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Njeets Full Test - 06

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Rankers Academy JEE

FIITJEE - NJEETS
(JEE MAIN TEST SERIES - 2024)
CLASS – XII & XII PASS
FULL TEST - 6
CONDUCTION DATE: 02/01/2024
Time Allotted: 3 Hours Maximum Marks: 300

▪ Do not open this Test Booklet until you are asked to do so.
▪ Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.

Important Instructions
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet before
attempting the paper. Wrong CODE or no CODE will give wrong results.

A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & C in the OMR. Part-B of OMR to be left unused
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided for rough
work.
6. No candidate is allowed to carry any textual material, printed or written, bits of papers, clip boards, log tables, slide
rule, calculator, cellular phones, pagers and electronic devices ext. except the Admit Card inside the examination hall
/ room.

B. Filling of OMR Sheet:


1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each character of your
Enrolment No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
4. Do not fold or make any stray marks on the Answer Sheet.

C. Marking Scheme for All Two Parts:


(i) Part-A (01-20) – Contains Twenty (20) multiple choice objective questions which have four (4) options each and only
one correct option. Each question carries +4 marks will be awarded for every correct answer and -1 mark will be
deducted for every incorrect answer.

(i) Part-C (01-05) contains Five (05) Numerical based questions with single digit integer as answer, ranging from 0 to 9
(both inclusive). Each question carries +4 marks will be awarded for every correct answer and NO MARKS will be
deducted for every incorrect answer.

Name of the Candidate :_______________________________________________

Batch :_______________________ Date of Examination :____________________

Enrolment Number :___________________________________________________

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Useful Data Chemistry:


Gas Constant = 8.314 J K−1 mol−1
R
= 0.0821 Lit atm K−1 mol−1
= 1.987  2 Cal K−1 mol−1
Avogadro's Number Na = 6.023  1023
Planck’s Constant h = 6.626  10–34 Js
= 6.25 x 10-27 erg.s
1 Faraday = 96500 Coulomb
1 calorie = 4.2 Joule
1 amu = 1.66 x 10-27 kg
1 eV = 1.6 x 10-19 J
Atomic No : H=1, D=1, Li=3, Na=11, K=19, Rb=37, Cs=55, F=9, Ca=20, He=2, O=8,
Au=79.
Atomic Masses: He=4, Mg=24, C=12, O=16, N=14, P=31, Br=80, Cu=63.5, Fe=56,
Mn=55, Si = 28 Pb=207, u=197, Ag=108, F=19, H=2, Cl=35.5
Useful Data Physics:
2
Acceleration due to gravity g = 10 m / s

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Section – I (Physics)
PART – A
Single Correct Choice Type

1. If L, R, C, V respectively represent inductance, resistance, capacitance and potential difference, then the
L
dimensions of are the same as those of
RCV
(A) Current (B) 1 (C) Charge (D) 1
Current Charge

2 A body starting from rest with acceleration  which varies with time t according as
 = At + B
where A and B are the constants.
The velocity of the particle after time t is:
At 2 At 2 Bt
(A) ( A + B)t (B) + 2Bt (C) + Bt (D) At +
2

2 2 2

3. Two point charges q1 and q2(=q1/2) are placed at points A(0, 1) and y

B(1,0) as shown in the figure. The electric field vector at point P(1,1)
makes an angle  with the x-axis, then the angle  is:
P (1,1)
A

1
−1 1
−1
q1 * *
(A) tan   (B) tan  
2 4
(C) tan (1)
−1
(D) tan ( 0 )
−1

B
x
O *
q2

4. From the surface of a certain planet a body is projected with a certain velocity at a certain angle from the
horizontal surface. The horizontal and vertical displacements x and y are given by
x = 10 3t and y = 10t − t 2
where t is the time in second and x and y are in meter. The magnitude and direction of the velocity of
projection are:
(A) 10 ms-1 at 300 from the horizontal (B) 20 ms-1 at 600 from the horizontal
-1 0
(C) 10 ms at 60 from the horizontal (D) 20 ms-1 at 300 from the horizontal

l
5. Three point charges 4 q , Q and q are placed in straight line of length l at points distant 0, , l
2
respectively. If the net force on charge q is zero, the magnitude of the force on charge 4q is
2 2
q 2q 3q 2 4q 2
(A) (B) (C) (D)
 0l 2  0l 2  0l 2  0l 2
6. The capacitance of a sphere of radius R1 is increased 3 times when it enclosed by an earthed sphere of
radius R2. The ratio R2/R1 is
3 4
(A) 2 (B) (C) (D) 3
2 3
7. The displacement x of a particle at any instant is related to its velocity as v = 2 x + 9. Its acceleration and
initial velocity are:
(A) 1 unit and 3 unit (B) 3 unit and 9 unit (C) 9 unit and 3 unit (D) 2 unit and 9 unit

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8. A body is moving down a long inclined plane of angle of inclination  . The coefficient of friction between the
body and the plane varies as  = 0.5x , where x is the distance moved down the plane. The body will have
the maximum velocity when it has travelled a distance x given by
2 2
(A) x = 2tan (B) x = (C) x = 2 cot  (D) x =
tan  cot 
9. At the instant t = 0 a force F = kt ( k is a constant ) acts on a small body F

of mass m resting on a smooth horizontal surface. The time, when body
leaves the surface is: m
(A) mgk sin  (B) k sin  / mg
(C) mg sin  / k (D) mg / k sin 

10. If the potential energy of a gas molecule is


M N
U= − ,
r 6 r12
M and N being positive constants, then the potential energy at equilibrium must be:
(A) zero (B) M 2 / 4 N (C) N 2 / 4 M (D) MN 2 / 4

