E3sconf Iccsre2021 01038
E3sconf Iccsre2021 01038
E3sconf Iccsre2021 01038
1051/e3sconf/202122901038
ICCSRE’2020
Abstract. The energy transition to prevent global warming is the main concern. Climatic change effects
show a catastrophic view to the word through the increase of temperature which promotes fire like in Siberia
or ices melts by trigging the extinction of polar bears in the future, also adding the flooding in Norway.
Thus, it is important to trait sectors the most polluters such as transport, industries, and residential tertiary
sectors. In the perspective to reduce their dependence on fossil fuels. However, the frequently used sources
of energy are unstable. They require an appropriate clean storage system and the technology of energy
storage relevant as green hydrogen. In this article, we focus first on the creation complete of the model of
production chain for green hydrogen by the fuel cell PEM. Then, the application of the model in one
technical-economic study for energetic consumption HVAC for a hotel. We will consider the usage of
thermic power resulting from the chemical reaction of the system, those powers allow us to demonstrate that
the fuel cell PEM presents the brilliant performance compare to electrolysis. Through that thermic power
from the fuel cells, we will expose the fact it is possible to avoid the utilization of natural gas and electricity
structure for domestic hot water. This technical-economic study show that green hydrogen technology can
be worthwhile for the short or middle term for the hotel industry.
*mpierrelaince12@gmail.com
© The Authors, published by EDP Sciences. This is an open access article distributed under the terms of the Creative Commons Attribution License 4.0
(http://creativecommons.org/licenses/by/4.0/).
E3S Web of Conferences 229, 01038 (2021) https://doi.org/10.1051/e3sconf/202122901038
ICCSRE’2020
to simulate in real time the entire production chain, representing the power absorbed and the power
acting on all the possible parameters, thus allowing a producing, (11) rate hydrogen.
global visibility on the system, but also, to apply this The thermal power released by the reaction is
modeling to a technical-economic study in the
residential-tertiary sector, in order to show the 𝑃𝑡ℎ = ±𝑁𝑠 × (𝑉 − 𝑈𝑡𝑚 ) × 𝐼 (12)
feasibility of the return on investment of the
implementation of this technology when using these (𝑁𝑠) number of cells in series; (𝑈𝑡𝑚 ) thermoneutral
heat losses. voltage of a cell = 1.48V.
The document is organized as follows: In paragraph, the
mathematical modeling of the electrolysis, the storage 2.2 Hydrogen storage tank
tank, followed by the modeling of the fuel cell. In
section, we present a case study of re-electrification by The storage tank intended to contain hydrogen at a
PEM cell followed by all the results. A conclusion and certain pressure in liquid or gaseous form can be
a list of references complete the paper. modeled according to [16]. Note that hydrogen storage
is done according to three main methods, high pressure
for stable systems 120 bars, for 250-700 bars mobile
2 Mathematical modelling re- systems, in liquid form (-259 ° C), then in hybrid metal
electrification by PEM fuel cell form.
𝑃 𝑉𝑚 𝑁𝐻2 𝑅 𝑇𝑡
2.1 Modeling of water electrolysis 𝑃𝑡 − 𝑃𝑡𝑖 = 𝑅𝑇 𝑀𝐻2𝑉𝑡
(13)
𝑛
𝑉(𝑇, 𝑃) = 𝑛𝑝 𝐼. 𝑅𝑖 (𝑇, 𝑃) + 𝑛𝑠 𝐸𝑟𝑒𝑣 (𝑇, 𝑃) (2) Description values
𝑝
𝑇0 20°C
(1) and (2) the voltage and current coming from the 𝑃0 1 atm
production of solar panels. 𝑘 0.0395 V/A
𝑅(273+𝑇) 𝑃
𝑅 0.082 l.atm-1.K-1.mol-1
𝐸𝑟𝑒𝑣 (𝑇, 𝑃) = 𝐸𝑟𝑒𝑣0 (𝑇, 𝑃) + ln ( ) (3)
2𝐹 𝑃0 𝐹 96487 C.mol-1
𝑃 𝑑𝑅𝑡 -3.812*10^-3 Ω.C-1
𝑅𝑖 (𝑇, 𝑃) = 𝑅𝑖0 + 𝑘𝑙𝑛 (𝑃 ) + 𝑑𝑅𝑡 (𝑇 + 𝑇0 ) (4)
0 𝑅𝑖0 0.326 Ω
𝑃𝐻2 = 𝑉𝑖 . 𝐼 (10)
𝐼 𝑁𝑠
𝑁𝐻2 = (11)
2𝐹
2
E3S Web of Conferences 229, 01038 (2021) https://doi.org/10.1051/e3sconf/202122901038
ICCSRE’2020
𝑃
𝑎𝑛
1 ≤ 𝜑𝑎𝑛 = 𝑃𝑣𝑎𝑝 ≤3 (25)
𝐻2,𝑠𝑎𝑡
𝑣𝑎𝑝
𝜑𝑎𝑛 : relative humidity, 𝑃𝐻2,𝑠𝑎𝑡 : saturation pressure
vapor, A: area of membrane electrode assembly (cm²).
