Practice Test-10 Prayas JEE (2024 31/12/2023

CHEMISTRY

Single Correct Type Questions 5. Find the incorrect statement

1. Hg is not considered as a transition element but (A) The IE of d-block element is greater than s-
Au is considered as transition element, which is block and lesser than p-block elements
placed just before Hg is periodic table since (B) Down the group, stability of higher oxidation
(A) Au is placed in 11th group prior to Hg state increases in transition elements
(B) It has one electron in valence shell ‘6s’ (C) First IE of d-block elements varies in the
subshell group as 4d > 3d > 5d
(C) In Au+ O.S. it has empty 6s subshell (D) None of these
(D) In Au3+, it has eight electrons in 5d subshell
6. Statement I: HNO3 is stronger acid than NHO2
Statement II: In HNO3 there are two nitrogen to
oxygen bonds where as in HNO2 there is only one.
2. In the light of the above statements, choose the
most appropriate answer from the options given
X, Y and Z are respectively below:
(A) 1, 2, 3 (A) Both statement I and statement II are
(B) 1, 5, 3 incorrect.
(B) Statement I is incorrect but statement II is
(C) 1, 3, 5
correct.
(D) 5, 3, 1
(C) Statement I is correct but statement II is
incorrect.
3. The product formed are incorrect, in which of the
(D) Both statement I and statement II are correct.
following reaction?
(A) (NH 4 )2 Cr2 O7 

 N 2  4H 2 O  Cr2 O3 7. Match the items of column I and Column II and
mark the correct option
(B) Ba(N 3 )2 

 Ba  3N 2
Column I Column II
(C) 3Mg  N 2   Mg 3 N 2 A. It may show partial P. XeF2

hydrolysis
(D) NH 4 Cl  NaNO 2 

 NaCl  NH 3  NO 2 B. It Shows disproportionation Q. XeF6
reaction on hydrolycis
C. Oxidation state of Xe changes R. XeF4
4. Given below are two statements: one is labelled as
during hydrolysis
Assertion A and the other is labelled as Reason R. D. It does not form clathrate S. Ne
Assertion A: Fluorine forms one oxoacid. compounds
Reason R: Fluorine has smallest size amongst all A B C D
halogens and is highly electronegative. (A) P S P, Q R
In the light of the above statements, choose the (B) P Q R S
most appropriate answer from the options given (C) Q P P, R S
below: (D) P R Q S
(A) Both A and R are correct and R is the correct
explanation of A. 8. In 3d transition series, if nuclear charge increases,
the screening effect
(B) Both A and R are correct but R is not the
(A) Increase
correct explanation of A. (B) Decrease
(C) A is correct but R is not correct. (C) First decreases and then increases
(D) A is not correct but R is correct. (D) First increases and then decreases
9. NH3  O 2 
Pt  Rh
 P  H 2O 15. The correct order is

(A) HF < HCl < HBr < HI : Acidic strength
P + O2  Q (B) HF > HCl < HBr > HI : Thermal stability
Q + H2O  R (C) HF > HCl > HBr > HI : Boiling point
P, Q and R are: (D) HF > HCl > HBr > HI : Bond dissociation
(A) N2O, NO2 and HNO3 enthalphy
(B) NO, NO2 and HNO3
(C) NO2, NO and HNO3 16. Incorrect statement regarding following reaction
(D) N2O, NO and HNO3 is

'X' + HCl
10. Arrange the following ions in order of their
magnetic moment PCl5 + Limited H2O
(i) V4+ (ii) Mn4+ 'Y' + HCl
(iii) Fe3+
(iv) Ni2+ (A) ‘X’ is tribasic acid
(Atomic number of V = 23, Mn = 25, Fe = 26, Ni (B) ‘Y’ is an oxyhalide of phosphorus
(C) ‘X’ is non-oxidizing acid
= 28)
(D) SiC is insoluble in X
(A) ii > iii > i > iv (B) iii > ii > iv > i
(C) i > iv > iii > ii (D) iv > iii > i > ii
17. The general electronic configuration
[Rn] 5f 1 – 14 6d 0 –1 7s2 is of the
(A) Lanthanoids (B) Actinoids
11. Phosphine is not obtained by the reaction
(C) s-block element (D) d-block element
(A) White P is heated with NaOH
(B) Red P is heated with NaOH
18. Which of the following statement is correct
(C) Ca3P2 reacts with water
regarding halogens?
(D) AP reacts with water (A) Density of Halogens F > Cl > Br > I
(B) Oxidizing power of halogen F2 > Cl2 > Br2 >
12. The colour of the transition metal ions is due to I2
I. d-d transition (C) Electron affinity of fluorine is highest
II. Charge transfer (D) All halogens show oxidation states from –1
III. Change in Geometry to +7.
(A) I only (B) I and II
(C) II and III (D) I and III 19. Which of the following is not correct about conc.
H2SO4?
13. The correct order of (O – O) bond length in O2, (A) Reducing agent
(B) Dehydrating agent
H2O2 and O3 is:
(C) Sulphonating agent
(A) O2 > H2O2 > O3
(D) Oxidising agent
(B) O3 > H2O2 O2
(C) O3 > O2 > H2O2
20. Which is called chromic anhydrided?
(D) H2O2 > O3 > O2
(A) CrO (B) Cr2O3
(C) CrO3 (D) CrO2
14. Lanthanoid contraction is caused due to
(A) The same effective nuclear charge from Ce to
Integer Type Questions
Lu
(B) The imperfect shielding on outer electrons by 21. The disproportionation of MnO 24 in acidic
4f electrons from the nuclear charge medium resulted in the formation of two
(C) The appreciable shielding on outer electrons maganese compounds A and B. If the oxidation
by 4f electrons from the nuclear charge state of Mn in B is smaller than that of A, then
(D) The appreciable shielding on outer electrons the spin-only magnetic moment () value of B in
by 5d electrons from the nuclear charge. BM is _______ (Nearest integer)
22. Consider the following statements about the 27. The number of statements correct from the
reaction between copper metal and dil. HNO3 following cor copper (at. no. 29) is/are ____.
(I) In this reaction NO gas will be released (A) Cu(II) complexes are always paramagnetic.
(II) Cu metal is oxidized to Cu (NO3)2 (B) Cu(I) complexes are generally colourless
(III) NO is paramagnetic and has one unpaired (C) Cu(I) is easily oxidised
electron in antibonding molecular orbitals
(IV) In this reaction N2O gas will be released. 28. The number of molecules of water needed to
The number of correct statement(s) is _______. convert one molecule of P4 O10 into
orthophosphoric acid is _____.
23. The ratio of sigma and  bonds present in
pyrophosphoric acid is ______.
29. Consider the following sulphur based oxoacids.
H 2SO3 , H 2SO 4 , H 2S2O8 and H 2S2 O7
24. Total number of moles of P – H bond(s) in Amongst these oxoacids, the number of those
product(s) when one mole of white phosphorus with peroxo (O – O) bond is _____.
completely reacts with KOH solution is _____.
30. The oxidation state of chromium in the final
25. The number of terminal oxygen atoms present in
the product B obtained from the following product formed by the reaction between KI and
reaction is ______. acidified K2Cr2O7 solution is ______.
FeCr2O4  Na 2CO3  O2 
 A  Fe2O3  CO2
A  H  
 B  H 2O  Na 

26. Number of compound(s) in which oxygen is in –

1 oxidation state is ______.
(i) Caro’s acid (ii) Marshall’s acid
(iii) BaO2 (iv) K2O

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