STRAIGHT OBJECTIVE TYPE

(Single Correct Answer)

This section contains multiple correct answer type questions. Each question has 4
choices (a), (6), (c) and (d), out of which only one is correct.
1. Which of the following gives rise to the formation of bond?

(a) (b)

(c) (d)

2The dipole moment of HCI is 1.03 D and its bond length is 1.26A, what is the
percentage ioniccharacter in HCI bond?
(a) 60% (b) 39% (c) 29% (d) 17%
3 The bond angles of NH3 ,
NH and NH are in the order:

(a)NH>NH3 > NH (b) NH> NH3 > NH2

(c) NH> NH2 > NH (d) NH3 > NH > NH2
4. Hybridization at central atom in IC1:
(a) dsp 2 (b) sp (c) sp (d) sp
3
 er
5.
5. Percentage
s-character in the
(b) 33%
hybrid orbital of BCI, is
(c) 50%
.

emislry
(a) 25% d) 66%
6. Resonance is possible in:
(b) H,0 (c) CH4 (d) NH
(a) O
7. Which of the following is not possible ?
(a) SF (b) OF; (c) OF4 (d) 0,F2
8. Which ofthe following does not have coordinate bonds?
(a) CO (b) 03 (c) CH NC (d) CO
The number of sp*-s sigma bonds in benzene are
(a) 3 (b)6 (c) 12 (d) 18
10. The correct order of C-0 bond strength of CO, cog and CO, is :

(a) Co<cO, < CO (b) CO <CO < CO

() CO< Co <CO d) cO« CO, <
CO
11. Among the oxides of nitrogen N20, NO and NO2, the molecules having unpaired
electrons are :
(a) N,O, N0 (b) NO, NO0 (c)N,0, NO2 (d) N0, NO, NO
12. The number of three centre two electron bonds in a
molecule of diborane is
(a) 0 (b)2 (c) 4 (d) 6
13. The solubility
of
Na 2 BeS04, MgS04 and BasO4 in water follow the order
S04,
(a) BeSO >
MgSO, > Na , SO4 > BaS04
(b) Na SO4> BeSO4 >MgS04> BaSO4
(c)BeSO, > Na, SO4 > MgS04 > BaS04
(d) MgSO4> BeSO4> Na2SO4 >
14. Which of the following pairs of
BaSO4
species have identical shapes?
(a) NO and NO (b) PCIs and
BrFs (c) XeF4 and ICl4 (d) TeCl4 and Xe0
15. The ratio of
o-bond and n-bond in tetracyano ethylene is
(a)2:1 (b) 1:1 ()1:2
16. The correct order of (d) none of these
strength of H-bond in following compound:
(a) H,0>H202 HF >H2S >
(b) HF> H202 >
(c) HF> H0> HS>H202
(d) HF> H,0>H2S
17. The shapes of
XeF4, Xef's and SnCl2 are: H,0>H,02 > H2S
(a) Octahedral, trigonal bipyramidal and
bent
(6) Sq.
pyramidal, pentagonal planar and linear
(c) Sq. planar, pentagonal planar and
(d) See-saw, T-shaped and linear
angular
18. Which compound has electrovalent,
covalent,
(a) CuSO4 5H,0 (b) ZnSO4 7H20 (c) co-ordinate as well as hydrogen bond
19. Among KO2, KAIO2, Ca02 and (d) FeCl6H,0
FeCl, 6H,0pFeSO47H,0
NO, unpaired electron is presenti
(a) NO, and Ca0 (b) KO2 and
KAlO,
(c) KO2 only (d) Ca0, only
hemrco
h e m i e aB
l on bonding nding
is
assumed by : (IV) Solid BeH2
L i n e a rs t r u c t u r e

(11) CS2 (III) NO

(0
NCO (b) (II), (111) and (IV)
( a )a l lt o u r (d) (I) and (111)
and (lII)
(I) moment?
(c)(D. dipole
Which
has
maximum

Cl
.
CI C
C (b)
(a)

Cl CI

C C (d)

CI
C moment is
molecule with highest dipole
the
22. Among
the following, (d) CCl4
(c) CHCl3
(a) CH Cl (b) CH2Cl2
angles is
correct order of bond > NO2
23. The (b) NO > NOZ
(a) NO > NO, > NO2 > NO2
(d) NO7> NO2
(c) NO2 > NO; > NO5
order is/are:
The correct solubility CO3 <K2 CO3
(I) Li2 CO3 Na2
<
24.
> BaCO3 > K2CO3
>
Rb, CO3
() CaCO > SrCO3 (IV) Na2 CO3
< Cs2 CO3
(11) K, CO3 <Rb2 CO3 TIV (d) 1, II, III
(b) I, IV
(c) III, II, ?
hybridization
(a) II, IV have the same
both the species
following pairs,
5. In which of the (11) I5. XefF
(I) SF4, XeF4 (V)CIog.PO
(1) ICi,Sicl4 (c) II, IV (d) I, I1, II
(b) II, III
following molecules
are
of the
(a) I, II central atom
to the
with respect
40 The geometry N (SiH3 )3 P pyramidal
N(SiH3 ): (CH, ); (b) planar, pyramidal,
planar
(a) planar, pyramidal, (d) pyramidal, planar, pyramidal
pyramidal
() pyramidal,
pyramidal, CCbond highest ?
length will be highest?
cases
following
27.. In
* which of the
In which F (c) F, CHF (d) CF3-CF3
FCH2-CH2
(a) CHCF
(a) CH CF3 (b) 0nds in
which both
have different hybridization but have same

