol. According to NCERT,
Pd-B aS O 4 Statement-I : Factual data,
Statement-II is true.
It is known as rosenmund reduction that is the
partial reduction of acid chloride to aldehyde But correct explanation is presence of completely
filled d and f-orbitals of heavier members
65. Which of the following molecule/species is most 69. Example of vinylic halide is
stable? CH2 X
  X
(1) (2)
(1) (2)
X
X
(3) (4) (3) (4)

Ans. (1) Ans. (1)


Sol. Vinyl carbon is sp2 hybridized aliphatic carbon
Sol. it is aromatic species x
is vinyl halide

66. Diamagnetic Lanthanoid ions are: x

(1) Nd3+ and Eu3+ (2) La3+ and Ce4+
3+ 4+ While is aryl halide
(3) Nd and Ce (4) Lu3+ and Eu3+
Ans. (2)
X
Sol. Ce : [Xe] 4f15d16s2 ; Ce4+ diamagnetic CH 2 -X
La : [Xe] 4f05d16s2 ; La3+ diamagnetic
and are allyl halide
67. Aluminium chloride in acidified aqueous solution
forms an ion having geometry
(1) Octahedral 70. Structure of 4-Methylpent-2-enal is
(2) Square Planar
CH3 O
(3) Tetrahedral | ||
(4) Trigonal bipyramidal (1) H 2 C  C  C  CH 2  C  H
Ans. (1) | |
H H
Sol. AlCl3 in acidified aqueous solution forms
O
octahedral geometry [Al(H2O)6]3+ ||
(2) CH3  CH 2  C  CH  C  H
68. Given below are two statements: |
CH 3
Statement-I: The orbitals having same energy are
called as degenerate orbitals. O
||
Statement-II: In hydrogen atom, 3p and 3d (3) CH3  CH 2  CH  C  C  H
orbitals are not degenerate orbitals. |
In the light of the above statements, choose the CH 3
most appropriate answer from the options given O
(1) Statement-I is true but Statement-II is false ||
(2) Both Statement-I and Statement-II are true. (4) CH3  CH  CH  CH  C  H
|
(3) Both Statement-I and Statement-II are false CH3
(4) Statement-I is false but Statement-II is true
Ans. (4)
Ans. (1)
Sol. For single electron species the energy depends upon O
5 4
principal quantum number „n‟ only. So, statement II Sol. CH3 - CH - CH = CH - C - H
3 2 1
is false. CH 3
Statement I is correct definition of degenerate orbitals. 4-methylpent-2-enal
M
71. Match List-I with List-II Ans. (2)
List-I List-II Sol.
Molecule Shape O
Br MgBr C–OMgBr
(A) BrF5 (I) T-shape Mg, ether O= C= O

(B) H2O (II) See saw

H+
(C) ClF3 (III) Bent
O
(D) SF4 (IV) Square pyramidal COOH
NH2 Br2 / NaOH C–NH2 NH3
(1) (A)-I, (B)-II, (C)-IV, (D)-III Hoffmann bromamide 
reaction
(2) (A) –II, (B)-I, (C)-III, (D)-IV
(3) (A)-III, (B)-IV, (C)-I, (D)-II
73. In the given reactions identify the reagent A and
(4) (A)-IV, (B)-III, (C)-I, (D)-II
reagent B
Ans. (4)
CH 3
“A” + (CH3 CO)2 O
F [Intermediate]
273-283K H3 O+
F F 
CHO
“B” + CS2
Sol. BrF5 Br Square pyramidal [Intermediate]

H3O +
F F
(1) A-CrO3 B-CrO3
O
(2) A-CrO3 B-CrO2Cl2
H2O H H Bent
F (3) A-CrO2Cl2 B-CrO2Cl2
..
ClF3 F Cl T-shape (4) A-CrO2Cl2 B-CrO3
..
F Ans. (2)
F Sol.
F
SF4, S See-saw CH 3 CH(OCOCH 3)2
F CrO3/(CH3CO)2O
F
72. The final product A, formed in the following CrO2 Cl2 H3 O+
Etard reaction CS2
multistep reaction sequence is: CHO
CH[OCrCl 2 (OH)]2 H3 O+
(i) Mg, ether
Br then CO,2 H+
(ii) NH3 , 
A
(iii) Br2, NaOH
74. Given below are two statement one is labeled as
O
NH2 Assertion (A) and the other is labeled as Reason (R).
(1) NH2 (2) Assertion (A): CH2 = CH – CH2 – Cl is an
example of allyl halide
O O
Reason (R): Allyl halides are the compounds in
(3) Br (4) OH
which the halogen atom is attached to sp2
hybridised carbon atom.
 In the light of the two above statements, choose the Sol. 24Cr  [Ar] 3d54s1; Cr2+  [Ar] 3d4
most appropriate answer from the options given 25Mn  [Ar] 3d54s2; Mn+  [Ar] 3d54s1
below:
28Ni  [Ar] 3d84s2; Ni2+  [Ar] 3d8
(1) (A) is true but (R) is false
23V  [Ar] 3d34s2; V+  [Ar] 3d34s1
(2) Both (A) and (R) are true but (R) is not the
correct explanation of (A)
77. Compound A formed in the following reaction reacts
(3) (A) is false but (R) is true
(4) Both (A) and (R) are true and (R) is the correct with B gives the product C. Find out A and B.
B
explanation of (A) CH3  C  CH  Na  A 
 CH3  C  C  CH 2  CH 2  NaBr
(C) |
Ans. (1) CH3