𝐼
𝑁̇𝑂2,𝑖 = 𝑆𝑂2 (27)
4𝐹
∆𝑆 0
0
𝐸𝑟𝑒𝑣 = 𝐸𝑟𝑒𝑣 + (𝑇 − 𝑇𝑟𝑒𝑓 ) × (28)
Fig. 1. Fuel cell PEM system. 𝑛𝐹
0
𝐸𝑠𝑡𝑎𝑐𝑘 = 𝐸𝑂𝑐 − 𝐸𝑎𝑐𝑡 − 𝐸𝑐𝑜𝑚 − 𝐸𝑜ℎ𝑚 (14) The theoretical minimum 𝐸𝑟𝑒𝑣 = 1.229 𝑉.
Cell voltage losses are composed of activation over- The speed of an electrochemical reaction is limited by
potential (Eact) due to the electro-catalyst layers, the energetic acti-barrier:
concentration over-potential (Econ) due to the
limitations of mass transfer and ohmic overvoltage
(Eohm). 𝑎𝑛
𝐸𝑎𝑐𝑡 = 𝐸𝑎𝑐𝑡 𝑐𝑎𝑡
− 𝐸𝑎𝑐𝑡 (30)
𝑅𝑇
𝐸𝑂𝑐 = 𝐸𝑟𝑒𝑣 + 2𝐹 𝑙𝑛(𝑝ℎ2 √𝑝𝑜2 ) (15)
𝑅𝑇 𝑖 𝑅𝑇 𝑖
𝐸𝑎𝑐𝑡 = ∝ 𝑙𝑛 (𝑖 𝑎𝑛 ) + ∝ 𝑙𝑛 (𝑖 𝑐𝑎𝑡) (31)
𝑎𝑛 𝐹 0 𝑐𝑎𝑡 𝐹 0
𝑛𝐻2
𝑎𝑛
𝐸𝑐𝑜𝑚 = 𝐸𝑐𝑜𝑚 𝑐𝑎𝑡
− 𝐸𝑐𝑜𝑚 (34)
𝑋𝐻2 = 𝑛 𝑎𝑛 (18)
𝐻2 +𝑛𝐻2𝑂 𝑚𝑒𝑚
𝑅𝑇 𝐶𝐻 𝑅𝑇 𝐶𝑂𝑚𝑒𝑚
𝐸𝑐𝑜𝑚 = 2𝐹 𝑙𝑛 ( 2
𝑚𝑒𝑚
𝐶𝐻
) + 2𝐹 𝑙𝑛 ( 2
𝐶𝑂𝑚𝑒𝑚
) (35)
𝑛𝑂2 2,0 2,0
𝑋𝑂2 = 𝑛 𝑎𝑛 (19)
𝑂2 +𝑛𝐻2𝑂
At the membrane-electrode interface, molar
𝑛𝑎𝑛
𝐻2𝑂 concentrations are expressed:
𝑋𝐻𝑎𝑛
2𝑂
=𝑛 𝑎𝑛 (20)
𝐻2 +𝑛𝐻2𝑂
𝑎𝑛
𝛿𝑒𝑙 ×𝑛𝐻2
𝐶𝐻𝑚𝑒𝑚 = 𝐶𝐻𝑐ℎ2 + 𝑎𝑛 (36)
The molar flow of hydrogen through the anode: 2 𝐷𝑒𝑓𝑓
𝑐𝑎𝑡
𝑁̇𝐻2,𝑖 𝛿𝑒𝑙 ×𝑛𝑂2
𝑛𝐻2 = (21) 𝐶𝑂𝑚𝑒𝑚
2
= 𝐶𝑂𝑐ℎ2 + 𝑐𝑎𝑡
𝐷𝑒𝑓𝑓
(37)
𝐴
3
E3S Web of Conferences 229, 01038 (2021) https://doi.org/10.1051/e3sconf/202122901038
ICCSRE’2020
Ω𝐷 =
1.06
+
0.193
+
1.036
+
1.765
(43) 𝑇𝑟𝑒𝑓 303𝐾
𝜏 0.156 𝑒 0.476𝜏 𝑒 1.53𝜏
0.0254 cm
3.894𝜏
𝜖𝑚𝑒𝑚
Ω𝐷 is a dimensionless diffusion collision integral; The ∝𝑎𝑛 0.7
mean molecular radi of species are express as following:
∝𝑐𝑎𝑡 1.7
𝜎𝐻2−𝐻 =
𝜎𝐻2 −𝜎𝐻2𝑂
(44) 𝛾𝑀 47
2𝑂 2
𝜎𝑂2 −𝜎𝐻2𝑂
𝑟𝑒𝑓
𝑖0,𝑎𝑛 1 × 10 𝐴. 𝑐𝑚−2
−4
𝜎𝑂2−𝐻2𝑂 = (45)
2 𝑟𝑒𝑓
𝑖0,𝑐𝑎𝑡 1 × 10−9 𝐴. 𝑐𝑚−2
𝑘𝑇
𝜏𝐻2 −𝐻2 𝑂 =
𝜀𝐻2−𝐻2𝑂
(46) 𝑎𝑛
𝛿𝑒𝑙 0.008 cm
𝑘𝑇
𝜎𝐻2 2.827 A
𝜏𝑂2−𝐻2 𝑂 = (47)
𝜀𝑂2−𝐻2𝑂 𝜎𝑂2 3.467 A
Lennard-Jones energies are expressed as follows: 𝜎𝐻2 𝑂 2.641 A
𝜀𝐻2 −𝐻2 𝑂 = √𝜀𝐻2 𝜀𝐻2 𝑂 (48)
