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    Che115b Assignment 1 18 Mar 2024 (Updated) - 2

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    Mushavhi Rudzi

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    Che115b Assignment 1 18 Mar 2024 (Updated) - 2

    Uploaded by

    Mushavhi Rudzi
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    Che115b Assignment 1 18 Mar 2024 (Updated)-2

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    Che115b Assignment 1 18 Mar 2024 (Updated) - 2

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    Chemistry (CHE115B): Assignment 1 Course Code BPML20 18th

    March 2024

    UNIT 2: CHEMICAL REACTION AND STOICHIOMETRY

    1. Arrange these samples in order of increasing numbers of carbon


    atoms: (3)
    (i) 2.69 g 14N,
    (ii) 0.3 mol C4H8,
    (iii) 6.9 × 1019 molecules of SO3.

    2. Calculate the number of H atoms in 0.7130 mol of C12H24O12 (2)

    3. Calculate the number of moles of glucose (C6H12O6) in 5.380 g


    sample. (3)

    4. Calculate the mass, in grams, of 0.639 mol of Barium nitrate. (3)

    5. (a) How many glucose molecules are in 5.23 g of C6H12O6? (4)


    (b) How many oxygen atoms are in this sample? (2)

    6. Determine how many grams of water are produced in the oxidation


    of 4.03 g of glucose, C6H12O6: (3)

    C6H12O6(s) + 6 O2(g) → 6 CO2(g) + 6 H2O(l)

    7. Ascorbic acid (vitamin C) contains 41.00% C, 4.50% H, and 54.50%


    O by mass.

    (a) What is the empirical formula of ascorbic acid? (4)

    8. Isopropyl alcohol, sold as rubbing alcohol, is composed of C, H, and


    O. Combustion of 0.248 g of isopropyl alcohol produces 0.553 g of
    CO2 and 0.299 g of H2O. (8)

    (a) Determine the empirical formula of isopropyl alcohol.

    9. The reaction:
    2 H2(g) + O2(g) → 2 H2O(g)
    is used to produce electricity in a hydrogen fuel cell. Suppose a fuel
    cell contains 3.00 g of H2(g) and 3.000 g of O2(g) (each measured
    to two significant figures).

    (a) How many grams of water can form? (4)

    10. Adipic acid, H2C6H8O4, used to produce nylon, is made


    commercially by a reaction between cyclohexane (C6H12) and O2:

    2 C6H12 (l) + 5 O2(g) → 2 H2C6H8O4(l) + 2 H2O(g)

    Assume that you carry out this reaction with 37.0 g of cyclohexane
    and that cyclohexane is the limiting reactant.

    (a) What is the theoretical yield of adipic acid? (3)

    (b) If you obtain 41.5 g of adipic acid, what is the percent yield for the
    reaction? (2)

    11. How many grams of Na2SO4 are required to make 0.147 L of 0.250
    M Na2SO4? (2)

    12. A solution is made by dissolving 18.4 g of glucose (C6H12O6) in


    0.100 kg of water.

    (a) What is the mass percentage of solute in this solution? (3)

    13. A 1.9 g sample of groundwater was found to contain 3.7 µg of Zn2+.

    (a) What is the concentration of Zn2+ in parts per million? (3)

    14. A solution is made by dissolving 6.31 g of glucose (C6H12O6) in 50.0


    mL of water at 25 °C. Calculate the molality of glucose in the
    solution. Water has a density of 1.00 g/mL. (4)

    15. An aqueous solution of hydrochloric acid contains 37% HCl by


    mass.

    (a) Calculate the mole fraction of HCl in the solution. (4)


    (b) Calculate the molality of HCl in the solution. (4)
    16. A solution with a density of 0.798 g/mL contains 3.2 g of toluene
    (C7H8) and 129 g of benzene. Calculate the molarity of the solution.
    (5)

    17. How many milliliters of 4.3 M H2SO4 are needed to make 650 mL
    of 0.20 M H2SO4? (3)

    18. What is the molar concentration of each ion present in a 0.125 M


    aqueous solution of Magnesium nitrate? (2)

    19. How many grams of Sr(OH)2 are needed to neutralize 50.0 mL of


    0.300 M HNO3? (4)

    20. Classify these ionic compounds as soluble or insoluble in water:

    (i) sodium carbonate, Na2CO3, (2)


    (ii) lead sulfate, PbSO4. (2)

    21. For the reaction between aqueous solutions of acetic acid


    (CH3COOH) and barium hydroxide, Ba(OH)2, write

    (a) the balanced molecular equation, (2)


    (b) the complete ionic equation, (2)
    (c) the net ionic equation. (2)

    Total: 85 Marks

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