CBSE

Class 11 chemistry
Sample Paper- 05

Time Allowed: 3Hrs M.M. : 70

General Instructions :

i. All questions are compulsory.

ii. Q. No. 1 to 5 are very short answer type questions and carry one mark each.
iii. Q. No. 6 to 10 are very short answer type questions and carry two marks each.
iv. Q. No. 11 to 22 are short answer type questions and carry three marks each.
v. Q. No. 23 is value based questions carries four marks.
vi. Q. No. 24 to 26 are long answer type questions and carry five marks each.
vii. Use log tables, if necessary, use of calculator is not allowed.

1. Define limiting reagent

2. Write the general electronic configuration of d-block elements?
3. Write vander Waal's equation for n moles of a real gas.
4. What is the state of hybridisation of each carbon atom in C6H6?

5. Predict the sign of the entropy change for the following:

6.
i. Define Pauli’s exclusion principle.
ii. Write electronic configuration of an atom having 2K, 8L, 5M electrons.

Or

The mass of an electron is 9.1 x 10-31 kg. If its kinetic energy is 3.0 x 10-25 J. Calculate

its wavelength. (Given h = 6.626 x 10-34 Js)

7. The concentration of hydrogen ion in a sample of soft dark is 3.8 x 10-3 M. What is its pH
? (log 3.8 = 0.58)
8. What happens when (write equation only):
i. Beryllium carbide reacts with water.
ii. Sodium sulphate solution is added to an aqueous solution of barium nitrate.

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 9. Propanal and Pentan-3-one are the ozonolysis product of an alkene. What is the
structural formula of the alkene?
10. Write reactions to justify amphoteric nature of aluminium.
11.
a. Write the IUPAC name of the following:

i.

ii.

b. Which isomerism is shown by following pair of compounds:

CH3COOH and HCOOCH3

12. Account for the following:

a. An anion is always bigger than its present atom.
b. Chlorine (Cl) has move negative electron gain enthalpy the fluorine (F).
c. Noble gases have positive electron gain enthalpy.
13. Give the shapes of following covalent molecules using VSEPR theory:
i. PCI5

ii. BrF3

iii. H2O

14. A sample of drinking water was found to be severely contaminated with chloroform
CHCl3, supposed to be carcinogen. The level on contamination was 15 ppm (by mass).

i. Express this in percent by mass.

ii. Determine the molality of chloroform in the water sample.
15.
a. State Hess's law.
b. Use standard enthalpies of formation, calculate the value of for the reaction.

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16.
a. The molecular orbital theory to predict why the BE molecule does not exist.
b. Compare the stability of and O2 on the basis of M.O. theory.

17.
a. Calculate the total pressure in a mixture of 8g of oxygen and 4g of hydrogen confined

in a vessel of 1 dm3 at 27°C.

Given R = 0.083 bar dm3 K-1 mol-1

b. Criticial temperature of CO2 and CH4 are 31.1°C and - 81.9°C respectively. Which of

there has stronger intermolecular forces and why?

Or

a. What would be the S.I. units of a quantity PV2T2/n ?

b. Calculate the temperature of 4.0 moles of a gas occupying 5 dm3 at 3.32 bar (R= 0.083

bar dm3 K-1 mol-1)

18.
a. What is the oxidation no. of Cr. in ?
b. Balance the equation: (Acidic medium)
19. Complete the following chemical reactions.
a.
b.
c.
20. Give reason for the following:
a. PbCl4 is a powerful oxidising agent.

b. Graphite acts as a good lubricant.

c. Boron halides don't dimerise like BH3

21.
a. Draw the structure of (i) BeCl2 (vapour) and (ii) BeCl2 solid

b. Complete the equation:

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22. Arrange the following in order of property mentioned against each:
a.

(increasing order of stability)

b. HCOOH, CH3COOH, CH3CH2COOH (Increasing acidic strength)

c.

Value Based Questions

23. Environmental pollution is causing a serious threat on the earth. Due to combustion of
fossil fuels, a number of poisonous and harmful gases enter into the atmosphere. Every
country has made strict laws for industries and individual citizens to keeps pollution
under control.
Now answer the following questions:
a. Why is it advised not to sleep with burning coke angithi in a closed room on winter
nights?
b. What does the combustion of motor fuels cause pollution of the atmosphere?
c. Name one natural source and one human activity by which SO2, enters into

atmosphere?
24.
a. Explain the following with example:
i. Common ion effect
ii. Buffer solution.

b. At a certain temperature and total pressure of 105 Pa, iodine vapours contains 40% by
volume of I atoms.

Calculate Kp for the equilibrium.

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 Or

a. Define Le- Chatelier's principle.

b. Define pH.
c. Equilibrium constant for the reason is 4.0. What will be the equilibrium constant for
the reverse reaction.

d. Calculate the pH of 10-8 M HCl solution.

25.
a. Define Heisenberg's uncertainty principle. Write its mathematical expression.
b. Calculate the uncertainty in the velocity of a cricket ball on mass 150 g. If the

uncertainty in its position is of the order of 1 .