𝜀𝐻2 59.7 K
𝜀𝐻2 𝑂 809.1 K
(49)
𝜀𝑂2−𝐻2 𝑂 = √𝜀𝑂2 𝜀𝐻2 𝑂
𝜀𝑂2 106.7 K
The ohmic overvoltage, resistance of electrodes, plates 𝑀𝐻2 𝑂 18.01528
0.06
𝑒𝑙 𝑝𝑙
and membrane respectively (𝑅𝑜𝑚ℎ , 𝑅𝑜𝑚ℎ 𝑒𝑡 𝑅𝑚𝑒𝑚 ): 𝑟̅
𝑝𝑙
𝑒𝑙
𝐸𝑜ℎ𝑚 = (𝑅𝑜𝑚ℎ + 𝑅𝑜𝑚ℎ +𝑅𝑚𝑒𝑚 )𝐼 (50)
3 Case study and results
𝑝𝑙 𝜌𝑒𝑙
𝑒𝑙
𝑅𝑜𝑚ℎ , 𝑅𝑜𝑚ℎ = (1−𝜀)1.5
(51)
3.1 Energy balance of the building studied.
𝜖 𝐼
𝐸𝑜ℎ𝑚 = 𝐴𝑚𝑒𝑚 (52)
𝜎 𝑚𝑒𝑚 This study will focus on data from a 3-star hotel in Paris
𝜖𝑚𝑒𝑚 𝑖 [20]. We will focus on the consumption of the hotel's
𝑚𝑒𝑚
𝐸𝑜ℎ𝑚 = (53)
𝜎𝑚𝑒𝑚 Heating Ventilation and Air Conditioning (HVAC)
circuits, which represents a significant part of the
The conductivity of the membrane can be empirically consumption of energy within a residence [21]. In
expressed as: addition, this sector is the second energy consumer and
1 1
4
E3S Web of Conferences 229, 01038 (2021) https://doi.org/10.1051/e3sconf/202122901038
ICCSRE’2020
𝑃𝑐 = 𝑇𝑐 × 𝐺𝐸𝑆 (59)
Energy
FE(gCO2e/ Cost (€/10
Pc(€/year) cost
KWh) years)
(€/year)
49 84,476 4318 Fig. 3. Hydrogen production
49 84,476 4318
59 256,32 10881.3
704624,56
59 823,89 34975.5
75 36,204 1209.04
58 304,9756 13169.9
443 14205,41 25854 400594.15
5
E3S Web of Conferences 229, 01038 (2021) https://doi.org/10.1051/e3sconf/202122901038
ICCSRE’2020
6
E3S Web of Conferences 229, 01038 (2021) https://doi.org/10.1051/e3sconf/202122901038
ICCSRE’2020
3.2.4 Cost analysis in thermic power for all the chains. However, this
simulation indicates it is possible to warm up 147
The cost of solar installation and hydrogen production circuits of hot water from the hotel study up to around
can be estimated according to [23-26] 70°C, by convection and thermal conduction.