11. A body is moving up an inclined plane of angle  with an initial kinetic energy E. The coefficient of friction
between the plane and the body is  . The work done against friction before the body comes to rest is
 cos  E cos  E cos
(A) (B)  E cos  (C) (D) ’
E cos + sin   cos − sin   cos + sin 
1
12. A body P strikes another body Q of mass that is p times that of body P and moving with a velocity that is
q
of the velocity of body P. If body P comes to rest, the coefficient of restitution is
p+q p−q p−q p+q
(A) (B) (C) (D)
p−q q ( p − 1) p ( q − 1) p ( q − 1)

13. A solid cylinder is rolling without slipping down an incline of inclination  . Minimum coefficient of friction so
that the cylinder does not slip on the incline is
tan  tan   
(A) tan  (B) (C) (D) tan  
2 3 3
14. A circular portion of diameter R is cut out from a uniform Cut out circular
circular disc of mass M and radius R as shown in Fig. The portion
moment of inertia of the remaining (shaded) portion of the
disc about an axis passing through the centre O of the disc
and perpendicular to its plane is R R
15 2 7 2
O
(A) MR (B) MR
32 16
13 2 3 2
(C) MR (D) MR
32 8

15. The centres of a ring of mass m and a sphere of mass M of m M


equal radius R, are at a distance 8R apart as shown in Fig
The force of attraction between the ring and the sphere is R R
2 2 GmM GmM 8R
(A) (B)
27 R 2 2 A B
8R
GmM 2 GmM
(C) (D)
9R
2
9 9R2

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16. The magnitude of gravitational force on a particle of mass m l x


placed at a distance x from the rod of mass M and length l as
shown in the figure is: m
GMm GMm
(A) 2 (B)
l + x2 l (l + x )
GMm GMm
(C) (D)
l2 x (l + x )
+ x2
4

17. Water from a tap emerges vertically downwards with an initial speed of 1 ms -1. The cross-sectional area of
top is 10-4m2. Assume that the pressure is constant throughout the stream of water and that the flow is
steady. The cross-sectional area of the stream 0.15 m below the top is (take g = 10ms -2)
−4 −5 −5 −5
(A) 5  10 m (B) 110 m (C) 5  10 m (D) 2  10 m
2 2 2 2

18. One end of a thermally insulated rod is kept at a temperature T1 and T1 l1 l2 T2


the other at T2. The rod is composed of two sections of lengths l1 and l2
and thermal conductivities k1 and k2 respectively. The temperature at
the interface of the section is
( ) (
A k1l2T1 + k2l1T2 / k1l1 + k2l2 ) ( ) (
B k2l1T1 + k1l2T2 / k2l1 + k1l2 ) k1 k2

C (k l T + k l T ) / (k l
11 1 2 1 2 1 2
+k l )
2 1
D (k l T + k l T ) / (k l
11 1 2 2 2 11
+k l )
2 2

19. The network shown in the following figure is part of a circuit. I 1 15V 5mH
What is the potential difference (VB − VA ) . When current I is A B

5A and is decreasing at a rate of 103 A / s ?


(A) 5 V (B) 10 V
(C) 15 V (D) zero

20. In the following figures, the block of mass m is slightly k 2k


m
displaced from its mean position.
The ratio of time periods of oscillations in Fig(i) and Fig(ii)
(i)
is:
(A) 1 : 2 (B) 2 : 3 k 2k
m
(C) 3 : 2 (D) 1 : 1
(ii)

PART – C
Integer Type

1. A particle starts from origin at t = 0 and moves in the x – y plane with a constant acceleration 6 m/s2 in y-
x2
direction. The equation of motion is y= , then its velocity component along x-direction at x = 2 is (in m/s)
3
2. From the top of a tower of height 40m, a ball is projected upwards with a speed of 20 ms -1 at an angle of 300
−2
to the horizontal. If g = 10ms , after how long (in seconds) will the ball hit the ground?

3. A particle is moving in a circle of radius R. At t = 0 its speed is zero and during its motion speed varies as
v = 2 s 2 where s is the distance travelled. The angle made by acceleration vector with radial direction after
n
one revolution is tan −1   . Find n.
 
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4. A body cools from 50.0 °C to 49.9 °C in 5s. It will take 2n seconds to cool from 40.0°C to 39.9°C. Find n.
Assume the temperature of the surroundings to be 30.00C and Newton’s law of cooling to be valid.

5. Third overtone of a closed organ pipe is in unison with fourth harmonic of an open organ pipe. The ratio of
n
lengths of the pipes is . Find n.
8

space for rough work

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Section – II (Chemistry)
PART – A
Single Correct Choice Type
1.
⎯⎯⎯
CHCl3
KOH

N
H

Cl
Only and
(A) (B)
N CHO N CHO N
H H
CHO CHO

Only and
(C) (D)
N N N COOH
H H H

2. Which of the following is the correct set of statements?


H2C NH2 CH3 NH 2
NH2
N
H
(I) (II) (III) (IV)

(I) Correct basic order is I > III > II > IV


(II) Compound III has more dipole moment than compound (IV)
(III) Compound III and IV have same direction of dipole moment.
(IV) ‘N’ atom in the given compounds is sp2 hybridised
(A) I, II, III and IV (B) II, III and IV
(C) I and III only (D) II and III only

3. The nitrogen atom in each of the following tertiary amine may be removed as trimethyl amine by repeated
Hoffmann eliminations. Which of the following amines requires the greater number of Hoffmann sequence to
accomplish this?

