At STR

CHAPTER-2 ATOMIC STR
1Q:
b) a) The energy associated with the first orbit in the hydrogen atom is -2.17x10 -18 J atom -1 . What is the
energy associated with the fifth orbit?
Calculate the radius of Bohr’s fifth orbit for hydrogen atom
A: Energy associated with 5 th orbit
E 5 = 2.17x10 -18 J atom -1/(5)2
=-8.68 x 10 -20 J
Radius of Bohr’s with 5 th orbit
rn = .0529 n2 nm
rn =0.0529 x 5 2 nm= 1.3225 nm
2Q:
(a) State Hund’s rule of maximum multiplicity.
(b) Write the electronic configuration of Fe2+ion. (atomic no. of Ee =26)
(c) How many sub-shells are associated with n = 4?
(d) How many electrons in an atom may have the following quantum numbers?
n = 4 ; ms = -1/2
(e) Using s, p and d notations, describe the orbitals with following quantum numbers :
(a) n = 1, l = 0
(b) n = 4, l = 3
(f) Yellow light emitted from a sodium lamp has a wavelength of 580 nm. Calculate the frequency (v)
of yellow light.
(g) State Heisenberg uncertainty principle.
A: (a) According to this rule electron pairing in p, d and f orbitals cannot occur until each orbital of a given
subshell contains one electron each or is singly occupied.
b) Fe (Z = 26) : [Ar]18 3d64s2 Fe2+ion : [Ar]18 3d6

c) 4
d) For n = 4
Total number of electrons = 2n2 = 2 × 16 = 32
Half out of these will have ms = -1/2
∴ Total electrons with ms (-1/2) = 16
e) i )1s ii) 4f
3Q : Calculate the wave number for the longest wavelength transition in the Balmer series of atomic
hydrogen.
A:
4Q:
(a) How many electrons can be filled in all the orbitals with n+l =5?
(b) Which series of lines of the hydrogen spectrum lie in the visible region’?
(c) Write the electronic configuration of Ni3+. (At. No. of Ni = 28)
(d) How many radial and angular nodes are present in 2p orbital?
(e) What are the maximum number of emission lines when the excited electron of a H atom in n = 4
drops to the ground state ?
(f) The three electrons present in 2p subshell of nitrogen remain unpaired, why?
(g) Cr has configuration 3d5 4s1 and not 3d4 4s2, why?
A:
(a) A (n+l)=5 has 5s,4p and 3d orbitals with two, six and ten electrons respectively. Therefore, the total
number of electrons=18.
(b) Balmer Series
(c) [Ar]3d7
(d) Radial nodes = 0, Angular nodes = 1
(e) 6
(f) Acc. To Hund’s Maximum multiplicity rule
(a) 3d half-filled configuration is more stable
Q5: How many electrons in an atom may have the following quantum numbers?
(a) n = 4 ; ms = -1/2
(b) n = 3, l = 0.
A: (a) For n = 4
Total number of electrons = 2n2 = 2 × 16 = 32
Half out of these will have ms = —1/2
∴ Total electrons with ms (-1/2) = 16
(b) For n = 3
l= 0 ; ml = 0, ms +1/2, -1/2 (two e–)
6Q: (i)Calculate the energy required for the process : He+(g) → He2+(g) + e–
The ionisation energy’ for the H atom in the ground state is 2.18 × 10-18 J atom-1
(ii)Write electronic distribution in:- (a) Cr3+ (Z=24) (b) Zr (Z=40).
(iii) Explain O2 exist in nature but He2 does not exist using MOT.
(iv)If the velocity of the electron in Bohr’s first orbit is 2.19 x 10 6 m s-1, Calculate the de-Brogile
wavelength associated with it.
(v)The electronic configuration of valence shell of Cu is 3d 10 4s1 and not 3d94s2. How is this configuration
explained?
(vi) Show that the circumference of the Bohr orbit for the hydrogen atom is an integral multiple of the de
Broglie wavelength associated with the electron revolving around the orbit.
A: I)
For H atom (Z = 1), En =2.18 × 10-18 × (l)2 J atom-1 (given)

