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JEE - Chemistry - Mole Concept

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Mole Concept

1. The most abundant elements by mass in the body of a healthy human adult are Oxygen (61.4%);
Carbon (22.9%), Hydrogen (10.0 %); and Nitrogen (2.6%). The weight which a 75 kg person would gain if
all 1H atoms are replaced by 2H atoms is

(a) 15 kg

(b) 37.5 kg

(c) 7.5 kg

(d) 10 kg

2. 1 g of a carbonate (M2CO3) on treatment with excess HCI produces 0.01186 mole of CO2. The molar
mass of M2CO3 in g mol-1 is

(a) 1186

(b) 84.3

(c) 118.6

(d) 11.86

3. Carbon occur in nature as a mixture of C-12 and C-13. Average atomic mass of carbon is 12.011 what
is the % abundance of C-12 in nature ?

(a) 98.9%

(b) 60.9%

(c) 32.9%

(d) 1.4%

4. The molecular formula of a commercial resin used for exchanging ions in water softening is C8H7SO3Na
(molecular weight = 206). What would be the maximum uptake of Ca2+ ions by the resin when expressed
in mole per gram resin?

1
(a)
103

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1
(b)
206
2
(c)
309
1
(d)
412

5. 3 g of activated charcoal was added to 50 mL of acetic acid solution (0.06N) in a flask. After an hour it
was filtered and the strength of the filtrate was found to be 0.042 N. The amount of acetic acid
adsorbed (per gram of charcoal) is

(a) 18 mg

(b) 36 mg

(c) 42 mg

(d) 54 mg

6. The ratio of mass of oxygen and nitrogen of a particular gaseous mixture is 1 : 4. The ratio of number
of their molecule is

(a) 1 : 4

(b) 7 : 32

(c) 1 : 8

(d) 3 : 16

7. The molarity of a solution obtained by mixing 750 mL of 0.5 M HCI with 250 mL of 2 M HCl will be

(a) 0.875 M

(b) 1.00 M

(c) 1.75 M

(d) 0.0975M

8. Dissolving 120 g of area (mol. wt. 60) in 1000 g of water gave a solution of density 1.15 g/mL. The
molarity of the solution is

(a) 1.78 M

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(b) 2.00 M

(c) 2.05 M

(d) 2.22 M

9. Given that the abundances of isotopes 54Fe, 56Fe and 57Fe are 5%, 90% and 5%, respectively, the
atomic mass of Fe is

(a) 55.85

(b) 55.95

(c) 55.75

(d) 56.05

10. Mixture X = 0.02 mole of [Co(NH3)5 SO4]Br and 0.02 mole of [Co(NH3)5 Br]SO4 was prepared in 2 L
solution.

1 L of mature X + excess of AgNO3 solution → Y

1 L of mature X + excess of BaCl2 solution → Z

Number of moles of Y and Z are

(a) 0.01, 0.01

(b) 0.02, 0.01

(c) 0.01, 0.02

(d) 0.02, 0.02

11. Which has maximum number of atoms?

(a) 24 g of C (12)

(b) 56 g of Fe (56)

(c) 27 g of Al (27)

(d) 108 g of Ag (108)

12. How many moles of electron weighs 1 kg?

(a) 6.023 1023

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1
(b) 1031
9.108
6.023
(c) 1054
9.108
1
(d) 108
9.108  6.023

13. The normality of 0.3 M phosphorus acid (H3PO3) is

(a) 0.1

(b) 0.9

(c) 0.3

(d) 0.6

14. In which mode of expression, the concentration of a solution remains independent of temperature?

(a) Molarity

(b) Normality

(c) Formality

(d) Molality

15. A molal solution is one that contains one mole of solute in

(a) 1000 g of solvent

(b) 1.0 L of solvent

(c) 1.0 L of solution

(d) 22.4 L of solution

16. If 0.50 mole of BaCl2 is mixed with 0.20 mole of Na3PO4, the maximum number of moles of Ba3(PO4)2
that can be formed is

(a) 0.70

(b) 0.50

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(c) 0.20

(d) 0.10

17. 2.76 g of silver carbonate on being strongly heated yields a residue weighing

(a) 2.16 g

(b) 2.48 g

(c) 2.32 g

(d) 2.64 g

18. When the same amount of zinc is treated separately with excess of sulphuric acid and excess of
sodium hydroxide, the ratio of volumes of hydrogen evolved is