Me NMe 2 Me

(A) (B) N (C) (D) N


N

 1  −a r
4. The wave function for 1s orbital of H-atom is 1s =   e 0 . The most probable distance of the
 (  a0 ) 
3/ 2

electron present in the 1s orbital from nucleus is


a0 a0
(A) a 0 (B) (C) (D) 2a0
2 3

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5. The d-orbitals which are not involved in hybridisation of central atom in ICl 4–
(A) d z 2 , d x2 − y 2 (B) d x2 − y 2 , d xy , d yz , d xz
(C) d z2 , d xy , d yz , d xz (D) d xy , d xz , d yz

6. Which of the following structure is correctly drawn according to fundamental idea of VSEPR theory?

F F

P
(A) F  F (B)
S
F F F

(  10928') (  90 )
Cl F F
Cl
I Si
(C) Cl (D)
Cl F F
( = 90 ) ( = 90 )
7. Propane reacts with Br2 to give 1, 2-dibromopropane. The anti-addition takes place due to the formation of
intermediate:
Br H3C HC CH2
+
(A) + (B) (C) H3C CH CH2 Br (D) None of these
H3C CH CH2 Br

dp
8. For a reversible adiabatic ideal gas expansion is equal to:
P
dV dV    dV dV
(A)  (B) − (C)   (D)
V V   −1 V V

9. Find the pH of a solution placed in a hydroquinone half-cell which was coupled with standard calomel
electrode. The emf of the combined cell was determined to be 0.123 V at 25 C
Ecalomel = 0.2415 V
EQo = 0.6996 V
(A) 2.67 (B) 4.35 (C) 5.67 (D) 6.02

10. Correct order of Acidity is-


OH

NO 2

I. CF3COOH II. NO 2
III. CH 3 SO3 H IV. HC  CCO2 H
(A) I  II  III  IV (B) III  I  IV  II (C) I  III  IV  II (D) III  IV  I  II

11. In cottrell Method of determination of molecular mass of non-volatile solute, 22 g of C6 H 6 was used as
solvent.
The readings on the differential thermometer before and after adding 0.586 g Napthalene (Mw=128), were
1.262 and 1.799 respectively. In a separate experiment, using the same amount of benzene but this time
adding 0.627 g of an organic compound X, the temperature readings were 1.269 and 1.963. Molecular mass
of X is-
(A) 106 (B) 53 (C) 123 (D) 86

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12. The IUPAC name of the following compound is:


CH3 OH

H3C CH CH CH2 COOH


(A) 4,4-Dimethyl-3-hydroxybutanoic acid (B) 2-Methyl-3-hydroxypentan-5-oic acid
(C) 3-Hydroxy-4-methylpentanoic acid (D) 4-Methyl-3-hydroxypentanoic acid

13. Which of the following has the most acidic hydrogen?


HO O
O O
(A) (B)
O OH
O O HO O

(C) (D)

HO O

14. Out of the following which are chiral


H3C H3C Cl

CH3 H3C CH3 CH3


(X) (Y) (Z)
(A) X, Y (B) Y (C) X, Z (D) Only Z

15. O
C CH3

( )
⎯⎯⎯→
Zn Hg
HCl

NO2
Product of the Clemmensen reduction is:

OH
H2C CH3
HC CH3

(A) (B)

NO2
NO2
OH
H2C CH3
H2C CH3

(C) (D)

NH2
NO2

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16. An optically active compound ‘X’ has molecular formula C 4H8O3. It evolves CO2 with NaHCO3. ‘X’ reacts with
LiAlH4 to give an achiral compound. ‘X’ is
H3C CH2 CH COOH H3C CH COOH
(A) (B)
OH CH3
H3C CH COOH H3C CH CH2COOH
(C) (D)
CH2OH OH

17. Of the ions Co2+, Sc3+ and Cr3+, which ones will give coloured aqueous solutions
(A) Co +2 (B) Sc +3 (C) Co +2 & Cr +3 (D) Sc +3 & Cr +3

18. EAN of [Ni (C2O4)3]4- is


(A) 34 (B) 38 (C) 28 (D) 30

19. Which of the following complex has a shape different from others?
(A) Ni (C2O4 )2  (B) Co ( NH3 )5 Cl 
-4 +2

(C) Co ( NH 3 )4  Cl 3 (D) Cu ( NH3 )4 


+2

20. Which of the following is known as Zeise’s salt


(A) K[PtCl3(2 ⎯C2H4)] (B) Pt Cl4
(C) [Pt (NH3)2 Cl2] (D) [Pt (NH3)3 Cl3]

PART – C
Numerical Based Type

1. Of the following amines how many can gives carbylamine reaction?


NH2 Me
N N
NH2
, H
, ,

Ph
Me NH2 Ph N
H , H

2. Find out the difference in number of angular nodes and number of radial nodes in the orbital to which last
electron of chromium is present.

3. 2SO2( g ) + O2( g ) 2SO3( g )


Starting with 2 mole of SO2 and 1 mole of O2 in 1 L flask mixture required 0.4 mole of MnO4– in acidic
medium. Find the value of Kc?

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4. Which compound shows stereoisomerism, position and functional isomerism?

H3C CH CH CH CH3 O

OH H3C CH2 CH2 C CH3


1 2
H3C CH2 CH CH2 CH2 CH3
Cl
3 4
CH2 CH2 OCH2 CHCH3
CH3CH2COOH
OH 6
5

5. Electrolysis of solution of MnSO4 in acidic medium is according to the reaction


Mn2+ ( aq ) + 2H 2O ⎯⎯
→ MnO2 ( s ) + 2H + ( aq ) + H 2 ( g )
If we pass 28.5 amp current for 24 hrs and 1 kg of MnO 2 formed then the current efficiency is x. The value of
x/10 is [atomic mass of Mn = 55]

pace for rough work

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Section – III (Mathematics)


PART – A
Single Correct Choice Type
y
1. If cos−1 x − cos−1 = , then
2
4 x 2 − 4 xy cos  + y 2 is equal to:
(A) −4sin 2  (B) 4sin 2  (C) 4 (D) 2sin 2

2. India plays two matches each with West Indies and Australia. In any match probabilities of India getting
points 0, 1 and 2 are 0.45, 0.05 and 0.5 respectively. Assuming that the outcomes are independent, the
probability of India getting at least 7 points is
(A) 0.8750 (B) 0.0875 (C) 0.0625 (D) 0.0250