(h = 6.6 x 10-34 Kg m2s-1)

Or

a. Which of the following orbitals are not possible

1p, 2s, 2p, 3S
b. Which of the following sets of quantum number are not possible? Give reasons.
i. n = 0, l = 0, ml = 0, ms = +1/2
ii. n = 1, l = 0, ml = 0, ms = -1/2
c. Electrons are emitted with zero velocity from a metal surface when it is expressed to

radiation of wavelength . Calculate threshold frequency and work

function of the metal.
26.
a. Define the following with example:
i. Wurtz reaction
ii. Markovnikoff’s Rule.
b. Give the main product of the region:

i.

ii.

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 iii.

Or

a. How can you convert the following:

i. Propan-1-ol to propan-2-ol
ii. Ethyl chloride to n-Butane
b. Complete the following reactions:

i.

ii.

iii.

Answers

1. The reactant which is completely consumed during the reaction is called limiting reagent.

2. (n - 1)d1-10 ns1-2.

3.

4. sp2 hybridisation.
5. -ve, as randomners decrease.
6.

a. No two e- in an atom can have same set of all the four quantum numbers.

b. Total e- = 15

E.C. = 1s2 2s2 2p6 3s2 3p3

Or

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 pH = -log [H+]

= -log 3.8 = 3 = 3 - 0.58

=2.42
i. Be2C + 4H2O 2Be(OH)2 + CH4

ii. Na2SO4 + Ba(NO3)2 BaSO4 + 2NaNO3

7.
8.
9.

10.

= -12977.57 + 13141.8
, Process is non-spontaneous
11.
a.
i. 4-Nitro benzoi acid
ii. 3-Methyl hexa-1, 5-diene
b. Functional isomerism
12.

a. Because nuclear charge decrease/e- increase.

b. Because of bigger size of chlorine/less e- - e- repulsion as compared to fluorine.

c. Because they have fully filled orbitals.
13.
a. Trigonal bipyramidal.
b. Bent T-shape
c. Bent/V-shape

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14.

a. 15 ppm means 15 parts in million (106) parts.a

b. Molar mass of CHCl3 = 119.5 g/mol

100 g of sample contain chloroform =

1000 g of sample contain =
Molality of chloroform =
Molality
15.
a. 2Al(s) + 3H2SO4 (aq) Al2(SO4)3 (aq) + 3H2(g)

b. 2Al(s) + 2NaOH (aq) + 6H2O(l) 2Na+[Al(OH)4]- (aq) + 3H2(g) Sodium tetrahydroxo

aluminate (III)
16.
a. Be:
Bond order =
As bond order of Be2 is zero and does not exist.

b.

Greater the bond order, move will be stability.

17.
a.

Total no of moles = 2+ 0.25 = 2.25 mol

V = 1 dm3, T = 300 K, R = 0.083 bar dm3 K-1 mol-1

PV = nRT

P = 56.025 bar

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 b. CO2 has stronger intermolecular forces because it can be liquiefied at temperature

upto but CH4 can be liquefied only upto .

18.
a. x = 6
b.
19.
a. PsB + 4H2O2 PbSO4 + 4H2O

b.
c. Ca3N2 + 6H2O Ca(OH)2 + 2NH3

20.

a. Because Pb+4 is reduced to more stable Pb+2.

b. Because of its soft and slippery nature.
c. Boron due its small size cannot four large size chlorine atoms around it and hence
exists as monomer.
21.
a.

i.

ii.

b.

22.

a.

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 b.

c.

23.
a. On burning coke, a lot of CO is produced which causes anoxia.
b. On burning motal-fuels, toxic oxides of nitrogen is formed which affect respiratory
system.
c. Due to volcanic eruption and through combustion of sulphur containing fuels.
d. Concern for environment
24.
a.
i. It is the shift in an ionic equilibrium caused by the addition of a solute that
provides caused by the addition of a solute that provides an ion that takes part in
the equilibrium.
ii. The solution which resist the change in pH on dilution/addition of acid or alkali.
b. Partial pressure of I atom (PI)

Partial pressure of I2 atom (PI2)

i. Correct statement.
ii. negative logarithm of hydrogen ion concentration.
iii.

iv. 10-8 M HCl

[H+] = 10-8 + 10-7

[ [H+] conc. due to water = 10-7]

Or [H+] = 11 x 10-8 PH = - log[11 x 10-8]

= 8 - 1.02 = 6.98
25.
a. It is impossible to measure simultaneously both the position and velocity of a
microscopic particle with accuracy or certainty.

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 Mathematically expression
b. Mass of ball m = 150 g

= 150 x 10-3 kg = 0.150 kg

Uncertainty in position

= 3.52 x 10-24 m s-1.

Or
a. 1p as n = l, not possible.
b. (i) n = 0, l = 0, ml = 0, ms = +1/2 not possible because n cannot be zero.
c. Energy of photon

= 2.93 x 10-19 J
Energy of photon = K.E. + W0 = 0 + W0 = W0

W0 = 2.93 x 10-19 J

Threshold frequency

26.
a.
i. It involves the chemical reaction between alkylhalides and metallic sodium in
presence of dry ether and from alkanes.

ii. It states that more electronegative part of the addendum adds to that carbon of
double bond which contains lesser no. of H-atoms.

b.
i.

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 Or
a.
i. C{H_3}C{H_2}C{H_2}OH\xrightarrow[\Delta ]{{alc.KOH}}C{H_3}CH = C{H_2

ii.
b.
i. CH3CH2CH2BR

ii. CH3 - CH3

iii. CH3-CH=CH-CH3

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