(a) 1 : 1

(b) 1 : 2

(c) 2 :1

(d) 9: 4

19. The largest number of molecules is in

(a) 36 g of water

(b) 28 g of CO

(c) 46 g of ethyl alcohol

(d) 54 g of nitrogen pentoxide (N2O5)

20. The total number of electrons in one molecule of carbon dioxide is

(a) 22

(b) 44

(c) 66

(d) 88

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21. 7.5 gram of a gas occupies 5.6 litres at STP. The gas is

(a) CO

(b) NO

(c) CO2

(d) N2O

22. A partially dried clay mineral contains 8% water. The original sample contains 12% water and 45%
silica. The % of silica in the partially dried sample is nearly.

(a) 50%

(b) 49%

(c) 55%

(d) 47%

1 1
23. If the mole fraction of a solute is changed from to by adding some solute in the 800 g of H2O
4 2
solvent, then the ratio of molality of two solutions will be :

(a) 1 : 3

(b) 1 : 4

(c) 2 : 3

(d) 1 : 2

24. In the balanced equation

the stoichiometric coefficients of FeS and MnO −4 are in the ratio:

(a) 8 : 5

(b) 5 : 8

(c) 9 : 5

(d) 5 : 9

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25. From the mixture of 4 moles Ca3(PO4)2 and 5 moles of P4O10 and 6 moles of H3PO3 all the phosphorus
atoms are removed then moles of P4 molecule formed from all these atoms is

(a) 8.5

(b) 17

(c) 34

(d) 10

26. The density of a liquid is 1.2 g/mL. There are 35 drops in 2 ml. The number of molecules in one drop
(molar mass of liquid = 70 g/mol) is :

 1.2 
(a)   NA
 35 
2
1  1 
(b)   NA
1.2  35 

1.2
(c) NA
(35) 2

(d) 1.2 NA

27. Sulphur exist in different allotropic forms like S2, S6 and S8 etc. If equal moles of these three forms
are taken in separate containers, then the ratio of number of atoms present in them respectively is :

(a) 1 : 3 : 4

(b) 1 : 1 : 1

(c) 12 : 4 : 3

(d) 4 : 3 : 1

28. There are two sample of HCI having molarity 1M and 0.25 M. Find volume of these sample taken in
order to prepare 0.75 M HCI solution. (Assume no water is used)

(a) 20 ml, 10 ml

(b) 100 ml, 60 ml

(c) 50 ml, 20 ml

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(d) 50 ml, 35 ml

29. The vapour density of a mixture containing equal number of moles of methane and ethane at STP is

(a) 11.5

(b) 11.0

(c) 23

(d) 12.0

30. The temperature at which molarity of pure water is equal to its molality is:

(a) 273 K

(b) 298 K

(c) 277 K

(d) None

31. A compound has the molecular formula X4O6. If 10 g of X4O6 has 5.72 g of X, then atomic mass of X is:

(a) 32 amu

(b) 37 amu

(c) 42 amu

(d) 98 amu

32. Equal masses of oxygen, hydrogen and methane are taken in a container in identical conditions. Find
the ratio of their moles

(a) 1 : 16 : 2

(b) 1 : 16 : 1

(c) 16 : 1 : 1

(d) 16 : 2 : 1

33. Number of electrons in 1.8 mL of H2O ( )

(a) 6.02  1023

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(b) 3.011  1023

(c) 0.6022  1023

(d) 60 22  1023

34. How many gram ions of SO 24 − are present in 1 gram molecule of K2SO4.Al2(SO4)3.24H2O :

(a) 2

(b) 3

(c) 1

(d) 4

35. Which of the following contains same number of molecules ?

(a) 1g of O2, 2g of SO2

(b) 1g of CO2, 1g of NO2

(c) 112 ml of O2 at STP, 224 ml of He at 0.5 atm and 273 K

(d) All of these

36. The density of water at 4C is 1  103 kg m-3. The volume occupied by one molecule of water is
approximately :

(a) 3 x 10-23 ml

(b) 4 x 10-23 ml

(c) 3 x 10-25 ml

(d) 5 x 10-22 ml

37. In the reaction: Na 2S2O3 + 4Cl2 + 5H2O → Na 2SO4 + H2SO4 + 8HCl ,

The equivalent weight of Na2S2O3 will be: (M = molecular weight of Na2S2O3)

(a) M/4

(b) M/8

(c) M/1

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(d) M/2

38. Chlorophyll, the green coloring matter of plants responsible for photosynthesis, contains 2.68% of
magnesium by mass. Calculate the number of magnesium atoms in 2.00g of chlorophyll.