3. The equation of the plane through intersection of planes x + 2 y + 3z = 4 and 2 x + y − z = −5 and perpendicular
to the plane 5x + 3 y + 6 z + 8 = 0, is
(A) 7 x − 2 y + 3z + 81 = 0 (B) 23x + 14 y − 9 z + 48 = 0
(C) 23x + 14 y − 9 z + 48 = 0 (D) 51x + 15 y − 50 z + 173 = 0

4. If x + y = a, x  y = b and x  a = 1, then

(A) x =
a + a b
,y=
( a 2 − 1) a − a  b ( ) (B) x =
a − a b ( ) , y = a + (a  b )
2

a2 a2 a2 a2

(C) x =
(
b + a b ), y can have any value (D) y =
(b 2
− 1) b − a  b
,y can have any value
2
a a2

5. The product of the perpendicular and drawn from any point on a hyperbola to its asymptotes is
ab ab a 2b2 a 2 + b2
(A) (B) 2 (C) (D)
a+ b a + b2 a 2 + b2 a 2b2

x y x2 y 2
6. If + = 2 touches the ellipse 2 + 2 = 1, then its eccentric angle  is equal to
a b a b
0 0
(A) 0 (B) 90 (C) 450 (D) 600

7. The latus rectum of a parabola whose focal chord is PSQ such that SP = 3 and SQ = 2 is given by
24 12 6
(A) (B) (C) (D) None of these
5 5 5

8. Let PQ and RS be tangent at the extremities of the diameter PR of a circle of radius r. If PS and RQ intersect
at a point X on the circumference of the circle, then 2r equals
PQ + RS 2 PQ.RS PQ2 + RS 2
(A) PQ.RS (B) (C) (D)
2 PQ + RS 2

9. The line of the system a ( 2 x − y − 2) + b ( x − 3 y + 4) = 0 situated farthest from the point (1, 1) is
(A) x + y − 4 = 0 (B) x + 2 y − 6 = 0 (C) 2 x + y − 6 = 0 (D) None of these

10. Solution of the equation


dy y
x = y + x tan is
dx x
x y x y
(A) sin = Cx (B) sin = Cx (C) sin = Cy (D) sin = Cy
y x y x
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10 
11. 
0
sin x dx is

(A) 20 (B) 8 (C) 10 (D) 18

dx
12. x 1 − x3
is equal to

1  1 − x3 − 1  1  1 − x3 − 3 
(A) log  +c (B) log  +c
3  1 − x3 + 1  3  1 − x3 + 3 
   
2  1  1  1 
(C) log   + c (D) log   + c
3  1− x  3  1− x 
3 3

1
13. If f ( x ) = log x − bx + x 2 , x  0, where b  0 is a constant, then
8
1
(A) f ( x ) has local minimum at x = for b = 1
4
(B) f ( x ) has no extremum for 0  b  1
b − b2 − 1
(C) f ( x ) has a local minimum at x = ,b  1
4
b + b2 − 1
(D) f ( x ) has a local maximum at x = ,b  1
4

14. y = 2 x + cot −1 x + log ( )


1 + x 2 − x , then y
(A) increases in 0,) only (B) decreases in 0 )
(C) neither increases nor decreases in 0 ) (D) increases in ( −, )
2
sin x
 12 1 1

lim 1sin x + 2 sin x + ... + n sin x 
2 2
15. =
x →0
 
( n + 1)
(A)  (B) 0 (C) (D) n
2

16. C02 − C12 + C22 ....( −1) Cn2 , where n is an even integer is
( −1) (C) ( −1)
2n n 2n n 2n
(A) Cn (B) Cn Cn −1 (D) None of these

17. The number of parallelograms that can be formed from a set of four parallel lines intersecting another set of
three parallel lines is
(A) 6 (B) 10 (C) 12 (D) 18

18. One root of the equation


3x − 8 3 3
3 3x − 8 3 = 0 is which of the following?
3 3 3x − 8
8 2 1 16
(A) (B) (C) (D) .
3 3 3 3

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19. If  is a complex number such that 2 +  + 1 = 0 , then 31 is


(A)  (B)  2 (C) 0 (D) 1

20. The domain of


x
f ( x ) = cot −1 , x  R is
x 2 −  x 2 

(A) R (B) R − 0 


(C) R −  n , n  N  (D) None of these

PART – C
Integer Type

12 3 63
1. If cos  = , cos  = , cos  = , then cos (  +  +  ) is:
13 5 65

x y −1 z − 2
2. Image of the point A(1,6,3) in the line = = is (a, b, c), then a + b + c is
1 2 3

3. If  2a + 4b c d  =   a c d  +  b c d  , then  +  =

x2
4. The number of values of c such that the straight line y = 4 x + c touches the curve + y 2 = 1 is
4

The digit at unit’s place in the number (13) + (11) − ( 23)


1225 1915 1225
5. is equal to:

space for rough work

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FIITJEE - NJEETS
(JEE MAIN TEST SERIES - 2024)
CLASS – XII & XII PASS
FULL TEST - 6
CONDUCTION DATE: 02/01/2024
ANSWERS
Section – I (Physics)
PART – A
1. B 2. C 3. A 4. D
5. C 6. B 7. A 8. A
9. D 10. B 11. D 12. D
13. C 14. C 15. A 16. D
17. C 18. A 19. B 20. C

PART – C
1. 3 2. 4 3. 1 4. 5
5. 7

Section – II (Chemistry)
PART – A
1. B 2. C 3. A 4. A
5. D 6. C 7. B 8. B
9. C 10. C 11. A 12 C
13. D 14. B 15. C 16. C
17. C 18. B 19. D 20. A
PART – C
1. 3 2. 2 3. 2 4. 1
5. 9

Section – III (Mathematics)