The economic study carried out shows us a short-
Table 5. Cost estimation over 10 years. term return on investment taking into account the fall in
the cost of solar panels over the next 10 years as opposed
Energy System to the increase in the carbon tax in this same period. A
Description
(Kwh/year) cost (€)
return on investment is estimated from the 5th year for
Electrolysis(599€/kw) 210240 5 247240
the use of green hydrogen compared to the use of
Fuel cell(40€/kw) 210240 350400
electricity + natural gas. This time is much shorter in the
Energy PV 1918440 284700
case of the use of electricity to cover all HVAC needs,
from the three and a half years.
𝑃𝑠𝑡𝑎𝑐𝑘 = 0.15 × 𝐶𝑜𝑠𝑡𝑃𝐸𝑀 (61)
In conclusion, a techno-economic study shows the use
𝑃𝑐𝑙𝑒𝑎𝑛𝑃𝑉 = 26.42 × 𝐴𝑟𝑒𝑎𝑃𝑉 (62) of thermal power of the fuel cell for tertiary heating
provides an interesting return on the investment. Thus,
In this part we present the evolution of the spending of encouraging investors on this sector to use green
the hotel over 10 years ( Figure 10), we note that the hydrogen for a better preventive energy strategy.
calculation takes into account; (61) the cost of solar In short, this techno-economic study shows that the
cleaning each year, as well as (62) the cost of changing use of the thermal power of the fuel cell for tertiary
the stacks every 5 years with the following equations heating makes it possible to obtain an interesting return
[26-27]. on investment thus making it possible to encourage
investors in this sector to use the green hydrogen.
30000000 Note that this cost can be further reduced by using
the water of the reaction in the fuel cell, indeed
20000000 according to statistics, the cost of water has been
Cost €
0
1 2 3 4 5 6 7 8 9 10
years Acknowledgements
PV+H2 electricity+gaz 100% electricity
My most sincere thanks to my supervisors Pr. Rabbah
Nabila and Pr Touati Abdelwahed who accompanies me
Fig. 10. Cost evolution. tirelessly, I also wish to thank Moussavou Fatombi
Bassiratou who help me correct the texts.
Case 1: the red curve shows the evolution of the cost
when the hotel is supplied with electricity and gas (the
DHW circuit supplies with natural gas), against the References
curve in blue solar+hydrogen where we recover 31 kw
of thermal power produced by the reaction when 1. “AR5 Synthesis Report: Climate Change 2014
generating an electrical power of 24kw (Figure 9). This — IPCC.” [Online]. Available:
thermal power generated at 80°C can heat the 147 water https://www.ipcc.ch/report/ar5/syr/. (Accessed:
circuits to 71°C and cover the cost of natural gas. We 07-Jul-2020).
see here that the return on investment is done after 5 2. “Outcomes of COP21 and the IPCC | World
years. Meteorological Organization.” [Online].
Available:
Case 2: This is the solution where all the heating is https://public.wmo.int/en/resources/bulletin/out
based on electricity in green against the solar hydrogen
comes-of-cop21-and-ipcc. (Accessed: 07-Jul-
system with heat recovery in blue. We see here a return
on investment in three and a half years. 2020).
3. M. Pfahler, S. Branner, and H. J. Refior, Die
komplette rotatorenmanschettenruptur -
4 Conclusion Differenzierte op-techniken und mittelfristige
ergebnisse, vol. 137, no. 4. (1999.)
To perform one realistic study of a technical-economic 4. “World Population Prospects - Population
base on evident data, we did the chain model and Division - United Nations.” [Online].
simulation of green hydrogen production for the re- Available: https://population.un.org/wpp/.
electrification by fuel cell PEM. Through this (Accessed: 02-Jul-2020).
simulation, we produce 24KW electric power per day by 5. ADEME, “Base carbone v11,” (2014.)
green hydrogen storage. That electrical production 6. Trajectoires d’évolution du mix électrique 2020-
creates a thermic power of 31 KW at 80ºC to fuel cell.
2060 ADEME. (2020.)
The study demonstrates fuel cells present better results
7
E3S Web of Conferences 229, 01038 (2021) https://doi.org/10.1051/e3sconf/202122901038
ICCSRE’2020