(a) 1.345  1021

(b) 1.345  1020

(c) 13.45  1021

(d) 1.345  1023

39. 6 litre of mixture of methane and propane on complete combustion gives 7 litre of CO2 Find out the
composition of the mixture?

(a) 5.5 lit., 0.5 lit.

(b) 4.5 lit., 1.5 lit.

(c) 3.5 lit., 2.5 lit.

(d) None of these

40. 50 gram of calcium carbonate was completely burnt in air. What is the weight (in grams) of the
residue?

(a) 28

(b) 2.8

(c) 46

(d) 4.8

41. In a compound Carbon = 52.2%, Hydrogen = 13%, Oxygen = 34.8% are present and vapour density of
the compound is 46. Calculate molecular formula of the compound?

(a) C3H6O2

(b) C4H6O2

(c) C4H10O

(d) C4H12O2

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42. Calculate the weight of 90% pure sulphuric acid required to neutralize 5g caustic soda.

(a) 19.19

(b) 6.81

(c) 11.11

(d) None of these

43. 6 g of a hydrocarbon on combustion in excess of oxygen produces 17.6 g of CO2 and 10.8 g of H2O.
The data illustrates the law of

(a) conservation of mass

(b) multiple proportions

(c) constant proportions

(d) reciprocal proportions

44. A breakfast cereal is advertised to contain 110 mg of sodium per 100 g of the cereal. The per cent of
sodium in the cereal is

(a) 0.110%

(b) 0.01 10%

(c) 11.0%

(d) 0.22%

45. How many millilitres of a 9N H2SO4 solution will be required to neutralize completely 20 ml of a 3.6 N
NaOH solution?

(a) 18.0 mL

(b) 8.0 mL

(c) 16.0 mL

(d) 80.0 mL

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Answer Key

1. d 2. b 3. a 4. d 5. d 6. b 7. a 8. c 9. b 10. a
11. a 12. d 13. d 14. d 15. a 16. d 17. a 18. a 19. a 20. a
21. b 22. d 23. a 24. d 25. a 26. c 27. a 28. a 29. a 30. c
31. a 32. a 33. a 34. d 35. d 36. a 37. b 38. a 39. a 40. a
41. d 42. b 43. a 44. a 45. b

1.
Solution:

2.
Solution:

`
3.
Solution:

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4.
Solution:

5.
Solution:

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6.
Solution:

7.
Solution:

8.
Solution:

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9.
Solution:

10.
Solution:

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11.
Solution:

12.
Solution:

13.
Solution:

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14.
Solution:

15.
Solution:

16.
Solution:

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17.
Solution:

18.
Solution:

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19.
Solution:

20.
Solution:

21.
Solution:
7.5 g of gas occupies 5.6 L at STP.

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7.5  4 of gas occupies 22 L at STP 30 grams is the molecular weight of NO gas.

22.

Solution:

23.

Solution:

24.

Solution: The stoichiometric coefficient are in the ratio 5 : 9.


10 FeS + 18 KMnO4 + 32 H2SO4 = 5 Fe2(SO4)3 + 9 K2SO4 + 18 MnSO4 + 32 H2O

25.

Solution:

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26.

Solution:

27.

Solution:

28.

Solution:

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29.

Solution:

30.

Solution:
At 4°c density of water is 1 g/ml.

31.

Solution:

32.

Solution:

33.

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Solution:

34.

Solution:

35.

Solution:

36.

Solution:

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37.

Solution:

38.

Solution:

39.

Solution:

40.

Solution:

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CaCO3 → CaO(residue) + CO2 
100 gram → 56 gram
50 gram gives 56 / 2 = 28 gram

41.

Solution:

42.

Solution:

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43.

Solution:

44.

Solution:
1g
110mg = 110mg  = 0.110g
1000g
0.110g
% of sodium = 100 = 0.110%
100g

45.

Solution:

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