PART – A
1. B 2. B 3. D 4. A
5. C 6. C 7. A 8. A
9. A 10. B 11. A 12. A
13. B 14. D 15. D 16. D
17. D 18. B 19. A 20. D

PART – C
1. 0 2. 8 3. 6 4. 2
5. 1

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HINTS & SOLUTIONS
Section – I (Physics)
PART – A
1. B
L
Sol. Dimensions of = Time
R
Dimensions of CV = Charge
2. C
At 2
Sol.   dt =  At + B = + Bt
2
3. A
Sol.
y

EB


EA
P

x
O q1 / 2

q1 q/2
EA = , EB =
4 0 4 0
E 1
tan  = B =
EA 2
1
 = tan −1  
2  
4. D
Sol. s3 = 10 3t and s y = 10t − t 2
ux = u cos , u y = u sin 
1
sx = ( u cos ) t + ax t 2 = 10 3t
2
u cos = 10 3m / s2
1
s y = ( u sin  ) t − a y t 2 = 10t − t 2
2
ay
u sin = 10m / s and = 1m / s 2
2
ay = 2 m / s2

( ux ) (
+ ( u y ) = 102 + 10 3 )
2 2 2
u2 = = 20m / s
uy 1
tan  = =   = 300
ux 3
5. C

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Sol. For net force on charge q to be zero, Q →


4q Q q
k ( 4q ) q k Q q
negative =
l2 l
2
0 l l
  2
2
 Q =q
Q = −q
k ( 4q ) q k ( 4q ) q
Net force on 4q charge = −
(l / 2)
2
l2
k 4a 2
= ( 4 − 1)
l2
3q 2
F=
 0l 2
6. B

Sol. C1 = 4 0 R1 , C2 =
(
4 0 R1 R2 )
(R 2
− R1)
4 ( R R )
Given C2 = 3C1 Hence
0
= 3  4 R
1 2

(R − R )
2 1
0 1

R2 3
Which given = , Which is choice B
R1 2

7. A
Sol. at x = 0
v2 = 9
initial velocity v = 3 units
dv 1 dx
= ( 2 x + 9 ) .2
−1/2
a=
dt 2 dt
a = 1 unit
8. A
Sol. The acceleration of the body down the plane is g sin  −  g cos = g ( sin  −  cos ) = g ( sin  − 0.5x cos ).
Therefore, the body will first accelerate up to x < 2 tan . The velocity will be maximum at x = 2 tan ,
because for x > 2 tan , the body starts decelerating. Hence, the correct choice is A
9. D
Sol.

kt sin  = mg
mg
t=
k sin 
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10. B
du  6M 12 N 
Sol. F =− = − + 13  =0
dr  r 7 r  r = r0
2N
 r06 =
M
M2
So, U 0 =
4N
11. D
Sol. a = g sin  −  g cos
2E
u=
m
2E
0= − 2as
m
E
s=
m ( g sin  −  g cos )
 mg cos E
W=
m ( g sin  −  g cos )
12. D
Sol. Given mQ = pmP and vQ = vP / q. From the principle of conversion of momentum, we have (since body P
comes to rest after collision)
mP vP + mQ vQ = mQ v
Where v is the velocity of body Q after collision. Thus
vP
mP vP + PmP = pmP v
q
v p+q
Which gives = ... ( i )
vP pq
Now, the coefficient of restitution is given by
v v
e= =
vP − vQ vP
vP −
q
v e
Which gives = ( q − 1) ... ( ii )
vP q
p+q
Equating (i) and (ii), we get e = which is choice D.
p ( q − 1)
13. C
Sol. For pure rolling on an inclined plane
mg sin 
friction needed = F =
 mR 2 
 + 1
 I 
Also F  f s /max
mg sin 
  mg cos 
 mR 2 
 + 1
 I 
14. C
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1 M 
Moment of inertial of complete disc about O is I = MR . Mass of the cut-out part is m =   . The
2
Sol.
2  4 
2
1 2 1  M  R  1
moment of inertial of the cut-out portion about its own centre I 0 = mr =    = MR because r
2

2 2  4  2  32
= R/2. From the parallel axes theorem, the moment of inertial of the cut out portion about O is
2
1  M  R  3
I c = I 0 + mr = MR +    = MR
2 2 2

32   
4 2 32
1 3 13
 Moment of inertial of the shaded portion about O is I s = I − I c = MR − MR = MR , which is choice C.
2 2 2

2 32 32

15. A

Sol. Let  be the mass per unit length of the ring. L = 2 R is C


dx
the length of the ring. Consider a small element of length dx
of the ring located at C. Then, Force along BC is R 3R
GM  dx
f = . Therefore, force along 
( 3R ) 8R
2
A B
GM  dx 8R 8 GM  dx
BA is dF = f cos = 2
=
9R 3R 27 R 2
8 GM 8 GMm
2 
 Total force =  dx =
27 R 27 R 2
Because   dx =   L = m, the mass of the ring. Hence the
correct choice is A.

16. D
Sol.
l r

m
dr x
M
dm = dr
l
Gmdm GmM 1
dF = = dr
r2 l r2
GmM l + x 1 GmM
F=  2 dr =
l x r x (l + x )
17. C
Sol. From equation of continuity
a1v1 = a2v2
v1 = 1ms −1 , a1 = 10−4 m2 , v2 = velocity of stream at h = 0.15 m below the tap.
v22 = v12 + 2 gh
v22 = 4
 a2 = 5 10−5 m2
18. A
Sol. Let T0 be the temperature at the interface and A be the cross-sectional area of each rod.