28. Sclect pair of compo

molecular geometryy (c) BCl3, PCl3 (d) PCl3, NCI3
(b) ICI, BeC12
(a) BF3, BrF3
 have planar structures ?
29. Which of the following set of species
(a) I.CH. CIO, .Sil
(b) TIC1.Al2Cl6, TeCI
(d) 1, Clg XeF2, BrFa , XeF
(c) SC1,, N,Os, SF^. XeOF;
Which order are correct ?
30. BaSo,4
<

CasO4 SrsO4 <

() Thermal stability: BeSO, < MgSO,

BeO< MgO < CaO
(1) Basic nature : Zn0< KOH > RbOH > CsOH
LiOH > NaOH>
(l) Solubility in water:
KCI> RbCl> CsCI LiC
>
(V) Melting point: NaCl>
(b) (), (11) and (IV)
(a) (). (IV)
(d) All correct
(c) (II). (IU)
31. The boiling point of p-nitrophenol is higher than that of o-nitrophenol because
se
:
(a) p-nitrophenol has inter-molecular hydrogen bonding while o-nitrophenol h.
as
intrahydrogen bonding
(b) p-nitrophenol has intramolecular hydrogen bonding while 0-nitrophenol has
inter-molecular hydrogen bonding
(c)-NO, group at p-position behaves in a different way than that of o-position
(d) Hydrogen bonding exists in p-nitrophenol but no hydrogen bonding is present in
0-nitrophenol
32. Which one of the following arrangement of molecules is correct on the basis of their
dipole moments?
(a) BF > NH3 > NF3 (b) BF>NF; >NH3
(c) NH>BF > NF (d) NH3> NF > BF3
33. NO and N, O4 are two forms of nitrogen dioxide. One exists in gaseous state while
other in liquid state. The nature of NO, and N,O4 forms are:
(a) both are paramagnetic
(b) both are diamagnetic
(c) NO, is paramagnetic while N, 04 is
diamagnetic
(d) NO2 is diamagnetic while N204 is
paramagnetic
34. The formal charge of the O-atoms in the ion|:0=N=0, is

(a)-2 b)-1 c)0

35. The (d)+1
dipole moment of HBr is 2.6 xX 10cm and the
The percentage
interatomic spacing is 1.41 A.
of ionic character in HBr is
(a) 10.5 (b) 11.5 (c) 12.5
36. Which of the following halides has different bond (d) 13.5
(a) BCI (b) CCl4
lengths?
(c) BeCl2
37. Which has maximum covalent character? (d) PCl5
(a) NaCl (b) SiCl4 (c) AICI
38. In which solvent NaCl has maximum
solubility? (d) MgCl2
(a) H0 (b) C,HOH (c)
CH,COCH3 (d) CH5OC; Hs
Chem

among
the following has highest
boiling point?
Which
(b) He
19
(a)H (c) Ne
(d) Xe
Which ofthe following is correct?
(a) Thenumberof electrons present in the valence shell in SF is 12
rates of ioni compounds are
(b) The very slow
(c) According to VSEPR, SnCl2 is a linear molecule
correct order of ability to form ionic
compounds among Na ,
Mg" and
A is AlS* > Mg*> Nat
The structure of diborane (B,H6 ) contains:
(a) four 2C-2e bonds and two 3C-2e bonds
b)wo 2C-2e bonds and four 3C-2e bonds
(c) two 2C-2e bonds and two 3C-2e bonds
d) four 2C-2e bonds and four 3C-2e bonds
4Molecularshapes of SF4, CF4 and XeF4 are
(a) the same with 2, 0 and I lone pair of electrons
(b) the same with 1, 1 and 1 lone pair of
electrons
(c) different with 0, 1 and 2 lone
pair of electrons
(d) different with 1, 0 and 2 lone
43. Lattice energy of
pair of electrons
BeCO3 (), MgCO, (1I) and
CaC0, (III) is in order
(a)I<II < III| (b)I>II> II
ldentify the correct sequence of increasing(c)I<
44.
III<II (d) II<I <III|
number of t-bonds in the structures of the
following molecules:
0)HS206 (I1) H2 SO3 (III) H2S2Os
(a) I, II, III (b) II, III, I
45. (c)II, I, II (d) I, III, II
Sulphur reacts with chlorine in 1:2ratio and forms X.
compoundY. What is the hybridization state of Hydrolysis of Xgives a sulphur
(a) sp central anion atom in the of Y?
(b) sp (c) sp (d) sp d
.Which of the following have undistorted octahedral
structures?
1. SF6
2. PF6 3. SiF 4. XeF6
Select the correct answer using the codes given below
(a)2,3 and 4 (b) 1,3 and 4 (c) 1,2 and 3
(d) 1,2 and 4
47. The cor
correct order of C-Obond lengths in CIO
CIO2,CIO and Cl0 is :
(a)CIo< CIO, <CIO3 CIO04 < b) CIO CIOg <CIO, CIO
<
<

