Project Work Chem.
Project Work Chem.
Project Work Chem.
Submitted By
Kabiraj Thakur
Grade: XI
Roll no: 059
Submitted To
Name of supervisor
Signature:
..............................
Date:13/06/2023
DECLARATION
In compliance with academic integrity, I proudly declare that the project work,
titled "Exploring Bonding Molecular Structure and Lewis Structure," submitted
to the Department of Chemistry at SOS Hermann Gmeiner school, Sanothimi
Bhaktapur, is a unique and original undertaking. This research was conducted
under the attentive guidance (Firoj Malla Sir) of the esteemed faculty of the
Chemistry Department. It is presented as a partial fulfillment for the
requirements of the grade 11th chemistry course. I affirm that this project work
report has not been presented for the attainment of any other academic degree or
qualification.
Signature:
.............................
Date:.........................
ACKNOWLEDGEMENT
I would like to express my sincere gratitude to all the people who have
supported me in the preparation of this report. Without their guidance,
encouragement, and assistance, I would not have been able to complete this
project.
First and foremost, I would like to thank my teacher, MR. Firoj Malla Sir,
for their invaluable support and guidance throughout the course of this
project. Their feedback, Insights, and encouragement have been instrumental
in helping me to develop my ideas and produce a high-quality report.
I would also like to acknowledge the support of the SOS Hermann Gmeiner
Library Staff. Who provided me with access to a wide range of resources and
materials that were crucial to the success of this project. Their expertise and
willingness to help make the research process much smoother and more
efficient.
This project takes a deep dive into the world of chemical bonds and how
those bonds build molecules. It looks at different types of bonds, like
covalent, ionic, and metallic, and how each one affects how a molecule acts.
Starting with the basics of Lewis structures and how molecules are shaped,
the project shows how important understanding these things is for predicting
chemical reactions and making new compounds.
The project also explores real-world uses for what it learns about chemical
bonds, in areas like materials science, pharmaceuticals, and environmental
chemistry. The research adds to what we know about chemical bonding by
questioning existing theories and comparing those with computer models.
Overall, this project helps us understand how molecules are built and how
important that is for chemistry. The things it learns can be used for further
research and give scientists, teachers, and others a better understanding of the
field, which can help them make exciting new discoveries and applications in
chemistry.
Table of Contents
CERTIFICATE OF APPROVAL................................................................................ii
RECOMMENDATION LETTER................................................................................iii
DECLARATION.........................................................................................................iv
ACKNOWLEDGEMENT…........................................................................................v
ABSTRACT…..............................................................................................................vi
TABLEOFCONTENTS...............................................................................................vii
INTRODUCTION............................................................................................................
OBJECTIVES OF STUDY..............................................................................................
CONCLUSION.................................................................................................................
RECOMMENDATION....................................................................................................
APPENDIX…....................................................................................................................
REFERENCES.............................................................................................................30
INTRODUCTION
Atoms are generally not capable of free existence but groups of atoms of the
same or different elements of one species, e.g. H2 , O2 , P4. Most of the molecules
are clusters of atoms. Molecules will only be formed if they have lower energy
and are more stable than the individual atoms.
The Atoms combine with each other to form a molecule in order to obtain
stability. The atoms are more stable in bonded form than in uncombined form as
the energy of the system is decreased in combined state Therefore, chemical
bonding is an essential part in formation of molecules by the atoms in order to
attain stability
It is well known that elements rarely occur in the free state at ordinary
temperature. Except for noble gasses, atoms of all other elements tend to
combine either with each other or with the atoms of other elements to form
aggregates of atoms with definite composition. The attraction between atoms
forming the compound is called a chemical bond or valence bond.
Chemical Bond
● A force when acts between two or more atoms to hold them together as a
stable molecule, the bond thus formed is chemical bond.
● It is a group of two or more atoms involving redistribution of electrons
among them.
● This process is accompanied by a decrease in energy.
● High M.P and B.P: Ionic compounds generally have high melting and
boiling points attributed to the strong electrostatic forces requiring
substantial energy for separation.
● High nuclear charge and small atomic size: tend to hold the valence
electrons more tightly and form covalent bonds.
● Number of valence electrons: Atoms having 5, 6, and 7 valence
(electrons hydrogen atom has only one electron) achieve the stable octet
by sharing 3, 2 or 1 electron pairs to form covalent bonds.