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T0

T1 A k1 B k2 T2

l1 l2

In the steady state, the rate of flow of heat through rod A = rate of flow of heat through rod B, i.e.
Q1 Q2
=
t t


(
k1 A T1 − T0 ) = k A (T
2 0
− T2 )
l1 l2

(
 k1l2 T1 − T0 = k2l1 T0 − T2 ( ) )
 T0 =
(k l T + k l T )
1 2 1 2 1 2

(k l + k l ) 1 2 2 1

19. B
Sol. Kirchhoff’s 2nd law
di
VA − VB = Ri + E + L
dt
 di 
1 5 − 15 + 5 10−3  −10−3 ( ) 
 dt
= 10−3 A / s 

VA − VB = −10V
VB − VA = 10V
20. C
Sol. In first case
K .2 K 2K
Keff = =
K + 2K 3
In second case
Keff K 2 = K + 2 K = 3K
m
T = 2
K
T1 3
=
T2 2
PART – C
1. 3
x2
Sol. y=
3
dy 2 x  dx 
=  
dt 3  dt 
2
d 2 y 2  dx  2 d 2 x
=   + x
dt 2 3  dt  3 dt 2
d 2x 
2
2  dx 
 6=    dt 2 = 0 
3  dt   
2. 4
Sol. The horizontal range R = AC is
u sin 2 20  20  sin 60
2 0

= = 20 3m
g 10
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20ms-1
B

300 C
A
R
20m/s

40m

20ms-1

Ground
D
At C, the velocity of the ball is again 20 ms-1 directed down as shown in Fig.
The downward vertical component of this velocity is 20sin300 = 10 ms-1. The ball will hit the ground at D after
travelling a vertical distance h = 40 m. If t1 is the time taken for this, then
1
h = ut1 + gt
2 1
40 = 10t1 + 5t1
2

t1 + 2t1 − 8 = 0
2

The positive root of this quadratic equation is t1 = 2s . Now, the time of flight from A to C via B is

2u sin  2 ( 20 )  sin 30
0

t2 = = = 2s
g 10
 Total time taken = t1 + t2 = 2s + 2s = 4s . Hence the correct choice is D
3. 1
Sol. dv vdv v
at = = = 8s3 a
dt ds
v 2
4s 4 at
ac = = 
R R
ac
a 8s3 2R
tan  = t = 4 =
ac 4s / R s
After one revolution s = 2 R
1
tan  =

4. 5
Sol. Rate of cooling
T1 − T2  T + T  
=   1 2  − Ts 
t  2  
0.1
Case I: =   49.95 − 30
5
0.1
=
5 19.95

0.1
Case II. =  39.95 − 30
t
0.1
=  9.950 
t
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0.1 0.1 9.95


 =   t  10s
5 5 19.95
5. 7
7
Sol. lc = 
4
4lc
=
7
7v
f7 =
4lc
For open pipe
4v
f4 =
2lo
( F7 ) closed = f ( 4 ) open
lc 14 7
= =
lo 16 8

Section – II (Chemistry)
PART - A
1. B
Sol. CHCl3 + KOH →: CCl2 + KCl + H 2O
Cl
Cl
+ : CCl2 → →
C
Cl +H+
N N N

H H

⎯⎯⎯⎯
2NaOH
−2NaCl
→ ⎯⎯⎯ →
OH −H2O
CCl2 C CHO
N N N
O H
H H H
2. C
Sol. Conceptual
3. A
Sol. In option (a) all group attached to the Nitrogen atom are alkyl chain (not a methyl group), so it requires most
number of sequences.
4. A
d 2
Sol. should be zero, when probability of distance of electron is maximum.
dr 2
−r /a
 e 0 =0
r
or ln e = − ln1
a0
r = a0
5. D
Sol. ICl4− = sp3d 2
s + px + p y + pz + d x2 − y2 + d z2 orbitals of iodine are involved in hybridisation.
6. C
Sol. (A)  = less than 109°28
(B) Incorrect position of L.P.
(C) Correct square planar structure with  = 90°
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(D)   90° in SiF4 because it is tetrahedral.


7. B
Sol. Formation of ring intermediate favour anti attack to avoid high steric hindrance.
8. B
Sol. PV  = K
P V  −1dV + V  dP = 0
dP dV
= −
P V
9. C
2.303RT
Sol: EQ = EQo − pH
F
H+ +e→ H
= 0.6996 − 0.0591 pH
Ecell = EQ − Ecalomel .
 0.123 = ( 0.6996 − 0.0591 pH ) − 0.2415
 pH = 5.67
10. C
Sol. Factual
11. A
0.586
Sol: T = 1000 Kb 
128  22
K b = 2.58
1000  Kb  0.627
M2 = = 106
0.694  22
12 C
Sol. Conceptual
13. D
Sol.
O O

HO O

 Most acidic H-atom is present in this compound.


14. B
Sol. X and Z has centre of symmetry
15. C
Sol.
O
C CH3

( )
⎯⎯⎯→
Zn Hg
HCl

NO2 NH2
16. C
Sol.

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NJEETS-2024 - FT - 6 -PCM -25

H3C CH CO2H ⎯⎯⎯


LAH
→ H3C CH CH2 OH
H2C OH H2C OH
(X)
NaHCO3

H3C CH CO2 CO2


H2C OH
17. C
Sol. Co2+ and Cr3+ have unpaired electrons in the 3d subshell. Hence, they will give coloured solutions and
attracted by the magnetic field. Sc3+ has no unpaired electron in 3d subsell. Hence it do not give colour.
18. B
Sol. Here EAN of Ni = [(28−2) + 3(2×2)] = 38
19. D
Sol. [Cu (NH3)4]2+ has square planar structure others are tetrahedral.
20. A
Sol. K[PtCl3(2 ⎯C2H4)] is known as Zeise’s salt where 2 shows two carbon atoms are attached to central atom
of the complex via  electron donation.
PART – C
1. 3
Sol. 1 amine gives carbylamine reaction.
2. 2
Sol. Cr ⎯⎯
→3d 5 4s1
Number of angular nodes = 2
Number of radial nodes = 3 – 2 – 1 = 0
Angular node – radial node = 2
3. 2
Sol. At equilibrium,
5SO2 + 2MnO4− ⎯⎯
→ 2Mn+2 + 5SO4−2
2 mole of MnO4– = 5 mole of SO2
5
 0.4 mole of MnO4– =  0.4 = 1 mole SO2 = 2x
2
1
x=
2
Now,
2SO2 + O2 2SO3
t=0 2 1 0
,
At eqm 2-2x 1-x 2x