48.
C) Cio< CIO CIO, CIO0
1Og is
< < (d)CIO4=CIOG CIO, =CIO
=

(a) ionic compound (b) covalent compound

C) coordinate compound (d) double salt
Which of the
c h of the following molecule is theoretically not possible?
(a) SF4 (b) OF2 (c) OF
(d) O,F2
 section contains statements
this
of fth given in two columns which have to
ch
ach ques
question

ements (a, bb, c, d) in Column-I have to be matched with statements

Statements

m a t c h e d .

be in Column-II. The answers to these

questions have to be
p9,
T, 5)
:ctrated in the following example. If the correct matches are
appropriately
bubbledas. (a-q, r), (b-p,
s(c-r,s)and
and (d-g) then the correctly bubbled matrix will look like the following:

S
aP
b

1Matchthe Column-Iwith Column-II:

Column-II
Column-I

(p) Two axial bonds+ three lone pairs

(a) PCls
(q) Two axial + two equitorial bonds
(b) XeF2
r) Two axial + one equitorial bonds
)SF4 bonds
(s) Three equitorial + two axial
(d) CIF Column-II
Column-I with their shapesin
Match the molecular species in

Column-I
Column-
(p) CS2
(a) Linear shape
(q) XeF
(b) sp hybridisation
CH
(c) spd hybridisation (s) NCO
isostructural to
(d) CO is Column-l and their magr.etic and
molecular orbitals

species in
3 Match the molecular

properties in Column-Il: Columin-II

Column-I 2
Bond order
=

(p)
(q) Diamagznetic
(a) O2
Bond order
=
3
b) N2 ()
(c) H2 (s) Paramagnetic
(d) o
 ht Chetmsr
44. Match the Column-I (molecules)
answer
with Column-II (bond order
Chemist
nd selectt
Column-l Column-I1 ,OTte
(p) 3
(a) Li
(b) N (q) 1.5

(c) Be2 (r) 1.0

d) O (s) 0
(1) 2

5. Match the Column-l with Column-lI:

Column- Column-11I
(a) Ethane (p) 2sp carbons
b) Ethylene
(q) 6sp carbons
(c) Acetylene
(r) 2sp carbons
d) Benzene
(s) 2sp carbons
() 1 sp and 1sp carbons
tch the Column-I with
Column-II:
Column- Column-II
(a) NH,C
(p) Covalent bond
b) HNC
(g) lonic bond
(c) Liquid H,0
() Hydrogen bond
(d) CuSO4 5H,0
7
7.
(s) Co-ordinate bond
Match the Column-I with Column-II
Column-I
Column-II
(a) NH2
(p) V-shaped
(b) ICl4
(q) T-shaped
(c) XeOF
(r) Square planar
(d) (Sbfs
(6) Square pyramidal
8. Match the Column-I
with Column-I:
Column-I1
(a) 1Cl2
Column-II
(p) Angular
(b) ClF
(q) Pyramidal
(c) BrF
() Linear
(d) AICl4
(s) Square planar
(t) Tetrahedral
 Column-lI:
M a t c ht h eC o l u m n - j
with
ke
C o l u m n - I

Column-II
Column-

(p) 120
(a) NO (q) 109°

(b) NO, (r) 115°

() NO (s) 180
(d) NO
(t) 134
with Column-II:

Match the Column-I Column-II

Column-I

(p) Distorted octahedral

(a) XeFa (q) Pyramidal

(b) XeF t) Tetrahedral

(c) Xe03 (s) Square planar

(d) Xe04
Column-II:
Column-I with
11. Match the Column-II
Column-I (Shapes)
(Hybridization)
(p) Square planar
2
(a) dsp (g) Trigonal prism
b) dsp (r) Octahedral

() dsp 3 (s) Trigonal bipyramidal

d) sp'd
Column-ll:
Column-I with
2. Match the Column- (Shape)
Column-I (Molecule)
(P) Square planar
(q) Trigonal bipyramid
(a) (CH )3 B
() Tetrahedral
(b) NH4CI
(c) [ICIl (s) Trigonal

(d) PCl5 Column-II

with
Match the Column-I Column-II
I(C-C-C) bond anglel
Column-
(Compound)
(p) 108°

(q) 180°
(a) Propyne form)
(Chair
Cyclohexane (r) 120°
(6)
(c) Planar cyclopentane

(s) 109.5°

(d) Propene
14. Match the Column-I with Column-II:
Column-I (Species) Column-II (Structure)
(p) Trigonal planar
(a) CIF
(b) PF3 (q) T-shaped (planar)
(c) BF (r) Pyramidal
(s) Octahedral
(d) SF%
15. Match the Column-I with Column-l1:
Column-I Column-lI

(a) P4 (p) Crown

(b) Ss (q) Polymeric (Dimeric)
(c) AICl3 (r) Tetrahedral
(d) PCl5 (s) Linear
()Trigonalbipyramid