Sol. CH 2  CH  CH 2  Cl (1) A=CH3 –C CNa , B = CH3 – CH2 – CH2 – Br
 (2) A=CH3–CH= CH2, B = CH3 – CH2 – CH2 – Br
3
It is allyl carbon and sp hybridized (3) A = CH3 – CH2 – CH3, B = CH3 – C  CH

(4) A = CH3 – C  CNa , B = CH3 – CH2 – CH3
75. What happens to freezing point of benzene when
small quantity of napthalene is added to benzene? Ans. (1)

(1) Increases Sol.

(2) Remains unchanged CH3 CH 2CH 2  Br
CH 3  C  C  Na 
Na
CH3  C  CH 
(3) First decreases and then increases
NaBr + CH3  C  C  CH 2CH 2CH 3
(4) Decreases
Ans. (4) 78. Following is a confirmatory test for aromatic
Sol. On addition of naphthalene to benzene there is primary amines. Identify reagent (A) and (B)
depression in freezing point of benzene. A  B
NH2 N2 Cl Scarlet red dye
NaOH
76. Match List-I with List-II OH
List-I List-II (1) A = HNO3/H2SO4; B=
Species Electronic distribution NH2
+2
(A) Cr (I) 3d8 (2) A= NaNO2 + HCl, 0 – 5°C; B=
+ 3 1 OH
(B) Mn (II) 3d 4s
(C) Ni+2 (III) 3d4
(3) A=NaNO2 + HCl, 0 – 5°C; B=
(D) V+ (IV) 3d54s1
Choose the correct answer from the options given
(4) A = NaNO2 + HCl, 0 – 5°C;
below:
OH
(1) (A)-I, (B)-II, (C)-III, (D)-IV
B=
(2) (A)-III, (B) – IV, (C) – I, (D)-II
(3) (A)-IV, (B)-III, (C)-I, (D)-II
Ans. (4)
(4) (A)-II, (B)-I, (C)-IV, (D)-III
Ans. (2)
83. 86. On a thin layer chromatographic plate, an organic
compound moved by 3.5 cm, while the solvent
B
V 30 moved by 5 cm. The retardation factor of the
(dm3 ) organic compound is _____ × 10-1
20
C Ans. (07)
10 A
Distance travelled by
0 10 20 30 sample/organiccompound
Sol. Retardation factor =
P(kPa) Distance travelled by solvent
An ideal gas undergoes a cyclic transformation 3.5
  7  101
starting from the point A and coming back to the 5
same point by tracing the path A  B  C  A 87. The compound formed by the reaction of ethanal

as shown in the diagram. The total work done in with semicarbazide contains _____number of

the process is _____ J. nitrogen atoms.

Ans. (200) Ans. (03)

Sol. Work done is given by area enclosed in the P vs V Sol.

cyclic graph or V vs P cyclic graph. O

CH3 -C = O + H2 N – NH – C – NH2
Sign of work is positive for clockwise cyclic
process for V vs P graph. H
Semicarbazide
1 O
W= × (30 – 10) × (30 - 10) = 200 kPa – dm3
2
CH3 – CH = N – NH – C – NH2
= 200 × 1000 Pa – L = 2 L-bar = 200 J
88. 0.05 cm thick coating of silver is deposited on a
plate of 0.05 m2 area. The number of silver atoms
84. if IUPAC name of an element is “Unununnium”
deposited on plate are _____ × 1023. (At mass Ag
then the element belongs to nth group of periodic
= 108, d = 7.9 g cm-3)
table. The value of n is______
Ans. (11)
Ans. (11)
Sol. Volume of silver coating = 0.05 × 0.05 × 10000
Sol. 111 belongs to 11th group
= 25 cm3
Mass of silver deposited = 25 × 7.9 g
85. The total number of molecular orbitals formed from
25  7.9
2s and 2p atomic orbitals of a diatomic molecule Moles of silver atoms =
108
Ans. (08) 25  7.9
Number of silver atoms =  6.023 1023
Sol. Two molecular orbitals  2s and 2s. 108

Six molecular orbitals  2pz and 2pz. = 11.01 × 1023

2px , 2py and 2px , *2py Ans. 11

89. 2MnO4  bI  cH2O  x I2  yMnO2  zOH 90. The mass of sodium acetate (CH3COONa) required

If the above equation is balanced with integer to prepare 250 mL of 0.35 M aqueous solution is

coefficients, the value of z is _______ ______ g. (Molar mass of CH3COONa is 82.02 g mol-1)

Ans. (08) Ans. (7)

Sol. Reduction Half Oxidation Half Sol. Moles = Molarity × Volume in litres

2MnO4  2MnO2 2I  I2  2e

= 0.35 × 0.25
Mass = moles × molar mass
2MnO4  4H2O  6e  2MnO2  8OH 6I  3I2  6e
= 0.35 × 0.25 × 82.02 = 7.18 g
Adding oxidation half and reduction half, net
Ans. 7
reaction is
2MnO4  6I  4H2O  3I2  2MnO2  8OH

z=8
 Ans 8