 SO3  =  2 x 
2 2

Now, KC =
 SO2  O2  1 − x  2 − 2 x 
2

2
 1
2  1 2
=  2
= =2
 1  1  11
1 −  2 − 2  
 2  2
4. 1
Sol. All the three types of isomerism are present in the species.
5. 9
Sol. w = Zit

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NJEETS-2024 - FT - 6 -PCM -26

87 i  24  60  60
1000 = 
2 96500
i = 25.676 A
25.676  100
Efficiency = = 90%
28.5
90
 =9
10
Section – III (Mathematics)
PART - A
1. B
y
Sol. cos−1 x − cos−1 =
2
 xy y2 
 cos −1  + 1 − x 2 1 − =
 2 4 

xy y2
 + 1 − x2 1 − = cos 
2 4
y2
2 1 − x2 1 − = 2cos  − xy
4
 y2 
 4 (1 − x 2 ) 1 −  = 4cos 2  + x 2 y 2 − 4 xy cos 
 4 
 (1 − x 2 )( 4 − y 2 ) = 4cos 2  + x 2 y 2 − 4 xy cos 
 4 − 4 x 2 − y 2 + x 2 y 2 = 4 cos 2  − 4 xy cos  + x 2 y 2
 4 − 4 x 2 − y 2 = 4 cos 2  − 4 xy cos 
4 x2 − 4 xy cos  + y 2 = 4 (1 − cos2  ) = 4sin 2 
2. B
Sol. Since there are just four matches to be played, India can get a maximum of 8 points.
 P(India gets at least 7 points)
= P(getting exactly 7 points) + P(getting exactly 8 points)
= P(getting 2 in each of the 3 matches and 1 in one match) + P(getting 2 in each of the four matches)
=4 c3 ( 0.5) ( 0.05) + 4 c4 ( 0.5)
3 4

= ( 0.5) ( 0.2 + 0.5) = 0.125  0.7 = 0.0875


3

3. D
Sol. Any plane through the intersection of the given planes is
x + 2 y + 3z − 4 + K ( 2x + y − z + 5) = 0
i.e. (1 + 2K ) x + ( 2 + K ) y + (3 − K ) z + 5K − 4 = 0
This is ⊥ to 5x + 3 y + 6 z + 8 = 0
5 (1 + 2K ) + 3( 2 + K ) + 6 (3 − K ) = 0
 29 + 7K = 0
29
K = −
7
 reqd. plane is
 58   29   29  145
1 −  x +  2 −  y +  3 +  z − −4 = 0
 7   7   7  7
 −51x − 15 y + 50 z − 173 = 0
 51x + 15 y − 50 z + 173 = 0
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4. A
Sol. x + y = a  y = a − x …1
x y = b …2
x.a = 1 …3
By (1) and (2), x  ( a − x ) = b
 xa = b
 a ( x  a) = a b
 ( a.a ) x − 1.a = a  b
 a x − 1.a = a  b
2

 x=
(a + a b )
a2

y=a−x =a−
( a + a  b ) = ( a − 1) a − a  b
2

a2 a2
5. C
a 2b2
Sol. Product of perpendicular and drawn from any point on a hyperbola to its asymptotes =
a 2 + b2
6. C
x cos  y sin 
Sol. Let  be the eccentric angle, then tangent at '  ' is + =1
a b
x y
Also, + = 1 is the tangent
2a 2b
cos  sin 
 = =1
1 1
2 2
1 1
 cos  = ;sin  =   = 450
2 2
7. A
2 1 1
Sol. Since = + (Where l is the semi-latus rectum of the parabola)
l SP SQ
2 1 1 5 12 24
 = + =  l =  2l =
l 3 2 6 5 5
24
 latus rectum =
5
8. A
PQ PQ
Sol. tan  = =
PR 2r
S
RS
cot  = 
2r Q
PQ.RS
 tan .cot  =
4r 2
 4r 2 = PQ.RS  2r = ( PQ )( RS ) 

R P
r

9. A
Sol. Point of intersection of 2 x − y − 2 = 0 and x − 3 y + 4 = 0 is (2, 2).

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The line of the system a ( 2 x − y − 2) + b ( x − 3 y + 4) = 0 situated farthest from the point (1, 1) is the line
passing through (2, 2) and perpendicular to the line passing through points (1,1) and (2,2).
10. B
Sol. Put y = vx
dv dy
v + x =
dx dx
dx
 cot vdv =  log sin v = log Cx
x
y
 sin v = Cx  sin = Cx
x
11. A
10 
 / 2 

Sol. 0 sin x dx = 10 
0
sin xdx + 
/ 2
sin xdx 

= 10  − cos x0 + 10  − cos x  / 2
/ 2 

= 101 + 1 = 10  2 = 20
12. A
Sol. Put 1 − x 3 = y 2  −3 x 2 dx = 2 ydy
dx 2 ydy 2 ydy
 = =
x 1− x 3
−3x 3
1− x 3
−3 (1 − y 2 ) y
2 dy 2 1 y −1
3  y2 −1 3 2
= = . log +c
y +1
1 1 − x3 − 1
= log +c
3 1 − x3 + 1
13. B
1 1
Sol. f’(x) = − b + 2 x; f " ( x ) = − 2 + 2
8x 8x
For max or min, f’(x) = 0
1 – 8bx + 16x2 =0
8b  64b2 − 64 b  b2 − 1
x= =
32 4
1
Case I. When b = 0, f’(x) = + 2x  0
8x
Hence there is no extreme value for b = 0
Case II. When 0 < b < 1, then b2 −1  0
 x is not real.
 there is no extreme value for 0  b  1
1
Case III. When b = 1, then x =
4
f "( x ) = 2 − 2 = 0
1 1
f ''' ( x ) = 3
= 16 (  0 ) for x =
4x 4
1
x= is a point of inflexion.
4
Case IV. When b > 1
b − b2 − 1 b + b2 − 1
Let  = , =
4 4
Clearly   