For He+ ion (Z = 2), En =2.18 × 10-18 × (2)2 = 8.72 × 10-18 J atom-1 (one electron species).
(ii) correct configuration
(iii) Calculation of bond order of oxygen =2
Calculation of bond order of helium=0
(iv)
(v)Configuration with completely filled and half-filled orbitals have extra stability. In 3d 104s1, d-orbitals are
completely filled and s-orbital is half- filled. Hence, it is a more stable configuration.
vi)
7Q: An Electron is jumped from First energy level to Second energy level, Calculate energy and
wavelength of Hydrogen spectrum ?
A: E n = -2.18 x10 -18( 1/n1 2 - 1/n2 2 ) Introducing correct values
Correct answer E n = 1.635 x10 -18 J Atom-1
E n = hv = h C/λ Introducing correct value ,
Correct Answer , λ= 1.2 nm

8 Q: (a)Write electronic configuration of Cu+ ion.
(b) Calculate the number of protons and neutrons in 80 35Br .
(c) Calculate the number of radial nodes for 2p orbital
(d) Why are half filled and fully filled orbitals extra stable?
(e) Write the relation between frequency and wavelength ?
(f) How many electrons in an atom may have the following quantum numbers? (i) n = 4, ms = – ½ (ii) n =
3, l = 0
(g) What is the maximum number of emission lines when the excited electron of a H atom in n = 6 drops
to the ground state?
A: (a)correct configuration
(b)Number of protons = 35 Number of neutrons = 80 – 35 = 45
(c) n-l-1 = 0
(d) due to more symmetry and chemical exchange energy
(e) c = ν λ
(f) 16 & 2
(g)15
9Q.: Calculate the wavelength, frequency and wave number of a light wave whose period is 2.0x10-10 S .
A: Time period : 2x 10-10 s
Frequency (v) = 1/Period = 1/2.0x 10-10 = 5x10 9 s-1 ,
Wavelength : c/v = 3x10 8 m/s /5X10 9 s -1 = 0.6 X 10 -1 = 6X 10 -2 m ; wave number = 1/ wavelength = 1/6X 10
-2
= 100/6 = 16.66 m-1
10Q: a) What is lowest value of n that allows g orbitals to exist?

(b) Give the number of electrons in the species H2+ , O2 + .
(c) An atomic orbital has n= 3. What are the possible values of l and mi?
(d) List the quantum numbers ( ml and l )of electrons for 2p orbital.
(e) Which of the following orbitals are possible?
1p, 2s, 3f
(f) Define Afbau Principle
(g) State Pauli's Exclusion Principle.
A: ( a) n= 5
(b) H2+ has 1 electron , O2+ ( 15 electron )
(c) n = 3 ,
for l = 0 , m = 0 ;
for l= 1, m = -1, 0, +1
for l = 2, m = -2 , -1 , 0 , +1 , +2
(d) l= 2 , ml = -1, 0 , +1
(e) For any value of n, l varies from 0 to (n-1). Therefore, 1p is not possible, 2s is possible, 3f is not possible
(f) Afbau's Principal: Electrons are filled in the orbitals in increasing order of energies in ground state.
(g) Pauli's Exclusion Principle states that no two electrons in an atom can have same set of four quantum
numbers.

At STR

Uploaded by

Copyright:

Available Formats

At STR

Uploaded by

Document Information

Original Description:

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

At STR

Uploaded by

Copyright:

Available Formats

CHAPTER-2 ATOMIC STR

A: Energy associated with 5 th orbit

E 5 = 2.17x10 -18 J atom -1/(5)2

Radius of Bohr’s with 5 th orbit

rn =0.0529 x 5 2 nm= 1.3225 nm

b) Fe (Z = 26) : [Ar]18 3d64s2 Fe2+ion : [Ar]18 3d6

(ii)Write electronic distribution in:- (a) Cr3+ (Z=24) (b) Zr (Z=40).

For H atom (Z = 1), En =2.18 × 10-18 × (l)2 J atom-1 (given)

(iii) Calculation of bond order of oxygen =2

Calculation of bond order of helium=0

Correct answer E n = 1.635 x10 -18 J Atom-1

E n = hv = h C/λ Introducing correct value ,

Correct Answer , λ= 1.2 nm

(b)Number of protons = 35 Number of neutrons = 80 – 35 = 45

(d) due to more symmetry and chemical exchange energy

10Q: a) What is lowest value of n that allows g orbitals to exist?

You might also like