Chemistry

DJ Sindh Govt.
Science College, Karachi

Preliminary Examination 2024
Chemistry – I
Time allowed: 03 hours Maximum Marks: 85
SECTION ‘A’ (MULTIPLE CHOICE QUESTIONS) – (M.C.Qs.)

Time allowed: 20 minutes (Marks : 17)
NOTE: (i). This section consists of 17 part questions and all are to be answered. Each question carries one
mark. (ii). The correct answer bubble must be filled on OMR sheet (I) Ⓐ Ⓑ Ⓒ Ⓓ pasted in answer
script. (iii). Use only blue / black ball point pen or pointer on OMR sheet.
(iv). Avoid using pencil / White-o pen on OMR sheet.
(v). All notations are used in their usual meanings. The use of Scientific Calculator is allowed.
Q. 1. Choose the correct answer for each from the given options.
1. The reaction PCl3 + Cl 2 ⇌ PCl5 will shift in backward direction if:

* [PCl3] is increased * [Cl2] is increased * [PCl5] is increased * [PCl5 ]is decreased
2. The unit of rate constant “K” for the zero order reaction is:
* sec -1 * dm3/mol.sec * mol/dm3.sec * mol/dm3
3. If a = b = c, α≠β≠ r ≠900 , then the cell will be

*Monoclinic * Triclinic * Tetragonal * Orthorhombic
4. This is an isoelectronic pair
*Li+ , H+ * K+ , Cl-- * K+ ,X * Na+ , Cl--
5. The n + l value of 5d orbital is
*4 *5 *6 *7
6. In pure water universal indicator aquires this colour
*Red *Green * Blue * Pink
7. The dipole moment of Br2 molecule is
* 0.00 D * 1.03 D * 1.85 D * 1.67 D
8. It has maximum bond angle?
*H2 S * H2O * NH3 * CO2
9. This is an intensive property
*Mole *Volume * Mass * Density
10. In the equation 4NH3 + 5O2  4NO + 6H2O:


* Kp = Kc * Kp 
Kc * Kp > Kc * Kp < Kc
11. If initial moles of reactants are ‘b' and it forms ‘x' moles of product at equilibrium state, the moles
of reactants left at this state will be:
*b+x *b-x *x-b *x
12. An aqueous solution of Sodium carbonate is
*Basic * Acidic * Neutral * Amphoteric
13. If 200 cm3 of 1M solution is diluted upto 2000 cm3 ,its molarity would be
* 10 M * 0.2M * 0.1M * 1.0M
14. Nitrogen has the electronic configuration 1s2, 2s2, 2px1, 2py1 , 2pz1 and not 1s2 , 2s2 , 2px2, 2py1, 2pz0, this
is determined by:
* Aufbau Principle * Pauli's Rule * Hund's Rule * n + l rule
15. A colloidal solution of liquid into liquid is known as:
* Gel * Foam * Solution * Emulsion
16. The outer body of dry cell is made up of
* Copper * Zinc * Lead * Iron
17. The density of methane gas at 400k and 3.5 atmosphere is :

* 2.7gm/dm3 * 0.7gm/dm3 *1.7gm/dm3 *none of these
DJ Sindh Govt. Science College, Karachi
Preliminary Examination 2024
Chemistry – I
Time allowed: 2 hour 40 minutes Maximum Marks: 68
NOTE: Attempt any nine-part questions from this section. All questions carry equal marks. The use
of scientific calculator is allowed. All notations are used in their usual meanings. Draw diagram where
necessary.
SECTION ‘B’ (SHORT-ANSWER QUESTIONS) (Max. Marks : 36)
Q.2. (i) Define the following.
*Molar volume * Bond Order * Percentage yield * Anisotropy
(ii) Ammonia gas can be generated as follows

2NH4Cl + Ca(OH)2 2NH3 + H2O + CaCl2
If 100 gms. Of both solids are heated. Calculate the actual amount of ammonia and identify the
limiting reactant.
(iii)State Charles’s law of ideal gas. Plot a graph for one mole of a gas to prove that gas become
liquefied earlier than – 273.16 oC. Also Calculate the density of O2 gas at STP.
(iv)Define Enthalpy of a thermodynamics system. Show that the change in enthalpy at constant
pressure is given by the expression qp=∆H.
(v) Give scientific reasons for any four of the following.
*s---s sigma bond is relatively weaker than p—p.
* Boiling point of water is lower at higher altitude.
* Water wet the glass surface but mercury does not.
* I.P decreases down ward in a group of Periodic Table.
* Ice has a sharp melting point where as glass melts over a range of temperature.
(vi) Determine the order of reaction with the help of following data for the reaction
NO + O2 NO2
Exp. NO Initial [NO ] Initial [O2] Initial Rate (Ms-1 )

1 0.10 M 0.10M 8 x 10 -4
2 0.10 M 0.20M 16 x10 -4
3 0.20M 0.10M 16 x 10 -4
(vii) Enumerate the rules of assigning oxidation number of elements.