Concept of formal charge
A formal charge (FC) is the charge assigned to an atom in a molecule,
assuming that electrons in all chemical bonds are shared equally between atoms,
regardless of relative electronegativity. When determining the best Lewis
structure (or predominant resonance structure) for a molecule, the structure is
chosen such that the formal charge on each of the atoms is as close to zero as
possible. The formal charge of any atom in a molecule can be calculated by the
following equation:
FC = V (no. of valence electron) -N (no. of lone pair electron)-B (no. of bonds)
Formal charge 0 0 0
Oxidation state -2 4 -2
● Neither Hard nor Brittle: Covalent compounds are soft and waxy,
lacking the hardness and brittleness of ionic compounds. Weak van der
Waals forces hold molecules together, allowing for easy breaking without
sharp cleavage.
coordinate covalent bond
● A coordinate covalent bond is also known as a dative bond, or a dative
covalent bond.
● A covalent bond is formed when 2 electrons (a bonding pair) is shared
between 2 atoms.
● A 'normal' or 'conventional' covalent bond is formed when each of the 2
atoms to be bonded contribute 1 electron to the bonding pair of electrons.
● A coordinate covalent bond (dative bond) is formed when both
electrons forming the bonding pair of electrons are provided by the same
atom.
● An atom with a lone pair of electrons (non-bonding pair of electrons) is
capable of forming a coordinate covalent bond (dative bond).
● Once the covalent bond is formed it is impossible to distinguish the origin
of the electrons so a coordinate covalent bond is exactly the same as any
other normal covalent bond.
● In this type of bonding, the atom that shares an electron pair from itself is
termed as the donor.
● The other atom which accepts these shared pairs of electrons is known as
a receptor or acceptor.
● Thus, A coordinate covalent bond is a covalent bond in which the
shared pair of electrons is contributed by only one atom.
Properties and Characteristics of coordinate covalent bond
● High melting and boiling points: The metallic bond is formed due to the
strong electrostatic forces between the sea of electrons and cations. As a
result, metals have high melting and boiling points.
● They are all short-range forces and hence only interactions between
nearest need to be considered instead of all the particles.
● The greater is the attraction if the molecules are closer due to Van der
Waals forces.
● Van der Waals forces are independent of temperature.
● Count the number of valence (outer shell) electrons that each atom has in
total (Q)
● Select the atom with least no. in the molecule or least Electronegative
atom / Atom with largest size as the central atom .
● Hydrogen and Fluorine can never be the central Atom
● Complete the octet of the corner atom at first .
● If net charge is positive (eg. H3o+) then it will be on central atom and if
the net charge is negative (eg. NO3-) then it will be on the corner atom.
Method: calculate
● Q= total valence electron + negative charge – positive charge
● When two or more valid Lewis structures can be drawn for the same
molecule, resonance occurs.
● A molecule can only resonate if it contains one or more double bonds.
Single-bond molecules never exhibit resonance.
● Every resonance structure needs to follow the octet rule and have the
appropriate amount of electrons.
● The resonating structures are formed due to delocalization of π-bond
RESONANCE IN NO2–
RESONANCE IN CO3
RESONANCE IN BENZENE
2 Linear
3 Trigonal Planar
4 Tetrahedral
5 Trigonal Bipyramidal
6 Octahedral
7 Pentagonal Bipyramidal
A. METHANE ( CH4 )
LEWIS STRUCTURE
GEOMETRY : TETRAHEDRAL
SHAPE :TRIGONAL
HYBRIDIZATION
The idea of combining two atomic orbitals to create a new class of hybridized
orbitals is known as hybridization in chemistry. Usually, this intermixing leads
to the formation of hybrid orbitals with completely distinct energies, forms, etc.
The majority of hybridization occurs between atomic orbitals of the same
energy level. But as long as they have the same amount of energy, half-filled
and fully-filled orbitals can also participate in this process.
Characteristics of Hybridization
1. When orbitals from the same atom or ion have comparable energies,
hybridization takes place.
2. The number of orbitals engaged in the hybridization process is equal to the
number of hybrid orbitals.
3. Hybrid orbitals are always similar in energy and shape.
4. Hybrid orbitals produce more stable bonds than pure atom orbitals.
5. The creation of equivalent orbitals with the highest symmetry is the aim of
hybridization.
TYPES OF HYBRIDIZATION
1. SP HYBRIDIZATION
● Mixing up of s and p orbital of nearly same energy
● Geometry = linear
● Eg : BeCl2 , C2H2
2. SP2 HYBRIDIZATION
● Eg : BF3 , C2H4
3. SP3 HYBRIDIZATION
● Geometry = Tetrahedral
● Energy Storage: Study chemical bonding for insights into energy storage
materials, crucial for advancing battery technologies.
● To comprehend the basic ideas behind chemical bonds, such as ionic and
covalent bonds, and how they affect the synthesis of molecules.
● Understanding how lone pairs and bonding pairs affect molecular shape
can help researchers apply the VSEPR theory to the study of various
compounds and predict their three-dimensional molecular geometry.
Chemical Bonding
3. chemistrylearner.com
4. Chem.libretexts.org
5. Wikipedia
6. Unacademy