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We have
1  2  
2
2 b
− b + 2 x =  x 2 − bx +  =  x −  − ( b 2 − 1) 
1 1 1
f '( x) =
8x x 2 16  x  4  16 
2  b 1 2  b 1 2 
= x− − b − 1  x − + b − 1 
x  4 4  4 4 
2 2
= ( x − )( x −  ) = ( x −  )( x −  )
x x
 f ' ( x )  0, for 0  x  
f '( x ) < 0, for   x   and f ' ( x )  0 for x  
 f ( x ) has a local Max. at

x==
1
4
( )
b − b2 − 1 and local min. at

1
(
x =  = b + b2 − 1
4
)
14. D
dy 1 1  1 
Sol. = 2− + 
 .2 x − 1
dx 1+ x 2
1 + x2 − x  2 1 + x 2 
1 1 x − 1 + x2
= 2− +
1 + x2 1 + x2 − x 1 + x2
1 1
= 2− −
1 + x2 1 + x2
2 x2 + 1 1
= −
1 + x2 1 + x2
2x2 + 1 − 1 + x2
=
1 + x2
dy
Now  0  2x2 + 1 − 1 + x2  0
dx
 ( 2 x 2 + 1)  1 + x 2
2

 4 x 4 + 3x 2  0
Which is true for all real value of x. Hence y increases in ( −, ) .
15. D
Sol. We have
sin 2 x
lim 11/ sin x + 21/ sin x + ... + n1/ sin x 
2 2 2

x →0  
1/ t  1 
= lim 1'+ 2'+ ....nt   where = t  1
t →0
 sin 2 x 
1t + 2t + 3t + ... + nt  1 + 2 + 3 + ... + n 
t

Since  
n  n 
 n ( n + 1) 
t

 1t + 2t + ... + nt  n  
 2n 
 n +1 
t

= n 
 2 
 n +1
 (1t + 2t + ... + nt )
1/ t
 n1/ t .  
 2 

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 n +1 n +1
 lim (1t + 2t + ... + nt )
1/ t
 lim n1/ t  
t → t →
 2  2
 n + 1
 n  1 2n  n + 1  n  2 
 
 lim (1t + 2t + ... + nt )
1/ t
=n
t →
16. D
We have (1 + x ) = C0 + C1 x + C2 x 2 + ... + Cn x n ... (1)
n
Sol.
n
 1 C1 C2 n Cn
1 −  = C0 − + 2 + ... + ( −1) n ... ( 2 )
 x x x x
 C02 − C12 + C22 ... + ( −1) Cn2
n

= co-eff. Of the term independent of x in


Product of R.H.S. (1) and (2)
= co-eff. Of term independent of x in
n

(1 + x ) 1 − 
n 1
 x
= co-eff. Of x n in ( −1) (1 − x 2 ) = n Cn / 2  nis even
n n

17. D
Sol. Since each parallelogram is formed by choosing two parallel straight lines from the first and two from the
second set.
 total no. of parallelograms formed
= 4 C2 3 C2 = 6  3 = 18
18. B
Sol. Operate R1 → R1 + R2 + R3 ,
3x − 2 3x − 2 3x − 2
3 3x − 8 3 =0
3 3 3x − 8
 x = 2 / 3 as one of the roots.
19. A
Sol. Since 2 +  + 1 = 0
−1  1 − 4 −1  3i
 = = =  or 2 .
2 2
Take  = 
  31 = 31 = 30 . = ( 3 ) .
10

= (1) . =  = 
10

Take  = 2  31 = ( 2 )
31

= 62 = 60 .2 = (1) 2 = 2 = 


Hence 31 =  .
20. D
is defined if x 2 = ( x 2 )  .
x
Sol. Domain of cot −1 x is R and
x −  x 
2 2

i.e.x 2 is not integer ( x 2   x 2  )


Hence x  non negative integer i.e. 0 or +ve integer.
2

Hence domain = R −  n  0, n  Z 
Thus correct answer is (D)

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NJEETS-2024 - FT - 6 -PCM -31

PART – C
1. 0
Sol. cos (  + +  ) = cos  cos  cos  − sin  sin  cos  − sin  cos  sin  − cos  sin  sin 
12 3 63 5 4 63 5 3 16 12 4 16
= . . − . . − . . − . .
13 5 65 13 5 65 13 5 65 13 5 65
2268 − 1260 − 240 − 768
= =0
13.5.65
2. 8
Sol. Any point P on the given line is
( r,2r +1,3r + 2)
 direction ratios of AP are
( r −1, 2r − 5,3r −1)
Now AP ⊥ to the given line if
1 ( r −1) + 2 ( 2r − 5) + 3(3r −1) = 0
14r −14 = 0  r = 1
 P is (1,3,5) .
Thus the foot of the ⊥ from A on the line is (1,3,5) . Let B ( a, b, c ) be the image of A in the given line. Then P
is the mid point of AB.
a +1 c+3
 = 1  a = 1 and =5c =7
2 2
b+6
=3b = 0
2
 B is (1, 0, 7)
3. 6
Sol.  2a + 4b c d  = 2  a c d  + 4 b c d 
     
=   a c d  +  b c d 
 = 2,  = 4  +  = 6
4. 2
x2 y 2
Sol. y = 4x + c touches + =1
4 1
If c 2 = a 2 m2 + b2  Here a 2 = 4, b2 = 1, m = 4
i.e. If c2 = 4 (16) + 1 = 65
This gives two values of c.
5. 1
(10 + 3) + (10 + 1) − ( 20 + 3)
1225 1915 1225
Sol.
I II III

Last term of Ist and IIIrd expansion gets cancelled and rest are divisible by 10 and in IInd expansion last term
is 1 and rest are divisible by 10 so at unit place this number has digit 1.

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