(viii) State Roullts law and derive its mathematical expression.
(ix) State Le Chatelier principle also describe its application.
(x) Explain Buffer solution with an example and write its applications.
(xi) Calculate the heat of formation CH3OH
i) C + 2H2 + ½ O2 CH3OH  HF = ?
ii) C + O2 CO2  Hf = - 394 kj/mol
iii) H2 + ½ O2 H2O  Hf = - 286 kj/mol
iv) CH3OH + 3/2O2 CO2 + 2H2O  Hf = - 726 kj/mol
(xii) At constant pressure of 101300 N/m2 when 4000 j of heat supplied to a system then 500 j of internal
energy raised. Calculate the change in volume of the system.
(xiii) Define Hydration and hydrolysis. Why is the aqueous solution of NH4Cl is acidic while that of
Na2CO3 is basic?
(xiv) The solubility of calcium oxalate (CaC2O4) is 0.0016 g/dm3 at 25oC.
Find solubility product of calcium oxalate: CaC2O4 Ca2+ + C2 O2
4
(xv) In a reaction H2 + I2 2HI when equilibrium was attained, the concentration was
3
[H2] = [I2] = [HI] = 4 mol/dm .
Calculate the equilibrium constant Kc, and the initial concentration of H2 and I2.
SECTION ‘C’ (DETAILED-ANSWER QUESTIONS) (Max. Marks : 32)
NOTE: Attempt any Two question from this section. Draw diagrams, where necessary. The use of scientific
calculator is allowed. All notations are used in their usual meanings.
Q.3. a) Write the main postulates of Bohr atomic theory and drive an expression for the energy and
frequency of electron.
b) Define rate of reaction . also describe its factors and explain any two of them.
Q4. a) What is orbital hybridization. Write its types . Identify the hybridization in H2O , NH3 and C2H2
b) Define Electrode potential. What is S.H.E.? How is the electrode potential of copper is determined?
Q.5 a) Balance the following equations by ion electron method.

(i) Cr2 O2 + I Cr+3 + IO1
+ H2O (Acidic medium)
7 2 3
(ii) Cr(OH)3 + SO2 Cr O2 + SO2 (Basic)

4 4 3
b) What is meant by Born Haber Cycle? Determine the lattice energy for RbCl writing all
thermochemical equations stepwise using following data.
Sublimation energy of Rb (s) = 82 KJ / mol
Ionisation energy of Rb (g) = 403 KJ / mol
Dissociation energy of Cl2 (g) = 242 KJ / mol
Electron affinity of Cl2 (g) = - 348.5 KJ / mol
Lattice energy of RbCl (s) = - 689 KJ / mol

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DJ Sindh Govt.

Science College, Karachi

SECTION ‘A’ (MULTIPLE CHOICE QUESTIONS) – (M.C.Qs.)

1. The reaction PCl3 + Cl 2 ⇌ PCl5 will shift in backward direction if:

3. If a = b = c, α≠β≠ r ≠900 , then the cell will be

10. In the equation 4NH3 + 5O2  4NO + 6H2O:

* Aufbau Principle * Pauli's Rule * Hund's Rule * n + l rule

15. A colloidal solution of liquid into liquid is known as:

* Gel * Foam * Solution * Emulsion

16. The outer body of dry cell is made up of

* Copper * Zinc * Lead * Iron

17. The density of methane gas at 400k and 3.5 atmosphere is :

SECTION ‘B’ (SHORT-ANSWER QUESTIONS) (Max. Marks : 36)

Q.2. (i) Define the following.

*Molar volume * Bond Order * Percentage yield * Anisotropy

(ii) Ammonia gas can be generated as follows

* Boiling point of water is lower at higher altitude.

* Water wet the glass surface but mercury does not.

* I.P decreases down ward in a group of Periodic Table.

Exp. NO Initial [NO ] Initial [O2] Initial Rate (Ms-1 )

(vii) Enumerate the rules of assigning oxidation number of elements.

SECTION ‘C’ (DETAILED-ANSWER QUESTIONS) (Max. Marks : 32)

Q.5 a) Balance the following equations by ion electron method.

(ii) Cr(OH)3 + SO2 Cr O2 + SO2 (Basic)

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Molar volume Bond Order * Percentage yield * Anisotropy